| Common Name: | FLEXKRETE-102 PART A, NOROX MEKP-9 |
| Manufacturer: | FLEXKRETE TECHNOLOGIES |
| SDS Revision Date: | 12/8/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 3XJC3 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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FLEXKRETE TECHNOLOGIES
SAFETY DATA SHEET
FLEXKRETE 102
| 1. IDENTIFICATION AND COMPANY INFORMATION |  |
PRODUCT NAME: FLEXKRETE-102 PART A
SDS NUMBER: 300000014503
PRODUCT TYPE: PROPRIETARY POLYMER
PRODUCT USE: INDUSTRIAL
MANUFACTURER, IMPORTER, SUPPLIER:
FLEXKRETE TECHNOLOGIES
881 N LOUISIANA DR.
CELINA, TX 75009
E-MAIL: SDS@FLEXKRETE.COM
TELEPHONE:
FOR EMERGENCY TRANSPORTATION INFORMATION:
BRANDON RICE: (360) 326-5468
FOR ADDITIONAL HEALTH, SAFETY OR REGULATORY INFORMATION, CALL:
(847) 836-3659
| 2. HAZARD IDENTIFICATION | |
EMERGENCY OVERVIEW:
FLAMMABLE LIQUID AND VAPOR. AVOID EYE CONTACT WITH VAPOR, SPRAY, OR MIST.
AVOID SKIN CONTACT. AVOID BREATHING OF VAPORS. DO NOT EAT, DRINK OR SMOKE
WHEN USING THIS PRODUCT. WASH EXPOSED AREAS THOROUGHLY WITH SOAP AND WATER.
HARMFUL IF SWALLOWED. ALSO HARMFUL BY INHALATION AND IN CONTACT WITH SKIN.
GHS CLASSIFICATION:
EYE IRRIT. 2B, FLAM. LIQ. 3, MUTA. 1B, SKIN IRRIT. 2, STOT SE 3 RTI
SYMBOL(S) OF PRODUCT:
FLAME
EXCLAMATION MARK
HEALTH HAZARD
SIGNAL WORD: DANGER
GHS HAZARD STATEMENTS:
EYE IRRITATION, CATEGORY 2B:
H320: CAUSES EYE IRRITATION.
FLAMMABLE LIQUID, CATEGORY 3:
H226: FLAMMABLE LIQUID AND VAPOUR
GERM CELL MUTAGENICITY, CATEGORY 1B:
H340:
MAY CAUSE GENETIC DEFECTS. CLASSIFIED AS MUTAGENIC CATEGORY 1 IF INGREDIENT
IS PRESENT AT OR ABOVE 0.1% APPLIES TO LIQUIDS, SOLIDS AND THE SUBSTANCE
MAY ALSO HAVE ITS OWN EXPOSURE LIMIT. ROUTES OF DEPENDANT ON INGREDIENT
FORM.
STOT, SINGLE EXPOSURE, CATEGORY 3:
H335: MAY CAUSE RESPIRATORY IRRITATION.
SKIN IRRITATION, CATEGORY 2:
H315: CAUSES SKIN IRRITATION.
GHS LABEL PRECAUTIONARY STATEMENTS:
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P210:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING.
P261: AVOID BREATHING DUST/FUME/GAS/MIST/VAPOURS/SPRAY.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P281: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P304+P341:
IF INHALED:
IF BREATHING IS DIFFICULT, REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN
A POSITION COMFORTABLE FOR BREATHING.
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P312: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P362: TAKE OFF CONTAMINATED CLOTHING.
P403+P233: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
P403+P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
P501:
DISPOSE OF CONTENTS/CONTAINER TO IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
GHS SDS PRECAUTIONARY STATEMENTS:
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
P241: USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING/.../EQUIPMENT.
P242: USE ONLY NON-SPARKING TOOLS.
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS-NO. WT.% GHS SYMBOLS GHS STATEMENTS
VINYL TOLUENE 25013-15-4 30 - 40 GHS07-GHS08 H304-315-320-335-340
THE TEXT FOR GHS HAZARD STATEMENTS SHOWN ABOVE (IF ANY) IS GIVEN IN THE
"OTHER INFORMATION" SECTION.
| 4. FIRST-AID MEASURES | |
FIRST AID - EYE CONTACT:
HOLD EYELIDS APART AND IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR
15 MINUTES. SEEK MEDICAL ADVICE. REMOVE CONTACT LENSES.
FIRST AID - INGESTION:
RINSE MOUTH WITH WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. OBTAIN MEDICAL ATTENTION. IF SWALLOWED, DO NOT INDUCE VOMITING
UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL.
FIRST AID - INHALATION:
REMOVE TO FRESH AIR. IF NOT BREATHING, ADMINISTER CPR UNTIL HELP ARRIVES OR
THE VICTIM STARTS TO BREATHE ON HIS OWN. IF BREATHING IS DIFFICULT, GIVE
OXYGEN. SEEK MEDICAL ATTENTION IMMEDIATELY.
FIRST AID - SKIN CONTACT:
IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES. REMOVE CONTAMINATED
CLOTHING. SEEK MEDICAL ATTENTION IMMEDIATELY. WASH THOROUGHLY AFTER
HANDLING.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE: DRY CHEMICAL, CO2, WATER FOG/MIST, FOAM
NOT SUITABLE: WATER JET
SPECIAL FIREFIGHTING PROCEDURES: WEAR FULL PROTECTIVE GEAR & SCBA.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
FLAMMABLE LIQUID. VAPORS CAN FORM AN IGNITABLE MIXTURE WITH AIR. VAPORS CAN
FLOW ALONG SURFACES TO A DISTANT IGNITION SOURCE AND FLASH BACK. CONTAINER
MAY RUPTURE ON HEATING.
| 6. ACCIDENTAL RELEASE MEASURES | |
ENVIRONMENTAL MEASURES:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL
OR AIR).
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
USE PERSONAL PROTECTIVE EQUIPMENT. PREVENT FURTHER LEAKAGE OR SPILLAGE IF
SAFE TO DO SO. TRY TO PREVENT THE MATERIAL FROM ENTERING DRAINS OR WATER
COURSES. CONTAIN SPILLAGE, AND THEN COLLECT WITH NON-COMBUSTIBLE ABSORBENT
MATERIAL, (E.G. SAND, EARTH, DIATOMACEOUS EARTH, VERMICULITE) AND PLACE IN
CONTAINER FOR DISPOSAL ACCORDING TO LOCAL / NATIONAL REGULATIONS
(SEE SECTION 13).
PRECAUTIONARY MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). DO NOT
TOUCH OR WALKTHROUGH SPILLED MATERIAL. AVOID DISPERSAL OF SPILLED MATERIAL
AND RUNOFF AND CONTACT WITH SOIL, WATERWAYS, DRAINS, AND SEWERS. INFORM
THE RELEVANT AUTHORITIES IF THE PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION
(SEWERS, WATERWAYS, SOIL, OR AIR).
| 7. HANDLING AND STORAGE | |
HANDLING:
FLAMMABLE LIQUID. AVOID HEAT, SPARKS AND OPEN FLAMES. AVOID BREATHING VAPOR
AND CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT LEAVE CONTAINERS OPEN.
AVOID REPEATED OR PROLONGED CONTACT WITH SKIN. EMPTY CONTAINERS RETAIN
PRODUCT RESIDUE. OBSERVE ALL SAFETY PRECAUTIONS. DO NOT REUSE CONTAINER.
STORAGE:
KEEP AWAY FROM OXIDIZERS, HEAT OR FLAMES. KEEP IN COOL, DRY, VENTILATED
STORAGE AND IN CLOSED CONTAINERS. STORE AWAY FROM ALL IGNITION SOURCES.
GROUND ALL CONTAINERS DURING TRANSFER. STORE IN A COOL, DRY PLACE. PROTECT
FROM DAMAGE. STORE AWAY FROM FLAME AND IGNITION SOURCES. KEEP ALL
CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. STORE OUT OF DIRECT SUNLIGHT AND
ON AN IMPERMEABLE FLOOR. DO NOT STORE WITH INCOMPATIBLE MATERIALS. STORE IN
UPRIGHT POSITION ONLY.
HYGIENIC PRACTICES:
GENERAL INDUSTRIAL HYGIENE PRACTICE. WASH HANDS BEFORE EATING, DRINKING,
OR SMOKING.
WORK PRACTICES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. WASH HANDS AFTER HANDLING
CHEMICALS AND BEFORE EATING, DRINKING, OR SMOKING. READ AND UNDERSTAND
ENTIRE SDS BEFORE HANDLING CHEMICAL.
SPECIAL HANDLING PROCEDURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. EATING, DRINKING, AND
SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS MATERIAL IS HANDLED,
STORED, AND PROCESSED. KEEP IN THE ORIGINAL CONTAINER OR AN APPROVED
ALTERNATIVE MADE FROM A COMPATIBLE MATERIAL, KEPT TIGHTLY CLOSED WHEN NOT
IN USE. STORE AND USE AWAY FROM HEAT, SPARKS, OPEN FLAME OR ANY OTHER
IGNITION SOURCE. USE EXPLOSION-PROOF ELECTRICAL (VENTILATING, LIGHTING AND
MATERIAL HANDLING) EQUIPMENT. USE NON-SPARKING TOOLS. TAKE PRECAUTIONARY
MEASURES AGAINST ELECTROSTATIC DISCHARGES. TO AVOID FIRE OR EXPLOSION,
DISSIPATE STATIC ELECTRICITY DURING TRANSFER BY GROUNDING AND BONDING
CONTAINERS AND EQUIPMENT BEFORE TRANSFERRING MATERIAL. FOLLOW US NFPA 30,
"FLAMMABLE AND COMBUSTIBLE LIQUIDS CODE", OR OTHER NATIONAL, STATE AND
LOCAL CODES ON SAFE HANDLING OF FLAMMABLE LIQUIDS. TRAIN WORKERS IN THE
RECOGNITION AND PREVENTION OF HAZARDS ASSOCIATED WITH THE STORAGE,
HANDLING, AND TRANSFER OF FLAMMABLE LIQUIDS IN THE PLANT. EMPTY CONTAINERS
RETAIN PRODUCT RESIDUE AND CAN BE HAZARDOUS.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
INGREDIENTS WITH OCCUPATIONAL EXPOSURE LIMITS:
CHEMICAL NAME ACGIH-TLV ACGIH-TLV OSHA-PEL OSHA
VINYL TOLUENE 50 PPM 100 PPM 100 PPM N.E.
FURTHER ADVICE:
MEL = MAXIMUM EXPOSURE LIMIT
OES = OCCUPATIONAL EXPOSURE STANDARD
SUP = SUPPLIER'S RECOMMENDATION
SK = SKIN SENSITIZER
N.E. = NOT ESTABLISHED
PERSONAL PROTECTION:
RESPIRATORY PROTECTION:
USE A PROPERLY-FITTED, AIR-PURIFYING OR AIR-FED RESPIRATOR COMPLYING WITH
AN APPROVED STANDARD IF A RISK ASSESSMENT INDICATES THIS IS NECESSARY.
RESPIRATOR SELECTION MUST BE BASED ON KNOWN OR ANTICIPATED EXPOSURE LEVELS,
THE HAZARDS OF THE PRODUCT AND THE SAFE WORKING LIMITS OF THE SELECTED
RESPIRATOR.
SKIN PROTECTION:
CHEMICAL RESISTANT GLOVES AND CHEMICAL GOGGLES SHOULD BE USED TO PREVENT
SKIN AND EYE CONTACT. IMPERVIOUS GLOVES.
EYE PROTECTION: SAFETY GLASSES WITH SIDE-SHIELDS. AVOID CONTACT WITH EYES.
OTHER PROTECTIVE EQUIPMENT:
USE GOOD HYGIENE PRACTICES. WASH FACE AND HANDS BEFORE EATING, DRINKING,
AND SMOKING. EYE WASH AND SAFETY SHOWERS SHOULD BE READILY AVAILABLE
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
COLOR: AMBER.
PHYSICAL STATE: VISCOUS LIQUID.
ODOR: AROMATIC.
ODOR THRESHOLD: NOT AVAILABLE
DENSITY, G/CM3: 1.160
PH: NOT AVAILABLE
FREEZE POINT, DEG. C: NOT AVAILABLE
VISCOSITY: NOT AVAILABLE
SOLUBILITY IN WATER: NOT AVAILABLE
PARTITION COEFFICIENT, N-OCTANOL/WATER: NOT AVAILABLE
DECOMPOSITION TEMP., DEG. C: NOT AVAILABLE
FLASH POINT, DEG. C / DEG. F: 53/127
BOILING RANGE, DEG. C: 168
EXPLOSIVE LIMITS, VOL%: NOT AVAILABLE
VAPOR PRESSURE: NOT AVAILABLE
AUTO-IGNITION TEMP., DEG. C: NOT AVAILABLE
(SEE "OTHER INFORMATION" SECTION FOR ABBREVIATION LEGEND)
| 10. STABILITY AND REACTIVITY | |
STABILITY:
THIS MATERIAL IS STABLE UNDER NORMAL STORAGE AND HANDLING CONDITIONS.
CONDITIONS TO AVOID:
HIGH TEMPERATURES, SPARKS, OPEN FLAME, AND ALL OTHER SOURCES OF IGNITION.
AVOID HEAT, SPARKS, FLAMES AND OTHER IGNITION SOURCES.
INCOMPATIBILITY: KEEP AWAY FROM STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
| 11. TOXICOLOGICAL INFORMATION | |
PRACTICAL EXPERIENCES:
EFFECT OF OVEREXPOSURE - EYE CONTACT:
MODERATE IRRITATION INCLUDING REDNESS, SWELLING, PAIN, TEARING AND HAZY
VISION. MAY CAUSE IRRITATION, DISCOMFORT, REDDENING AND TEARING.
EFFECT OF OVEREXPOSURE - INGESTION:
MAY CAUSE IRRITATION OF THE RESPIRATORY TRACT AND CNS EFFECTS SUCH AS
DIZZINESS, HEADACHES, NAUSEA AND NARCOSIS.
EFFECT OF OVEREXPOSURE - INHALATION:
INHALATION OF HIGH CONCENTRATIONS MAY CAUSE HEADACHE, NAUSEA, AND
DIZZINESS.
EFFECT OF OVEREXPOSURE - SKIN CONTACT:
PROLONGED CONTACT MAY CAUSE IRRITATION AND/OR REDNESS.
EFFECT OF OVEREXPOSURE - CHRONIC HAZARDS: NO INFORMATION
CARCINOGENICITY: NO INFORMATION
PRIMARY ROUTE(S) OF ENTRY: EYE CONTACT, INGESTION, INHALATION, SKIN CONTACT
ACUTE TOXICITY VALUES:
THE ACUTE EFFECTS OF THIS PRODUCT HAVE NOT BEEN TESTED. DATA ON INDIVIDUAL
COMPONENTS ARE TABULATED BELOW:
CAS-NO. NAME ACCORDING TO EEC ORAL LD50 DERMAL LD50 VAPOR LC50
25013-15-4 VINYL TOLUENE 2255 MG/KG 4490 MG/KG >3535 MG/L
RAT RABBIT RAT (4 HOURS)
N.L. = NO INFORMATION
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION:
ECOLOGICAL EVALUATION OF THIS MATERIAL HAS NOT BEEN PERFORMED; HOWEVER,
DO NOT ALLOW THE PRODUCT TO BE RELEASED TO THE ENVIRONMENT WITHOUT
GOVERNMENTAL APPROVAL/PERMITS. DISCHARGE INTO THE ENVIRONMENT MUST BE
AVOIDED.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHOD:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD ALWAYS
COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE DISPOSAL
LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE OF
SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL
CONTRACTOR. AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT
WITH SOIL, WATERWAYS, DRAINS, AND SEWERS.
| 14. TRANSPORT INFORMATION | |
SPECIAL TRANSPORT PRECAUTIONS: NO INFORMATION
INTERNATIONAL TRANSPORT REGULATIONS:
REGULATORY UN/NA PROPER SHIPPING CLASSES/*PG REPORTABLE
INFORMATION NUMBER NAME QUANTITY (RQ)
CFR UN1866 RESIN SOLUTION CLASS 3 PGIII
IMO/IMDG UN1866 RESIN SOLUTION CLASS 3 PGIII
IATA UN1866 RESIN SOLUTION CLASS 3 PGIII
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
CERCLA-SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA 'HAZARD CATEGORIES'
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
NO SARA 313 COMPONENTS EXIST IN THIS PRODUCT.
TOXIC SUBSTANCES CONTROL ACT:
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT TO THE
REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE UNITED STATES:
NO TSCA COMPONENTS EXIST IN THIS PRODUCT.
U.S. STATE REGULATIONS:
NEW JERSEY RIGHT-TO-KNOW: THE FOLLOWING HAZARDOUS MATERIALS ARE LISTED.
CHEMICAL NAME CAS-NO.
VINYL TOLUENE 25013-15-4
MEDIUM ALIPHATIC SOLVENT NAPHTHA (PETROLEUM) 64742-88-7
1,4-NAPHTHALENEDIONE 130-15-4
PENNSYLVANIA RIGHT-TO-KNOW:
THE FOLLOWING HAZARDOUS INGREDIENTS ARE PRESENT:
CHEMICAL NAME CAS-NO.
VINYL TOLUENE 25013-15-4
1,4-NAPHTHALENEDIONE 130-15-4
MASSACHUSETTS RIGHT-TO-KNOW: THE FOLLOWING HAZARDOUS MATERIALS ARE LISTED.
CHEMICAL NAME CAS-NO.
VINYL TOLUENE 25013-15-4
1,4-NAPHTHALENEDIONE 130-15-4
CALIFORNIA PROPOSITION 65 CARCINOGENS:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
NO PROPOSITION 65 CARCINOGENS EXIST IN THIS PRODUCT.
CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS, OR OTHER REPRODUCTIVE HAZARDS.
NO PROPOSITION 65 REPRODUCTIVE TOXINS EXIST IN THIS PRODUCT.
INTERNATIONAL REGULATIONS:
CANADIAN WHMIS:
THIS SDS HAS BEEN PREPARED IN COMPLIANCE WITH CONTROLLED PRODUCT
REGULATIONS EXCEPT FOR THE USE OF THE 16 HEADINGS.
WHMIS CLASS: B2, D2A
CHEMICAL INVENTORIES:
AUSTRALIA INVENTORY (AICS): ALL COMPONENTS ARE LISTED OR EXEMPTED
CANADA INVENTORY (DSL): ALL COMPONENTS ARE LISTED OR EXEMPTED
JAPAN INVENTORY (ENCSC): NOT DETERMINED
CHINA INVENTORY (IECSC): ALL COMPONENTS ARE LISTED OR EXEMPTED
KOREA INVENTORY (KECI): ALL COMPONENTS ARE LISTED OR EXEMPTED
NEW ZEALAND (NZIOC): ALL COMPONENTS ARE LISTED OR EXEMPTED
PHILIPPINES (PICCS): ALL COMPONENTS ARE LISTED OR EXEMPTED
UNITED STATES INVENTORY (TSCA 8B): ALL COMPONENTS ARE LISTED OR EXEMPTED
| 16. OTHER INFORMATION | |
REVISION DATE: 12/8/2015
SUPERSEDES DATE: NEW SDS
REASON FOR REVISION: NO INFORMATION
DATA SHEET PRODUCED BY: REGULATORY DEPARTMENT
HMIS RATINGS:
HEALTH 2
FLAMMABILITY 2
REACTIVITY 0
PERSONAL PROTECTION N.I.
CHRONIC RATING N.I.
TEXT FOR GHS HAZARD STATEMENTS SHOWN IN SECTION 3 DESCRIBING EACH
INGREDIENT:
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
H315: CAUSES SKIN IRRITATION.
H320: CAUSES EYE IRRITATION.
H335: MAY CAUSE RESPIRATORY IRRITATION.
H340: MAY CAUSE GENETIC DEFECTS.
ICONS FOR GHS PICTOGRAMS SHOWN IN SECTION 3 DESCRIBING EACH INGREDIENT:
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
LEGEND:
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
N.D. - NOT DETERMINED
N.I. - NO INFORMATION
THE INFORMATION PROVIDED HEREIN WAS BELIEVED BY FLEXKRETE TECHNOLOGIES TO
BE ACCURATE AT THE TIME OF PREPARATION OR PREPARED FROM SOURCES BELIEVED TO
BE RELIABLE, BUT IT IS THE RESPONSIBILITY OF THE USER TO INVESTIGATE AND
UNDERSTAND OTHER PERTINENT SOURCES OF INFORMATION, TO COMPLY WITH ALL LAWS
AND PROCEDURES APPLICABLE TO THE SAFE HANDLING AND USE OF THE PRODUCT AND
TO DETERMINE THE SUITABILITY OF THE PRODUCT FOR ITS INTENDED USE. ALL
PRODUCTS SUPPLIED BY FLEXKRETE TECHNOLOGIES ARE SUBJECT TO FLEXKRETE
TECHNOLOGIES' TERMS AND CONDITIONS OF SALE. FLEXKRETE TECHNOLOGIES MAKES
NO WARRANTY, EXPRESSED OR IMPLIED, CONCERNING THE PRODUCT OR THE
MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE OR CONCERNING THE
ACCURACY OF ANY INFORMATION PROVIDED BY FLEXKRETE TECHNOLOGIES EXCEPT THAT
THE PRODUCT SHALL CONFORM TO FLEXKRETE TECHNOLOGIES SPECIFICATIONS. NOTHING
CONTAINED HEREIN CONSTITUTES AN OFFER FOR THE SALE OF ANY PRODUCT.
PRINTED: 04/18/2017
PRODUCT: 300000014503
SAFETY DATA SHEET
FLEXKRETE PART B
MATERIAL NO.:
SPECIFICATION: 185546
ORDER NUMBER:
VERSION: 1.1/US
REVISION DATE: 12/18/2016
PRINT DATE: 04/18/2017
| 1. IDENTIFICATION | |
1.1. PRODUCT IDENTIFIER:
TRADE NAME: NOROX(R*) MEKP-9
1.2. RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RELEVANT APPLICATIONS IDENTIFIED: CURING AGENT (POLYMER TECHNOLOGY)
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
COMPANY:
UNITED INITIATORS, INC.
334 PHILLIPS 311 RD.
HELENA, AR 72342-9033
USA
TELEPHONE: 870-572-2935
TELEFAX: 870-572-1416
EMAIL ADDRESS: CS-INITIATORS.NAFTA@UNITED-IN.COM
1.4. 24 HOUR EMERGENCY TELEPHONE NUMBERS:
CHEMTREC - US & CANADA: 800-424-9300
CHEMTREC INTERNATIONAL: +1 703-527-3887 (COLLECT CALLS ACCEPTED)
PRODUCT REGULATORY INFORMATION: 800-231-2702
| 2. HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLASSIFICATION ACCORDING TO REGULATION 29 CFR 1910.1200
FLAMMABLE LIQUIDS:
CATEGORY 4: H227
ORGANIC PEROXIDES:
TYPE D: H242
SKIN CORROSION:
CATEGORY 1B: H314
SERIOUS EYE DAMAGE:
CATEGORY 1: H318
ACUTE AQUATIC TOXICITY:
CATEGORY 3: H402
CHRONIC AQUATIC TOXICITY:
CATEGORY 3: H412
2.2. LABEL ELEMENTS:
STATUTORY BASIS: CLASSIFICATION ACCORDING TO REGULATION 29 CFR 1910.1200
SYMBOL(S):
FLAME
CORROSION
SIGNAL WORD: DANGER
HAZARD STATEMENT:
H227: COMBUSTIBLE LIQUID
H242: HEATING MAY CAUSE A FIRE.
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENT PREVENTION:
P210:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING.
P220:
KEEP/STORE AWAY FROM CLOTHING/STRONG ACIDS, BASES, HEAVY METAL SALTS AND
OTHER REDUCING SUBSTANCES/COMBUSTIBLE MATERIALS.
P234: KEEP ONLY IN ORIGINAL CONTAINER.
P260: DO NOT BREATHE DUST OR MIST.
P264: WASH SKIN THOROUGHLY AFTER HANDLING.
P273: AVOID RELEASE TO THE ENVIRONMENT.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
PRECAUTIONARY STATEMENT REACTION:
P301 + P330 + P331:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
P303 + P361 + P353:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
P304 + P340:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
P305 + P351 + P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
P310: IMMEDIATELY CALL A POISON CENTER/DOCTOR.
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE.
P370 + P378:
IN CASE OF FIRE:
USE WATER SPRAY, ALCOHOL-RESISTANT FOAM, DRY CHEMICAL OR CARBON DIOXIDE TO
EXTINGUISH.
P391: COLLECT SPILLAGE.
PRECAUTIONARY STATEMENT STORAGE:
P403 + P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
P405: STORE LOCKED UP.
P411: STORE AT TEMPERATURES NOT EXCEEDING 38 DEG. C (100 DEG. F).
P420: STORE AWAY FROM OTHER MATERIALS.
PRECAUTIONARY STATEMENT DISPOSAL:
P501: DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.
2.3. OTHER HAZARDS: NONE KNOWN.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
| METHYL ETHYL KETONE PEROXIDE 32% - 35%
CAS-NO.: 1338-23-4
FLAMMABLE LIQUIDS: CATEGORY 4
ORGANIC PEROXIDES: TYPE D
ACUTE TOXICITY (ORAL): CATEGORY 4
SKIN CORROSION: CATEGORY 1B
SERIOUS EYE DAMAGE: CATEGORY 1
| DIMETHYL PHTHALATE 35% - 60%
CAS-NO.: 131-11-3
REMARKS: NOT A HAZARDOUS SUBSTANCE OR MIXTURE.
| PHLEGMATIZER 6% - 26%
CAS-NO.: PROPRIETARY
ACUTE AQUATIC TOXICITY: CATEGORY 2
CHRONIC AQUATIC TOXICITY: CATEGORY 2
| METHYL ETHYL KETONE 0% - 2%
CAS-NO.: 78-93-3
FLAMMABLE LIQUIDS: CATEGORY 2
EYE IRRITATION: CATEGORY 2A
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE (CENTRAL NERVOUS SYSTEM):
CATEGORY 3
| HYDROGEN PEROXIDE <=1%
CAS-NO.: 7722-84-1
OXIDIZING LIQUIDS: CATEGORY 1
ACUTE TOXICITY (ORAL): CATEGORY 4
SKIN CORROSION: CATEGORY 1A
SERIOUS EYE DAMAGE: CATEGORY 1
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE (RESPIRATORY SYSTEM):
CATEGORY 3
CHRONIC AQUATIC TOXICITY: CATEGORY 3
OTHER INFORMATION:
THIS MATERIAL IS CLASSIFIED AS HAZARDOUS UNDER OSHA REGULATIONS.
| 4. FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
IF INHALED, REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
IF UNCONSCIOUS, EVALUATE THE NEED FOR ARTIFICIAL RESPIRATION. GET IMMEDIATE
MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH SKIN WITH SOAP AND PLENTY OF WATER. REMOVE CONTAMINATED
CLOTHING. OBTAIN MEDICAL ATTENTION IMMEDIATELY IF SYMPTOMS OCCUR.
WASH CLOTHING BEFORE REUSE.
EYE CONTACT:
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER. OBTAIN
MEDICAL ATTENTION IF IRRITATION DEVELOPS.
INGESTION:
IF SWALLOWED, DO NOT INDUCE VOMITING:
SEEK MEDICAL ADVICE IMMEDIATELY AND SHOW THIS CONTAINER OR LABEL.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS: NONE KNOWN
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: NONE KNOWN.
| 5. FIRE-FIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE WATER SPRAY, ALCOHOL-RESISTANT FOAM, DRY CHEMICAL OR CARBON DIOXIDE.,
DRY CHEMICAL COMBINED WITH PEROXIDE MAY REIGNITE FIRE., LIGHT WATER
ADDITIVES MAY BE PARTICULARLY EFFECTIVE AT EXTINGUISHING PEROXIDE FIRES.
UNSUITABLE EXTINGUISHING MEDIA: HIGH VOLUME WATER JET.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
THE HEAT OF DECOMPOSITION OF THE PEROXIDES ADDS TO THE HEAT OF THE FIRE.
DRY CHEMICAL FIRE EXTINGUISHING AGENT MAY CATALYZE THE DECOMPOSITION.
5.3. ADVICE FOR FIREFIGHTERS:
IF DRY CHEMICAL IS USED TO EXTINGUISH A PEROXIDE FIRE, THE EXTINGUISHED
AREA MUST BE THOROUGHLY WETTED DOWN WITH WATER TO PREVENT REIGNITION.
AS IN ANY FIRE, WEAR SELF-CONTAINED POSITIVE-PRESSURE BREATHING APPARATUS
AND FULL PROTECTIVE GEAR.
CONTAINERS NEAR THE SOURCE OF FIRE SHOULD BE COOLED WITH A WATER SPRAY TO
PREVENT CONTENTS FROM REACHING DECOMPOSITION TEMPERATURE.
| 6. ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE PERSONNEL TO SAFE AREAS. WEAR A SELF-CONTAINED BREATHING APPARATUS
AND APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. (SEE SECTION 8 - EXPOSURE
CONTROLS/PERSONAL PROTECTION.) REMOVE ALL SOURCES OF IGNITION. VENTILATE
THE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
OBEY RELEVANT LOCAL, STATE, PROVINCIAL AND FEDERAL LAWS AND REGULATIONS.
DO NOT CONTAMINATE ANY LAKES, STREAMS, PONDS, GROUNDWATER OR SOIL.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
DIKE SPILL TO PREVENT RUNOFF FROM ENTERING DRAINS, SEWERS, STREAMS, ETC.
WET SPILLED MATERIAL WITH WATER AND ABSORB WITH AN INERT ABSORBENT MATERIAL
SUCH AS PERLITE, VERMICULITE, OR SAND. SWEEP UP USING NON-SPARKING TOOLS
AND PLACE IN A CLEAN POLYETHYLENE DRUM OR A POLYETHYLENE PAIL. DO NOT PLACE
INTO A STEEL CONTAINER, LINED OR UNLINED, AS DECOMPOSITION MAY OCCUR. TREAT
ANY CONTAMINATED CARDBOARD PACKAGING AS HAZARDOUS WASTE. WET CONTAINER WITH
ADDITIONAL WATER PRIOR TO SEALING. USE ABSORBENT/ABSORBENT MATERIAL TO
SOLIDIFY LIQUIDS. CLEAN UP PROMPTLY BY SWEEPING OR VACUUM. WEAR PROTECTIVE
EQUIPMENT, INCLUDING EYE PROTECTION, TO AVOID EXPOSURE (SEE SECTION 8 FOR
SPECIFIC HANDLING PRECAUTIONS).
| 7. HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
ROTATE STOCK USING THE OLDEST MATERIAL FIRST. AVOID CONTACT WITH SKIN, EYES
AND CLOTHING. USE PPE AS SPECIFIED IN SECTION 8. KEEP CONTAINERS CLOSED TO
PREVENT CONTAMINATION. KEEP AWAY FROM SOURCES OF HEAT, SPARKS, OR FLAME.
DO NOT ADD TO HOT SOLVENTS OR MONOMERS AS A VIOLENT DECOMPOSITION AND/OR
REACTION MAY RESULT. WHEN USING SPRAY EQUIPMENT, NEVER SPRAY RAW PEROXIDE
ONTO CURING OR INTO RAW RESIN OR FLUES. KEEP PEROXIDE IN ITS ORIGINAL
CONTAINER. DO NOT USE NEAR FOOD OR DRINK. WASH THOROUGHLY AFTER HANDLING.
PROTECT FROM CONTAMINATION. KEEP TIGHTLY SEALED IN ORIGINAL PACKING. RISK
OF DECOMPOSITION. WASH THOROUGHLY AFTER HANDLING.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
THE STABILITY OF PEROXIDE FORMULATIONS US DIRECTLY RELATED TO THE SHIPPING
AND STORAGE TEMPERATURE HISTORY. COOL STORAGE AT 80 DEG. F (27 DEG. C) OR
BELOW IS RECOMMENDED FOR LONGER SHELF LIFE AND STABILITY. PROLONGED STORAGE
AT ELEVATED TEMPERATURES OF 100 DEG. F (38 DEG. C) AND HIGHER WILL CAUSE
PRODUCT DEGRADATION, GASSING AND POTENTIAL CONTAINER RUPTURE WHICH CAN
RESULT IN A FIRE AND/OR EXPLOSION. STORE OUT OF DIRECT SUNLIGHT IN A WELL
VENTILATED AREA AWAY FROM COMBUSTIBLE AND INCOMPATIBLE MATERIAL. DO NOT
STORE WITH FOOD OR DRINK.
REFER TO NFPA 400 HAZARDOUS MATERIALS CODE FROM THE NATIONAL FIRE
PROTECTION ASSOCIATION FOR ADDITIONAL STORAGE INFORMATION.
FURTHER INFORMATION:
STORE APART FROM OTHER DANGEROUS AND INCOMPATIBLE SUBSTANCES.
KEEP AWAY FROM DIRECT SUNLIGHT.
KEEP CONTAINERS TIGHTLY CLOSED IN A COOL, WELL-VENTILATED PLACE.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
| METHYL ETHYL KETONE PEROXIDE:
CAS-NO.: 1338-23-4
CONTROL PARAMETERS: 0.2 PPM
CEILING LIMIT VALUE: (ACGIH)
CONTROL PARAMETERS:
0.2 PPM
1.5 MG/M3
CEILING LIMIT VALUE: (US CA OEL)
| DIMETHYL PHTHALATE:
CAS-NO.: 131-11-3
CONTROL PARAMETERS: 5 MG/M3
TIME WEIGHTED AVERAGE (TWA): (ACGIH)
CONTROL PARAMETERS: 5 MG/M3
PERMISSIBLE EXPOSURE LIMIT: (OSHA Z1)
CONTROL PARAMETERS: 5 MG/M3
TIME WEIGHTED AVERAGE (TWA) PERMISSIBLE EXPOSURE LIMIT (PEL): (US CA OEL)
| METHYL ETHYL KETONE:
CAS-NO.: 78-93-3
CONTROL PARAMETERS: 200 PPM
TIME WEIGHTED AVERAGE (TWA): (ACGIH)
CONTROL PARAMETERS: 300 PPM
SHORT TERM EXPOSURE LIMIT (STEL): (ACGIH)
CONTROL PARAMETERS:
200 PPM
590 MG/M3
PERMISSIBLE EXPOSURE LIMIT: (OSHA Z1)
CONTROL PARAMETERS:
200 PPM
590 MG/M3
TIME WEIGHTED AVERAGE (TWA) PERMISSIBLE EXPOSURE LIMIT (PEL): (US CA OEL)
CONTROL PARAMETERS:
300 PPM
885 MG/M3
SHORT TERM EXPOSURE LIMIT (STEL): (US CA OEL)
| HYDROGEN PEROXIDE:
CAS-NO.: 7722-84-1
CONTROL PARAMETERS: 1 PPM
TIME WEIGHTED AVERAGE (TWA): (ACGIH)
CONTROL PARAMETERS:
1 PPM
1.4 MG/M3
PERMISSIBLE EXPOSURE LIMIT: (OSHA Z1)
CONTROL PARAMETERS:
1 PPM
1.4 MG/M3
TIME WEIGHTED AVERAGE (TWA) PERMISSIBLE EXPOSURE LIMIT (PEL): (US CA OEL)
8.2. EXPOSURE CONTROLS:
ENGINEERING MEASURES: LOCAL EXHAUST AND MECHANICAL VENTILATION RECOMMENDED.
8.3. PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 1910.134 AND ANSI Z88.2
OR APPLICABLE FEDERAL/PROVINCIAL REQUIREMENTS MUST BE FOLLOWED WHENEVER
WORKPLACE CONDITIONS WARRANT RESPIRATOR USE. NIOSH'S "RESPIRATOR DECISION
LOGIC" MAY BE USEFUL IN DETERMINING THE SUITABILITY OF VARIOUS TYPES OF
RESPIRATORS.
HAND PROTECTION:
WEAR PROTECTIVE GLOVES MADE OF THE FOLLOWING MATERIALS:
SOLVENT-RESISTANT GLOVES (BUTYL-RUBBER)
NITRILE RUBBER
NEOPRENE GLOVES
SKIN SHOULD BE WASHED AFTER CONTACT.
EYE PROTECTION: USE CHEMICAL SPLASH GOGGLES OR FACE SHIELD.
SKIN AND BODY PROTECTION:
A SAFETY SHOWER AND EYE WASH FOUNTAIN SHOULD BE READILY AVAILABLE.
TO IDENTIFY ADDITIONAL PERSONAL PROTECTIVE EQUIPMENT (PPE) REQUIREMENTS,
IT IS RECOMMENDED THAT A HAZARD ASSESSMENT IN ACCORDANCE WITH THE OSHA PPE
STANDARD (29 CFR 1910.132) BE CONDUCTED BEFORE USING THIS PRODUCT.
HYGIENE MEASURES:
DO NOT EAT, DRINK OR SMOKE DURING USE.
WASH HANDS BEFORE BREAKS AND IMMEDIATELY AFTER HANDLING THE PRODUCT.
PROTECTIVE MEASURES:
PERSONAL PROTECTIVE EQUIPMENT COMPRISING:
SUITABLE PROTECTIVE GLOVES, SAFETY GOGGLES AND PROTECTIVE CLOTHING
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
COLOUR: WATER-WHITE.
FORM: LIQUID
ODOUR: SLIGHT
ODOUR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT/RANGE: NO DATA AVAILABLE
BOILING POINT/RANGE: NOT DETERMINED
FLASH POINT: >76 DEG. C (SETA CLOSED CUP)
EVAPORATION RATE: NOT DETERMINED
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
LOWER EXPLOSION LIMIT: NO DATA AVAILABLE
UPPER EXPLOSION LIMIT: NO DATA AVAILABLE
VAPOUR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOUR DENSITY: >1
RELATIVE DENSITY: 1.1
WATER SOLUBILITY: SOLUBLE
SOLUBILITY/QUALITATIVE: NO DATA AVAILABLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
THERMAL DECOMPOSITION: >60 DEG. C
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NOT DETERMINED
9.2. OTHER INFORMATION:
PEROXIDES:
THE SUBSTANCE OR MIXTURE IS AN ORGANIC PEROXIDE CLASSIFIED AS TYPE D.
SADT:
SADT: >60 DEG. C
| 10. STABILITY AND REACTIVITY | |
10.1. REACTIVITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
10.2. CHEMICAL STABILITY:
CONTACT WITH INCOMPATIBLE SUBSTANCES CAN CAUSE DISINTEGRATION AT OR
BELOW SADT.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
VAPORS MAY FORM EXPLOSIVE MIXTURES WITH AIR.
10.4. CONDITIONS TO AVOID:
KEEP AWAY FROM HEAT AND SOURCES OF IGNITION.
EXPOSURE TO SUNLIGHT.
PROLONGED STORAGE ABOVE 100 DEG. F (38 DEG.). STORAGE ABOVE SADT. STORAGE
NEAR FLAMMABLE OR COMBUSTIBLE MATERIAL.
10.5. INCOMPATIBLE MATERIALS:
KEEP AWAY FROM STRONG ACIDS, BASES, HEAVY METALS, SALTS, REDUCING AGENTS
AND ACCELERATORS.
CONTAMINANTS (E.G. RUST, DUST, ASH). COMBUSTIBLE MATERIALS., RISK OF
DECOMPOSITION.
DIMETHYLANILINE, COBALT NAPTHENATE AND OTHER PROMOTERS, ACCELERATORS,
REDUCING AGENTS, OR ANY HOT MATERIAL.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON MONOXIDE, CARBON DIOXIDE AND UNBURNED HYDROCARBONS (SMOKE).,
IRRITANT, CAUSTIC, FLAMMABLE, NOXIOUS/TOXIC GASES AND VAPORS CAN DEVELOP IN
THE CASE OF FIRE AND DECOMPOSITION., ACRID SMOKE AND IRRITATING FUMES.
| 11. TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
NO TOXICOLOGICAL STUDIES ARE AVAILABLE ON THE MIXTURE.
CARCINOGENICITY ASSESSMENT:
NTP:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
IARC:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS PROBABLE, POSSIBLE OR CONFIRMED HUMAN CARCINOGEN BY
IARC.
OSHA:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY OSHA.
TOXICOLOGICAL INFORMATION ON COMPONENTS:
METHYL ETHYL KETONE PEROXIDE:
ACUTE ORAL TOXICITY:
LD50 ORAL RAT(MALE): 1017 MG/KG
SKIN IRRITATION:
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
CAUSES BURNS.
EYE IRRITATION:
CAUSES SERIOUS EYE DAMAGE.
RISK OF SERIOUS DAMAGE TO EYES.
DIMETHYL PHTHALATE:
ACUTE ORAL TOXICITY:
LD50 ORAL RAT: 8200 MG/KG
ACUTE INHALATION TOXICITY:
LC50: 10.4 MG/L/6H
ASSESSMENT:
H332: HARMFUL IF INHALED.
ACUTE DERMAL TOXICITY:
LD50 DERMAL RAT: >12000 MG/KG
SKIN IRRITATION: NO SKIN IRRITATION
EYE IRRITATION: NO EYE IRRITATION
SENSITIZATION: NOT SENSITIZING.
PHLEGMATIZER:
ACUTE ORAL TOXICITY:
LD50 ORAL RAT(FEMALE): >2000 MG/KG
ACUTE INHALATION TOXICITY:
LCLO RAT: >0.12 MG/L / 6 H
ACUTE DERMAL TOXICITY:
LD50 DERMAL RAT(MALE/FEMALE): >2000 MG/KG
SKIN IRRITATION: NO SKIN IRRITATION
EYE IRRITATION: NO EYE IRRITATION
HYDROGEN PEROXIDE:
ACUTE ORAL TOXICITY:
LD50 ORAL RAT(MALE): 1026 MG/KG
TEST SUBSTANCE:
HYDROGEN PEROXIDE: >=50%
LD50 ORAL RAT(FEMALE): 693.7 MG/KG
TEST SUBSTANCE:
HYDROGEN PEROXIDE: >=50%
ACUTE INHALATION TOXICITY:
ASSESSMENT: HARMFUL IF INHALED.
ACUTE DERMAL TOXICITY:
LD50 DERMAL RAT(MALE AND FEMALE): >2000 MG/KG
SKIN IRRITATION: CORROSIVE
EYE IRRITATION: CORROSIVE
SENSITIZATION: NOT SENSITIZING.
ASSESSMENT OF STOT SINGLE EXPOSURE:
ASSESSMENT: MAY CAUSE RESPIRATORY IRRITATION.
METHYL ETHYL KETONE:
ACUTE ORAL TOXICITY:
LD50 ORAL RAT: 2737 MG/KG
ACUTE INHALATION TOXICITY:
LC50 RAT: 23500 MG/L / 8 H
ACUTE DERMAL TOXICITY:
LD50 RABBIT: 6480 MG/KG
EYE IRRITATION:
IRRITATING TO EYES.
IRRITATING
ASSESSMENT OF STOT SINGLE EXPOSURE:
TARGET ORGANS: CENTRAL NERVOUS SYSTEM
ASSESSMENT: MAY CAUSE DROWSINESS OR DIZZINESS.
MUTAGENICITY ASSESSMENT: THIS PRODUCT MAY CAUSE MUTAGENIC EFFECTS.
| 12. ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
TOXICITY TO FISH: THERE IS NO DATA AVAILABLE FOR THIS PRODUCT.
TOXICITY IN AQUATIC INVERTEBRATES:
NO DATA IS AVAILABLE ON THE PRODUCT ITSELF.
TOXICITY TO ALGAE: NO DATA IS AVAILABLE ON THE PRODUCT ITSELF.
12.2. PERSISTENCE AND DEGRADABILITY:
BIODEGRADABILITY: NO DATA AVAILABLE
12.3. BIOACCUMULATIVE POTENTIAL:
BIOACCUMULATION: NO DATA AVAILABLE
12.4. MOBILITY IN SOIL:
MOBILITY: NO DATA AVAILABLE
12.5. OTHER ADVERSE EFFECTS:
FURTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| 13. DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
PRODUCT:
WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATIONS. INCINERATION IS THE PREFERRED METHOD OF DISPOSAL. CONTACT
UNITED INITIATORS FOR ADDITIONAL INFORMATION. EMPTY CONTAINERS MUST BE
HANDLED WITH CARE DUE TO PRODUCT RESIDUE. DO NOT HEAT OR CUT THE EMPTY
CONTAINER WITH ELECTRIC OR GAS TORCH.
UNCLEANED PACKAGING:
PACKAGING MATERIAL SHOULD BE RECYCLED OR DISPOSED OF IN ACCORDANCE WITH
FEDERAL, STATE AND LOCAL REGULATIONS.
| 14. TRANSPORT INFORMATION | |
D.O.T. ROAD/RAIL:
14.1. UN NUMBER: UN 3105
14.2. UN PROPER SHIPPING NAME:
ORGANIC PEROXIDE TYPE D, LIQUID(METHYL ETHYL KETONE PEROXIDE <=45%)
14.3. TRANSPORT HAZARD CLASS(ES): 5.2
14.4. PACKING GROUP: II
14.5. ENVIRONMENTAL HAZARDS (MARINE POLLUTANT):
14.6. SPECIAL PRECAUTIONS FOR USER: NO
AIR TRANSPORT ICAO-TI/IATA-DGR:
14.1. UN NUMBER: UN 3105
14.2. UN PROPER SHIPPING NAME:
ORGANIC PEROXIDE TYPE D, LIQUID (METHYL ETHYL KETONE PEROXIDE <=45%)
14.3. TRANSPORT HAZARD CLASS(ES): 5.2
14.4. PACKING GROUP:
14.5. ENVIRONMENTAL HAZARDS:
14.6. SPECIAL PRECAUTIONS FOR USER: YES
IATA-C: ERG-CODE 5L
MUST BE PROTECTED FROM DIRECT SUNLIGHT AND STORED AWAY FROM ALL SOURCES
OF HEAT IN A WELL-VENTILATED AREA.
IATA-P: ERG-CODE 5L
MUST BE PROTECTED FROM DIRECT SUNLIGHT AND STORED AWAY FROM ALL SOURCES
OF HEAT IN A WELL-VENTILATED AREA.
SEA TRANSPORT IMDG-CODE/GGVSEE (GERMANY):
14.1. UN NUMBER: UN 3105
14.2. UN PROPER SHIPPING NAME:
ORGANIC PEROXIDE TYPE D, LIQUID(METHYL ETHYL KETONE PEROXIDE <=45%)
14.3. TRANSPORT HAZARD CLASS(ES): 5.2
14.4. PACKING GROUP:
14.5. ENVIRONMENTAL HAZARDS (MARINE POLLUTANT):
14.6. SPECIAL PRECAUTIONS FOR USER: YES
EMS: F-J, S-R
"SEPARATED FROM" ACIDS AND ALKALIS.
PROTECTED FROM SOURCES OF HEAT.
14.7. TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC
CODE: FOR TRANSPORT APPROVAL SEE REGULATORY INFORMATION.
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
OSHA:
IF LISTED BELOW, CHEMICAL SPECIFIC STANDARDS APPLY TO THE PRODUCT OR
COMPONENTS:
| NONE LISTED
CLEAN AIR ACT SECTION (112):
IF LISTED BELOW, COMPONENTS PRESENT AT OR ABOVE THE DE MINIMUS LEVEL ARE
HAZARDOUS AIR POLLUTANTS:
| DIMETHYL PHTHALATE:
CAS-NO.: 131-11-3
CERCLA REPORTABLE QUANTITIES:
IF LISTED BELOW, A REPORTABLE QUANTITY (RQ) APPLIES TO THE PRODUCT BASED
ON THE PERCENT OF THE NAMED COMPONENT:
| METHYL ETHYL KETONE PEROXIDE:
CAS-NO.: 1338-23-4
REPORTABLE QUANTITY: 29 LBS
SARA TITLE III SECTION 311/312 HAZARD CATEGORIES:
THE PRODUCT MEETS THE CRITERIA ONLY FOR THE LISTED HAZARD CLASSES:
| ACUTE HEALTH HAZARD
| FIRE HAZARD
SARA TITLE III SECTION 313 REPORTABLE SUBSTANCES:
IF LISTED BELOW, COMPONENTS ARE SUBJECT TO THE REPORTING REQUIREMENTS OF
SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT OF 1986 AND 40 CFR PART 372:
| NONE LISTED
TOXIC SUBSTANCES CONTROL ACT (TSCA):
IF LISTED BELOW, NON-PROPRIETARY SUBSTANCES ARE SUBJECT TO EXPORT
NOTIFICATION UNDER SECTION 12 (B) OF TSCA:
| NONE LISTED
STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
A WARNING UNDER THE CALIFORNIA DRINKING WATER ACT IS REQUIRED ONLY IF
LISTED BELOW:
| NONE LISTED
INTERNATIONAL CHEMICAL INVENTORY STATUS:
UNLESS OTHERWISE NOTED, THIS PRODUCT IS IN COMPLIANCE WITH THE INVENTORY
LISTING OF THE COUNTRIES SHOWN BELOW. FOR INFORMATION ON LISTING FOR
COUNTRIES NOT SHOWN, CONTACT THE PRODUCT REGULATORY SERVICES DEPARTMENT.
| EUROPE (EINECS/ELINCS): LISTED/REGISTERED
| USA (TSCA): LISTED/REGISTERED
| CANADA (DSL): LISTED/REGISTERED
| AUSTRALIA (AICS): LISTED/REGISTERED
| JAPAN (MITI): LISTED/REGISTERED
| KOREA (TCCL): LISTED/REGISTERED
| PHILIPPINES (PICCS): NOT LISTED/REGISTERED
| CHINA: LISTED/REGISTERED
| NEW ZEALAND: NOT LISTED/REGISTERED
AN EMPLOYER USING HMIS/NFPA LABELING MUST THROUGH TRAINING ENSURE THAT
ITS EMPLOYEES ARE FULLY AWARE OF THE HAZARDS OF THE CHEMICALS USED.
HMIS RATINGS:
HEALTH 3
FLAMMABILITY 2
PHYSICAL HAZARD 2
NFPA RATINGS:
HEALTH 3
FLAMMABILITY 2
REACTIVITY 2
| 16. OTHER INFORMATION | |
FURTHER INFORMATION:
REVISION DATE: 12/18/2016
CHANGES SINCE THE LAST VERSION ARE HIGHLIGHTED IN THE MARGIN. THIS VERSION
REPLACES ALL PREVIOUS VERSIONS.
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT.
LEGEND:
ACC: AMERICAN CHEMISTRY COUNCIL
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
ACS: ADVISORY COMMITTEE ON SUSTAINABILITY
ADI: ACCEPTABLE DAILY INTAKE
ASTM: AMERICAN SOCIETY FOR TESTING AND MATERIALS
ATP: ADAPTATION TO TECHNICAL PROGRESS
BCF: BIOCONCENTRATION FACTOR
BOD: BIOCHEMICAL OXYGEN DEMAND
C.C.: CLOSED CUP
CAO: CARGO AIRCRAFT ONLY
CARE: CARCINOGEN
CAS: CHEMICAL ABSTRACT SERVICES
CDN: CANADA
CEPA: CANADIAN ENVIRONMENTAL PROTECTION ACT
CERCLA:
COMPREHENSIVE ENVIRONMENTAL RESPONSE - COMPENSATION AND LIABILITY ACT
CFR: CODE OF FEDERAL REGULATIONS
CMR: CARCINOGENIC-MUTAGENIC-TOXIC FOR REPRODUCTION
COD: CHEMICAL OXYGEN DEMAND
DIN: GERMAN INSTITUTE FOR STANDARDIZATION
DMEL: DERIVED MINIMUM EFFECT LEVEL
DNEL: DERIVED NO EFFECT LEVEL
DOT: DEPARTMENT OF TRANSPORTATION
EC50: HALF MAXIMAL EFFECTIVE CONCENTRATION
EPA: ENVIRONMENTAL PROTECTION AGENCY
ERC50: REDUCTION OF GROWTH RATE
ERG: EMERGENCY RESPONSE GUIDE BOOK
FDA: FOOD AND DRUG ADMINISTRATION
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
(GHS)
GLP: GOOD LABORATORY PRACTICE
GMO: GENETIC MODIFIED ORGANISM
HCS: HAZARD COMMUNICATION STANDARD
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
ICAO-TI: INTERNATIONAL CIVIL AVIATION ORGANIZATION- TECHNICAL INSTRUCTIONS
ICCA: INTERNATIONAL COUNCIL OF CHEMICAL ASSOCIATION
ID: IDENTIFICATION NUMBER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
IUPAC: INTERNATIONAL UNION OF PURE AND APPLIED CHEMISTRY
ISO: INTERNATIONAL ORGANIZATION FOR STANDARDIZATION
LC50: 50% LETHAL CONCENTRATION
LD50: 50% LETHAL DOSE
L(E)C50: LC50 OR EC50
LOAEL: LOWEST OBSERVED ADVERSE EFFECT LEVEL
LOEL: LOWEST OBSERVED EFFECT LEVEL
MARPOL: INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION
NOAEL: NO OBSERVED ADVERSE EFFECT LEVEL
NOEC: NO OBSERVED EFFECT CONCENTRATION
NOEL: NO OBSERVED EFFECT LEVEL
O. C.: OPEN CUP
OECD: ORGANISATION FOR ECONOMIC COOPERATION AND DEVELOPMENT
OEL: OCCUPATIONAL EXPOSURE LIMIT
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
PBT: PERSISTENT, BIOACCUMULATIVE, TOXIC
PEC: PREDICTED EFFECT CONCENTRATION
PNEC: PREDICTED NO EFFECT CONCENTRATION
RQ: REPORTABLE QUANTITY
SDS: SAFETY DATA SHEET
STOT: SPECIFIC TARGET ORGAN TOXICITY
UN: UNITED NATIONS
VPVB: VERY PERSISTENT, VERY BIOACCUMULATIVE
VOC: VOLATILE ORGANIC COMPOUNDS
WHMIS: WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM
WHO: WORLD HEALTH ORGANIZATION
US-GHS(P27/001) / 13.04.2015 09:10