SDS Table of Contents Click the desired link below to jump directly to that section in the SDS. DRAGER PRODUCT SAFETY INFORMATION SHEET PRODUCT: DRAGER-TUBES(TM) (WHICH ARE NOT CLASSIFIED AS DANGEROUS GOODS!) REVISION DATE: 30.10.2020 DATE OF ISSUE: 30.10.20 VERSION: 10/2020 PRODUCT SAFETY INFORMATION SHEET: DOCUMENT: 9030165 VERSION: 10/2020 FORMAT: DRAGER-TUBES(TM) (WHICH ARE NOT CLASSIFIED AS DANGEROUS GOODS!)_PSIS_EN.DOC DATE OF REVISION: 30.10.2020 SUPERSEDES: VERSION 06/2020 STATUS: RELEASED
AND OF THE COMPANY/UNDERTAKING 1.1 IDENTIFICATION OF THE SUBSTANCE OR PREPARATION: TRADE NAME: DRAGER-TUBES(TM) (WHICH ARE NOT CLASSIFIED AS DANGEROUS GOODS!) PART NOS.: VARIOUS (SEE SECTION 1.5) 1.2 USE OF THE SUBSTANCE/PREPARATION: DETECTION OF GASES, MEASURING OF GAS CONCENTRATIONS. 1.3 COMPANY/UNDERTAKING NAME: DRAGER SAFETY AG & CO. KGAA REVALSTR. 1 D-23560 LUBECK TELEPHONE NUMBER: +49 451/882-0 FAX NUMBER: +49 451/882-2080 CONTACT FOR INFORMATION: DRAGER GLOBAL EHS MANAGEMENT TELEPHONE NUMBER: +49 451/882-6979 FAX NUMBER: +49 451/882-76979 1.4 EMERGENCY TELEPHONE: +49 451/882-2395 1.5 RELEVANT PRODUCTS: SACH-NR. TRADE NAME 8103551 1,3-DICHLOROPROPENE 0.1/A 6726665 ACETALDEHYDE 100/A 8101071 ACETIC ACID 10/A-D 6722101 ACETIC ACID 5/A CH22901 ACETONE 100/B 8103381 ACETONE 40/A 8101121 ACID TEST 6728591 ACRYLONITRILE 0.5/A 8103701 ACRYLONITRILE 0,2/A CH26901 ACRYLONITRILE 5/B 8101141 ACTIVE TUBE FOR FORMALDEHYDE 0.2A CH29701 ALCOHOL 100/A 8101631 ALCOHOL 25/A 8101061 AMINE TEST 8101711 AMMONIA 0.25/A CH31901 AMMONIA 0.5 %/A 6728231 AMMONIA 10/A-L 6733231 AMMONIA 2/A 8101301 AMMONIA 20/A-D 8103 301 AMMONIA 3/A CH20501 AMMONIA 5/A 8101941 AMMONIA 5/B 6733171 ANILINE 0.5/A CH20401 ANILINE 5/A CH25001 ARSINE 0.05/A 6728561 BENZENE 0.5/A 6718801 BENZENE 5/A 8101161 BUTADIENE 10/A-D 8103861 N-BUTANOL 10/A CH30801 CARBON DIOXIDE 0.01 % CH23501 CARBON DIOXIDE 0.1 %/A CH31401 CARBON DIOXIDE 0.5 %/A CH25101 CARBON DIOXIDE 1 %/A 8101051 CARBON DIOXIDE 1 %/A-D 8101811 CARBON DIOXIDE 100/A 6728521 CARBON DIOXIDE 100/A-P 6728611 CARBON DIOXIDE 1000/A-L CH20301 CARBON DIOXIDE 5 %/A 8101381 CARBON DIOXIDE 500/A-D 8101891 CARBON DISULPHIDE 3/A CH23201 CARBON DISULPHIDE 30/A 8101951 CARBON MONOXIDE 10/C 8103321 CARBON MONOXIDE 10/D 6733191 CARBON MONOXIDE 50/A-D CH24101 CARBON PRE-TUBE 8103501 CARBON TETRACHLORIDE 0.1/A 8101791 CARBON TETRACHLORIDE 0.2/B 8101021 CARBON TETRACHLORIDE 1/A CH27401 CARBON TETRACHLORIDE 5/C 8103140 CDS SET I 8103150 CDS SET II 8103160 CDS SET III 8103200 CDS SET V 8103230 CDS TRAINING-KIT I 8103240 CDS TRAINING-KIT V CH24301 CHLORINE 0.2/A 6728411 CHLORINE 0.3/B CH20701 CHLORINE 50/A 8103491 CHLORINE DIOXIDE 0.025/A 6728761 CHLOROBENZENE 5/A 6718601 CHLOROFORMATES 0.2/B 6718901 CHLOROPRENE 5/A 6728681 CHROMIC ACID 0.1/A 6728791 CYANIDE 2/A CH19801 CYANOGEN CHLORIDE 0.25/A 6725201 CYCLOHEXANE 100/A 6728931 CYCLOHEXYLAMINE 2/A 8103475 DIESEL FUEL 6730501 DIETHYL ETHER 100/A 6718501 DIMETHYL FORMAMIDE 10/B 6718701 DIMETHYL SULPHATE 0.005/C 6728451 DIMETHYL SULPHIDE 1/A 6728111 EPICHLOROHYDRIN 5/C 8103761 ETHANOL 100/A 8101151 ETHANOL 1000/A-D CH20201 ETHYL ACETATE 200/A 6728381 ETHYL BENZENE 30/A 6726801 ETHYL GLYCOL ACETATE 50/A 8101331 ETHYLENE 0.1/A 8101351 ETHYLENE GLYCOL 10 6728961 ETHYLENE OXIDE 1/A 6728241 ETHYLENE OXIDE 25/A 8101491 FLUORINE 0.1/A 6733081 FORMALDEHYDE 0.2/A 8101751 FORMALDEHYDE 2/A 6722701 FORMIC ACID 1/A 8103410 FUMIGATION-TEST-SET 6728391 HEXANE 100/A 8103351 HYDRAZINE 0.01/A 6733121 HYDRAZINE 0.2/A CH31801 HYDRAZINE 0.25/A 6728571 HYDRO CARBON 100/A-L 8101681 HYDROCHLORIC ACID / NITRIC ACID 1/A 8103481 HYDROCHLORIC ACID 0,2/A CH29501 HYDROCHLORIC ACID 1/A 6733111 HYDROCHLORIC ACID 10/A-D 6728181 HYDROCHLORIC ACID 50/A 8103601 HYDROCYANIC ACID 0,5/A CH25701 HYDROCYANIC ACID 2/A 6733221 HYDROCYANIC ACID 20/A-D 8101511 HYDROGEN 0.2 %/A CH30901 HYDROGEN 0.5 %/A 8103251 HYDROGEN FLUORIDE 0.5/A CH30301 HYDROGEN FLUORIDE 1.5/B 8101041 HYDROGEN PEROXIDE 0,1/A CH28201 HYDROGEN SULPHIDE + SULPHUR DIOXIDE 0.2 %/A CH28101 HYDROGEN SULPHIDE 0.2 %/A 8101461 HYDROGEN SULPHIDE 0.2/A 8101991 HYDROGEN SULPHIDE 0.2/B 6728041 HYDROGEN SULPHIDE 0.5/A 6719001 HYDROGEN SULPHIDE 1/C 8101831 HYDROGEN SULPHIDE 1/D 6733091 HYDROGEN SULPHIDE 10/A-D CH29101 HYDROGEN SULPHIDE 100/A 8101211 HYDROGEN SULPHIDE 2 %/A 6728821 HYDROGEN SULPHIDE 2/A 8101961 HYDROGEN SULPHIDE 2/B 6728141 HYDROGEN SULPHIDE 5/A-L CH29801 HYDROGEN SULPHIDE 5/B 8103521 IODINE 0.1/A 8103281 MERCAPTAN 0.1/A 6728981 MERCAPTAN 0.5/A 8101871 MERCAPTAN 20/A CH23101 MERCURY VAPOUR 0.1/B 8103801 METHANOL 20/A 8103391 METHYL BROMIDE 0.2/A 8101671 METHYL BROMIDE 0.5/A 6728211 METHYL BROMIDE 3/A CH27301 METHYL BROMIDE 5/B 8103591 METHYLENE CHLORIDE 20/A 8103485 MITC 0.1/A 8103071 NATURAL GAS ODORIZATION, TERT.-BUTYL MERCAPTAN (TBM) CH19501 NICKEL TETRACARBONYL 0.1/A 6728311 NITRIC ACID 1/A 8103631 NITROGEN DIOXIDE 0.1/A CH30001 NITROGEN DIOXIDE 0.5/C 8101111 NITROGEN DIOXIDE 10/A-D 6719101 NITROGEN DIOXIDE 2/C 8103661 NITROUS FUMES 0,2/A CH29401 NITROUS FUMES 0,5/A CH31001 NITROUS FUMES 2/A 6724001 NITROUS FUMES 20/A 6728911 NITROUS FUMES 5/A-L 8101921 NITROUS FUMES 50/A 8103941 NITROUS FUMES 50/B CH27701 NITROUS FUMES 100/C CH31201 OLEFINES 0.05 % /A CH26303 ORGANIC ARSENIC COMPOUNDS CH25903 ORGANIC BASIC NITROGEN COMPOUNDS 6733181 OZONE 0.05/B CH21001 OZONE 10/A 6724701 PENTANE 100/A 8101551 PERCHLOROETHYLENE 0.1/A CH30701 PERCHLOROETHYLENE 10/B 8101501 PERCHLOROETHYLENE 2/A 8101401 PERCHLOROETHYLENE 200/A-D 6730201 PETROLEUM HYDROCARBONS 100A 8101691 PETROLEUM HYDROCARBONS 10A 8101641 PHENOL 1/B 8101521 PHOSGENE 0.02/A CH19401 PHOSGENE 0.05/A CH28301 PHOSGENE 0.25/C 8103711 PHOSPHINE 0,1/C 8101611 PHOSPHINE 0.01/A CH31101 PHOSPHINE 0.1/A 8103341 PHOSPHINE 0.1/B IN ACETYLENE 8101801 PHOSPHINE 1/A 8101621 PHOSPHINE 25/A CH21201 PHOSPHINE 50/A 6728461 PHOSPHORIC ACID ESTER 0.05/A 8103531 PID-PRE-FILTER TUBE HUMIDITY 8103741 I-PROPANOL 50/A 6728651 PYRIDINE 5/A 6728851 SILICAGEL TYPE G 8101735 SIMULTANEOUS TEST-SET I FOR INORGANIC FUMES 8101736 SIMULTANEOUS TEST-SET II FOR INORGANIC FUMES 8101770 SIMULTANEOUS TEST-SET III FOR ORGANIC VAPOURS 8103180 SIMULTANEUS TEST SET 8103380 SIMULTANEUS TEST SET FOR CONTAINER FUMIGATION 8103170 SIMULTANEUS TEST SET INDICATOR SUBSTANCES 6723301 STYRENE 10/A CH27601 STYRENE 50/A 6727101 SULPHUR DIOXIDE 0.1/A 6728491 SULPHUR DIOXIDE 0.5/A CH31701 SULPHUR DIOXIDE 1/A 6728921 SULPHUR DIOXIDE 2/A-L CH24201 SULPHUR DIOXIDE 20/A 8101091 SULPHUR DIOXIDE 5/A-D 8101531 SULPHUR DIOXIDE 50/B 6728781 SULPHURIC ACID 1/A 8101341 TETRAHYDROTHIOPHENE 1/B CH25803 THIOETHER 8101731 TOLUENE 100/A 8101421 TOLUENE 100/A-D CH23001 TOLUENE 5/A 8101661 TOLUENE 5/B 8101701 TOLUENE 50/A 6724501 TOLUENE DIISOCYANATE 0.02/A CH21101 TRICHLOROETHANE 50/D CH24401 TRICHLOROETHYLENE 10/A 6728541 TRICHLOROETHYLENE 2/A 8101441 TRICHLOROETHYLENE 200/A-D 8101881 TRICHLOROETHYLENE 50/A 6718401 TRIETHYLAMINE 5/A 8101721 VINYL CHLORIDE 0.5/B 6728031 VINYL CHLORIDE 1/A CH19601 VINYL CHLORIDE 100/A CH23401 WATER VAPOUR 0,1 8101321 WATER VAPOUR 0,1/A 8101081 WATER VAPOUR 1/A 8101781 WATER VAPOUR 1/B 8103031 WATER VAPOUR 3/A 8103061 WATER VAPOUR 20/A-P 6728531 WATER VAPOUR 5/A-P
2.0 GENERAL INFORMATION: DRAGER-TUBES(TM) ARE ARTICLES WHICH ARE NOT SUBJECT TO LABELLING. THE REQUIREMENTS OF EC REGULATIONS 1907/2006 (REACH) AND 1272/2008 (GHS/CLP) DO NOT APPLY TO SUCH PRODUCTS. HENCE, THE INFORMATION IN THIS PRODUCT SAFETY INFORMATION SHEET IS PURELY VOLUNTARY! 2.1 CLASSIFICATION: NATURE OF HAZARD: "GHS07", "H332", H312", H302" "H318" 2.2 PARTICULAR HAZARDS FOR MAN AND ENVIRONMENT: THESE PRODUCTS ARE NON-FLAMMABLE, GRANULATE FILLED GLASS TUBES. IMPROPER HANDLING, LEAKS, AND/OR DAMAGE TO THE TUBES MAY RELEASE WEAK CAUSTIC/ CORROSIVE AND/OR IRRITANT/HARMFUL GRANULATE MATERIAL IN SOLID FORM. THE CHEMICALS AND PREPARATIONS IN THE DETECTOR TUBES MAY CAUSE DIFFERENT IRRITATION OR INJURY TO THE SKIN, EYES, GASTROINTESTINAL TRACT AND MAY CAUSE IRRITATION TO THE RESPIRATORY TRACT. IF THE GLASS TUBES ARE BROKEN, THE SHARP EDGES MAY CAUSE CUTS OR SCRATCHES.
3.1 CHEMICAL CHARACTERISATION (CONSTITUENT): NOT APPLICABLE 3.2 CHEMICAL CHARACTERISATION (MIXTURES): DRAGER-TUBES(TM) ARE GLASS TUBES USUALLY CONTAINING SMALL AMOUNTS OF INERT INORGANIC CARRIER MATERIALS WHICH HAVE BEEN IMPREGNATED WITH DIFFERENT CHEMICALS. IN THE FOLLOWING TABLE SUCH CHEMICALS ARE LISTED; FOR DETAILED INFORMATION ABOUT THE INGREDIENTS IN THE DIFFERENT TUBES PLEASE SEE THE DRAGER-TUBES(TM)-/CMS HANDBOOK. EINECS / CAS-NO. DESIGNATION ACC. TO CONTENT ELINCS-NO. THE EC REGULATIONS 203-564-8 108-24-7 ACETIC ACID ANHYDRID 0-1 N/A N/A AMINE COMPOUNDS 0-3 N/A N/A BARIUMCHLOROANILAT 0-0.1 N/A N/A BUTYRYLCHOLINIODIDE 0-0.1 237-029-5 10294-42-5 CERIUM SULFATE 0-0.1 N/A N/A CHROMIUM(VI) SALTS <1 N/A N/A COPPER SALTS 0-10 N/A 107-21-1 ETHYLENE GLYCOL 0-0,2 N/A N/A FORMALDEHYDE 0-0.1 N/A N/A FURFUROL 0-0.1 N/A N/A GOLD SALTS 0-1 206-114-9 7803-57-8 HYDRAZINE-HYDRATE 0-6 N/A N/A HYDROCHLORIC ACID 0-0.5 231-442-4 7553-56-2 IODINE 0-3 234-740-2 12029-98-0 IODINEPENTOXIDE 0-0.01 N/A N.A LEAD SALTS 0-0,1 N/A N/A MAGNESIUM PERCHLORATE 0-0.1 N/A N/A MERCURY SALTS 0-0.1 202-088-8 91-66-7 N,N-DIETHYLANILINE 0-0.2 204-358-0 119-93-7 O-TOLIDINE 0-0.5 N/A N/A O-DIANISIDINE 0-0.1 N/A N/A PALLADIUM COMPOUNDS 0-0.2 231-760-3 7722-64-7 POTASSIUM PERMANGANATE 0-0.1 231-633-2 7664-38-2 O-PHOSPHORIC ACID 0-10 203-809-9 110-86-1 PYRIDINE 0-5 N/A N/A PYRIDYLPYRIDINIUMCHLORIDE 0-0.1 N/A N/A SILVER SALTS 0-0.1 N/A N/A SELENIUM SALTS <1 N/A N/A SODIUM SALTS 0-1 N/A N/A SULPHURIC ACID 0-5 N/A N/A XYLENE 0-1 N/A N/A ZIRCONIUM COMPOUNDS 0-0.0005 DESIGNATION ACC. UNIT GHS-PICTOGRAM H-PHRASES TO THE EC REGULATIONS ACETIC ACID ANHYDRID W/W PER CENT GHS05 H302, H314, H332 AMINE COMPOUNDS W/W PER CENT GHS06, GHS08, H302, H319, GHS09 H331, H335, H373, H400, H410 BARIUMCHLOROANILAT W/W PER CENT GHS07 H302, H332 BUTYRYLCHOLINIODIDE W/W PER CENT GHS07 H315, H319, H335 CERIUM SULFATE W/W PER CENT GHS07 H315, H319 CHROMIUM(VI) SALTS W/W PER CENT GHS06, GHS09 H301, H312, H315, H317, H318, H330, H335, H400, H410 COPPER SALTS W/W PER CENT GHS07, GHS09 H302, H315, H319, H400, H410 ETHYLENE GLYCOL W/W PER CENT GHS07 H302 FORMALDEHYDE W/W PER CENT GHS07 H302, H315, H317, H319, H332, H335, FURFUROL W/W PER CENT GHS06, GHS07 H301, H312, H319, H330, H331, H335 GOLD SALTS W/W PER CENT GHS05 H302, H314 HYDRAZINE-HYDRATE W/W PER CENT GHS06, GHS09 H301, H311, H314, H317, H330, H331, H400, H410 HYDROCHLORIC ACID W/W PER CENT GHS05 H314, H335 IODINE W/W PER CENT GHS07, GHS09 H312, H332, H400 IODINEPENTOXIDE W/W PER CENT GHS07 H315, H319 LEAD SALTS W/W PER CENT GHS06, GHS09 H373, H400, H410 MAGNESIUM PERCHLORATE W/W PER CENT GHS07 H315, H319, H335 MERCURY SALTS W/W PER CENT GHS06, GHS09 H300, H314, H372, H400, H410 N,N-DIETHYLANILINE W/W PER CENT GHS06, GHS09 H301, H311, H330, H331, H373, H411 O-TOLIDINE W/W PER CENT GHS06, GHS09 H302, H411 O-DIANISIDINE W/W PER CENT GHS06 H302 PALLADIUM COMPOUNDS W/W PER CENT GHS05 H314 POTASSIUM PERM ANGANATE W/W PER CENT GHS07, GHS09 H302, H400, H410 O-PHOSPHORIC ACID W/W PER CENT GHS05 H290, H314 PYRIDINE W/W PER CENT GHS07 H302, H312, H332 PYRIDYLPYRIDINIUMCHLORIDE W/W PER CENT GHS07 H315, H319, H335 SILVER SALTS W/W PER CENT GHS05, GHS09 H314, H400, H410 SELENIUM SALTS W/W PER CENT GHS06, GHS09 H330, H331, H373, H400, H410 SODIUM SALTS W/W PER CENT GHS05 H314 SULPHURIC ACID W/W PER CENT GHS05 H314 XYLENE W/W PER CENT GHS07 H312, H315, H332 ZIRCONIUM COMPOUNDS W/W PER CENT GHS05 H314 * BASED ON THE GROSS WEIGHT OF THE DRAEGER TUBE(TM). THE INFORMATION CONTAINED IN THIS PRODUCT SAFETY INFORMATION SHEET IS APPLICABLE TO THE HAZARDOUS CONTENTS OF THE DRAEGER TUBE(TM). 2.3 OTHER INFORMATION: DRAGER-TUBES(TM) ARE CLOSED GLASS TUBES WHICH ARE FILLED WITH SEVERAL PREPARATION LAYERS. THE PREPARATION LAYERS ARE USUALLY FIXED BY HOLDING AND SEPARATING ELEMENTS WITHIN THE GLASS TUBE. PARTIALLY THE DRAGER-TUBES(TM) CONTAIN FILLED GLASS AMPOULES ALSO WITH REACTIVE LIQUIDS. IMPORTANT INGREDIENTS IN PREPARATIONS USED FOR THE DRAGER-TUBES(TM): INORGANIC ACID, INORGANIC SALTS, AND ORGANIC CHEMICALS/INDICATORS IN SMALL QUANTITIES AND IN CONCENTRATIONS BELOW THE LIMIT FOR LABELLING-REQUIREMENTS IN ACC. TO CLP AND THE GERMAN GEFSTOFFV. IMPORTANT INGREDIENTS OF THE AMPOULES USED IN THE DRAGER-TUBES(TM): INORGANIC ACIDS, ORGANIC SOLVENTS. DRAGER-TUBES(TM) CONTAIN NO OZONE-DEPLETING CHEMICALS AND NO VOLATILE ORGANIC CHEMICALS (EXCEPT SPECIAL AMPOULES). DURING THE MANUFACTURING PROCESS FOR THE DRAGER-TUBES(TM) (EXCEPT SPECIAL CALIBRATION PROCEDURES) NO OZONE-DEPLETING CHEMICALS (GROUP I-IV OF THE MONTREAL PROTOCOL) WERE USED.
4.1 AFTER INHALATION: IF DUSTS OF THIS PRODUCT IS INHALED, REMOVE PERSON IMMEDIATELY TO FRESH AIR. SEEK MEDICAL ATTENTION IF SYMPTOMS DEVELOP OR PERSIST. 4.2 AFTER CONTACT WITH SKIN: WASH WITH PLENTY OF WATER. TUBE CONTENTS CAN BE NEUTRALIZED WITH LIME AND WATER, OR RINSED WITH PLENTY OF WATER, THEN TREATED WITH POLYETHYLENE GLYCOL 400. IF IRRITATION PERSISTS, GET MEDICAL ADVICE. DISCARD ANY SHOES OR CLOTHING ITEMS THAT CANNOT BE DECONTAMINATED. 4.3 AFTER CONTACT WITH THE EYES: IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER (FOR AT LEAST 15 MINUTES), WHILE HOLDING EYELIDS OPEN. SEEK MEDICAL ADVICE AT ONCE. DANGER OF CORNEAL CLOUDING. 4.4 AFTER INGESTION: IF THE MATERIAL IS SWALLOWED, GET IMMEDIATE MEDICAL ATTENTION OR ADVICE. DO NOT INDUCE VOMITING (DANGER OF PERFORATION!). 4.5 INFORMATION FOR THE DOCTOR: AFTER INGESTION THERE IS A DANGER OF THE OESOPHAGUS AND THE STOMACH BECOMING PERFORATED.
5.1 SUITABLE EXTINGUISHING MEDIA: DRY CHEMICAL, CARBON DIOXIDE. ADAPT EXTINGUISHING MEDIA TO THE ENVIRONMENT. MATERIALS IN THE GLASS TUBES ARE NONFLAMMABLE. AVOID DIRECT CONTACT OF THIS PRODUCT WITH WATER SINCE THIS MAY CAUSE AN EXOTHERMIC REACTION. 5.2 EXTINGUISHING MEDIA WHICH MUST NOT BE USED FOR SAFETY REASONS: NOT CHECKED 5.3 SPECIAL EXPOSURE HAZARDS ARISING FROM SUBSTANCES OR PREPARATION ITSELF, COMBUSTION PRODUCTS, RESULTING GASES: NON-FLAMMABLE. THERMAL DECOMPOSITION OF THE TUBE CONTENTS MAY PRODUCE WEAK AMOUNT OF HARMFUL, IRRITANT OR TOXIC GASES (SULPHUR OXIDES, CARBON MONOXIDE, ETC.). WHEN USING WATER AS AN EXTINGUISHING MEDIA, TAKE CARE OF THE RESULTING SLIGHT ACIDIC FIRE-FIGHTING WATER. CONTENTS OF THE TUBES ARE CORROSIVE TO THE EYES, SKIN, GASTROINTESTINAL TRACT AND MAY CAUSE IRRITATION TO THE RESPIRATORY TRACT. IMPROPER HANDLING, LEAKS, AND/OR DAMAGE TO THE TUBE MAY RELEASE CAUSTIC GRANULATE MATERIAL IN SOLID FORM. 5.4 SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS: RECOMMENDATION: WEAR FULL PROTECTIVE CLOTHING, INCLUDING HELMET, SELF-CONTAINED POSITIVE PRESSURE OR PRESSURE DEMAND BREATHING APPARATUS, PROTECTIVE CLOTHING AND FACE MASK.
6.1 PERSONAL PRECAUTIONS: DO NOT INHALE RELEASED VAPOUR, FUMES, OR DUSTS FROM THE SPILLED MATERIAL. DO NOT ALLOW SPILLED MATERIALS TO CONTACT EYES OR SKIN, USE PROTECTIVE GLOVES (E.G. PE/PP, LATEX, RUBBER) RESISTANT AGAINST ACIDIC MATERIALS AND SAFETY GOGGLES. ISOLATE AREA. KEEP UNNECESSARY PERSONNEL AWAY. USE DUST MASK WITH P2/FFP2 FILTERS. 6.2 ENVIRONMENTAL PRECAUTIONS: BLOCK ANY POTENTIAL ROUTES TO WATER SYSTEMS. DO NOT DISCHARGE INTO THE SEWER SYSTEM. DO NOT ALLOW TO ENTER DRAINS/SURFACE WATER/GROUNDWATER. 6.3 METHODS FOR CLEANING UP: SWEEP UP DRY WHILE AVOIDING FORMATION OF DUSTS. DO NOT PICK UP GLASS WITH BARE HANDS. DILUTE TUBE CONTENTS WITH WATER AND BAKING SODA. SHOVEL MATERIAL INTO APPROPRIATE CONTAINER FOR DISPOSAL. THOROUGHLY WASH THE AREA WITH WATER AFTER A SPILL OR LEAK CLEAN-UP. SWEEP UP OR SCRAPE BROKEN TUBES INTO CONTAINER FOR DISPOSAL. 6.4 ADDITIONAL INFORMATION: FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
7.1 HANDLING: PRECAUTIONS FOR SAFETY HANDLING: OBSERVE THE INSTRUCTIONS FOR USE. INFORMATION FOR PROTECTION AGAINST FIRE AND EXPLOSION: THESE PRODUCTS ARE NON-FLAMMABLE. 7.2 STORAGE: REQUIREMENTS FOR STORAGE AND CONTAINERS: KEEP CONTAINERS TIGHTLY CLOSED AND DRY. DO NOT STORE AT TEMPERATURES EXCEEDING 77 DEG. F (25 DEG. C). HANDLING ACCORDING TO THE INSTRUCTIONS FOR USE. STORE THE PRODUCT IN THE ORIGINAL PACKAGING. THE EXPIRY DATE ON THE PACKAGING MUST BE CONSIDERED. INFORMATION ON STORAGE TOGETHER WITH OTHER MATERIALS: OBSERVE VCI-CONCEPT FOR STORING CHEMICALS. FURTHER INFORMATION ON STORAGE CONDITIONS: CONTENTS ARE CORROSIVE. AVOID CONTACT WITH WATER. OPEN TUBES SHOULD BE STORED IN THE CONTAINER IN A WELL VENTILATED AREA UNTIL THEY ARE DISPOSED OF. STORAGE CLASS: LGK 10-13 (VCI-CONCEPT). 7.3 CERTAIN APPLICATION: N/A
8.1 COMPONENTS WITH EXPOSURE LIMIT VALUES: SEVERAL, IN RELATION TO THE CHEMICALS IN THE TUBES (SEE SECTION 2). BUT WITH NORMAL HANDLING OF THE DRAGER-TUBES(TM) THERE SHOULD BE NO EXPOSURE TO CONTENTS. HOWEVER, IF EXPOSURE DOES OCCUR, FOLLOW THE NATIONAL EXPOSURE LIMITS FOR THE RELEVANT CHEMICALS. FOR DETAILED INFORMATION ABOUT THE INGREDIENTS IN THE DIFFERENT TUBES, PLEASE SEE THE DRAGER-TUBES(TM) -/CMS HANDBOOK. EC, CAS-NO. DESCRIPTION OF MATERIAL TYPE CONTENT UNIT LAND D 7664-93-9 SULPHURIC ACID MAK 0,1 E** MG/M3 D N/A CHROMIUM(VI) COMPOUNDS TRK 0,05 E* MG/M3 D 1333-82-0 CHROMIUM TRIOXIDE EG CARC. CAT 1 / S D 7664-38-2 O-PHOSPHORIC ACID MAK 2 MG/M3 D 7778-50-9 POTASSIUM DICHROMATE EG CARC. CAT 1 / MUTA. CAT. 2 / S D 110-86-1 PYRIDINE DFG, 16 MG/M3 EU- 5 ML/M3 CLASSIFICATION E = INHALABLE FRACTION CARC. CAT 1 = MAK = GERMAN CARCINOGEN TO HUMAN TLV BODY CARC. CAT 2 = CARCINOGEN TO HUMAN BODY IS POSSIBLE. MUTA. CAT 2 = REPRODUCTIVE TOXIC TO HUMAN BODY IS POSSIBLE. S = HAZARD OF SENSITIZATION 8.2 EXPOSURE CONTROLS: 8.2.1 OCCUPATIONAL EXPOSURE CONTROLS: GENERAL PROTECTION AND HYGIENE MEASURES: WITH NORMAL HANDLING OF THE DRAGER-TUBES(TM) THERE SHOULD BE NO EXPOSURE TO CONTENTS. HOWEVER, IF EXPOSURE DOES OCCUR, FOLLOW THE EXPOSURE LIMITS. USE GOOD INDUSTRIAL HYGIENE PRACTICES. PERSONAL PROTECTION: 8.2.1.1 RESPIRATORY PROTECTION: NOT NECESSARY WHEN HANDLED ACCORDING TO THE INSTRUCTIONS FOR USE. 8.2.1.2 HAND PROTECTION: WITH NORMAL HANDLING OF THE DRAGER-TUBES(TM) THERE SHOULD BE NO EXPOSURE TO CONTENTS. IN CASE OF ACCIDENTS USE SUITABLE PROTECTIVE GLOVES MADE FROM PE/ PP, LATEX, BUTYL OR NITRILE RUBBER. PLEASE OBSERVE THE GLOVE MANUFACTURERS INSTRUCTIONS ON PERMEABILITY AND RUPTURE TIMES AS WELL AS THE SPECIFIC WORKPLACE CONDITIONS. 8.2.1.3 EYE PROTECTION: NOT NECESSARY WHEN HANDLED ACCORDING TO THE INSTRUCTIONS FOR USE. RECOMMENDATION: WEAR SAFETY GLASSES WITH SIDE SHIELDS. 8.2.1.4 SKIN PROTECTION: PROPHYLACTIC SKIN PROTECTION IS RECOMMENDED. WASH THOROUGHLY AFTER HANDLING. SKIN CARE. 8.2.2 ADDITIONAL INFORMATION ON PLANT DESIGN: HANDLING ACCORDING TO THE INSTRUCTIONS FOR USE.
9.1 GENERAL INFORMATION: FORM: GLASS TUBES CONTAINING COLOURLESS AND/OR COLOURED SOLIDS. COLOUR: VARIOUS ODOUR: SLIGHTLY PUNGENT/ODOURLESS 9.2 IMPORTANT INFORMATION ABOUT THE PROTECTION OF HEALTH, SAFETY AND THE ENVIRONMENT: METHOD (67/548/EEC): SOLUBILITY: N/A PH-VALUE: N/A (WEAK ACIDIC REACTION) BOILING POINT: N/A MELTING POINT: N/A FLAME POINT: N/A INFLAMEABILITY: N/A EXPLOSION LIMITS: LOWER: N/A UPPER: N/A IGNITION TEMPERATURE: N/A VAPOUR PRESSURE: N/A MASS DENSITY: N/A FURTHER INFORMATION: N/A 9.3 OTHER INFORMATION: N/A
GENERAL INFORMATION: STABLE UNDER NORMAL CONDITIONS AND APPROPRIATE COMMERCE. 10.1 CONDITIONS TO AVOID: DO NOT MIX OTHER SUBSTANCES WITH CONTENTS OF TUBES. AVOID CONTACT WITH WATER. STABLE UNDER NORMAL CONDITIONS. HAZARDOUS POLYMERISATION WILL NOT OCCUR. DO NOT STORE ABOVE 25 DEG. C (77 DEG. F). 10.2 MATERIALS TO AVOID: TUBES CONTENTS REACT WITH BASES. POSSIBILITY OF A SLIGHT EXOTHERMIC REACTION. 10.3 HAZARDOUS DECOMPOSITION PRODUCTS: DECOMPOSITION OF GRANULATE IN THE TUBES MAY PRODUCE TOXIC SUBSTANCES (E.G. SULPHUR OXIDES). POSSIBILITY OF A DANGEROUS EXOTHERMIC REACTION: AVOID CONTACT WITH BASES/WATER, TUBE CONTENTS MAY REACT WITH BASES AND WATER IN AN EXOTHERMIC REACTION. DANGEROUS PRODUCTS OF DECOMPOSITION AT CONTACT WITH WATER: ACIDS AND SOLUTIONS OF (HEAVY) METAL SALTS 10.4 FURTHER INFORMATION: N/A
11.1 TOXICITY TESTS: CLASSIFICATION-RELEVANT LD/LC50-VALUES: NO TOXICITY DATA ARE AVAILABLE FOR THE CONTENTS OF THE TUBES (CARRIER MATERIALS IMPREGNATED WITH DIFFERENT CHEMICALS!). 11.1.1 SPECIFIC SYMPTOMS IN ANIMAL STUDIES: NO DATA ARE AVAILABLE. 11.1.2 IRRITANT/CORROSIVE EFFECTS: IRRITANT AND WEAK CORROSIVE EFFECTS OF THE CONTENTS OF THE TUBES CANNOT BE EXCLUDED. 11.1.3 SENSITIZATION: SENSITIZATION EFFECTS OF THE CONTENTS OF THE TUBES CANNOT BE EXCLUDED. 11.1.4 SUBACUTE AND CHRONICAL TOXICITY: EXPERIMENTS: NO DATA ARE AVAILABLE. SPECIES: NO DATA ARE AVAILABLE. 11.1.5 CARCINOGENIC, MUTAGENIC AND REPRODUCTIVE TOXIC EFFECTS: NO DATA ARE AVAILABLE. SEE SECTION 11.3 11.1.6 FURTHER INFORMATION: FOR DETAILED INFORMATION ABOUT THE INGREDIENTS IN THE DIFFERENT TUBES AND THEIR HAZARDS, PLEASE SEE THE DRAGER-TUBES(TM)-/CMS HANDBOOK AND SECTION 2. 11.2 EFFECTS ON HUMAN BODY/EXPERIMENTS MADE IN PRACTICE: AFTER INHALATION: INHALATION OF DUSTS FROM THE TUBE CONTENTS MAY CAUSE IRRITATION OR INJURY TO THE RESPIRATORY SYSTEM. AFTER INGESTION: PRODUCT CONTENTS MAY BE HARMFUL OR FATAL IF SWALLOWED. THIS PRODUCT MAY PRODUCE CORROSIVE DAMAGE TO THE GASTROINTESTINAL TRACT IF SWALLOWED. AFTER EYE CONTACT: EYE CONTACT WITH CONTENTS OF THE TUBES MAY CAUSE CORROSIVE DAMAGE WITH IRRITATION, AND POSSIBLE EYE INJURY. AFTER SKIN CONTACT: SKIN CONTACT WITH THE CONTENTS OF THE TUBES MAY CAUSE SLIGHT CORROSIVE DAMAGE WITH IRRITATION. 11.3 ADDITIONAL TOXICOLOGICAL INFORMATION: THE TOXICITY OF THE IMPREGNATED CARRIER MATERIAL CONTAINED IN THE TUBES HAS NOT BEEN TESTED IN DETAIL. WITH RESPECT TO THE CHEMICALS USED FOR THE IMPREGNATION THESE MATERIALS SHOULD BE HANDLED IN THE SAME WAY AS THE PURE CHEMICALS. THEY MAY CAUSE SENSITIZATION, IRRITATION OR INJURY TO THE SKIN, EYES AND MUCOUS MEMBRANE. CARCINOGENIC, MUTAGENIC AND REPRODUCTIVE TOXIC EFFECTS CAN NOT BE EXCLUDED, BECAUSE SOME OF THE IMPREGNATION CHEMICALS IN PURE FORM ARE CLASSIFIED ACCORDINGLY. FURTHER INFORMATION: IF THE GLASS TUBE IS BROKEN, THE SHARP EDGES MAY CAUSE CUTS OR SCRATCHES.
12.1 ECOTOXICITY: NO ECOTOXICITY DATA ARE AVAILABLE FOR THE PREPARATIONS/COMPONENTS IN THE DRAGER-TUBES(TM). 12.2 MOBILITY: NO DATA ARE AVAILABLE 12.3 PERSISTENCE AND DEGRADABILITY: BIOLOGICAL DECOMPOSITIONABILITY: NO DATA ARE AVAILABLE BEHAVIOUR IN PURIFICATION PLANTS: NO DATA ARE AVAILABLE 12.4 BIOACCUMULATIVE POTENTIAL: NO DATA ARE AVAILABLE 12.5 OTHER ADVERSE EFFECTS: NO DATA ARE AVAILABLE 12.6 ADDITIONAL INFORMATION: DRAGER-TUBES(TM) THEMSELVES AND ALSO THE CHEMICAL PREPARATIONS/COMPONENTS IN THE TUBES SHOULDN'T BE RELEASED INTO WATER BECAUSE THE CHEMICALS ON THE CARRIER MATERIAL COULD BE DISSOLVED AND THEN CONTAMINATE THE WATER. NORMALLY WATER EXTRACTS FROM THE IMPREGNATED CARRIER MATERIALS HAVE A LOW PH-VALUE AND CONTAIN SMALL AMOUNTS OF THE CHEMICALS USED FOR IMPREGNATION. SO, IT WOULD BE EXPECTED TO PRODUCE ECOTOXICITY UPON EXPOSURE TO AQUATIC ORGANISMS AND AQUATIC SYSTEMS. DRAGER-TUBES(TM) THEMSELVES AND THE CHEMICAL PREPARATIONS/COMPONENTS IN THE TUBES ARE NOT EXPECTED TO ACCUMULATE IN THE FOOD CHAIN.
13.1 PRODUCT (RECOMMENDATIONS): IF DISCARDED, WASTES MAY BE CLASSIFIED AS CORROSIVE WASTE OR REACTIVE WASTE. PRIOR TO DISPOSAL, CAREFULLY DILUTE TUBE CONTENTS WITH WATER. ADD BAKING SODA TO NEUTRALISE ACIDITY. DO NOT ALLOW THIS MATERIAL TO DRAIN INTO SEWERS/WATER SUPPLIES. WASTE MUST BE HANDLED IN ACCORDANCE WITH ALL FEDERAL, STATE, PROVINCIAL, AND LOCAL REGULATIONS. DRAGER-TUBES(TM) MUST BE DISPOSED OF IN ACCORDANCE WITH LOCAL WASTE DISPOSAL REGULATIONS. IF DISCARDED, WASTES MAY BE CLASSIFIED AS HAZARDOUS WASTE. APPLICABLE "WASTE NUMBERS" (FEDERAL, STATE, PROVINCIAL, AND LOCAL) FOR THIS PRODUCTS OR THEIR COMPONENTS HAVE NOT BEEN CHECKED IN DETAIL. WASTE CATEGORY: EWL (EUROPEAN WASTE LIST): 170204* WASTE DESIGNATION: GLASS, PLASTIC AND WOOD CONTAINING OR CONTAMINATED WITH DANGEROUS SUBSTANCES. OBLIGATION TO PROVE CORRECT DISPOSAL: YES 13.2 NOT CLEANED PACKAGING MATERIAL (RECOMMENDATIONS): THE DISPOSAL OF PLASTIC CONTAINERS AND FLEXIBLE PACKAGES IS POSSIBLE BY EWL 150102, AND FIBRE BOARD BOXES BY EWL 150101.
14.1 ROAD TRANSPORT ADR/RID AND GGVSE (CROSS-BORDER/DOMESTIC): UN-NO.: ./. CLASS: ./. PACKING GROUP: ./. NAME: ./. CLASSIFICATION CODE: ./. REMARKS: DRAGER-TUBES(TM) CITED IN SECTION 1 ARE NO DANGEROUS GOODS. THESE DRAGER-TUBES(TM) ARE NO HAZARDOUS MATERIAL AS DEFINED BY THE TRANSPORT REGULATIONS. 14.2 MARINE TRANSPORT IMDG-CODE/GGVSEE: UN-NO.: ./. CORRECT TECHNICAL NAME: ./. CLASS: ./. SUB RISK: PACKING GROUP: ./. EMS-NO.: ./. MFAG: ./. MARINE POLLUTANT: ./. REMARKS: DRAGER-TUBES(TM) CITED IN SECTION 1 ARE NO DANGEROUS GOODS. THESE DRAGER-TUBES(TM) ARE NO HAZARDOUS MATERIAL AS DEFINED BY THE TRANSPORT REGULATIONS. 14.3 AIR TRANSPORT ICAO-TI UND IATA-DGR: UN-NO.: ./. PROPER SHIPPING NAME: ./. CLASS: ./. SUB RISK: ./. PG: ./. REMARKS: DRAGER-TUBES(TM) CITED IN SECTION 1 ARE NO DANGEROUS GOODS. THESE DRAGER-TUBES(TM) ARE NO HAZARDOUS MATERIAL AS DEFINED BY THE TRANSPORT REGULATIONS. 14.4 TRANSPORT/FURTHER INFORMATION: MAY BE SENT BY POST.
15.1 LABELLING ACCORDING TO EC REGULATIONS: HAZARDOUS SYMBOLS AND INDICATORS OF DANGER FOR DANGEROUS SUBSTANCES AND PREPARATIONS: NO LABELLING NECESSARY. HAZARDOUS COMPONENTS TO BE INDICATED ON LABEL: CONTAINS: N/A H-PHRASES: N/A P-PHRASES (RECOMMENDATION): P102: KEEP OUT OF REACH OF CHILDREN. P302+P352: IF ON SKIN: WASH WITH PLENTY OF WATER. P305+P351+P338: IF IN EYES: RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. P308+P313: IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION. 15.2 NATIONAL REGULATIONS: ADDITIONAL CLASSIFICATION ACC. TO GEFSTOFFV ANNEX II NO. (ONLY IF DIFFERING FROM EC CLASSIFICATION): N/A RESTRICTIONS OF OCCUPATION: N/A STATUTORY ORDER ON HAZARDOUS INCIDENTS: N/A WATER POLLUTION CLASS: 3 (SELF-CLASSIFICATION) INFORMATION ACCORDING 1999/13/EC ABOUT LIMITATION OF EMISSIONS OF VOLATILE ORGANIC COMPOUNDS (VOC-GUIDELINE): FURTHER REGULATIONS, RESTRICTIONS, AND PROHIBITION REGULATION: (SUCH AS PRINCIPLES OF INDUSTRIAL MEDICINE AND HEALTH AND SAFETY REGULATIONS) INSTRUCTION SHEET BG-CHEMIE (CHEMICAL PROFESSIONAL ASSOCIATION): OTHER STATE REGULATIONS MAY APPLY. CHECK INDIVIDUAL STATE REQUIREMENTS.
USE OF THE SUBSTANCE / PREPARATION: SEE SECTION 1.2; ADDITIONAL INFORMATION IN THE INSTRUCTIONS FOR USE. RELEVANT H-PHRASES: H270: MAY CAUSE OR INTENSIFY FIRE; OXIDISER. H290: MAY BE CORROSIVE TO METALS H300: FATAL IF SWALLOWED. H301: TOXIC IF SWALLOWED. H302: HARMFUL IF SWALLOWED. H311: TOXIC IN CONTACT WITH SKIN. H312: HARMFUL IN CONTACT WITH SKIN. H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE. H315: CAUSES SKIN IRRITATION. H317: MAY CAUSE AN ALLERGIC SKIN REACTION. H318: CAUSES SERIOUS EYE DAMAGE. H319: CAUSES SERIOUS EYE IRRITATION. H330: FATAL IF INHALED. H331: TOXIC IF INHALED. H332: HARMFUL IF INHALED. H335: MAY CAUSE RESPIRATORY IRRITATION. H372: CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. H400: VERY TOXIC TO AQUATIC LIFE. H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS. H411: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS. COMMENTS: N. A.; N/A; ./.: NOT APPLICABLE MAC: MAXIMUM ALLOWABLE CONCENTRATION COD: CHEMICAL OXYGEN DEMAND BOD: BIOCHEMICAL OXYGEN DEMAND EWL: EUROPEAN WASTE LIST VOC: VOLATILE ORGANIC COMPOUNDS VCI: VERBAND DER CHEMISCHEN INDUSTRIE E.V. (ASSOCIATION OF THE GERMAN CHEMICAL INDUSTRY) WGK: GERMAN WATER HAZARD CLASS FURTHER INFORMATION: THE ABOVE INFORMATION REPRESENTS OUR CURRENT STATE OF EXPERIENCE AND DESCRIBES THE PRODUCT ONLY WITH RESPECT TO SAFETY REQUIREMENTS. THE MANUFACTURER MAKES NO REPRESENTATIONS AND ASSUMES NO LIABILITY FOR ANY DIRECT, INCIDENTAL OR CONSEQUENTIAL DAMAGES RESULTING FROM ITS USE. IT IS THE RESPONSIBILITY OF THE CUSTOMER TO TEST WHETHER THE PRODUCT IS SUITABLE FOR THE PURPOSE INTENDED BY THE CUSTOMER. ANY QUESTIONS OF WARRANTY AND LIABILITY FOR THIS PRODUCT ARE SUBJECT TO OUR GENERAL TERMS AND CONDITIONS UNLESS LEGISLATION IMPERATIVELY PROVIDES OTHERWISE. DATA SHEET ISSUED BY: GLOBAL EHS MANAGEMENT CONTACT: DR. MICHAELA SCHATZ, MICHAELA.SCHATZ@DRAEGER.COM CHANGES TO PRECEDING VERSION: IN HEADER AND SECTION 1. |