| Common Name: | BONDO GLASS REINFORCED FILLER 271, 272, 272M, 272C, 272E, 272ES, 272K, 272T, 272 |
| Manufacturer: | 3M |
| SDS Revision Date: | 3/18/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 3RAT1 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
3M(TM) BONDO GLASS REINFORCED FILLER 271, 272, 272M, 272C, 272E, 272ES,
272K, 272T, 272W, 274, 274C, 277, 31272
03/18/15
3M
SAFETY DATA SHEET
COPYRIGHT, 2015, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 24-2442-2
VERSION NUMBER: 3.03
ISSUE DATE: 03/18/15
SUPERCEDES DATE: 03/20/14
PRODUCT IDENTIFIER:
3M(TM) BONDO GLASS REINFORCED FILLER 271, 272, 272M, 272C, 272E, 272ES,
272K, 272T, 272W, 274, 274C, 277, 31272
ID NUMBER(S):
60-4550-5656-8, 60-4550-5661-8, 60-4550-5817-6, 60-4550-6594-0,
60-4550-6601-3, 60-4550-7263-1, 60-4550-8124-4
RECOMMENDED USE: AUTOMOTIVE, BODY REPAIR
SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: AUTOMOTIVE AFTERMARKET
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
EMERGENCY TELEPHONE NUMBER: 1-800-364-3577 OR (651) 737-6501 (24 HOURS)
THIS PRODUCT IS A KIT OR A MULTIPART PRODUCT WHICH CONSISTS OF MULTIPLE,
INDEPENDENTLY PACKAGED COMPONENTS. A SAFETY DATA SHEET (SDS), ARTICLE
INFORMATION SHEET (AIS), OR ARTICLE INFORMATION LETTER (AIL) FOR EACH OF
THESE COMPONENTS IS INCLUDED. PLEASE DO NOT SEPARATE THE COMPONENT
DOCUMENTS FROM THIS COVER SHEET.
THE DOCUMENT NUMBERS FOR COMPONENTS OF THIS PRODUCT ARE:
29-5993-0, 24-2443-0
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM
CREAM HARDENER (RED, WHITE & BLUE)
02/21/14
3M
SAFETY DATA SHEET
COPYRIGHT, 2014, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 29-5993-0
VERSION NUMBER: 3.02
ISSUE DATE: 02/21/14
SUPERCEDES DATE: 10/02/12
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER: CREAM HARDENER (RED, WHITE & BLUE)
PRODUCT IDENTIFICATION NUMBERS:
LB-K100-0965-7, LB-K100-0965-8, LB-K100-0965-9, LB-K100-0966-0,
LB-K100-0966-1, LB-K100-0966-2, LB-K100-0966-3, LB-K100-1035-6,
LB-K100-1045-4, LB-K100-1286-7, 41-0003-7987-9, 60-4550-6614-6,
60-4550-6617-9, 60-4550-6830-8, 60-4550-6981-9, 60-4550-6982-7,
60-4550-8123-6
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: AUTOMOTIVE
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: AUTOMOTIVE AFTERMARKET
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
THE LABEL ELEMENTS BELOW WERE PREPARED IN ACCORDANCE WITH OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200. THIS INFORMATION MAY BE DIFFERENT
FROM THE ACTUAL PRODUCT LABEL INFORMATION FOR LABELS REGULATED BY OTHER
AGENCIES.
2.1. HAZARD CLASSIFICATION:
ORGANIC PEROXIDE: TYPE E.
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2A.
SKIN SENSITIZER: CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: WARNING
SYMBOLS:
FLAME
EXCLAMATION MARK
PICTOGRAMS:
FLAME
EXCLAMATION MARK
HAZARD STATEMENTS:
HEATING MAY CAUSE A FIRE.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
PRECAUTIONARY STATEMENTS:
GENERAL: KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
KEEP AWAY FROM CLOTHING AND OTHER COMBUSTIBLE MATERIALS.
KEEP ONLY IN ORIGINAL CONTAINER.
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
STORAGE:
PROTECT FROM SUNLIGHT.
STORE AT TEMPERATURES NOT EXCEEDING 32C/90F. KEEP COOL.
STORE AWAY FROM OTHER MATERIALS.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
NOTES TO PHYSICIAN: NOT APPLICABLE
2.3. HAZARDS NOT OTHERWISE CLASSIFIED: NONE.
6% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE DERMAL TOXICITY.
14% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE INHALATION
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
BENZOYL PEROXIDE 94-36-0 30 - 60 TRADE SECRET *
WATER 7732-18-5 10 - 30 TRADE SECRET *
BENZOIC ACID, C9-11-BRANCHED ALKYL 131298-44-7 10 - 30 TRADE SECRET *
ESTERS
ZINC STEARATE 557-05-1 3 - 7 TRADE SECRET *
OXIRANE, POLYMER WITH METHYLOXIRANE, 9038-95-3 1 - 5 TRADE SECRET *
MONOBUTYL ETHER
CALCIUM SULFATE 7778-18-9 1 - 5 TRADE SECRET *
IRON OXIDE (FE2O3) 1309-37-1 1 - 5 TRADE SECRET *
FERRIC FERROCYANIDE 14038-43-8 0 - 1 TRADE SECRET *
FERRIC AMMONIUM FERROCYANIDE 25869-00-5 0 - 1 TRADE SECRET *
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF
EASY TO DO. CONTINUE RINSING. GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY COMBUSTIBLE MATERIAL SUCH
AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY BUILD PRESSURE AND EXPLODE.
PART OF THE OXYGEN FOR COMBUSTION IS SUPPLIED BY THE PEROXIDE ITSELF.
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO UNUSUAL FIRE OR EXPLOSION HAZARDS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. ELIMINATE ALL IGNITION SOURCES IF SAFE TO DO SO. KEEP AWAY
FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. USE ONLY
NON-SPARKING TOOLS. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE.
WARNING!
A MOTOR COULD BE AN IGNITION SOURCE AND COULD CAUSE FLAMMABLE GASES OR
VAPORS IN THE SPILL AREA TO BURN OR EXPLODE. REFER TO OTHER SECTIONS OF
THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH HAZARDS, RESPIRATORY
PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND BUILD
DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER
WITH BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT
MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER,
ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR
ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE
USING NON-SPARKING TOOLS. CLEAN UP RESIDUE WITH AN APPROPRIATE SOLVENT
SELECTED BY A QUALIFIED AND AUTHORIZED PERSON. VENTILATE THE AREA WITH
FRESH AIR. READ AND FOLLOW SAFETY PRECAUTIONS ON THE SOLVENT LABEL AND SDS.
SEAL THE CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
AVOID BREATHING OF DUST CREATED BY CUTTING, SANDING, GRINDING OR MACHINING.
DO NOT USE IN A CONFINED AREA WITH MINIMAL AIR EXCHANGE. KEEP OUT OF REACH
OF CHILDREN. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO
SMOKING. AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN
EYES, ON SKIN, OR ON CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS
PRODUCT. WASH THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD
NOT BE ALLOWED OUT OF THE WORKPLACE. AVOID RELEASE TO THE ENVIRONMENT. WASH
CONTAMINATED CLOTHING BEFORE REUSE.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
KEEP CONTAINER TIGHTLY CLOSED. PROTECT FROM SUNLIGHT. STORE AWAY FROM HEAT.
STORE AT TEMPERATURES NOT EXCEEDING 32C/90F. KEEP COOL. KEEP ONLY IN
ORIGINAL CONTAINER. STORE AWAY FROM OTHER MATERIALS. KEEP/STORE AWAY FROM
CLOTHING AND OTHER COMBUSTIBLE MATERIALS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
IRON OXIDE (FE2O3) 1309-37-1 AMER CONF OF TWA (RESPIRABLE
GOV. INDUST. FRACTION):
HYG. 5 MG/M3
IRON OXIDE (FE2O3) 1309-37-1 US DEPT OF TWA (AS FUME):
LABOR - OSHA 10 MG/M3
CYANIDES 14038-43-8 US DEPT OF TWA (AS CN): SKIN
LABOR - OSHA 5 MG/M3 NOTATION
ZINC STEARATE 557-05-1 US DEPT OF TWA (AS TOTAL
LABOR - OSHA DUST):
15 MG/M3
TWA (RESPIRABLE
FRACTION):
5 MG/M3
CALCIUM SULFATE 7778-18-9 AMER CONF OF TWA (INHALABLE
GOV. INDUST. FRACTION):
HYG. 10 MG/M3
CALCIUM SULFATE 7778-18-9 US DEPT OF TWA (AS TOTAL
LABOR - OSHA DUST):
15 MG/M3
TWA (RESPIRABLE
FRACTION):
5 MG/M3
BENZOYL PEROXIDE 94-36-0 AMER CONF OF TWA: 5 MG/M3
GOV. INDUST.
HYG.
BENZOYL PEROXIDE 94-36-0 US DEPT OF TWA: 5 MG/M3
LABOR - OSHA
AMER CONF OF GOV. INDUST. HYG.:
AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AMERICAN INDUST. HYGIENE ASSOC: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CHEMICAL MANUFACTURER REC GUID:
CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
US DEPT OF LABOR - OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
PROVIDE VENTILATION ADEQUATE TO MAINTAIN DUST CONCENTRATION BELOW MINIMUM
EXPLOSIVE CONCENTRATIONS. USE GENERAL DILUTION VENTILATION AND/OR LOCAL
EXHAUST VENTILATION TO CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT
EXPOSURE LIMITS AND/OR CONTROL DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF
VENTILATION IS NOT ADEQUATE, USE RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT. THE FOLLOWING EYE/FACE PROTECTION(S) ARE
RECOMMENDED: INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED: NITRILE RUBBER
IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL FOR
EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF PROTECTIVE
COVERALLS MAY BE NECESSARY. SELECT AND USE BODY PROTECTION TO PREVENT
CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT. THE FOLLOWING
PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED: APRON - NITRILE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: SOLID
SPECIFIC PHYSICAL FORM: VISCOUS
ODOR, COLOR, GRADE: RED PASTE WITH SLIGHT ESTER ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: 111 DEG. C [TEST METHOD: ESTIMATED]
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS):
ORGANIC PEROXIDE: TYPE E.
FLAMMABLE LIMITS (LEL): NOT APPLICABLE
FLAMMABLE LIMITS (UEL): NOT APPLICABLE
VAPOR PRESSURE: NOT APPLICABLE
VAPOR DENSITY: NOT APPLICABLE
DENSITY: 1.2 G/CM3
SPECIFIC GRAVITY: 1.2 [@ 25 DEG. C] [REF STD: WATER=1]
SOLUBILITY IN WATER: NEGLIGIBLE
SOLUBILITY- NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/ WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: NO DATA AVAILABLE
HAZARDOUS AIR POLLUTANTS: 0% WEIGHT [TEST METHOD: CALCULATED]
VOLATILE ORGANIC COMPOUNDS:
0 LB/GAL [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
VOLATILE ORGANIC COMPOUNDS:
0 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
VOLATILE ORGANIC COMPOUNDS:
0% WEIGHT [TEST METHOD: CALCULATED PER CARB TITLE 2]
PERCENT VOLATILE: 20% [DETAILS: WATER IS THE VOLATILE COMPONENT]
VOC LESS H2O & EXEMPT SOLVENTS:
0 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY:
STABLE. STABLE UNLESS EXPOSED TO HEAT, FLAMES AND DRYING CONDITIONS.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: HEAT
10.5. INCOMPATIBLE MATERIALS: ACCELERATORS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE NOT SPECIFIED
CARBON DIOXIDE NOT SPECIFIED
TOXIC VAPOR, GAS, PARTICULATE NOT SPECIFIED
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
MAY BE HARMFUL IF INHALED. RESPIRATORY TRACT IRRITATION: SIGNS/SYMPTOMS MAY
INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE, HOARSENESS, AND NOSE
AND THROAT PAIN.
SKIN CONTACT:
MAY BE HARMFUL IN CONTACT WITH SKIN.
CONTACT WITH THE SKIN DURING PRODUCT USE IS NOT EXPECTED TO RESULT IN
SIGNIFICANT IRRITATION. ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
SEVERE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE SIGNIFICANT REDNESS, SWELLING, PAIN, TEARING,
CLOUDY APPEARANCE OF THE CORNEA, AND IMPAIRED VISION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE:
4,339.3 MG/KG
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE;
DUST/MIST CALCULATED ATE:
(4 HR) 10.7 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
BENZOYL PEROXIDE DERMAL LD50:
ESTIMATED TO BE
2,000 - 5,000 MG/KG
BENZOYL PEROXIDE INHALATION- RAT LC50: >24.3 MG/L
DUST/MIST
(4 HOURS)
BENZOYL PEROXIDE INGESTION RAT LD50: >5,000 MG/KG
BENZOIC ACID, C9-11- DERMAL RABBIT LD50: >2,000 MG/KG
BRANCHED ALKYL ESTERS
BENZOIC ACID, C9-11- INHALATION- RAT LC50: 2 MG/L
BRANCHED ALKYL ESTERS DUST/MIST
(4 HOURS)
BENZOIC ACID, C9-11- INGESTION RAT LD50: >5,000 MG/KG
BRANCHED ALKYL ESTERS
ZINC STEARATE DERMAL RABBIT LD50: >2,000 MG/KG
ZINC STEARATE INGESTION RAT LD50: >5,000 MG/KG
OXIRANE, POLYMER WITH DERMAL RABBIT LD50: >16,960 MG/KG
METHYLOXIRANE, MONOBUTYL
ETHER
CALCIUM SULFATE INGESTION RAT LD50: >5,000 MG/KG
OXIRANE, POLYMER WITH INHALATION- RAT LC50: >5 MG/L
METHYLOXIRANE, MONOBUTYL DUST/MIST
ETHER (4 HOURS)
OXIRANE, POLYMER WITH INGESTION RAT LD50: 4,240 MG/KG
METHYLOXIRANE, MONOBUTYL
ETHER
IRON OXIDE (FE2O3) DERMAL NOT LD50: 3,100 MG/KG
AVAILABLE
IRON OXIDE (FE2O3) INGESTION NOT LD50: 3,700 MG/KG
AVAILABLE
FERRIC AMMONIUM INGESTION RAT LD50: >5,110 MG/KG
FERROCYANIDE
FERRIC FERROCYANIDE INGESTION RAT LD50: >8,000 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
BENZOYL PEROXIDE RABBIT MINIMAL IRRITATION
OXIRANE, POLYMER WITH RABBIT MINIMAL IRRITATION
METHYLOXIRANE, MONOBUTYL ETHER
IRON OXIDE (FE2O3) RABBIT NO SIGNIFICANT IRRITATION
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
BENZOYL PEROXIDE RABBIT SEVERE IRRITANT
OXIRANE, POLYMER WITH RABBIT NO SIGNIFICANT IRRITATION
METHYLOXIRANE, MONOBUTYL ETHER
IRON OXIDE (FE2O3) RABBIT NO SIGNIFICANT IRRITATION
SKIN SENSITIZATION:
NAME SPECIES VALUE
BENZOYL PEROXIDE HUMAN SENSITIZING
AND
ANIMAL
IRON OXIDE (FE2O3) HUMAN SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
RESPIRATORY SENSITIZATION:
NAME SPECIES VALUE
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
BENZOYL PEROXIDE IN VITRO NOT MUTAGENIC
BENZOYL PEROXIDE IN VIVO NOT MUTAGENIC
IRON OXIDE (FE2O3) IN VITRO NOT MUTAGENIC
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
BENZOYL PEROXIDE INGESTION MULTIPLE NOT CARCINOGENIC
ANIMAL
SPECIES
BENZOYL PEROXIDE DERMAL MOUSE SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
OXIRANE, POLYMER WITH INGESTION RAT NOT CARCINOGENIC
METHYLOXIRANE,
MONOBUTYL ETHER
IRON OXIDE (FE2O3) INHALATION HUMAN SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
BENZOYL PEROXIDE INGESTION NOT TOXIC TO FEMALE
REPRODUCTION
BENZOYL PEROXIDE INGESTION SOME POSITIVE MALE
REPRODUCTIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
BENZOYL PEROXIDE INGESTION SOME POSITIVE
DEVELOPMENTAL DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
OXIRANE, POLYMER WITH METHYLOXIRANE, INGESTION NOT TOXIC TO FEMALE
MONOBUTYL ETHER REPRODUCTION
OXIRANE, POLYMER WITH METHYLOXIRANE, INGESTION NOT TOXIC TO MALE
MONOBUTYL ETHER REPRODUCTION
OXIRANE, POLYMER WITH METHYLOXIRANE, INHALATION SOME POSITIVE MALE
MONOBUTYL ETHER REPRODUCTIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
BENZOYL PEROXIDE RAT NOAEL: 1,000 MG/KG/DAY PREMATING &
DURING GESTATION
BENZOYL PEROXIDE RAT NOAEL: 500 MG/KG/DAY PREMATING &
DURING GESTATION
BENZOYL PEROXIDE RAT NOAEL: 500 MG/KG/DAY PREMATING &
DURING GESTATION
OXIRANE, POLYMER RAT NOAEL: 3,770 MG/KG/DAY 90 DAYS
WITH METHYLOXIRANE,
MONOBUTYL ETHER
OXIRANE, POLYMER RAT NOAEL: 3,770 MG/KG/DAY 90 DAYS
WITH METHYLOXIRANE,
MONOBUTYL ETHER
OXIRANE, POLYMER RAT NOAEL: 1 MG/L 2 WEEKS
WITH METHYLOXIRANE,
MONOBUTYL ETHER
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
OXIRANE, POLYMER WITH INGESTION NERVOUS SYSTEM SOME POSITIVE DATA
METHYLOXIRANE, EXIST, BUT THE DATA
MONOBUTYL ETHER ARE NOT SUFFICIENT
FOR CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
OXIRANE, POLYMER WITH RAT NOAEL: NOT AVAILABLE
METHYLOXIRANE,
MONOBUTYL ETHER
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
OXIRANE, POLYMER INHALATION ENDOCRINE SYSTEM SOME POSITIVE DATA
WITH METHYLOXIRANE, HEMATOPOIETIC SYSTEM EXIST, BUT THE DATA
MONOBUTYL ETHER LIVER ARE NOT SUFFICIENT
NERVOUS SYSTEM FOR CLASSIFICATION
OXIRANE, POLYMER INHALATION KIDNEY AND/OR BLADDER SOME POSITIVE DATA
WITH METHYLOXIRANE, EXIST, BUT THE DATA
MONOBUTYL ETHER ARE NOT SUFFICIENT
FOR CLASSIFICATION
OXIRANE, POLYMER INHALATION RESPIRATORY SYSTEM SOME POSITIVE DATA
WITH METHYLOXIRANE, EXIST, BUT THE DATA
MONOBUTYL ETHER ARE NOT SUFFICIENT
FOR CLASSIFICATION
OXIRANE, POLYMER INHALATION HEART ALL DATA ARE
WITH METHYLOXIRANE, NEGATIVE
MONOBUTYL ETHER
OXIRANE, POLYMER INGESTION LIVER SOME POSITIVE DATA
WITH METHYLOXIRANE, KIDNEY AND/OR BLADDER EXIST, BUT THE DATA
MONOBUTYL ETHER ARE NOT SUFFICIENT
FOR CLASSIFICATION
OXIRANE, POLYMER INGESTION HEMATOPOIETIC SYSTEM ALL DATA ARE
WITH METHYLOXIRANE, NEGATIVE
MONOBUTYL ETHER
OXIRANE, POLYMER INGESTION HEART ALL DATA ARE
WITH METHYLOXIRANE, ENDOCRINE SYSTEM NEGATIVE
MONOBUTYL ETHER RESPIRATORY SYSTEM
IRON OXIDE (FE2O3) INHALATION PULMONARY FIBROSIS SOME POSITIVE DATA
PNEUMOCONIOSIS EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
OXIRANE, POLYMER RAT NOAEL: 1 MG/L 2 WEEKS
WITH METHYLOXIRANE,
MONOBUTYL ETHER
OXIRANE, POLYMER RAT NOAEL: .005 MG/L 2 WEEKS
WITH METHYLOXIRANE,
MONOBUTYL ETHER
OXIRANE, POLYMER RAT LOAEL: .001 MG/L 2 WEEKS
WITH METHYLOXIRANE,
MONOBUTYL ETHER
OXIRANE, POLYMER RAT NOAEL: .5 MG/L 2 WEEKS
WITH METHYLOXIRANE,
MONOBUTYL ETHER
OXIRANE, POLYMER RAT NOAEL: 145 MG/KG/DAY 90 DAYS
WITH METHYLOXIRANE,
MONOBUTYL ETHER
OXIRANE, POLYMER RAT NOAEL: 500 MG/KG/DAY 2 YEARS
WITH METHYLOXIRANE,
MONOBUTYL ETHER
OXIRANE, POLYMER RAT NOAEL: 3,770 MG/KG/DAY 90 DAYS
WITH METHYLOXIRANE,
MONOBUTYL ETHER
IRON OXIDE (FE2O3) HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL
EXPOSURE
ASPIRATION HAZARD:
NAME VALUE
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/ CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
INCINERATE UNCURED PRODUCT IN A PERMITTED WASTE INCINERATION FACILITY.
PROPER DESTRUCTION MAY REQUIRE THE USE OF ADDITIONAL FUEL DURING
INCINERATION PROCESSES. EMPTY DRUMS/BARRELS/CONTAINERS USED FOR
TRANSPORTING AND HANDLING HAZARDOUS CHEMICALS (CHEMICAL
SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS HAZARDOUS AS PER APPLICABLE
REGULATIONS) SHALL BE CONSIDERED, STORED, TREATED & DISPOSED OF AS
HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY APPLICABLE WASTE REGULATIONS.
CONSULT WITH THE RESPECTIVE REGULATING AUTHORITIES TO DETERMINE THE
AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: YES
PRESSURE HAZARD: NO
REACTIVITY HAZARD: YES
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
ZINC STEARATE (ZINC COMPOUNDS) 557-05-1 3 - 7
BENZOYL PEROXIDE 94-36-0 30 - 60
FERRIC FERROCYANIDE (CYANIDES) 14038-43-8 0 - 1
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 2
INSTABILITY 1
SPECIAL HAZARDS OXIDIZER
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
HMIS HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
PHYSICAL HAZARD 1
PERSONAL PROTECTION X - SEE PPE SECTION.
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM (HMIS(R*) III) HAZARD RATINGS ARE
DESIGNED TO INFORM EMPLOYEES OF CHEMICAL HAZARDS IN THE WORKPLACE. THESE
RATINGS ARE BASED ON THE INHERENT PROPERTIES OF THE MATERIAL UNDER EXPECTED
CONDITIONS OF NORMAL USE AND ARE NOT INTENDED FOR USE IN EMERGENCY
SITUATIONS. HMIS(R*) III RATINGS ARE TO BE USED WITH A FULLY IMPLEMENTED
HMIS(R*) III PROGRAM. HMIS(R*) IS A REGISTERED MARK OF THE AMERICAN
COATINGS ASSOCIATION (ACA).
DOCUMENT GROUP: 29-5993-0
VERSION NUMBER: 3.02
ISSUE DATE: 02/21/14
SUPERCEDES DATE: 10/02/12
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM
3M(TM) BONDO GLASS REINFORCED FILLER, P.N. 270, 271, 272, 272C, 272E,
272ES, 272K, 272T, 272W, 274, 274C, 277
04/17/15
3M
SAFETY DATA SHEET
COPYRIGHT, 2015, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 24-2443-0
VERSION NUMBER: 9.01
ISSUE DATE: 04/17/15
SUPERCEDES DATE: 03/18/15
| SECTION 1: IDENTIFICATION | |
1.1. PRODUCT IDENTIFIER:
3M(TM) BONDO GLASS REINFORCED FILLER, P.N. 270, 271, 272, 272C, 272E,
272ES, 272K, 272T, 272W, 274, 274C, 277
PRODUCT IDENTIFICATION NUMBERS:
LB-K100-0411-5, LB-K100-0411-6, LB-K100-0525-3, LB-K100-0525-4,
LB-K100-0525-6, LB-K100-1045-3, LB-K100-1380-6, 41-3701-1515-0
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: AUTOMOTIVE, REPAIRING AUTOBODY
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: AUTOMOTIVE AFTERMARKET
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
THE LABEL ELEMENTS BELOW WERE PREPARED IN ACCORDANCE WITH OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200. THIS INFORMATION MAY BE DIFFERENT
FROM THE ACTUAL PRODUCT LABEL INFORMATION FOR LABELS REGULATED BY OTHER
AGENCIES.
2.1. HAZARD CLASSIFICATION:
FLAMMABLE LIQUID: CATEGORY 3.
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2B.
CARCINOGENICITY: CATEGORY 2.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 1.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
FLAME
HEALTH HAZARD
PICTOGRAMS:
FLAME
HEALTH HAZARD
HAZARD STATEMENTS:
FLAMMABLE LIQUID AND VAPOR.
CAUSES EYE IRRITATION.
SUSPECTED OF CAUSING CANCER.
CAUSES DAMAGE TO ORGANS:
LIVER
SENSORY ORGANS
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE:
RESPIRATORY SYSTEM
SENSORY ORGANS
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE: LIVER
PRECAUTIONARY STATEMENTS:
GENERAL: KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
USE ONLY NON-SPARKING TOOLS.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
KEEP CONTAINER TIGHTLY CLOSED.
USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING EQUIPMENT.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
RESPONSE:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR FLAMMABLE LIQUIDS SUCH AS DRY
CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED: NONE.
2% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE ORAL TOXICITY.
51% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE DERMAL
TOXICITY.
37% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE INHALATION
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
POLYESTER RESIN TRADE SECRET* 15 - 40 TRADE SECRET *
TALC 14807-96-6 15 - 40 TRADE SECRET *
STYRENE MONOMER 100-42-5 10 - 30 TRADE SECRET *
MAGNESIUM CARBONATE 546-93-0 10 - 30 TRADE SECRET *
GLASS FILAMENT 65997-17-3 3 - 7 TRADE SECRET *
ANY REMAINING COMPONENTS DO NOT CONTRIBUTE TO THE HAZARDS OF THIS MATERIAL.
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTACT LENSES IF EASY TO DO. CONTINUE RINSING. IMMEDIATELY GET
MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR FLAMMABLE LIQUIDS SUCH AS DRY
CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY BUILD PRESSURE AND EXPLODE.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
HYDROCARBONS DURING COMBUSTION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
TOXIC VAPOR, GAS, PARTICULATE DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
WATER MAY NOT EFFECTIVELY EXTINGUISH FIRE; HOWEVER, IT SHOULD BE USED TO
KEEP FIRE-EXPOSED CONTAINERS AND SURFACES COOL AND PREVENT EXPLOSIVE
RUPTURE.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO
SMOKING. USE ONLY NON-SPARKING TOOLS. VENTILATE THE AREA WITH FRESH AIR.
REFER TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND
HEALTH HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL
PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND BUILD
DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
COVER SPILL AREA WITH A FIRE-EXTINGUISHING FOAM. AN APPROPRIATE AQUEOUS
FILM FORMING FOAM (AFFF) IS RECOMMENDED. WORKING FROM AROUND THE EDGES OF
THE SPILL INWARD, COVER WITH BENTONITE, VERMICULITE, OR COMMERCIALLY
AVAILABLE INORGANIC ABSORBENT MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL
IT APPEARS DRY. REMEMBER, ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A
PHYSICAL, HEALTH, OR ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED
MATERIAL AS POSSIBLE USING NON-SPARKING TOOLS. PLACE IN A METAL CONTAINER
APPROVED FOR TRANSPORTATION BY APPROPRIATE AUTHORITIES. CLEAN UP RESIDUE
WITH AN APPROPRIATE SOLVENT SELECTED BY A QUALIFIED AND AUTHORIZED PERSON.
VENTILATE THE AREA WITH FRESH AIR. READ AND FOLLOW SAFETY PRECAUTIONS ON
THE SOLVENT LABEL AND SDS. SEAL THE CONTAINER. DISPOSE OF COLLECTED
MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
AVOID BREATHING OF DUST CREATED BY CUTTING, SANDING, GRINDING OR MACHINING.
KEEP OUT OF REACH OF CHILDREN. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS
HAVE BEEN READ AND UNDERSTOOD. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT
SURFACES. - NO SMOKING. USE ONLY NON-SPARKING TOOLS. TAKE PRECAUTIONARY
MEASURES AGAINST STATIC DISCHARGE. DO NOT BREATHE
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. AVOID CONTACT WITH OXIDIZING AGENTS (EG.
CHLORINE, CHROMIC ACID ETC.) WEAR LOW STATIC OR PROPERLY GROUNDED SHOES.
USE PERSONAL PROTECTIVE EQUIPMENT (GLOVES, RESPIRATORS, ETC.) AS REQUIRED.
TO MINIMIZE THE RISK OF IGNITION, DETERMINE APPLICABLE ELECTRICAL
CLASSIFICATIONS FOR THE PROCESS USING THIS PRODUCT AND SELECT SPECIFIC
LOCAL EXHAUST VENTILATION EQUIPMENT TO AVOID FLAMMABLE VAPOR ACCUMULATION.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT IF THERE IS POTENTIAL FOR
STATIC ELECTRICITY ACCUMULATION DURING TRANSFER.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE IN A WELL-VENTILATED PLACE. KEEP COOL. KEEP CONTAINER TIGHTLY CLOSED.
STORE AWAY FROM HEAT. STORE AWAY FROM ACIDS. STORE AWAY FROM STRONG BASES.
STORE AWAY FROM OXIDIZING AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
STYRENE MONOMER 100-42-5 ACGIH TWA: 20 PPM A4:
STEL: 40 PPM NOT CLASS.
AS HUMAN
CARCIN
STYRENE MONOMER 100-42-5 OSHA TWA: 100 PPM
CEIL: 200 PPM
TALC 14807-96-6 ACGIH TWA (RESPIRABLE A4:
FRACTION): NOT CLASS.
2 MG/M3 AS HUMAN
CARCIN
TALC 14807-96-6 CMRG TWA (AS
RESPIRABLE
DUST):
0.5 MG/M3
TALC 14807-96-6 OSHA TWA
CONCENTRATION
(AS TOTAL
DUST):
0.3 MG/M3
TWA
CONCENTRATION
(RESPIRABLE):
0.1 MG/M3
(2.4 MILLIONS
OF PARTICLES/
CU. FT.)
TWA:
20 MILLIONS
OF PARTICLES/
CU. FT.
MAGNESIUM 546-93-0 OSHA TWA (AS TOTAL
CARBONATE DUST):
15 MG/M3
TWA (RESPIRABLE
FRACTION):
5 MG/M3
CERAMIC FIBERS 65997-17-3 ACGIH TWA (AS FIBER): A2:
0.2 FIBER/CC SUSPECTED
HUMAN
CARCIN.
GLASS FILAMENT 65997-17-3 MANUFACTURER TWA (AS DUST):
DETERMINED 10 MG/M3
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT. USE EXPLOSION-PROOF VENTILATION
EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT. THE FOLLOWING EYE/FACE PROTECTION(S) ARE
RECOMMENDED: INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED: FLUOROELASTOMER
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
SPECIFIC PHYSICAL FORM: PASTE
ODOR, COLOR, GRADE: PUNGENT ORGANIC ODOR. GREEN.
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
BOILING POINT: 293 DEG. F
FLASH POINT: 88 DEG. F [TEST METHOD: CLOSED CUP]
EVAPORATION RATE: <=1 [REF STD: ETHER=1]
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS (LEL): 1.1%
FLAMMABLE LIMITS (UEL): NO DATA AVAILABLE
VAPOR PRESSURE: 4.5 MMHg
VAPOR DENSITY: 3.6 [REF STD: AIR=1]
VAPOR DENSITY: NO DATA AVAILABLE
DENSITY: 1.638 G/ML
SPECIFIC GRAVITY: 1.638 [REF STD: WATER=1]
SOLUBILITY IN WATER: NO DATA AVAILABLE
SOLUBILITY IN WATER: NEGLIGIBLE
SOLUBILITY- NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/ WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: NO DATA AVAILABLE
HAZARDOUS AIR POLLUTANTS: 0.27 LB HAPS/LB SOLIDS [TEST METHOD: CALCULATED]
VOLATILE ORGANIC COMPOUNDS:
247 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
VOLATILE ORGANIC COMPOUNDS:
15.1% WEIGHT [TEST METHOD: CALCULATED PER CARB TITLE 2]
PERCENT VOLATILE: 15.1% WEIGHT
VOC LESS H2O & EXEMPT SOLVENTS:
247 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID:
HEAT
SPARKS AND/OR FLAMES
10.5. INCOMPATIBLE MATERIALS:
STRONG ACIDS
STRONG BASES
STRONG OXIDIZING AGENTS
ALKALI AND ALKALINE EARTH METALS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
MAY BE HARMFUL IF INHALED.
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
MILD SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, AND
DRYNESS.
EYE CONTACT:
MODERATE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, PAIN, TEARING, AND BLURRED OR
HAZY VISION.
INGESTION:
MAY BE HARMFUL IF SWALLOWED.
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
SINGLE EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
AUDITORY EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE HEARING IMPAIRMENT, BALANCE DYSFUNCTION AND
RINGING IN THE EARS.
LIVER EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE LOSS OF APPETITE, WEIGHT LOSS, FATIGUE,
WEAKNESS, ABDOMINAL TENDERNESS AND JAUNDICE.
PROLONGED OR REPEATED EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
PNEUMOCONIOSIS:
SIGN/SYMPTOMS MAY INCLUDE PERSISTENT COUGH, BREATHLESSNESS, CHEST PAIN,
INCREASED AMOUNTS OF SPUTUM, AND CHANGES IN LUNG FUNCTION TESTS.
OCULAR EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE BLURRED OR SIGNIFICANTLY IMPAIRED VISION.
AUDITORY EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE HEARING IMPAIRMENT, BALANCE DYSFUNCTION AND
RINGING IN THE EARS.
LIVER EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE LOSS OF APPETITE, WEIGHT LOSS, FATIGUE,
WEAKNESS, ABDOMINAL TENDERNESS AND JAUNDICE.
CARCINOGENICITY: CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE CANCER.
INGREDIENT CAS NO. CLASS DESCRIPTION REGULATION
GENERIC: 65997-17-3 GRP. 2B: INTERNATIONAL AGENCY
CERAMIC FIBERS POSSIBLE HUMAN CARC. FOR RESEARCH ON
CANCER
GENERIC: 65997-17-3 ANTICIPATED HUMAN NATIONAL TOXICOLOGY
CERAMIC FIBERS CARCINOGEN PROGRAM CARCINOGENS
GENERIC: 65997-17-3 ANTICIPATED HUMAN NATIONAL TOXICOLOGY
GLASS FILAMENTS CARCINOGEN PROGRAM CARCINOGENS
STYRENE MONOMER 100-42-5 GRP. 2B: INTERNATIONAL AGENCY
POSSIBLE HUMAN CARC. FOR RESEARCH ON
CANCER
STYRENE MONOMER 100-42-5 ANTICIPATED HUMAN NATIONAL TOXICOLOGY
CARCINOGEN PROGRAM CARCINOGENS
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE;
VAPOR CALCULATED ATE:
(4 HR) 20 - 50 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
2,000 - 5,000 MG/KG
TALC DERMAL LD50: NOT AVAILABLE
TALC INGESTION LD50: NOT AVAILABLE
POLYESTER RESIN INGESTION LD50:
ESTIMATED TO BE
2,000 - 5,000 MG/KG
MAGNESIUM CARBONATE INGESTION MOUSE LD50: >5,000 MG/KG
STYRENE MONOMER DERMAL RAT LD50: >2,000 MG/KG
STYRENE MONOMER INHALATION- RAT LC50: 8.3 MG/L
VAPOR
(4 HOURS)
STYRENE MONOMER INGESTION RAT LD50: 5,000 MG/KG
GLASS FILAMENT DERMAL LD50:
ESTIMATED TO BE
>5,000 MG/KG
GLASS FILAMENT INGESTION LD50:
ESTIMATED TO BE
2,000 - 5,000 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
TALC RABBIT NO SIGNIFICANT IRRITATION
MAGNESIUM CARBONATE IN VITRO MINIMAL IRRITATION
DATA
STYRENE MONOMER OFFICIAL MILD IRRITANT
CLASSIFICATION
GLASS FILAMENT PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGEMENT
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
TALC RABBIT NO SIGNIFICANT IRRITATION
MAGNESIUM CARBONATE RABBIT MILD IRRITANT
STYRENE MONOMER OFFICIAL MODERATE IRRITANT
CLASSIFICATION
GLASS FILAMENT PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGEMENT
SKIN SENSITIZATION:
NAME SPECIES VALUE
STYRENE MONOMER GUINEA NOT SENSITIZING
PIG
RESPIRATORY SENSITIZATION:
NAME SPECIES VALUE
TALC HUMAN NOT SENSITIZING
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
TALC IN VITRO NOT MUTAGENIC
TALC IN VIVO NOT MUTAGENIC
STYRENE MONOMER IN VITRO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
STYRENE MONOMER IN VIVO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
GLASS FILAMENT IN VITRO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
TALC INHALATION RAT SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
STYRENE MONOMER INGESTION MOUSE CARCINOGENIC
STYRENE MONOMER INHALATION HUMAN CARCINOGENIC
AND
ANIMAL
GLASS FILAMENT INHALATION MULTIPLE SOME POSITIVE DATA EXIST,
ANIMAL BUT THE DATA ARE NOT
SPECIES SUFFICIENT FOR
CLASSIFICATION
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
TALC INGESTION NOT TOXIC TO DEVELOPMENT
STYRENE MONOMER INGESTION NOT TOXIC TO FEMALE REPRODUCTION
STYRENE MONOMER INHALATION NOT TOXIC TO FEMALE REPRODUCTION
STYRENE MONOMER INHALATION NOT TOXIC TO MALE REPRODUCTION
STYRENE MONOMER INGESTION SOME POSITIVE MALE REPRODUCTIVE
DATA EXIST, BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
STYRENE MONOMER INGESTION SOME POSITIVE DEVELOPMENTAL DATA
EXIST, BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
STYRENE MONOMER INHALATION SOME POSITIVE DEVELOPMENTAL DATA
EXIST, BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
TALC RAT NOAEL: 1,600 MG/KG DURING
ORGANOGENESIS
STYRENE MONOMER RAT NOAEL: 21 MG/KG/DAY 3 GENERATION
STYRENE MONOMER RAT NOAEL: 2.1 MG/L 2 GENERATION
STYRENE MONOMER RAT NOAEL: 2.1 MG/L 2 GENERATION
STYRENE MONOMER RAT NOAEL: 400 MG/KG/DAY 60 DAYS
STYRENE MONOMER RAT NOAEL: 400 MG/KG/DAY DURING GESTATION
STYRENE MONOMER MULTIPLE NOAEL: 2.1 MG/L DURING GESTATION
ANIMAL
SPECIES
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
STYRENE MONOMER INHALATION AUDITORY SYSTEM CAUSES DAMAGE TO
ORGANS
STYRENE MONOMER INHALATION LIVER CAUSES DAMAGE TO
ORGANS
STYRENE MONOMER INHALATION CENTRAL NERVOUS MAY CAUSE
SYSTEM DEPRESSION DROWSINESS OR
DIZZINESS
STYRENE MONOMER INHALATION RESPIRATORY IRRITATION SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
STYRENE MONOMER INHALATION ENDOCRINE SYSTEM ALL DATA ARE
NEGATIVE
STYRENE MONOMER INHALATION KIDNEY AND/OR BLADDER ALL DATA ARE
NEGATIVE
NAME SPECIES TEST RESULT EXPOSURE DURATION
STYRENE MONOMER MULTIPLE LOAEL: 4.3 MG/L NOT AVAILABLE
ANIMAL
SPECIES
STYRENE MONOMER MOUSE LOAEL: 2.1 MG/L NOT AVAILABLE
STYRENE MONOMER HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL
EXPOSURE
STYRENE MONOMER HUMAN NOAEL: NOT AVAILABLE
AND
ANIMAL
STYRENE MONOMER RAT NOAEL: NOT AVAILABLE NOT AVAILABLE
STYRENE MONOMER MULTIPLE NOAEL: 2.1 MG/L NOT AVAILABLE
ANIMAL
SPECIES
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
TALC INHALATION PNEUMOCONIOSIS CAUSES DAMAGE TO
ORGANS THROUGH
PROLONGED OR
REPEATED EXPOSURE
TALC INHALATION PULMONARY FIBROSIS SOME POSITIVE DATA
RESPIRATORY SYSTEM EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
STYRENE MONOMER INHALATION EYES CAUSES DAMAGE TO
ORGANS THROUGH
PROLONGED OR
REPEATED EXPOSURE
STYRENE MONOMER INHALATION AUDITORY SYSTEM MAY CAUSE DAMAGE TO
ORGANS THOUGH
PROLONGED OR
REPEATED EXPOSURE
STYRENE MONOMER INHALATION LIVER MAY CAUSE DAMAGE TO
ORGANS THOUGH
PROLONGED OR
REPEATED EXPOSURE
STYRENE MONOMER INHALATION NERVOUS SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
STYRENE MONOMER INHALATION HEMATOPOIETIC SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
STYRENE MONOMER INHALATION ENDOCRINE SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
STYRENE MONOMER INHALATION RESPIRATORY SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
STYRENE MONOMER INHALATION HEART ALL DATA ARE
BONE, TEETH, NAILS, NEGATIVE
AND/OR HAIR
MUSCLES
KIDNEY AND/OR BLADDER
STYRENE MONOMER INGESTION NERVOUS SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
STYRENE MONOMER INGESTION IMMUNE SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
STYRENE MONOMER INGESTION LIVER SOME POSITIVE DATA
KIDNEY AND/OR BLADDER EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
STYRENE MONOMER INGESTION HEMATOPOIETIC SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
STYRENE MONOMER INGESTION HEART ALL DATA ARE
RESPIRATORY SYSTEM NEGATIVE
GLASS FILAMENT INHALATION RESPIRATORY SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
TALC HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL
EXPOSURE
TALC RAT NOAEL: 18 MG/M3 113 WEEKS
STYRENE MONOMER HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL
EXPOSURE
STYRENE MONOMER MULTIPLE NOAEL: 1.3 MG/L NOT AVAILABLE
ANIMAL
SPECIES
STYRENE MONOMER MOUSE LOAEL: 0.85 MG/L 13 WEEKS
STYRENE MONOMER MULTIPLE LOAEL: 1.1 MG/L NOT AVAILABLE
ANIMAL
SPECIES
STYRENE MONOMER RAT NOAEL: 0.85 MG/L 7 DAYS
STYRENE MONOMER RAT NOAEL: 0.6 MG/L 10 DAYS
STYRENE MONOMER MULTIPLE LOAEL: 0.09 MG/L NOT AVAILABLE
ANIMAL
SPECIES
STYRENE MONOMER MULTIPLE NOAEL: 4.3 MG/L 2 YEARS
ANIMAL
SPECIES
STYRENE MONOMER RAT LOAEL: 500 MG/KG/DAY 8 WEEKS
STYRENE MONOMER MULTIPLE NOAEL: NOT AVAILABLE NOT AVAILABLE
ANIMAL
SPECIES
STYRENE MONOMER RAT NOAEL: 677 MG/KG/DAY 6 MONTHS
STYRENE MONOMER DOG NOAEL: 600 MG/KG/DAY 470 DAYS
STYRENE MONOMER RAT NOAEL: 35 MG/KG/DAY 105 WEEKS
GLASS FILAMENT HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL
EXPOSURE
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/ CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
INCINERATE UNCURED PRODUCT IN A PERMITTED WASTE INCINERATION FACILITY.
DISPOSE OF COMPLETELY CURED (OR POLYMERIZED) MATERIAL IN A PERMITTED
INDUSTRIAL WASTE FACILITY. IF NO OTHER DISPOSAL OPTIONS ARE AVAILABLE,
WASTE PRODUCT THAT HAS BEEN COMPLETELY CURED OR POLYMERIZED MAY BE PLACED
IN A LANDFILL PROPERLY DESIGNED FOR INDUSTRIAL WASTE. EMPTY
DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: YES
PRESSURE HAZARD: NO
REACTIVITY HAZARD: NO
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
STYRENE MONOMER 100-42-5 10 - 30
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 1
FLAMMABILITY 3
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 24-2443-0
VERSION NUMBER: 9.01
ISSUE DATE: 04/17/15
SUPERCEDES DATE: 03/18/15
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM