| Common Name: | TROUBLESHOOTER BASEBOARD STRIPPER |
| Manufacturer: | 3M |
| SDS Revision Date: | 4/16/2019 |
| SDS Format: | GHS-US |
| Item Number(s): | 3U123 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) TROUBLESHOOTER(TM) BASEBOARD STRIPPER
04/16/19
3M
SAFETY DATA SHEET
COPYRIGHT, 2019, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 10-2818-2
VERSION NUMBER: 23.00
ISSUE DATE: 04/16/19
SUPERCEDES DATE: 01/08/18
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER: 3M(TM) TROUBLESHOOTER(TM) BASEBOARD STRIPPER
PRODUCT IDENTIFICATION NUMBERS:
ID NUMBER UPC
61-5000-6131-4 00-48011-14001-8
7100134190
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE:
BASEBOARD STRIPPER, HEAVY DUTY AEROSOL CLEANER REMOVES SOIL, GREASE AND
FINISH BUILDUP. UPSIDE DOWN SPRAY FEATURE FOR HARD-TO-REACH PLACES. USE
ON BASEBOARDS, FLOOR EDGES, CORNERS, STAIRWAYS AND CERAMIC TILE. CONTAINS
NO OZONE DEPLETING CHEMICALS.
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: COMMERCIAL SOLUTIONS DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
GAS UNDER PRESSURE: LIQUEFIED GAS.
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2A.
SKIN CORROSION/IRRITATION: CATEGORY 1B.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 1.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 3.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
GAS CYLINDER
CORROSION
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
GAS CYLINDER
CORROSION
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
CAUSES SEVERE SKIN BURNS.
MAY CAUSE DROWSINESS OR DIZZINESS.
CAUSES DAMAGE TO ORGANS: CARDIOVASCULAR SYSTEM
PRECAUTIONARY STATEMENTS:
GENERAL: KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, AND EYE/FACE PROTECTION.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
RESPONSE:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
SPECIFIC TREATMENT (SEE NOTES TO PHYSICIAN ON THIS LABEL).
STORAGE:
PROTECT FROM SUNLIGHT.
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
NOTES TO PHYSICIAN:
EXPOSURE MAY INCREASE MYOCARDIAL IRRITABILITY. DO NOT ADMINISTER
SYMPATHOMIMETIC DRUGS UNLESS ABSOLUTELY NECESSARY.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED:
MAY CAUSE CHEMICAL GASTROINTESTINAL BURNS.
9% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE DERMAL TOXICITY.
9% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE INHALATION
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
WATER 7732-18-5 60 - 90 TRADE SECRET*
2-BUTOXYETHANOL 111-76-2 10 - 30 TRADE SECRET*
PETROLEUM GASES, LIQUEFIED, 68476-86-8 5 - 10 TRADE SECRET*
SWEETENED
ETHANOLAMINE 141-43-5 3 - 7 TRADE SECRET*
ETHOXYLATED C12-C15 ALCOHOLS 68131-39-5 0.1 - 1 TRADE SECRET*
FRAGRANCE ADDED MIXTURE <0.5 TRADE SECRET*
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION)
OF THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION: REMOVE PERSON TO FRESH AIR. GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTAMINATED CLOTHING. GET IMMEDIATE MEDICAL ATTENTION. WASH
CLOTHING BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF
EASY TO DO. CONTINUE RINSING. GET MEDICAL ATTENTION.
IF SWALLOWED:
RINSE MOUTH. DO NOT INDUCE VOMITING. GET IMMEDIATE MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED:
EXPOSURE MAY INCREASE MYOCARDIAL IRRITABILITY. DO NOT ADMINISTER
SYMPATHOMIMETIC DRUGS UNLESS ABSOLUTELY NECESSARY.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
MATERIAL WILL NOT BURN. USE A FIRE FIGHTING AGENT SUITABLE FOR THE
SURROUNDING FIRE.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY BUILD PRESSURE AND EXPLODE.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO
SMOKING. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR SPILLS IN
CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR EXHAUST
VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE. REFER TO
OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH
HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE
EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
FOR LARGER SPILLS, COVER DRAINS AND BUILD DIKES TO PREVENT ENTRY INTO
SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
IF POSSIBLE, SEAL LEAKING CONTAINER. PLACE LEAKING CONTAINERS IN A
WELL-VENTILATED AREA, PREFERABLY AN OPERATING EXHAUST HOOD, OR IF NECESSARY
OUTDOORS ON AN IMPERMEABLE SURFACE UNTIL APPROPRIATE PACKAGING FOR THE
LEAKING CONTAINER OR ITS CONTENTS IS AVAILABLE. CONTAIN SPILL. FOR LARGE
SPILLS, IF NECESSARY, GET ASSISTANCE FROM PROFESSIONAL SPILL CLEAN UP TEAM.
FOR SMALL SPILLS, CAREFULLY NEUTRALIZE SPILL BY ADDING APPROPRIATE DILUTE
ACID SUCH AS VINEGAR. WORK SLOWLY TO AVOID BOILING OR SPATTERING. CONTINUE
TO ADD NEUTRALIZING AGENT UNTIL REACTION STOPS. LET COOL BEFORE COLLECTING.
OR USE A COMMERCIALLY AVAILABLE CAUSTIC (ALKALINE OR BASIC) SPILL CLEAN-UP
KIT. FOLLOW KIT DIRECTIONS EXACTLY. WORKING FROM AROUND THE EDGES OF THE
SPILL INWARD, COVER WITH BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE
INORGANIC ABSORBENT MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS
DRY. REMEMBER, ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL,
HEALTH, OR ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL
AS POSSIBLE. PLACE IN A METAL CONTAINER APPROVED FOR USE IN TRANSPORTATION
BY APPROPRIATE AUTHORITIES. THE CONTAINER MUST BE LINED WITH POLYETHYLENE
PLASTIC OR CONTAIN A PLASTIC DRUM LINER MADE OF POLYETHYLENE. CLEAN UP
RESIDUE WITH WATER. SEAL THE CONTAINER. DISPOSE OF COLLECTED MATERIAL AS
SOON AS POSSIBLE IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
KEEP OUT OF REACH OF CHILDREN. DO NOT PIERCE OR BURN, EVEN AFTER USE. DO
NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN,
OR ON CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. WASH CONTAMINATED CLOTHING BEFORE REUSE. AVOID
CONTACT WITH OXIDIZING AGENTS (EG. CHLORINE, CHROMIC ACID ETC.)
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. PROTECT
FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50C/122F. PROTECT
FROM SUNLIGHT. STORE IN A WELL-VENTILATED PLACE. STORE AWAY FROM HEAT.
STORE AWAY FROM ACIDS. STORE AWAY FROM OXIDIZING AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE
TABLE BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE
COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
2-BUTOXYETHANOL 111-76-2 ACGIH TWA: 20 PPM A3:
CONFIRMED
ANIMAL
CARCIN.
2-BUTOXYETHANOL 111-76-2 OSHA TWA: SKIN
240 MG/M3
(50 PPM)
ETHANOLAMINE 141-43-5 ACGIH TWA: 3 PPM
STEL: 6 PPM
ETHANOLAMINE 141-43-5 OSHA TWA:
6 MG/M3
(3 PPM)
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR
CONTROL DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE,
USE RESPIRATORY PROTECTION EQUIPMENT. DO NOT REMAIN IN AREA WHERE
AVAILABLE OXYGEN MAY BE REDUCED.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE
CONDITIONS. CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER
FOR SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
NOTE:
NITRILE GLOVES MAY BE WORN OVER POLYMER LAMINATE GLOVES TO IMPROVE
DEXTERITY.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
POLYMER LAMINATE
IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL FOR
EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF
PROTECTIVE COVERALLS MAY BE NECESSARY. SELECT AND USE BODY PROTECTION
TO PREVENT CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED:
APRON - POLYMER LAMINATE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM.
BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING
RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
SPECIFIC PHYSICAL FORM: AEROSOL
ODOR, COLOR, GRADE: OFF WHITE, MILKY LIQUID.
ODOR THRESHOLD: NO DATA AVAILABLE
PH: 11 - 12.1
MELTING POINT: NOT APPLICABLE
BOILING POINT: >212 DEG. F
FLASH POINT: NO FLASH POINT
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS (LEL): NO DATA AVAILABLE
FLAMMABLE LIMITS (UEL): NO DATA AVAILABLE
VAPOR PRESSURE: NO DATA AVAILABLE
VAPOR DENSITY: NO DATA AVAILABLE
DENSITY: 0.967 - 1.027 G/ML
SPECIFIC GRAVITY: 0.967 - 1.027 [REF STD: WATER=1]
SOLUBILITY IN WATER: COMPLETE
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: >80 CENTIPOISE
MOLECULAR WEIGHT: NO DATA AVAILABLE
VOLATILE ORGANIC COMPOUNDS:
15 - 20% WEIGHT [TEST METHOD: CALCULATED PER CARB TITLE 2]
PERCENT VOLATILE: 60 - 90% WEIGHT
VOC LESS H2O & EXEMPT SOLVENTS:
615 - 645 G/L [TEST METHOD: CALCULATED PER CARB TITLE 2]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID:
HEAT
SPARKS AND/OR FLAMES
10.5. INCOMPATIBLE MATERIALS:
STRONG OXIDIZING AGENTS
STRONG ACIDS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL
MAY PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
CORROSIVE (SKIN BURNS):
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, INTENSE
PAIN, BLISTERING, ULCERATION, AND TISSUE DESTRUCTION.
EYE CONTACT:
SEVERE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE SIGNIFICANT REDNESS, SWELLING, PAIN, TEARING,
CLOUDY APPEARANCE OF THE CORNEA, AND IMPAIRED VISION.
INGESTION:
GASTROINTESTINAL CORROSION:
SIGNS/SYMPTOMS MAY INCLUDE SEVERE MOUTH, THROAT AND ABDOMINAL PAIN;
NAUSEA; VOMITING; AND DIARRHEA; BLOOD IN THE FECES AND/OR VOMITUS MAY ALSO
BE SEEN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
SINGLE EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION:
SIGNS/SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS, DROWSINESS, INCOORDINATION,
NAUSEA, SLOWED REACTION TIME, SLURRED SPEECH, GIDDINESS, AND
UNCONSCIOUSNESS.
CARDIAC SENSITIZATION:
SIGNS/SYMPTOMS MAY INCLUDE IRREGULAR HEARTBEAT (ARRHYTHMIA), FAINTNESS,
CHEST PAIN, AND MAY BE FATAL.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE;
VAPOR CALCULATED ATE:
(4 HR) >50 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
2-BUTOXYETHANOL DERMAL GUINEA LD50: >2,000 MG/KG
PIG
2-BUTOXYETHANOL INHALATION- GUINEA LC50: >2.6 MG/L
VAPOR PIG
(4 HOURS)
2-BUTOXYETHANOL INGESTION GUINEA LD50: 1,414 MG/KG
PIG
PETROLEUM GASES, INHALATION- RAT LC50: 277,000 PPM
LIQUEFIED, SWEETENED GAS
(4 HOURS)
ETHANOLAMINE INHALATION- OFFICIAL LC50 ESTIMATED TO
VAPOR CLASSIFICATION BE 10 - 20 MG/L
ETHANOLAMINE DERMAL RABBIT LD50: 1,000 MG/KG
ETHANOLAMINE INGESTION RAT LD50: 1,720 MG/KG
ETHOXYLATED C12-C15 DERMAL RAT LD50: 5,000 MG/KG
ALCOHOLS
ETHOXYLATED C12-C15 INGESTION RAT LD50: 1,200 MG/KG
ALCOHOLS
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
OVERALL PRODUCT IN VITRO DATA CORROSIVE
2-BUTOXYETHANOL RABBIT IRRITANT
PETROLEUM GASES, PROFESSIONAL NO SIGNIFICANT IRRITATION
LIQUEFIED, SWEETENED JUDGEMENT
ETHANOLAMINE RABBIT CORROSIVE
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
OVERALL PRODUCT PROFESSIONAL SEVERE IRRITANT
JUDGEMENT
2-BUTOXYETHANOL RABBIT SEVERE IRRITANT
PETROLEUM GASES, PROFESSIONAL NO SIGNIFICANT IRRITATION
LIQUEFIED, SWEETENED JUDGEMENT
ETHANOLAMINE RABBIT CORROSIVE
ETHOXYLATED C12-C15 ALCOHOLS NOT AVAILABLE CORROSIVE
SKIN SENSITIZATION:
NAME SPECIES VALUE
2-BUTOXYETHANOL GUINEA PIG NOT CLASSIFIED
ETHANOLAMINE GUINEA PIG NOT CLASSIFIED
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
2-BUTOXYETHANOL IN VITRO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
PETROLEUM GASES, LIQUEFIED, IN VITRO NOT MUTAGENIC
SWEETENED
ETHANOLAMINE IN VITRO NOT MUTAGENIC
ETHANOLAMINE IN VIVO NOT MUTAGENIC
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
2-BUTOXYETHANOL INHALATION MULTIPLE SOME POSITIVE DATA EXIST,
ANIMAL BUT THE DATA ARE NOT
SPECIES SUFFICIENT FOR CLASSIFICATION
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
2-BUTOXYETHANOL DERMAL NOT CLASSIFIED FOR DEVELOPMENT
2-BUTOXYETHANOL INGESTION NOT CLASSIFIED FOR DEVELOPMENT
2-BUTOXYETHANOL INHALATION NOT CLASSIFIED FOR DEVELOPMENT
ETHANOLAMINE DERMAL NOT CLASSIFIED FOR DEVELOPMENT
ETHANOLAMINE INGESTION NOT CLASSIFIED FOR DEVELOPMENT
NAME SPECIES TEST RESULT EXPOSURE DURATION
2-BUTOXYETHANOL RAT NOAEL: DURING GESTATION
1,760 MG/KG/DAY
2-BUTOXYETHANOL RAT NOAEL: DURING
100 MG/KG/DAY ORGANOGENESIS
2-BUTOXYETHANOL MULTIPLE NOAEL: DURING
ANIMAL 0.48 MG/L ORGANOGENESIS
SPECIES
ETHANOLAMINE RAT NOAEL: DURING
225 MG/KG/DAY ORGANOGENESIS
ETHANOLAMINE RAT NOAEL: DURING
616 MG/KG/DAY ORGANOGENESIS
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
2-BUTOXYETHANOL DERMAL ENDOCRINE SYSTEM NOT CLASSIFIED
2-BUTOXYETHANOL DERMAL LIVER NOT CLASSIFIED
2-BUTOXYETHANOL DERMAL KIDNEY AND/OR NOT CLASSIFIED
BLADDER
2-BUTOXYETHANOL DERMAL BLOOD NOT CLASSIFIED
2-BUTOXYETHANOL INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
2-BUTOXYETHANOL INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
2-BUTOXYETHANOL INHALATION BLOOD NOT CLASSIFIED
2-BUTOXYETHANOL INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
2-BUTOXYETHANOL INGESTION BLOOD NOT CLASSIFIED
2-BUTOXYETHANOL INGESTION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
PETROLEUM GASES, INHALATION CARDIAC CAUSES DAMAGE TO
LIQUEFIED, SENSITIZATION ORGANS
SWEETENED
PETROLEUM GASES, INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
LIQUEFIED, SYSTEM DEPRESSION OR DIZZINESS
SWEETENED
PETROLEUM GASES, INHALATION RESPIRATORY NOT CLASSIFIED
LIQUEFIED, IRRITATION
SWEETENED
ETHANOLAMINE INHALATION RESPIRATORY MAY CAUSE
IRRITATION RESPIRATORY
IRRITATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
2-BUTOXYETHANOL RABBIT NOAEL: 6 HOURS
902 MG/KG
2-BUTOXYETHANOL RABBIT LOAEL: 72 MG/KG NOT AVAILABLE
2-BUTOXYETHANOL RABBIT LOAEL: 451 MG/KG 6 HOURS
2-BUTOXYETHANOL MULTIPLE NOAEL:
ANIMAL NOT AVAILABLE
SPECIES
2-BUTOXYETHANOL HUMAN NOAEL:
NOT AVAILABLE
2-BUTOXYETHANOL HUMAN NOAEL:
NOT AVAILABLE
2-BUTOXYETHANOL MULTIPLE NOAEL:
ANIMAL NOT AVAILABLE
SPECIES
2-BUTOXYETHANOL PROFESSIONAL NOAEL:
JUDGEMENT NOT AVAILABLE
2-BUTOXYETHANOL MULTIPLE NOAEL:
ANIMAL NOT AVAILABLE
SPECIES
2-BUTOXYETHANOL HUMAN NOAEL: POISONING
NOT AVAILABLE AND/OR ABUSE
PETROLEUM GASES, SIMILAR NOAEL:
LIQUEFIED, COMPOUNDS NOT AVAILABLE
SWEETENED
PETROLEUM GASES, NOAEL:
LIQUEFIED, NOT AVAILABLE
SWEETENED
PETROLEUM GASES, NOAEL:
LIQUEFIED, NOT AVAILABLE
SWEETENED
ETHANOLAMINE HUMAN AND NOAEL:
ANIMAL NOT AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
2-BUTOXYETHANOL DERMAL BLOOD NOT CLASSIFIED
2-BUTOXYETHANOL DERMAL ENDOCRINE SYSTEM NOT CLASSIFIED
2-BUTOXYETHANOL INHALATION LIVER NOT CLASSIFIED
2-BUTOXYETHANOL INHALATION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
2-BUTOXYETHANOL INHALATION BLOOD NOT CLASSIFIED
2-BUTOXYETHANOL INHALATION ENDOCRINE SYSTEM NOT CLASSIFIED
2-BUTOXYETHANOL INGESTION BLOOD NOT CLASSIFIED
2-BUTOXYETHANOL INGESTION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
PETROLEUM GASES, INHALATION KIDNEY AND/OR NOT CLASSIFIED
LIQUEFIED, BLADDER
SWEETENED
ETHANOLAMINE INHALATION LIVER NOT CLASSIFIED
KIDNEY AND/OR
BLADDER
RESPIRATORY
SYSTEM
ETHANOLAMINE INGESTION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
LIVER
KIDNEY AND/OR
BLADDER
RESPIRATORY
SYSTEM
NAME SPECIES TEST RESULT EXPOSURE DURATION
2-BUTOXYETHANOL MULTIPLE NOAEL: NOT AVAILABLE
ANIMAL NOT AVAILABLE
SPECIES
2-BUTOXYETHANOL RABBIT NOAEL: 90 DAYS
150 MG/KG/DAY
2-BUTOXYETHANOL RAT NOAEL: 2.4 MG/L 14 WEEKS
2-BUTOXYETHANOL RAT NOAEL: 0.15 MG/L 14 WEEKS
2-BUTOXYETHANOL RAT LOAEL: 0.15 MG/L 6 MONTHS
2-BUTOXYETHANOL DOG LOAEL: 1.9 MG/L 8 DAYS
2-BUTOXYETHANOL RAT LOAEL: 13 WEEKS
69 MG/KG/DAY
2-BUTOXYETHANOL MULTIPLE NOAEL: NOT AVAILABLE
ANIMAL NOT AVAILABLE
SPECIES
PETROLEUM GASES, RAT NOAEL:
LIQUEFIED, NOT AVAILABLE
SWEETENED
ETHANOLAMINE MULTIPLE NOAEL: 5 WEEKS
ANIMAL 0.656 MG/L
SPECIES
ETHANOLAMINE RAT NOAEL:
NOT AVAILABLE
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
A 3M PRODUCT ENVIRONMENTAL DATA SHEET (PED) IS AVAILABLE.
CHEMICAL FATE INFORMATION:
A 3M PRODUCT ENVIRONMENTAL DATA SHEET (PED) IS AVAILABLE.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
INCINERATE IN A PERMITTED WASTE INCINERATION FACILITY. PROPER DESTRUCTION
MAY REQUIRE THE USE OF ADDITIONAL FUEL DURING INCINERATION PROCESSES.
FACILITY MUST BE CAPABLE OF HANDLING AEROSOL CANS. AS A DISPOSAL
ALTERNATIVE, UTILIZE AN ACCEPTABLE PERMITTED WASTE DISPOSAL FACILITY.
EMPTY DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING
HAZARDOUS CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED
AS HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): D002 (CORROSIVE)
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
EPCRA 311/312 HAZARD CLASSIFICATIONS:
PHYSICAL HAZARDS: GAS UNDER PRESSURE
HEALTH HAZARDS:
HAZARD NOT OTHERWISE CLASSIFIED (HNOC)
SERIOUS EYE DAMAGE OR EYE IRRITATION
SKIN CORROSION OR IRRITATION
SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF
THAT SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
2-BUTOXYETHANOL (GLYCOL ETHERS) 111-76-2 10 - 30
15.2. STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
INGREDIENT C.A.S. NO. LISTING
CADMIUM NONE MALE REPRODUCTIVE TOXIN
CADMIUM AND CADMIUM COMPOUNDS NONE CARCINOGEN
CADMIUM NONE DEVELOPMENTAL TOXIN
MERCURY AND MERCURY COMPOUNDS NONE DEVELOPMENTAL TOXIN
ETHYLENE GLYCOL (INGESTED) 107-21-1 DEVELOPMENTAL TOXIN
CHROMIUM (HEXAVALENT COMPOUNDS) NONE FEMALE REPRODUCTIVE TOXIN
CHROMIUM (HEXAVALENT COMPOUNDS) NONE MALE REPRODUCTIVE TOXIN
CHROMIUM (HEXAVALENT COMPOUNDS) NONE CARCINOGEN
CHROMIUM (HEXAVALENT COMPOUNDS) NONE DEVELOPMENTAL TOXIN
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
AUSTRALIA NATIONAL INDUSTRIAL CHEMICAL NOTIFICATION AND ASSESSMENT SCHEME
(NICNAS). CERTAIN RESTRICTIONS MAY APPLY. CONTACT THE SELLING DIVISION
FOR ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE NEW SUBSTANCE
NOTIFICATION REQUIREMENTS OF CEPA.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE CHINA "MEASURES
ON ENVIRONMENTAL MANAGEMENT OF NEW CHEMICAL SUBSTANCE". CERTAIN
RESTRICTIONS MAY APPLY. CONTACT THE SELLING DIVISION FOR ADDITIONAL
INFORMATION.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
THE KOREAN TOXIC CHEMICAL CONTROL LAW. CERTAIN RESTRICTIONS MAY APPLY.
CONTACT THE SELLING DIVISION FOR ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
PHILIPPINES RA 6969 REQUIREMENTS. CERTAIN RESTRICTIONS MAY APPLY. CONTACT
THE SELLING DIVISION FOR ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA. ALL REQUIRED COMPONENTS OF THIS
PRODUCT ARE LISTED ON THE ACTIVE PORTION OF THE TSCA INVENTORY.
THIS PRODUCT COMPLIES WITH THE NEW ZEALAND HAZARDOUS SUBSTANCES AND NEW
ORGANISMS ACT (1996).
15.4. INTERNATIONAL REGULATIONS:
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 3
FLAMMABILITY 2
INSTABILITY 0
SPECIAL HAZARDS NONE
AEROSOL STORAGE CODE: 1
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED
FOR USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED
ON THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO
INCLUDE THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT
ARE KNOWN TO BE GENERATED IN SIGNIFICANT QUANTITIES.
HMIS HAZARD CLASSIFICATION:
HEALTH 3*
FLAMMABILITY 2
PHYSICAL HAZARD 0
PERSONAL PROTECTION X - SEE PPE SECTION.
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM (HMIS(R*) IV) HAZARD RATINGS ARE
DESIGNED TO INFORM EMPLOYEES OF CHEMICAL HAZARDS IN THE WORKPLACE. THESE
RATINGS ARE BASED ON THE INHERENT PROPERTIES OF THE MATERIAL UNDER EXPECTED
CONDITIONS OF NORMAL USE AND ARE NOT INTENDED FOR USE IN EMERGENCY
SITUATIONS. HMIS(R*) IV RATINGS ARE TO BE USED WITH A FULLY IMPLEMENTED
HMIS(R*) IV PROGRAM. HMIS(R*) IS A REGISTERED MARK OF THE AMERICAN COATINGS
ASSOCIATION (ACA).
DOCUMENT GROUP: 10-2818-2
VERSION NUMBER: 23.00
ISSUE DATE: 04/16/19
SUPERCEDES DATE: 01/08/18
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THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
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PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
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