| Common Name: | ALL-STATE NO. 4-T, ALL-STATE NO. 4-60T |
| Manufacturer: | ESAB |
| SDS Revision Date: | 1/14/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 400G74, 400G75 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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ESAB(R*)
SAFETY DATA SHEET
THIS SAFETY DATA SHEET COMPLIES WITH ANNEX II OF 830/2015 AMENDING
EC NO. 1907/2006, CLP DIRECTIVE 1272/2008, ALSO IN ACCORDANCE WITH
ISO 11014-1 AND ANSI Z400.1
ALL-STATE NO. 4-T
ISSUED: 2018-01-14
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
TRADE NAME: ALL-STATE NO. 4-T
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE: ARC WELDING
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
SDS CREATED BY: TDS TEAM
SUPPLIER: ESAB DENTON
STREET:
ADDRESS 2800 AIRPORT ROAD
DENTON, TX 76207
TELEPHONE: 1-800-372-2123
EMAIL: SDSREQUEST@ESAB.COM
WEB SITE: WWW.ESAB.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY PHONE NUMBER: 1-800-372-2123
AVAILABLE OUTSIDE OFFICE HOURS: NO
OTHER:
AWS CLASSIFICATION: NONE
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
THE PRODUCT IS NOT CLASSIFIED
2.2. LABEL ELEMENTS: THE PRODUCT DO NOT REQUIRE LABELING
2.3. OTHER HAZARDS:
EMERGENCY OVERVIEW:
METAL WIRE OR RODS IN VARYING COLOURS. THIS PRODUCT IS NORMALLY NOT
CONSIDERED HAZARDOUS AS SHIPPED. GLOVES SHOULD BE WORN WHEN HANDLING
TO PREVENT CUTS AND ABRASIONS.
THIS PRODUCT CONTAINS NICKEL, WHICH IS CLASSIFIED AS TOXIC BY PROLONGED
INHALATION, A SKIN SENSITIZER AND A SUSPECT CARCINOGEN. IN THE FORM THAT
NICKEL IS PRESENT IN THIS PRODUCT IT DOES NOT CONTRIBUTE TO A HAZARD
CLASSIFICATION OF THE PRODUCT.
SKIN CONTACT IS NORMALLY NO HAZARD BUT SHOULD BE AVOIDED TO PREVENT
POSSIBLE ALLERGIC REACTIONS.
PERSONS WITH A PACEMAKER SHOULD NOT GO NEAR WELDING OR CUTTING OPERATIONS
UNTIL THEY HAVE CONSULTED THEIR DOCTOR AND OBTAINED INFORMATION FROM THE
MANUFACTURER OF THE DEVICE.
WHEN THIS PRODUCT IS USED IN A WELDING PROCESS, THE MOST IMPORTANT HAZARDS
ARE WELDING FUMES, HEAT, RADIATION AND ELECTRIC SHOCK.
HEAT: SPATTER AND MELTING METAL CAN CAUSE BURN INJURIES AND START FIRES.
RADIATION: ARC RAYS CAN SEVERELY DAMAGE EYES OR SKIN.
FUMES:
OVEREXPOSURE TO WELDING FUMES MAY RESULT IN SYMPTOMS LIKE METAL FUME FEVER,
DIZZINESS, NAUSEA, DRYNESS OR IRRITATION OF THE NOSE, THROAT OR EYES.
CHRONIC OVEREXPOSURE TO WELDING FUMES MAY AFFECT PULMONARY FUNCTION.
PROLONGED INHALATION OF NICKEL COMPOUNDS ABOVE SAFE EXPOSURE LIMITS CAN
CAUSE CANCER. OVEREXPOSURE TO MANGANESE AND MANGANESE COMPOUNDS ABOVE
SAFE EXPOSURE LIMITS CAN CAUSE IRREVERSIBLE DAMAGE TO THE CENTRAL NERVOUS
SYSTEM, INCLUDING THE BRAIN, SYMPTOMS OF WHICH MAY INCLUDE SLURRED SPEECH,
LETHARGY, TREMOR, MUSCULAR WEAKNESS, PSYCHOLOGICAL DISTURBANCES AND SPASTIC
GAIT.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.2. MIXTURES:
CHEMICAL NAME CAS NO. CONCENTRATION CLASSIFICATION R-PHRASE
EC NO. H-PHRASE
REACH NO.
NICKEL 7440-02-0 >98% CARC. 2, SKIN H317,
231-111-4 SENS. 1, STOT H351,
RE 1 H372
CARBON 7440-44-0 <0,1%
231-153-3
IRON 7439-89-6 <0,1%
231-096-4
REGISTERED
MANGANESE 7439-96-5 <0,1%
231-105-1
PRODUCT BASED ON:
THIS PRODUCT IS CONTINUOUS METAL WIRES AND SOLID METAL RODS.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
ELECTRIC SHOCK:
DISCONNECT AND TURN OFF THE POWER. USE A NONCONDUCTIVE MATERIAL TO PULL
VICTIM AWAY FROM CONTACT WITH LIVE PARTS OR WIRES. IF NOT BREATHING,
BEGIN ARTIFICIAL RESPIRATION, PREFERABLY MOUTH-TO-MOUTH. IF NO DETECTABLE
PULSE, BEGIN CPR CALL A PHYSICIAN IMMEDIATELY.
INHALATION:
IF BREATHING HAS STOPPED, PERFORM ARTIFICIAL RESPIRATION AND OBTAIN MEDICAL
ASSISTANCE IMMEDIATELY! IF BREATHING IS DIFFICULT, PROVIDE FRESH AIR AND
CALL PHYSICIAN.
SKIN CONTACT:
FOR SKIN BURNS FROM ARC RADIATION, PROMPTLY FLUSH WITH COLD WATER. GET
MEDICAL ATTENTION FOR BURNS OR IRRITATIONS THAT PERSIST. TO REMOVE DUST
OR PARTICLES WASH WITH MILD SOAP AND WATER.
EYE CONTACT:
FOR RADIATION BURNS DUE TO ARC FLASH, SEE PHYSICIAN. TO REMOVE DUSTS
OR FUMES FLUSH WITH WATER FOR AT LEAST FIFTEEN MINUTES. IF IRRITATION
PERSISTS, OBTAIN MEDICAL ASSISTANCE.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
NOT APPLICABLE
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
NOT APPLICABLE
OTHER:
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
NO SPECIFIC RECOMMENDATIONS FOR BRAZING CONSUMABLES. BRAZING SPARKS CAN
IGNITE COMBUSTIBLE AND FLAMMABLE MATERIALS. USE THE EXTINGUISHING MEDIA
RECOMMENDED FOR THE BURNING MATERIALS AND FIRE SITUATION. WEAR
SELF-CONTAINED BREATHING APPARATUS AS FUMES OR VAPORS MAY BE HARMFUL.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NOT APPLICABLE
5.3. ADVICE FOR FIREFIGHTERS: NOT APPLICABLE
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
WEAR RESPIRATORY PROTECTION. AVOID DUST FORMATION. AVOID BREATHING VAPORS,
MIST OR GAS.
ENSURE ADEQUATE VENTILATION.
EVACUATE PERSONNEL TO SAFE AREAS. AVOID BREATHING DUST.
USE RESPIRATOR OR AIR SUPPLIED RESPIRATOR WHEN BRAZING IN A CONFINED SPACE,
OR WHERE LOCAL EXHAUST OR VENTILATION IS NOT SUFFICIENT TO KEEP EXPOSURE
VALUES WITHIN SAFE LIMITS. USE SPECIAL CARE WHEN BRAZING PAINTED OR COATED
STEELS SINCE HAZARDOUS SUBSTANCES FROM THE COATING MAY BE EMITTED. WEAR
HAND, HEAD, EYES, EAR AND BODY PROTECTION LIKE WELDERS GLOVES, HELMET OR
FACE SHIELD WITH FILTER LENS, SAFETY BOOTS, APRON, ARM AND SHOULDER
PROTECTION. KEEP PROTECTIVE CLOTHING CLEAN AND DRY.
6.2. ENVIRONMENTAL PRECAUTIONS: REFER TO SECTION 13.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
NOT APPLICABLE
6.4. REFERENCE TO OTHER SECTIONS: NOT APPLICABLE
OTHER:
SOLID OBJECTS MAY BE PICKED UP AND PLACED INTO A CONTAINER. LIQUIDS OR
PASTES SHOULD BE SCOOPED UP AND PLACED INTO A CONTAINER. WEAR PROPER
PROTECTIVE EQUIPMENT WHILE HANDLING THESE MATERIALS. DO NOT DISCARD AS
REFUSE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PREVENTIVE HANDLING PRECAUTIONS:
HANDLE WITH CARE TO AVOID STINGS AND CUTS. WEAR GLOVES WHEN HANDLING
WELDING CONSUMABLES. AVOID EXPOSURE TO DUST. DO NOT INGEST. SOME
INDIVIDUALS CAN DEVELOP AN ALLERGIC REACTION TO CERTAIN MATERIALS.
RETAIN ALL WARNING AND IDENTITY LABELS.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
KEEP SEPARATE FROM CHEMICAL SUBSTANCES LIKE ACIDS AND STRONG BASES, WHICH
COULD CAUSE CHEMICAL REACTIONS. STORE IN COOL/WELL-VENTILATED PLACE.
7.3. SPECIFIC END USE(S): ARC WELDING
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
EXPOSURE LIMITS USE INDUSTRIAL HYGIENE MONITORING EQUIPMENT TO ENSURE THAT
EXPOSURE DOES NOT EXCEED APPLICABLE NATIONAL EXPOSURE LIMITS. THE FOLLOWING
LIMITS CAN BE USED AS GUIDANCE. UNLESS NOTED, ALL VALUES ARE FOR 8 HOUR
TIME WEIGHTED AVERAGES (TWA). FOR INFORMATION ABOUT WELDING FUME ANALYSIS
REFER TO SECTION 10.
NATIONAL OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT CAS NO. EC NO. EXPOSURE SHORT-TERM CEILING
LIMIT EXPOSURE EXPOSURE
MG/M3- LIMIT LIMIT
PPM MG/M3-PPM MG/M3-PPM
CARBON 7440-44-0 231-153-3
IRON 7439-89-6 231-096-4
MANGANESE 7439-96-5 231-105-1 5
NICKEL 7440-02-0 231-111-4 1
INGREDIENT REMARK SOURCE YEAR
CARBON NO PEL OSHA 2017
IRON NO PEL OSHA 2017
MANGANESE AS Mn OSHA 2017
NICKEL AS Ni OSHA 2017
8.2. EXPOSURE CONTROLS:
TECHNICAL PRECAUTION MEASURES:
ENSURE SUFFICIENT VENTILATION, LOCAL EXHAUST, OR BOTH. KEEP WORKING PLACE
AND PROTECTIVE CLOTHING CLEAN AND DRY. CHECK CONDITION OF PROTECTIVE
CLOTHING AND EQUIPMENT ON A REGULAR BASIS. TRAIN WELDERS TO AVOID
CONTACT WITH LIVE ELECTRICAL PARTS AND INSULATE CONDUCTIVE PARTS.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE: SOLID, NON-VOLATILE WITH VARYING COLOR
APPEARANCE, COLOUR: NOT APPLICABLE
APPEARANCE, PHYSICAL STATE: NOT APPLICABLE
AUTO-IGNITION TEMPERATURE: NOT APPLICABLE
DECOMPOSITION TEMPERATURE: NOT APPLICABLE
EVAPORATION RATE: NOT APPLICABLE
EXPLOSIVE PROPERTIES: NOT APPLICABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLASH POINT: NOT APPLICABLE
INITIAL BOILING POINT AND BOILING RANGE: NOT APPLICABLE
MELTING POINT: >1000 DEG. C/>1800 DEG. F
MELTING POINT / FREEZING POINT: NOT APPLICABLE
ODOUR: NOT APPLICABLE
ODOUR TRESHOLD: NOT APPLICABLE
OXIDISING PROPERTIES: NOT APPLICABLE
PARTITION COEFFICIENT:
N-OCTANOL / WATER: NOT APPLICABLE
PH VALUE: NOT APPLICABLE
RELATIVE DENSITY: NOT APPLICABLE
SOLUBILITY: NOT APPLICABLE
UPPER / LOWER FLAMMABILITY OR EXPLOSIVE LIMITS: NOT APPLICABLE
VAPOUR DENSITY: NOT APPLICABLE
VAPOUR PRESSURE: NOT APPLICABLE
VISCOSITY: NOT APPLICABLE
9.2. OTHER INFORMATION: NOT APPLICABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
REACTIVITY:
CONTACT WITH CHEMICAL SUBSTANCES LIKE ACIDS OR STRONG BASES COULD CAUSE
GENERATION OF GAS.
10.2. CHEMICAL STABILITY:
CHEMICAL STABILITY: THIS PRODUCT IS STABLE UNDER NORMAL CONDITIONS.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NOT APPLICABLE
10.4. CONDITIONS TO AVOID: NOT APPLICABLE
10.5. INCOMPATIBLE MATERIALS: NOT APPLICABLE
10.6. HAZARDOUS DECOMPOSITION PRODUCTS: NOT APPLICABLE
OTHER:
THIS PRODUCTS IS ONLY INTENDED FOR NORMAL BRAZING AND WELDING PURPOSES
WHEN THESE PRODUCTS ARE USED IN A BRAZING AND WELDING PROCESS, HAZARDOUS
DECOMPOSITION PRODUCTS WOULD INCLUDE THOSE FROM THE VOLATILIZATION,
REACTION OR OXIDATION OF THE MATERIALS LISTED IN SECTION 3 AND THOSE
FROM THE BRAZING AND WELDING CONSUMABLES, THE BASE METAL AND COATING.
REFER TO APPLICABLE NATIONAL EXPOSURE LIMITS FOR FUME COMPOUNDS, INCLUDING
THOSE EXPOSURE LIMITS FOR FUME COMPOUNDS FOUND IN SECTION 8.
MANGANESE AND NICKEL ALSO HAVE LOW EXPOSURE LIMITS, IN SOME COUNTRIES,
THAT MAY BE EASILY EXCEEDED.
REASONABLY EXPECTED GASEOUS PRODUCTS WOULD INCLUDE CARBON OXIDES, NITROGEN
OXIDES AND OZONE. AIR CONTAMINANTS AROUND THE WELDING AREA CAN BE AFFECTED
BY THE WELDING PROCESS AND INFLUENCE THE COMPOSITION AND QUANTITY OF FUMES
AND GASES PRODUCED.
FUMES FROM THESE PRODUCTS MAY CONTAIN COMPOUNDS OF THE FOLLOWING CHEMICAL
ELEMENTS:
Fe, O, C, Mn, Si, Ni. THE REST IS NOT ANALYZED, ACCORDING TO AVAILABLE
STANDARDS.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
INFORMATION ON TOXICOLOGICAL EFFECTS:
INHALATION OF SOLDERING FUMES AND GASES CAN BE DANGEROUS TO YOUR HEALTH.
CLASSIFICATION OF SOLDERING FUMES IS DIFFICULT BECAUSE OF VARYING BASE
MATERIALS, COATINGS, AIR CONTAMINATION AND PROCESSES. THE INTERNATIONAL
AGENCY FOR RESEARCH ON CANCER HAS CLASSIFIED WELDING FUMES AS POSSIBLY
CARCINOGENIC TO HUMANS (GROUP 2B).
ACUTE TOXICITY:
OVEREXPOSURE TO SOLDERING FUMES MAY RESULT IN SYMPTOMS LIKE METAL FUME
FEVER, DIZZINESS, NAUSEA, DRYNESS OR IRRITATION OF THE NOSE, THROAT OR
EYES.
SKIN CORROSION/IRRITATION: NO DATA AVAILABLE
SERIOUS EYE DAMAGE/IRRITATION: NO DATA AVAILABLE
RESPIRATORY/SKIN SENSITIZATION: NO DATA AVAILABLE
GERM CELL MUTAGENICITY: NO DATA AVAILABLE
GENOTOXICITY: NO DATA AVAILABLE
CARCINOGENICITY:
THIS PRODUCT CONTAINS OR PRODUCES A CHEMICAL KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER AND BIRTH DEFECTS (OR OTHER REPRODUCTIVE
HARM). (CALIFORNIA HEALTH & SAFETY CODE SUBSECTION 25249.5 ET SEQ.)
REPEATED DOSE TOXICITY: NO DATA AVAILABLE
REPRODUCTIVE TOXICITY: NO DATA AVAILABLE
STOT-SINGLE EXPOSURE: NO DATA AVAILABLE
STOT-REPEATED EXPOSURE: NO DATA AVAILABLE
ASPIRATION HAZARD: NO DATA AVAILABLE
LD50 ORAL: NO DATA AVAILABLE
LD50 DERMAL: NO DATA AVAILABLE
LC50 INHALATION: NO DATA AVAILABLE
OTHER:
LONG TERM EFFECT:
OVEREXPOSURE TO WELDING FUMES MAY RESULT IN SYMPTOMS LIKE METAL FUME FEVER,
DIZZINESS, NAUSEA, DRYNESS OR IRRITATION OF THE NOSE, THROAT OR EYES.
CHRONIC OVEREXPOSURE TO WELDING FUMES MAY AFFECT PULMONARY FUNCTION.
PROLONGED INHALATION OF NICKEL COMPOUNDS ABOVE SAFE EXPOSURE LIMITS CAN
CAUSE CANCER. OVEREXPOSURE TO MANGANESE AND MANGANESE COMPOUNDS ABOVE
SAFE EXPOSURE LIMITS CAN CAUSE IRREVERSIBLE DAMAGE TO THE CENTRAL NERVOUS
SYSTEM, INCLUDING THE BRAIN, SYMPTOMS OF WHICH MAY INCLUDE SLURRED SPEECH,
LETHARGY, TREMOR, MUSCULAR WEAKNESS, PSYCHOLOGICAL DISTURBANCES AND SPASTIC
GAIT.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ACUTE TOXICITY: NO DATA AVAILABLE
TOXICITY: NO DATA AVAILABLE
AQUATIC: NO DATA AVAILABLE
SOIL: NO DATA AVAILABLE
ACUTE FISH TOXICITY: NO DATA AVAILABLE
ACUTE ALGAE TOXICITY: NO DATA AVAILABLE
ACUTE CRUSTACEAN TOXICITY: NO DATA AVAILABLE
CHRONICAL TOXICITY: NO DATA AVAILABLE
12.2. PERSISTENCE AND DEGRADABILITY:
PERSISTENCE AND DEGRADABILITY: NO DATA AVAILABLE
DECAY/TRANSFORMATION: NO DATA AVAILABLE
12.3. BIOACCUMULATIVE POTENTIAL:
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE
12.4. MOBILITY IN SOIL:
MOBILITY: NO DATA AVAILABLE
12.5. RESULTS OF PBT AND VPVB ASSESSMENT:
RESULTS OF PBT AND VPVB ASSESSMENT: NO DATA AVAILABLE
12.6. OTHER ADVERSE EFFECTS: NOT APPLICABLE
OTHER:
BRAZING CONSUMABLES AND MATERIALS COULD DEGRADE/WEATHER INTO COMPONENTS
ORIGINATING FROM THE CONSUMABLES OR FROM THE MATERIALS USED IN THE
BRAZING PROCESS. AVOID EXPOSURE TO CONDITIONS THAT COULD LEAD TO
ACCUMULATION IN SOILS OR GROUNDWATER.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
DISPOSAL CONSIDERATIONS:
DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER OR LINER IN AN
ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE WITH FEDERAL
AND LOCAL REGULATIONS. USE RECYCLING PROCEDURES IF AVAILABLE.
USA RCRA: THIS PRODUCT IS NOT CONSIDERED HAZARDOUS WASTE IF DISCARDED.
RESIDUES FROM BRAZING AND WELDING CONSUMABLES AND PROCESSES COULD DEGRADE
AND ACCUMULATE IN SOILS AND GROUNDWATER.
| SECTION 14: TRANSPORT INFORMATION | |
14.1. UN NUMBER: NOT APPLICABLE
14.2. UN PROPER SHIPPING NAME: NOT APPLICABLE
14.3. TRANSPORT HAZARD CLASS(ES): NOT APPLICABLE
14.4. PACKING GROUP: NOT APPLICABLE
14.5. ENVIRONMENTAL HAZARDS: NOT APPLICABLE
14.6. SPECIAL PRECAUTIONS FOR USER: NOT APPLICABLE
14.7. TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL AND THE IBC CODE:
NOT APPLICABLE
| SECTION 15: REGULATORY INFORMATION | |
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR
THE SUBSTANCE OR MIXTURE:
EU REGULATIONS:
REGULATION (EC) NO 1907/2006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
OF 18 DECEMBER 2006 CONCERNING THE REGISTRATION, EVALUATION, AUTHORISATION
AND RESTRICTION OF CHEMICALS (REACH), ESTABLISHING A EUROPEAN CHEMICALS
AGENCY, AMENDING DIRECTIVE 1999/45/EC AND REPEALING COUNCIL REGULATION
(EEC) NO 793/93 AND COMMISSION REGULATION (EC) NO 1488/94 AS WELL AS
COUNCIL DIRECTIVE 76/769/EEC AND COMMISSION DIRECTIVES 91/155/EEC,
93/67/EEC, 93/105/EC AND 2000/21/EC.
REGULATION (EC) NO 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
OF 16 DECEMBER 2008 ON CLASSIFICATION, LABELLING AND PACKAGING OF
SUBSTANCES AND MIXTURES, AMENDING AND REPEALING DIRECTIVES 67/548/EEC AND
1999/45/EC, AND AMENDING REGULATION (EC) NO 1907/2006 COMMISSION REGULATION
(EU) 2015/830 OF 28 MAY 2015 AMENDING REGULATION (EC) NO 1907/2006 OF THE
EUROPEAN PARLIAMENT AND THE COUNCIL CONCERNING THE REGISTRATION,
EVALUATION, AUTHORISATION AND RESTRICTION OF CHEMICALS (REACH)
DIRECTIVE 2008/98/EC OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL. OF 19
NOVEMBER 2008. ON WASTE AND REPEALING CERTAIN DIRECTIVES.
EUROPEAN PARLIAMENT AND COUNCIL DIRECTIVE 94/62/EC OF 20 DECEMBER 1994 ON
PACKAGING AND PACKAGING WASTE.
OTHER REGULATIONS, LIMITATIONS AND LEGAL REGULATIONS:
POLAND REGULATIONS:
ACT OF 25 FEBRUARY 2011 ON THE CHEMICAL SUBSTANCES AND THEIR
MIXTURES(OJ # 63, POZ. 322).
REGULATION OF THE MINISTER OF LABOUR AND SOCIAL POLICY OF 6 JUNE 2014 ON
MAXIMUM PERMISSIBLE CONCENTRATION AND INTENSITY OF AGENTS HARMFUL TO HEALTH
IN THE WORKING ENVIRONMENT (DZ. U. Z. 2014, POZ 817).
THE ACT ON WASTE OF 14 DECEMBER 2012, JOURNAL OF LAWS OF 2013, ITEM 21 WITH
AMENDMENTS
ACT OF 13TH JUNE 2013 ON PACKAGING MANAGEMENT AND PACKAGING WASTE (JOURNAL
OF LAWS OF 2013, ITEM 888).
REGULATION OF THE MINISTER OF THE ENVIRONMENT OF 9 DECEMBER 2014 ON WASTE
CATALOGUE (JOURNAL OF LAWS OF 2014, ITEM 1923).
REGULATION OF THE MINISTER OF ECONOMY OF 21 DECEMBER 2005. CONCERNING
ESSENTIAL REQUIREMENTS FOR PERSONAL PROTECTIVE EQUIPMENT (JOURNAL. LAWS
NO. 259, ITEM. 2173).
REGULATION OF THE MINISTER OF HEALTH OF 2 FEBRUARY 2011 ON TESTS AND
MEASUREMENTS OF FACTORS HARMFUL TO HEALTH IN THE WORKING ENVIRONMENT
(THE JOURNAL OF LAWS 2011, NO. 33, ITEM 166).
USA REGULATIONS:
USA:
THIS PRODUCT CONTAINS OR PRODUCES A CHEMICAL KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER AND BIRTH DEFECTS (OR OTHER REPRODUCTIVE
HARM). (CALIFORNIA HEALTH & SAFETY CODE SUBSECTION 25249.5 ET SEQ.)
CERCLA/SARA TITLE III REPORTABLE QUANTITIES (RQS) AND/OR THRESHOLD PLANNING
QUANTITIES (TPQS):
PRODUCT IS A SOLID SOLUTION IN THE FORM OF A SOLID ARTICLE. SPILLS OR
RELEASES RESULTING IN THE LOSS OF ANY INGREDIENT AT OR ABOVE ITS RQ
REQUIRE IMMEDIATE NOTIFICATION TO THE NATIONAL RESPONSE CENTER AND TO
YOUR LOCAL EMERGENCY PLANNING COMMITTEE.
EPCRA/SARA TITLE III 313 TOXIC CHEMICALS:
THE FOLLOWING METALLIC COMPONENTS ARE LISTED AS SARA 313 "TOXIC CHEMICALS"
AND POTENTIAL SUBJECT TO ANNUAL SARA 313 REPORTING. SEE SECTION 3 FOR
WEIGHT PERCENT.
NICKEL: 0.1% DE MINIMIS CONCENTRATION
MANGANESE: 1.0% DE MINIMIS CONCENTRATION
INTERNATIONAL INVENTORIES:
AUSTRALIA:
THE SUBSTANCE(S) IN THIS PRODUCT IS/ARE IN COMPLIANCE WITH THE INVENTORY
REQUIREMENTS OF AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES (AICS)
UNITED STATES EPA TOXIC SUBSTANCE CONTROL ACT:
ALL CONSTITUENTS OF THIS PRODUCT ARE ON THE TSCA INVENTORY LIST OR ARE
EXCLUDED FROM LISTING.
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA):
ALL CONSTITUENT(S) OF THIS PRODUCT IS/ARE ON THE DOMESTIC SUBSTANCE
LIST (DSL).
15.2. CHEMICAL SAFETY ASSESSMENT:
CHEMICAL SAFETY ASSESSMENT: NO DATA AVAILABLE
OTHER:
READ AND UNDERSTAND THE MANUFACTURER'S INSTRUCTIONS, YOUR EMPLOYER'S SAFETY
PRACTICES AND THE HEALTH AND SAFETY INSTRUCTIONS ON THE LABEL. OBSERVE ANY
FEDERAL AND LOCAL REGULATIONS. TAKE PRECAUTIONS WHEN WELDING AND PROTECT
YOURSELF AND OTHERS.
WARNING:
WELDING FUMES AND GASES ARE HAZARDOUS TO YOUR HEALTH AND MAY DAMAGE LUNGS
AND OTHER ORGANS. USE ADEQUATE VENTILATION. ELECTRIC SHOCK CAN KILL. ARC
RAYS AND SPARKS CAN INJURE EYES AND BURN SKIN.
WEAR CORRECT HAND, HEAD, EYE AND BODY PROTECTION.
| SECTION 16: OTHER INFORMATION | |
CHANGES TO PREVIOUS REVISION:
THIS SAFETY DATA SHEET HAS BEEN REVISED DUE TO MODIFICATIONS TO
SECTIONS 1-16.
REFERENCES TO KEY LITERATURE AND DATA SOURCES:
REFER TO ESAB "WELDING AND CUTTING - RISKS AND MEASURES", F52-529
"PRECAUTIONS AND SAFE PRACTICES FOR ELECTRIC WELDING AND CUTTING" AND
F2035 "PRECAUTIONS AND SAFE PRACTICES FOR GAS WELDING, CUTTING AND
HEATING" AVAILABLE FROM ESAB, AND TO: WWW.ESAB.COM
PHRASE MEANING:
CARC. 2: CARCINOGENICITY, HAZARD CATEGORY 2
SKIN SENS. 1: SKIN SENSITISATION, HAZARD CATEGORY 1
STOT RE 1:
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE, HAZARD CATEGORY 1
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H351: SUSPECTED OF CAUSING CANCER.
H372: CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
OTHER:
ADDITIONAL INFORMATION:
USA:
CONTACT ESAB AT WWW.ESABNA.COM OR 1-800 ESAB-123 IF YOU HAVE ANY QUESTIONS
ABOUT THIS SDS.
AMERICAN NATIONAL STANDARD Z49.1 SAFETY IN WELDING AND CUTTING, ANSI/AWS
F1.5 METHODS FOR SAMPLING AND ANALYZING GASES FROM WELDING AND ALLIED
PROCESSES, ANSI/AWS F1.1 "METHOD FOR SAMPLING AIRBORNE PARTICLES GENERATED
BY WELDING AND ALLIED PROCESSES", AWSF3.2M/F3.2 "VENTILATION GUIDE FOR
WELD FUME", 550 NORTH LE JEUNE ROAD, MIAMI FLORIDA 33135. SAFETY AND HEALTH
FACT SHEETS AVAILABLE FROM AWS AT WWW.AWS.ORG.
OSHA PUBLICATION 2206 (29 C.F.R. 1910), U.S. GOVERNMENT PRINTING OFFICE,
SUPERINTENDENT OF DOCUMENTS, P.O. BOX 371954, PITTSBURGH, PA 15250-7954
AMERICAN CONFERENCE OF GOVERNMENTAL HYGIENISTS (ACGIH), THRESHOLD LIMIT
VALUES AND BIOLOGICAL EXPOSURE INDICES, 6500 GLENWAY AVE., CINCINNATI,
OHIO 45211, USA.
NFPA 51B "STANDARD FOR FIRE PREVENTION DURING WELDING, CUTTING AND OTHER
HOT WORK" PUBLISHED BY THE NATIONAL FIRE PROTECTION ASSOCIATION, 1
BATTERYMARCH PARK, QUINCY, MA 02169
UK:
WMA PUBLICATION 236 AND 237, "HAZARDS FROM WELDING FUME", "THE ARC WELDER
AT WORK, SOME GENERAL ASPECTS OF HEALTH AND SAFETY".
GERMANY:
ACCIDENT PREVENTION REGULATION BGV D1, "WELDING, CUTTING AND RELATED
PROCEDURES"
CANADA:
CSA STANDARD CAN/CSA-W117.2-01 "SAFETY IN WELDING, CUTTING, AND ALLIED
PROCESSES".
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
CPR AND THE SDS CONTAINS ALL OF THE INFORMATION REQUIRED BY THE CPR.
ESAB REQUESTS THE USERS OF THIS PRODUCT TO STUDY THIS SAFETY DATA SHEET
(SDS) AND BECOME AWARE OF PRODUCT HAZARDS AND SAFETY INFORMATION. TO
PROMOTE SAFE USE OF THIS PRODUCT A USER SHOULD:
NOTIFY ITS EMPLOYEES, AGENTS AND CONTRACTORS OF THE INFORMATION ON THIS
SDS AND ANY PRODUCT HAZARDS/SAFETY INFORMATION.FURNISH THIS SAME
INFORMATION TO EACH OF ITS CUSTOMERS FOR THE PRODUCTS
REQUEST SUCH CUSTOMERS TO NOTIFY EMPLOYEES AND CUSTOMERS FOR THE SAME
PRODUCT HAZARDS AND SAFETY INFORMATION.
THE INFORMATION HEREIN IS GIVEN IN GOOD FAITH AND BASED ON TECHNICAL DATA
THAT ESAB BELIEVES TO BE RELIABLE. SINCE THE CONDITIONS OF USE IS OUTSIDE
OUR CONTROL, WE ASSUME NO LIABILITY IN CONNECTION WITH ANY USE OF THIS
INFORMATION AND NO WARRANTY EXPRESSED OR IMPLIED IS GIVEN. CONTACT ESAB
FOR MORE INFORMATION.
ESAB(R*)
SAFETY DATA SHEET
THIS SAFETY DATA SHEET COMPLIES WITH ANNEX II OF 830/2015 AMENDING
EC NO. 1907/2006, CLP DIRECTIVE 1272/2008, ALSO IN ACCORDANCE WITH
ISO 11014-1 AND ANSI Z400.1
ALL-STATE NO. 4-60T
ISSUED: 2018-01-14
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE | |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
TRADE NAME: ALL-STATE NO. 4-60T
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES
ADVISED AGAINST:
USE: ARC WELDING
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
SDS CREATED BY: TDS TEAM
SUPPLIER: ESAB DENTON
STREET ADDRESS:
2800 AIRPORT ROAD
DENTON, TX 76207
TELEPHONE: 1-800-372-2123
EMAIL: SDSREQUEST@ESAB.COM
WEB SITE: WWW.ESAB.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY PHONE NUMBER: 1-800-372-2123
AVAILABLE OUTSIDE OFFICE HOURS: NO
OTHER:
AWS CLASSIFICATION: NONE
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
THE PRODUCT IS NOT CLASSIFIED
2.2. LABEL ELEMENTS: THE PRODUCT DO NOT REQUIRE LABELING
2.3. OTHER HAZARDS:
EMERGENCY OVERVIEW:
METAL WIRE OR RODS IN VARYING COLOURS. THIS PRODUCT IS NORMALLY NOT
CONSIDERED HAZARDOUS AS SHIPPED. GLOVES SHOULD BE WORN WHEN HANDLING
TO PREVENT CUTS AND ABRASIONS.
THIS PRODUCT CONTAINS NICKEL, WHICH IS CLASSIFIED AS TOXIC BY PROLONGED
INHALATION, A SKIN SENSITIZER AND A SUSPECT CARCINOGEN. IN THE FORM THAT
NICKEL IS PRESENT IN THIS PRODUCT IT DOES NOT CONTRIBUTE TO A HAZARD
CLASSIFICATION OF THE PRODUCT.
SKIN CONTACT IS NORMALLY NO HAZARD BUT SHOULD BE AVOIDED TO PREVENT
POSSIBLE ALLERGIC REACTIONS.
PERSONS WITH A PACEMAKER SHOULD NOT GO NEAR WELDING OR CUTTING OPERATIONS
UNTIL THEY HAVE CONSULTED THEIR DOCTOR AND OBTAINED INFORMATION FROM THE
MANUFACTURER OF THE DEVICE.
WHEN THIS PRODUCT IS USED IN A WELDING PROCESS, THE MOST IMPORTANT HAZARDS
ARE WELDING FUMES, HEAT, RADIATION AND ELECTRIC SHOCK.
HEAT: SPATTER AND MELTING METAL CAN CAUSE BURN INJURIES AND START FIRES.
RADIATION: ARC RAYS CAN SEVERELY DAMAGE EYES OR SKIN.
FUMES:
OVEREXPOSURE TO WELDING FUMES MAY RESULT IN SYMPTOMS LIKE METAL FUME FEVER,
DIZZINESS, NAUSEA, DRYNESS OR IRRITATION OF THE NOSE, THROAT OR EYES.
CHRONIC OVEREXPOSURE TO WELDING FUMES MAY AFFECT PULMONARY FUNCTION.
PROLONGED INHALATION OF NICKEL COMPOUNDS ABOVE SAFE EXPOSURE LIMITS CAN
CAUSE CANCER. OVEREXPOSURE TO MANGANESE AND MANGANESE COMPOUNDS ABOVE SAFE
EXPOSURE LIMITS CAN CAUSE IRREVERSIBLE DAMAGE TO THE CENTRAL NERVOUS
SYSTEM, INCLUDING THE BRAIN, SYMPTOMS OF WHICH MAY INCLUDE SLURRED SPEECH,
LETHARGY, TREMOR, MUSCULAR WEAKNESS, PSYCHOLOGICAL DISTURBANCES AND SPASTIC
GAIT.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.2. MIXTURES:
CHEMICAL NAME CAS NO. CONCENTRATION CLASSIFICATION R-PHRASE
EC NO. H-PHRASE
REACH NO.
NICKEL 7440-02-0 55 - 56% CARC. 2, SKIN H317,
231-111-4 SENS. 1, STOT H351,
RE 1 H372
IRON 7439-89-6 43 - 44%
231-096-4
REGISTERED
MANGANESE 7439-96-5 <0,25%
231-105-1
SILICON 7440-21-3 <0,15%
231-130-8
CARBON 7440-44-0 <0,05%
231-153-3
PRODUCT BASED ON:
THIS PRODUCT IS CONTINUOUS METAL WIRES AND SOLID METAL RODS.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
ELECTRIC SHOCK:
DISCONNECT AND TURN OFF THE POWER. USE A NONCONDUCTIVE MATERIAL TO PULL
VICTIM AWAY FROM CONTACT WITH LIVE PARTS OR WIRES. IF NOT BREATHING,
BEGIN ARTIFICIAL RESPIRATION, PREFERABLY MOUTH-TO-MOUTH. IF NO DETECTABLE
PULSE, BEGIN CPR CALL A PHYSICIAN IMMEDIATELY.
INHALATION:
IF BREATHING HAS STOPPED, PERFORM ARTIFICIAL RESPIRATION AND OBTAIN MEDICAL
ASSISTANCE IMMEDIATELY! IF BREATHING IS DIFFICULT, PROVIDE FRESH AIR AND
CALL PHYSICIAN.
SKIN CONTACT:
FOR SKIN BURNS FROM ARC RADIATION, PROMPTLY FLUSH WITH COLD WATER. GET
MEDICAL ATTENTION FOR BURNS OR IRRITATIONS THAT PERSIST. TO REMOVE DUST
OR PARTICLES WASH WITH MILD SOAP AND WATER.
EYE CONTACT:
FOR RADIATION BURNS DUE TO ARC FLASH, SEE PHYSICIAN. TO REMOVE DUSTS OR
FUMES FLUSH WITH WATER FOR AT LEAST FIFTEEN MINUTES. IF IRRITATION
PERSISTS, OBTAIN MEDICAL ASSISTANCE.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
NOT APPLICABLE
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
NOT APPLICABLE
OTHER:
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
NO SPECIFIC RECOMMENDATIONS FOR BRAZING CONSUMABLES. BRAZING SPARKS CAN
IGNITE COMBUSTIBLE AND FLAMMABLE MATERIALS. USE THE EXTINGUISHING MEDIA
RECOMMENDED FOR THE BURNING MATERIALS AND FIRE SITUATION. WEAR
SELF-CONTAINED BREATHING APPARATUS AS FUMES OR VAPORS MAY BE HARMFUL.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NOT APPLICABLE
5.3. ADVICE FOR FIREFIGHTERS: NOT APPLICABLE
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
WEAR RESPIRATORY PROTECTION. AVOID DUST FORMATION. AVOID BREATHING VAPORS,
MIST OR GAS.
ENSURE ADEQUATE VENTILATION.
EVACUATE PERSONNEL TO SAFE AREAS. AVOID BREATHING DUST.
USE RESPIRATOR OR AIR SUPPLIED RESPIRATOR WHEN BRAZING IN A CONFINED SPACE,
OR WHERE LOCAL EXHAUST OR VENTILATION IS NOT SUFFICIENT TO KEEP EXPOSURE
VALUES WITHIN SAFE LIMITS. USE SPECIAL CARE WHEN BRAZING PAINTED OR COATED
STEELS SINCE HAZARDOUS SUBSTANCES FROM THE COATING MAY BE EMITTED. WEAR
HAND, HEAD, EYES, EAR AND BODY PROTECTION LIKE WELDERS GLOVES, HELMET OR
FACE SHIELD WITH FILTER LENS, SAFETY BOOTS, APRON, ARM AND SHOULDER
PROTECTION. KEEP PROTECTIVE CLOTHING CLEAN AND DRY.
6.2. ENVIRONMENTAL PRECAUTIONS: REFER TO SECTION 13.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
NOT APPLICABLE
6.4. REFERENCE TO OTHER SECTIONS: NOT APPLICABLE
OTHER:
SOLID OBJECTS MAY BE PICKED UP AND PLACED INTO A CONTAINER. LIQUIDS OR
PASTES SHOULD BE SCOOPED UP AND PLACED INTO A CONTAINER. WEAR PROPER
PROTECTIVE EQUIPMENT WHILE HANDLING THESE MATERIALS. DO NOT DISCARD AS
REFUSE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PREVENTIVE HANDLING PRECAUTIONS:
HANDLE WITH CARE TO AVOID STINGS AND CUTS. WEAR GLOVES WHEN HANDLING
WELDING CONSUMABLES. AVOID EXPOSURE TO DUST. DO NOT INGEST. SOME
INDIVIDUALS CAN DEVELOP AN ALLERGIC REACTION TO CERTAIN MATERIALS.
RETAIN ALL WARNING AND IDENTITY LABELS.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
KEEP SEPARATE FROM CHEMICAL SUBSTANCES LIKE ACIDS AND STRONG BASES,
WHICH COULD CAUSE CHEMICAL REACTIONS. STORE IN COOL/WELL-VENTILATED
PLACE.
7.3. SPECIFIC END USE(S): ARC WELDING
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
EXPOSURE LIMITS:
USE INDUSTRIAL HYGIENE MONITORING EQUIPMENT TO ENSURE THAT EXPOSURE DOES
NOT EXCEED APPLICABLE NATIONAL EXPOSURE LIMITS. THE FOLLOWING LIMITS CAN
BE USED AS GUIDANCE. UNLESS NOTED, ALL VALUES ARE FOR 8 HOUR TIME WEIGHTED
AVERAGES (TWA). FOR INFORMATION ABOUT WELDING FUME ANALYSIS REFER TO
SECTION 10.
NATIONAL OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT CAS NO. EC NO. EXPOSURE SHORT-TERM CEILING
LIMIT EXPOSURE EXPOSURE
MG/M3-PPM LIMIT LIMIT
MG/M3-PPM MG/M3-PPM
CARBON 7440-44-0 231-153-3
IRON 7439-89-6 231-096-4
MANGANESE 7439-96-5 231-105-1 5
NICKEL 7440-02-0 231-111-4 1
SILICON 7440-21-3 231-130-8 15
SILICON 7440-21-3 231-130-8 5
INGREDIENT REMARK SOURCE YEAR
CARBON NO PEL OSHA 2017
IRON NO PEL OSHA 2017
MANGANESE AS Mn OSHA 2017
NICKEL AS Ni OSHA 2017
SILICON TOTAL DUST OSHA 2017
SILICON RESPIRABLE FRACTION OSHA 2017
8.2. EXPOSURE CONTROLS:
TECHNICAL PRECAUTION MEASURES:
ENSURE SUFFICIENT VENTILATION, LOCAL EXHAUST, OR BOTH. KEEP WORKING PLACE
AND PROTECTIVE CLOTHING CLEAN AND DRY. CHECK CONDITION OF PROTECTIVE
CLOTHING AND EQUIPMENT ON A REGULAR BASIS. TRAIN WELDERS TO AVOID
CONTACT WITH LIVE ELECTRICAL PARTS AND INSULATE CONDUCTIVE PARTS.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE: SOLID, NON-VOLATILE WITH VARYING COLOR
APPEARANCE, COLOUR: NOT APPLICABLE
APPEARANCE, PHYSICAL STATE: NOT APPLICABLE
AUTO-IGNITION TEMPERATURE: NOT APPLICABLE
DECOMPOSITION TEMPERATURE: NOT APPLICABLE
EVAPORATION RATE: NOT APPLICABLE
EXPLOSIVE PROPERTIES: NOT APPLICABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLASH POINT: NOT APPLICABLE
INITIAL BOILING POINT AND BOILING RANGE: NOT APPLICABLE
MELTING POINT: >1000 DEG. C/>1800 DEG. F
MELTING POINT / FREEZING POINT: NOT APPLICABLE
ODOUR: NOT APPLICABLE
ODOUR TRESHOLD: NOT APPLICABLE
OXIDISING PROPERTIES: NOT APPLICABLE
PARTITION COEFFICIENT:
N-OCTANOL / WATER: NOT APPLICABLE
PH VALUE: NOT APPLICABLE
RELATIVE DENSITY: NOT APPLICABLE
SOLUBILITY: NOT APPLICABLE
UPPER / LOWER FLAMMABILITY OR EXPLOSIVE LIMITS: NOT APPLICABLE
VAPOUR DENSITY: NOT APPLICABLE
VAPOUR PRESSURE: NOT APPLICABLE
VISCOSITY: NOT APPLICABLE
9.2. OTHER INFORMATION: NOT APPLICABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
REACTIVITY:
CONTACT WITH CHEMICAL SUBSTANCES LIKE ACIDS OR STRONG BASES COULD CAUSE
GENERATION OF GAS.
10.2. CHEMICAL STABILITY:
CHEMICAL STABILITY: THIS PRODUCT IS STABLE UNDER NORMAL CONDITIONS.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NOT APPLICABLE
10.4. CONDITIONS TO AVOID: NOT APPLICABLE
10.5. INCOMPATIBLE MATERIALS: NOT APPLICABLE
10.6. HAZARDOUS DECOMPOSITION PRODUCTS: NOT APPLICABLE
OTHER:
THIS PRODUCTS IS ONLY INTENDED FOR NORMAL BRAZING AND WELDING PURPOSES
WHEN THESE PRODUCTS ARE USED IN A BRAZING AND WELDING PROCESS, HAZARDOUS
DECOMPOSITION PRODUCTS WOULD INCLUDE THOSE FROM THE VOLATILIZATION,
REACTION OR OXIDATION OF THE MATERIALS LISTED IN SECTION 3 AND THOSE FROM
THE BRAZING AND WELDING CONSUMABLES, THE BASE METAL AND COATING.
REFER TO APPLICABLE NATIONAL EXPOSURE LIMITS FOR FUME COMPOUNDS, INCLUDING
THOSE EXPOSURE LIMITS FOR FUME COMPOUNDS FOUND IN SECTION 8.
MANGANESE AND NICKEL ALSO HAVE LOW EXPOSURE LIMITS, IN SOME COUNTRIES,
THAT MAY BE EASILY EXCEEDED.
REASONABLY EXPECTED GASEOUS PRODUCTS WOULD INCLUDE CARBON OXIDES, NITROGEN
OXIDES AND OZONE. AIR CONTAMINANTS AROUND THE WELDING AREA CAN BE AFFECTED
BY THE WELDING PROCESS AND INFLUENCE THE COMPOSITION AND QUANTITY OF FUMES
AND GASES PRODUCED.
FUMES FROM THESE PRODUCTS MAY CONTAIN COMPOUNDS OF THE FOLLOWING CHEMICAL
ELEMENTS:
Fe, O, C, Mn, Si, Ni. THE REST IS NOT ANALYZED, ACCORDING TO AVAILABLE
STANDARDS.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
INFORMATION ON TOXICOLOGICAL EFFECTS:
INHALATION OF SOLDERING FUMES AND GASES CAN BE DANGEROUS TO YOUR HEALTH.
CLASSIFICATION OF SOLDERING FUMES IS DIFFICULT BECAUSE OF VARYING BASE
MATERIALS, COATINGS, AIR CONTAMINATION AND PROCESSES. THE INTERNATIONAL
AGENCY FOR RESEARCH ON CANCER HAS CLASSIFIED WELDING FUMES AS POSSIBLY
CARCINOGENIC TO HUMANS (GROUP 2B).
ACUTE TOXICITY:
OVEREXPOSURE TO SOLDERING FUMES MAY RESULT IN SYMPTOMS LIKE METAL FUME
FEVER, DIZZINESS, NAUSEA, DRYNESS OR IRRITATION OF THE NOSE, THROAT OR
EYES.
SKIN CORROSION/IRRITATION: NO DATA AVAILABLE
SERIOUS EYE DAMAGE/IRRITATION: NO DATA AVAILABLE
RESPIRATORY/SKIN SENSITIZATION: NO DATA AVAILABLE
GERM CELL MUTAGENICITY: NO DATA AVAILABLE
GENOTOXICITY: NO DATA AVAILABLE
CARCINOGENICITY:
THIS PRODUCT CONTAINS OR PRODUCES A CHEMICAL KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER AND BIRTH DEFECTS (OR OTHER REPRODUCTIVE
HARM). (CALIFORNIA HEALTH & SAFETY CODE SUBSECTION 25249.5 ET SEQ.)
REPEATED DOSE TOXICITY: NO DATA AVAILABLE
REPRODUCTIVE TOXICITY: NO DATA AVAILABLE
STOT-SINGLE EXPOSURE: NO DATA AVAILABLE
STOT-REPEATED EXPOSURE: NO DATA AVAILABLE
ASPIRATION HAZARD: NO DATA AVAILABLE
LD50 ORAL: NO DATA AVAILABLE
LD50 DERMAL: NO DATA AVAILABLE
LC50 INHALATION: NO DATA AVAILABLE
OTHER:
LONG TERM EFFECT:
OVEREXPOSURE TO WELDING FUMES MAY RESULT IN SYMPTOMS LIKE METAL FUME
FEVER, DIZZINESS, NAUSEA, DRYNESS OR IRRITATION OF THE NOSE, THROAT
OR EYES. CHRONIC OVEREXPOSURE TO WELDING FUMES MAY AFFECT PULMONARY
FUNCTION. PROLONGED INHALATION OF NICKEL COMPOUNDS ABOVE SAFE EXPOSURE
LIMITS CAN CAUSE CANCER. OVEREXPOSURE TO MANGANESE AND MANGANESE
COMPOUNDS ABOVE SAFE EXPOSURE LIMITS CAN CAUSE IRREVERSIBLE DAMAGE TO
THE CENTRAL NERVOUS SYSTEM, INCLUDING THE BRAIN, SYMPTOMS OF WHICH MAY
INCLUDE SLURRED SPEECH, LETHARGY, TREMOR, MUSCULAR WEAKNESS, PSYCHOLOGICAL
DISTURBANCES AND SPASTIC GAIT.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ACUTE TOXICITY: NO DATA AVAILABLE
TOXICITY: NO DATA AVAILABLE
AQUATIC: NO DATA AVAILABLE
SOIL: NO DATA AVAILABLE
ACUTE FISH TOXICITY: NO DATA AVAILABLE
ACUTE ALGAE TOXICITY: NO DATA AVAILABLE
ACUTE CRUSTACEAN TOXICITY: NO DATA AVAILABLE
CHRONICAL TOXICITY: NO DATA AVAILABLE
12.2. PERSISTENCE AND DEGRADABILITY:
PERSISTENCE AND DEGRADABILITY: NO DATA AVAILABLE
DECAY/TRANSFORMATION: NO DATA AVAILABLE
12.3. BIOACCUMULATIVE POTENTIAL:
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE
12.4. MOBILITY IN SOIL:
MOBILITY: NO DATA AVAILABLE
12.5. RESULTS OF PBT AND VPVB ASSESSMENT:
RESULTS OF PBT AND VPVB ASSESSMENT: NO DATA AVAILABLE
12.6. OTHER ADVERSE EFFECTS: NOT APPLICABLE
OTHER:
BRAZING CONSUMABLES AND MATERIALS COULD DEGRADE/WEATHER INTO COMPONENTS
ORIGINATING FROM THE CONSUMABLES OR FROM THE MATERIALS USED IN THE
BRAZING PROCESS. AVOID EXPOSURE TO CONDITIONS THAT COULD LEAD TO
ACCUMULATION IN SOILS OR GROUNDWATER.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
DISPOSAL CONSIDERATIONS:
DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER OR LINER IN AN
ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE WITH FEDERAL
AND LOCAL REGULATIONS. USE RECYCLING PROCEDURES IF AVAILABLE.
USA RCRA: THIS PRODUCT IS NOT CONSIDERED HAZARDOUS WASTE IF DISCARDED.
RESIDUES FROM BRAZING AND WELDING CONSUMABLES AND PROCESSES COULD DEGRADE
AND ACCUMULATE IN SOILS AND GROUNDWATER.
| SECTION 14: TRANSPORT INFORMATION | |
14.1. UN NUMBER: NOT APPLICABLE
14.2. UN PROPER SHIPPING NAME: NOT APPLICABLE
14.3. TRANSPORT HAZARD CLASS(ES): NOT APPLICABLE
14.4. PACKING GROUP: NOT APPLICABLE
14.5. ENVIRONMENTAL HAZARDS: NOT APPLICABLE
14.6. SPECIAL PRECAUTIONS FOR USER: NOT APPLICABLE
14.7. TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL AND THE IBC CODE:
NOT APPLICABLE
| SECTION 15: REGULATORY INFORMATION | |
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR
THE SUBSTANCE OR MIXTURE:
EU REGULATIONS:
REGULATION (EC) NO 1907/2006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
OF 18 DECEMBER 2006 CONCERNING THE REGISTRATION, EVALUATION, AUTHORISATION
AND RESTRICTION OF CHEMICALS (REACH), ESTABLISHING A EUROPEAN CHEMICALS
AGENCY, AMENDING DIRECTIVE 1999/45/EC AND REPEALING COUNCIL REGULATION
(EEC) NO 793/93 AND COMMISSION REGULATION (EC) NO 1488/94 AS WELL AS
COUNCIL DIRECTIVE 76/769/EEC AND COMMISSION DIRECTIVES 91/155/EEC,
93/67/EEC, 93/105/EC AND 2000/21/EC.
REGULATION (EC) NO 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
OF 16 DECEMBER 2008 ON CLASSIFICATION, LABELLING AND PACKAGING OF
SUBSTANCES AND MIXTURES, AMENDING AND REPEALING DIRECTIVES 67/548/EEC AND
1999/45/EC, AND AMENDING REGULATION (EC) NO 1907/2006
COMMISSION REGULATION (EU) 2015/830 OF 28 MAY 2015 AMENDING REGULATION (EC)
NO 1907/2006 OF THE EUROPEAN PARLIAMENT AND THE COUNCIL CONCERNING THE
REGISTRATION, EVALUATION, AUTHORISATION AND RESTRICTION OF CHEMICALS
(REACH)
DIRECTIVE 2008/98/EC OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL. OF 19
NOVEMBER 2008. ON WASTE AND REPEALING CERTAIN DIRECTIVES.
EUROPEAN PARLIAMENT AND COUNCIL DIRECTIVE 94/62/EC OF 20 DECEMBER 1994 ON
PACKAGING AND PACKAGING WASTE.
OTHER REGULATIONS, LIMITATIONS AND LEGAL REGULATIONS:
POLAND REGULATIONS:
ACT OF 25 FEBRUARY 2011 ON THE CHEMICAL SUBSTANCES AND THEIR
MIXTURES(OJ # 63, POZ. 322).
REGULATION OF THE MINISTER OF LABOUR AND SOCIAL POLICY OF 6 JUNE 2014 ON
MAXIMUM PERMISSIBLE CONCENTRATION AND INTENSITY OF AGENTS HARMFUL TO HEALTH
IN THE WORKING ENVIRONMENT (DZ. U. Z. 2014, POZ 817).
THE ACT ON WASTE OF 14 DECEMBER 2012, JOURNAL OF LAWS OF 2013, ITEM 21
WITH AMENDMENTS
ACT OF 13TH JUNE 2013 ON PACKAGING MANAGEMENT AND PACKAGING WASTE (JOURNAL
OF LAWS OF 2013, ITEM 888).
REGULATION OF THE MINISTER OF THE ENVIRONMENT OF 9 DECEMBER 2014 ON WASTE
CATALOGUE (JOURNAL OF LAWS OF 2014, ITEM 1923).
REGULATION OF THE MINISTER OF ECONOMY OF 21 DECEMBER 2005. CONCERNING
ESSENTIAL REQUIREMENTS FOR PERSONAL PROTECTIVE EQUIPMENT (JOURNAL. LAWS
NO. 259, ITEM. 2173).
REGULATION OF THE MINISTER OF HEALTH OF 2 FEBRUARY 2011 ON TESTS AND
MEASUREMENTS OF FACTORS HARMFUL TO HEALTH IN THE WORKING ENVIRONMENT
(THE JOURNAL OF LAWS 2011, NO. 33, ITEM 166).
USA REGULATIONS:
USA:
THIS PRODUCT CONTAINS OR PRODUCES A CHEMICAL KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER AND BIRTH DEFECTS (OR OTHER REPRODUCTIVE
HARM). (CALIFORNIA HEALTH & SAFETY CODE SUBSECTION 25249.5 ET SEQ.)
CERCLA/SARA TITLE III REPORTABLE QUANTITIES (RQS) AND/OR THRESHOLD PLANNING
QUANTITIES (TPQS):
PRODUCT IS A SOLID SOLUTION IN THE FORM OF A SOLID ARTICLE. SPILLS OR
RELEASES RESULTING IN THE LOSS OF ANY INGREDIENT AT OR ABOVE ITS RQ REQUIRE
IMMEDIATE NOTIFICATION TO THE NATIONAL RESPONSE CENTER AND TO YOUR LOCAL
EMERGENCY PLANNING COMMITTEE.
EPCRA/SARA TITLE III 313 TOXIC CHEMICALS:
THE FOLLOWING METALLIC COMPONENTS ARE LISTED AS SARA 313 "TOXIC CHEMICALS"
AND POTENTIAL SUBJECT TO ANNUAL SARA 313 REPORTING. SEE SECTION 3 FOR
WEIGHT PERCENT.
NICKEL: 0.1% DE MINIMIS CONCENTRATION
MANGANESE: 1.0% DE MINIMIS CONCENTRATION
INTERNATIONAL INVENTORIES:
AUSTRALIA:
THE SUBSTANCE(S) IN THIS PRODUCT IS/ARE IN COMPLIANCE WITH THE INVENTORY
REQUIREMENTS OF AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES (AICS)
UNITED STATES EPA TOXIC SUBSTANCE CONTROL ACT:
ALL CONSTITUENTS OF THIS PRODUCT ARE ON THE TSCA INVENTORY LIST OR ARE
EXCLUDED FROM LISTING.
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA):
ALL CONSTITUENT(S) OF THIS PRODUCT IS/ARE ON THE DOMESTIC SUBSTANCE
LIST (DSL).
15.2. CHEMICAL SAFETY ASSESSMENT:
CHEMICAL SAFETY ASSESSMENT: NO DATA AVAILABLE
OTHER:
READ AND UNDERSTAND THE MANUFACTURER'S INSTRUCTIONS, YOUR EMPLOYER'S SAFETY
PRACTICES AND THE HEALTH AND SAFETY INSTRUCTIONS ON THE LABEL. OBSERVE ANY
FEDERAL AND LOCAL REGULATIONS. TAKE PRECAUTIONS WHEN WELDING AND PROTECT
YOURSELF AND OTHERS.
WARNING:
WELDING FUMES AND GASES ARE HAZARDOUS TO YOUR HEALTH AND MAY DAMAGE LUNGS
AND OTHER ORGANS. USE ADEQUATE VENTILATION. ELECTRIC SHOCK CAN KILL. ARC
RAYS AND SPARKS CAN INJURE EYES AND BURN SKIN.
WEAR CORRECT HAND, HEAD, EYE AND BODY PROTECTION.
| SECTION 16: OTHER INFORMATION | |
CHANGES TO PREVIOUS REVISION:
THIS SAFETY DATA SHEET HAS BEEN REVISED DUE TO MODIFICATIONS TO
SECTIONS 1-16.
REFERENCES TO KEY LITERATURE AND DATA SOURCES:
REFER TO ESAB "WELDING AND CUTTING - RISKS AND MEASURES", F52-529
"PRECAUTIONS AND SAFE PRACTICES FOR ELECTRIC WELDING AND CUTTING" AND
F2035 "PRECAUTIONS AND SAFE PRACTICES FOR GAS WELDING, CUTTING AND
HEATING" AVAILABLE FROM ESAB, AND TO: WWW.ESAB.COM
PHRASE MEANING:
CARC. 2: CARCINOGENICITY, HAZARD CATEGORY 2
SKIN SENS. 1: SKIN SENSITISATION, HAZARD CATEGORY 1
STOT RE 1:
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE, HAZARD CATEGORY 1
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H351: SUSPECTED OF CAUSING CANCER.
H372: CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
OTHER:
ADDITIONAL INFORMATION:
USA:
CONTACT ESAB AT WWW.ESABNA.COM OR 1-800 ESAB-123 IF YOU HAVE ANY QUESTIONS
ABOUT THIS SDS. AMERICAN NATIONAL STANDARD Z49.1 SAFETY IN WELDING AND
CUTTING, ANSI/AWS F1.5 METHODS FOR SAMPLING AND ANALYZING GASES FROM
WELDING AND ALLIED PROCESSES, ANSI/AWS F1.1 "METHOD FOR SAMPLING AIRBORNE
PARTICLES GENERATED BY WELDING AND ALLIED PROCESSES", AWSF3.2M/F3.2
"VENTILATION GUIDE FOR WELD FUME", 550 NORTH LE JEUNE ROAD, MIAMI FLORIDA
33135. SAFETY AND HEALTH FACT SHEETS AVAILABLE FROM AWS AT WWW.AWS.ORG.
OSHA PUBLICATION 2206 (29 C.F.R. 1910), U.S. GOVERNMENT PRINTING OFFICE,
SUPERINTENDENT OF DOCUMENTS, P.O. BOX 371954, PITTSBURGH, PA 15250-7954
AMERICAN CONFERENCE OF GOVERNMENTAL HYGIENISTS (ACGIH), THRESHOLD LIMIT
VALUES AND BIOLOGICAL EXPOSURE INDICES, 6500 GLENWAY AVE., CINCINNATI,
OHIO 45211, USA.
NFPA 51B "STANDARD FOR FIRE PREVENTION DURING WELDING, CUTTING AND OTHER
HOT WORK" PUBLISHED BY THE NATIONAL FIRE PROTECTION ASSOCIATION, 1
BATTERYMARCH PARK, QUINCY, MA 02169
UK:
WMA PUBLICATION 236 AND 237, "HAZARDS FROM WELDING FUME", "THE ARC WELDER
AT WORK, SOME GENERAL ASPECTS OF HEALTH AND SAFETY".
GERMANY:
ACCIDENT PREVENTION REGULATION BGV D1, "WELDING, CUTTING AND RELATED
PROCEDURES"
CANADA:
CSA STANDARD CAN/CSA-W117.2-01 "SAFETY IN WELDING, CUTTING, AND ALLIED
PROCESSES".
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
CPR AND THE SDS CONTAINS ALL OF THE INFORMATION REQUIRED BY THE CPR.
ESAB REQUESTS THE USERS OF THIS PRODUCT TO STUDY THIS SAFETY DATA SHEET
(SDS) AND BECOME AWARE OF PRODUCT HAZARDS AND SAFETY INFORMATION. TO
PROMOTE SAFE USE OF THIS PRODUCT A USER SHOULD:
NOTIFY ITS EMPLOYEES, AGENTS AND CONTRACTORS OF THE INFORMATION ON THIS
SDS AND ANY PRODUCT HAZARDS/SAFETY INFORMATION.FURNISH THIS SAME
INFORMATION TO EACH OF ITS CUSTOMERS FOR THE PRODUCTS
REQUEST SUCH CUSTOMERS TO NOTIFY EMPLOYEES AND CUSTOMERS FOR THE SAME
PRODUCT HAZARDS AND SAFETY INFORMATION.
THE INFORMATION HEREIN IS GIVEN IN GOOD FAITH AND BASED ON TECHNICAL DATA
THAT ESAB BELIEVES TO BE RELIABLE. SINCE THE CONDITIONS OF USE IS OUTSIDE
OUR CONTROL, WE ASSUME NO LIABILITY IN CONNECTION WITH ANY USE OF THIS
INFORMATION AND NO WARRANTY EXPRESSED OR IMPLIED IS GIVEN. CONTACT ESAB
FOR MORE INFORMATION.