| Common Name: | HPX/HPA GARNET ABRASIVE GRAINS AND POWDERS |
| Manufacturer: | AGSCO |
| SDS Revision Date: | 1/1/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 402F54, 402F55, 402F56, 402F57 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
PRODUCT NAME: HPX/HPA GARNET ABRASIVE GRAINS AND POWDERS
PRODUCT DESCRIPTION: ALMANDINE, ALMANDITE AND PYROPE GARNET
| 1 - IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1 IDENTIFICATION OF THE SUBSTANCE OR PREPARATION:
PRODUCT NAMES: GARNET PARTICLES
1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
RELEVANT IDENTIFIED USE(S): INDUSTRIAL ABRASIVES
1.3 OTHER MEANS OF IDENTIFICATION:
1.4 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET-MANUFACTURER/SUPPLIER:
COMPANY NAME: AGSCO CORPORATION
ADDRESS:
160 WEST HINTZ ROAD
WHEELING ILLINOIS 60090
EMERGENCY NUMBER: 847-520-4455
INFORMATION NUMBER: 847-520-4455
DATE PREPARED: JANUARY 2015
| 2 - HAZARDS IDENTIFICATION | |
EU/EEC:
ACCORDING TO REGULATION (EC) NO 1272/2008 (CLP)/REACH 1907/2006 [AMENDED
BY 453/2010]
ACCORDING TO EU DIRECTIVE 67/548/EEC (DSD) OR 1999/45/EC (DPD)
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLP: NOT CLASSIFIED
DSD/DPD: NOT CLASSIFIED
2.2 LABEL ELEMENTS:
CLP:
HAZARD STATEMENTS: NO LABEL ELEMENT(S) REQUIRED
DSD/DPD:
RISK PHRASES: NO LABEL ELEMENT(S) REQUIRED
2.3 OTHER HAZARDS:
CLP:
ACCORDING TO REGULATION (EC) NO. 1272/2008 (CLP) THIS MATERIAL IS NOT
CONSIDERED HAZARDOUS.
DSD/DPD:
ACCORDING TO EUROPEAN DIRECTIVE 1999/45/EC THIS MATERIAL IS NOT CONSIDERED
DANGEROUS.
UNITED STATES (US):
ACCORDING TO OSHA 29 CFR 1910.1200 HCS:
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
OSHA HCS 2012: CARCINOGENICITY 1A - H350
2.2 LABEL ELEMENTS:
OSHA HCS 2012:
DANGER: HEALTH HAZARD
HAZARD STATEMENTS: MAY CAUSE CANCER. - H350
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. - P201
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND
UNDERSTOOD. - P202
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE
PROTECTION. - P280
RESPONSE:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION. - P308+P313
STORAGE/DISPOSAL:
STORE LOCKED UP. - P405
DISPOSE OF CONTENT AND/OR CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL,
NATIONAL, AND/OR INTERNATIONAL REGULATIONS. - P501
2.3 OTHER HAZARDS:
OSHA HCS 2012:
UNDER UNITED STATES REGULATIONS (29 CFR 1910.1200 - HAZARD COMMUNICATION
STANDARD), THIS PRODUCT IS CONSIDERED HAZARDOUS.
CANADA:
ACCORDING TO WHMIS:
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
WHMIS: OTHER TOXIC EFFECTS - D2A
2.2 LABEL ELEMENTS: D2 - MATERIALS CAUSING OTHER TOXIC EFFECTS
WHMIS: OTHER TOXIC EFFECTS - D2A
2.3 OTHER HAZARDS:
WHMIS:
IN CANADA, THE PRODUCT MENTIONED ABOVE IS CONSIDERED HAZARDOUS UNDER THE
WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS).
| 3 - COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1 SUBSTANCES:
MATERIAL DOES NOT MEET THE CRITERIA OF A SUBSTANCE IN ACCORDANCE WITH
REGULATION (EC) NO 1272/2008.
3.2 MIXTURES:
COMPOSITION:
CHEMICAL NAME IDENTIFIERS %
ALMANDLNE/ALMANDLTE-FERRIC CAS: 1302-62-1 94% TO 99.6%
ALUMINUM SILICATE
QUARTZ CAS: 14808-60-7 <0.65%
EC NUMBER: 238-878-4
IRON CAS: 7439-89-6 0.01% TO 0.2%
EC NUMBER: 231-096-4
HORNBLENDE CAS: 12178-42-6 0.01% TO 0.2%
FELDSPARS CAS: 68476-25-5 0.01% TO 0.2%
EC NUMBER: 270-666-7
CHEMICAL NAME LD50/LC50 CLASSIFICATIONS COMMENTS
ACCORDING TO
REGULATION/DIRECTIVE
ALMANDLNE/ALMANDLTE- NDA EU DSD/DPD: NDA
FERRIC ALUMINUM NOT CLASSIFIED
EU CLP:
NOT CLASSIFIED
SILICATE OSHA HCS 2012:
NOT CLASSIFIED
QUARTZ NDA EU DSD/DPD: NDA
SELF CLASSIFIED:
T; R48/20
EU CLP:
SELF CLASSIFIED:
STOT RE 1 H372
OSHA HCS 2012:
CARC. 1A; STOT RE 1
(LUNGS, INHL)
IRON INGESTION/ORAL-RAT EU DSD/DPD: NDA
LD50: 750 MG/KG SELF CLASSIFIED:
XN R22 XI,
R37 XN R48/20
EU CLP:
SELF CLASSIFIED:
STOT SE 3:
RESP. IRRIT., H335;
STOT RE 2
(LUNGS, LIVER), H373;
ACUTE TOX. 4 (ORAL),
H302
OSHA HCS 2012:
STOT SE 3:
RESP. IRRIT.;
STOT RE 2
(LUNGS, LIVER);
ACUTE TOX 4 (ORAL)
HORNBLENDE NDA EU DSD/DPD: NDA
NOT CLASSIFIED
EU CLP:
NOT CLASSIFIED
OSHA HCS 2012:
NOT CLASSIFIED
FELDSPARS NDA EU DSD/DPD: NDA
NOT CLASSIFIED
EU CLP:
NOT CLASSIFIED
OSHA HCS 2012:
NOT CLASSIFIED
| 4 - FIRST AID MEASURES | |
4.1 DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. ADMINISTER OXYGEN IF BREATHING IS DIFFICULT. GIVE ARTIFICIAL
RESPIRATION IF VICTIM IS NOT BREATHING. GET MEDICAL ATTENTION IMMEDIATELY.
SKIN:
IN CASE OF CONTACT WITH SUBSTANCE, IMMEDIATELY FLUSH SKIN WITH RUNNING
WATER FOR AT LEAST 20 MINUTES. WASH SKIN WITH SOAP AND WATER.
EYE:
IN CASE OF CONTACT WITH SUBSTANCE, IMMEDIATELY FLUSH EYES WITH RUNNING
WATER FOR AT LEAST 20 MINUTES.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
INGESTION: GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
REFER TO SECTION 11 - TOXICOLOGICAL INFORMATION.
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
NOTES TO PHYSICIAN:
ALL TREATMENTS SHOULD BE BASED ON OBSERVED SIGNS AND SYMPTOMS OF DISTRESS
IN THE PATIENT. CONSIDERATION SHOULD BE GIVEN TO THE POSSIBILITY THAT
OVEREXPOSURE TO MATERIALS OTHER THAN THIS PRODUCT MAY HAVE OCCURRED.
| 5 - FIREFIGHTING MEASURES | |
5.1 EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE USE MEDIA AS APPROPRIATE FOR SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NO DATA AVAILABLE.
5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
UNUSUAL FIRE AND EXPLOSION HAZARDS: NONE
HAZARDOUS COMBUSTION PRODUCTS: NO DATA AVAILABLE.
5.3 ADVICE FOR FIREFIGHTERS:
WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA).
STRUCTURAL FIREFIGHTERS' PROTECTIVE CLOTHING WILL ONLY PROVIDE LIMITED
PROTECTION.
| 6 - ACCIDENTAL RELEASE MEASURES | |
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
DO NOT WALK THROUGH SPILLED MATERIAL. WEAR APPROPRIATE PERSONAL PROTECTIVE
EQUIPMENT (PPE)
EMERGENCY PROCEDURES:
AS AN IMMEDIATE PRECAUTIONARY MEASURE, ISOLATE SPILL OR LEAK AREA FOR AT
LEAST 25 METERS (75 FEET) IN ALL DIRECTIONS.
6.2 ENVIRONMENTAL PRECAUTIONS: AVOID RUN OFF TO WATERWAYS AND SEWERS.
6.3 METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAINMENT/CLEAN-UP MEASURES:
AVOID GENERATING DUST. SWEEP OR VACUUM UP MATERIAL FOR DISPOSAL OR
RECOVERY.
6.4 REFERENCE TO OTHER SECTIONS:
REFER TO SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION AND
SECTION 13 - DISPOSAL CONSIDERATIONS.
| 7 - HANDLING AND STORAGE | |
7.1 PRECAUTIONS FOR SAFE HANDLING:
HANDLING:
NO SPECIAL PRECAUTIONS NECESSARY FOR NORMAL HANDLING OF THE MATERIAL. USE
ONLY WITH ADEQUATE VENTILATION. DO NOT BREATHE DUST. WEAR APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT, AVOID DIRECT CONTACT.
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
NO SPECIAL PRECAUTIONS NECESSARY FOR NORMAL STORAGE OF THE MATERIAL. KEEP
CONTAINER/PACKAGE TIGHTLY CLOSED AND IN A WELL-VENTILATED PLACE. STORE
LOCKED UP.
7.3 SPECIFIC END USE(S): REFER TO SECTION 1.2 - RELEVANT IDENTIFIED USES.
| 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1 CONTROL PARAMETERS:
RESULT ACGIH NIOSH
QUARTZ TWAS 0.025 MG/M3 TWA 0.05 MG/M3 TWA
(14808-60-7) (RESPIRABLE FRACTION) (RESPIRABLE DUST)
MAKS NOT ESTABLISHED NOT ESTABLISHED
8.2 EXPOSURE CONTROLS:
ENGINEERING MEASURES/CONTROLS:
GOOD GENERAL VENTILATION SHOULD BE USED. VENTILATION RATES SHOULD BE
MATCHED TO CONDITIONS. IF APPLICABLE, USE PROCESS ENCLOSURES, LOCAL EXHAUST
VENTILATION, OR OTHER ENGINEERING CONTROLS TO MAINTAIN AIRBORNE LEVELS
BELOW RECOMMENDED EXPOSURE LIMITS. IF EXPOSURE LIMITS HAVE NOT BEEN
ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN ACCEPTABLE LEVEL.
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY:
FOR LIMITED EXPOSURE USE AN N95 DUST MASK. FOR PROLONGED EXPOSURE USE AN
AIR-PURIFYING RESPIRATOR WITH HIGH EFFICIENCY PARTICULATE AIR (HEPA)
FILTERS. FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134
OR EUROPEAN STANDARD EN 149. USE A NIOSH/MSHA OR EUROPEAN STANDARD EN 149
APPROVED RESPIRATOR IF EXPOSURE LIMITS ARE EXCEEDED OR SYMPTOMS ARE
EXPERIENCED.
EYE/FACE: WEAR SAFETY GLASSES.
SKIN/BODY: WEAR PROTECTIVE CLOTHING AND GLOVES.
ENVIRONMENTAL EXPOSURE CONTROLS:
CONTROLS SHOULD BE ENGINEERED TO PREVENT RELEASE TO THE ENVIRONMENT,
INCLUDING PROCEDURES TO PREVENT SPILLS, ATMOSPHERIC RELEASE AND RELEASE
TO WATERWAYS. FOLLOW BEST PRACTICE FOR SITE MANAGEMENT AND DISPOSAL OF
WASTE.
KEY TO ABBREVIATIONS:
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENE
LLV: LIMIT LEVEL VALUE IS THE EXPOSURE LIMIT FOR 8-HOUR WORK DAY
MAK:
MAXIMALE ARBEITSPLATZ KONZENTRATION IS THE MAXIMUM PERMISSIBLE
CONCENTRATION
MAC: MAXIMUM ALLOWABLE CONCENTRATION
NIOSH: NATIONAL INSTITUTE OF OCCUPATIONAL SAFETY AND HEALTH
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
PEL: PERMISSIBLE EXPOSURE LEVEL BY OSHA
STEL: SHORT TERM EXPOSURE LIMIT ARE BASED ON 15 MINUTE EXPOSURES
STEV: SHORT TERM EXPOSURE VALUE
TLV: THRESHOLD LIMIT VALUE DETERMINED BY ACHIG
TWA: TIME WEIGHTED AVERAGES ARE BASED ON 8HR/DAY, 40HR/WEEK
| 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
9.1 INFORMATION ON PHYSICAL AND CHEMICAL PROPERTIES:
MATERIAL DESCRIPTION:
PHYSICAL FORM: SOLID
APPEARANCE/DESCRIPTION: REDDISH BROWN TO PINK GRAINS
COLOR: REDDISH BROWN TO PINK.
ODOR: ODORLESS
PARTICULATE SIZE: VARIES UPON CUSTOMER DEMAND
ODOR THRESHOLD: DATA LACKING
GENERAL PROPERTIES:
BOILING POINT: DATA LACKING
MELTING POINT: 1315 DEG. C (2399 F)
DECOMPOSITION TEMPERATURE: >750 C (>1382 F)
PH: NOT RELEVANT
SPECIFIC GRAVITY/RELATIVE DENSITY: 4.1 WATER=1
BULK DENSITY: 2.4 G/CM3
WATER SOLUBILITY: INSOLUBLE
VISCOSITY: DATA LACKING
EXPLOSIVE PROPERTIES: NON-EXPLOSIVE
OXIDIZING PROPERTIES: DATA LACKING
VOLATILITY:
VAPOR PRESSURE: NOT RELEVANT
VAPOR DENSITY: NOT RELEVANT
EVAPORATION RATE: NOT RELEVANT
VOC (WT.): NOT RELEVANT
FLAMMABILITY:
FLASH POINT: NOT RELEVANT
UEL: NOT RELEVANT
LEL: NOT RELEVANT
AUTOIGNITION: DATA LACKING
FLAMMABILITY (SOLID, GAS): NON-FLAMMABLE
ENVIRONMENTAL:
OCTANOL/WATER PARTITION COEFFICIENT: DATA LACKING
9.2 OTHER INFORMATION:
NO ADDITIONAL PHYSICAL AND CHEMICAL PARAMETERS NOTED.
| 10 - STABILITY AND REACTIVITY | |
10.1 REACTIVITY:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
10.2 CHEMICAL STABILITY: STABLE
10.3 POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4 CONDITIONS TO AVOID: NO DATA AVAILABLE.
10.5 INCOMPATIBLE MATERIALS: NONE KNOWN.
10.6 HAZARDOUS DECOMPOSITION PRODUCTS: NONE KNOWN.
| 11 - TOXICOLOGICAL INFORMATION | |
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS:
COMPONENTS:
IRON (0.01% TO 0.2%) 7439-89-6:
ACUTE TOXICITY:
INGESTION/ORAL-RAT LD50: 750 MG/KG
BLOOD: CHANGES IN SERUM COMPOSITION (E.G., TP, BILIRUBIN CHOLESTEROL)
BIOCHEMICAL:
ENZYME INHIBITION, INDUCTION, OR CHANGE IN B/OOD OR TISSUE LEVELS:
TRANSAMINASES
QUARTZ (<0.65%) 4808-60-7:
ACUTE TOXICITY:
INHALATION-HUMAN TCLO: 16 MPPCF 8 HOUR(S) 17.9 YEAR(S)-INTERMITTENT
LUNGS, THORAX, OR RESPIRATION: FIBROSIS, FOCAL (PNEUMOCONIOSIS)
LUNGS, THORAX, OR RESPIRATION: COUGH
LUNGS, THORAX, OR RESPIRATION: DYSPNEA
INHALATION-RAT TCLO: 200 MG/KG
LUNGS, THORAX, OR RESPIRATION: FIBROSIS, FOCAL (PNEUMOCONIOSIS)
LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
NUTRITIONAL AND GROSS METABOLIC:
CHANGES IN CHEMISTRY OR TEMPERATURE: Fe
MULTI-DOSE TOXICITY:
INHALATION-HAMSTER TCLO: 3 MG/M3 6 HOUR(S) 78 WEEK(S)-INTERMITTENT
LUNGS, THORAX, OR RESPIRATION: FIBROSIS (INTERSTITIAL)
LUNGS, THORAX, OR RESPIRATION: CHANGES IN LUNG WEIGHT
INHALATION-RAT TCLO: 6.2 MG/M3 6 HOUR(S) 6 WEEK(S)-INTERMITTENT
LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
BLOOD: CHANGES IN SPLEEN
IMMUNOLOGICAL INCLUDING ALLERGIC: INCREASE IN CELLULAR IMMUNE RESPONSE
INHALATION-RAT TCLO: 80 MG/M3 26 WEEK(S) - INTERMITTENT
LUNGS, THORAX, OR RESPIRATION: FIBROSIS, FOCAL (PNEUMOCONIOSIS)
BLOOD: CHANGES IN SPLEEN
IMMUNOLOGICAL INCLUDING ALLERGIC: DECREASE IN CELLULAR IMMUNE RESPONSE
TUMORIGEN / CARCINOGEN:
INHALATION-RAT TCLO: 50 MG/M3 6 HOUR(S) 71 WEEK(S)-INTERMITTENT
TUMORIGENIC: CARCINOGENIC BY RTECS CRITERIA
LIVER: TUMORS
GHS PROPERTIES CLASSIFICATION
ACUTE TOXICITY EU/CLP: DATA LACKING
OSHA HCS 2012: DATA LACKING
ASPIRATION HAZARD EU/CLP: DATA LACKING
OSHA HCS 2012: DATA LACKING
CARCINOGENICITY EU/CLP: DATA LACKING
OSHA HCS 2012: CARCINOGENICITY 1A
GERM CEN MUTAGENICITY EU/CLP: DATA LACKING
OSHA HCS 2012: DATA LACKING
SKIN CORROSION/IRRITATION EU/CLP: DATA LACKING
OSHA HCS 2012: DATA LACKING
SKIN SENSITIZATION EU/CLP: DATA LACKING
OSHA HCS 2012: DATA LACKING
STOT-RE EU/CLP:
OSHA HCS 2012: DATA LACKING
STOT-SE EU/CLP: DATA LACKING
OSHA HCS 2012: DATA LACKING
TOXICITY FOR REPRODUCTION EU/CLP: DATA LACKING
OSHA HCS 2012: DATA LACKING
RESPIRATORY SENSITIZATION EU/CLP: DATA LACKING
OSHA HCS 2012: DATA LACKING
SERIOUS EYE DAMAGE/IRRITATION EU/CLP: DATA LACKING
OSHA HCS 2012: DATA LACKING
POTENTIAL HEALTH EFFECTS:
INHALATION:
ACUTE (IMMEDIATE): EXPOSURE TO DUST MAY CAUSE IRRITATION.
CHRONIC (DELAYED):
INHALATION OF RESPIRABLE DUSTS CONTAINING CRYSTALLINE SILICA MAY CAUSE
LUNG INJURY OR DISEASE INCLUDING SILICOSIS AND/OR CANCER.
SKIN:
ACUTE (IMMEDIATE): MAY CAUSE ABRASIONS.
CHRONIC (DELAYED): NO DATA AVAILABLE
EYE:
ACUTE (IMMEDIATE): EXPOSURE TO DUST MAY CAUSE IRRITATION.
CHRONIC (DELAYED): NO DATA AVAILABLE
INGESTION:
ACUTE (IMMEDIATE): NO KNOWN EFFECTS, HOWEVER INGESTION NOT RECOMMENDED
CHRONIC (DELAYED): NO DATA AVAILABLE
CARCINOGENIC EFFECTS:
MAY CAUSE CANCER. THIS PRODUCT CONTAINS CRYSTALLINE SILICA AS CRISTOBALITE
AND/OR QUARTZ. IARC MONOGRAPHS ON EVALUATION OF CARCINOGENIC RISK OF
CHEMICALS TO HUMANS (MONOGRAPH 68, 1997) CONCLUDES THAT THERE IS SUFFICIENT
EVIDENCE FOR THE CARCINOGENICITY OF CRYSTALLINE SILICA TO HUMANS
(IARC GROUP I). CRYSTALLINE SILICA IS CLASSIFIED AS A KNOWN CARCINOGEN
ACCORDING TO NTP
CARCINOGENIC EFFECTS:
CAS IARC NTP
QUARTZ 14808-60-7 GROUP 1-CARCINOGENIC KNOWN HUMAN CARCINOGEN
KEY TO ABBREVIATIONS:
LD = LETHAL DOSE
TC = TOXIC CONCENTRATION
| 12 - ECOLOGICAL INFORMATION | |
12.1 TOXICITY: MATERIAL DATA LACKING.
12.2 PERSISTENCE AND DEGRADABILITY: MATERIAL DATA LACKING.
12.3 BIOACCUMULATIVE POTENTIAL: MATERIAL DATA LACKING.
12.4 MOBILITY IN SOIL: MATERIAL DATA LACKING.
12.5 RESULTS OF PBT AND VPVB ASSESSMENT:
NO PBT AND VPVB ASSESSMENT HAS BEEN CONDUCTED.
12.6 OTHER ADVERSE EFFECTS: NO STUDIES HAVE BEEN FOUND.
| 13 - DISPOSAL CONSIDERATIONS | |
13.1 WASTE TREATMENT METHODS:
PRODUCT WASTE:
DISPOSE OF CONTENT AND/OR CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL,
NATIONAL, AND/OR INTERNATIONAL REGULATIONS.
PACKAGING WASTE:
DISPOSE OF CONTENT AND/OR CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL,
NATIONAL, AND/OR INTERNATIONAL REGULATIONS
| 14 - TRANSPORT INFORMATION | |
14.1 UN 14.2 UN 14.3 14.4 14.5
NUMBER PROPER TRANSPORT PACKING ENVIRONMENTAL
SHIPPING NAME HAZARD GROUP HAZARDS
CLASS(ES)
DOT NDA NOT REGULATED NDA NDA NDA
TDG NDA NOT REGULATED NDA NDA NDA
IMO/IMD NDA NOT REGULATED NDA NDA NDA
IATA/ICA NDA NOT REGULATED NDA NDA NDA
14.6 SPECIAL PRECAUTIONS FOR USER: NONE SPECIFIED.
14.7 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC
CODE: DATA LACKING.
| 15 - REGULATORY INFORMATION | |
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC
FOR THE SUBSTANCE OR MIXTURE:
SARA HAZARD CLASSIFICATIONS: CHRONIC
INVENTORY:
COMPONENT CAS CANADA CANADA CHIN EU EU
DSL NDSL EINECS ELNICS
ALMANDINE / ALMANDITE 1302-62-1 NO NO NO NO NO
FERRIC ALUMINUM
SILICATE
FELDSPARS 68476-25-5 NO YES YES YES NO
HORNBLENDE 12178-42-6 NO NO NO NO NO
IRON 7439-89-6 YES NO YES YES NO
QUARTZ 14808-60-7 YES NO YES YES NO
CANADA:
LABOR:
CANADA - WHMIS - CLASSIFICATIONS OF SUBSTANCES:
IRON 7439-89-6 UNCONTROLLED PRODUCT
ACCORDING TO WHMIS
CLASSIFICATION CRITERIA
FELDSPARS 68476-25-5 NOT LISTED
ALMANDINE / ALMANDITE-FERRIC 1302-62-1 NOT LISTED
ALUMINUM SILICATE
QUARTZ 14808-60-7 D2A (IN CERTAIN CASES,
THIS CLASSIFICATION DOES
NOT APPLY. FOR MORE
INFORMATION, CONSULT
THE SECTION SUBSTANCE
SPECIFIC ISSUES - SILICA,
CRYSTALLINE, ENCAPSULATED
ON HEALTH CANADA'S WHMIS
DIVISION WEBSITE.
HORNBLENDE 12178-42-6 NOT LISTED
CANADA - WHMIS - INGREDIENT DISCLOSURE LIST:
IRON 7439-89-6 NOT LISTED
FELDSPARS 68476-25-5 NOT LISTED
ALMANDITE-FERRIC ALUMINUM 1302-62-1 NOT LISTED
SILICATE
QUARTZ 14808-60-7 1%
HORNBLENDE 12178-42-6 NOT LISTED
ENVIRONMENT:
CANADA - CEPA - PRIORITY SUBSTANCES LIST:
IRON 7439-89-6 NOT LISTED
FELDSPARS 68476-25-5 NOT LISTED
ALMANDINE / ALMANDITE-FERRIC 1302-62-1 NOT LISTED
ALUMINUM SILICATE
QUARTZ 14808-60-7 NOT LISTED
HORNBLENDE 12178-42-6 NOT LISTED
EUROPE:
ENVIRONMENT:
EU - AIR POLLUTION (2001/379/EC) - HEAVY METAL POLLUTANTS:
IRON 7439-89-6 NOT LISTED
FELDSPARS 68476-25-5 NOT LISTED
ALMANDITE-FERRIC ALUMINUM 1302-62-1 NOT LISTED
SILICATE
QUARTZ 14808-60-7 NOT LISTED
HORNBLENDE 12178-42-6 NOT LISTED
EU - SUBSTANCES DEPLETING THE OZONE LAYER (1005/2009) -
ANNEX I SUBSTANCES: 7439-89-6 NOT LISTED
FELDSPARS 68476-25-5 NOT LISTED
ALMANDITE-FERRIC ALUMINUM 1302-62-1 NOT LISTED
SILICATE
QUARTZ 14808-60-7 NOT LISTED
HORNBLENDE 12178-42-6 NOT LISTED
OTHER:
EU - EXPORT AND IMPORT RESTRICTIONS (689/2008) - CHEMICALS AND ARTICLES
SUBJECT TO EXPORT BAN:
IRON 7439-89-6 NOT LISTED
FELDSPARS 68476-25-5 NOT LISTED
ALMANDITE-FERRIC ALUMINUM 1302-62-1 NOT LISTED
SILICATE
QUARTZ 14808-60-7 NOT LISTED
HORNBLENDE 12178-42-6 NOT LISTED
EU - EXPORT AND IMPORT RESTRICTIONS (689/2008) - CHEMICALS QUALIFYING FOR
PIC NOTIFICATION:
IRON 7439-89-6 NOT LISTED
FELDSPARS 68476-25-5 NOT LISTED
ALMANDITE-FERRIC ALUMINUM 1302-62-1 NOT LISTED
SILICATE
QUARTZ 14808-60-7 NOT LISTED
HORNBLENDE 12178-42-6 NOT LISTED
EU - WATER FRAMEWORK DIRECTIVE (2000/60/EC) - LIST OF PRIORITY
SUBSTANCES - ANNEX X:
IRON 7439-89-6 NOT LISTED
FELDSPARS 68476-25-5 NOT LISTED
ALMANDITE-FERRIC ALUMINUM 1302-62-1 NOT LISTED
SILICATE
QUARTZ 14808-60-7 NOT LISTED
HORNBLENDE 12178-42-6 NOT LISTED
12178-42-6 NOT LISTED
FELDSPARS 68476-25-5 NOT LISTED
ALMANDITE-FERRIC ALUMINUM 1302-62-1 NOT LISTED
SILICATE
QUARTZ 14808-60-7 NOT LISTED
HORNBLENDE 12178-42-6 NOT LISTED
FELDSPARS 68476-25-5 NOT LISTED
ALMANDITE-FERRIC ALUMINUM 1302-62-1 NOT LISTED
SILICATE
QUARTZ 14808-60-7 NOT LISTED
HORNBLENDE 12178-42-6 NOT LISTED
MEXICO:
ENVIRONMENT:
MEXICO - ECOLOGICAL CRITERIA FOR WATER QUALITY - AGRICULTURAL IRRIGATION:
IRON 7439-89-6 5.0 MG/L
FELDSPARS 68476-25-5 NOT LISTED
ALMANDITE-FERRIC ALUMINUM 1302-62-1 NOT LISTED
SILICATE
QUARTZ 14808-60-7 NOT LISTED
HORNBLENDE 12178-42-6 NOT LISTED
MEXICO - ECOLOGICAL CRITERIA FOR WATER QUALITY - DRINKING WATER SUPPLY:
SOURCE:
IRON 7439-89-6 0.3 MG/L
FELDSPARS 68476-25-5 NOT LISTED
ALMANDITE-FERRIC ALUMINUM 1302-62-1 NOT LISTED
SILICATE
QUARTZ 14808-60-7 NOT LISTED
HORNBLENDE 12178-42-6 NOT LISTED
MEXICO - ECOLOGICAL CRITERIA FOR WATER QUALITY - PROTECTION OF FRESH
WATER AQUATIC LIFE:
IRON 7439-89-6 1.0 MG/L
FELDSPARS 68476-25-5 NOT LISTED
ALMANDITE-FERRIC ALUMINUM 1302-62-1 NOT LISTED
SILICATE
QUARTZ 14808-60-7 NOT LISTED
HORNBLENDE 12178-42-6 NOT LISTED
MEXICO - ECOLOGICAL CRITERIA FOR WATER QUALITY - PROTECTION OF MARINE
WATER AQUATIC LIFE:
IRON 7439-89-6 0.05 MG/L
FELDSPARS 68476-25-5 NOT LISTED
ALMANDITE-FERRIC ALUMINUM 1302-62-1 NOT LISTED
SILICATE
QUARTZ 14808-60-7 NOT LISTED
HORNBLENDE 12178-42-6 NOT LISTED
UNITED STATES:
LABOR:
U.S. - OSHA - PROCESS SAFETY MANAGEMENT - HIGHLY HAZARDOUS CHEMICALS:
IRON 7439-89-6 NOT LISTED
FELDSPARS 68476-25-5 NOT LISTED
ALMANDITE-FERRIC ALUMINUM 1302-62-1 NOT LISTED
SILICATE
QUARTZ 14808-60-7 NOT LISTED
HORNBLENDE 12178-42-6 NOT LISTED
U.S. - OSHA - SPECIFICALLY REGULATED CHEMICALS:
IRON 7439-89-6 NOT LISTED
FELDSPARS 68476-25-5 NOT LISTED
ALMANDITE-FERRIC ALUMINUM 1302-62-1 NOT LISTED
SILICATE
QUARTZ 14808-60-7 NOT LISTED
HORNBLENDE 12178-42-6 NOT LISTED
ENVIRONMENT:
U.S. - CAA (CLEAN AIR ACT) - 1990 HAZARDOUS AIR POLLUTANTS:
IRON 7439-89-6 NOT LISTED
FELDSPARS 68476-25-5 NOT LISTED
ALMANDITE-FERRIC ALUMINUM 1302-62-1 NOT LISTED
SILICATE
QUARTZ 14808-60-7 NOT LISTED
HORNBLENDE 12178-42-6 NOT LISTED
U.S. - CERCLA/SARA - HAZARDOUS SUBSTANCES AND THEIR REPORTABLE QUANTITIES:
IRON 7439-89-6 NOT LISTED
FELDSPARS 68476-25-5 NOT LISTED
ALMANDITE-FERRIC ALUMINUM 1302-62-1 NOT LISTED
SILICATE
QUARTZ 14808-60-7 NOT LISTED
HORNBLENDE 12178-42-6 NOT LISTED
U.S. - CERCLA/SARA - RADIONUCLIDES AND THEIR REPORTABLE QUANTITIES:
IRON 7439-89-6 NOT LISTED
FELDSPARS 68476-25-5 NOT LISTED
ALMANDITE-FERRIC ALUMINUM 1302-62-1 NOT LISTED
SILICATE
QUARTZ 14808-60-7 NOT LISTED
HORNBLENDE 12178-42-6 NOT LISTED
U.S. - CERCLA/SARA - SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES EPCRA RQS:
IRON 7439-89-6 NOT LISTED
FELDSPARS 68476-25-5 NOT LISTED
ALMANDITE-FERRIC ALUMINUM 1302-62-1 NOT LISTED
SILICATE
QUARTZ 14808-60-7 NOT LISTED
HORNBLENDE 12178-42-6 NOT LISTED
U.S. - CERCLA/SARA - SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES TPQS:
IRON 7439-89-6 NOT LISTED
FELDSPARS 68476-25-5 NOT LISTED
ALMANDITE-FERRIC ALUMINUM 1302-62-1 NOT LISTED
SILICATE
QUARTZ 14808-60-7 NOT LISTED
HORNBLENDE 12178-42-6 NOT LISTED
U.S. - CERCLA/SARA - SECTION 313 - EMISSION REPORTING:
IRON 7439-89-6 NOT LISTED
FELDSPARS 68476-25-5 NOT LISTED
ALMANDITE-FERRIC ALUMINUM 1302-62-1 NOT LISTED
SILICATE
QUARTZ 14808-60-7 NOT LISTED
HORNBLENDE 12178-42-6 NOT LISTED
U.S. - CERCLA/SARA - SECTION 313 - PBT CHEMICAL LISTING:
IRON 7439-89-6 NOT LISTED
FELDSPARS 68476-25-5 NOT LISTED
ALMANDITE-FERRIC ALUMINUM 1302-62-1 NOT LISTED
SILICATE
QUARTZ 14808-60-7 NOT LISTED
HORNBLENDE 12178-42-6 NOT LISTED
UNITED STATES - CALIFORNIA:
ENVIRONMENT:
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST:
IRON 7439-89-6 NOT LISTED
FELDSPARS 68476-25-5 NOT LISTED
ALMANDITE-FERRIC ALUMINUM 1302-62-1 NOT LISTED
SILICATE
QUARTZ 14808-60-7 CARCINOGEN:
INITIAL DATE-0/1/88
(AIRBORNE PARTICLES
OF RESPIRABLE SIZE)
HORNBLENDE 12178-42-6 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY:
IRON 7439-89-6 NOT LISTED
FELDSPARS 68476-25-5 NOT LISTED
ALMANDITE-FERRIC ALUMINUM 1302-62-1 NOT LISTED
SILICATE
QUARTZ 14808-60-7 NOT LISTED
HORNBLENDE 12178-42-6 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - MAXIMUM ALLOWABLE DOSE LEVELS (MADL):
IRON 7439-89-6 NOT LISTED
FELDSPARS 68476-25-5 NOT LISTED
ALMANDITE-FERRIC ALUMINUM 1302-62-1 NOT LISTED
SILICATE
QUARTZ 14808-60-7 NOT LISTED
HORNBLENDE 12178-42-6 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - NO SIGNIFICANT RISK LEVELS (NSRL):
IRON 7439-89-6 NOT LISTED
FELDSPARS 68476-25-5 NOT LISTED
ALMANDITE-FERRIC ALUMINUM 1302-62-1 NOT LISTED
SILICATE
QUARTZ 14808-60-7 NOT LISTED
HORNBLENDE 12178-42-6 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE:
IRON 7439-89-6 NOT LISTED
FELDSPARS 68476-25-5 NOT LISTED
ALMANDITE-FERRIC ALUMINUM 1302-62-1 NOT LISTED
SILICATE
QUARTZ 14808-60-7 NOT LISTED
HORNBLENDE 12178-42-6 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE:
IRON 7439-89-6 NOT LISTED
FELDSPARS 68476-25-5 NOT LISTED
ALMANDITE-FERRIC ALUMINUM 1302-62-1 NOT LISTED
SILICATE
QUARTZ 14808-60-7 NOT LISTED
HORNBLENDE 12178-42-6 NOT LISTED
15.2 CHEMICAL SAFETY ASSESSMENT:
NO CHEMICAL SAFETY ASSESSMENT HAS BEEN CARRIED OUT.
15.3 OTHER INFORMATION:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
| 16 - OTHER INFORMATION | |
RELEVANT PHRASES (CODE & FULL TEXT):
H335: MAY CAUSE RESPIRATORY IRRITATION
H302: HARMFUL IF SWALLOWED
H372: CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
R22: HARMFUL IF SWALLOWED.
R37: IRRITATING TO RESPIRATORY SYSTEM.
R48/20:
HARMFUL:
DANGER OF SERIOUS DAMAGE TO HEALTH BY PROLONGED EXPOSURE THROUGH
INHALATION.
KEY TO ABBREVIATIONS:
NDA = NO DATA AVAILABLE
DISCLAIMER/STATEMENT OF LIABILITY:
THE INFORMATION IN THIS MSDS WAS OBTAINED FROM SOURCES THAT ARE BELIEVED
TO BE RELIABLE; HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY
REPRESENTATION OR WARRANTY, EXPRESS OR IMPLIED, REGARDING ITS ACCURACY OR
CORRECTNESS. THE CONDITIONS OR METHODS OF HANDLING, STORAGE, USE, AND
DISPOSAL OF THIS PRODUCT ARE BEYOND OUR CONTROL AND MAY BE BEYOND OUR
KNOWLEDGE. FOR THIS AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND
EXPRESSLY DISCLAIM LIABILITY FOR LOSS, DAMAGE, OR EXPENSE ARISING OUT OF,
OR IN ANY WAY CONNECTED WITH, THE HANDLING, STORAGE, USE OR DISPOSAL OF
THIS PRODUCT.