| Common Name: | STAY CLEAN LIQUID SOLDERING FLUX |
| Manufacturer: | HARRIS PRODUCTS GROUP |
| SDS Revision Date: | 2/18/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 3THF6, 54RY04 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
SAFETY DATA SHEET
HARRIS(R*)
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER: STAY CLEAN(R*) LIQUID SOLDERING FLUX
OTHER MEANS OF IDENTIFICATION:
SDS NUMBER: 0099
PRODUCT TYPE: LIQUID FLUX
RECOMMENDED USE: SOLDERING OF METAL.
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER/IMPORTER/SUPPLIER/DISTRIBUTOR INFORMATION:
MANUFACTURER/SUPPLIER:
HARRIS PRODUCTS GROUP
4501 QUALITY PLACE
MASON, OHIO 45040 US
CUSTSERVMASON@JWHARRIS.COM
TELEPHONE NUMBER: 513-754-2000
EMERGENCY TELEPHONE NUMBERS: 1-888-609-1762 (US, CANADA, MEXICO ONLY)
PLEASE QUOTE 333988
| 2. HAZARD(S) IDENTIFICATION | |
PHYSICAL HAZARDS: NOT CLASSIFIED.
HEALTH HAZARDS:
ACUTE TOXICITY, ORAL: CATEGORY 4
ACUTE TOXICITY, INHALATION: CATEGORY 4
SKIN CORROSION/IRRITATION: CATEGORY 1
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 1
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE: CATEGORY 1 (OPTIC NERVE)
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE:
CATEGORY 3 RESPIRATORY TRACT IRRITATION
OSHA DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS:
CORROSION
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENT:
HARMFUL IF SWALLOWED. HARMFUL IF INHALED. CAUSES SEVERE SKIN BURNS AND EYE
DAMAGE. MAY CAUSE RESPIRATORY IRRITATION. CAUSES DAMAGE TO ORGANS (OPTIC
NERVE).
PRECAUTIONARY STATEMENT:
PREVENTION DO NOT BREATHE MIST OR VAPOR. WASH THOROUGHLY AFTER HANDLING. DO
NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. USE ONLY OUTDOORS OR IN A
WELL-VENTILATED AREA. WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE
PROTECTION/FACE PROTECTION.
RESPONSE:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON
CENTER/DOCTOR. SPECIFIC TREATMENT (SEE THIS LABEL). WASH CONTAMINATED
CLOTHING BEFORE REUSE.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
CHEMICAL NAME CAS NUMBER %
AMMONIUM CHLORIDE 12125-02-9 5-25
ZINC CHLORIDE 7646-85-7 <30
HYDROCHLORIC ACID 7647-01-0 <5
METHANOL 67-56-1 <5
COMPOSITION COMMENTS:
ALL CONCENTRATIONS ARE IN PERCENT BY WEIGHT UNLESS INGREDIENT IS A GAS.
GAS CONCENTRATIONS ARE IN PERCENT BY VOLUME.
| 4. FIRST-AID MEASURES | |
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED. CALL A POISON CENTER
OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
SKIN CONTACT:
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER. CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY.
CHEMICAL BURNS MUST BE TREATED BY A PHYSICIAN. WASH CONTAMINATED CLOTHING
BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING.
CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY.
INGESTION:
CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. RINSE MOUTH. DO NOT
INDUCE VOMITING. IF VOMITING OCCURS, KEEP HEAD LOW SO THAT STOMACH CONTENT
DOESN'T GET INTO THE LUNGS.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
SYMPTOMS OF INHALATION OVER-EXPOSURE MAY INCLUDE SORE THROAT, CHOKING,
COUGHING, DIFFICULTY BREATHING. LUNG DAMAGE MAY OCCUR AFTER SEVERE
INHALATION EXPOSURES. DEPENDING ON THE DURATION AND CONCENTRATION OF
OVER-EXPOSURE, SKIN OR EYE CONTACT WITH THIS PRODUCT CAN IRRITATE AND BURN
CONTAMINATED TISSUE. INGESTION OVEREXPOSURE MAY BE HARMFUL OR FATAL.
PROLONGED OR REPEATED INHALATION OVER-EXPOSURE MAY CAUSE BURNS AND ULCERS
TO THE NOSE AND THROAT, DENTAL EROSION, BRONCHITIS, AND STOMACH PAINS.
REPEATED OR PROLONGED OVER-EXPOSURE TO THIS PRODUCT MAY RESULT IN
DERMATITIS (RED, DRY, ITCHY SKIN) AND ULCERATION.
DERMATITIS, OTHER SKIN DISORDERS, AND RESPIRATORY CONDITIONS MAY BE
AGGRAVATED BY OVER-EXPOSURE TO THIS PRODUCT.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
KEEP VICTIM UNDER OBSERVATION. CHEMICAL BURNS: FLUSH WITH WATER
IMMEDIATELY. WHILE FLUSHING, REMOVE CLOTHES WHICH DO NOT ADHERE TO AFFECTED
AREA. CALL AN AMBULANCE. CONTINUE FLUSHING DURING TRANSPORT TO HOSPITAL.
PULMONARY FUNCTION TESTS, CHEST X-RAYS, AND NERVOUS SYSTEM EVALUATIONS MAY
PROVE USEFUL. CONSULTATION WITH AN OPHTHALMOLOGIST IS RECOMMENDED IF EYE
EXPOSURE LEADS TO TISSUE DAMAGE. IN CASE OF SHORTNESS OF BREATH, GIVE
OXYGEN. SYMPTOMS MAY BE DELAYED.
GENERAL INFORMATION:
IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED, AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES. SHOW THIS SAFETY DATA SHEET TO THE
DOCTOR IN ATTENDANCE.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER FOG. FOAM. DRY CHEMICAL POWDER. CARBON DIOXIDE (CO2). HALONS.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
THIS PRODUCT IS ACIDIC AND PRESENTS A CONTACT HAZARD TO FIREFIGHTERS.
DURING A FIRE, IRRITATING AND TOXIC GASES (E.G., CARBON MONOXIDE, CARBON
DIOXIDE, HYDROGEN CHLORIDE, NITROGEN AND ZINC OXIDES, AND AMMONIA) MAY BE
GENERATED.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING MUST BE
WORN IN CASE OF FIRE.
FIRE FIGHTING EQUIPMENT/INSTRUCTIONS:
MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO SO WITHOUT RISK.
SPECIFIC METHODS:
USE STANDARD FIREFIGHTING PROCEDURES AND CONSIDER THE HAZARDS OF OTHER
INVOLVED MATERIALS.
GENERAL FIRE HAZARDS:
NO UNUSUAL FIRE OR EXPLOSION HAZARDS NOTED. THIS PRODUCT IS NEITHER
FLAMMABLE NOR REACTIVE UNDER NORMAL CIRCUMSTANCES; HOWEVER, IT MAY
GENERATE FLAMMABLE HYDROGEN GAS UPON CONTACT WITH METALS.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND CLOTHING DURING
CLEAN-UP. DO NOT BREATHE MIST OR VAPOR. DO NOT TOUCH DAMAGED CONTAINERS
OR SPILLED MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING. ENSURE
ADEQUATE VENTILATION. LOCAL AUTHORITIES SHOULD BE ADVISED IF SIGNIFICANT
SPILLAGES CANNOT BE CONTAINED. FOR PERSONAL PROTECTION, SEE SECTION 8 OF
THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
THIS PRODUCT IS MISCIBLE IN WATER. THIS MATERIAL IS CLASSIFIED AS A
WATER POLLUTANT UNDER THE CLEAN WATER ACT AND SHOULD BE PREVENTED FROM
CONTAMINATING SOIL OR FROM ENTERING SEWAGE AND DRAINAGE SYSTEMS WHICH
LEAD TO WATERWAYS.
LARGE SPILLS:
STOP THE FLOW OF MATERIAL, IF THIS IS WITHOUT RISK. DIKE THE SPILLED
MATERIAL, WHERE THIS IS POSSIBLE. COVER WITH PLASTIC SHEET TO PREVENT
SPREADING. ABSORB IN VERMICULITE, DRY SAND OR EARTH AND PLACE INTO
CONTAINERS. FOLLOWING PRODUCT RECOVERY, FLUSH AREA WITH WATER.
SMALL SPILLS:
WIPE UP WITH ABSORBENT MATERIAL (E.G. CLOTH, FLEECE). CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
NEVER RETURN SPILLS TO ORIGINAL CONTAINERS FOR RE-USE. FOR WASTE DISPOSAL,
SEE SECTION 13 OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. PREVENT FURTHER LEAKAGE OR SPILLAGE IF
SAFE TO DO SO. AVOID DISCHARGE INTO DRAINS, WATER COURSES OR ONTO THE
GROUND. INFORM APPROPRIATE MANAGERIAL OR SUPERVISORY PERSONNEL OF ALL
ENVIRONMENTAL RELEASES.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
DO NOT BREATHE MIST OR VAPOR. PROVIDE ADEQUATE VENTILATION. DO NOT USE IN
AREAS WITHOUT ADEQUATE VENTILATION. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. AVOID PROLONGED EXPOSURE. DO NOT TASTE OR SWALLOW. WHEN USING, DO
NOT EAT, DRINK OR SMOKE. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. WASH HANDS THOROUGHLY AFTER
HANDLING. HANDLE AND OPEN CONTAINER WITH CARE. OBSERVE GOOD INDUSTRIAL
HYGIENE PRACTICES. AVOID RELEASE TO THE ENVIRONMENT.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE LOCKED UP. STORE IN ORIGINAL TIGHTLY CLOSED CONTAINER. STORE AWAY
FROM DIRECT SUNLIGHT, SOURCES OF INTENSE HEAT, OR WHERE FREEZING IS
POSSIBLE. STORE IN A WELL-VENTILATED PLACE. STORE AWAY FROM INCOMPATIBLE
MATERIALS (SEE SECTION 10 OF THE SDS). MATERIAL SHOULD BE STORED IN
SECONDARY CONTAINERS OR IN A DIKED AREA, AS APPROPRIATE. STORAGE AND USE
AREAS SHOULD BE COVERED WITH IMPERVIOUS MATERIALS.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
COMPONENTS TYPE VALUE FORM
HYDROCHLORIC ACID (CAS 7647-01-0) CEILING 7 MG/M3
5 PPM
METHANOL (CAS 67-56-1) PEL 260 MG/M3
200 PPM
ZINC CHLORIDE (CAS 7646-85-7) PEL 1 MG/M3 FUME.
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE FORM
AMMONIUM CHLORIDE (CAS 12125-02-9) STEL 20 MG/M3 FUME.
TWA 10 MG/M3 FUME.
HYDROCHLORIC ACID (CAS 7647-01-0) CEILING 2 PPM
METHANOL (CAS 67-56-1) STEL 250 PPM
TWA 200 PPM
ZINC CHLORIDE (CAS 7646-85-7) STEL 2 MG/M3 FUME.
TWA 1 MG/M3 FUME.
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
COMPONENTS TYPE VALUE FORM
AMMONIUM CHLORIDE (CAS 12125-02-9) STEL 20 MG/M3 FUME.
TWA 10 MG/M3 FUME.
HYDROCHLORIC ACID (CAS 7647-01-0) CEILING 7 MG/M3
5 PPM
METHANOL (CAS 67-56-1) STEL 325 MG/M3
250 PPM
TWA 260 MG/M3
200 PPM
ZINC CHLORIDE (CAS 7646-85-7) STEL 2 MG/M3 FUME.
TWA 1 MG/M3 FUME.
BIOLOGICAL LIMIT VALUES:
ACGIH BIOLOGICAL EXPOSURE INDICES:
COMPONENTS VALUE DETERMINANT SPECIMEN SAMPLING TIME
METHANOL (CAS 67-56-1) 15 MG/L METHANOL URINE *
* - FOR SAMPLING DETAILS, PLEASE SEE THE SOURCE DOCUMENT.
EXPOSURE GUIDELINES:
US - CALIFORNIA OELS: SKIN DESIGNATION
METHANOL (CAS 67-56-1) CAN BE ABSORBED THROUGH THE SKIN.
US - MINNESOTA HAZ SUBS: SKIN DESIGNATION APPLIES
METHANOL (CAS 67-56-1) SKIN DESIGNATION APPLIES.
US - TENNESSEE OELS: SKIN DESIGNATION
METHANOL (CAS 67-56-1) CAN BE ABSORBED THROUGH THE SKIN.
US ACGIH THRESHOLD LIMIT VALUES: SKIN DESIGNATION
METHANOL (CAS 67-56-1) CAN BE ABSORBED THROUGH THE SKIN.
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
METHANOL (CAS 67-56-1) CAN BE ABSORBED THROUGH THE SKIN.
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE
USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE,
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
IF EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS
TO AN ACCEPTABLE LEVEL. EYE WASH FACILITIES AND EMERGENCY SHOWER MUST
BE AVAILABLE WHEN HANDLING THIS PRODUCT.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
CHEMICAL RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE AND FULL FACEPIECE.
SKIN PROTECTION:
HAND PROTECTION: WEAR NEOPRENE OR RUBBER GLOVES FOR ROUTINE INDUSTRIAL USE.
OTHER:
WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING. USE OF AN IMPERVIOUS APRON IS
RECOMMENDED.
RESPIRATORY PROTECTION:
CHEMICAL RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE AND FULL FACEPIECE.
THERMAL HAZARDS:
WEAR APPROPRIATE THERMAL PROTECTIVE CLOTHING, WHEN NECESSARY.
GENERAL HYGIENE CONSIDERATIONS:
KEEP AWAY FROM FOOD AND DRINK. ALWAYS OBSERVE GOOD PERSONAL HYGIENE
MEASURES, SUCH AS WASHING AFTER HANDLING THE MATERIAL AND BEFORE EATING,
DRINKING, AND/OR SMOKING. ROUTINELY WASH WORK CLOTHING AND PROTECTIVE
EQUIPMENT TO REMOVE CONTAMINANTS.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
FORM: LIQUID. LIQUID
COLOR: CLEAR COLORLESS.
ODOR: SLIGHTLY SWEET.
ODOR THRESHOLD: NOT AVAILABLE.
PH: ACIDIC.
MELTING POINT/FREEZING POINT: NOT AVAILABLE.
INITIAL BOILING POINT AND BOILING RANGE: NOT AVAILABLE.
FLASH POINT: NOT FLAMMABLE.
EVAPORATION RATE: >1 (NBUAC = 1).
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): NOT AVAILABLE.
FLAMMABILITY LIMIT - UPPER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - LOWER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - UPPER (%): NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
VAPOR DENSITY: 4 (AIR = 1).
RELATIVE DENSITY: 1.32 (WATER = 1).
SOLUBILITY(IES):
SOLUBILITY (WATER): SLIGHTLY SOLUBLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: NOT AVAILABLE.
OTHER INFORMATION:
LITMUS PAPER WILL TURN RED UPON CONTACT WITH THIS PRODUCT. THE ODOR
MAY ALSO ACT AS A DISTINGUISHING CHARACTERISTIC OF THIS PRODUCT.
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
THE PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS OF USE,
STORAGE AND TRANSPORT.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CONDITIONS TO AVOID:
CONTACT WITH INCOMPATIBLE MATERIALS. EXTREME TEMPERATURES.
INCOMPATIBLE MATERIALS:
ACID. ALKALIS AND THEIR CARBONATES, HYDROGEN CYANIDE, INTERHALOGENS,
AMMONIUM NITRATE, POTASSIUM CHLORATE, LEAD AND SILVER SALTS. STRONG
OXIDIZING AGENTS. AMINES. DO NOT MIX WITH OTHER CHEMICALS. THIS PRODUCT
IS NEITHER FLAMMABLE NOR REACTIVE UNDER NORMAL CIRCUMSTANCES; HOWEVER,
IT MAY GENERATE FLAMMABLE HYDROGEN GAS UPON CONTACT WITH METALS.
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON DIOXIDE (CO2). NITROGEN OXIDES (NOX). AMMONIA. HYDROGEN CHLORIDE
(HCl). ZINC OXIDES.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION:
HARMFUL IF INHALED. MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING
DIFFICULTIES IF INHALED. MAY CAUSE DAMAGE TO ORGANS BY INHALATION. IF
VAPORS, MISTS, OR SPRAYS OF THIS PRODUCT ARE INHALED, THEY CAN IRRITATE AND
BURN THE NOSE, THROAT, AND RESPIRATORY SYSTEM. SYMPTOMS OF INHALATION
OVER-EXPOSURE MAY INCLUDE SORE THROAT, CHOKING, COUGHING, AND DIFFICULTY
BREATHING. PROLONGED OR REPEATED OVER-EXPOSURE MAY CAUSE BURNS AND ULCERS
TO THE NOSE AND THROAT, DENTAL EROSION, BRONCHITIS, AND STOMACH PAINS. IT
HAS BEEN REPORTED THAT A WORKER DEVELOPED ASTHMATIC SYMPTOMS AFTER
PERFORMING SOLDERING WORK WITH A FLUX CONTAINING AMMONIUM AND ZINC
CHLORIDES (COMPONENTS OF THIS PRODUCT). IT HAS BEEN REPORTED THAT
INHALATION OF METHANOL (A COMPONENT OF THIS PRODUCT) VAPORS IN HIGH
CONCENTRATIONS CAN CAUSE BLINDNESS. SEVERE INHALATION OVEREXPOSURE MAY
CAUSE PULMONARY EDEMA (A LIFE-THREATENING ACCUMULATION OF FLUID IN THE
LUNGS) OR PNEUMONITIS. SYMPTOMS OF PULMONARY EDEMA (E.G., SHORTNESS OF
BREATH, CHEST PAINS) CAN BE DELAYED FOR SEVERAL HOURS AFTER EXPOSURE.
SEVERE INHALATION OF VAPORS OR FUMES (AS MAY OCCUR IF INDIVIDUALS ARE
EXPOSED IN POORLY VENTILATED AREAS, SUCH AS CONFINED SPACES) MAY BE
HARMFUL.
SKIN CONTACT:
CAUSES SEVERE SKIN BURNS. DEPENDING ON THE DURATION AND CONCENTRATION OF
OVER-EXPOSURE, SKIN CONTACT WITH THIS PRODUCT CAN IRRITATE AND BURN THE
SKIN. REPEATED OR PROLONGED OVER-EXPOSURE TO THIS PRODUCT MAY RESULT IN
DERMATITIS (RED, DRY, ITCHY SKIN) AND ULCERATION. METHANOL (A COMPONENT
OF THIS PRODUCT) IS READILY ABSORBED THROUGH THE SKIN. BECAUSE METHANOL
IS A MINOR COMPONENT OF THIS PRODUCT, SKIN ABSORPTION IS NOT ANTICIPATED
TO BE A SIGNIFICANT ROUTE OF OVER-EXPOSURE.
EYE CONTACT:
DEPENDING ON THE DURATION AND CONCENTRATION OF OVER-EXPOSURE, EYE CONTACT
WITH THIS PRODUCT CAN IRRITATE AND BURN THE EYES. EYE OVER-EXPOSURE CAN
CAUSE PAIN, TEARING, AND REDNESS. SEVERE EYE OVER-EXPOSURE MAY CAUSE
BLINDNESS. CAUSES SERIOUS EYE DAMAGE.
INGESTION:
HARMFUL IF SWALLOWED. CAUSES DIGESTIVE TRACT BURNS. IF THIS FLUX IS
INGESTED, NAUSEA, VOMITING, AND DIARRHEA MAY OCCUR (DEPENDING ON THE
AMOUNT OF THE PRODUCT SWALLOWED). SEVERE INGESTION EXPOSURES MAY RESULT
IN DAMAGE TO THE TISSUES OF THE GASTROINTESTINAL SYSTEM, AND DEATH.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
SYMPTOMS OF INHALATION OVER-EXPOSURE MAY INCLUDE SORE THROAT, CHOKING,
COUGHING, DIFFICULTY BREATHING. LUNG DAMAGE MAY OCCUR AFTER SEVERE
INHALATION EXPOSURES. DEPENDING ON THE DURATION AND CONCENTRATION OF
OVER-EXPOSURE, SKIN OR EYE CONTACT WITH THIS PRODUCT CAN IRRITATE AND BURN
CONTAMINATED TISSUE. INGESTION OVEREXPOSURE MAY BE HARMFUL OR FATAL.
PROLONGED OR REPEATED INHALATION OVER-EXPOSURE MAY CAUSE BURNS AND ULCERS
TO THE NOSE AND THROAT, DENTAL EROSION, BRONCHITIS, AND STOMACH PAINS.
REPEATED OR PROLONGED OVER-EXPOSURE TO THIS PRODUCT MAY RESULT IN
DERMATITIS (RED, DRY, ITCHY SKIN) AND ULCERATION.
DERMATITIS, OTHER SKIN DISORDERS, AND RESPIRATORY CONDITIONS MAY BE
AGGRAVATED BY OVER-EXPOSURE TO THIS PRODUCT.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
HARMFUL IF INHALED. HARMFUL IF SWALLOWED. MAY CAUSE RESPIRATORY IRRITATION.
COMPONENTS SPECIES TEST RESULTS
HYDROCHLORIC ACID (CAS 7647-01-0)
ACUTE:
INHALATION:
LC50 RAT 3124 MG/L, 1 HOURS
ORAL:
LD50 RABBIT 900 MG/KG
METHANOL (CAS 67-56-1)
ACUTE:
INHALATION:
LC50 RAT 22500 PPM, 8 HOURS
ORAL:
LD50 RAT 6200 MG/KG
* ESTIMATES FOR PRODUCT MAY BE BASED ON ADDITIONAL COMPONENT DATA NOT
SHOWN.
SKIN CORROSION/IRRITATION: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE DAMAGE.
RESPIRATORY OR SKIN SENSITIZATION:
RESPIRATORY SENSITIZATION: NOT A RESPIRATORY SENSITIZER.
IT HAS BEEN REPORTED THAT A WORKER DEVELOPED ASTHMATIC SYMPTOMS AFTER
PERFORMING SOLDERING WORK WITH A FLUX CONTAINING AMMONIUM AND ZINC
CHLORIDES (COMPONENTS OF THIS PRODUCT).
SKIN SENSITIZATION:
THIS PRODUCT IS NOT EXPECTED TO CAUSE SKIN SENSITIZATION.
GERM CELL MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
CARCINOGENICITY:
THIS PRODUCT IS NOT CONSIDERED TO BE A CARCINOGEN BY IARC, ACGIH, NTP, OR
OSHA.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY:
HYDROCHLORIC ACID (CAS 7647-01-0) 3 NOT CLASSIFIABLE AS TO
CARCINOGENICITY TO HUMANS.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050): NOT LISTED.
REPRODUCTIVE TOXICITY:
THIS PRODUCT IS NOT EXPECTED TO CAUSE REPRODUCTIVE OR DEVELOPMENTAL
EFFECTS. CLINICAL STUDIES ON TEST ANIMALS EXPOSED TO RELATIVELY HIGH
DOSES OF METHANOL AND ZINC CHLORIDE (COMPONENTS OF THIS PRODUCT) INDICATE
TERATOGENIC EFFECTS AND ADVERSE REPRODUCTIVE EFFECTS.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
CAUSES DAMAGE TO ORGANS (OPTIC NERVE). MAY CAUSE RESPIRATORY IRRITATION.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED.
ASPIRATION HAZARD: NOT AN ASPIRATION HAZARD.
CHRONIC EFFECTS: PROLONGED INHALATION MAY BE HARMFUL.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
COMPONENTS SPECIES TEST RESULTS
HYDROCHLORIC ACID (CAS 7647-01-0)
AQUATIC:
FISH LC50 WESTERN MOSQUITOFISH (GAMBUSIA AFFINIS) 282 MG/L, 96
HOURS
* ESTIMATES FOR PRODUCT MAY BE BASED ON ADDITIONAL COMPONENT DATA NOT
SHOWN.
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF THIS PRODUCT.
BIOACCUMULATIVE POTENTIAL:
PARTITION COEFFICIENT N-OCTANOL / WATER (LOG KOW):
METHANOL (CAS 67-56-1) -0.77
MOBILITY IN SOIL: NO DATA AVAILABLE.
OTHER ADVERSE EFFECTS:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION, PHOTOCHEMICAL
OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION, GLOBAL WARMING POTENTIAL)
ARE EXPECTED FROM THIS COMPONENT.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS:
COLLECT AND RECLAIM OR DISPOSE IN SEALED CONTAINERS AT LICENSED WASTE
DISPOSAL SITE. DO NOT ALLOW THIS MATERIAL TO DRAIN INTO SEWERS/WATER
SUPPLIES. DO NOT CONTAMINATE PONDS, WATERWAYS OR DITCHES WITH CHEMICAL
OR USED CONTAINER. DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
LOCAL DISPOSAL REGULATIONS:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE:
THE WASTE CODE SHOULD BE ASSIGNED IN DISCUSSION BETWEEN THE USER, THE
PRODUCER AND THE WASTE DISPOSAL COMPANY.
WASTE FROM RESIDUES / UNUSED PRODUCTS:
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS. EMPTY CONTAINERS OR LINERS
MAY RETAIN SOME PRODUCT RESIDUES. THIS MATERIAL AND ITS CONTAINER MUST BE
DISPOSED OF IN A SAFE MANNER (SEE: DISPOSAL INSTRUCTIONS).
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL. SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED.
| 14. TRANSPORT INFORMATION | |
DOT:
UN NUMBER: UN1760
UN PROPER SHIPPING NAME:
CORROSIVE LIQUIDS, N.O.S. (ZINC CHLORIDE, HYDROCHLORIC ACID)
TRANSPORT HAZARD CLASS(ES):
CLASS: 8
SUBSIDIARY RISK:
LABEL(S): 8
PACKING GROUP: III
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: YES
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
SPECIAL PROVISIONS: IB3, T7, TP1, TP28
PACKAGING EXCEPTIONS: 154
PACKAGING NON BULK: 203
PACKAGING BULK: 241
IATA:
UN NUMBER: UN1760
UN PROPER SHIPPING NAME:
CORROSIVE LIQUIDS, N.O.S. (ZINC CHLORIDE, HYDROCHLORIC ACID)
TRANSPORT HAZARD CLASS(ES):
CLASS: 8
SUBSIDIARY RISK:
LABEL(S): 8
PACKING GROUP: III
ENVIRONMENTAL HAZARDS: YES
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
IMDG:
UN NUMBER: UN1760
UN PROPER SHIPPING NAME:
CORROSIVE LIQUIDS, N.O.S. (ZINC CHLORIDE, HYDROCHLORIC ACID)
TRANSPORT HAZARD CLASS(ES):
CLASS: 8
SUBSIDIARY RISK:
LABEL(S) 8:
PACKING GROUP: III
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: YES
EMS: NOT AVAILABLE.
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT ESTABLISHED.
GENERAL INFORMATION:
DOT REGULATED MARINE POLLUTANT. IMDG REGULATED MARINE POLLUTANT.
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
ALL COMPONENTS ARE ON THE U.S. EPA TSCA INVENTORY LIST.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050): NOT LISTED.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4):
AMMONIUM CHLORIDE (CAS 12125-02-9) LISTED
HYDROCHLORIC ACID (CAS 7647-01-0) LISTED
METHANOL (CAS 67-56-1) LISTED
ZINC CHLORIDE (CAS 7646-85-7) LISTED
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
HAZARD CATEGORIES:
IMMEDIATE HAZARD: YES
DELAYED HAZARD: NO
FIRE HAZARD: NO
REACTIVITY HAZARD: NO
PRESSURE HAZARD: NO
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE:
CHEMICAL NAME CAS NUMBER REPORTABLE THRESHOLD THRESHOLD THRESHOLD
QUANTITY PLANNING PLANNING PLANNING
(POUNDS) QUANTITY QUANTITY, QUANTITY,
(POUNDS) LOWER VALUE UPPER VALUE
(POUNDS) (POUNDS)
HYDROCHLORIC 7647-01-0 5000 500
ACID
SARA 311/312 HAZARDOUS CHEMICAL: YES
SARA 313 (TRI REPORTING):
CHEMICAL NAME CAS NUMBER % BY WT.
AMMONIUM CHLORIDE 12125-02-9 5-25
ZINC CHLORIDE 7646-85-7 <30
HYDROCHLORIC ACID 7647-01-0 <5
METHANOL 67-56-1 <5
OTHER FEDERAL REGULATIONS:
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
HYDROCHLORIC ACID (CAS 7647-01-0)
METHANOL (CAS 67-56-1)
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION (40 CFR
68.130): HYDROCHLORIC ACID (CAS 7647-01-0)
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
DRUG ENFORCEMENT ADMINISTRATION (DEA). LIST 2, ESSENTIAL CHEMICALS (21 CFR
1310.02(B) AND 1310.04(F)(2) AND CHEMICAL CODE NUMBER:
HYDROCHLORIC ACID (CAS 7647-01-0) 6545
DRUG ENFORCEMENT ADMINISTRATION (DEA). LIST 1 & 2 EXEMPT CHEMICAL MIXTURES
(21 CFR 1310.12(C)):
HYDROCHLORIC ACID (CAS 7647-01-0) 20%WV
DEA EXEMPT CHEMICAL MIXTURES CODE NUMBER:
HYDROCHLORIC ACID (CAS 7647-01-0) 6545
US STATE REGULATIONS:
US. MASSACHUSETTS RTK - SUBSTANCE LIST:
AMMONIUM CHLORIDE (CAS 12125-02-9)
HYDROCHLORIC ACID (CAS 7647-01-0)
METHANOL (CAS 67-56-1)
ZINC CHLORIDE (CAS 7646-85-7)
US. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
AMMONIUM CHLORIDE (CAS 12125-02-9)
HYDROCHLORIC ACID (CAS 7647-01-0)
METHANOL (CAS 67-56-1)
ZINC CHLORIDE (CAS 7646-85-7)
US. PENNSYLVANIA WORKER AND COMMUNITY RIGHT-TO-KNOW LAW:
AMMONIUM CHLORIDE (CAS 12125-02-9)
HYDROCHLORIC ACID (CAS 7647-01-0)
METHANOL (CAS 67-56-1)
ZINC CHLORIDE (CAS 7646-85-7)
US. RHODE ISLAND RTK:
AMMONIUM CHLORIDE (CAS 12125-02-9)
HYDROCHLORIC ACID (CAS 7647-01-0)
METHANOL (CAS 67-56-1)
ZINC CHLORIDE (CAS 7646-85-7)
US. CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
US - CALIFORNIA PROPOSITION 65 - CARCINOGENS & REPRODUCTIVE TOXICITY (CRT):
LISTED SUBSTANCE
METHANOL (CAS 67-56-1)
INTERNATIONAL INVENTORIES:
COUNTRY(S) OR REGION INVENTORY NAME ON INVENTORY
(YES/NO)*
AUSTRALIA AUSTRALIAN INVENTORY OF CHEMICAL YES
SUBSTANCES (AICS)
CANADA DOMESTIC SUBSTANCES LIST (DSL) YES
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) NO
CHINA INVENTORY OF EXISTING CHEMICAL YES
SUBSTANCES IN CHINA (IECSC)
EUROPE EUROPEAN INVENTORY OF EXISTING YES
COMMERCIAL CHEMICAL SUBSTANCES
(EINECS)
EUROPE EUROPEAN LIST OF NOTIFIED CHEMICAL NO
SUBSTANCES (ELINCS)
JAPAN INVENTORY OF EXISTING AND NEW YES
CHEMICAL SUBSTANCES (ENCS)
KOREA EXISTING CHEMICALS LIST (ECL) YES
NEW ZEALAND NEW ZEALAND INVENTORY YES
PHILIPPINES PHILIPPINE INVENTORY OF CHEMICALS YES
AND CHEMICAL SUBSTANCES (PICCS)
UNITED STATES & TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
PUERTO RICO INVENTORY
*A "YES" INDICATES THIS PRODUCT COMPLIES WITH THE INVENTORY REQUIREMENTS
ADMINISTERED BY THE GOVERNING COUNTRY(S).
A "NO" INDICATES THAT ONE OR MORE COMPONENTS OF THE PRODUCT ARE NOT LISTED
OR EXEMPT FROM LISTING ON THE INVENTORY ADMINISTERED BY THE GOVERNING
COUNTRY(S).
| 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION | |
OR LAST REVISION
ISSUE DATE: 18-FEBRUARY-2015
REVISION DATE:
VERSION #: 01
NFPA RATINGS:
3
0
0
DISCLAIMER:
HARRIS PRODUCTS GROUP CANNOT ANTICIPATE ALL CONDITIONS UNDER WHICH THIS
INFORMATION AND ITS PRODUCT, OR THE PRODUCTS OF OTHER MANUFACTURERS IN
COMBINATION WITH ITS PRODUCT, MAY BE USED. IT IS THE USER'S RESPONSIBILITY
TO ENSURE SAFE CONDITIONS FOR HANDLING, STORAGE AND DISPOSAL OF THE
PRODUCT, AND TO ASSUME LIABILITY FOR LOSS, INJURY, DAMAGE OR EXPENSE DUE
TO IMPROPER USE. THE INFORMATION IN THE SHEET WAS WRITTEN BASED ON THE
BEST KNOWLEDGE AND EXPERIENCE CURRENTLY AVAILABLE.
924591
SDS US