| Common Name: | SHARPSHOOTER EXTRA STRENGTH NO RINSE MARK REMOVER, 70-0712-8530-1, 70-0716-8311- |
| Manufacturer: | 3M |
| SDS Revision Date: | 9/28/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 3U124 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SHARPSHOOTER(TM) EXTRA STRENGTH NO RINSE MARK REMOVER
09/28/15
3M
SAFETY DATA SHEET
COPYRIGHT, 2015, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 33-6984-0
VERSION NUMBER: 3.00
ISSUE DATE: 09/28/15
SUPERCEDES DATE: 11/11/14
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
SHARPSHOOTER(TM) EXTRA STRENGTH NO RINSE MARK REMOVER
PRODUCT IDENTIFICATION NUMBERS:
70-0712-8530-1, 70-0716-8311-7, 70-0716-8314-1
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE:
THIS NO-RINSE CLEANER REMOVES TOUGH STAINS SUCH AS GREASE, LIPSTICK,
CRAYON, BLACK HEEL MARKS, PENCIL MARKS AND SMOKE FILM FROM MOST WASHABLE
HARD SURFACES., HARD SURFACE CLEANER
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: COMMERCIAL SOLUTIONS DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 1.
SKIN CORROSION/IRRITATION: CATEGORY 1B.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 1.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
CORROSION
HEALTH HAZARD
PICTOGRAMS:
CORROSION
HEALTH HAZARD
HAZARD STATEMENTS:
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
CAUSES DAMAGE TO ORGANS: BLOOD OR BLOOD-FORMING ORGANS
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE:
BLOOD OR BLOOD-FORMING ORGANS
PRECAUTIONARY STATEMENTS:
GENERAL: KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, AND EYE/FACE PROTECTION.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
RESPONSE:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED:
MAY CAUSE CHEMICAL GASTROINTESTINAL BURNS.
2% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE INHALATION
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
WATER 7732-18-5 80 - 95 TRADE SECRET *
2-BUTOXYETHANOL 111-76-2 3 - 7 TRADE SECRET *
ETHANOLAMINE 141-43-5 1 - 5 TRADE SECRET *
ALCOHOLS, C6-12, ETHOXYLATED 68439-45-2 0.5 - 1.5 TRADE SECRET *
ALCOHOLS, C12-14-SECONDARY, 84133-50-6 0.5 - 1.5 TRADE SECRET *
ETHOXYLATED
POTASSIUM HYDROXIDE 1310-58-3 0.1 - 1 TRADE SECRET *
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTAMINATED CLOTHING. GET IMMEDIATE MEDICAL ATTENTION.
WASH CLOTHING BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTACT LENSES IF EASY TO DO. CONTINUE RINSING. IMMEDIATELY GET
MEDICAL ATTENTION.
IF SWALLOWED:
RINSE MOUTH. DO NOT INDUCE VOMITING. GET IMMEDIATE MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
MATERIAL WILL NOT BURN. USE A FIRE FIGHTING AGENT SUITABLE FOR THE
SURROUNDING FIRE.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE. REFER
TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH
HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE
EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND BUILD
DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. FOR LARGE SPILLS, IF NECESSARY, GET ASSISTANCE FROM
PROFESSIONAL SPILL CLEAN UP TEAM. FOR SMALL SPILLS, CAREFULLY NEUTRALIZE
SPILL BY ADDING APPROPRIATE DILUTE ACID SUCH AS VINEGAR. WORK SLOWLY TO
AVOID BOILING OR SPATTERING. CONTINUE TO ADD NEUTRALIZING AGENT UNTIL
REACTION STOPS. LET COOL BEFORE COLLECTING. OR USE A COMMERCIALLY AVAILABLE
CAUSTIC (ALKALINE OR BASIC) SPILL CLEAN-UP KIT. FOLLOW KIT DIRECTIONS
EXACTLY. WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER WITH
BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT
MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER,
ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR
ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE.
PLACE IN A METAL CONTAINER APPROVED FOR USE IN TRANSPORTATION BY
APPROPRIATE AUTHORITIES. THE CONTAINER MUST BE LINED WITH POLYETHYLENE
PLASTIC OR CONTAIN A PLASTIC DRUM LINER MADE OF POLYETHYLENE. CLEAN UP
RESIDUE WITH WATER. COVER, BUT DO NOT SEAL FOR 48 HOURS. DISPOSE OF
COLLECTED MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
DO NOT USE IN A CONFINED AREA WITH MINIMAL AIR EXCHANGE. KEEP OUT OF REACH
OF CHILDREN. DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN
EYES, ON SKIN, OR ON CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS
PRODUCT. WASH THOROUGHLY AFTER HANDLING. AVOID RELEASE TO THE ENVIRONMENT.
WASH CONTAMINATED CLOTHING BEFORE REUSE. KEEP AWAY FROM REACTIVE METALS
(EG. ALUMINUM, ZINC ETC.) TO AVOID THE FORMATION OF HYDROGEN GAS THAT COULD
CREATE AN EXPLOSION HAZARD.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE AWAY FROM ACIDS. STORE AWAY FROM AREAS WHERE PRODUCT MAY COME INTO
CONTACT WITH FOOD OR PHARMACEUTICALS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
2-BUTOXYETHANOL 111-76-2 ACGIH TWA: 20 PPM A3:
CONFIRMED ANIMAL
CARCIN.
2-BUTOXYETHANOL 111-76-2 OSHA TWA: SKIN NOTATION
240 MG/M3
(50 PPM)
POTASSIUM HYDROXIDE 1310-58-3 ACGIH CEIL: 2 MG/M3
ETHANOLAMINE 141-43-5 ACGIH TWA: 3 PPM
STEL: 6 PPM
ETHANOLAMINE 141-43-5 OSHA TWA:
6 MG/M3
(3 PPM)
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
FULL FACE SHIELD
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
NOTE:
NITRILE GLOVES MAY BE WORN OVER POLYMER LAMINATE GLOVES TO IMPROVE
DEXTERITY.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED: BUTYL RUBBER
NITRILE RUBBER
POLYMER LAMINATE
IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL FOR
EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF PROTECTIVE
COVERALLS MAY BE NECESSARY. SELECT AND USE BODY PROTECTION TO PREVENT
CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED:
APRON - BUTYL RUBBER
APRON - NITRILE
APRON - POLYMER LAMINATE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
ODOR, COLOR, GRADE: CLEAR, COLORLESS; MILD SOLVENT ODOR
ODOR THRESHOLD: NOT APPLICABLE
PH: 12.7 - 13.4
BOILING POINT: >212 DEG. F
FLASH POINT: NO FLASH POINT
EVAPORATION RATE: APPROXIMATELY 1 [REF STD: WATER=1]
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS (LEL): NOT APPLICABLE
FLAMMABLE LIMITS (UEL): NOT APPLICABLE
VAPOR PRESSURE: <27 PSIA [@ 131 DEG. F]
DENSITY: APPROXIMATELY 1.002 G/ML
SPECIFIC GRAVITY: APPROXIMATELY 1.001 - 1.011 [REF STD: WATER=1]
SOLUBILITY IN WATER: COMPLETE
SOLUBILITY-NON-WATER: NOT APPLICABLE
AUTOIGNITION TEMPERATURE: NOT APPLICABLE
DECOMPOSITION TEMPERATURE: NOT APPLICABLE
VISCOSITY: <100 CENTIPOISE
VOLATILE ORGANIC COMPOUNDS:
6 - 8% WEIGHT [TEST METHOD: CALCULATED PER CARB TITLE 2]
PERCENT VOLATILE: 80 - 100% WEIGHT
VOC LESS H2O & EXEMPT SOLVENTS:
850 - 870 G/L [TEST METHOD: CALCULATED PER CARB TITLE 2]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL IS CONSIDERED TO BE NON REACTIVE UNDER NORMAL USE CONDITIONS.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: NONE KNOWN.
10.5. INCOMPATIBLE MATERIALS: NONE KNOWN.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE NOT SPECIFIED
CARBON DIOXIDE NOT SPECIFIED
OXIDES OF NITROGEN NOT SPECIFIED
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR
THE SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT
BELOW THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION: MAY BE HARMFUL IF INHALED.
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
CORROSIVE (SKIN BURNS):
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, INTENSE
PAIN, BLISTERING, ULCERATION, AND TISSUE DESTRUCTION.
EYE CONTACT:
CORROSIVE (EYE BURNS):
SIGNS/SYMPTOMS MAY INCLUDE CLOUDY APPEARANCE OF THE CORNEA, CHEMICAL BURNS,
SEVERE PAIN, TEARING, ULCERATIONS, SIGNIFICANTLY IMPAIRED VISION OR
COMPLETE LOSS OF VISION.
INGESTION:
GASTROINTESTINAL CORROSION:
SIGNS/SYMPTOMS MAY INCLUDE SEVERE MOUTH, THROAT AND ABDOMINAL PAIN; NAUSEA;
VOMITING; AND DIARRHEA; BLOOD IN THE FECES AND/OR VOMITUS MAY ALSO BE SEEN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
SINGLE EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
BLOOD EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE GENERALIZED WEAKNESS AND FATIGUE, SKIN PALLOR,
CHANGES IN BLOOD CLOTTING TIME, INTERNAL BLEEDING, AND/OR HEMOGLOBINEMIA.
PROLONGED OR REPEATED EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
BLOOD EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE GENERALIZED WEAKNESS AND FATIGUE, SKIN PALLOR,
CHANGES IN BLOOD CLOTTING TIME, INTERNAL BLEEDING, AND/OR HEMOGLOBINEMIA.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE;
VAPOR (4 HR) CALCULATED ATE:
20 - 50 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
2-BUTOXYETHANOL DERMAL GUINEA LD50: >2,000 MG/KG
PIG
2-BUTOXYETHANOL INHALATION- GUINEA LC50: >2.6 MG/L
VAPOR PIG
(4 HOURS)
2-BUTOXYETHANOL INGESTION GUINEA LD50: 1,414 MG/KG
PIG
ETHANOLAMINE INHALATION- OFFICIAL LC50:
VAPOR CLASSIFICATION ESTIMATED TO BE
10 - 20 MG/L
ETHANOLAMINE DERMAL RABBIT LD50: 1,000 MG/KG
ETHANOLAMINE INGESTION RAT LD50: 1,720 MG/KG
ALCOHOLS, C12-14- DERMAL RABBIT LD50: 1,127 MG/KG
SECONDARY, ETHOXYLATED
ALCOHOLS, C6-12, DERMAL RABBIT LD50: 1,500 MG/KG
ETHOXYLATED
ALCOHOLS, C12-14- INHALATION- RAT LC50: 1.1 MG/L
SECONDARY, ETHOXYLATED DUST/MIST
(4 HOURS)
ALCOHOLS, C12-14- INGESTION RAT LD50: 412 MG/KG
SECONDARY, ETHOXYLATED
ALCOHOLS, C6-12, INGESTION RAT LD50: 5,100 MG/KG
ETHOXYLATED
POTASSIUM HYDROXIDE DERMAL RABBIT LD50: >1,260 MG/KG
POTASSIUM HYDROXIDE INGESTION RAT LD50: 273 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
OVERALL PRODUCT CORROSIVE
2-BUTOXYETHANOL RABBIT IRRITANT
ETHANOLAMINE RABBIT CORROSIVE
POTASSIUM HYDROXIDE RABBIT CORROSIVE
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
2-BUTOXYETHANOL RABBIT SEVERE IRRITANT
ETHANOLAMINE RABBIT CORROSIVE
POTASSIUM HYDROXIDE RABBIT CORROSIVE
SKIN SENSITIZATION:
NAME SPECIES VALUE
2-BUTOXYETHANOL GUINEA PIG NOT SENSITIZING
ETHANOLAMINE GUINEA PIG SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
2-BUTOXYETHANOL IN VITRO SOME POSITIVE DATA EXIST, BUT THE DATA
ARE NOT SUFFICIENT FOR CLASSIFICATION
ETHANOLAMINE IN VITRO NOT MUTAGENIC
ETHANOLAMINE IN VIVO NOT MUTAGENIC
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
2-BUTOXYETHANOL INHALATION MULTIPLE SOME POSITIVE DATA EXIST, BUT THE
ANIMAL DATA ARE NOT SUFFICIENT FOR
SPECIES CLASSIFICATION
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
2-BUTOXYETHANOL DERMAL NOT TOXIC TO DEVELOPMENT
2-BUTOXYETHANOL INGESTION SOME POSITIVE DEVELOPMENTAL DATA EXIST,
BUT THE DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
2-BUTOXYETHANOL INHALATION SOME POSITIVE DEVELOPMENTAL DATA EXIST,
BUT THE DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
ETHANOLAMINE DERMAL NOT TOXIC TO DEVELOPMENT
ETHANOLAMINE INGESTION NOT TOXIC TO DEVELOPMENT
NAME SPECIES TEST RESULT EXPOSURE
DURATION
2-BUTOXYETHANOL RAT NOAEL: 1,760 MG/KG/DAY DURING
GESTATION
2-BUTOXYETHANOL RAT NOAEL: 100 MG/KG/DAY DURING
ORGANOGENESIS
2-BUTOXYETHANOL MULTIPLE NOAEL: 0.48 MG/L DURING
ANIMAL ORGANOGENESIS
SPECIES
ETHANOLAMINE RAT NOAEL: 225 MG/KG/DAY DURING
ORGANOGENESIS
ETHANOLAMINE RAT NOAEL: 616 MG/KG/DAY DURING
ORGANOGENESIS
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
2-BUTOXYETHANOL DERMAL ENDOCRINE SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
2-BUTOXYETHANOL DERMAL LIVER SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
2-BUTOXYETHANOL DERMAL KIDNEY AND/OR SOME POSITIVE DATA
BLADDER EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
2-BUTOXYETHANOL DERMAL BLOOD SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
2-BUTOXYETHANOL INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DIZZINESS
DEPRESSION
2-BUTOXYETHANOL INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
2-BUTOXYETHANOL INHALATION BLOOD SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
2-BUTOXYETHANOL INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM OR DIZZINESS
DEPRESSION
2-BUTOXYETHANOL INGESTION BLOOD SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
2-BUTOXYETHANOL INGESTION KIDNEY AND/OR SOME POSITIVE DATA
BLADDER EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
ETHANOLAMINE INHALATION RESPIRATORY MAY CAUSE RESPIRATORY
IRRITATION IRRITATION
POTASSIUM HYDROXIDE INHALATION RESPIRATORY MAY CAUSE RESPIRATORY
IRRITATION IRRITATION
NAME SPECIES TEST RESULT EXPOSURE
DURATION
2-BUTOXYETHANOL RABBIT NOAEL: 902 MG/KG 6 HOURS
2-BUTOXYETHANOL RABBIT LOAEL: 72 MG/KG NOT AVAILABLE
2-BUTOXYETHANOL RABBIT LOAEL: 451 MG/KG 6 HOURS
2-BUTOXYETHANOL MULTIPLE NOAEL: NOT AVAILABLE
ANIMAL
SPECIES
2-BUTOXYETHANOL HUMAN NOAEL: NOT AVAILABLE
2-BUTOXYETHANOL HUMAN NOAEL: NOT AVAILABLE
2-BUTOXYETHANOL MULTIPLE NOAEL: NOT AVAILABLE
ANIMAL
SPECIES
2-BUTOXYETHANOL PROFESSIONAL NOAEL: NOT AVAILABLE
JUDGEMENT
2-BUTOXYETHANOL MULTIPLE NOAEL: NOT AVAILABLE
ANIMAL
SPECIES
2-BUTOXYETHANOL HUMAN NOAEL: NOT AVAILABLE POISONING
AND/OR ABUSE
ETHANOLAMINE HUMAN AND NOAEL: NOT AVAILABLE
ANIMAL
POTASSIUM HYDROXIDE HUMAN NOAEL: NOT AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
2-BUTOXYETHANOL DERMAL BLOOD SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
2-BUTOXYETHANOL DERMAL ENDOCRINE SYSTEM ALL DATA ARE NEGATIVE
2-BUTOXYETHANOL INHALATION LIVER SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
2-BUTOXYETHANOL INHALATION KIDNEY AND/OR SOME POSITIVE DATA EXIST,
BLADDER BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
2-BUTOXYETHANOL INHALATION BLOOD SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
2-BUTOXYETHANOL INHALATION ENDOCRINE SYSTEM SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
2-BUTOXYETHANOL INGESTION BLOOD SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
2-BUTOXYETHANOL INGESTION KIDNEY AND/OR SOME POSITIVE DATA EXIST,
BLADDER BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
ETHANOLAMINE INHALATION LIVER SOME POSITIVE DATA EXIST,
KIDNEY AND/OR BUT THE DATA ARE NOT
BLADDER SUFFICIENT FOR
RESPIRATORY CLASSIFICATION
SYSTEM
ETHANOLAMINE INGESTION HEMATOPOIETIC SOME POSITIVE DATA EXIST,
SYSTEM BUT THE DATA ARE NOT
LIVER SUFFICIENT FOR
KIDNEY AND/OR CLASSIFICATION
BLADDER
RESPIRATORY
SYSTEM
NAME SPECIES TEST RESULT EXPOSURE
DURATION
2-BUTOXYETHANOL MULTIPLE NOAEL: NOT AVAILABLE NOT AVAILABLE
ANIMAL
SPECIES
2-BUTOXYETHANOL RABBIT NOAEL: 150 MG/KG/DAY 90 DAYS
2-BUTOXYETHANOL RAT NOAEL: 2.4 MG/L 14 WEEKS
2-BUTOXYETHANOL RAT NOAEL: 0.15 MG/L 14 WEEKS
2-BUTOXYETHANOL RAT LOAEL: 0.15 MG/L 6 MONTHS
2-BUTOXYETHANOL DOG LOAEL: 1.9 MG/L 8 DAYS
2-BUTOXYETHANOL RAT LOAEL: 69 MG/KG/DAY 13 WEEKS
2-BUTOXYETHANOL MULTIPLE NOAEL: NOT AVAILABLE NOT AVAILABLE
ANIMAL
SPECIES
ETHANOLAMINE MULTIPLE NOAEL: 0.656 MG/L 5 WEEKS
ANIMAL
SPECIES
ETHANOLAMINE RAT NOAEL: NOT AVAILABLE
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/ CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF WASTE PRODUCT IN A PERMITTED INDUSTRIAL WASTE FACILITY. EMPTY
DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): D002 (CORROSIVE)
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
311/312 HAZARD CATEGORIES:
FIRE HAZARD: NO
PRESSURE HAZARD: NO
REACTIVITY HAZARD: NO
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
2-BUTOXYETHANOL (GLYCOL ETHERS) 111-76-2 3 - 7
15.2. STATE REGULATIONS:
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
AUSTRALIA NATIONAL INDUSTRIAL CHEMICAL NOTIFICATION AND ASSESSMENT SCHEME
(NICNAS). CERTAIN RESTRICTIONS MAY APPLY. CONTACT THE SELLING DIVISION FOR
ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE NEW SUBSTANCE
NOTIFICATION REQUIREMENTS OF CEPA.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE CHINA
"MEASURES ON ENVIRONMENTAL MANAGEMENT OF NEW CHEMICAL SUBSTANCE". CERTAIN
RESTRICTIONS MAY APPLY. CONTACT THE SELLING DIVISION FOR ADDITIONAL
INFORMATION.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
THE KOREAN TOXIC CHEMICAL CONTROL LAW. CERTAIN RESTRICTIONS MAY APPLY.
CONTACT THE SELLING DIVISION FOR ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
15.4. INTERNATIONAL REGULATIONS:
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 3
FLAMMABILITY 0
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED
FOR USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
HMIS HAZARD CLASSIFICATION:
HEALTH 4
FLAMMABILITY 0
PHYSICAL HAZARD 0
PERSONAL PROTECTION X - SEE PPE SECTION.
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM (HMIS(R*) IV) HAZARD RATINGS ARE
DESIGNED TO INFORM EMPLOYEES OF CHEMICAL HAZARDS IN THE WORKPLACE. THESE
RATINGS ARE BASED ON THE INHERENT PROPERTIES OF THE MATERIAL UNDER EXPECTED
CONDITIONS OF NORMAL USE AND ARE NOT INTENDED FOR USE IN EMERGENCY
SITUATIONS. HMIS(R*) IV RATINGS ARE TO BE USED WITH A FULLY IMPLEMENTED
HMIS(R*) IV PROGRAM. HMIS(R*) IS A REGISTERED MARK OF THE AMERICAN COATINGS
ASSOCIATION (ACA).
DOCUMENT GROUP: 33-6984-0
VERSION NUMBER: 3.00
ISSUE DATE: 09/28/15
SUPERCEDES DATE: 11/11/14
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INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
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