| Common Name: | HVAC PROFESSIONAL 100% RTV SILICONE SEALANT ALL COLORS |
| Manufacturer: | DAP |
| SDS Revision Date: | 3/21/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 406W22, 406W23, 406W24 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SDS NUMBER: 00015007001
REVISION DATE: 3/21/2017
DAP(R*)
SAFETY DATA SHEET
24 HOUR EMERGENCY PHONE NUMBERS MEDICAL/POISON CONTROL:
IN U.S.: CALL 1-800-222-1222
OUTSIDE U.S.: CALL YOUR LOCAL POISON CONTROL CENTER
TRANSPORTATION/NATIONAL RESPONSE CENTER:
1-800-535-5053
1-352-323-3500
NOTE:
THE NATIONAL RESPONSE CENTER EMERGENCY NUMBERS TO BE USED ONLY IN THE EVENT
OF CHEMICAL EMERGENCIES INVOLVING A SPILL, LEAK, FIRE, EXPOSURE OR ACCIDENT
INVOLVING CHEMICALS.
IMPORTANT:
PROVIDE THIS INFORMATION TO EMPLOYEES, CUSTOMERS, AND USERS OF THIS
PRODUCT. READ THIS SDS BEFORE HANDLING OR DISPOSING OF THIS PRODUCT. THIS
PRODUCT IS COVERED BY THE OSHA HAZARD COMMUNICATION STANDARD AND THIS
DOCUMENT HAS BEEN PREPARED IN ACCORDANCE WITH REQUIREMENTS OF THIS
STANDARD. ALL ABBREVIATED TERMS USED IN THIS SDS ARE FURTHER DESCRIBED IN
SECTION 16.
| 1. IDENTIFICATION |  |
THIS SAFETY DATA SHEET IS AVAILABLE IN AMERICAN SPANISH UPON REQUEST.
PRODUCT NAME: DAP HVAC PROFESSIONAL 100% RTV SILICONE SEALANT ALL COLORS
PRODUCT UPC NUMBER: 070798080102, 070798080126
PRODUCT USE/CLASS: CAULKING COMPOUND
MANUFACTURED FOR:
DAP PRODUCTS INC.
2400 BOSTON STREET SUITE 200
BALTIMORE, MD 21224-4723
888-327-8477 (NON - EMERGENCY MATTERS)
EMERGENCY TELEPHONE: 1-800-535-5053, 1-352-323-3500, 1-800-222-1222
SAFETY DATA SHEET COORDINATOR: MSDS@DAP.COM
REVISION DATE: 3/21/2017
SUPERCEDES DATE: NEW SDS
SDS NO: 00015007001
PREPARER: REGULATORY DEPARTMENT
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
UNDER NORMAL USE CONDITIONS, THIS PRODUCT IS NOT EXPECTED TO CAUSE ADVERSE
HEALTH EFFECTS. HIGH CONCENTRATION OF VAPORS MAY CAUSE IRRITATION TO EYES
AND RESPIRATORY SYSTEM.
GHS CLASSIFICATION: CARC. 1B
SYMBOL(S) OF PRODUCT: HEALTH HAZARD
SIGNAL WORD: DANGER
POSSIBLE HAZARDS:
3% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE TOXICITY
GHS HAZARD STATEMENTS:
CARCINOGENICITY, CATEGORY 1B:
H350: MAY CAUSE CANCER.
GHS LABEL PRECAUTIONARY STATEMENTS:
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P405: STORE LOCKED UP.
P501: DISPOSE OF CONTENTS/CONTAINER TO
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS-NO. WT. %
PROPRIETARY POLYMER 63148-62-9 10-25
SILICA, AMORPHOUS 7631-86-9 2.5-10
HYDROTREATED MIDDLE DISTILLATE 64742-46-7 2.5-10
SILANETRIOL, METHYL-, TRIACETA 4253-34-3 2.5-10
ETHYLTRIACETOXYSILANE 17689-77-9 2.5-10
TITANIUM DIOXIDE 13463-67-7 1.0-2.5
ALUMINUM 7429-90-5 1.0-2.5
CARBON BLACK 1333-86-4 1.0-2.5
CHEMICAL NAME GHS SYMBOLS GHS STATEMENTS
PROPRIETARY POLYMER NO INFORMATION NO INFORMATION
SILICA, AMORPHOUS GHS07 H332
HYDROTREATED MIDDLE DISTILLATE GHS07-GHS08 H332-350
SILANETRIOL, METHYL-, TRIACETA GHS07 H302-312-315-319-332
ETHYLTRIACETOXYSILANE GHS07 H302-312-315-319-332
TITANIUM DIOXIDE NO INFORMATION NO INFORMATION
ALUMINUM GHS02-GHS06 H228-250-261-312-331
CARBON BLACK NO INFORMATION NO INFORMATION
THE TEXT FOR GHS HAZARD STATEMENTS SHOWN ABOVE (IF ANY) IS GIVEN IN THE
"OTHER INFORMATION" SECTION.
| 4. FIRST-AID MEASURES | |
FIRST AID - INHALATION:
MATERIAL IS NOT LIKELY TO PRESENT AN INHALATION HAZARD AT AMBIENT
CONDITIONS. IF YOU EXPERIENCE DIFFICULTY IN BREATHING, LEAVE THE AREA TO
OBTAIN FRESH AIR. IF CONTINUED DIFFICULTY IS EXPERIENCED, GET MEDICAL
ATTENTION IMMEDIATELY.
FIRST AID - SKIN CONTACT:
WASH SKIN WITH SOAP AND WATER FOR 15 MINUTES. GET MEDICAL AID IF SYMPTOMS
PERSIST.
FIRST AID - EYE CONTACT:
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH LARGE QUANTITIES OF WATER
FOR AT LEAST 15 MINUTES UNTIL IRRITATION SUBSIDES. GET MEDICAL ATTENTION
IMMEDIATELY.
FIRST AID - INGESTION:
IF SWALLOWED, DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION IMMEDIATELY.
| 5. FIRE-FIGHTING MEASURES | |
UNUSUAL FIRE AND EXPLOSION HAZARDS: NO INFORMATION
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND (NIOSH APPROVED OR
EQUIVALENT) AND FULL PROTECTIVE GEAR. USE WATER SPRAY TO COOL EXPOSED
SURFACES.
EXTINGUISHING MEDIA: CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER FOG
| 6. ACCIDENTAL RELEASE MEASURES | |
ENVIRONMENTAL MEASURES: NO INFORMATION
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
CONTAIN SPILLED MATERIAL AND REMOVE WITH INERT ABSORBENT. DISPOSE OF
CONTAMINATED ABSORBENT, CONTAINER AND UNUSED CONTENTS IN ACCORDANCE WITH
LOCAL, STATE AND FEDERAL REGULATIONS. SCRAPE UP DRIED MATERIAL AND PLACE
INTO CONTAINERS. USE PERSONAL PROTECTIVE EQUIPMENT AS NECESSARY. IN CASE OF
SPILLAGE, ABSORB WITH INERT MATERIAL AND DISPOSE OF IN ACCORDANCE WITH
APPLICABLE REGULATIONS.
| 7. HANDLING AND STORAGE | |
HANDLING:
KEEP OUT OF REACH OF CHILDREN!
DO NOT TAKE INTERNALLY. AVOID BREATHING VAPOR AND CONTACT WITH EYES,
SKIN AND CLOTHING. USE ONLY WITH ADEQUATE VENTILATION. ENSURE FRESH
AIR ENTRY DURING APPLICATION AND DRYING. WASH THOROUGHLY AFTER HANDLING.
REMOVE CONTACT LENSES BEFORE USING. DO NOT HANDLE CONTACT LENSES UNTIL
ALL SEALANT HAS BEEN CLEANED FROM FINGERTIPS, NAILS AND CUTICLES. RESIDUAL
SEALANT MAY TRANSFER TO CONTACT LENSES AND CAUSE SEVERE EYE IRRITATION.
STORAGE:
AVOID EXCESSIVE HEAT AND FREEZING. DO NOT STORE AT TEMPERATURES ABOVE 120
DEGREES F. STORE AWAY FROM CAUSTICS AND OXIDIZERS.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
INGREDIENTS WITH OCCUPATIONAL EXPOSURE LIMITS:
CHEMICAL NAME ACGIH ACGIH-TLV OSHA OSHA PEL-
TLV-TWA STEL PEL-TWA CEILING
PROPRIETARY POLYMER N.E. N.E. N.E. N.E.
SILICA, AMORPHOUS N.E. N.E. N.E. N.E.
HYDROTREATED MIDDLE N.E. N.E. N.E. N.E.
DISTILLATE
ETHYLTRIACETOXYSILANE N.E. N.E. N.E. N.E.
SILANETRIOL, METHYL-, N.E. N.E. N.E. N.E.
TRIACETA
TITANIUM DIOXIDE 10 MG/M3 TWA N.E. 15 MG/M3 TWA N.E.
TOTAL DUST
ALUMINUM 1 MG/M3 TWA N.E. 15 MG/M3 TWA N.E.
RESPIRABLE TOTAL DUST,
PARTICULATE 5 MG/M3 TWA
MATTER RESPIRABLE
FRACTION
CARBON BLACK 3 MG/M3 TWA N.E. 3.5 MG/M3 N.E.
INHALABLE TWA
PARTICULATE
MATTER
FURTHER ADVICE:
MEL = MAXIMUM EXPOSURE LIMIT
OES = OCCUPATIONAL EXPOSURE STANDARD
SUP = SUPPLIER'S RECOMMENDATION
SK = SKIN SENSITIZER
N.E. = NOT ESTABLISHED
PERSONAL PROTECTION:
RESPIRATORY PROTECTION:
NO PERSONAL RESPIRATORY PROTECTIVE EQUIPMENT NORMALLY REQUIRED.
FULL-FACE RESPIRATOR
SKIN PROTECTION: WEAR NITRILE OR NEOPRENE GLOVES.
GLOVES
EYE PROTECTION: GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS.
SAFETY GLASSES
OTHER PROTECTIVE EQUIPMENT: NOT REQUIRED UNDER NORMAL USE.
FULL SUIT
HYGIENIC PRACTICES:
WASH HANDS BEFORE BREAKS AND AT THE END OF WORKDAY. REMOVE AND WASH
CONTAMINATED CLOTHING BEFORE RE-USE.
HAND WASH
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: COLORED
PHYSICAL STATE: PASTE
ODOR: SLIGHT
ODOR THRESHOLD: NOT ESTABLISHED
DENSITY, G/CM3: 1.01 - 1.01
PH: NOT ESTABLISHED
FREEZE POINT, DEG. C: NOT ESTABLISHED
VISCOSITY (MPA.S): NOT ESTABLISHED
SOLUBILITY IN WATER: NO INFORMATION
PARTITION COEFF., N-OCTANOL/WATER: NOT ESTABLISHED
DECOMPOSITION TEMPERATURE, DEG. C: NOT ESTABLISHED
EXPLOSIVE LIMITS, %: N.I. - N.I.
BOILING RANGE, DEG. C: N.I. - N.I.
AUTO-IGNITION TEMPERATURE, DEG. C NOT ESTABLISHED
MINIMUM FLASH POINT, DEG. C: 100
VAPOR PRESSURE, MMHG: NOT ESTABLISHED
EVAPORATION RATE: SLOWER THAN N-BUTYL ACETATE
FLASH METHOD: SETA CLOSED CUP
VAPOR DENSITY: NOT ESTABLISHED
FLAMMABILITY: NOT DETERMINED
COMBUSTIBILITY: DOES NOT SUPPORT COMBUSTION
(SEE "OTHER INFORMATION" SECTION FOR ABBREVIATION LEGEND)
(IF PRODUCT IS AN AEROSOL, THE FLASH POINT STATED ABOVE IS THAT OF THE
PROPELLANT.)
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
CONDITIONS TO AVOID: OXIDIZING AGENTS. EXCESSIVE HEAT AND FREEZING.
INCOMPATIBILITY: INCOMPATIBLE WITH STRONG BASES AND OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
NORMAL DECOMPOSITION PRODUCTS, I.E., COX, NOX.
| 11. TOXICOLOGICAL INFORMATION | |
EFFECT OF OVEREXPOSURE - INHALATION:
UNDER NORMAL USE CONDITIONS, THIS PRODUCT IS NOT EXPECTED TO CAUSE ADVERSE
HEALTH EFFECTS. DURING APPLICATION AND CURE, THIS PRODUCT RELEASES
METHANOL. DURING APPLICATION AND CURE, THIS PRODUCT RELEASES ACETIC ACID.
INHALATION OF VAPORS IN HIGH CONCENTRATION MAY CAUSE MILD IRRITATION OF
RESPIRATORY SYSTEM (NOSE, MOUTH, MUCOUS MEMBRANES).
EFFECT OF OVEREXPOSURE - SKIN CONTACT:
UNDER NORMAL USE CONDITIONS, THIS PRODUCT IS NOT EXPECTED TO CAUSE ADVERSE
HEALTH EFFECTS. PROLONGED OR REPEATED CONTACT WITH SKIN MAY CAUSE MILD
IRRITATION.
EFFECT OF OVEREXPOSURE - EYE CONTACT:
UNDER NORMAL USE CONDITIONS, THIS PRODUCT IS NOT EXPECTED TO CAUSE ADVERSE
HEALTH EFFECTS. DIRECT EYE CONTACT MAY CAUSE IRRITATION.
EFFECT OF OVEREXPOSURE - INGESTION:
UNDER NORMAL USE CONDITIONS, THIS PRODUCT IS NOT EXPECTED TO CAUSE ADVERSE
HEALTH EFFECTS. SINGLE DOSE ORAL TOXICITY IS VERY LOW. AMOUNTS INGESTED
INCIDENTAL TO INDUSTRIAL HANDLING ARE NOT LIKELY TO CAUSE INJURY; HOWEVER,
INGESTION OF LARGE AMOUNTS MAY CAUSE INJURY. INGESTION MAY RESULT IN
OBSTRUCTION WHEN MATERIAL HARDENS.
CARCINOGENICITY: NO INFORMATION
EFFECT OF OVEREXPOSURE - CHRONIC HAZARDS:
REPEATED OR PROLONGED EXPOSURE MAY CAUSE MILD IRRITATION OF EYES AND SKIN.
PRIMARY ROUTE(S) OF ENTRY: EYE CONTACT, INHALATION, SKIN CONTACT
ACUTE TOXICITY VALUES:
THE ACUTE EFFECTS OF THIS PRODUCT HAVE NOT BEEN TESTED. DATA ON INDIVIDUAL
COMPONENTS ARE TABULATED BELOW
CAS-NO. CHEMICAL NAME ORAL LD50 DERMAL LD50 VAPOR LC50
63148-62-9 PROPRIETARY POLYMER >5000 MG/KG >2008 MG/KG >20 MG/L
RAT RABBIT
7631-86-9 SILICA, AMORPHOUS >3300 MG/KG >5000 MG/KG >20 MG/L
RAT RABBIT
64742-46-7 HYDROTREATED MIDDLE 7400 MG/KG
DISTILLATE RAT RABBIT >20 MG/L
4253-34-3 SILANETRIOL, METHYL-, 1602 MG/KG 1060 MG/KG 11.6 MG/L
TRIACETA RAT RABBIT
17689-77-9 ETHYLTRIACETOXYSILANE 1460 MG/KG 1060 MG/KG 11.6 MG/KG
RAT RABBIT RAT
13463-67-7 TITANIUM DIOXIDE >10000 MG/KG >5000 MG/KG >20 MG/L
RAT RABBIT
7429-90-5 ALUMINUM >2000 MG/KG 2000 MG/KG 7.6 MG/L
RAT RAT RAT
1333-86-4 CARBON BLACK >8000 MG/KG >3000 MG/KG >20 MG/L
RAT RABBIT
N.I. = NO INFORMATION
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION:
ECOLOGICAL INJURIES ARE NOT KNOWN OR EXPECTED UNDER NORMAL USE.
| 13. DISPOSAL INFORMATION | |
DISPOSAL INFORMATION:
THIS PRODUCT DOES NOT MEET THE DEFINITION OF A HAZARDOUS WASTE ACCORDING TO
U.S. EPA HAZARDOUS WASTE MANAGEMENT REGULATION, 40 CFR SECTION 261. DISPOSE
AS HAZARDOUS WASTE ACCORDING TO ALL LOCAL, STATE, FEDERAL AND PROVINCIAL
REGULATIONS. STATE AND LOCAL REGULATIONS/RESTRICTIONS ARE COMPLEX AND MAY
DIFFER FROM FEDERAL REGULATIONS. RESPONSIBILITY FOR PROPER WASTE DISPOSAL
IS WITH THE OWNER OF THE WASTE.
| 14. TRANSPORT INFORMATION | |
SPECIAL TRANSPORT PRECAUTIONS: NO INFORMATION
DOT UN/NA NUMBER: N.A.
DOT PROPER SHIPPING NAME: NOT REGULATED
DOT TECHNICAL NAME: N.A.
DOT HAZARD CLASS: N.A.
HAZARD SUBCLASS: N.A.
PACKING GROUP: N.A.
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA "HAZARD CATEGORIES"
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
ACUTE HEALTH HAZARD, CHRONIC HEALTH HAZARD
SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
CHEMICAL NAME CAS-NO.
ALUMINUM 7429-90-5
TOXIC SUBSTANCES CONTROL ACT:
ALL INGREDIENTS IN THIS PRODUCT ARE EITHER ON TSCA INVENTORY LIST, OR
OTHERWISE EXEMPT.
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT TO THE
REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE UNITED STATES: NO
TSCA 12(B) COMPONENTS EXIST IN THIS PRODUCT.
CALIFORNIA PROPOSITION 65 CARCINOGENS AND REPRODUCTIVE TOXINS:
CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
INTERNATIONAL REGULATIONS: AS FOLLOWS -
CANADIAN WHMIS:
THIS SDS HAS BEEN PREPARED IN COMPLIANCE WITH CONTROLLED PRODUCT
REGULATIONS EXCEPT FOR THE USE OF THE 16 HEADINGS.
WHMIS CLASS: CONSUMER COMMODITY
| 16. OTHER INFORMATION | |
REVISION DATE: 3/21/2017
SUPERSEDES DATE: NEW MSDS
REASON FOR REVISION: HAZCOM2012/GHS CONVERSION
DATASHEET PRODUCED BY: REGULATORY DEPARTMENT
HMIS RATINGS:
HEALTH 0
FLAMMABILITY 0
REACTIVITY 1
PERSONAL PROTECTION X
VOC LESS WATER LESS EXEMPT SOLVENT, G/L: 23.0
VOC MATERIAL, G/L: 23
VOC AS DEFINED BY CALIFORNIA CONSUMER PRODUCT REGULATION, WT/WT%: 13.0
TEXT FOR GHS HAZARD STATEMENTS SHOWN IN SECTION 3 DESCRIBING EACH
INGREDIENT:
H228: FLAMMABLE SOLID.
H250: CATCHES FIRE SPONTANEOUSLY IF EXPOSED TO AIR.
H261: IN CONTACT WITH WATER RELEASES FLAMMABLE GASES.
H302: HARMFUL IF SWALLOWED.
H312: HARMFUL IN CONTACT WITH SKIN.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H331: TOXIC IF INHALED.
H332: HARMFUL IF INHALED.
H350: MAY CAUSE CANCER.
ICONS FOR GHS PICTOGRAMS SHOWN IN SECTION 3 DESCRIBING EACH INGREDIENT:
GHS02: FLAME
GHS06: SKULLS AND CROSSBONES
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
LEGEND:
N.A.: NOT APPLICABLE
N.E.: NOT ESTABLISHED
N.D.: NOT DETERMINED
DAP BELIEVES THE DATA AND STATEMENTS CONTAINED HEREIN ARE ACCURATE AS OF
THE DATE HEREOF. THEY ARE OFFERED IN GOOD FAITH AS TYPICAL VALUES AND NOT
AS A PRODUCT SPECIFICATION. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF
FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR
IMPLIED, IS MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE
PRODUCT TO WHICH THE INFORMATION REFERS. SINCE THIS DOCUMENT IS INTENDED
ONLY AS A GUIDE TO THE APPROPRIATE USE AND PRECAUTIONARY HANDLING OF THE
REFERENCED PRODUCT BY A PROPERLY TRAINED PERSON, IT IS THEREFORE THE
RESPONSIBILITY OF THE USER TO (I) REVIEW THE RECOMMENDATIONS WITH DUE
CONSIDERATION FOR THE SPECIFIC CONTEXT OF THE INTENDED USE AND (II)
DETERMINE IF THEY ARE APPROPRIATE.