| Common Name: | U-10, 06220 |
| Manufacturer: | LPS LABORATORIES |
| SDS Revision Date: | 4/18/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 3RWT7 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LPS(R*)
SAFETY DATA SHEET
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER: LPS(R*) U-10
OTHER MEANS OF IDENTIFICATION:
PART NUMBER: 06220
RECOMMENDED USE:
A SPRAY BRAKE CLEANER DESIGNED TO REMOVE OIL, GREASE, BRAKE FLUID, BRAKE PAD
MATERIAL OR DIRT FROM MOTOR VEHICLE BRAKE MECHANISMS.
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER/IMPORTER/SUPPLIER/DISTRIBUTOR INFORMATION:
MANUFACTURER:
MANUFACTURER:
COMPANY NAME: LPS LABORATORIES, A DIVISION OF ILLINOIS TOOL WORKS, INC.
ADDRESS:
4647 HUGH HOWELL RD.
TUCKER, GA 30084
COUNTRY: (U.S.A.)
TEL: +1 770-243-8800
IN CASE OF EMERGENCY:
1-800-424-9300 (INSIDE U.S.)
+001 703-527-3887 (OUTSIDE U.S.)
WEBSITE: WWW.LPSLABS.COM
E-MAIL: SDS@LPSLABS.COM
| 2. HAZARD(S) IDENTIFICATION | |
PHYSICAL HAZARDS:
FLAMMABLE AEROSOLS: CATEGORY 1
GASES UNDER PRESSURE: COMPRESSED GAS
HEALTH HAZARDS:
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE: CATEGORY 3 NARCOTIC EFFECTS
ASPIRATION HAZARD: CATEGORY 1
ENVIRONMENTAL HAZARDS: NOT CLASSIFIED.
OSHA DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS:
FLAME
GAS CYLINDER
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENT:
EXTREMELY FLAMMABLE AEROSOL. CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF
HEATED. MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS. CAUSES SERIOUS EYE
IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS.
PRECAUTIONARY STATEMENT:
PREVENTION:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. DO NOT
SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
PRESSURIZED CONTAINER:
DO NOT PIERCE OR BURN, EVEN AFTER USE. AVOID BREATHING GAS. WASH THOROUGHLY
AFTER HANDLING. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. WEAR EYE/FACE
PROTECTION.
RESPONSE:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER/DOCTOR. DO NOT INDUCE VOMITING. CALL A
POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP. PROTECT FROM SUNLIGHT. STORE IN A WELL-VENTILATED PLACE. PROTECT
FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50 DEG. C/122 DEG. F.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN.
SUPPLEMENTAL INFORMATION: NONE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
CHEMICAL NAME COMMON NAME AND SYNONYMS CAS NUMBER %
ACETONE 67-64-1 80 - 90
CARBON DIOXIDE 124-38-9 5 - 10
CYCLOHEXYLMETHANE 108-87-2 1 - 10
| 4. FIRST-AID MEASURES | |
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED. DO NOT USE
MOUTH-TO-MOUTH METHOD IF VICTIM INHALED THE SUBSTANCE. INDUCE ARTIFICIAL
RESPIRATION WITH THE AID OF A POCKET MASK EQUIPPED WITH A ONE-WAY VALVE OR
OTHER PROPER RESPIRATORY MEDICAL DEVICE. CALL A POISON CENTER OR
DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
SKIN CONTACT:
WASH OFF IMMEDIATELY WITH SOAP AND PLENTY OF WATER WHILE REMOVING ALL
CONTAMINATED CLOTHES AND SHOES. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
EYE CONTACT:
IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. IF EASY TO
DO, REMOVE CONTACT LENSES. GET MEDICAL ATTENTION IMMEDIATELY.
INGESTION:
CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. ONLY INDUCE VOMITING
AT THE INSTRUCTION OF MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. IF VOMITING OCCURS, KEEP HEAD LOW SO THAT STOMACH
CONTENT DOESN'T GET INTO THE LUNGS.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND BLURRED
VISION. DIRECT CONTACT WITH EYES MAY CAUSE TEMPORARY IRRITATION. VAPORS HAVE
A NARCOTIC EFFECT AND MAY CAUSE HEADACHE, FATIGUE, DIZZINESS AND NAUSEA.
MAY CAUSE REDNESS AND PAIN.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY.
GENERAL INFORMATION:
IF EXPOSED OR CONCERNED:
GET MEDICAL ADVICE/ATTENTION. ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE
MATERIAL(S) INVOLVED, AND TAKE PRECAUTIONS TO PROTECT THEMSELVES.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
POWDER. ALCOHOL RESISTANT FOAM. WATER. CARBON DIOXIDE (CO2).
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
CONTENTS UNDER PRESSURE. PRESSURIZED CONTAINER MAY EXPLODE WHEN EXPOSED TO
HEAT OR FLAME.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
FIREFIGHTERS MUST USE STANDARD PROTECTIVE EQUIPMENT INCLUDING FLAME RETARDANT
COAT, HELMET WITH FACE SHIELD, GLOVES, RUBBER BOOTS, AND IN ENCLOSED SPACES,
SCBA.
FIRE-FIGHTING EQUIPMENT/INSTRUCTIONS:
IN CASE OF FIRE:
STOP LEAK IF SAFE TO DO SO. DO NOT MOVE CARGO OR VEHICLE IF CARGO HAS BEEN
EXPOSED TO HEAT. IF TANK, RAIL CAR OR TANK TRUCK IS INVOLVED IN A FIRE,
ISOLATE FOR 800 METERS (1/2 MILE) IN ALL DIRECTIONS; ALSO CONSIDER INITIAL
EVACUATION FOR 800 METERS (1/2 MILE) IN ALL DIRECTIONS. ALWAYS STAY AWAY
FROM TANKS ENGULFED IN FLAME. MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO
SO WITHOUT RISK. CONTAINERS SHOULD BE COOLED WITH WATER TO PREVENT VAPOR
PRESSURE BUILD UP. FOR MASSIVE FIRE IN CARGO AREA, USE UNMANNED HOSE HOLDER
OR MONITOR NOZZLES, IF POSSIBLE. IF NOT, WITHDRAW AND LET FIRE BURN OUT.
SPECIFIC METHODS:
USE STANDARD FIREFIGHTING PROCEDURES AND CONSIDER THE HAZARDS OF OTHER
INVOLVED MATERIALS. MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO SO WITHOUT
RISK. COOL CONTAINERS EXPOSED TO FLAMES WITH WATER UNTIL WELL AFTER THE FIRE
IS OUT. IN THE EVENT OF FIRE AND/OR EXPLOSION DO NOT BREATHE FUMES.
GENERAL FIRE HAZARDS: EXTREMELY FLAMMABLE AEROSOL.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. KEEP OUT OF LOW AREAS. WEAR APPROPRIATE PROTECTIVE EQUIPMENT
AND CLOTHING DURING CLEAN-UP. AVOID BREATHING GAS. DO NOT TOUCH DAMAGED
CONTAINERS OR SPILLED MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE
CLOTHING. VENTILATE CLOSED SPACES BEFORE ENTERING THEM. LOCAL AUTHORITIES
SHOULD BE ADVISED IF SIGNIFICANT SPILLAGES CANNOT BE CONTAINED. USE PERSONAL
PROTECTION RECOMMENDED IN SECTION 8 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
REFER TO ATTACHED SAFETY DATA SHEETS AND/OR INSTRUCTIONS FOR USE. ELIMINATE
ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS, OR FLAMES IN IMMEDIATE
AREA). KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM SPILLED
MATERIAL. THIS PRODUCT IS MISCIBLE IN WATER. STOP LEAK IF YOU CAN DO SO
WITHOUT RISK. MOVE THE CYLINDER TO A SAFE AND OPEN AREA IF THE LEAK IS
IRREPARABLE. ISOLATE AREA UNTIL GAS HAS DISPERSED. SCOOP UP USED ABSORBENT
INTO DRUMS OR OTHER APPROPRIATE CONTAINER. FOLLOWING PRODUCT RECOVERY, FLUSH
AREA WITH WATER. FOR WASTE DISPOSAL, SEE SECTION 13 OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
AVOID DISCHARGE INTO DRAINS, WATER COURSES OR ONTO THE GROUND.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PRESSURIZED CONTAINER:
DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT USE IF SPRAY BUTTON IS MISSING
OR DEFECTIVE. DO NOT SPRAY ON A NAKED FLAME OR ANY OTHER INCANDESCENT
MATERIAL. DO NOT SMOKE WHILE USING OR UNTIL SPRAYED SURFACE IS THOROUGHLY
DRY. DO NOT CUT, WELD, SOLDER, DRILL, GRIND, OR EXPOSE CONTAINERS TO HEAT,
FLAME, SPARKS, OR OTHER SOURCES OF IGNITION. ALL EQUIPMENT USED WHEN
HANDLING THE PRODUCT MUST BE GROUNDED. DO NOT RE-USE EMPTY CONTAINERS. AVOID
BREATHING GAS. AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. AVOID PROLONGED
EXPOSURE. USE ONLY IN WELL-VENTILATED AREAS. WEAR APPROPRIATE PERSONAL
PROTECTIVE EQUIPMENT. OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES: LEVEL 2 AEROSOL.
STORE LOCKED UP. PRESSURIZED CONTAINER. PROTECT FROM SUNLIGHT AND DO NOT
EXPOSE TO TEMPERATURES EXCEEDING 50 DEG. C/122 DEG. F. DO NOT PUNCTURE,
INCINERATE OR CRUSH. DO NOT HANDLE OR STORE NEAR AN OPEN FLAME, HEAT OR
OTHER SOURCES OF IGNITION. THIS MATERIAL CAN ACCUMULATE STATIC CHARGE WHICH
MAY CAUSE SPARK AND BECOME AN IGNITION SOURCE. PREVENT ELECTROSTATIC CHARGE
BUILD-UP BY USING COMMON BONDING AND GROUNDING TECHNIQUES. STORE IN ORIGINAL
TIGHTLY CLOSED CONTAINER. STORE IN A WELL-VENTILATED PLACE. STORE AWAY FROM
INCOMPATIBLE MATERIALS (SEE SECTION 10 OF THE SDS). KEEP OUT OF THE REACH OF
CHILDREN.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
ACETONE (CAS 67-64-1) PEL 2400 MG/M3
1000 PPM
CARBON DIOXIDE (CAS 124-38-9) PEL 9000 MG/M3
5000 PPM
CYCLOHEXYLMETHANE (CAS 108-87-2) PEL 2000 MG/M3
500 PPM
ISO AMYL ACETATE (CAS 123-92-2) PEL 525 MG/M3
100 PPM
PRIMARY AMYL ACETATE (CAS 628-63-7) PEL 525 MG/M3
100 PPM
US. OSHA TABLE Z-2 (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
TOLUENE (CAS 108-88-3) CEILING 300 PPM
TWA 200 PPM
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE
2-METHYL BUTYL ACETATE (CAS 624-41-9) STEL 100 PPM
TWA 50 PPM
ACETONE (CAS 67-64-1) STEL 750 PPM
TWA 500 PPM
CARBON DIOXIDE (CAS 124-38-9) STEL 30000 PPM
TWA 5000 PPM
CYCLOHEXYLMETHANE (CAS 108-87-2) TWA 400 PPM
ISO AMYL ACETATE (CAS 123-92-2) STEL 100 PPM
TWA 50 PPM
PRIMARY AMYL ACETATE (CAS 628-63-7) STEL 100 PPM
TWA 50 PPM
TOLUENE (CAS 108-88-3) TWA 20 PPM
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
COMPONENTS TYPE VALUE
ACETONE (CAS 67-64-1) TWA 590 MG/M3
250 PPM
CARBON DIOXIDE (CAS 124-38-9) STEL 54000 MG/M3
30000 PPM
TWA 9000 MG/M3
5000 PPM
CYCLOHEXYLMETHANE (CAS 108-87-2) TWA 1600 MG/M3
400 PPM
ISO AMYL ACETATE (CAS 123-92-2) TWA 525 MG/M3
100 PPM
PRIMARY AMYL ACETATE (CAS 628-63-7) TWA 525 MG/M3
100 PPM
TOLUENE (CAS 108-88-3) STEL 560 MG/M3
150 PPM
TWA 375 MG/M3
100 PPM
BIOLOGICAL LIMIT VALUES:
ACGIH BIOLOGICAL EXPOSURE INDICES:
COMPONENTS VALUE DETERMINANT SPECIMEN SAMPLING TIME
ACETONE (CAS 67-64-1) 50 MG/L ACETONE URINE *
TOLUENE (CAS 108-88-3) 0.3 MG/G O-CRESOL, WITH CREATININE *
HYDROLYSIS IN URINE
0.03 MG/L TOLUENE URINE *
0.02 MG/L TOLUENE BLOOD *
* - FOR SAMPLING DETAILS, PLEASE SEE THE SOURCE DOCUMENT.
EXPOSURE GUIDELINES:
US - CALIFORNIA OELS SKIN DESIGNATION
TOLUENE (CAS 108-88-3) CAN BE ABSORBED THROUGH THE SKIN.
US - MINNESOTA HAZ SUBS SKIN DESIGNATION APPLIES
TOLUENE (CAS 108-88-3) SKIN DESIGNATION APPLIES.
APPROPRIATE ENGINEERING CONTROLS:
PROVIDE ADEQUATE GENERAL AND LOCAL EXHAUST VENTILATION. PROVIDE EYEWASH
STATION.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
DO NOT GET IN EYES. WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
EYE WASH FOUNTAIN IS RECOMMENDED.
SKIN PROTECTION:
HAND PROTECTION: CHEMICAL RESISTANT GLOVES ARE RECOMMENDED.
OTHER:
AVOID CONTACT WITH THE SKIN. WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING.
RESPIRATORY PROTECTION:
IN CASE OF INSUFFICIENT VENTILATION, WEAR SUITABLE RESPIRATORY EQUIPMENT.
THERMAL HAZARDS: NONE KNOWN.
GENERAL HYGIENE CONSIDERATIONS:
WHEN USING, DO NOT EAT, DRINK OR SMOKE. ALWAYS OBSERVE GOOD PERSONAL HYGIENE
MEASURES, SUCH AS WASHING AFTER HANDLING THE MATERIAL AND BEFORE EATING,
DRINKING, AND/OR SMOKING. ROUTINELY WASH WORK CLOTHING AND PROTECTIVE
EQUIPMENT TO REMOVE CONTAMINANTS.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: LIQUID.
PHYSICAL STATE: GAS.
FORM: AEROSOL. COMPRESSED GAS.
COLOR: CLEAR WATER-WHITE
ODOR: ETHER-LIKE. FRUITY.
ODOR THRESHOLD: NOT ESTABLISHED
PH: NOT APPLICABLE
MELTING POINT/FREEZING POINT: NOT ESTABLISHED
INITIAL BOILING POINT AND BOILING RANGE: 132.8 DEG. F (56 DEG. C)
FLASH POINT: <1.4 DEG. F (<-17.0 DEG. C) TAG CLOSED CUP
EVAPORATION RATE: >1 BUAC
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): 2.6%
FLAMMABILITY LIMIT - UPPER (%): 12.8%
EXPLOSIVE LIMIT - LOWER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - UPPER (%): NOT AVAILABLE.
VAPOR PRESSURE: >75 MMHg @ 20 DEG. C
VAPOR DENSITY: >2
RELATIVE DENSITY: NOT AVAILABLE.
SOLUBILITY(IES):
SOLUBILITY (WATER): SOLUBLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): >1
AUTO-IGNITION TEMPERATURE: 869 DEG. F (465 DEG. C)
DECOMPOSITION TEMPERATURE: NOT ESTABLISHED
VISCOSITY: <3 CST @ 25 DEG. C
OTHER INFORMATION:
HEAT OF COMBUSTION: 25 - 30 KJ/G
PERCENT VOLATILE: 100%
SPECIFIC GRAVITY: 0.75 - 0.77 @ 20 DEG. C
VOC (WEIGHT %): 9.4% PER US STATE & FEDERAL CONSUMER PRODUCT REGULATIONS
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
THE PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS OF USE,
STORAGE AND TRANSPORT.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
CONDITIONS TO AVOID:
AVOID TEMPERATURES EXCEEDING THE FLASH POINT. CONTACT WITH INCOMPATIBLE
MATERIALS.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS: CARBON OXIDES.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INGESTION:
MAY CAUSE DISCOMFORT IF SWALLOWED. MAY BE FATAL IF SWALLOWED AND ENTERS
AIRWAYS. HOWEVER, INGESTION IS NOT LIKELY TO BE A PRIMARY ROUTE OF
OCCUPATIONAL EXPOSURE.
INHALATION:
VAPORS HAVE A NARCOTIC EFFECT AND MAY CAUSE HEADACHE, FATIGUE, DIZZINESS AND
NAUSEA.
SKIN CONTACT:
FREQUENT OR PROLONGED CONTACT MAY DEFAT AND DRY THE SKIN, LEADING TO
DISCOMFORT AND DERMATITIS.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL CHARACTERISTICS:
CAUSES SERIOUS EYE IRRITATION. SYMPTOMS MAY INCLUDE STINGING, TEARING,
REDNESS, SWELLING, AND BLURRED VISION. VAPORS HAVE A NARCOTIC EFFECT AND MAY
CAUSE HEADACHE, FATIGUE, DIZZINESS AND NAUSEA.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NARCOTIC EFFECTS.
COMPONENTS SPECIES TEST RESULTS
ACETONE (CAS 67-64-1):
ACUTE:
DERMAL:
LD50 RABBIT >15800 MG/KG
20 ML/KG
INHALATION:
LC50 RAT 55700 PPM
76 MG/L, 4 HOURS
50.1 MG/L
50.1 MG/L, 8 HOURS
ORAL:
LD50 MOUSE 3000 MG/KG
RABBIT 5340 MG/KG
RAT 5800 MG/KG
2.2 ML/KG
OTHER:
LD50 MOUSE 1297 MG/KG
RAT 5500 MG/KG
CYCLOHEXYLMETHANE (CAS 108-87-2):
ACUTE:
DERMAL:
LD50 RAT >=4 ML/KG
INHALATION:
LC25 RABBIT 7300 MG/L
LC50 RAT 16 MG/L
ORAL:
LD50 RAT >8 ML/KG
ISO AMYL ACETATE (CAS 123-92-2):
ACUTE:
DERMAL:
LD50 RABBIT >5 G/KG
ORAL:
LD50 RABBIT 7400 MG/KG
RAT 16600 MG/KG
TOLUENE (CAS 108-88-3):
ACUTE:
DERMAL:
LD50 RABBIT >5000 MG/KG
14.1 ML/KG
INHALATION:
LC50 MOUSE 6405 - 7436 PPM
5320 MG/L, 8 HOURS
400 MG/L, 24 HOURS
RAT 26700 MG/L, 1 HOURS
12200 MG/L, 2 HOURS
8000 MG/L, 4 HOURS
5879 - 6281 PPM
25.7 MG/L
ORAL:
LD50 RAT 2.6 G/KG
OTHER:
LD50 MOUSE 59 MG/KG
RAT 1332 MG/KG
SKIN CORROSION/IRRITATION:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
RESPIRATORY OR SKIN SENSITIZATION:
RESPIRATORY SENSITIZATION:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
SKIN SENSITIZATION:
THIS PRODUCT IS NOT EXPECTED TO CAUSE SKIN SENSITIZATION.
GERM CELL MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
CARCINOGENICITY:
THIS PRODUCT IS NOT CONSIDERED TO BE A CARCINOGEN BY IARC, ACGIH, NTP, OR
OSHA.
ACGIH CARCINOGENS:
ACETONE (CAS 67-64-1): A4 NOT CLASSIFIABLE AS A HUMAN CARCINOGEN.
TOLUENE (CAS 108-88-3): A4 NOT CLASSIFIABLE AS A HUMAN CARCINOGEN.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY:
TOLUENE (CAS 108-88-3): 3 NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050): NOT LISTED.
REPRODUCTIVE TOXICITY:
THIS PRODUCT IS NOT EXPECTED TO CAUSE REPRODUCTIVE OR DEVELOPMENTAL EFFECTS.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
MAY CAUSE DROWSINESS OR DIZZINESS.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
ASPIRATION HAZARD: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
CHRONIC EFFECTS: PROLONGED INHALATION MAY BE HARMFUL.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: ECOLOGICAL INJURIES ARE NOT KNOWN OR EXPECTED UNDER NORMAL USE.
COMPONENTS SPECIES TEST RESULTS
ACETONE (CAS 67-64-1):
AQUATIC:
CRUSTACEA EC50 WATER FLEA 10294 - 17704 MG/L, 48 HOURS
(DAPHNIA MAGNA)
FISH LC50 RAINBOW TROUT, 4740 - 6330 MG/L, 96 HOURS
DONALDSON TROUT
(ONCORHYNCHUS MYKISS)
CYCLOHEXYLMETHANE (CAS 108-87-2):
AQUATIC:
FISH LC50 STRIPED BASS (MORONE 5.8 MG/L, 96 HOURS
SAXATILIS)
PRIMARY AMYL ACETATE (CAS 628-63-7):
AQUATIC:
FISH LC50 WESTERN MOSQUITOFISH 65 MG/L, 96 HOURS
(GAMBUSIA AFFINIS)
TOLUENE (CAS 108-88-3):
AQUATIC:
CRUSTACEA EC50 WATER FLEA 5.46 - 9.83 MG/L, 48 HOURS
(DAPHNIA MAGNA)
FISH LC50 COHO SALMON, 8.11 MG/L, 96 HOURS
SILVER SALMON
(ONCORHYNCHUS
KISUTCH)
PERSISTENCE AND DEGRADABILITY: NOT INHERENTLY BIODEGRADABLE.
BIOACCUMULATIVE POTENTIAL: NOT AVAILABLE.
PARTITION COEFFICIENT N-OCTANOL / WATER (LOG KOW):
LPS(R*) U-10: >1
ACETONE: -0.24
CYCLOHEXYLMETHANE: 3.61
PRIMARY AMYL ACETATE: 2.3
TOLUENE: 2.73
MOBILITY IN SOIL: NO DATA AVAILABLE.
OTHER ADVERSE EFFECTS: NONE KNOWN.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS:
CONSULT AUTHORITIES BEFORE DISPOSAL. CONTENTS UNDER PRESSURE. DO NOT
PUNCTURE, INCINERATE OR CRUSH. DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE
WITH LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
LOCAL DISPOSAL REGULATIONS:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE:
D001: WASTE FLAMMABLE MATERIAL WITH A FLASH POINT <140 F
D003: WASTE REACTIVE MATERIAL
WASTE FROM RESIDUES / UNUSED PRODUCTS:
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS. EMPTY CONTAINERS OR LINERS
MAY RETAIN SOME PRODUCT RESIDUES. THIS MATERIAL AND ITS CONTAINER MUST BE
DISPOSED OF IN A SAFE MANNER (SEE: DISPOSAL INSTRUCTIONS).
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL. SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED. DO NOT RE-USE EMPTY
CONTAINERS.
| 14. TRANSPORT INFORMATION | |
DOT:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.1
SUBSIDIARY RISK:
LABEL(S): 2.1
PACKING GROUP: NOT APPLICABLE.
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
SPECIAL PROVISIONS: N82
PACKAGING EXCEPTIONS: 306
PACKAGING NON BULK: NONE
PACKAGING BULK: NONE
IATA:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.1
SUBSIDIARY RISK:
PACKING GROUP: NOT APPLICABLE.
ENVIRONMENTAL HAZARDS: NO
ERG CODE: 10L
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
OTHER INFORMATION:
PASSENGER AND CARGO AIRCRAFT: ALLOWED.
CARGO AIRCRAFT ONLY: ALLOWED.
IMDG:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.1
SUBSIDIARY RISK:
PACKING GROUP: NOT APPLICABLE.
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO
EMS: F-D, S-U
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT APPLICABLE.
DOT: FLAMMABLE GAS, CLASS/DIVISION 2.1
IATA; IMDG: CLASS 2.1 - FLAMMABLE GASES
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4):
ACETONE (CAS 67-64-1): LISTED.
ISO AMYL ACETATE (CAS 123-92-2): LISTED.
PRIMARY AMYL ACETATE (CAS 628-63-7): LISTED.
TOLUENE (CAS 108-88-3): LISTED.
SARA 304 EMERGENCY RELEASE NOTIFICATION: NOT REGULATED.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050): NOT LISTED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
HAZARD CATEGORIES:
IMMEDIATE HAZARD: YES
DELAYED HAZARD: NO
FIRE HAZARD: YES
PRESSURE HAZARD: YES
REACTIVITY HAZARD: NO
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NOT LISTED.
SARA 311/312 HAZARDOUS CHEMICAL: YES
SARA 313 (TRI REPORTING): NOT REGULATED.
OTHER FEDERAL REGULATIONS:
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
TOLUENE (CAS 108-88-3)
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION
(40 CFR 68.130): NOT REGULATED.
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
DRUG ENFORCEMENT ADMINISTRATION (DEA). LIST 2, ESSENTIAL CHEMICALS (21 CFR
1310.02(B) AND 1310.04(F)(2) AND CHEMICAL CODE NUMBER:
ACETONE (CAS 67-64-1): 6532
TOLUENE (CAS 108-88-3): 6594
DRUG ENFORCEMENT ADMINISTRATION (DEA). LIST 1 & 2 EXEMPT CHEMICAL MIXTURES
(21 CFR 1310.12(C)):
ACETONE (CAS 67-64-1): 35% WEIGHT/VOLUMN
TOLUENE (CAS 108-88-3): 35% WEIGHT/VOLUMN
DEA EXEMPT CHEMICAL MIXTURES CODE NUMBER:
ACETONE (CAS 67-64-1): 6532
TOLUENE (CAS 108-88-3): 594
US STATE REGULATIONS:
US. MASSACHUSETTS RTK - SUBSTANCE LIST:
ACETONE (CAS 67-64-1)
CARBON DIOXIDE (CAS 124-38-9)
CYCLOHEXYLMETHANE (CAS 108-87-2)
ISO AMYL ACETATE (CAS 123-92-2)
PRIMARY AMYL ACETATE (CAS 628-63-7)
TOLUENE (CAS 108-88-3)
US. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
ACETONE (CAS 67-64-1)
CARBON DIOXIDE (CAS 124-38-9)
CYCLOHEXYLMETHANE (CAS 108-87-2)
ISO AMYL ACETATE (CAS 123-92-2)
PRIMARY AMYL ACETATE (CAS 628-63-7)
TOLUENE (CAS 108-88-3)
US. PENNSYLVANIA WORKER AND COMMUNITY RIGHT-TO-KNOW LAW:
ACETONE (CAS 67-64-1)
CARBON DIOXIDE (CAS 124-38-9)
CYCLOHEXYLMETHANE (CAS 108-87-2)
ISO AMYL ACETATE (CAS 123-92-2)
PRIMARY AMYL ACETATE (CAS 628-63-7)
TOLUENE (CAS 108-88-3)
US. RHODE ISLAND RTK:
ACETONE (CAS 67-64-1)
ISO AMYL ACETATE (CAS 123-92-2)
PRIMARY AMYL ACETATE (CAS 628-63-7)
TOLUENE (CAS 108-88-3)
US. CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
US - CALIFORNIA PROPOSITION 65 - CRT LISTED DATE/DEVELOPMENTAL TOXIN
TOLUENE (CAS 108-88-3) LISTED JANUARY 1, 1991
US - CALIFORNIA PROPOSITION 65 - CRT LISTED DATE/FEMALE REPRODUCTIVE TOXIN
TOLUENE (CAS 108-88-3) LISTED AUGUST 7, 2009
INTERNATIONAL INVENTORIES:
COUNTRY(S) OR INVENTORY NAME ON INVENTORY
REGION (YES/NO)*
AUSTRALIA AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES YES
(AICS)
CANADA DOMESTIC SUBSTANCES LIST (DSL) YES
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) NO
CHINA INVENTORY OF EXISTING CHEMICAL SUBSTANCES YES
IN CHINA (IECSC)
EUROPE EUROPEAN INVENTORY OF EXISTING COMMERCIAL YES
CHEMICAL SUBSTANCES (EINECS)
EUROPE EUROPEAN LIST OF NOTIFIED CHEMICAL NO
SUBSTANCES (ELINCS)
JAPAN INVENTORY OF EXISTING AND NEW CHEMICAL YES
SUBSTANCES (ENCS)
KOREA EXISTING CHEMICALS LIST (ECL) YES
NEW ZEALAND NEW ZEALAND INVENTORY NO
PHILIPPINES PHILIPPINE INVENTORY OF CHEMICALS AND YES
CHEMICAL SUBSTANCES (PICCS)
UNITED STATES & TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
PUERTO RICO INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
A "NO" INDICATES THAT ONE OR MORE COMPONENTS OF THE PRODUCT ARE NOT LISTED
OR EXEMPT FROM LISTING ON THE INVENTORY ADMINISTERED BY THE GOVERNING
COUNTRY(S).
| 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION | |
OR LAST REVISION
ISSUE DATE: 04-18-2014
REVISION DATE: 04-18-2014
VERSION #: 02
DISCLAIMER:
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST OF
OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION. THE
INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING, USE,
PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT TO BE
CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION RELATES ONLY
TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR SUCH MATERIAL
USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY PROCESS, UNLESS
SPECIFIED IN THE TEXT.
REVISION INFORMATION:
COMPOSITION / INFORMATION ON INGREDIENTS: INGREDIENTS
TRANSPORT INFORMATION: MATERIAL TRANSPORTATION INFORMATION
REGULATORY INFORMATION: RISK PHRASES - LABELING
GHS: CLASSIFICATION
MATERIAL NAME: LPS(R*) U-10
773
SDS: US