| Common Name: | ALL-STATE LOW FUMING, ALL-STATE LOW FUMING BRONZE FLUX COATED, ALL-STATE 41FC |
| Manufacturer: | ESAB |
| SDS Revision Date: | 1/14/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 400G78, 400G79, 400G80 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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ESAB(R*)
SAFETY DATA SHEET
THIS SAFETY DATA SHEET COMPLIES WITH ANNEX II OF 830/2015 AMENDING
EC NO. 1907/2006, CLP DIRECTIVE 1272/2008, ALSO IN ACCORDANCE WITH
ISO 11014-1 AND ANSI Z400.1
ALL-STATE LOW FUMING
ISSUED: 2018-01-14
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
TRADE NAME: ALL-STATE LOW FUMING
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE: COPPER BASED BRAZING ALLOYS
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
SDS CREATED BY: TDS TEAM
SUPPLIER: ESAB DENTON
STREET ADDRESS:
2800 AIRPORT ROAD
DENTON, TX 76207
TELEPHONE: 1-800-372-2123
EMAIL: SDSREQUEST@ESAB.COM
WEB SITE: WWW.ESAB.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY PHONE NUMBER: 1-800-372-2123
AVAILABLE OUTSIDE OFFICE HOURS: NO
OTHER:
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
THE PRODUCT IS NOT CLASSIFIED
2.2. LABEL ELEMENTS: THE PRODUCT DO NOT REQUIRE LABELING
2.3. OTHER HAZARDS:
AVOID EYE CONTACT OR INHALATION OF DUST FROM THE PRODUCT. SKIN CONTACT
IS NORMALLY NO HAZARD BUT SHOULD BE AVOIDED TO PREVENT POSSIBLE ALLERGIC
REACTIONS.
PERSONS WITH A PACEMAKER SHOULD NOT GO NEAR WELDING OR CUTTING OPERATIONS
UNTIL THEY HAVE CONSULTED THEIR DOCTOR AND OBTAINED INFORMATION FROM THE
MANUFACTURER OF THE DEVICE.
WHEN THIS PRODUCT IS USED IN A WELDING PROCESS, THE MOST IMPORTANT HAZARDS
ARE WELDING FUMES, HEAT, RADIATION AND ELECTRIC SHOCK.
FUMES:
OVEREXPOSURE TO WELDING FUMES MAY RESULT IN SYMPTOMS LIKE METAL FUME FEVER,
DIZZINESS, NAUSEA, DRYNESS OR IRRITATION OF THE NOSE, THROAT OR EYES.
CHRONIC OVEREXPOSURE TO WELDING FUMES MAY AFFECT PULMONARY FUNCTION.
OVEREXPOSURE TO MANGANESE AND MANGANESE COMPOUNDS ABOVE SAFE EXPOSURE
LIMITS CAN CAUSE IRREVERSIBLE DAMAGE TO THE CENTRAL NERVOUS SYSTEM,
INCLUDING THE BRAIN, SYMPTOMS OF WHICH MAY INCLUDE SLURRED SPEECH,
LETHARGY, TREMOR, MUSCULAR WEAKNESS,
HEAT: SPATTER AND MELTING METAL CAN CAUSE BURN INJURIES AND START FIRES.
RADIATION: ARC RAYS CAN SEVERELY DAMAGE EYES OR SKIN.
ELECTRICITY: ELECTRIC SHOCK CAN KILL.
OTHER:
EMERGENCY OVERVIEW:
COATED METAL RODS IN VARYING COLOURS. THIS PRODUCT IS NORMALLY NOT
CONSIDERED HAZARDOUS AS SHIPPED. GLOVES SHOULD BE WORN WHEN HANDLING
TO PREVENT CONTAMINATING HANDS WITH PRODUCT DUST.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.2. MIXTURES:
CHEMICAL NAME CAS NO. CONCENTRATION CLASSIFICATION R-PHRASE
EC NO. H-PHRASE
REACH NO.
COPPER 7440-50-8 56 - 62%
231-159-6
ZINC 7440-66-6 38 - 42%
231-175-3
TIN 7440-31-5 0,3 - 1,5%
231-141-8
IRON 7439-89-6 <1%
231-096-4
REGISTERED
MANGANESE 7439-96-5 <0,5%
231-105-1
SILICON 7440-21-3 <0,5%
231-130-8
PRODUCT BASED:
ON THIS PRODUCT IS A PREPARATION OF CORE WIRE WITH EXTRUDED COATING.
THE CORE WIRE TYPE IS MILD STEEL.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
ELECTRIC SHOCK:
DISCONNECT AND TURN OFF THE POWER. USE A NONCONDUCTIVE MATERIAL TO PULL
VICTIM AWAY FROM CONTACT WITH LIVE PARTS OR WIRES. IF NOT BREATHING, BEGIN
ARTIFICIAL RESPIRATION, PREFERABLY MOUTH-TO-MOUTH. IF NO DETECTABLE PULSE,
BEGIN CARDIO PULMONARY RESUSCITATION (CPR). CALL EMERGENCY PHYSICIAN TO THE
SCENE OF THE ACCIDENT. CALL A PHYSICIAN IMMEDIATELY.
INHALATION:
IF BREATHING HAS STOPPED, PERFORM ARTIFICIAL RESPIRATION AND OBTAIN MEDICAL
ASSISTANCE IMMEDIATELY! IF BREATHING IS DIFFICULT, PROVIDE FRESH AIR AND
CALL PHYSICIAN.
SKIN CONTACT:
FOR SKIN BURNS FROM ARC RADIATION, PROMPTLY FLUSH WITH COLD WATER. GET
MEDICAL ATTENTION FOR BURNS OR IRRITATIONS THAT PERSIST. TO REMOVE DUST
OR PARTICLES WASH WITH MILD SOAP AND WATER.
EYE CONTACT:
FOR RADIATION BURNS DUE TO ARC FLASH, SEE PHYSICIAN. TO REMOVE DUSTS
OR FUMES FLUSH WITH WATER FOR AT LEAST FIFTEEN MINUTES. IF IRRITATION
PERSISTS, OBTAIN MEDICAL ASSISTANCE.
INGESTION:
NOT A LIKELY ROUTE OF EXPOSURE. IF PRODUCT DUSTS ARE SWALLOWED, CALL A
PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. DO NOT INDUCE VOMITING
UNLESS DIRECTED TO DO SO BY A PHYSICIAN.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
NOT APPLICABLE
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
NOT APPLICABLE
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
NO SPECIFIC RECOMMENDATIONS FOR WELDING CONSUMABLES. WELDING ARCS AND
SPARKS CAN IGNITE COMBUSTIBLE AND FLAMMABLE MATERIALS. USE THE
EXTINGUISHING MEDIA RECOMMENDED FOR THE BURNING MATERIALS AND FIRE
SITUATION.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NOT APPLICABLE
5.3. ADVICE FOR FIREFIGHTERS:
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
WEAR SELF-CONTAINED BREATHING APPARATUS AS FUMES OR VAPORS MAY BE HARMFUL.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
WEAR HAND, HEAD, EYES, EAR AND BODY PROTECTION LIKE WELDERS GLOVES, HELMET
OR FACE SHIELD WITH FILTER LENS, SAFETY BOOTS, APRON, ARM AND SHOULDER
PROTECTION. KEEP PROTECTIVE CLOTHING CLEAN AND DRY.
6.2. ENVIRONMENTAL PRECAUTIONS: REFER TO SECTION 13.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
SOLID OBJECTS MAY BE PICKED UP AND PLACED INTO A CONTAINER. LIQUIDS OR
PASTES SHOULD BE SCOOPED UP AND PLACED INTO A CONTAINER. WEAR PROPER
PROTECTIVE EQUIPMENT WHILE HANDLING THESE MATERIALS. DO NOT DISCARD AS
REFUSE.
6.4. REFERENCE TO OTHER SECTIONS: REFER TO SECTION 8/13
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PREVENTIVE HANDLING PRECAUTIONS:
HANDLE WITH CARE TO AVOID STINGS AND CUTS. WEAR GLOVES WHEN HANDLING
WELDING CONSUMABLES. AVOID EXPOSURE TO DUST. DO NOT INGEST. SOME
INDIVIDUALS CAN DEVELOP AN ALLERGIC REACTION TO CERTAIN MATERIALS.
RETAIN ALL WARNING AND IDENTITY LABELS.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
KEEP SEPARATE FROM CHEMICAL SUBSTANCES LIKE ACIDS AND STRONG BASES, WHICH
COULD CAUSE CHEMICAL REACTIONS.
7.3. SPECIFIC END USE(S): ARC WELDING
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
EXPOSURE LIMITS:
USE INDUSTRIAL HYGIENE MONITORING EQUIPMENT TO ENSURE THAT EXPOSURE DOES
NOT EXCEED APPLICABLE NATIONAL EXPOSURE LIMITS. THE FOLLOWING LIMITS CAN
BE USED AS GUIDANCE. UNLESS NOTED, ALL VALUES ARE FOR 8 HOUR TIME WEIGHTED
AVERAGES (TWA). FOR INFORMATION ABOUT WELDING FUME ANALYSIS REFER TO
SECTION 10.
NATIONAL OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT CAS NO. EC NO. EXPOSURE SHORT-TERM CEILING
LIMIT EXPOSURE EXPOSURE
MG/M3-PPM LIMIT LIMIT
MG/M3-PPM MG/M3-PPM
IRON 7439-89-6 231-096-4
MANGANESE 7439-96-5 231-105-1 5
COPPER 7440-50-8 231-159-6 0,1
COPPER 7440-50-8 231-159-6 1
SILICON 7440-21-3 231-130-8 15
SILICON 7440-21-3 231-130-8 5
TIN 7440-31-5 231-141-8 2
ZINC 7440-66-6 231-175-3
INGREDIENT REMARK SOURCE YEAR
IRON NO PEL OSHA 2017
MANGANESE AS Mn OSHA 2017
COPPER AS Cu (FUME) OSHA 2017
COPPER AS Cu (DUST,MIST) OSHA 2017
SILICON TOTAL DUST OSHA 2017
SILICON RESPIRABLE FRACTION OSHA 2017
TIN METAL OSHA 2017
ZINC OSHA 2017
8.2. EXPOSURE CONTROLS: NOT APPLICABLE
OTHER:
AVOID EXPOSURE TO WELDING FUMES, RADIATION, SPATTER, ELECTRIC SHOCK,
HEATED MATERIALS AND DUST.
TRAIN WELDERS TO AVOID CONTACT WITH LIVE ELECTRICAL PARTS AND INSULATE
CONDUCTIVE PARTS.
VENTILATION:
ENSURE SUFFICIENT VENTILATION, LOCAL EXHAUST, OR BOTH, TO KEEP WELDING
FUMES AND GASES FROM BREATHING ZONE AND GENERAL AREA. USE SPECIAL CARE
WHEN WELDING PAINTED OR COATED STEELS SINCE HAZARDOUS SUBSTANCES FROM
THE COATING MAY BE EMITTED. USE RESPIRATOR OR AIR SUPPLIED RESPIRATOR
WHEN WELDING OR BRAZING IN A CONFINED SPACE, OR WHERE LOCAL EXHAUST OR
VENTILATION IS NOT SUFFICIENT TO KEEP EXPOSURE VALUES WITHIN SAFE LIMITS.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE: METAL RODS IN VARYING COLOR.
APPEARANCE, COLOUR: NOT APPLICABLE
APPEARANCE, PHYSICAL STATE: NOT APPLICABLE
AUTO-IGNITION TEMPERATURE: NOT APPLICABLE
BOILING POINT: 907 DEG. C/1665 DEG. F (ZINC)
DECOMPOSITION TEMPERATURE: NOT APPLICABLE
EVAPORATION RATE: NOT APPLICABLE
EXPLOSIVE PROPERTIES: NOT APPLICABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLASH POINT: NOT FLAMMABLE.
INITIAL BOILING POINT AND BOILING RANGE: NOT APPLICABLE
MELTING POINT: 1600-1900 DEG. C/871-1038 DEG. F (COPPER)
MELTING POINT / FREEZING POINT: NOT APPLICABLE
ODOUR: NOT APPLICABLE
ODOUR TRESHOLD: NOT APPLICABLE
OXIDISING PROPERTIES: NOT APPLICABLE
PARTITION COEFFICIENT:
N-OCTANOL / WATER: NOT APPLICABLE
PH VALUE: NOT APPLICABLE
RELATIVE DENSITY: NOT APPLICABLE
SOLUBILITY: NOT APPLICABLE
SPECIFIC GRAVITY: 8.3 - 8.5 (H2O = 1)
UPPER / LOWER FLAMMABILITY OR EXPLOSIVE LIMITS: NOT APPLICABLE
VAPOUR DENSITY: NOT APPLICABLE
VAPOUR PRESSURE: NOT APPLICABLE
VISCOSITY: NOT APPLICABLE
9.2. OTHER INFORMATION: NOT APPLICABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
REACTIVITY:
CONTACT WITH CHEMICAL SUBSTANCES LIKE ACIDS OR STRONG BASES COULD CAUSE
GENERATION OF GAS.
10.2. CHEMICAL STABILITY:
CHEMICAL STABILITY: STABLE AT NORMAL CONDITIONS
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NOT APPLICABLE
10.4. CONDITIONS TO AVOID:
CONDITIONS TO AVOID:
THIS PRODUCT IS ONLY INTENDED FOR NORMAL WELDING PURPOSES.
10.5. INCOMPATIBLE MATERIALS: NOT APPLICABLE
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
HAZARDOUS DECOMPOSITION PRODUCTS:
WHEN THESE PRODUCTS ARE USED IN A BRAZING OR SOLDERING PROCESS, HAZARDOUS
DECOMPOSITION PRODUCTS WOULD INCLUDE THOSE FROM THE VOLATILIZATION,
REACTION OR OXIDATION OF THE MATERIALS LISTED IN SECTION 3 AND THOSE FROM
THE BASE METAL AND COATING. FUMES FROM THESE PRODUCTS MAY CONTAIN COMPOUNDS
OF THE FOLLOWING CHEMICAL ELEMENTS:
B, Cu, Fe, O, Mn, Si, Sn AND Zn. THE REST IS NOT ANALYZED, ACCORDING TO
AVAILABLE STANDARDS.
OTHER:
REFER TO APPLICABLE NATIONAL EXPOSURE LIMITS FOR FUME COMPOUNDS, INCLUDING
THOSE EXPOSURE LIMITS FOR FUME COMPOUNDS FOUND IN SECTION 8. MANGANESE HAS
A LOW EXPOSURE LIMIT, IN SOME COUNTRIES, THAT MAY BE EASILY EXCEEDED.
REASONABLY EXPECTED GASEOUS PRODUCTS WOULD INCLUDE CARBON OXIDES, NITROGEN
OXIDES AND OZONE. AIR CONTAMINANTS AROUND THE WELDING AREA CAN BE AFFECTED
BY THE WELDING PROCESS AND INFLUENCE THE COMPOSITION AND QUANTITY OF FUMES
AND GASES PRODUCED.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
INFORMATION ON TOXICOLOGICAL EFFECTS INHALATION OF WELDING FUMES AND GASES
CAN BE DANGEROUS TO YOUR HEALTH. CLASSIFICATION OF WELDING FUMES IS
DIFFICULT BECAUSE OF VARYING BASE MATERIALS, COATINGS, AIR CONTAMINATION
AND PROCESSES. THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER HAS
CLASSIFIED WELDING FUMES AS POSSIBLY CARCINOGENIC TO HUMANS (GROUP 2B).
ACUTE TOXICITY:
OVEREXPOSURE TO WELDING FUMES MAY RESULT IN SYMPTOMS LIKE METAL FUME FEVER,
DIZZINESS, NAUSEA, DRYNESS OR IRRITATION OF THE NOSE, THROAT OR EYES.
SKIN CORROSION/IRRITATION: NO DATA AVAILABLE
SERIOUS EYE DAMAGE/IRRITATION: NO DATA AVAILABLE
RESPIRATORY/SKIN SENSITIZATION: NO DATA AVAILABLE
GERM CELL MUTAGENICITY: NO DATA AVAILABLE
GENOTOXICITY: NO DATA AVAILABLE
CARCINOGENICITY: NO DATA AVAILABLE
REPEATED DOSE TOXICITY: NO DATA AVAILABLE
REPRODUCTIVE TOXICITY: NO DATA AVAILABLE
STOT-SINGLE EXPOSURE: NO DATA AVAILABLE
STOT-REPEATED EXPOSURE: NO DATA AVAILABLE
ASPIRATION HAZARD: NO DATA AVAILABLE
LD50 ORAL: NO DATA AVAILABLE
LD50 DERMAL: NO DATA AVAILABLE
LC50 INHALATION: NO DATA AVAILABLE
ROUTES OF EXPOSURE: NO DATA AVAILABLE
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
NO DATA AVAILABLE
MIXTURE VERSUS SUBSTANCE INFORMATION: NO DATA AVAILABLE
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
NO DATA AVAILABLE
INTERACTIVE EFFECTS: NO DATA AVAILABLE
TOXICITY IN CASE OF SKIN CONTACT: NO DATA AVAILABLE
ABSENCE OF SPECIFIC DATA: NO DATA AVAILABLE
TOXICITY IN CASE OF EYE CONTACT: NO DATA AVAILABLE
MIXTURES: NO DATA AVAILABLE
TOXICITY IN CASE OF INGESTION: NO DATA AVAILABLE
OTHER:
ACUTE EFFECTS: NO DATA AVAILABLE
LONG TERM EFFECT:
CHRONIC TOXICITY:
OVEREXPOSURE TO WELDING FUMES MAY AFFECT PULMONARY FUNCTION. OVEREXPOSURE
TO MANGANESE AND MANGANESE COMPOUNDS ABOVE SAFE EXPOSURE LIMITS CAN CAUSE
IRREVERSIBLE DAMAGE TO THE CENTRAL NERVOUS SYSTEM, INCLUDING THE BRAIN,
SYMPTOMS OF WHICH MAY INCLUDE SLURRED SPEECH, LETHARGY, TREMOR, MUSCULAR
WEAKNESS, PSYCHOLOGICAL DISTURBANCES AND SPASTIC GAIT.
INFORMATION TO DOCTOR: NO DATA AVAILABLE
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ACUTE TOXICITY: NO DATA AVAILABLE
TOXICITY: NO DATA AVAILABLE
AQUATIC: NO DATA AVAILABLE
SOIL: NO DATA AVAILABLE
ACUTE FISH TOXICITY: NO DATA AVAILABLE
ACUTE ALGAE TOXICITY: NO DATA AVAILABLE
ACUTE CRUSTACEAN TOXICITY: NO DATA AVAILABLE
CHRONICAL TOXICITY: NO DATA AVAILABLE
12.2. PERSISTENCE AND DEGRADABILITY:
PERSISTENCE AND DEGRADABILITY: NO DATA AVAILABLE
DECAY/TRANSFORMATION: NO DATA AVAILABLE
12.3. BIOACCUMULATIVE POTENTIAL:
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE
12.4. MOBILITY IN SOIL:
MOBILITY: NO DATA AVAILABLE
12.5. RESULTS OF PBT AND VPVB ASSESSMENT:
RESULTS OF PBT AND VPVB ASSESSMENT: NO DATA AVAILABLE
12.6. OTHER ADVERSE EFFECTS:
OTHER ADVERSE EFFECTS: NO DATA AVAILABLE
OTHER:
WELDING CONSUMABLES AND MATERIALS COULD DEGRADE/WEATHER INTO COMPONENTS
ORIGINATING FROM THE CONSUMABLES OR FROM THE MATERIALS USED IN THE
WELDING PROCESS. AVOID EXPOSURE TO CONDITIONS THAT COULD LEAD TO
ACCUMULATION IN SOILS OR GROUNDWATER.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
DISPOSAL CONSIDERATIONS:
DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER OR LINER IN AN
ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE WITH FEDERAL
AND LOCAL REGULATIONS. USE RECYCLING PROCEDURES IF AVAILABLE.
USA RCRA: THIS PRODUCT IS NOT CONSIDERED HAZARDOUS WASTE IF DISCARDED.
RESIDUES FROM BRAZING CONSUMABLES AND PROCESSES COULD DEGRADE AND
ACCUMULATE IN SOILS AND GROUNDWATER. BRAZING RESIDUES FROM THESE
PRODUCTS TYPICALLY CONTAIN MAINLY THE FOLLOWING COMPONENTS:
B, Cu, Fe, O, Mn, Si, Sn, AND Zn.
| SECTION 14: TRANSPORT INFORMATION | |
14.1. UN NUMBER: NOT APPLICABLE
14.2. UN PROPER SHIPPING NAME: NOT APPLICABLE
14.3. TRANSPORT HAZARD CLASS(ES): NOT APPLICABLE
14.4. PACKING GROUP: NOT APPLICABLE
14.5. ENVIRONMENTAL HAZARDS: NOT APPLICABLE
14.6. SPECIAL PRECAUTIONS FOR USER: NOT APPLICABLE
14.7. TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL AND THE IBC CODE:
NOT APPLICABLE
| SECTION 15: REGULATORY INFORMATION | |
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR
THE SUBSTANCE OR MIXTURE:
EU REGULATIONS:
REGULATION (EC) NO 1907/2006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
OF 18 DECEMBER 2006 CONCERNING THE REGISTRATION, EVALUATION, AUTHORISATION
AND RESTRICTION OF CHEMICALS (REACH), ESTABLISHING A EUROPEAN CHEMICALS
AGENCY, AMENDING DIRECTIVE 1999/45/EC AND REPEALING COUNCIL REGULATION
(EEC) NO 793/93 AND COMMISSION REGULATION (EC) NO 1488/94 AS WELL AS
COUNCIL DIRECTIVE 76/769/EEC AND COMMISSION DIRECTIVES 91/155/EEC,
93/67/EEC, 93/105/EC AND 2000/21/EC.
REGULATION (EC) NO 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
OF 16 DECEMBER 2008 ON CLASSIFICATION, LABELLING AND PACKAGING OF
SUBSTANCES AND MIXTURES, AMENDING AND REPEALING DIRECTIVES 67/548/EEC AND
1999/45/EC, AND AMENDING REGULATION (EC) NO 1907/2006 COMMISSION
REGULATION (EU) 2015/830 OF 28 MAY 2015 AMENDING REGULATION (EC) NO
1907/2006 OF THE EUROPEAN PARLIAMENT AND THE COUNCIL CONCERNING THE
REGISTRATION, EVALUATION, AUTHORISATION AND RESTRICTION OF CHEMICALS
(REACH)
DIRECTIVE 2008/98/EC OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL. OF 19
NOVEMBER 2008. ON WASTE AND REPEALING CERTAIN DIRECTIVES.
EUROPEAN PARLIAMENT AND COUNCIL DIRECTIVE 94/62/EC OF 20 DECEMBER 1994 ON
PACKAGING AND PACKAGING WASTE.
OTHER REGULATIONS, LIMITATIONS AND LEGAL REGULATIONS:
POLAND REGULATIONS:
ACT OF 25 FEBRUARY 2011 ON THE CHEMICAL SUBSTANCES AND THEIR
MIXTURES(OJ # 63, POZ. 322).
REGULATION OF THE MINISTER OF LABOUR AND SOCIAL POLICY OF 6 JUNE 2014 ON
MAXIMUM PERMISSIBLE CONCENTRATION AND INTENSITY OF AGENTS HARMFUL TO HEALTH
IN THE WORKING ENVIRONMENT (DZ. U. Z. 2014, POZ 817).
THE ACT ON WASTE OF 14 DECEMBER 2012, JOURNAL OF LAWS OF 2013, ITEM 21 WITH
AMENDMENTS
ACT OF 13TH JUNE 2013 ON PACKAGING MANAGEMENT AND PACKAGING WASTE (JOURNAL
OF LAWS OF 2013, ITEM 888).
REGULATION OF THE MINISTER OF THE ENVIRONMENT OF 9 DECEMBER 2014 ON WASTE
CATALOGUE (JOURNAL OF LAWS OF 2014, ITEM 1923).
REGULATION OF THE MINISTER OF ECONOMY OF 21 DECEMBER 2005. CONCERNING
ESSENTIAL REQUIREMENTS FOR PERSONAL PROTECTIVE EQUIPMENT (JOURNAL.
LAWS NO. 259, ITEM. 2173).
REGULATION OF THE MINISTER OF HEALTH OF 2 FEBRUARY 2011 ON TESTS AND
MEASUREMENTS OF FACTORS HARMFUL TO HEALTH IN THE WORKING ENVIRONMENT
(THE JOURNAL OF LAWS 2011, NO. 33, ITEM 166).
USA REGULATIONS:
USA:
THIS PRODUCT CONTAINS OR PRODUCES A CHEMICAL KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER AND BIRTH DEFECTS (OR OTHER REPRODUCTIVE
HARM). (CALIFORNIA HEALTH & SAFETY CODE SUBSECTION 25249.5 ET SEQ.)
CERCLA/SARA TITLE III REPORTABLE QUANTITIES (RQS) AND/OR THRESHOLD
PLANNING QUANTITIES (TPQS):
PRODUCT IS A SOLID SOLUTION IN THE FORM OF A SOLID ARTICLE. SPILLS OR
RELEASES RESULTING IN THE LOSS OF ANY INGREDIENT AT OR ABOVE ITS RQ
REQUIRE IMMEDIATE NOTIFICATION TO THE NATIONAL RESPONSE CENTER AND TO
YOUR LOCAL EMERGENCY PLANNING COMMITTEE.
EPCRA/SARA TITLE III 313 TOXIC CHEMICALS:
THE FOLLOWING METALLIC COMPONENTS ARE LISTED AS SARA 313 "TOXIC CHEMICALS"
AND POTENTIAL SUBJECT TO ANNUAL SARA 313 REPORTING. SEE SECTION 3 FOR
WEIGHT PERCENT.
MANGANESE: 1.0% DE MINIMIS CONCENTRATION
CANADA:
WHMIS CLASSIFICATION: CLASS D; DIVISION 2, SUBDIVISION A
MANGANESE/1.0% DE MINIMIS CONCENTRATION
INTERNATIONAL INVENTORIES:
AUSTRALIA:
THE SUBSTANCE(S) IN THIS PRODUCT IS/ARE IN COMPLIANCE WITH THE INVENTORY
REQUIREMENTS OF AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES (AICS)
UNITED STATES EPA TOXIC SUBSTANCE CONTROL ACT:
ALL CONSTITUENTS OF THIS PRODUCT ARE ON THE TSCA INVENTORY LIST OR ARE
EXCLUDED FROM LISTING.
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA):
ALL CONSTITUENT(S) OF THIS PRODUCT IS/ARE ON THE DOMESTIC SUBSTANCE
LIST (DSL).
15.2. CHEMICAL SAFETY ASSESSMENT:
CHEMICAL SAFETY ASSESSMENT: NO DATA AVAILABLE
OTHER:
READ AND UNDERSTAND THE MANUFACTURER'S INSTRUCTIONS, YOUR EMPLOYER'S SAFETY
PRACTICES AND THE HEALTH AND SAFETY INSTRUCTIONS ON THE LABEL. OBSERVE ANY
FEDERAL AND LOCAL REGULATIONS. TAKE PRECAUTIONS WHEN WELDING AND PROTECT
YOURSELF AND OTHERS.
WARNING:
WELDING FUMES AND GASES ARE HAZARDOUS TO YOUR HEALTH AND MAY DAMAGE LUNGS
AND OTHER ORGANS. USE ADEQUATE VENTILATION. ELECTRIC SHOCK CAN KILL. ARC
RAYS AND SPARKS CAN INJURE EYES AND BURN SKIN.
WEAR CORRECT HAND, HEAD, EYE AND BODY PROTECTION.
| SECTION 16: OTHER INFORMATION | |
CHANGES TO PREVIOUS REVISION:
THIS SAFETY DATA SHEET HAS BEEN REVISED DUE TO MODIFICATIONS TO SECTIONS
1-16.
REFERENCES TO KEY LITERATURE AND DATA SOURCES:
REFER TO ESAB "WELDING AND CUTTING - RISKS AND MEASURES", F52-529
"PRECAUTIONS AND SAFE PRACTICES FOR ELECTRIC WELDING AND CUTTING" AND
F2035 "PRECAUTIONS AND SAFE PRACTICES FOR GAS WELDING, CUTTING AND
HEATING" AVAILABLE FROM ESAB, AND TO: WWW.ESAB.COM
OTHER:
ADDITIONAL INFORMATION:
USA:
CONTACT ESAB AT WWW.ESABNA.COM OR 1-800 ESAB-123 IF YOU HAVE ANY QUESTIONS
ABOUT THIS SDS. AMERICAN NATIONAL STANDARD Z49.1 SAFETY IN WELDING AND
CUTTING, ANSI/AWS F1.5 METHODS FOR SAMPLING AND ANALYZING GASES FROM
WELDING AND ALLIED PROCESSES, ANSI/AWS F1.1 "METHOD FOR SAMPLING AIRBORNE
PARTICLES GENERATED BY WELDING AND ALLIED PROCESSES", AWSF3.2M/F3.2
"VENTILATION GUIDE FOR WELD FUME", 550 NORTH LE JEUNE ROAD, MIAMI FLORIDA
33135. SAFETY AND HEALTH FACT SHEETS AVAILABLE FROM AWS AT WWW.AWS.ORG.
OSHA PUBLICATION 2206 (29 C.F.R. 1910), U.S. GOVERNMENT PRINTING OFFICE,
SUPERINTENDENT OF DOCUMENTS, P.O. BOX 371954, PITTSBURGH, PA 15250-7954
AMERICAN CONFERENCE OF GOVERNMENTAL HYGIENISTS (ACGIH), THRESHOLD LIMIT
VALUES AND BIOLOGICAL EXPOSURE INDICES, 6500 GLENWAY AVE., CINCINNATI,
OHIO 45211, USA.
NFPA 51B "STANDARD FOR FIRE PREVENTION DURING WELDING, CUTTING AND OTHER
HOT WORK" PUBLISHED BY THE NATIONAL FIRE PROTECTION ASSOCIATION, 1
BATTERYMARCH PARK, QUINCY, MA 02169
UK:
WMA PUBLICATION 236 AND 237, "HAZARDS FROM WELDING FUME", "THE ARC WELDER
AT WORK, SOME GENERAL ASPECTS OF HEALTH AND SAFETY".
GERMANY:
ACCIDENT PREVENTION REGULATION BGV D1, "WELDING, CUTTING AND RELATED
PROCEDURES"
CANADA:
CSA STANDARD CAN/CSA-W117.2-01 "SAFETY IN WELDING, CUTTING, AND ALLIED
PROCESSES".
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
CPR AND THE SDS CONTAINS ALL OF THE INFORMATION REQUIRED BY THE CPR.
ESAB REQUESTS THE USERS OF THIS PRODUCT TO STUDY THIS SAFETY DATA SHEET
(SDS) AND BECOME AWARE OF PRODUCT HAZARDS AND SAFETY INFORMATION. TO
PROMOTE SAFE USE OF THIS PRODUCT A USER SHOULD:
NOTIFY ITS EMPLOYEES, AGENTS AND CONTRACTORS OF THE INFORMATION ON THIS
SDS AND ANY PRODUCT HAZARDS/SAFETY INFORMATION.FURNISH THIS SAME
INFORMATION TO EACH OF ITS CUSTOMERS FOR THE PRODUCTS
REQUEST SUCH CUSTOMERS TO NOTIFY EMPLOYEES AND CUSTOMERS FOR THE SAME
PRODUCT HAZARDS AND SAFETY INFORMATION.
THE INFORMATION HEREIN IS GIVEN IN GOOD FAITH AND BASED ON TECHNICAL DATA
THAT ESAB BELIEVES TO BE RELIABLE. SINCE THE CONDITIONS OF USE IS OUTSIDE
OUR CONTROL, WE ASSUME NO LIABILITY IN CONNECTION WITH ANY USE OF THIS
INFORMATION AND NO WARRANTY EXPRESSED OR IMPLIED IS GIVEN. CONTACT ESAB
FOR MORE INFORMATION.
ESAB(R*)
SAFETY DATA SHEET
THIS SAFETY DATA SHEET COMPLIES WITH ANNEX II OF 830/2015 AMENDING
EC NO. 1907/2006, CLP DIRECTIVE 1272/2008, ALSO IN ACCORDANCE WITH
ISO 11014-1 AND ANSI Z400.1
ALL-STATE LOW FUMING BRONZE FLUX COATED
ISSUED: 2018-01-14
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE | |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
TRADE NAME: ALL-STATE LOW FUMING BRONZE FLUX COATED
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE: COPPER BASED BRAZING ALLOYS
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
SDS: CREATED BY TDS TEAM
SUPPLIER: ESAB DENTON
STREET ADDRESS:
2800 AIRPORT ROAD
DENTON, TX 76207
TELEPHONE: 1-800-372-2123
EMAIL: SDSREQUEST@ESAB.COM
WEB SITE: WWW.ESAB.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY PHONE NUMBER: 1-800-372-2123
AVAILABLE OUTSIDE OFFICE HOURS: NO
OTHER:
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
THE PRODUCT IS NOT CLASSIFIED
2.2. LABEL ELEMENTS: THE PRODUCT DO NOT REQUIRE LABELING
2.3. OTHER HAZARDS:
AVOID EYE CONTACT OR INHALATION OF DUST FROM THE PRODUCT. SKIN CONTACT
IS NORMALLY NO HAZARD BUT SHOULD BE AVOIDED TO PREVENT POSSIBLE ALLERGIC
REACTIONS.
PERSONS WITH A PACEMAKER SHOULD NOT GO NEAR WELDING OR CUTTING OPERATIONS
UNTIL THEY HAVE CONSULTED THEIR DOCTOR AND OBTAINED INFORMATION FROM THE
MANUFACTURER OF THE DEVICE.
WHEN THIS PRODUCT IS USED IN A WELDING PROCESS, THE MOST IMPORTANT HAZARDS
ARE WELDING FUMES, HEAT, RADIATION AND ELECTRIC SHOCK.
FUMES:
OVEREXPOSURE TO WELDING FUMES MAY RESULT IN SYMPTOMS LIKE METAL FUME FEVER,
DIZZINESS, NAUSEA, DRYNESS OR IRRITATION OF THE NOSE, THROAT OR EYES.
CHRONIC OVEREXPOSURE TO WELDING FUMES MAY AFFECT PULMONARY FUNCTION.
OVEREXPOSURE TO MANGANESE AND MANGANESE COMPOUNDS ABOVE SAFE EXPOSURE
LIMITS CAN CAUSE IRREVERSIBLE DAMAGE TO THE CENTRAL NERVOUS SYSTEM,
INCLUDING THE BRAIN, SYMPTOMS OF WHICH MAY INCLUDE SLURRED SPEECH,
LETHARGY, TREMOR, MUSCULAR WEAKNESS, PSYCHOLOGICAL DISTURBANCES AND SPASTIC
GAIT
HEAT: SPATTER AND MELTING METAL CAN CAUSE BURN INJURIES AND START FIRES.
RADIATION: ARC RAYS CAN SEVERELY DAMAGE EYES OR SKIN.
ELECTRICITY: ELECTRIC SHOCK CAN KILL.
OTHER:
EMERGENCY OVERVIEW:
COATED METAL RODS IN VARYING COLOURS. THIS PRODUCT IS NORMALLY NOT
CONSIDERED HAZARDOUS AS SHIPPED. GLOVES SHOULD BE WORN WHEN HANDLING
TO PREVENT CONTAMINATING HANDS WITH PRODUCT DUST.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.2. MIXTURES:
CHEMICAL NAME CAS NO. CONCENTRATION CLASSIFICATION R-PHRASE
EC NO. H-PHRASE
REACH NO.
COPPER 7440-50-8 55 - 58%
231-159-6
ZINC 7440-66-6 32 - 39%
231-175-3
BORIC ACID 10043-35-3 3 - 6% REPR. 1B H360FD
233-139-2
SODIUM 1330-43-4 0,5 - 2,5% REPR. 1B H360FD
TETRABORATE 215-540-4
TIN 7440-31-5 0,3 - 1,5%
231-141-8
IRON 7439-89-6 <1%
231-096-4
REGISTERED
METHACRYLATE/ PROPRIETARY <1%
ALIPHATIC &
NAPHTHENIC
HYDROCARBON
COMPOUND
SILICON 7440-21-3 <0,5%
231-130-8
MANGANESE 7439-96-5 <0,4%
231-105-1
PRODUCT BASED ON:
THIS PRODUCT IS A PREPARATION OF CORE WIRE WITH EXTRUDED COATING. THE CORE
WIRE TYPE IS MILD STEEL.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
ELECTRIC SHOCK:
DISCONNECT AND TURN OFF THE POWER. USE A NONCONDUCTIVE MATERIAL TO PULL
VICTIM AWAY FROM CONTACT WITH LIVE PARTS OR WIRES. IF NOT BREATHING, BEGIN
ARTIFICIAL RESPIRATION, PREFERABLY MOUTH-TO-MOUTH. IF NO DETECTABLE PULSE,
BEGIN CARDIO PULMONARY RESUSCITATION (CPR). CALL EMERGENCY PHYSICIAN TO THE
SCENE OF THE ACCIDENT. CALL A PHYSICIAN IMMEDIATELY.
INHALATION:
IF BREATHING HAS STOPPED, PERFORM ARTIFICIAL RESPIRATION AND OBTAIN MEDICAL
ASSISTANCE IMMEDIATELY! IF BREATHING IS DIFFICULT, PROVIDE FRESH AIR AND
CALL PHYSICIAN.
SKIN CONTACT:
FOR SKIN BURNS FROM ARC RADIATION, PROMPTLY FLUSH WITH COLD WATER. GET
MEDICAL ATTENTION FOR BURNS OR IRRITATIONS THAT PERSIST. TO REMOVE DUST
OR PARTICLES WASH WITH MILD SOAP AND WATER.
EYE CONTACT:
FOR RADIATION BURNS DUE TO ARC FLASH, SEE PHYSICIAN. TO REMOVE DUSTS
OR FUMES FLUSH WITH WATER FOR AT LEAST FIFTEEN MINUTES. IF IRRITATION
PERSISTS, OBTAIN MEDICAL ASSISTANCE.
INGESTION:
NOT A LIKELY ROUTE OF EXPOSURE. IF PRODUCT DUSTS ARE SWALLOWED, CALL A
PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. DO NOT INDUCE VOMITING
UNLESS DIRECTED TO DO SO BY A PHYSICIAN.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
NOT APPLICABLE
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
NOT APPLICABLE
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
NO SPECIFIC RECOMMENDATIONS FOR WELDING CONSUMABLES. WELDING ARCS AND
SPARKS CAN IGNITE COMBUSTIBLE AND FLAMMABLE MATERIALS. USE THE
EXTINGUISHING MEDIA RECOMMENDED FOR THE BURNING MATERIALS AND FIRE
SITUATION.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NOT APPLICABLE
5.3. ADVICE FOR FIREFIGHTERS:
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
WEAR SELF-CONTAINED BREATHING APPARATUS AS FUMES OR VAPORS MAY BE HARMFUL.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
WEAR HAND, HEAD, EYES, EAR AND BODY PROTECTION LIKE WELDERS GLOVES, HELMET
OR FACE SHIELD WITH FILTER LENS, SAFETY BOOTS, APRON, ARM AND SHOULDER
PROTECTION. KEEP PROTECTIVE CLOTHING CLEAN AND DRY.
6.2. ENVIRONMENTAL PRECAUTIONS: REFER TO SECTION 13.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
SOLID OBJECTS MAY BE PICKED UP AND PLACED INTO A CONTAINER. LIQUIDS OR
PASTES SHOULD BE SCOOPED UP AND PLACED INTO A CONTAINER. WEAR PROPER
PROTECTIVE EQUIPMENT WHILE HANDLING THESE MATERIALS. DO NOT DISCARD AS
REFUSE.
6.4. REFERENCE TO OTHER SECTIONS: REFER TO SECTION 8/13
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PREVENTIVE HANDLING PRECAUTIONS:
HANDLE WITH CARE TO AVOID STINGS AND CUTS. WEAR GLOVES WHEN HANDLING
WELDING CONSUMABLES. AVOID EXPOSURE TO DUST. DO NOT INGEST. SOME
INDIVIDUALS CAN DEVELOP AN ALLERGIC REACTION TO CERTAIN MATERIALS.
RETAIN ALL WARNING AND IDENTITY LABELS.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
KEEP SEPARATE FROM CHEMICAL SUBSTANCES LIKE ACIDS AND STRONG BASES, WHICH
COULD CAUSE CHEMICAL REACTIONS.
7.3. SPECIFIC END USE(S): ARC WELDING
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
EXPOSURE LIMITS:
USE INDUSTRIAL HYGIENE MONITORING EQUIPMENT TO ENSURE THAT EXPOSURE DOES
NOT EXCEED APPLICABLE NATIONAL EXPOSURE LIMITS. THE FOLLOWING LIMITS CAN
BE USED AS GUIDANCE. UNLESS NOTED, ALL VALUES ARE FOR 8 HOUR TIME WEIGHTED
AVERAGES (TWA). FOR INFORMATION ABOUT WELDING FUME ANALYSIS REFER TO
SECTION 10.
NATIONAL OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT CAS NO. EXPOSURE SHORT-TERM CEILING
EC NO. LIMIT EXPOSURE EXPOSURE
MG/M3-PPM LIMIT LIMIT
MG/M3-PPM MG/M3-PPM
IRON 7439-89-6
231-096-4
MANGANESE 7439-96-5 5
231-105-1
COPPER 7440-50-8 0,1
231-159-6
COPPER 7440-50-8 1
231-159-6
SILICON 7440-21-3 15
231-130-8
SILICON 7440-21-3 5
231-130-8
TIN 7440-31-5 2
231-141-8
ZINC 7440-66-6
231-175-3
SODIUM TETRABORATE 1330-43-4
215-540-4
BORIC ACID 10043-35-3
233-139-2
METHACRYLATE/ALIPHATIC PROPRIETARY
& NAPHTHENIC
HYDROCARBON COMPOUND
INGREDIENT REMARK SOURCE YEAR
IRON NO PEL OSHA 2017
MANGANESE AS Mn OSHA 2017
COPPER AS Cu (FUME) OSHA 2017
COPPER AS Cu (DUST,MIST) OSHA 2017
SILICON TOTAL DUST OSHA 2017
SILICON RESPIRABLE FRACTION OSHA 2017
TIN METAL OSHA 2017
ZINC OSHA 2017
SODIUM TETRABORATE OSHA 2017
BORIC ACID OSHA 2017
METHACRYLATE/ALIPHATIC & OSHA 2017
NAPHTHENIC HYDROCARBON
COMPOUND
8.2. EXPOSURE CONTROLS: NOT APPLICABLE
OTHER:
AVOID EXPOSURE TO WELDING FUMES, RADIATION, SPATTER, ELECTRIC SHOCK,
HEATED MATERIALS AND DUST.
TRAIN WELDERS TO AVOID CONTACT WITH LIVE ELECTRICAL PARTS AND INSULATE
CONDUCTIVE PARTS.
VENTILATION:
ENSURE SUFFICIENT VENTILATION, LOCAL EXHAUST, OR BOTH, TO KEEP WELDING
FUMES AND GASES FROM BREATHING ZONE AND GENERAL AREA. USE SPECIAL CARE
WHEN WELDING PAINTED OR COATED STEELS SINCE HAZARDOUS SUBSTANCES FROM
THE COATING MAY BE EMITTED. USE RESPIRATOR OR AIR SUPPLIED RESPIRATOR
WHEN WELDING OR BRAZING IN A CONFINED SPACE, OR WHERE LOCAL EXHAUST OR
VENTILATION IS NOT SUFFICIENT TO KEEP EXPOSURE VALUES WITHIN SAFE LIMITS.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
A) APPEARANCE: NOT APPLICABLE
B) ODOUR: NOT APPLICABLE
C) ODOUR TRESHOLD: NOT APPLICABLE
D) PH VALUE: NOT APPLICABLE
E) MELTING POINT / FREEZING POINT: NOT APPLICABLE
F) INITIAL BOILING POINT AND BOILING RANGE: NOT APPLICABLE
G) FLASH POINT: NOT FLAMMABLE.
H) EVAPORATION RATE: NOT APPLICABLE
I) FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
J) UPPER / LOWER FLAMMABILITY OR EXPLOSIVE LIMITS: NOT APPLICABLE
K) VAPOUR PRESSURE: NOT APPLICABLE
L) VAPOUR DENSITY: NOT APPLICABLE
M) RELATIVE DENSITY: NOT APPLICABLE
N) SOLUBILITY: NOT APPLICABLE
O) PARTITION COEFFICIENT:
N-OCTANOL / WATER: NOT APPLICABLE
P) AUTO-IGNITION TEMPERATURE: NOT APPLICABLE
Q) DECOMPOSITION TEMPERATURE: NOT APPLICABLE
R) VISCOSITY: NOT APPLICABLE
S) EXPLOSIVE PROPERTIES: NOT APPLICABLE
T) OXIDISING PROPERTIES: NOT APPLICABLE
BOILING POINT: 907 DEG. C/1665 DEG. F (ZINC)
SPECIFIC GRAVITY: 8.3 - 8.5 (H2O = 1)
MELTING POINT: 1600-1900 DEG. C/871-1038 DEG. F (COPPER)
APPEARANCE: METAL RODS IN VARYING COLOR.
9.2. OTHER INFORMATION: NOT APPLICABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
REACTIVITY:
CONTACT WITH CHEMICAL SUBSTANCES LIKE ACIDS OR STRONG BASES COULD CAUSE
GENERATION OF GAS.
10.2. CHEMICAL STABILITY:
CHEMICAL STABILITY: STABLE AT NORMAL CONDITIONS
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NOT APPLICABLE
10.4. CONDITIONS TO AVOID:
CONDITIONS TO AVOID:
THIS PRODUCT IS ONLY INTENDED FOR NORMAL WELDING PURPOSES.
10.5. INCOMPATIBLE MATERIALS: NOT APPLICABLE
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
HAZARDOUS DECOMPOSITION PRODUCTS:
WHEN THESE PRODUCTS ARE USED IN A BRAZING OR SOLDERING PROCESS, HAZARDOUS
DECOMPOSITION PRODUCTS WOULD INCLUDE THOSE FROM THE VOLATILIZATION,
REACTION OR OXIDATION OF THE MATERIALS LISTED IN SECTION 3 AND THOSE FROM
THE BASE METAL AND COATING. FUMES FROM THESE PRODUCTS MAY CONTAIN COMPOUNDS
OF THE FOLLOWING CHEMICAL ELEMENTS:
B, Cu, Fe, O, Mn, Si, Sn AND Zn. THE REST IS NOT ANALYZED, ACCORDING TO
AVAILABLE STANDARDS.
OTHER:
REFER TO APPLICABLE NATIONAL EXPOSURE LIMITS FOR FUME COMPOUNDS, INCLUDING
THOSE EXPOSURE LIMITS FOR FUME COMPOUNDS FOUND IN SECTION 8. MANGANESE HAS
A LOW EXPOSURE LIMIT, IN SOME COUNTRIES, THAT MAY BE EASILY EXCEEDED.
REASONABLY EXPECTED GASEOUS PRODUCTS WOULD INCLUDE CARBON OXIDES, NITROGEN
OXIDES AND OZONE. AIR CONTAMINANTS AROUND THE WELDING AREA CAN BE AFFECTED
BY THE WELDING PROCESS AND INFLUENCE THE COMPOSITION AND QUANTITY OF FUMES
AND GASES PRODUCED.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
INFORMATION ON TOXICOLOGICAL EFFECTS:
INHALATION OF WELDING FUMES AND GASES CAN BE DANGEROUS TO YOUR HEALTH.
CLASSIFICATION OF WELDING FUMES IS DIFFICULT BECAUSE OF VARYING BASE
MATERIALS, COATINGS, AIR CONTAMINATION AND PROCESSES. THE INTERNATIONAL
AGENCY FOR RESEARCH ON CANCER HAS CLASSIFIED WELDING FUMES AS POSSIBLY
CARCINOGENIC TO HUMANS (GROUP 2B).
ACUTE TOXICITY:
OVEREXPOSURE TO WELDING FUMES MAY RESULT IN SYMPTOMS LIKE METAL FUME FEVER,
DIZZINESS, NAUSEA, DRYNESS OR IRRITATION OF THE NOSE, THROAT OR EYES.
SKIN CORROSION/IRRITATION: NO DATA AVAILABLE
SERIOUS EYE DAMAGE/IRRITATION: NO DATA AVAILABLE
RESPIRATORY/SKIN SENSITIZATION: NO DATA AVAILABLE
GERM CELL MUTAGENICITY: NO DATA AVAILABLE
GENOTOXICITY: NO DATA AVAILABLE
CARCINOGENICITY: NO DATA AVAILABLE
REPEATED DOSE TOXICITY: NO DATA AVAILABLE
REPRODUCTIVE TOXICITY: NO DATA AVAILABLE
STOT-SINGLE EXPOSURE: NO DATA AVAILABLE
STOT-REPEATED EXPOSURE: NO DATA AVAILABLE
ASPIRATION HAZARD: NO DATA AVAILABLE
LD50 ORAL: NO DATA AVAILABLE
LD50 DERMAL: NO DATA AVAILABLE
LC50 INHALATION: NO DATA AVAILABLE
ROUTES OF EXPOSURE: NO DATA AVAILABLE
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
NO DATA AVAILABLE
MIXTURE VERSUS SUBSTANCE INFORMATION: NO DATA AVAILABLE
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT
AND LONG-TERM EXPOSURE:
NO DATA AVAILABLE
INTERACTIVE EFFECTS: NO DATA AVAILABLE
TOXICITY IN CASE OF SKIN CONTACT: NO DATA AVAILABLE
ABSENCE OF SPECIFIC DATA: NO DATA AVAILABLE
TOXICITY IN CASE OF EYE CONTACT: NO DATA AVAILABLE
MIXTURES: NO DATA AVAILABLE
TOXICITY IN CASE OF INGESTION: NO DATA AVAILABLE
OTHER:
ACUTE EFFECTS: NO DATA AVAILABLE
LONG TERM EFFECT:
CHRONIC TOXICITY:
OVEREXPOSURE TO WELDING FUMES MAY AFFECT PULMONARY FUNCTION. OVEREXPOSURE
TO MANGANESE AND MANGANESE COMPOUNDS ABOVE SAFE EXPOSURE LIMITS CAN CAUSE
IRREVERSIBLE DAMAGE TO THE CENTRAL NERVOUS SYSTEM, INCLUDING THE BRAIN,
SYMPTOMS OF WHICH MAY INCLUDE SLURRED SPEECH, LETHARGY, TREMOR, MUSCULAR
WEAKNESS, PSYCHOLOGICAL DISTURBANCES AND SPASTIC GAIT.
INFORMATION TO DOCTOR: NO DATA AVAILABLE
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ACUTE TOXICITY: NO DATA AVAILABLE
TOXICITY: NO DATA AVAILABLE
AQUATIC: NO DATA AVAILABLE
SOIL: NO DATA AVAILABLE
ACUTE FISH TOXICITY: NO DATA AVAILABLE
ACUTE ALGAE TOXICITY: NO DATA AVAILABLE
ACUTE CRUSTACEAN TOXICITY: NO DATA AVAILABLE
CHRONICAL TOXICITY: NO DATA AVAILABLE
12.2. PERSISTENCE AND DEGRADABILITY:
PERSISTENCE AND DEGRADABILITY: NO DATA AVAILABLE
DECAY/TRANSFORMATION: NO DATA AVAILABLE
12.3. BIOACCUMULATIVE POTENTIAL:
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE
12.4. MOBILITY IN SOIL:
MOBILITY: NO DATA AVAILABLE
12.5. RESULTS OF PBT AND VPVB ASSESSMENT:
RESULTS OF PBT AND VPVB ASSESSMENT: NO DATA AVAILABLE
12.6. OTHER ADVERSE EFFECTS:
OTHER ADVERSE EFFECTS: NO DATA AVAILABLE
OTHER:
WELDING CONSUMABLES AND MATERIALS COULD DEGRADE/WEATHER INTO COMPONENTS
ORIGINATING FROM THE CONSUMABLES OR FROM THE MATERIALS USED IN THE
WELDING PROCESS. AVOID EXPOSURE TO CONDITIONS THAT COULD LEAD TO
ACCUMULATION IN SOILS OR GROUNDWATER.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
DISPOSAL CONSIDERATIONS:
DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER OR LINER IN AN
ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE WITH FEDERAL
AND LOCAL REGULATIONS. USE RECYCLING PROCEDURES IF AVAILABLE.
USA RCRA:
THIS PRODUCT IS NOT CONSIDERED HAZARDOUS WASTE IF DISCARDED. RESIDUES FROM
BRAZING CONSUMABLES AND PROCESSES COULD DEGRADE AND ACCUMULATE IN SOILS AND
GROUNDWATER. BRAZING RESIDUES FROM THESE PRODUCTS TYPICALLY CONTAIN MAINLY
THE FOLLOWING COMPONENTS:
B, Cu, Fe, O, Mn, Si, Sn, AND Zn.
| SECTION 14: TRANSPORT INFORMATION | |
14.1. UN NUMBER: NOT APPLICABLE
14.2. UN PROPER SHIPPING NAME: NOT APPLICABLE
14.3. TRANSPORT HAZARD CLASS(ES): NOT APPLICABLE
14.4. PACKING GROUP: NOT APPLICABLE
14.5. ENVIRONMENTAL HAZARDS: NOT APPLICABLE
14.6. SPECIAL PRECAUTIONS FOR USER: NOT APPLICABLE
14.7. TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL AND THE IBC CODE:
NOT APPLICABLE
| SECTION 15: REGULATORY INFORMATION | |
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR
THE SUBSTANCE OR MIXTURE:
EU REGULATIONS:
REGULATION (EC) NO 1907/2006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
OF 18 DECEMBER 2006 CONCERNING THE REGISTRATION, EVALUATION, AUTHORISATION
AND RESTRICTION OF CHEMICALS (REACH), ESTABLISHING A EUROPEAN CHEMICALS
AGENCY, AMENDING DIRECTIVE 1999/45/EC AND REPEALING COUNCIL REGULATION
(EEC) NO 793/93 AND COMMISSION REGULATION (EC) NO 1488/94 AS WELL AS
COUNCIL DIRECTIVE 76/769/EEC AND COMMISSION DIRECTIVES 91/155/EEC,
93/67/EEC, 93/105/EC AND 2000/21/EC.
REGULATION (EC) NO 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
OF 16 DECEMBER 2008 ON CLASSIFICATION, LABELLING AND PACKAGING OF
SUBSTANCES AND MIXTURES, AMENDING AND REPEALING DIRECTIVES 67/548/EEC AND
1999/45/EC, AND AMENDING REGULATION (EC) NO 1907/2006
COMMISSION REGULATION (EU) 2015/830 OF 28 MAY 2015 AMENDING REGULATION (EC)
NO 1907/2006 OF THE EUROPEAN PARLIAMENT AND THE COUNCIL CONCERNING THE
REGISTRATION, EVALUATION, AUTHORISATION AND RESTRICTION OF CHEMICALS
(REACH)
DIRECTIVE 2008/98/EC OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL. OF 19
NOVEMBER 2008. ON WASTE AND REPEALING CERTAIN DIRECTIVES.
EUROPEAN PARLIAMENT AND COUNCIL DIRECTIVE 94/62/EC OF 20 DECEMBER 1994 ON
PACKAGING AND PACKAGING WASTE.
OTHER REGULATIONS, LIMITATIONS AND LEGAL REGULATIONS:
POLAND REGULATIONS:
ACT OF 25 FEBRUARY 2011 ON THE CHEMICAL SUBSTANCES AND THEIR
MIXTURES(OJ # 63, POZ. 322).
REGULATION OF THE MINISTER OF LABOUR AND SOCIAL POLICY OF 6 JUNE 2014 ON
MAXIMUM PERMISSIBLE CONCENTRATION AND INTENSITY OF AGENTS HARMFUL TO HEALTH
IN THE WORKING ENVIRONMENT (DZ. U. Z. 2014, POZ 817).
THE ACT ON WASTE OF 14 DECEMBER 2012, JOURNAL OF LAWS OF 2013, ITEM 21 WITH
AMENDMENTS
ACT OF 13TH JUNE 2013 ON PACKAGING MANAGEMENT AND PACKAGING WASTE (JOURNAL
OF LAWS OF 2013, ITEM 888).
REGULATION OF THE MINISTER OF THE ENVIRONMENT OF 9 DECEMBER 2014 ON WASTE
CATALOGUE (JOURNAL OF LAWS OF 2014, ITEM 1923).
REGULATION OF THE MINISTER OF ECONOMY OF 21 DECEMBER 2005. CONCERNING
ESSENTIAL REQUIREMENTS FOR PERSONAL PROTECTIVE EQUIPMENT (JOURNAL. LAWS
NO. 259, ITEM. 2173).
REGULATION OF THE MINISTER OF HEALTH OF 2 FEBRUARY 2011 ON TESTS AND
MEASUREMENTS OF FACTORS HARMFUL TO HEALTH IN THE WORKING ENVIRONMENT
(THE JOURNAL OF LAWS 2011, NO. 33, ITEM 166).
USA REGULATIONS:
USA:
THIS PRODUCT CONTAINS OR PRODUCES A CHEMICAL KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER AND BIRTH DEFECTS (OR OTHER REPRODUCTIVE
HARM). (CALIFORNIA HEALTH & SAFETY CODE SUBSECTION 25249.5 ET SEQ.)
CERCLA/SARA TITLE III REPORTABLE QUANTITIES (RQS) AND/OR THRESHOLD
PLANNING QUANTITIES (TPQS):
PRODUCT IS A SOLID SOLUTION IN THE FORM OF A SOLID ARTICLE. SPILLS OR
RELEASES RESULTING IN THE LOSS OF ANY INGREDIENT AT OR ABOVE ITS RQ
REQUIRE IMMEDIATE NOTIFICATION TO THE NATIONAL RESPONSE CENTER AND TO
YOUR LOCAL EMERGENCY PLANNING COMMITTEE.
EPCRA/SARA TITLE III 313 TOXIC CHEMICALS: THE FOLLOWING METALLIC COMPONENTS
ARE LISTED AS SARA 313 "TOXIC CHEMICALS" AND POTENTIAL SUBJECT TO ANNUAL
SARA 313 REPORTING. SEE SECTION 3 FOR WEIGHT PERCENT.
COPPER: 1.0% DE MINIMIS CONCENTRATION
ZINC: 1.0% DE MINIMIS CONCENTRATION
MANGANESE: 1.0% DE MINIMIS CONCENTRATION
INTERNATIONAL INVENTORIES:
AUSTRALIA:
THE SUBSTANCE(S) IN THIS PRODUCT IS/ARE IN COMPLIANCE WITH THE INVENTORY
REQUIREMENTS OF AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES (AICS)
UNITED STATES EPA TOXIC SUBSTANCE CONTROL ACT:
ALL CONSTITUENTS OF THIS PRODUCT ARE ON THE TSCA INVENTORY LIST OR ARE
EXCLUDED FROM LISTING.
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA):
ALL CONSTITUENT(S) OF THIS PRODUCT IS/ARE ON THE DOMESTIC SUBSTANCE
LIST (DSL).
15.2. CHEMICAL SAFETY ASSESSMENT:
CHEMICAL SAFETY ASSESSMENT: NO DATA AVAILABLE
OTHER:
READ AND UNDERSTAND THE MANUFACTURER'S INSTRUCTIONS, YOUR EMPLOYER'S SAFETY
PRACTICES AND THE HEALTH AND SAFETY INSTRUCTIONS ON THE LABEL. OBSERVE ANY
FEDERAL AND LOCAL REGULATIONS. TAKE PRECAUTIONS WHEN WELDING AND PROTECT
YOURSELF AND OTHERS.
WARNING:
WELDING FUMES AND GASES ARE HAZARDOUS TO YOUR HEALTH AND MAY DAMAGE LUNGS
AND OTHER ORGANS. USE ADEQUATE VENTILATION. ELECTRIC SHOCK CAN KILL. ARC
RAYS AND SPARKS CAN INJURE EYES AND BURN SKIN.
WEAR CORRECT HAND, HEAD, EYE AND BODY PROTECTION.
| SECTION 16: OTHER INFORMATION | |
CHANGES TO PREVIOUS REVISION:
THIS SAFETY DATA SHEET HAS BEEN REVISED DUE TO MODIFICATIONS TO
SECTIONS 1-16.
REFERENCES TO KEY LITERATURE AND DATA SOURCES:
REFER TO ESAB "WELDING AND CUTTING - RISKS AND MEASURES", F52-529
"PRECAUTIONS AND SAFE PRACTICES FOR ELECTRIC WELDING AND CUTTING" AND
F2035 "PRECAUTIONS AND SAFE PRACTICES FOR GAS WELDING, CUTTING AND
HEATING" AVAILABLE FROM ESAB, AND TO: WWW.ESAB.COM
PHRASE MEANING:
REPR. 1B - REPRODUCTIVE TOXICITY, HAZARD CATEGORY 1B
H360FD - FD MAY DAMAGE FERTILITY. MAY DAMAGE THE UNBORN CHILD
OTHER:
ADDITIONAL INFORMATION:
USA:
CONTACT ESAB AT WWW.ESABNA.COM OR 1-800 ESAB-123 IF YOU HAVE ANY QUESTIONS
ABOUT THIS SDS. AMERICAN NATIONAL STANDARD Z49.1 SAFETY IN WELDING AND
CUTTING, ANSI/AWS F1.5 METHODS FOR SAMPLING AND ANALYZING GASES FROM
WELDING AND ALLIED PROCESSES, ANSI/AWS F1.1 "METHOD FOR SAMPLING AIRBORNE
PARTICLES GENERATED BY WELDING AND ALLIED PROCESSES", AWSF3.2M/F3.2
"VENTILATION GUIDE FOR WELD FUME", 550 NORTH LE JEUNE ROAD, MIAMI FLORIDA
33135. SAFETY AND HEALTH FACT SHEETS AVAILABLE FROM AWS AT WWW.AWS.ORG.
OSHA PUBLICATION 2206 (29 C.F.R. 1910), U.S. GOVERNMENT PRINTING OFFICE,
SUPERINTENDENT OF DOCUMENTS, P.O. BOX 371954, PITTSBURGH, PA 15250-7954
AMERICAN CONFERENCE OF GOVERNMENTAL HYGIENISTS (ACGIH), THRESHOLD LIMIT
VALUES AND BIOLOGICAL EXPOSURE INDICES, 6500 GLENWAY AVE., CINCINNATI,
OHIO 45211, USA.
NFPA 51B "STANDARD FOR FIRE PREVENTION DURING WELDING, CUTTING AND OTHER
HOT WORK" PUBLISHED BY THE NATIONAL FIRE PROTECTION ASSOCIATION, 1
BATTERYMARCH PARK, QUINCY, MA 02169
UK:
WMA PUBLICATION 236 AND 237, "HAZARDS FROM WELDING FUME", "THE ARC WELDER
AT WORK, SOME GENERAL ASPECTS OF HEALTH AND SAFETY".
GERMANY:
ACCIDENT PREVENTION REGULATION BGV D1, "WELDING, CUTTING AND RELATED
PROCEDURES"
CANADA:
CSA STANDARD CAN/CSA-W117.2-01 "SAFETY IN WELDING, CUTTING, AND ALLIED
PROCESSES".
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
CPR AND THE SDS CONTAINS ALL OF THE INFORMATION REQUIRED BY THE CPR.
ESAB REQUESTS THE USERS OF THIS PRODUCT TO STUDY THIS SAFETY DATA SHEET
(SDS) AND BECOME AWARE OF PRODUCT HAZARDS AND SAFETY INFORMATION. TO
PROMOTE SAFE USE OF THIS PRODUCT A USER SHOULD:
NOTIFY ITS EMPLOYEES, AGENTS AND CONTRACTORS OF THE INFORMATION ON THIS SDS
AND ANY PRODUCT HAZARDS/SAFETY INFORMATION.FURNISH THIS SAME INFORMATION TO
EACH OF ITS CUSTOMERS FOR THE PRODUCTS
REQUEST SUCH CUSTOMERS TO NOTIFY EMPLOYEES AND CUSTOMERS FOR THE SAME
PRODUCT HAZARDS AND SAFETY INFORMATION.
THE INFORMATION HEREIN IS GIVEN IN GOOD FAITH AND BASED ON TECHNICAL DATA
THAT ESAB BELIEVES TO BE RELIABLE. SINCE THE CONDITIONS OF USE IS OUTSIDE
OUR CONTROL, WE ASSUME NO LIABILITY IN CONNECTION WITH ANY USE OF THIS
INFORMATION AND NO WARRANTY EXPRESSED OR IMPLIED IS GIVEN. CONTACT ESAB
FOR MORE INFORMATION.
ESAB(R*)
SAFETY DATA SHEET
THIS SAFETY DATA SHEET COMPLIES WITH ANNEX II OF 830/2015 AMENDING
EC NO. 1907/2006, CLP DIRECTIVE 1272/2008, ALSO IN ACCORDANCE WITH
ISO 11014-1 AND ANSI Z400.1
ALL-STATE 41FC
ISSUED: 2018-01-14
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE | |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
TRADE NAME: ALL-STATE 41FC
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE: COPPER BASED BRAZING ALLOYS
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
SDS CREATED BY: TDS TEAM
SUPPLIER: ESAB DENTON
STREET ADDRESS:
2800 AIRPORT ROAD
DENTON, TX 76207
TELEPHONE: 1-800-372-2123
EMAIL: SDSREQUEST@ESAB.COM
WEB SITE: WWW.ESAB.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY PHONE NUMBER: 1-800-372-2123
AVAILABLE OUTSIDE OFFICE HOURS: NO
OTHER:
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
THE PRODUCT IS NOT CLASSIFIED
2.2. LABEL ELEMENTS: THE PRODUCT DO NOT REQUIRE LABELING
2.3. OTHER HAZARDS:
AVOID EYE CONTACT OR INHALATION OF DUST FROM THE PRODUCT. SKIN CONTACT
IS NORMALLY NO HAZARD BUT SHOULD BE AVOIDED TO PREVENT POSSIBLE ALLERGIC
REACTIONS.
PERSONS WITH A PACEMAKER SHOULD NOT GO NEAR WELDING OR CUTTING OPERATIONS
UNTIL THEY HAVE CONSULTED THEIR DOCTOR AND OBTAINED INFORMATION FROM THE
MANUFACTURER OF THE DEVICE.
WHEN THIS PRODUCT IS USED IN A WELDING PROCESS, THE MOST IMPORTANT HAZARDS
ARE WELDING FUMES, HEAT, RADIATION AND ELECTRIC SHOCK.
FUMES:
OVEREXPOSURE TO WELDING FUMES MAY RESULT IN SYMPTOMS LIKE METAL FUME
FEVER, DIZZINESS, NAUSEA, DRYNESS OR IRRITATION OF THE NOSE, THROAT OR
EYES. CHRONIC OVEREXPOSURE TO WELDING FUMES MAY AFFECT PULMONARY FUNCTION.
OVEREXPOSURE TO MANGANESE AND MANGANESE COMPOUNDS ABOVE SAFE EXPOSURE
LIMITS CAN CAUSE IRREVERSIBLE DAMAGE TO THE CENTRAL NERVOUS SYSTEM,
INCLUDING THE BRAIN, SYMPTOMS OF WHICH MAY INCLUDE SLURRED SPEECH,
LETHARGY, TREMOR, MUSCULAR WEAKNESS,
HEAT: SPATTER AND MELTING METAL CAN CAUSE BURN INJURIES AND START FIRES.
RADIATION: ARC RAYS CAN SEVERELY DAMAGE EYES OR SKIN.
ELECTRICITY: ELECTRIC SHOCK CAN KILL.
OTHER:
EMERGENCY OVERVIEW:
COATED METAL RODS IN VARYING COLOURS. THIS PRODUCT IS NORMALLY NOT
CONSIDERED HAZARDOUS AS SHIPPED. GLOVES SHOULD BE WORN WHEN HANDLING
TO PREVENT CONTAMINATING HANDS WITH PRODUCT DUST.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.2. MIXTURES:
CHEMICAL NAME CAS NO. CONCENTRATION CLASSIFICATION R-PHRASE
EC NO. H-PHRASE
REACH NO.
COPPER 7440-50-8 55 - 58%
231-159-6
ZINC 7440-66-6 32 - 39%
231-175-3
BORIC ACID 10043-35-3 3 - 6% REPR. 1B H360FD
233-139-2
SODIUM 1330-43-4 0,5 - 2,5% REPR. 1B H360FD
TETRABORATE 215-540-4
TIN 7440-31-5 0,3 - 1,5%
231-141-8
IRON 7439-89-6 <1%
231-096-4
REGISTERED
METHACRYLATE/ PROPRIETARY <1%
ALIPHATIC &
NAPHTHENIC
HYDROCARBON
COMPOUND
SILICON 7440-21-3 <0,5%
231-130-8
MANGANESE 7439-96-5 <0,4%
231-105-1
PRODUCT BASED ON:
THIS PRODUCT IS A PREPARATION OF CORE WIRE WITH EXTRUDED COATING.
THE CORE WIRE TYPE IS MILD STEEL.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
ELECTRIC SHOCK:
DISCONNECT AND TURN OFF THE POWER. USE A NONCONDUCTIVE MATERIAL TO PULL
VICTIM AWAY FROM CONTACT WITH LIVE PARTS OR WIRES. IF NOT BREATHING,
BEGIN ARTIFICIAL RESPIRATION, PREFERABLY MOUTH-TO-MOUTH. IF NO DETECTABLE
PULSE, BEGIN CARDIO PULMONARY RESUSCITATION (CPR). CALL EMERGENCY PHYSICIAN
TO THE SCENE OF THE ACCIDENT. CALL A PHYSICIAN IMMEDIATELY.
INHALATION:
IF BREATHING HAS STOPPED, PERFORM ARTIFICIAL RESPIRATION AND OBTAIN MEDICAL
ASSISTANCE IMMEDIATELY! IF BREATHING IS DIFFICULT, PROVIDE FRESH AIR AND
CALL PHYSICIAN.
SKIN CONTACT:
FOR SKIN BURNS FROM ARC RADIATION, PROMPTLY FLUSH WITH COLD WATER. GET
MEDICAL ATTENTION FOR BURNS OR IRRITATIONS THAT PERSIST. TO REMOVE DUST
OR PARTICLES WASH WITH MILD SOAP AND WATER.
EYE CONTACT:
FOR RADIATION BURNS DUE TO ARC FLASH, SEE PHYSICIAN. TO REMOVE DUSTS
OR FUMES FLUSH WITH WATER FOR AT LEAST FIFTEEN MINUTES. IF IRRITATION
PERSISTS, OBTAIN MEDICAL ASSISTANCE.
INGESTION:
NOT A LIKELY ROUTE OF EXPOSURE. IF PRODUCT DUSTS ARE SWALLOWED, CALL A
PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. DO NOT INDUCE VOMITING
UNLESS DIRECTED TO DO SO BY A PHYSICIAN.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
NOT APPLICABLE
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
NOT APPLICABLE
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
NO SPECIFIC RECOMMENDATIONS FOR WELDING CONSUMABLES. WELDING ARCS
AND SPARKS CAN IGNITE COMBUSTIBLE AND FLAMMABLE MATERIALS. USE THE
EXTINGUISHING MEDIA RECOMMENDED FOR THE BURNING MATERIALS AND FIRE
SITUATION.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NOT APPLICABLE
5.3. ADVICE FOR FIREFIGHTERS:
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
WEAR SELF-CONTAINED BREATHING APPARATUS AS FUMES OR VAPORS MAY BE HARMFUL.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
WEAR HAND, HEAD, EYES, EAR AND BODY PROTECTION LIKE WELDERS GLOVES, HELMET
OR FACE SHIELD WITH FILTER LENS, SAFETY BOOTS, APRON, ARM AND SHOULDER
PROTECTION. KEEP PROTECTIVE CLOTHING CLEAN AND DRY.
6.2. ENVIRONMENTAL PRECAUTIONS: REFER TO SECTION 13.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
SOLID OBJECTS MAY BE PICKED UP AND PLACED INTO A CONTAINER. LIQUIDS OR
PASTES SHOULD BE SCOOPED UP AND PLACED INTO A CONTAINER. WEAR PROPER
PROTECTIVE EQUIPMENT WHILE HANDLING THESE MATERIALS. DO NOT DISCARD AS
REFUSE.
6.4. REFERENCE TO OTHER SECTIONS: REFER TO SECTION 8/13
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PREVENTIVE HANDLING PRECAUTIONS:
HANDLE WITH CARE TO AVOID STINGS AND CUTS. WEAR GLOVES WHEN HANDLING WELDING
CONSUMABLES. AVOID EXPOSURE TO DUST. DO NOT INGEST. SOME INDIVIDUALS CAN
DEVELOP AN ALLERGIC REACTION TO CERTAIN MATERIALS. RETAIN ALL WARNING AND
IDENTITY LABELS.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
KEEP SEPARATE FROM CHEMICAL SUBSTANCES LIKE ACIDS AND STRONG BASES, WHICH
COULD CAUSE CHEMICAL REACTIONS.
7.3. SPECIFIC END USE(S): ARC WELDING
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
EXPOSURE LIMITS USE INDUSTRIAL HYGIENE MONITORING EQUIPMENT TO ENSURE THAT
EXPOSURE DOES NOT EXCEED APPLICABLE NATIONAL EXPOSURE LIMITS. THE FOLLOWING
LIMITS CAN BE USED AS GUIDANCE. UNLESS NOTED, ALL VALUES ARE FOR 8 HOUR
TIME WEIGHTED AVERAGES (TWA). FOR INFORMATION ABOUT WELDING FUME ANALYSIS
REFER TO SECTION 10.
NATIONAL OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT CAS NO. EC NO. EXPOSURE SHORT-TERM CEILING
LIMIT EXPOSURE EXPOSURE
MG/M3- LIMIT LIMIT
PPM MG/M3-PPM MG/M3-PPM
IRON 7439-89-6 231-096-4
MANGANESE 7439-96-5 231-105-1 5
COPPER 7440-50-8 231-159-6 0,1
COPPER 7440-50-8 231-159-6 1
SILICON 7440-21-3 231-130-8 15
SILICON 7440-21-3 231-130-8 5
TIN 7440-31-5 231-141-8 2
ZINC 7440-66-6 231-175-3
SODIUM 1330-43-4 215-540-4
TETRABORATE
BORIC ACID 10043-35-3 233-139-2
METHACRYLATE/ PROPRIETARY
ALIPHATIC
& NAPHTHENIC
HYDROCARBON
COMPOUND
INGREDIENT REMARK SOURCE YEAR
IRON NO PEL OSHA 2017
MANGANESE AS Mn OSHA 2017
COPPER AS Cu (FUME) OSHA 2017
COPPER AS Cu (DUST,MIST) OSHA 2017
SILICON TOTAL DUST OSHA 2017
SILICON RESPIRABLE FRACTION OSHA 2017
TIN METAL OSHA 2017
ZINC OSHA 2017
SODIUM OSHA 2017
TETRABORATE
BORIC ACID OSHA 2017
METHACRYLATE/ OSHA 2017
ALIPHATIC
& NAPHTHENIC
HYDROCARBON
COMPOUND
8.2. EXPOSURE CONTROLS: NOT APPLICABLE
OTHER:
AVOID EXPOSURE TO WELDING FUMES, RADIATION, SPATTER, ELECTRIC SHOCK, HEATED
MATERIALS AND DUST. TRAIN WELDERS TO AVOID CONTACT WITH LIVE ELECTRICAL
PARTS AND INSULATE CONDUCTIVE PARTS.
VENTILATION:
ENSURE SUFFICIENT VENTILATION, LOCAL EXHAUST, OR BOTH, TO KEEP WELDING
FUMES AND GASES FROM BREATHING ZONE AND GENERAL AREA. USE SPECIAL CARE
WHEN WELDING PAINTED OR COATED STEELS SINCE HAZARDOUS SUBSTANCES FROM THE
COATING MAY BE EMITTED. USE RESPIRATOR OR AIR SUPPLIED RESPIRATOR WHEN
WELDING OR BRAZING IN A CONFINED SPACE, OR WHERE LOCAL EXHAUST OR
VENTILATION IS NOT SUFFICIENT TO KEEP EXPOSURE VALUES WITHIN SAFE LIMITS.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE: METAL RODS IN VARYING COLOR.
APPEARANCE, COLOUR: NOT APPLICABLE
APPEARANCE, PHYSICAL STATE: NOT APPLICABLE
AUTO-IGNITION TEMPERATURE: NOT APPLICABLE
BOILING POINT: 907 DEG. C/1665 DEG. F (ZINC)
DECOMPOSITION TEMPERATURE: NOT APPLICABLE
EVAPORATION RATE: NOT APPLICABLE
EXPLOSIVE PROPERTIES: NOT APPLICABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLASH POINT: NOT FLAMMABLE.
INITIAL BOILING POINT AND BOILING RANGE: NOT APPLICABLE
MELTING POINT: 419 DEG. C/786 DEG. F (ZINC)
MELTING POINT / FREEZING POINT: NOT APPLICABLE
ODOUR: NOT APPLICABLE
ODOUR TRESHOLD: NOT APPLICABLE
OXIDISING PROPERTIES: NOT APPLICABLE
PARTITION COEFFICIENT:
N-OCTANOL / WATER: NOT APPLICABLE
PH VALUE: NOT APPLICABLE
RELATIVE DENSITY: NOT APPLICABLE
SOLUBILITY: NOT APPLICABLE
SPECIFIC GRAVITY: 8.3 - 8.5 (H2O = 1)
UPPER / LOWER FLAMMABILITY OR EXPLOSIVE LIMITS: NOT APPLICABLE
VAPOUR DENSITY: NOT APPLICABLE
VAPOUR PRESSURE: NOT APPLICABLE
VISCOSITY: NOT APPLICABLE
9.2. OTHER INFORMATION: NOT APPLICABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
REACTIVITY:
CONTACT WITH CHEMICAL SUBSTANCES LIKE ACIDS OR STRONG BASES COULD CAUSE
GENERATION OF GAS.
10.2. CHEMICAL STABILITY:
CHEMICAL STABILITY: STABLE AT NORMAL CONDITIONS
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NOT APPLICABLE
10.4. CONDITIONS TO AVOID:
CONDITIONS TO AVOID:
THIS PRODUCT IS ONLY INTENDED FOR NORMAL WELDING PURPOSES.
10.5. INCOMPATIBLE MATERIALS: NOT APPLICABLE
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
HAZARDOUS DECOMPOSITION PRODUCTS:
WHEN THESE PRODUCTS ARE USED IN A BRAZING OR SOLDERING PROCESS, HAZARDOUS
DECOMPOSITION PRODUCTS WOULD INCLUDE THOSE FROM THE VOLATILIZATION,
REACTION OR OXIDATION OF THE MATERIALS LISTED IN SECTION 3 AND THOSE FROM
THE BASE METAL AND COATING. FUMES FROM THESE PRODUCTS MAY CONTAIN COMPOUNDS
OF THE FOLLOWING CHEMICAL ELEMENTS:
B, Cu, Fe, O, Mn, Si, Sn AND Zn. THE REST IS NOT ANALYZED, ACCORDING TO
AVAILABLE STANDARDS.
OTHER:
REFER TO APPLICABLE NATIONAL EXPOSURE LIMITS FOR FUME COMPOUNDS, INCLUDING
THOSE EXPOSURE LIMITS FOR FUME COMPOUNDS FOUND IN SECTION 8. MANGANESE HAS
A LOW EXPOSURE LIMIT, IN SOME COUNTRIES, THAT MAY BE EASILY EXCEEDED.
REASONABLY EXPECTED GASEOUS PRODUCTS WOULD INCLUDE CARBON OXIDES, NITROGEN
OXIDES AND OZONE. AIR CONTAMINANTS AROUND THE WELDING AREA CAN BE AFFECTED
BY THE WELDING PROCESS AND INFLUENCE THE COMPOSITION AND QUANTITY OF FUMES
AND GASES PRODUCED.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
INFORMATION ON TOXICOLOGICAL EFFECTS:
INHALATION OF WELDING FUMES AND GASES CAN BE DANGEROUS TO YOUR HEALTH.
CLASSIFICATION OF WELDING FUMES IS DIFFICULT BECAUSE OF VARYING BASE
MATERIALS, COATINGS, AIR CONTAMINATION AND PROCESSES. THE INTERNATIONAL
AGENCY FOR RESEARCH ON CANCER HAS CLASSIFIED WELDING FUMES AS POSSIBLY
CARCINOGENIC TO HUMANS (GROUP 2B).
ACUTE TOXICITY:
OVEREXPOSURE TO WELDING FUMES MAY RESULT IN SYMPTOMS LIKE METAL FUME FEVER,
DIZZINESS, NAUSEA, DRYNESS OR IRRITATION OF THE NOSE, THROAT OR EYES.
SKIN CORROSION/IRRITATION: NO DATA AVAILABLE
SERIOUS EYE DAMAGE/IRRITATION: NO DATA AVAILABLE
RESPIRATORY/SKIN SENSITIZATION: NO DATA AVAILABLE
GERM CELL MUTAGENICITY: NO DATA AVAILABLE
GENOTOXICITY: NO DATA AVAILABLE
CARCINOGENICITY: NO DATA AVAILABLE
REPEATED DOSE TOXICITY: NO DATA AVAILABLE
REPRODUCTIVE TOXICITY: NO DATA AVAILABLE
STOT-SINGLE EXPOSURE: NO DATA AVAILABLE
STOT-REPEATED EXPOSURE: NO DATA AVAILABLE
ASPIRATION HAZARD: NO DATA AVAILABLE
LD50 ORAL: NO DATA AVAILABLE
LD50 DERMAL: NO DATA AVAILABLE
LC50 INHALATION: NO DATA AVAILABLE
ROUTES OF EXPOSURE: NO DATA AVAILABLE
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
NO DATA AVAILABLE
MIXTURE VERSUS SUBSTANCE INFORMATION: NO DATA AVAILABLE
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
NO DATA AVAILABLE
INTERACTIVE EFFECTS: NO DATA AVAILABLE
TOXICITY IN CASE OF SKIN CONTACT: NO DATA AVAILABLE
ABSENCE OF SPECIFIC DATA: NO DATA AVAILABLE
TOXICITY IN CASE OF EYE CONTACT: NO DATA AVAILABLE
MIXTURES: NO DATA AVAILABLE
TOXICITY IN CASE OF INGESTION: NO DATA AVAILABLE
OTHER:
ACUTE EFFECTS: NO DATA AVAILABLE
LONG TERM EFFECT:
CHRONIC TOXICITY:
OVEREXPOSURE TO WELDING FUMES MAY AFFECT PULMONARY FUNCTION. OVEREXPOSURE
TO MANGANESE AND MANGANESE COMPOUNDS ABOVE SAFE EXPOSURE LIMITS CAN CAUSE
IRREVERSIBLE DAMAGE TO THE CENTRAL NERVOUS SYSTEM, INCLUDING THE BRAIN,
SYMPTOMS OF WHICH MAY INCLUDE SLURRED SPEECH, LETHARGY, TREMOR, MUSCULAR
WEAKNESS, PSYCHOLOGICAL DISTURBANCES AND SPASTIC GAIT.
INFORMATION TO DOCTOR: NO DATA AVAILABLE
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ACUTE TOXICITY: NO DATA AVAILABLE
TOXICITY: NO DATA AVAILABLE
AQUATIC: NO DATA AVAILABLE
SOIL: NO DATA AVAILABLE
ACUTE FISH TOXICITY: NO DATA AVAILABLE
ACUTE ALGAE TOXICITY: NO DATA AVAILABLE
ACUTE CRUSTACEAN TOXICITY: NO DATA AVAILABLE
CHRONICAL TOXICITY: NO DATA AVAILABLE
12.2. PERSISTENCE AND DEGRADABILITY:
PERSISTENCE AND DEGRADABILITY: NO DATA AVAILABLE
DECAY/TRANSFORMATION: NO DATA AVAILABLE
12.3. BIOACCUMULATIVE POTENTIAL:
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE
12.4. MOBILITY IN SOIL:
MOBILITY: NO DATA AVAILABLE
12.5. RESULTS OF PBT AND VPVB ASSESSMENT:
RESULTS OF PBT AND VPVB ASSESSMENT: NO DATA AVAILABLE
12.6. OTHER ADVERSE EFFECTS:
OTHER ADVERSE EFFECTS: NO DATA AVAILABLE
OTHER:
WELDING CONSUMABLES AND MATERIALS COULD DEGRADE/WEATHER INTO COMPONENTS
ORIGINATING FROM THE CONSUMABLES OR FROM THE MATERIALS USED IN THE
WELDING PROCESS. AVOID EXPOSURE TO CONDITIONS THAT COULD LEAD TO
ACCUMULATION IN SOILS OR GROUNDWATER.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
DISPOSAL CONSIDERATIONS:
DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER OR LINER IN AN
ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE WITH FEDERAL
AND LOCAL REGULATIONS. USE RECYCLING PROCEDURES IF AVAILABLE.
USA RCRA: THIS PRODUCT IS NOT CONSIDERED HAZARDOUS WASTE IF DISCARDED.
RESIDUES FROM BRAZING CONSUMABLES AND PROCESSES COULD DEGRADE AND
ACCUMULATE IN SOILS AND GROUNDWATER. BRAZING RESIDUES FROM THESE
PRODUCTS TYPICALLY CONTAIN MAINLY THE FOLLOWING COMPONENTS:
B, Cu, Fe, O, Mn, Si, Sn, AND Zn.
| SECTION 14: TRANSPORT INFORMATION | |
14.1. UN NUMBER: NOT APPLICABLE
14.2. UN PROPER SHIPPING NAME: NOT APPLICABLE
14.3. TRANSPORT HAZARD CLASS(ES): NOT APPLICABLE
14.4. PACKING GROUP: NOT APPLICABLE
14.5. ENVIRONMENTAL HAZARDS: NOT APPLICABLE
14.6. SPECIAL PRECAUTIONS FOR USER: NOT APPLICABLE
14.7. TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL AND THE IBC CODE:
NOT APPLICABLE
| SECTION 15: REGULATORY INFORMATION | |
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR
THE SUBSTANCE OR MIXTURE:
EU REGULATIONS:
REGULATION (EC) NO 1907/2006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
OF 18 DECEMBER 2006 CONCERNING THE REGISTRATION, EVALUATION, AUTHORISATION
AND RESTRICTION OF CHEMICALS (REACH), ESTABLISHING A EUROPEAN CHEMICALS
AGENCY, AMENDING DIRECTIVE 1999/45/EC AND REPEALING COUNCIL REGULATION
(EEC) NO 793/93 AND COMMISSION REGULATION (EC) NO 1488/94 AS WELL AS
COUNCIL DIRECTIVE 76/769/EEC AND COMMISSION DIRECTIVES 91/155/EEC,
93/67/EEC, 93/105/EC AND 2000/21/EC.
REGULATION (EC) NO 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
OF 16 DECEMBER 2008 ON CLASSIFICATION, LABELLING AND PACKAGING OF
SUBSTANCES AND MIXTURES, AMENDING AND REPEALING DIRECTIVES 67/548/EEC AND
1999/45/EC, AND AMENDING REGULATION (EC) NO 1907/2006 COMMISSION REGULATION
(EU) 2015/830 OF 28 MAY 2015 AMENDING REGULATION (EC) NO 1907/2006 OF THE
EUROPEAN PARLIAMENT AND THE COUNCIL CONCERNING THE REGISTRATION,
EVALUATION, AUTHORISATION AND RESTRICTION OF CHEMICALS (REACH)
DIRECTIVE 2008/98/EC OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL.
OF 19 NOVEMBER 2008. ON WASTE AND REPEALING CERTAIN DIRECTIVES.
EUROPEAN PARLIAMENT AND COUNCIL DIRECTIVE 94/62/EC OF 20 DECEMBER 1994 ON
PACKAGING AND PACKAGING WASTE.
OTHER REGULATIONS, LIMITATIONS AND LEGAL REGULATIONS:
POLAND REGULATIONS:
ACT OF 25 FEBRUARY 2011 ON THE CHEMICAL SUBSTANCES AND THEIR MIXTURES(OJ #
63, POZ. 322).
REGULATION OF THE MINISTER OF LABOUR AND SOCIAL POLICY OF 6 JUNE 2014 ON
MAXIMUM PERMISSIBLE CONCENTRATION AND INTENSITY OF AGENTS HARMFUL TO HEALTH
IN THE WORKING ENVIRONMENT (DZ. U. Z. 2014, POZ 817).
THE ACT ON WASTE OF 14 DECEMBER 2012, JOURNAL OF LAWS OF 2013, ITEM 21 WITH
AMENDMENTS
ACT OF 13TH JUNE 2013 ON PACKAGING MANAGEMENT AND PACKAGING WASTE (JOURNAL
OF LAWS OF 2013, ITEM 888).
REGULATION OF THE MINISTER OF THE ENVIRONMENT OF 9 DECEMBER 2014 ON WASTE
CATALOGUE (JOURNAL OF LAWS OF 2014, ITEM 1923).
REGULATION OF THE MINISTER OF ECONOMY OF 21 DECEMBER 2005. CONCERNING
ESSENTIAL REQUIREMENTS FOR PERSONAL PROTECTIVE EQUIPMENT (JOURNAL. LAWS
NO. 259, ITEM. 2173).
REGULATION OF THE MINISTER OF HEALTH OF 2 FEBRUARY 2011 ON TESTS AND
MEASUREMENTS OF FACTORS HARMFUL TO HEALTH IN THE WORKING ENVIRONMENT
(THE JOURNAL OF LAWS 2011, NO. 33, ITEM 166).
USA REGULATIONS:
USA:
THIS PRODUCT CONTAINS OR PRODUCES A CHEMICAL KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER AND BIRTH DEFECTS (OR OTHER REPRODUCTIVE HARM).
(CALIFORNIA HEALTH & SAFETY CODE SUBSECTION 25249.5 ET SEQ.)
CERCLA/SARA TITLE III REPORTABLE QUANTITIES (RQS) AND/OR THRESHOLD PLANNING
QUANTITIES (TPQS):
PRODUCT IS A SOLID SOLUTION IN THE FORM OF A SOLID ARTICLE. SPILLS OR
RELEASES RESULTING IN THE LOSS OF ANY INGREDIENT AT OR ABOVE ITS RQ
REQUIRE IMMEDIATE NOTIFICATION TO THE NATIONAL RESPONSE CENTER AND TO
YOUR LOCAL EMERGENCY PLANNING COMMITTEE.
EPCRA/SARA TITLE III 313 TOXIC CHEMICALS: THE FOLLOWING METALLIC COMPONENTS
ARE LISTED AS SARA 313 "TOXIC CHEMICALS" AND POTENTIAL SUBJECT TO ANNUAL
SARA 313 REPORTING. SEE SECTION 3 FOR WEIGHT PERCENT.
MANGANESE: 1.0% DE MINIMIS CONCENTRATION
CANADA:
WHMIS CLASSIFICATION: CLASS D; DIVISION 2, SUBDIVISION A
MANGANESE/1.0% DE MINIMIS CONCENTRATION
INTERNATIONAL INVENTORIES:
AUSTRALIA:
THE SUBSTANCE(S) IN THIS PRODUCT IS/ARE IN COMPLIANCE WITH THE INVENTORY
REQUIREMENTS OF AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES (AICS)
UNITED STATES EPA TOXIC SUBSTANCE CONTROL ACT:
ALL CONSTITUENTS OF THIS PRODUCT ARE ON THE TSCA INVENTORY LIST OR ARE
EXCLUDED FROM LISTING.
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA):
ALL CONSTITUENT(S) OF THIS PRODUCT IS/ARE ON THE DOMESTIC SUBSTANCE
LIST (DSL).
15.2. CHEMICAL SAFETY ASSESSMENT:
CHEMICAL SAFETY ASSESSMENT: NO DATA AVAILABLE
OTHER:
READ AND UNDERSTAND THE MANUFACTURER'S INSTRUCTIONS, YOUR EMPLOYER'S SAFETY
PRACTICES AND THE HEALTH AND SAFETY INSTRUCTIONS ON THE LABEL. OBSERVE ANY
FEDERAL AND LOCAL REGULATIONS. TAKE PRECAUTIONS WHEN WELDING AND PROTECT
YOURSELF AND OTHERS.
WARNING:
WELDING FUMES AND GASES ARE HAZARDOUS TO YOUR HEALTH AND MAY DAMAGE LUNGS
AND OTHER ORGANS. USE ADEQUATE VENTILATION. ELECTRIC SHOCK CAN KILL. ARC
RAYS AND SPARKS CAN INJURE EYES AND BURN SKIN.
WEAR CORRECT HAND, HEAD, EYE AND BODY PROTECTION.
| SECTION 16: OTHER INFORMATION | |
CHANGES TO PREVIOUS REVISION:
THIS SAFETY DATA SHEET HAS BEEN REVISED DUE TO MODIFICATIONS TO SECTIONS
1-16.
REFERENCES TO KEY LITERATURE AND DATA SOURCES:
REFER TO ESAB "WELDING AND CUTTING - RISKS AND MEASURES", F52-529
"PRECAUTIONS AND SAFE PRACTICES FOR ELECTRIC WELDING AND CUTTING" AND
F2035 "PRECAUTIONS AND SAFE PRACTICES FOR GAS WELDING, CUTTING AND
HEATING" AVAILABLE FROM ESAB, AND TO: WWW.ESAB.COM
PHRASE MEANING:
REPR. 1B - REPRODUCTIVE TOXICITY, HAZARD CATEGORY 1B
H360FD - FD MAY DAMAGE FERTILITY. MAY DAMAGE THE UNBORN CHILD
OTHER:
ADDITIONAL INFORMATION:
USA:
CONTACT ESAB AT WWW.ESABNA.COM OR 1-800 ESAB-123 IF YOU HAVE ANY QUESTIONS
ABOUT THIS SDS. AMERICAN NATIONAL STANDARD Z49.1 SAFETY IN WELDING AND
CUTTING, ANSI/AWS F1.5 METHODS FOR SAMPLING AND ANALYZING GASES FROM
WELDING AND ALLIED PROCESSES, ANSI/AWS F1.1 "METHOD FOR SAMPLING AIRBORNE
PARTICLES GENERATED BY WELDING AND ALLIED PROCESSES", AWSF3.2M/F3.2
"VENTILATION GUIDE FOR WELD FUME", 550 NORTH LE JEUNE ROAD, MIAMI FLORIDA
33135. SAFETY AND HEALTH FACT SHEETS AVAILABLE FROM AWS AT WWW.AWS.ORG.
OSHA PUBLICATION 2206 (29 C.F.R. 1910), U.S. GOVERNMENT PRINTING OFFICE,
SUPERINTENDENT OF DOCUMENTS, P.O. BOX 371954, PITTSBURGH, PA 15250-7954
AMERICAN CONFERENCE OF GOVERNMENTAL HYGIENISTS (ACGIH), THRESHOLD LIMIT
VALUES AND BIOLOGICAL EXPOSURE INDICES, 6500 GLENWAY AVE., CINCINNATI,
OHIO 45211, USA.
NFPA 51B "STANDARD FOR FIRE PREVENTION DURING WELDING, CUTTING AND OTHER
HOT WORK" PUBLISHED BY THE NATIONAL FIRE PROTECTION ASSOCIATION, 1
BATTERYMARCH PARK, QUINCY, MA 02169
UK:
WMA PUBLICATION 236 AND 237, "HAZARDS FROM WELDING FUME", "THE ARC WELDER
AT WORK, SOME GENERAL ASPECTS OF HEALTH AND SAFETY".
GERMANY:
ACCIDENT PREVENTION REGULATION BGV D1, "WELDING, CUTTING AND RELATED
PROCEDURES"
CANADA:
CSA STANDARD CAN/CSA-W117.2-01 "SAFETY IN WELDING, CUTTING, AND ALLIED
PROCESSES".
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
CPR AND THE SDS CONTAINS ALL OF THE INFORMATION REQUIRED BY THE CPR.
ESAB REQUESTS THE USERS OF THIS PRODUCT TO STUDY THIS SAFETY DATA SHEET
(SDS) AND BECOME AWARE OF PRODUCT HAZARDS AND SAFETY INFORMATION. TO
PROMOTE SAFE USE OF THIS PRODUCT A USER SHOULD:
NOTIFY ITS EMPLOYEES, AGENTS AND CONTRACTORS OF THE INFORMATION ON THIS
SDS AND ANY PRODUCT HAZARDS/SAFETY INFORMATION.FURNISH THIS SAME
INFORMATION TO EACH OF ITS CUSTOMERS FOR THE PRODUCTS REQUEST SUCH
CUSTOMERS TO NOTIFY EMPLOYEES AND CUSTOMERS FOR THE SAME PRODUCT HAZARDS
AND SAFETY INFORMATION.
THE INFORMATION HEREIN IS GIVEN IN GOOD FAITH AND BASED ON TECHNICAL DATA
THAT ESAB BELIEVES TO BE RELIABLE. SINCE THE CONDITIONS OF USE IS OUTSIDE
OUR CONTROL, WE ASSUME NO LIABILITY IN CONNECTION WITH ANY USE OF THIS
INFORMATION AND NO WARRANTY EXPRESSED OR IMPLIED IS GIVEN. CONTACT ESAB
FOR MORE INFORMATION.