| Common Name: | FLOOR STRIPPER |
| Manufacturer: | 3M |
| SDS Revision Date: | 10/9/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 3U142 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) FLOOR STRIPPER
10/09/18
3M
SAFETY DATA SHEET
COPYRIGHT, 2018, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 19-4136-8
VERSION NUMBER: 5.00
ISSUE DATE: 10/09/18
SUPERCEDES DATE: 01/22/18
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER: 3M(TM) FLOOR STRIPPER
PRODUCT IDENTIFICATION NUMBERS:
61-5000-3758-7, 70-0716-8280-4 7000045889, 7100077221
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE:
LOW-FOAMING, EASY-RINSING FLOOR STRIPPER DESIGNED TO AGRESSIVELY REMOVE
FINISHES AND SEALERS; INCLUDING FINISHES HARDENED BY FREQUENT BURNISHING,
EXCESS FINISH BUILD-UP AND TOUGH METAL INTERLOCK FINISHES., HARD FLOOR
MAINTENANCE
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: COMMERCIAL SOLUTIONS DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 1.
SKIN CORROSION/IRRITATION: CATEGORY 1C.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 1.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
CORROSION
HEALTH HAZARD
PICTOGRAMS:
CORROSION
HEALTH HAZARD
HAZARD STATEMENTS:
CAUSES SEVERE SKIN BUMS AND EYE DAMAGE.
CAUSES DAMAGE TO ORGANS: BLOOD OR BLOOD-FORMING ORGANS
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE:
BLOOD OR BLOOD-FORMING ORGANS
PRECAUTIONARY STATEMENTS:
PREVENTION:
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, AND EYE/FACE PROTECTION.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
RESPONSE:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO.
CONTINUE RINSING.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF EXPOSED: CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
3% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE ORAL TOXICITY.
5% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE DERMAL TOXICITY.
10% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE INHALATION
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
WATER 7732-18-5 60 - 90 TRADE SECRET *
2-BUTOXYETHANOL 111-76-2 7 - 13 TRADE SECRET *
SODIUM METASILICATE 6834-92-0 1 - 5 TRADE SECRET *
ETHANOLAMINE 141-43-5 1 - 5 TRADE SECRET *
SODIUM HYDROXIDE 1310-73-2 1 - 5 TRADE SECRET *
SULFONIC ACIDS, C14-16 ALKANE 68439-57-6 1 - 5 TRADE SECRET *
HYDROXY AND C14-16 ALKENE,
SODIUM SALTS
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTAMINATED CLOTHING. GET IMMEDIATE MEDICAL ATTENTION. WASH
CLOTHING BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTACT LENSES IF EASY TO DO. CONTINUE RINSING. IMMEDIATELY GET
MEDICAL ATTENTION.
IF SWALLOWED:
RINSE MOUTH. DO NOT INDUCE VOMITING. GET IMMEDIATE MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
MATERIAL WILL NOT BURN. USE A FIRE FIGHTING AGENT SUITABLE FOR THE
SURROUNDING FIRE.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE. REFER
TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND
HEALTH HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL
PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND
BUILD DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. FOR LARGE SPILLS, IF NECESSARY, GET ASSISTANCE FROM
PROFESSIONAL SPILL CLEAN UP TEAM. FOR SMALL SPILLS, CAREFULLY NEUTRALIZE
SPILL BY ADDING APPROPRIATE DILUTE ACID SUCH AS VINEGAR. WORK SLOWLY TO
AVOID BOILING OR SPATTERING. CONTINUE TO ADD NEUTRALIZING AGENT UNTIL
REACTION STOPS. LET COOL BEFORE COLLECTING. OR USE A COMMERCIALLY
AVAILABLE CAUSTIC (ALKALINE OR BASIC) SPILL CLEAN-UP KIT. FOLLOW KIT
DIRECTIONS EXACTLY. WORKING FROM AROUND THE EDGES OF THE SPILL INWARD,
COVER WITH BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC
ABSORBENT MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY.
REMEMBER, ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH,
OR ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS
POSSIBLE. PLACE IN A METAL CONTAINER APPROVED FOR USE IN TRANSPORTATION BY
APPROPRIATE AUTHORITIES. THE CONTAINER MUST BE LINED WITH POLYETHYLENE
PLASTIC OR CONTAIN A PLASTIC DRUM LINER MADE OF POLYETHYLENE. CLEAN UP
RESIDUE WITH WATER. COVER, BUT DO NOT SEAL FOR 48 HOURS. DISPOSE OF
COLLECTED MATERIAL AS SOON AS POSSIBLE IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON
SKIN, OR ON CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING. AVOID RELEASE TO THE ENVIRONMENT. WASH
CONTAMINATED CLOTHING BEFORE REUSE. KEEP AWAY FROM REACTIVE METALS (EG.
ALUMINUM, ZINC ETC.) TO AVOID THE FORMATION OF HYDROGEN GAS THAT COULD
CREATE AN EXPLOSION HAZARD.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE AWAY FROM ACIDS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
2-BUTOXYETHANOL 111-76-2 ACGIH TWA: 20 PPM A3:
CONFIRMED
ANIMAL CARCIN.
2-BUTOXYETHANOL 111-76-2 OSHA TWA: SKIN
240 MG/M3 (50 PPM)
SODIUM HYDROXIDE 1310-73-2 ACGIH CEIL: 2 MG/M3
SODIUM HYDROXIDE 1310-73-2 OSHA TWA: 2 MG/M3
ETHANOLAMINE 141-43-5 ACGIH TWA: 3 PPM
STEL: 6 PPM
ETHANOLAMINE 141-43-5 OSHA TWA:
6 MG/M3 (3 PPM)
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
FULL FACE SHIELD
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
NOTE:
NITRILE GLOVES MAY BE WORN OVER POLYMER LAMINATE GLOVES TO IMPROVE
DEXTERITY.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
BUTYL RUBBER
POLYMER LAMINATE
IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL FOR
EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF PROTECTIVE
COVERALLS MAY BE NECESSARY. SELECT AND USE BODY PROTECTION TO PREVENT
CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED:
APRON - BUTYL RUBBER
APRON - POLYMER LAMINATE
BOOTS - RUBBER
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM.
BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING
RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR ORGANIC VAPORS
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
SPECIFIC PHYSICAL FORM: LIQUID
ODOR, COLOR, GRADE: CLEAR, SLIGHTLY YELLOW HOMOGENOUS LIQUID
ODOR THRESHOLD: NO DATA AVAILABLE
PH: 12.4 - 14
MELTING POINT: NOT APPLICABLE
BOILING POINT: >212 DEG. F
FLASH POINT: NO FLASH POINT
EVAPORATION RATE: NOT APPLICABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): NOT APPLICABLE
FLAMMABLE LIMITS(UEL): NOT APPLICABLE
VAPOR PRESSURE: NOT APPLICABLE
VAPOR DENSITY: NOT APPLICABLE
DENSITY: NO DATA AVAILABLE
SPECIFIC GRAVITY: 1.053 - 1.063 [REF STD: WATER=1]
SOLUBILITY IN WATER: COMPLETE
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT APPLICABLE
AUTOIGNITION TEMPERATURE: NOT APPLICABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: <100 CENTIPOISE
AVERAGE PARTICLE SIZE: NOT APPLICABLE
BULK DENSITY: NOT APPLICABLE
HAZARDOUS AIR POLLUTANTS: NOT APPLICABLE
VOLATILE ORGANIC COMPOUNDS: 10 - 15% WEIGHT
PERCENT VOLATILE: 60 - 90
VOC LESS H2O & EXEMPT SOLVENTS: 600 - 650 G/L
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: NONE KNOWN.
10.5. INCOMPATIBLE MATERIALS: STRONG ACIDS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
MAY BE HARMFUL IF INHALED.
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
MAY BE HARMFUL IN CONTACT WITH SKIN.
CORROSIVE (SKIN BURNS):
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, INTENSE
PAIN, BLISTERING, ULCERATION, AND TISSUE DESTRUCTION.
EYE CONTACT:
CORROSIVE (EYE BURNS):
SIGNS/SYMPTOMS MAY INCLUDE CLOUDY APPEARANCE OF THE CORNEA, CHEMICAL BURNS,
SEVERE PAIN, TEARING, ULCERATIONS, SIGNIFICANTLY IMPAIRED VISION OR
COMPLETE LOSS OF VISION.
INGESTION:
MAY BE HARMFUL IF SWALLOWED.
GASTROINTESTINAL CORROSION:
SIGNS/SYMPTOMS MAY INCLUDE SEVERE MOUTH, THROAT AND ABDOMINAL PAIN; NAUSEA;
VOMITING; AND DIARRHEA; BLOOD IN THE FECES AND/OR VOMITUS MAY ALSO BE SEEN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
SINGLE EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
BLOOD EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE GENERALIZED WEAKNESS AND FATIGUE, SKIN PALLOR,
CHANGES IN BLOOD CLOTTING TIME, INTERNAL BLEEDING, AND/OR HEMOGLOBINEMIA.
PROLONGED OR REPEATED EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
BLOOD EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE GENERALIZED WEAKNESS AND FATIGUE, SKIN PALLOR,
CHANGES IN BLOOD CLOTTING TIME, INTERNAL BLEEDING, AND/OR HEMOGLOBINEMIA.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE
2,000 - 5,000 MG/KG
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE;
VAPOR (4 HR) CALCULATED ATE
20 - 50 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE
2,000 - 5,000 MG/KG
2-BUTOXYETHANOL DERMAL GUINEA PIG LD50: >2,000 MG/KG
2-BUTOXYETHANOL INHALATION- GUINEA PIG LC50: >2.6 MG/L
VAPOR
(4 HOURS)
2-BUTOXYETHANOL INGESTION GUINEA PIG LD50: 1,414 MG/KG
SODIUM METASILICATE DERMAL RABBIT LD50: >4,640 MG/KG
SODIUM METASILICATE INGESTION RAT LD50: 500 MG/KG
ETHANOLAMINE INHALATION- OFFICIAL LC50 ESTIMATED TO BE
VAPOR CLASSIFICATION 10 - 20 MG/L
ETHANOLAMINE DERMAL RABBIT LD50: 1,000 MG/KG
ETHANOLAMINE INGESTION RAT LD50: 1,720 MG/KG
SULFONIC ACIDS, DERMAL RAT LD50: >2,000 MG/KG
C14-16 ALKANE HYDROXY
AND C14-16 ALKENE,
SODIUM SALTS
SULFONIC ACIDS, INGESTION RAT LD50: 578 MG/KG
C14-16 ALKANE HYDROXY
AND C14-16 ALKENE,
SODIUM SALTS
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
2-BUTOXYETHANOL RABBIT IRRITANT
SODIUM METASILICATE RABBIT CORROSIVE
ETHANOLAMINE RABBIT CORROSIVE
SODIUM HYDROXIDE RABBIT CORROSIVE
SULFONIC ACIDS, C14-16 ALKANE RABBIT MILD IRRITANT
HYDROXY AND C14-16 ALKENE, SODIUM SALTS
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
2-BUTOXYETHANOL RABBIT SEVERE IRRITANT
SODIUM METASILICATE RABBIT CORROSIVE
ETHANOLAMINE RABBIT CORROSIVE
SODIUM HYDROXIDE RABBIT CORROSIVE
SULFONIC ACIDS, C14-16 ALKANE HYDROXY AND RABBIT CORROSIVE
C14-16 ALKENE, SODIUM SALTS
SKIN SENSITIZATION:
NAME SPECIES VALUE
2-BUTOXYETHANOL GUINEA PIG NOT CLASSIFIED
SODIUM METASILICATE MOUSE NOT CLASSIFIED
ETHANOLAMINE GUINEA PIG NOT CLASSIFIED
SODIUM HYDROXIDE HUMAN NOT CLASSIFIED
SULFONIC ACIDS, C14-16 ALKANE HYDROXY GUINEA PIG NOT CLASSIFIED
AND C14-16 ALKENE, SODIUM SALTS
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
2-BUTOXYETHANOL IN VITRO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
SODIUM METASILICATE IN VITRO NOT MUTAGENIC
SODIUM METASILICATE IN VIVO NOT MUTAGENIC
ETHANOLAMINE IN VITRO NOT MUTAGENIC
ETHANOLAMINE IN VIVO NOT MUTAGENIC
SODIUM HYDROXIDE IN VITRO NOT MUTAGENIC
SULFONIC ACIDS, C14-16 IN VITRO NOT MUTAGENIC
ALKANE HYDROXY AND C14-16
ALKENE, SODIUM SALTS
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
2-BUTOXYETHANOL INHALATION MULTIPLE SOME POSITIVE DATA EXIST, BUT
ANIMAL THE DATA ARE NOT SUFFICIENT
SPECIES FOR CLASSIFICATION
SULFONIC ACIDS, DERMAL RAT NOT CARCINOGENIC
C14-16 ALKANE
HYDROXY AND
C14-16 ALKENE,
SODIUM SALTS
SULFONIC ACIDS, INGESTION RAT NOT CARCINOGENIC
C14-16 ALKANE
HYDROXY AND
C14-16 ALKENE,
SODIUM SALTS
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
2-BUTOXYETHANOL DERMAL NOT CLASSIFIED FOR DEVELOPMENT
2-BUTOXYETHANOL INGESTION NOT CLASSIFIED FOR DEVELOPMENT
2-BUTOXYETHANOL INHALATION NOT CLASSIFIED FOR DEVELOPMENT
SODIUM METASILICATE INGESTION NOT CLASSIFIED FOR DEVELOPMENT
ETHANOLAMINE DERMAL NOT CLASSIFIED FOR DEVELOPMENT
ETHANOLAMINE INGESTION NOT CLASSIFIED FOR DEVELOPMENT
SULFONIC ACIDS, C14-16 INGESTION NOT CLASSIFIED FOR FEMALE
ALKANE HYDROXY AND REPRODUCTION
C14-16 ALKENE, SODIUM
SALTS
SULFONIC ACIDS, C14-16 INGESTION NOT CLASSIFIED FOR MALE
ALKANE HYDROXY AND REPRODUCTION
C14-16 ALKENE, SODIUM
SALTS
SULFONIC ACIDS, C14-16 INGESTION NOT CLASSIFIED FOR DEVELOPMENT
ALKANE HYDROXY AND
C14-16 ALKENE, SODIUM
SALTS
NAME SPECIES TEST RESULT EXPOSURE DURATION
2-BUTOXYETHANOL RAT NOAEL: DURING GESTATION
1,760 MG/KG/DAY
2-BUTOXYETHANOL RAT NOAEL: DURING
100 MG/KG/DAY ORGANOGENESIS
2-BUTOXYETHANOL MULTIPLE NOAEL: 0.48 MG/L DURING
ANIMAL ORGANOGENESIS
SPECIES
SODIUM METASILICATE MOUSE NOAEL: DURING GESTATION
200 MG/KG/DAY
ETHANOLAMINE RAT NOAEL: DURING
225 MG/KG/DAY ORGANOGENESIS
ETHANOLAMINE RAT NOAEL: DURING
616 MG/KG/DAY ORGANOGENESIS
SULFONIC ACIDS, C14-16 RAT NOAEL: 871 MG/KG 2 GENERATION
ALKANE HYDROXY AND
C14-16 ALKENE, SODIUM
SALTS
SULFONIC ACIDS, C14-16 RAT NOAEL: 891 MG/KG 2 GENERATION
ALKANE HYDROXY AND
C14-16 ALKENE, SODIUM
SALTS
SULFONIC ACIDS, C14-16 RABBIT NOAEL: 600 MG/KG DURING
ALKANE HYDROXY AND ORGANOGENESIS
C14-16 ALKENE, SODIUM
SALTS
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
2-BUTOXYETHANOL DERMAL ENDOCRINE SYSTEM NOT CLASSIFIED
2-BUTOXYETHANOL DERMAL LIVER NOT CLASSIFIED
2-BUTOXYETHANOL DERMAL KIDNEY AND/OR BLADDER NOT CLASSIFIED
2-BUTOXYETHANOL DERMAL BLOOD NOT CLASSIFIED
2-BUTOXYETHANOL INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
2-BUTOXYETHANOL INHALATION RESPIRATORY IRRITATION SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
2-BUTOXYETHANOL INHALATION BLOOD NOT CLASSIFIED
2-BUTOXYETHANOL INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
2-BUTOXYETHANOL INGESTION BLOOD NOT CLASSIFIED
2-BUTOXYETHANOL INGESTION KIDNEY AND/OR BLADDER NOT CLASSIFIED
SODIUM INHALATION RESPIRATORY IRRITATION MAY CAUSE
METASILICATE RESPIRATORY
IRRITATION
ETHANOLAMINE INHALATION RESPIRATORY IRRITATION MAY CAUSE
RESPIRATORY
IRRITATION
SODIUM HYDROXIDE INHALATION RESPIRATORY IRRITATION MAY CAUSE
RESPIRATORY
IRRITATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
2-BUTOXYETHANOL RABBIT NOAEL: 902 MG/KG 6 HOURS
2-BUTOXYETHANOL RABBIT LOAEL: 72 MG/KG NOT AVAILABLE
2-BUTOXYETHANOL RABBIT LOAEL: 451 MG/KG 6 HOURS
2-BUTOXYETHANOL MULTIPLE NOAEL: NOT AVAILABLE
ANIMAL
SPECIES
2-BUTOXYETHANOL HUMAN NOAEL: NOT AVAILABLE
2-BUTOXYETHANOL HUMAN NOAEL: NOT AVAILABLE
2-BUTOXYETHANOL MULTIPLE NOAEL: NOT AVAILABLE
ANIMAL
SPECIES
2-BUTOXYETHANOL PROFESSIONAL NOAEL: NOT AVAILABLE
JUDGEMENT
2-BUTOXYETHANOL MULTIPLE NOAEL: NOT AVAILABLE
ANIMAL
SPECIES
2-BUTOXYETHANOL HUMAN NOAEL: NOT AVAILABLE POISONING AND/OR
ABUSE
SODIUM OFFICIAL NOAEL: NOT AVAILABLE
METASILICATE CLASSIFICATION
ETHANOLAMINE HUMAN AND NOAEL: NOT AVAILABLE
ANIMAL
SODIUM HYDROXIDE HUMAN NOAEL: NOT AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
2-BUTOXYETHANOL DERMAL BLOOD NOT CLASSIFIED
2-BUTOXYETHANOL DERMAL ENDOCRINE SYSTEM NOT CLASSIFIED
2-BUTOXYETHANOL INHALATION LIVER NOT CLASSIFIED
2-BUTOXYETHANOL INHALATION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
2-BUTOXYETHANOL INHALATION BLOOD NOT CLASSIFIED
2-BUTOXYETHANOL INHALATION ENDOCRINE SYSTEM NOT CLASSIFIED
2-BUTOXYETHANOL INGESTION BLOOD NOT CLASSIFIED
2-BUTOXYETHANOL INGESTION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
SODIUM METASILICATE INGESTION KIDNEY AND/OR SOME POSITIVE DATA
BLADDER EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
SODIUM METASILICATE INGESTION ENDOCRINE SYSTEM NOT CLASSIFIED
BLOOD
SODIUM METASILICATE INGESTION HEART NOT CLASSIFIED
LIVER
ETHANOLAMINE INHALATION LIVER NOT CLASSIFIED
KIDNEY AND/OR
BLADDER
RESPIRATORY SYSTEM
ETHANOLAMINE INGESTION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
LIVER
KIDNEY AND/OR
BLADDER
RESPIRATORY SYSTEM
SULFONIC ACIDS, INGESTION LIVER NOT CLASSIFIED
C14-16 ALKANE
HYDROXY AND C14-16
ALKENE, SODIUM SALTS
SULFONIC ACIDS, INGESTION KIDNEY AND/OR NOT CLASSIFIED
C14-16 ALKANE BLADDER
HYDROXY AND C14-16
ALKENE, SODIUM SALTS
NAME SPECIES TEST RESULT EXPOSURE DURATION
2-BUTOXYETHANOL MULTIPLE NOAEL: NOT AVAILABLE NOT AVAILABLE
ANIMAL
SPECIES
2-BUTOXYETHANOL RABBIT NOAEL: 150 MG/KG/DAY 90 DAYS
2-BUTOXYETHANOL RAT NOAEL: 2.4 MG/L 14 WEEKS
2-BUTOXYETHANOL RAT NOAEL: 0.15 MG/L 14 WEEKS
2-BUTOXYETHANOL RAT LOAEL: 0.15 MG/L 6 MONTHS
2-BUTOXYETHANOL DOG LOAEL: 1.9 MG/L 8 DAYS
2-BUTOXYETHANOL RAT LOAEL: 69 MG/KG/DAY 13 WEEKS
2-BUTOXYETHANOL MULTIPLE NOAEL: NOT AVAILABLE NOT AVAILABLE
ANIMAL
SPECIES
SODIUM METASILICATE DOG LOAEL: 4 WEEKS
2,400 MG/KG/DAY
SODIUM METASILICATE RAT NOAEL: 804 MG/KG/DAY 3 MONTHS
SODIUM METASILICATE RAT NOAEL: 8 WEEKS
1,259 MG/KG/DAY
ETHANOLAMINE MULTIPLE NOAEL: 0.656 MG/L 5 WEEKS
ANIMAL
SPECIES
ETHANOLAMINE RAT NOAEL: NOT AVAILABLE
SULFONIC ACIDS, RAT NOAEL: 500 MG/KG/DAY 6 MONTHS
C14-16 ALKANE
HYDROXY AND C14-16
ALKENE, SODIUM
SALTS
SULFONIC ACIDS, RAT NOAEL: 500 MG/KG 6 MONTHS
C14-16 ALKANE
HYDROXY AND C14-16
ALKENE, SODIUM
SALTS
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
AS A DISPOSAL ALTERNATIVE, UTILIZE AN ACCEPTABLE PERMITTED WASTE DISPOSAL
FACILITY. EMPTY DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING
HAZARDOUS CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED
AS HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): D002 (CORROSIVE)
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
EPCRA 311/312 HAZARD CLASSIFICATIONS:
PHYSICAL HAZARDS: NOT APPLICABLE
HEALTH HAZARDS:
HAZARD NOT OTHERWISE CLASSIFIED (HNOC)
SERIOUS EYE DAMAGE OR EYE IRRITATION SKIN CORROSION OR IRRITATION
SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
2-BUTOXYETHANOL (GLYCOL ETHERS) 111-76-2 7 - 13
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
CALIFORNIA PROPOSITION 65:
INGREDIENT C.A.S. NO. LISTING
ARSENIC (INORGANIC ARSENIC COMPOUNDS) NONE CARCINOGEN
CADMIUM NONE MALE REPRODUCTIVE TOXIN
CADMIUM AND CADMIUM COMPOUNDS NONE CARCINOGEN
CADMIUM NONE DEVELOPMENTAL TOXIN
LEAD NONE FEMALE REPRODUCTIVE
TOXIN
LEAD NONE MALE REPRODUCTIVE TOXIN
LEAD NONE CARCINOGEN
LEAD NONE DEVELOPMENTAL TOXIN
MERCURY AND MERCURY COMPOUNDS NONE DEVELOPMENTAL TOXIN
NICKEL (METALLIC) NONE CARCINOGEN
PROPYLENE OXIDE NONE CARCINOGEN
BERYLLIUM AND BERYLLIUM COMPOUNDS NONE CARCINOGEN
ETHYLENE GLYCOL (INGESTED) 107-21-1 DEVELOPMENTAL TOXIN
CHROMIUM (HEXAVALENT COMPOUNDS) NONE FEMALE REPRODUCTIVE
TOXIN
CHROMIUM (HEXAVALENT COMPOUNDS) NONE MALE REPRODUCTIVE TOXIN
CHROMIUM (HEXAVALENT COMPOUNDS) NONE CARCINOGEN
CHROMIUM (HEXAVALENT COMPOUNDS) NONE DEVELOPMENTAL TOXIN
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
AUSTRALIA NATIONAL INDUSTRIAL CHEMICAL NOTIFICATION AND ASSESSMENT SCHEME
(NICNAS). CERTAIN RESTRICTIONS MAY APPLY. CONTACT THE SELLING DIVISION FOR
ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE NEW SUBSTANCE
NOTIFICATION REQUIREMENTS OF CEPA.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE CHINA "MEASURES
ON ENVIRONMENTAL MANAGEMENT OF NEW CHEMICAL SUBSTANCE". CERTAIN
RESTRICTIONS MAY APPLY. CONTACT THE SELLING DIVISION FOR ADDITIONAL
INFORMATION.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
THE KOREAN TOXIC CHEMICAL CONTROL LAW. CERTAIN RESTRICTIONS MAY APPLY.
CONTACT THE SELLING DIVISION FOR ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
JAPAN CHEMICAL SUBSTANCE CONTROL LAW. CERTAIN RESTRICTIONS MAY APPLY.
CONTACT THE SELLING DIVISION FOR ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 3
FLAMMABILITY 0
INSTABILITY 0
SPECIAL HAZARDS NONE
CORROSIVE: YES
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED
FOR USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
HMIS HAZARD CLASSIFICATION:
HEALTH 3
FLAMMABILITY 0
PHYSICAL HAZARD 0
PERSONAL PROTECTION X - SEE PPE SECTION.
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM (HMIS(R*) IV) HAZARD RATINGS ARE
DESIGNED TO INFORM EMPLOYEES OF CHEMICAL HAZARDS IN THE WORKPLACE. THESE
RATINGS ARE BASED ON THE INHERENT PROPERTIES OF THE MATERIAL UNDER EXPECTED
CONDITIONS OF NORMAL USE AND ARE NOT INTENDED FOR USE IN EMERGENCY
SITUATIONS. HMIS(R*) IV RATINGS ARE TO BE USED WITH A FULLY IMPLEMENTED
HMIS(R*) IV PROGRAM. HMIS(R*) IS A REGISTERED MARK OF THE AMERICAN COATINGS
ASSOCIATION (ACA).
DOCUMENT GROUP: 19-4136-8
VERSION NUMBER: 5.00
ISSUE DATE: 10/09/18
SUPERCEDES DATE: 01/22/18
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