| Common Name: | SIMPLE GREEN LIME SCALE REMOVER |
| Manufacturer: | SUNSHINE MAKERS |
| SDS Revision Date: | 2/3/2021 |
| SDS Format: | No Format Specified |
| Item Number(s): | 3UP43, 3UP44, 820RY4, 820RY5 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
SIMPLE GREEN(R*) LIME SCALE REMOVER
VERSION NO.: 50128-21A
ISSUE DATE: FEBRUARY 3, 2021
SUPERSEDES DATE: OCTOBER 7, 2014
OSHA HCS-2012 / GHS
| SECTION 1: IDENTIFICATION |  |
PRODUCT NAME: SIMPLE GREEN(R*) LIME SCALE REMOVER
ADDITIONAL NAMES:
MANUFACTURER'S PART NUMBER: *PLEASE REFER TO SECTION 16
RECOMMENDED USE:
ACID BASED CLEANER FOR THE REMOVAL OF LIME, SCALE, AND MINERAL BUILDUP
RESTRICTIONS ON USE:
DO NOT USE IN CONJUNCTION WITH OTHER CHEMICALS OR WITH ON SURFACES NOT
RESISTANT TO ACIDS.
COMPANY:
SUNSHINE MAKERS, INC.
15922 PACIFIC COAST HIGHWAY
HUNTINGTON BEACH, CA 92649
USA
TELEPHONE: 800-228-0709 - 562-795-6000 MON - FRI, 8AM - 5PM PST
FAX: 562-592-3830
EMAIL: INFO@SIMPLEGREEN.COM
EMERGENCY PHONE:
CHEM-TEL 24-HOUR EMERGENCY SERVICE: 800-255-3924
| SECTION 2: HAZARDS IDENTIFICATION | |
THIS PRODUCT IS CONSIDERED HAZARDOUS UNDER 2012 OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).:
EYE DAMAGE - CATEGORY 1
OSHA HCS 2012
LABEL ELEMENTS:
SIGNAL WORD: DANGER
HAZARD SYMBOL(S)/PICTOGRAM(S): CORROSION
HAZARD STATEMENTS: CAUSES SERIOUS EYE DAMAGE.
PRECAUTIONARY STATEMENTS: WEAR EYE PROTECTION.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON
CENTER/DOCTOR.
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN
OTHER INFORMATION: NONE KNOWN
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT CAS NUMBER PERCENT RANGE
WATER 7732-18-5 >76.998%*
UREA MONOHYDROCHLORIDE MIXTURE PROPRIETARY </=6.000%*
MIXTURE
SODIUM CITRATE 68-04-2 <5.000%*
ETHOXYLATED ALCOHOLS PROPRIETARY <5.000%*
MIXTURE
ORGANIC SALT PROPRIETARY <1.000%*
MIXTURE
FRAGRANCES PROPRIETARY <1.000%*
MIXTURE
METHYL SALICYLATE 119-36-8 <1.000%*
ACID GREEN 25 4403-90-1 <0.001%*
SODIUM; 4-CHLORO-3- 6359-90-6 <0.001%*
(3-METHYL-5-OXO-4-PHENYLDIAZENYL-
4H-PYRAZOL-1-YL)BENZENESULFONATE
*SPECIFIC PERCENTAGES OF COMPOSITION ARE BEING WITHHELD AS A
TRADE SECRET
| SECTION 4: FIRST-AID MEASURES | |
INHALATION:
NOT EXPECTED TO CAUSE RESPIRATORY IRRITATION. IF ADVERSE EFFECT OCCURS,
MOVE TO FRESH AIR.
SKIN CONTACT:
NOT EXPECTED TO CAUSE SKIN IRRITATION. IF ADVERSE EFFECT OCCURS, RINSE
SKIN WITH WATER.
EYE CONTACT:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON
CENTER/DOCTOR.
INGESTION:
MAY CAUSE UPSET STOMACH. DRINK PLENTY OF WATER TO DILUTE. SEE SECTION 11.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED: NONE KNOWN.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED,
IF NECESSARY: TREAT SYMPTOMATICALLY
| SECTION 5: FIRE-FIGHTING MEASURES | |
SUITABLE & UNSUITABLE EXTINGUISHING MEDIA:
USE DRY CHEMICAL, CO2, WATER SPRAY OR "ALCOHOL" FOAM. AVOID HIGH VOLUME
JET WATER.
SPECIFIC HAZARDS ARISING FROM CHEMICAL:
IN EVENT OF FIRE, FIRE CREATED CARBON OXIDES MAY BE FORMED.
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS; WEAR FULL
PROTECTIVE CLOTHING.
THIS PRODUCT IS NON-FLAMMABLE. SEE SECTION 9 FOR PHYSICAL PROPERTIES.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY AND EMERGENCY PERSONNEL:
SEE SECTION 8 - PERSONAL PROTECTION. AVOID EYE CONTACT. SAFETY GOGGLES
REQUIRED.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW INTO OPEN WATERWAYS AND GROUND WATER SYSTEMS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEAN UP:
DIKE OR SOAK UP WITH INERT ABSORBENT MATERIAL. SEE SECTION 13 FOR DISPOSAL
CONSIDERATIONS.
| SECTION 7: HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
ENSURE ADEQUATE VENTILATION. KEEP OUT OF REACH OF CHILDREN. KEEP AWAY FROM
HEAT, SPARKS, OPEN FLAME AND DIRECT SUNLIGHT. DO NOT PIERCE ANY PART OF
THE CONTAINER. DO NOT MIX OR CONTAMINATE WITH ANY OTHER CHEMICAL. DO NOT
EAT, DRINK OR SMOKE WHILE USING THIS PRODUCT.
CONDITIONS FOR SAFE STORAGE INCLUDING INCOMPATIBILITIES:
KEEP CONTAINER TIGHTLY CLOSED. KEEP IN COOL DRY AREA. AVOID PROLONGED
EXPOSURE TO SUNLIGHT. DO NOT STORE AT TEMPERATURES ABOVE 109 DEG. F
(42.7 DEG. C). IF SEPARATION OCCURS, MIX THE PRODUCT FOR RECONSTITUTION.
| SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EXPOSURE LIMIT VALUES:
NO COMPONENTS LISTED WITH TWA OR STEL VALUES UNDER OSHA OR ACGIH.
APPROPRIATE ENGINEERING CONTROLS:
SHOWERS, EYEWASH STATIONS, VENTILATION SYSTEMS
INDIVIDUAL PROTECTION MEASURES / PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE CONTACT: WEAR EYE PROTECTION.
RESPIRATORY:
USE IN WELL VENTILATED AREAS OR LOCAL EXHAUST VENTILATIONS WHEN CLEANING
SMALL SPACES.
SKIN CONTACT:
USE PROTECTIVE GLOVES (ANY MATERIAL) WHEN USED FOR PROLONGED PERIODS OR
DERMALLY SENSITIVE.
GENERAL HYGIENE CONSIDERATIONS:
WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR DRINKING.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: TURQUOISE LIQUID
ODOR: ADDED WINTERGREEN ODOR
ODOR THRESHOLD: NOT DETERMINED
PH: 1.0 - 1.5
FREEZING POINT: 0 DEG. C (32 DEG. F)
BOILING POINT & RANGE: 101 DEG. C (213.8 DEG. F)
FLASH POINT: >212 DEG. F
EVAPORATION RATE: NOT DETERMINED
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS: NOT APPLICABLE
VAPOR PRESSURE: NOT DETERMINED
VAPOR DENSITY: NOT DETERMINED
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT DETERMINED
AUTOIGNITION TEMPERATURE: NON-FLAMMABLE
DECOMPOSITION TEMPERATURE: 109 DEG. F
VISCOSITY: LIKE WATER
SPECIFIC GRAVITY: 1.00 - 1.03
VOCS: **WATER & FRAGRANCE EXEMPTION IN CALCULATION
SCAQMD 304-91 / EPA 24: NOT TESTED
CARB METHOD 310**:
<1.5G/L
<0.012LB/GAL
<0.15%
SCAQMD METHOD 313: NOT TESTED
VOC COMPOSITE PARTIAL PRESSURE: NOT DETERMINED
RELATIVE DENSITY: 8.34 - 8.59 LB/GAL
SOLUBILITY: 100% IN WATER
| SECTION 10: STABILITY AND REACTIVITY | |
REACTIVITY: NON-REACTIVE.
CHEMICAL STABILITY:
STABLE UNDER NORMAL CONDITIONS 70 DEG. F (21 DEG. C) AND 14.7 PSIG
(760 MMHG).
POSSIBILITY OF HAZARDOUS REACTIONS: NONE KNOWN.
CONDITIONS TO AVOID: EXCESSIVE HEAT OR COLD.
INCOMPATIBLE MATERIALS:
DO NOT MIX WITH OXIDIZERS, ACIDS, BATHROOM CLEANERS, DISINFECTING AGENTS
OR AMMONIA.
HAZARDOUS DECOMPOSITION PRODUCTS: NORMAL PRODUCTS OF COMBUSTION - CO, CO2.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
LIKELY ROUTES OF EXPOSURE:
INHALATION: OVEREXPOSURE MAY CAUSE HEADACHE.
SKIN CONTACT:
NOT EXPECTED TO CAUSE IRRITATION, REPEATED CONTACT MAY CAUSE DRY SKIN.
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INGESTION: MAY CAUSE STOMACH UPSET.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
NO SYMPTOMS EXPECTED UNDER TYPICAL USE CONDITIONS.
DELAYED AND IMMEDIATE EFFECTS AND OR CHRONIC EFFECTS FROM SHORT TERM
EXPOSURE:
NO SYMPTOMS EXPECTED UNDER TYPICAL USE CONDITIONS.
DELAYED AND IMMEDIATE EFFECTS AND OR CHRONIC EFFECTS FROM LONG TERM
EXPOSURE:
HEADACHE, DRY SKIN, OR SKIN IRRITATION MAY OCCUR.
INTERACTIVE EFFECTS: NOT KNOWN.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY:
ORAL LD50 (RAT): >5 G/KG BODY WEIGHT
DERMAL LD50 (RABBIT): >5 G/KG BODY WEIGHT
CALCULATED VIA OSHA HCS 2012 / GLOBALLY HARMONIZED SYSTEM OF
CLASSIFICATION AND LABELLING OF CHEMICALS
SKIN CORROSION/IRRITATION:
MIXTURE DOES NOT CLASSIFY UNDER THIS CATEGORY PER CALCULATION AND
PROPRIETARY TEST RESULTS.
EYE DAMAGE/IRRITATION: CLASSIFIES AS SERIOUS EYE DAMAGE UNDER GHS.
GERM CELL MUTAGENICITY: MIXTURE DOES NOT CLASSIFY UNDER THIS CATEGORY.
CARCINOGENICITY: MIXTURE DOES NOT CLASSIFY UNDER THIS CATEGORY.
REPRODUCTIVE TOXICITY: MIXTURE DOES NOT CLASSIFY UNDER THIS CATEGORY.
STOT-SINGLE EXPOSURE: MIXTURE DOES NOT CLASSIFY UNDER THIS CATEGORY.
STOT-REPEATED EXPOSURE: MIXTURE DOES NOT CLASSIFY UNDER THIS CATEGORY.
ASPIRATION HAZARD: MIXTURE DOES NOT CLASSIFY UNDER THIS CATEGORY.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICITY:
VOLUME OF INGREDIENTS USED DOES NOT TRIGGER TOXICITY CLASSIFICATIONS
UNDER THE GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING
OF CHEMICALS.
AQUATIC: NOT TESTED ON FINISHED FORMULATION.
TERRESTRIAL: NOT TESTED ON FINISHED FORMULATION.
PERSISTENCE AND DEGRADABILITY: NO DATA AVAILABLE.
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE.
MOBILITY IN SOIL: NO DATA AVAILABLE.
OTHER ADVERSE EFFECTS: NO DATA AVAILABLE.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
UNUSED OR USED LIQUID:
MAY BE CONSIDERED HAZARDOUS IN YOUR AREA DEPENDING ON USAGE AND TONNAGE
OF DISPOSAL - CHECK WITH LOCAL, REGIONAL, AND OR NATIONAL REGULATIONS
FOR APPROPRIATE METHODS OF DISPOSAL.
EMPTY CONTAINERS: MAY BE OFFERED FOR RECYCLING.
NEVER DISPOSE OF USED DEGREASING RINSATES INTO LAKES, STREAMS, AND OPEN
BODIES OF WATER OR STORM DRAINS.
| SECTION 14: TRANSPORT INFORMATION | |
U.N. NUMBER: NOT APPLICABLE
U.N. PROPER SHIPPING NAME: CLEANING COMPOUND, LIQUID NOI
TRANSPORT HAZARD CLASS(ES): NOT APPLICABLE
PACKING GROUP: NOT APPLICABLE
ENVIRONMENTAL HAZARDS: MARINE POLLUTANT - NO
TRANSPORT IN BULK (ACCORDING TO ANNEX II OF MARPOL 73/78 AND IBC CODE):
UNKNOWN.
SPECIAL PRECAUTIONS WHICH USER NEEDS TO BE AWARE OF/COMPLY WITH, IN
CONNECTION WITH TRANSPORT OR CONVEYANCE EITHER WITHIN OR OUTSIDE THEIR
PREMISES: NONE KNOWN.
U.S. (DOT) / CANADIAN TDG: NOT REGULATED FOR SHIPPING.
ICAO/ IATA: NOT CLASSIFIED AS HAZARDOUS
IMO / IDMG: NOT CLASSIFIED AS HAZARDOUS
ADR/RID: NOT CLASSIFIED AS HAZARDOUS
EPA TEST METHOD 1110A: NON-CORROSIVE TO STEEL (SAE 1020)
| SECTION 15: REGULATORY INFORMATION | |
ALL COMPONENTS ARE LISTED ON: TSCA AND DSL INVENTORY.
SARA TITLE III:
SECTIONS 311/312 HAZARD CATEGORIES - NOT APPLICABLE.
SECTIONS 313 SUPERFUNDS AMENDMENTS AND REAUTHORIZATIONS ACT OF 1986:
NOT APPLICABLE.
SECTIONS 302: NOT APPLICABLE.
CLEAN AIR ACT (CAA): NOT APPLICABLE
CLEAN WATER ACT (CWA): NOT APPLICABLE
STATE RIGHT TO KNOW LISTS: NO INGREDIENTS LISTED
CALIFORNIA PROPOSITION 65: NO INGREDIENTS LISTED
THIS PRODUCT HAS BEEN CLASSIFIED AS "HAZARDOUS" IN ACCORDANCE WITH
CONSUMER PRODUCT SAFETY COMMISSION (16 CFR CHAPTER 2),AND LABELLED
AND PACKAGED ACCORDINGLY.
US CONSUMER PRODUCT SAFETY COMMISSION REGULATIONS:
THIS PRODUCT IS LABELED IN ACCORDANCE WITH REGULATIONS ADMINISTERED BY
THE CONSUMER PRODUCT SAFETY COMMISSION (CPSC). HOWEVER, THE USE PATTERN
AND EXPOSURE IN THE WORKPLACE ARE GENERALLY NOT CONSISTENT WITH THOSE
EXPERIENCED BY CONSUMERS. THEREFORE, THE REQUIREMENTS OF THE OCCUPATIONAL
SAFETY AND HEALTH ADMINISTRATION APPLICABLE TO THIS SDS DIFFER FROM THE
LABELING REQUIREMENTS OF THE CPSC, AND THIS SDS MAY CONTAIN ADDITIONAL
HEALTH HAZARD INFORMATION NOT PERTINENT TO CONSUMER USE AND NOT FOUND ON
THE PRODUCT LABEL.
| SECTION 16: OTHER INFORMATION | |
SIZE UPC
2 FL. OZ. 043318500015
22 FL. OZ. 043318500220
32 FL. OZ. 043318500329
1 GALLON 043318501289
5 GALLON 043318500053
55 GALLON 043318501555
USA ITEMS LISTED ONLY. NOT ALL ITEMS LISTED. USA ITEMS MAY NOT BE
VALID FOR INTERNATIONAL SALE.
NFPA:
HEALTH CORROSIVE TO EYES
FLAMMABILITY NON-FLAMMABLE
STABILITY STABLE
SPECIAL NONE
NFPA:
3
0
0
ACRONYMS:
NTP: NATIONAL TOXICOLOGY PROGRAM
IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
CPSC: CONSUMER PRODUCT SAFETY COMMISSION
TSCA: TOXIC SUBSTANCES CONTROL ACT
DSL: DOMESTIC SUBSTANCES LIST
PREPARED / REVISED BY:
SUNSHINE MAKERS, INC., REGULATORY DEPARTMENT.
THIS SDS HAS BEEN REVISED IN THE FOLLOWING SECTIONS:
ALIGNED SECTION 3 WITH CALIFORNIA INGREDIENT DISCLOSURE, HAZARD
RECLASSIFICATION, AND MINOR FIXES.
DISCLAIMER:
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE
BEST OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS
PUBLICATION. THE INFORMATION GIVEN IS DESIGNED ONLY AS GUIDANCE FOR
SAFE HANDLING, USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL
AND RELEASE AND IS NOT TO BE CONSIDERED A WARRANTY OR QUALITY
SPECIFICATION. THE INFORMATION RELATES ONLY TO THE SPECIFIC MATERIAL
DESIGNATED AND MAY NOT BE VALID FOR SUCH MATERIAL USED IN COMBINATION
WITH ANY OTHER MATERIALS OR IN ANY PROCESS, UNLESS SPECIFIED IN THE
TEXT.