| Common Name: | DELUXE ROADSIDE EMERGENCY KIT |
| Manufacturer: | DYNAREX |
| SDS Revision Date: | 6/6/2017 |
| SDS Format: | No Format Specified |
| Item Number(s): | 407K11 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
ORION(R*)
THE BRIGHTEST NAME IN SAFETY
SAFETY DATA SHEET
EFFECTIVE DATE: 06/06/17
ITEM: DELUXE ROADSIDE EMERGENCY KIT
PART # UPC
8901 039147089012
8901S
CONTENTS:
ALCOHOL PREP/SWAB
ANTISEPTIC TOWELETTE
BATTERY
FIRST AID BURN CREAM
RED EMERGENCY FLARE
INSTANT COLD PACK
LIGHT STICK (GREEN)
MOIST TOWELETTE
STING & BITE PAD
DYNAREX
CORPORATE HEADQUARTERS
10 GLENSHAW STREET
ORANGEBURG, NY 10962
TEL: 845.365.8200
FAX: 845.365.8201
TOLL-FREE: 888.DYNAREX
REVIEWED ON: 5/4/15
SAFETY DATA SHEET
| SECTION 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: ALCOHOL PREPARATION PADS/SWAB
RECOMMENDED USE: TOPICAL SKIN ANTISEPTIC
PRODUCT CODE: AM-20200, 1113, 1114, 1116, PK-1114
MANUFACTURER'S NAME: DYNAREX CORPORATION
MANUFACTURER'S ADDRESS:
10 GLENSHAW STREET
ORANGEBURG, NY 10962
EMERGENCY OR INFORMATION: 888-DYNAREX OR 845-365-8200
PHONE NO.: AT OTHER TIMES, CONTACT THE LOCAL POISON CONTROL CENTER
| SECTION 2. HAZARDS IDENTIFICATION | |
MAIN HAZARDS:
HIGHLY FLAMMABLE; IRRITATION TO EYES; VAPOR MAY CAUSE DROWSINESS AND
DIZZINESS
ABSORPTION: EYE CONTACT; INGESTION; INHALATION; SKIN CONTACT
CARCINOGENIC STATUS: NOT CONSIDERED CARCINOGENIC BY NTP, IARC, AND OSHA
TARGET ORGANS: CENTRAL NERVES SYSTEM; SKIN; EYE; LIVER; RESPIRATORY SYSTEM
HEALTH EFFECTS:
EYES:
LIQUID, MIST OR VAPOR WILL CAUSE CONJUNCTIVAL IRRITATION AND POSSIBLE
CORNEAL DAMAGE.
SKIN:
REPEATED OR PROLONGED CONTACT MAY PRODUCE DEFATTING OF THE SKIN LEADING TO
IRRITATION AND DERMATITIS. LIQUID MAY BE ABSORBED THROUGH THE SKIN BUT NOT
IN TOXICOLOGICALLY SIGNIFICANT AMOUNTS, UNLESS THE CONTACT AREA IS LARGE
AND UNDER PROLONGED EXPOSURE.
INGESTION:
SWALLOWING A SMALL AMOUNT MAY HAVE THE EFFECT OF ANY OF THESE SYMPTOMS:
IRRITATION OF MOUTH, THROAT, DIGESTIVE TRACT, AND CENTRAL NERVES SYSTEM
DEPRESSION.
INGESTION:
A LARGE DOSE MAY HAVE THE EFFECT OF ANY OF THESE SYMPTOMS:
DIZZINESS, DROWSINESS, HEADACHE, MENTAL CONFUSION, NERVE DAMAGE LEADING TO
NUMBNESS AND MUSCLE WEAKNESS, FALL OF BLOOD PRESSURE, LIVER DAMAGE, LUNG
DAMAGE.
INHALATION:
EXPOSURE TO VAPOR MAY HAVE THE EFFECT OF ANY OF THESE SYMPTOMS:
IRRITATION OF NOSE, THROAT AND RESPIRATORY TRACT, CENTRAL NERVE SYSTEM
DEPRESSION.
INHALATION:
EXPOSURE TO VAPOR AT HIGH CONCENTRATION MAY HAVE THE EFFECTS OF ANY OF
THESE SYMPTOMS:
DIZZINESS, DROWSINESS, HEADACHE, MENTAL CONFUSION, LUNG DAMAGE, FALL OF
BLOOD PRESSURE, LIVER DAMAGE, NERVE DAMAGE LEADING TO NUMBNESS AND MUSCLE
WEAKNESS.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
HAZARDOUS INGREDIENTS (SPECIFIC) % COMPOSITION CAS NUMBER
ISOPROPYL ALCOHOL (2-PROPANOL) 70% 67-63-0
INACTIVE INGREDIENT
WATER 30% 7732-18-5
| SECTION 4. FIRST-AID MEASURES | |
EYES:
IMMEDIATELY FLOOD THE EYE WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES,
HOLDING THE EYE OPEN. OBTAIN MEDICAL ATTENTION IF SORENESS OR REDNESS
PERSISTS.
SKIN:
IMMEDIATELY FLOOD THE AFFECTED SKIN AREA WITH LARGE QUANTITY OF WATER,
PERFERABLY UNDER A SHOWER. REMOVE CONTAMINATED CLOTHING AND CONTINUE
WASHING. CONTAMINATED CLOTHING SHOULD BE WASHED THOROUGHLY BEFORE RE-USE.
OBTAIN MEDICAL ATTENTION IF BLISTERING OF THE SKIN OCCURS OR REDNESS
PERSISTS.
INGESTION:
DO NOT INDUCE VOMITING. HAVE VICTIM DRINK SERVAL LARGE GLASSES OF WATER TO
DILUTE THE STOMACH CONTENTS. GIVE THE VICTIM OXYGEN IF HE/SHE HAS
DIFFICULTY IN BREATHING. OBTAIN MEDICAL ATTENTION IMMEDIATELY.
INHALATION:
REMOVE THE VICTIM FROM EXPOSURE IMMEDIATELY. GIVE THE VICTIM OXYGEN IF
HE/SHE HAS DIFFICULTY IN BREATHING. OBTAIN MEDICAL ATTENTION IMMEDIATELY.
MEDICAL PERSONNEL:
MONITOR THE VICTIM FOR SYSTEMIC SECONDARY EFFECTS ON LIVER AND KIDNEY
FUNCTIONS. SUPPORT AND TREAT AS APPROPRIATE.
| SECTION 5. FIRE-FIGHTING MEASURES | |
FLASH POINT: 20 DEG. C/68 DEG. F
BOILING POINT: 80 DEG. C/176 DEG. F
EXTINGUISHING MEDIA:
DRY CHEMICAL OR ALCOHOL TYPE FOAM, CARBON DIOXIDE BE AWARE OF THE
POSSIBILITY OF RE-IGNITION. KEEP CONTAINERS AND SURROUNDINGS COOL WITH
WATER SPRAY.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
CLASS 3 FLAMMABILITY. VAPOR CAN TRAVEL A CONSIDERABLE DISTANCE TO A SOURCE
OF IGNITION AND FLASHBACK. FLASHBACK CAN OCCUR IF AIR TEMPERATURE EXCEEDS
FLASH POINT. BE AWARE THE POSSIBILITY OF RE-IGNITION.
SPECIAL FIRE FIGHTING PROCEDURES:
HANDLE AS FLAMMABLE LIQUID. USE RESPIRATORY PROTECTION. WEAR FULL
PROTECTIVE CLOTHING FOR FIRE FIGHTING PERSONNEL.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
FLUSH SPILLS WITH WATER.
CONTAIN AND ABSORB USING SOIL, SAND, OR OTHER INERT MATERIAL.
VAPOR CAN ACCUMMULATE IN LOW AREAS. CONSIDER THE NEED FOR EVACUATION.
PREVENT THE MATERIAL FROM ENTERING DRAINS OR WATER COURSES.
| SECTION 7. HANDLING AND STORAGE | |
ELIMINATE ALL SOURCES OF IGNITION. STORE AWAY FROM HEAT.
STORE IN WELL VENTILATED AREA.
HANDLE AS FLAMMABLE LIQUID. FOLLOW LOCAL, STATE AND FEDERAL REGULATIONS.
AVOID INHALING VAPOR. AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
WEAR EYE PROTECTION IF SPLASHING IS EXPECTED.
WEAR APPROPRIATE PROTECTIVE CLOTHING.
USE RESPIRATOR IF EXPOSURE LEVEL IS HIGH WHEN HANDLING BULK LIQUID.
KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OSHA OCCUPATION EXPOSURE STANDARDS PEL 400PPM (980 MG/M3) 8H TWA
UK EH40: OES 400PPM (980MG/M3) 8H TWA
UK EH40: OES 500PPM (1225MG/M3) 15MIN TWA
ACGIH: TLV 200PPM (980MG/M3) 8H TWA
ACGIH: STEL 400PPM (1225MG/M3) 15MIN TWA
PERSONAL PROTECTIVE EQUIPMENT:
GLOVES
EYE
CLOTHING
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: LIQUID SATURATED TOWELETTE / PAD / SWAB
COLOR: CLEAR
ODOR: ALCOHOL
VAPOR DENSITY: 2.1 (AIR = 1)
VISCOSITY (CST): 2.9 CPS AT <@2> DEG. C
EVAPORATION RATE: ENVIRONMENTAL DEPENDENT
WATER SOLUBILITY: COMPLETE
SPECIFIC GRAVITY: 0.8405
| SECTION 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS
CONDITIONS TO AVOID: NONE
INCOMPATIBILITY: NONE
HAZARDOUS DECOMPOSITION OR BY-PRODUCT: OXIDES OF CARBON
POLYMERIZATION: WILL NOT OCCUR.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
ACUTE TOXICITY:
LOW LEVEL OF ACUTE TOXICITY PREDICTED.
MAY BE HARMFUL BY SKIN ABSORPTION.
ORAL LD50 (RAT) 5045 MG/KG.
DERMAL LD50 (RABBIT) 12800 MG/KG.
INHALATION LCLO (RAT) 1600 PPM 4H.
CHRONIC TOXICITY / CARCINOGENICITY:
MATERIAL NOT EXPECTED TO CAUSE LONG-TERM ADVERSE HEALTH EFFECTS.
MATERIAL NOT CLASSIFIABLE AS TO ITS CARCINOGENICITY TO HUMANS (GROUP 3).
CHRONIC / SUB-CHRONIC STUDIES RESULTED IN ADVERSE EFFECTS TO:
LIVER, SPLEEN, BIOCHEMICAL EFFECTS, BRAIN TISSUE DEGENERATION, CHANGES IN
REFLEX BEHAVIOR, SENSORY NERVE DAMAGE.
GENEALOGY TOXICITY:
MATERIAL IS NOT EXPECTED TO CAUSE ANY MUTAGENIC EFFECTS.
REPRODUCTIVE / DEVELOPMENTAL TOXICITY:
MATERIAL IS NOT EXPECTED TO CAUSE REPRODUCTIVE OR DEVELOPMENTAL HEALTH
EFFECTS.
EXPERIMENTAL STUDIES IN ANIMALS HAVE PROVIDED SOME EVIDENCE OF EMBRYO /
FETUS TOXICITY AND BIRTH DEFECTS ONLY AT DOES PRODUCING MARKED MATERNAL
TOXICITY.
| SECTION 12. ECOLOGICAL INFORMATION | |
MOBILITY:
IF RELEASED TO SOIL, IPA IS EXPECTED TO HAVE VERY HIGH MOBILITY
PERSISTENCE / DEGRADABILITY
IPA IS READILY DEGRADED IN AEROBIC AQUEOUS SYSTEMS
BIO-ACCUMULATION
LOW POTENTIAL FOR BIO-CONCENTRATION IN AQUATIC ORGANISMS
| SECTION 13. DISPOSAL CONSIDERATIONS | |
TRANSFER INTO SUITABLE CONTAINERS FOR RECOVERY OR DISPOSAL.
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE LOCAL AND NATIONAL REGULATIONS.
DO NOT REMOVE LABELS FROM CONTAINER UNTIL THE CONTAINER HAS BEEN CLEANED.
DO NOT CUT, PUNCTURE OR WELD ON OR NEAR THE CONTAINER.
DO NOT INCINERATE CLOSED CONTAINERS.
EMPTY CONTAINERS MAY CONTAIN HAZARDOUS RESIDUES
| SECTION 14. TRANSPORT INFORMATION | |
DOT CFR 172.101
NOT REGULATED PER 49 CFR 173.4 SMALL QUANTITY EXEMPTION
| SECTION 15. REGULATORY INFORMATION | |
THIS PRODUCT IS COMPLIANT WITH THE FOLLOWING:
EU LABEL:
CLASSIFICATION AND LABELING HAVE BEEN PERFORMED ACCORDING TO EU DIRECTIVE
67/548/EEC AND 99/45/EC INCLUDING AMENDMENTS
EU HAZARD SYMBOL AND INDICATION OF DANGER
F: HIGHLY FLAMMABLE
XI: IRRITANT
R11: HIGHLY FLAMMABLE
R36: IRRITATING TO EYES
R67: VAPORS MAY CAUSE DROWSINESS AND DIZZINESS
S2: KEEP OUT OF REACH OF CHILDREN
S7: KEEP CONTAINER TIGHTLY CLOSED
S16: KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING
S24 / S25: AVOID CONTACT WITH SKIN AND EYES
S26:
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND
SEEK MEDICAL ADVICE
US (FEDERAL AND STATE) REGULATIONS AND INTERNATIONAL CHEMICAL REGISTRATION
LAWS TSCA LISTING
THIS PRODUCT CONTAINS INGREDIENTS THAT ARE LISTED ON OR EXEMPT FROM LISTING
ON THE EPA TOXIC SUBSTANCE CONTROL ACT CHEMICAL INVENTORY
THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS SUBJECT TO EPA TITLE III OF THE
SARA LISTING IN SECTIONS 302 AND 304
ALL INGREDIENTS IN THIS PRODUCT ARE LISTED ON THE EUROPEAN INVENTORY OF
EXISTING COMMERCIAL CHEMICAL SUBSTANCE (EINECS LISTING) OR ARE EXEMPTED
FROM LISTING
ALL INGREDIENTS IN THIS PRODUCT ARE LISTED ON THE CANADA DOMESTIC SUBSTANCE
LIST (DSL LISTING)
| SECTION 16. OTHER INFORMATION | |
DISCLAIMER:
THIS SAFETY DATA SHEET, WHICH TAKES INTO CONSIDERATION THE REQUIREMENTS OF
DIRECTIVE 76/768/EC AND SUBSEQUENT AMENDMENTS AND DIRECTIVE 1999/45/EC PLUS
SUBSEQUENT AMENDMENTS, HAS BEEN PREPARED IN ACCORDANCE WITH DIRECTIVE (EC)
1907/2006. IT IS BELIEVED TO BE CORRECT AND CORRESPONDS TO THE LATEST
SCIENTIFIC/TECHNICAL KNOWLEDGE BUT ALL DATA, INSTRUCTIONS, RECOMMENDATIONS
AND/OR SUGGESTIONS ARE MADE WITHOUT GUARANTEE. NO WARRANTY, EXPRESSED OR
IMPLIED, IS MADE AND DYNAREX CORP. ASSUMES NO LEGAL RESPONSIBILITY OR
LIABILITY RESULTING FROM ITS USE.
TILLOTSON(TM)
HEALTHCARE BRAND
ORANGEBURG, NY
ADA, OH
POCAHONTAS, AR
JACKSONVILLE, FL
MCCARRAN, NV
WWW.DYNAREX.COM
DYNAREX
CORPORATE HEADQUARTERS
10 GLENSHAW STREET
ORANGEBURG, NY 10962
TEL: 845.365.8200
FAX: 845.365.8201
TOLL-FREE: 888.DYNAREX
REVIEWED ON: 9/16/15
SAFETY DATA SHEET
| SECTION 1. PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NAME: BZK ANTISEPTIC TOWELETTE
PRODUCT USE: ANTISEPTIC
PRODUCT CODE: 1303, 1331
MANUFACTURER'S NAME: DYNAREX CORPORATION
MANUFACTURER'S ADDRESS:
10 GLENSHAW STREET
ORANGEBURG, NY 10962
EMERGENCY OR INFORMATION PHONE NO.:
888-DYNAREX OR 845-365-8200
AT OTHER TIMES, CONTACT THE LOCAL POISON CONTROL CENTER
| SECTION 2. HAZARDS IDENTIFICATION | |
PHYSICAL HAZARDS: NOT CLASSIFIED
HEALTH HAZARDS: NOT CLASSIFIED
ENVIRONMENTAL HAZARDS: NOT DETERMINED
OSHA DEFINED HAZARDS: NOT CLASSIFIED
LABEL ELEMENTS:
HAZARD SYMBOL: NONE
SIGNAL WORD: NOT AVAILABLE
HAZARD STATEMENT: NOT AVAILABLE
PRECAUTIONARY STATEMENT:
PREVENTION: NOT AVAILABLE
RESPONSE: NOT AVAILABLE
STORAGE: NOT AVAILABLE
DISPOSAL: NOT AVAILABLE
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN
SUPPLEMENTAL INFORMATION: NONE
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENTS CAS NUMBER %
BZK 8001-54-5 0.13
WATER 7732-18-5 99.87
| SECTION 4. FIRST-AID MEASURES | |
FIRST AID PROCEDURES:
EYE CONTACT:
FLUSH WITH COOL WATER. REMOVE CONTACT LENSES, IF APPLICABLE, AND CONTINUE
FLUSHING. OBTAIN MEDICAL ATTENTION IF IRRITATION PERSISTS.
SKIN CONTACT: IN CASE OF SKIN IRRITATION, DISCONTINUE USE OF PRODUCT.
INHALATION:
NOT A NORMAL ROUTE OF EXPOSURE. IF SYMPTOMS DEVELOP MOVE VICTIM TO FRESH
AIR. IF SYMPTOMS PERSIST, OBTAIN MEDICAL ATTENTION.
INGESTION:
NOT A NORMAL ROUTE OF EXPOSURE. DO NOT INDUCE VOMITING, NEVER GIVE ANYTHING
BY MOUTH IF VICTIM IS UNCONSCIOUS, OR IS CONVULSING. OBTAIN MEDICAL
ATTENTION.
NOTES TO PHYSICIAN: SYMPTOMS MAY BE DELAYED.
GENERAL ADVICE:
IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED, AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES. SHOW THIS SAFETY DATA SHEET TO THE
DOCTOR IN ATTENDANCE. KEEP OUT OF REACH OF CHILDREN. AVOID CONTACT WITH
EYES.
FLAMMABLE LIMITS: N/A
FLASH POINT: N/A
| SECTION 5. FIRE-FIGHTING MEASURES | |
FLASH POINT: NOT AVAILABLE
FLAMMABLE LIMITS: NOT AVAILABLE
EXTINGUISHING MEDIA: ANY
SPECIAL FIRE FIGHTING PROCEDURES: NONE
UNUSUAL FIRE AND EXPLOSION HAZARDS: NONE
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
KEEP UNNECESSARY PERSONNEL AWAY. DO NOT TOUCH OR WALK THROUGH SPILLED
MATERIAL. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS
WEARING APPROPRIATE PROTECTIVE CLOTHING. KEEP PEOPLE AWAY FROM AND
UPWIND OF SPILL/LEAK.
METHODS FOR CONTAINMENT:
PREVENT ENTRY INTO WATERWAYS, SEWERS, BASEMENTS OR CONFINED AREAS.
METHODS FOR CLEANING UP: PICK UP AND DISCARD TOWEL.
| SECTION 7. HANDLING AND STORAGE | |
HANDLING: USE GOOD INDUSTRIAL HYGIENE PRACTICES IN HANDLING THIS MATERIAL.
STORAGE:
KEEP OUT OF REACH OF CHILDREN. STORE IN A CLOSED CONTAINER AWAY FROM
INCOMPATIBLE MATERIALS.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
ENGINEERING CONTROLS:
PERSONAL PROTECTIVE EQUIPMENT: GENERAL VENTILATION NORMALLY ADEQUATE.
EYE/FACE PROTECTION: FOLLOW STANDARD INDUSTRIAL HYGIENE PRACTICES.
HAND PROTECTION: NOT REQUIRED.
SKIN AND BODY PROTECTION: AS REQUIRED BY EMPLOYER CODE.
RESPIRATORY PROTECTION:
WHERE EXPOSURE GUIDELINE LEVELS MAY BE EXCEEDED, USE AND APPROVED NIOSH
RESPIRATOR.
GENERAL HYGIENE CONSIDERATIONS:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE. WHEN
USING DO NOT EAT OR DRINK.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE/ODOR: LIQUID SATURATED ON WIPE
COLOR: CLEAR LIQUID
FORM: LIQUID SATURATED ON WIPE
ODOR: CHARACTERISTIC
ODOR THRESHOLD: NOT AVAILABLE
PHYSICAL STATE: SOLID
BOILING POINT: <200 DEG. F
PAPER COMPONENTS: 100% VIRGIN PAPER
SPECIFIC GRAVITY: 1
| SECTION 10. STABILITY AND REACTIVITY | |
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
INCOMPATIBILITY: CAUSTICS. ACIDS. OXIDIZERS.
HAZARDOUS DECOMPOSITION PRODUCTS:
MAY INCLUDE AND ARE NOT LIMITED TO: OXIDES OF CARBON; HYDROGEN CHLORIDE.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
CONDITIONS TO AVOID: DO NOT MIX WITH OTHER CHEMICALS.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
EFFECTS OF ACUTE EXPOSURE:
EYE: MAY CAUSE IRRITATION
SKIN: IN CASE OF SKIN IRRITATION, DISCONTINUE USE OF THE PRODUCT.
INHALATION:
NOT A NORMAL ROUTE OF EXPOSURE. MAY CAUSE RESPIRATORY TRACT IRRITATION.
INGESTION:
NOT A NORMAL ROUTE OF EXPOSURE. MAY CAUSE STOMACH DISTRESS, NAUSEA OR
VOMITING.
SENSITIZATION: NON-HAZARDOUS BY WHMIS/OSHA CRITERIA.
CHRONIC EFFECTS: NON-HAZARDOUS BY WHMIS/OSHA CRITERIA.
CARCINOGENICITY: NON-HAZARDOUS BY WHMIS/OSHA CRITERIA.
MUTAGENICITY: NON-HAZARDOUS BY WHMIS/OSHA CRITERIA.
REPRODUCTIVE EFFECTS: NON-HAZARDOUS BY WHMIS/OSHA CRITERIA.
TERATOGENICITY: NON-HAZARDOUS BY WHMIS/OSHA CRITERIA.
| SECTION 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: NOT AVAILABLE
ENVIRONMENTAL EFFECTS: NOT AVAILABLE
AQUATIC TOXICITY: NOT AVAILABLE
PERSISTENCE / DEGRADABILITY: NOT AVAILABLE
BIOACCUMULATION / ACCUMULATION: NOT AVAILABLE
PARTITION COEFFICIENT: NOT AVAILABLE
MOBILITY IN ENVIRONMENTAL MEDIA: NOT AVAILABLE
CHEMICAL FATE INFORMATION: NOT AVAILABLE
OTHER ADVERSE EFFECTS: NOT AVAILABLE
| SECTION 13. DISPOSAL CONSIDERATIONS | |
WASTE CODES: NOT AVAILABLE
DISPOSAL INSTRUCTIONS:
DISCARD AFTER SINGLE USE.
REVIEW FEDERAL, STATE/PROVINCIAL, AND LOCAL GOVERNMENT REQUIREMENTS PRIOR
TO DISPOSAL.
DISCARD WITH SOLID WASTE. DISPOSE IN ACCORDANCE WITH ALL APPLICABLE
REGULATIONS.
WASTE FROM RESIDUES / UNUSED PRODUCTS: NOT AVAILABLE
CONTAMINATED PACKAGING: NOT AVAILABLE
| SECTION 14. TRANSPORT INFORMATION | |
U.S. DEPARTMENT OF TRANSPORTATION (DOT): NOT REGULATED AS DANGEROUS GOODS.
TRANSPORTATION OF DANGEROUS GOODS (TDG - CANADA):
NOT REGULATED AS DANGEROUS GOODS.
| SECTION 15. REGULATORY INFORMATION | |
CANADIAN FEDERAL REGULATIONS:
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF
THE CONTROLLED PRODUCTS REGULATIONS AND THE MSDS CONTAINS ALL THE
INFORMATION REQUIRED BY THE CONTROLLED PRODUCTS REGULATIONS.
US FEDERAL REGULATIONS:
THIS PRODUCT IS NOT KNOWN TO BE A "HAZARDOUS CHEMICAL" AS DEFINED BY THE
OSHA HAZARD COMMUNICATION STANDARD, 29 CFR 1910.1200. ALL COMPONENTS ARE ON
THE U.S. EPA TSCA INVENTORY LIST.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA):
29 CFR 1910.1200 HAZARDOUS NO CHEMICAL
CERCLA (SUPERFUND) REPORTABLE QUANTITY:
BENZENE: 10.0000
BENZENE, METHYL-: 1000.0000
BENZENE, (CHLOROMETHYL)-: 100.0000
PROPYLENE OXIDE: 100.0000
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
HAZARD CATEGORIES:
IMMEDIATE HAZARD: NO
DELAYED HAZARD: NO
FIRE HAZARD: NO
PRESSURE HAZARD: NO
REACTIVITY HAZARD: NO
SECTION 302 EXTREMELY HAZARDOUS SUBSTANCE: NO
SECTION 311 HAZARDOUS CHEMICAL: NO
CLEAN AIR ACT (CAA): NOT AVAILABLE
CLEAN WATER ACT (CWA): NOT AVAILABLE
SAFE DRINKING WATER ACT (SDWA): NOT AVAILABLE
DRUG ENFORCEMENT AGENCY (DEA): NOT AVAILABLE
FOOD AND DRUG ADMINISTRATION (FDA): NOT AVAILABLE
STATE REGULATIONS:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
| SECTION 16. OTHER INFORMATION | |
DISCLAIMER:
THIS SAFETY DATA SHEET, WHICH TAKES INTO CONSIDERATION THE REQUIREMENTS OF
DIRECTIVE 76/768/EC AND SUBSEQUENT AMENDMENTS AND DIRECTIVE 1999/45/EC PLUS
SUBSEQUENT AMENDMENTS, HAS BEEN PREPARED IN ACCORDANCE WITH DIRECTIVE (EC)
1907/2006. IT IS BELIEVED TO BE CORRECT AND CORRESPONDS TO THE LATEST
SCIENTIFIC/TECHNICAL KNOWLEDGE BUT ALL DATA, INSTRUCTIONS, RECOMMENDATIONS
AND/OR SUGGESTIONS ARE MADE WITHOUT GUARANTEE. NO WARRANTY, EXPRESSED OR
IMPLIED, IS MADE AND DYNAREX CORP. ASSUMES NO LEGAL RESPONSIBILITY OR
LIABILITY RESULTING FROM ITS USE.
TILLOTSON(TM)
HEALTHCARE BRAND
ORANGEBURG, NY
ADA, OH
POCAHONTAS, AR
JACKSONVILLE, FL
MCCARRAN, NV
WWW.DYNAREX.COM
RAYOVAC(R*)
SAFETY DATA SHEET
SPECTRUM BRANDS, INC.
RAYOVAC DIVISION
3001 DEMING WAY
MIDDLETON, WI 53562-1431
PHONE: (608) 275-3340
FAX: (608) 275-4577
HTTP://WWW.RAYOVAC.COM
THE SAFETY DATA SHEET IS SUPPLIED AS A SERVICE TO YOU. FOR OTHER RELATED
INFORMATION, PLEASE VISIT: HTTP://WWW.RAYOVAC.COM
| 1. IDENTIFICATION | |
PRODUCT NAME: ZINC CHLORIDE BATTERY
SIZES: ALL SIZES
EMERGENCY HOTLINE: 800-424-9300 (24 HR, CHEMTREC)
EDITION DATE: 08/11/2014
| 2. HAZARD IDENTIFICATION | |
WE WOULD LIKE TO INFORM OUR CUSTOMERS THAT THESE BATTERIES ARE EXEMPT
ARTICLES AND ARE NOT SUBJECT TO THE 29 CFR 1910.1200 OSHA REQUIREMENTS,
CANADIAN WHMIS REQUIREMENTS OR GHS REQUIREMENTS.
EMERGENCY OVERVIEW:
OSHA HAZARDS: NOT APPLICABLE
TARGET ORGANS: NOT APPLICABLE
GHS CLASSIFICATION: NOT APPLICABLE
GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENT: NOT APPLICABLE
PICTOGRAM: NOT APPLICABLE
SIGNAL WORDS: NOT APPLICABLE
HAZARD STATEMENTS: NOT APPLICABLE
PRECAUTIONARY STATEMENTS: NOT APPLICABLE
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT NAME CAS # % TLV*/**TWA
STEEL 7439-89-6 8-14 NOT LISTED
MANGANESE DIOXIDE 1313-13-9 28-32 C5.0 MG/M3 (TWA)
ZINC 7440-66-6 16-20 5.0 MG/M3 (ZNOAS FUME)
ACETYLENE BLACK 1333-86-4 7-13 3.5 MG/M3 (CARBON BLACK,
TWA)
AMMONIUM CHLORIDE 12125-02-9 1-3 NOT LISTED
ZINC CHLORIDE 7646-85-7 6-10 NOT LISTED
LEAD 7439-92-1 <0.02 50 UG/M3 (TWA)
WATER, PAPER, PLASTIC, OTHER BALANCE
*SOURCE: OSHA 29 CFR 1910.1000 TABLE Z-1, 2 OR 3 11-01-2012
| 4. FIRST AID INFORMATION | |
THRESHOLD LIMIT VALUE (TLV) AND SOURCE: NA
EFFECTS OF OVEREXPOSURE:
NONE (SEE SECTION 2 AND 4 FOR FIRE OR RUPTURE SITUATIONS)
EMERGENCY FIRST AID PROCEDURES:
SKIN AND EYES:
IN THE EVENT THAT BATTERY RUPTURES, FLUSH EXPOSED SKIN WITH FLOWING
LUKEWARM WATER FOR A MINIMUM OF 15 MINUTES. GET IMMEDIATE MEDICAL
ATTENTION FOR EYES. WASH SKIN WITH SOAP AND WATER.
SWALLOWING:
IF YOU OR YOUR DOCTOR SUSPECTS THAT A BATTERY HAS BEEN INGESTED-FOR
ASSISTANCE IN THE US CALL THE NATIONAL BATTERY INGESTION HOTLINE ANY
TIME AT (202) 625-3333: IN CANADA CALL 416-813-5900.
FOR MORE INFORMATION, PLEASE VISIT:
HTTP://WWW.NEMA.ORG/POLICY/ENVIRONMENTAL-STEWARDSHIP/DOCUMENTS/
BATTERYINGEST.PDF
| 5. FIRE FIGHTING MEASURES | |
FLASH POINT: NA
FLAMMABLE LIMITS IN AIR (%): NA
LOWER (LEL): NA
UPPER (UEL): NA
EXTINGUISHING MEDIA: USE WATER, FOAM, OR DRY POWDER AS APPROPRIATE.
AUTO-IGNITION: NA
SPECIAL FIRE FIGHTING PROCEDURES:
AS WITH ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS TO AVOID
INHALATION OF HAZARDOUS DECOMPOSITION PRODUCTS (SEE SECTION 2).
SPECIAL FIRE OR EXPLOSION HAZARDS:
LIKE ANY SEALED CONTAINER, BATTERY CELLS MAY RUPTURE WHEN EXPOSED TO
EXCESSIVE HEAT; THIS COULD RESULT IN THE RELEASE OF CORROSIVE MATERIALS.
| 6. ACCIDENTAL RELEASE MEASURES | |
TO CONTAIN AND CLEAN UP LEAKS OR SPILLS:
IN THE EVENT OF A BATTERY RUPTURE, PREVENT SKIN CONTACT AND COLLECT ALL
RELEASED MATERIAL IN A PLASTIC LINED METAL CONTAINER.
REPORTING PROCEDURE:
REPORT ALL SPILLS IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REPORTING
REQUIREMENTS.
| 7. HANDLING AND STORAGE | |
STORE BATTERIES IN A DRY PLACE. STORING UNPACKAGED CELLS TOGETHER COULD
RESULT IN CELL SHORTING AND HEAT BUILD-UP. DO NOT RECHARGE. DO NOT PUNCTURE
OR ABUSE.
| 8. EXPOSURE CONTROL/PERSONAL PROTECTION | |
RESPIRATORY PROTECTION (SPECIFY TYPE): NA
VENTILATION:
LOCAL EXHAUST: NA
MECHANICAL (GENERAL): NA
SPECIAL: NA
OTHER: NA
PROTECTIVE GLOVES: NA
EYE PROTECTION: NA
OTHER PROTECTIVE CLOTHING: NA
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
BOILING POINT @ 760 MM Hg (DEG. C): NA
PERCENT VOLATILE BY VOLUME (%): NA
VAPOR PRESSURE (MMHg @ 25 DEG. C): NA
EVAPORATION RATE (BUTYL ACETATE = 1): NA
VAPOR DENSITY (AIR = 1): NA
PHYSICAL STATE: NA
DENSITY (GRAMS/CC): NA
SOLUBILITY IN WATER (% BY WEIGHT): NA
PH: NA
APPEARANCE AND ODOR: GEOMETRIC SOLID OBJECT
| 10. STABILITY AND REACTIVITY | |
STABLE OR UNSTABLE: STABLE
INCOMPATIBILITY (MATERIALS TO AVOID): NA
HAZARDOUS DECOMPOSITION PRODUCTS: NA
DECOMPOSITION TEMPERATURE (0 DEG. F): NA
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
CONDITIONS TO AVOID: AVOID ELECTRICAL SHORTING, PUNCTURING OR DEFORMING
| 11. TOXICOLOGICAL INFORMATION | |
INGREDIENT NAME CAS # % TLV*/**TWA
STEEL 7439-89-6 8-14 NOT LISTED
MANGANESE DIOXIDE 1313-13-9 28-32 C5.0 MG/M3 (TWA)
ZINC 7440-66-6 16-20 5.0 MG/M3 (ZNOAS FUME)
ACETYLENE BLACK 1333-86-4 7-13 3.5 MG/M3 (CARBON BLACK,
TWA)
AMMONIUM CHLORIDE 12125-02-9 1-3 NOT LISTED
ZINC CHLORIDE 7646-85-7 6-10 NOT LISTED
LEAD 7439-92-1 <0.02 50 UG/M3 (TWA)
WATER, PAPER, PLASTIC, OTHER BALANCE
*SOURCE: OSHA 29 CFR 1910.1000 TABLE Z-1, 2 OR 3 11-01-2012
| 12. ECOLOGICAL INFORMATION | |
UNDER NORMAL USE THESE BATTERIES DO NOT RELEASE THEIR INGREDIENTS INTO THE
ENVIRONMENT. DAMAGED OR ABUSED BATTERIES CAN RELEASE SMALL AMOUNTS OF ZINC,
AND MANGANESE. DAMAGED BATTERIES CARELESSLY DISCARDED COULD RELEASE SMALL
AMOUNTS OF ZINC TO STORM OR SURFACE WATER. DO NOT PLACE IN FIRE. DISPOSE OF
PROPERLY WHEN DISCHARGED. USE A RECYCLING OUTLET IF AVAILABLE. THOSE
COLLECTING BATTERIES SHOULD FOLLOW STATE AND FEDERAL REGULATIONS.
PARTIALLY DISCHARGED DAMAGED BATTERIES CAN OVERHEAT AND CAUSE FIRES IN THE
PRESENCE OF OTHER COMBUSTIBLE MATERIALS.
| 13. DISPOSAL CONSIDERATIONS | |
ALWAYS COMPLY WITH FEDERAL, STATE OR LOCAL REQUIREMENTS. IF YOU CHOOSE TO
RETAIN DISCHARGED BATTERIES AND RECYCLE BE SURE TO STORE THEM OUT OF THE
REACH OF CHILDREN AND PETS. DO NOT STORE WITH ADULT MEDICATIONS OF SIMILAR
SIZE OR SHAPE. FOR ADDITIONAL INFORMATION ON DISPOSAL/RECLAIM OPTIONS,
VISIT:
HTTP://WWW.NEMA.ORG/POLICY/ENVIRONMENTALSTEWARDSHIP/DOCUMENTS/COMPANIES%
20CLAIMING%20TO%20RECYCLE.MARCH2005.PDF
| 14. TRANSPORTATION INFORMATION | |
TRANSPORTATION-SHIPPING:
THESE ARE CONSIDERED DRY-CELL BATTERIES AND THEY ARE NON-DANGEROUS GOODS
FOR TRANSPORTATION. THESE BATTERIES MUST BE PACKED IN A WAY TO PREVENT
SHORT CIRCUITS OR GENERATION OF A DANGEROUS QUANTITY OF HEAT.
USDOT: SEE SPECIAL PROVISION 130.
IMDG/OCEAN: NOT LISTED.
ICAO/IATA:
SEE SPECIAL PROVISION A123. THIS SPECIAL PROVISION ALSO STATES TO PUT THE
WORDS "NOT RESTRICTED" AND "SPECIAL PROVISION A123" ON THE AIR WAYBILL WHEN
AN AIR WAYBILL IS ISSUED.
| 15. REGULATORY INFORMATION | |
SARA 313:
NOTIFICATION IS NOT REQUIRED BECAUSE THESE PRODUCTS ARE ARTICLE(S) THAT DO
NOT RELEASE A COVERED TOXIC CHEMICAL UNDER THE NORMAL CONDITIONS OF
STORAGE, USE, OR HANDLING.
NOTICE:
THE INFORMATION AND RECOMMENDATIONS SET FORTH ARE MADE IN GOOD FAITH AND
ARE BELIEVED TO BE ACCURATE AT THE DATE OF PREPARATION. SPECTRUM BRANDS
INC. (RAYOVAC) MAKES NO WARRANTY EXPRESSED OR IMPLIED.
NA = NOT APPLICABLE
SAFETY DATA SHEET INFORMATION: (800) 237-7000
WATER-JET(R*) TECHNOLOGIES
SAFETY DATA SHEET
| SECTION 1: PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT IDENTIFIER: #007
PRODUCT NAME: FIRST AID BURN CREAM
PRODUCT USE: TOPICAL ANTISEPTIC AND ANALGESIC SKIN CREAM
MANUFACTURER:
WATER JEL TECHNOLOGIES LLC
50 BROAD STREET
CARLSTADT, NEW JERSEY 07072
TELEPHONE: 201-507-8300
E-MAIL ADDRESS: WWW.WATERJEL.COM
EMERGENCY TELEPHONE: 1-800-275-3433
FAX NUMBER: 201-507-8325
ISSUE DATE: 08-25-2015
| SECTION 2: HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
THIS PRODUCT IS REGULATED BY THE US FDA AS AN OVER-THE-COUNTER, MONOGRAPH
DRUG.
FOR CONSUMERS, CONSULT THE DRUG FACTS ON THE PACKAGE FOR USE DIRECTIONS AND
WARNINGS INFORMATION.
WARNINGS: FOR EXTERNAL USE ONLY.
WHEN USING THIS PRODUCT, AVOID CONTACT WITH THE EYES.
DO NOT USE ON LARGE AREAS OF THE BODY OR ON BROKEN, BLISTERED OR OOZING
SKIN.
STOP USE AND ASK A DOCTOR IF CONDITION WORSENS OR SYMPTOMS PERSIST FOR MORE
THAN 7 DAYS.
IF SWALLOWED, GET MEDICAL HELP OR CONTACT A POISON CONTROL CENTER
IMMEDIATELY.
PHYSICAL HAZARDS: THIS MIXTURE DOES NOT MEET THE CLASSIFICATION CRITERIA
ACCORDING TO OSHA HAZCOM 2012.
HEALTH HAZARDS: THIS MIXTURE DOES NOT MEET THE CLASSIFICATION CRITERIA
ACCORDING TO OSHA HAZCOM 2012.
ENVIRONMENTAL HAZARDS: THIS MIXTURE DOES NOT MEET THE CLASSIFICATION
CRITERIA ACCORDING TO OSHA HAZCOM 2012.
OSHA DEFINED HAZARDS: THIS MIXTURE DOES NOT MEET THE CLASSIFICATION
CRITERIA ACCORDING TO OSHA HAZCOM 2012.
LABEL ELEMENTS:
HAZARD SYMBOL: NONE
SIGNAL WORD: NONE
HAZARD STATEMENT:
THE MIXTURE DOES NOT MEET THE CRITERIA FOR CLASSIFICATION.
PRECAUTIONARY STATEMENT:
PREVENTION: NONE REQUIRED ACCORDING TO OSHA HAZCOM 2012.
RESPONSE: NONE REQUIRED ACCORDING TO OSHA HAZCOM 2012.
STORAGE: NONE REQUIRED ACCORDING TO OSHA HAZCOM 2012.
DISPOSAL: NONE REQUIRED ACCORDING TO OSHA HAZCOM 2012.
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN.
SUPPLEMENTAL INFORMATION: NONE.
ROUTE OF ENTRY:
SKIN CONTACT: MAY CAUSE IRRITATION, REDNESS, INFLAMMATION OR DRYNESS.
SKIN ABSORPTION: NO ADVERSE CONDITIONS EXPECTED.
EYE CONTACT:
FLUSH EYES WITH CLEAR RUNNING WATER FOR A MINIMUM OF 15 MINUTES; IF
IRRITATION PERSISTS, SEEK MEDICAL ATTENTION.
INHALATION: NOT EXPECTED DUE TO FORM.
INGESTION: MAY CAUSE IRRITATION OF THE DIGESTIVE TRACT.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
CHEMICAL NAME COMMON NAME AND SYNONYMS CAS NUMBER %
BENZALKONIUM CHLORIDE 63449-41-2 0.13
LIDOCAINE HCL 6108-05-0 0.5
GLYCERIN 1, 2, 3, PROPANETRIOL 56-81-5 PROPRIETARY
TRIETHANOLAMINE TROLAMINE 102-71-6 PROPRIETARY
PROPYLENE GLYCOL 1, 2, 3, PROPANETRIOL 57-55-6 PROPRIETARY
2-HYDROXYPROPANOL
| SECTION 4: FIRST AID MEASURES | |
SKIN CONTACT:
WASH OFF WITH WARM WATER AND SOAP. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
SKIN ABSORPTION: NO ADVERSE CONDITIONS EXPECTED.
EYE CONTACT:
FLUSH EYES WITH CLEAR RUNNING WATER FOR A MINIMUM OF 15 MINUTES; IF
IRRITATION PERSISTS, SEEK MEDICAL ATTENTION.
INHALATION: REMOVE VICTIM TO FRESH AIR.
INGESTION: MAY CAUSE IRRITATION OF THE DIGESTIVE TRACT.
| SECTION 5: FIRE-FIGHTING MEASURES | |
FLAMMABLE: NO
MEANS OF EXTINCTION:
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE. USE WATER SPRAY,
FOAM OR DRY CHEMICAL.
IN FIRES INVOLVING LARGE QUANTITIES OF THIS PRODUCT, THE USE OF LARGE
STREAMS OF WATER SHOULD BE AVOIDED.
USE SELF-CONTAINED BREATHING APPARATUS WHEN FIGHTING FIRES THAT INVOLVE
THIS MATERIAL.
FLASH POINT AND METHOD: NA
UPPER FLAMMABLE LIMIT (% BY VOLUME): NA
LOWER FLAMMABLE LIMIT (% BY VOLUME): NA
AUTOIGNITION TEMPERATURE (DEG. C): NA
EXPLOSION DATA - SENSITIVITY TO IMPACT:
NO UNUSUAL FIRE OR EXPLOSION HAZARDS NOTED.
EXPLOSION DATA - SENSITIVITY TO STATIC DISCHARGE:
NO UNUSUAL FIRE OR EXPLOSION HAZARDS NOTED.
HAZARDOUS COMBUSTION PRODUCTS: CARBON OXIDES. NITROGEN OXIDES (NOX).
NFPA:
HEALTH 1
FIRE 0
REACTIVITY 0
OTHER NA
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEAN UP:
ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN A
SEALED CONTAINER FOR CHEMICAL WASTE.
LARGE SPILLS:
FLUSH WITH PLENTY OF WATER. PREVENT ENTRY INTO WATERWAYS, SEWER, BASEMENTS
OR CONFINED AREAS. DIKE FOR LATER DISPOSAL.
SMALL SPILLS:
WIPE UP WITH ABSORBENT MATERIAL (E.G. CLOTH, FLEECE). CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
ENVIRONMENTAL PRECAUTIONS: AVOID DISCHARGE INTO DRAINS AND WATER SOURCES.
| SECTION 7: HANDLING AND STORAGE | |
HANDLING PROCEDURES AND EQUIPMENT:
KEEP THIS AND OTHER CHEMICALS OUT OF THE REACH OF CHILDREN.
STORAGE TEMPERATURE:
DO NOT STORE OR MIX WITH STRONG ACIDS OR OXIDIZERS. STORE AT ROOM
TEMPERATURE.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
COMPONENTS ACGIH-TLVS OSHA-PELS NIOSH FORM
GLYCERIN (CAS 57-55-8) NE 5 MG/M3 AEROSOL
PROPYLENE GLYCOL (CAS 57-55-6) 10 MG/M3 NE NE AEROSOL
TRIETHANOLAMINE (CAS 102-71-6) 5 MG/M3 NE NE AEROSOL
BIOLOGICAL LIMIT VALUES:
NO BIOLOGICAL EXPOSURE LIMITS NOTED FOR THE INGREDIENTS.
VENTILATION AND ENGINEERING CONTROLS: ENSURE ADEQUATE VENTILATION.
PERSONAL PROTECTIVE EQUIPMENT: NONE REQUIRED UNDER NORMAL CONDITIONS
HAND PROTECTION: NONE REQUIRED UNDER NORMAL CONDITIONS.
EYE AND FACE PROTECTION:
EYE PROTECTION, AS NECESSARY TO PREVENT EXCESSIVE CONTACT.
SKIN PROTECTION: NONE REQUIRED UNDER NORMAL CONDITIONS.
GENERAL HYGIENE CONSIDERATIONS: PRACTICE SAFE WORK HABITS.
OTHER PROTECTIVE EQUIPMENT:
EYE WASH STATIONS SHOULD BE NEARBY AND READY TO USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: CREAM.
PHYSICAL STATE: CREAM.
FORM: CREAM.
COLOR: WHITE, HOMOGENEOUS.
ODOR: SLIGHTLY FATTY ODOR.
PH: NO INFORMATION AVAILABLE.
BOILING POINT: 275 DEG. F
MELTING POINT: NO INFORMATION AVAILABLE.
FLASH POINT: N/A
EXPLOSIVE PROPERTIES: NO INFORMATION AVAILABLE.
OXIDIZING PROPERTIES: NO INFORMATION AVAILABLE.
SPECIFIC GRAVITY: 0.81
WATER SOLUBILITY: MISCIBLE.
PARTITION COEFFICIENT: NO INFORMATION AVAILABLE.
VISCOSITY: NO INFORMATION AVAILABLE.
VAPOR PRESSURE (MM Hg): NO INFORMATION AVAILABLE.
VAPOR DENSITY (AIR=1): NO INFORMATION AVAILABLE.
EVAPORATION RATE: NO INFORMATION AVAILABLE.
% VOLATILE: NO INFORMATION AVAILABLE.
| SECTION 10: STABILITY AND REACTIVITY | |
REACTIVITY:
THE PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS OF USE.
CHEMICAL STABILITY: STABLE AT NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
CONDITIONS TO AVOID: EXTREME HEAT.
MATERIALS TO AVOID: STRONG OXIDANTS AND STRONG ACIDS.
HAZARDOUS DECOMPOSITION PRODUCTS: CARBON MONOXIDE, CARBON DIOXIDE.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE:
THE HEALTH HAZARD INFORMATION PROVIDED IS FOR HANDLING THIS PRODUCT IN AN
OCCUPATIONAL SETTING.
EFFECTS OF ACUTE AND CHRONIC EXPOSURE:
ACUTE:
THE PRIMARY HEALTH EFFECT THAT MAY BE EXPERIENCED IN AN OCCUPATIONAL
SETTING IS MILD IRRITATION OF CONTAMINATED SKIN. ACCIDENTAL INGESTION MAY
BE HARMFUL. ALTHOUGH UNLIKELY, IRRITATION CAN IRRITATE THE RESPIRATORY
SYSTEM. EYE CONTACT WILL CAUSE IRRITATION.
CHRONIC: NE
TARGET ORGANS:
ACUTE:
OCCUPATIONAL EXPOSURE: SKIN, EYES.
CHRONIC:
OCCUPATIONAL EXPOSURE: SKIN.
INHALATION:
MIST MAY SLIGHTLY IRRITATE THE NOSE, THROAT AND LUNGS. SYMPTOMS ARE
GENERALLY ALLEVIATED UPON BREATHING FRESH AIR.
SKIN CONTACT:
SKIN CONTACT MAY CAUSE BURNING SENSATION, STINGING, ITCHING AND TINGLING.
EYE CONTACT:
EYE CONTACT CAN CAUSE IRRITATION, STINGING, REDNESS AND TEARING.
INGESTION:
INGESTION IS NOT A SIGNIFICANT ROUTE OF OCCUPATIONAL OVEREXPOSURE. ACUTE
INGESTION OF LARGE QUANTITIES OF THIS PRODUCT OR CHRONIC INGESTION MAY
CAUSE ADVERSE SYMPTOMS THAT MAY INCLUDE NAUSEA, VOMITING AND DIARRHEA.
IRRITANCY OF THE PRODUCT:
THIS PRODUCT MAY CAUSE MILD TO MODERATE IRRITATION ON DAMAGED SKIN.
SKIN SENSITIZATION: NOT EXPECTED.
RESPIRATORY SENSITIZATION: NOT EXPECTED.
LD50/LC50:
PROPYLENE GLYCOL (CAS 57-55-6):
ORAL (RAT): 2200MG/K
DERMAL: (RABBIT) 20800 MG/K
TRIETHANOLAMINE):
ORAL (RAT): 6110 MG/KG
DERMAL: (RABBIT): >19870 MG/K
GLYCERIN (MIST):
ORAL (RAT): 12,600 MG/KG
SUBCUTANEOUS (RAT): NOT AVAILABLE
CARCINOGENICITY: NOT CLASSIFIED AS A HUMAN CARCINOGEN BY IARC OR ACGIH.
REPRODUCTIVE TOXICITY:
MUTAGENIC/EMBRYO TOXICITY:
THE COMPONENTS OF THIS PRODUCT ARE NOT REPORTED TO CAUSE MUTAGENIC OR
EMBRYONIC EFFECTS IN HUMANS.
TERATOGENICITY: NOT AVAILABLE.
REPRODUCTIVE TOXICITY: NOT AVAILABLE.
| SECTION 12: ECOLOGICAL INFORMATION | |
NO SPECIFIC INFORMATION IS CURRENTLY AVAILABLE ON THE EFFECT OF THIS
PRODUCT ON PLANTS OR ANIMALS IN THE ENVIRONMENT. THE PRODUCT MAY BE HARMFUL
TO CONTAMINATED TERRESTRIAL AND AQUATIC PLANT LIFE IN LARGE QUANTITIES. THE
FOLLOWING AQUATIC TOXICITY DATA CURRENTLY AVAILABLE FOR COMPONENTS OF THIS
PRODUCT:
PROPYLENE GLYCOL:
EC50 GREEN ALGAE (DESMODESMUS SUBSPICATUS): 19000 MG/L 96 HOURS
EC50 WATER FLEA (DAPHNIA MAGNA): 43500 MG/L 48 HOURS
LC 50 FATHEAD MINNOW (PIMEPHALES PROMELAS): 46500 MG/L 96 HOURS
TRIETHANOLAMINE:
EC50 GREEN ALGAE (DESMODESMUS SUBSPICATUS): 512 MG/L 72 HOURS
NOEC WATER FLEA (DAPHNIA MAGNA): 16 MG/L 21 DAYS
LC 50 FATHEAD MINNOW (PIMEPHALES PROMELAS): 11800 MG/L 96 HOURS
ENVIRONMENTAL EXPOSURE CONTROLS:
CONTROLS SHOULD BE ENGINEERED TO PREVENT RELEASE TO THE ENVIRONMENT,
INCLUDING PROCEDURES TO PREVENT SPILLS, ATMOSPHERIC RELEASE AND RELEASE TO
WATERWAYS.
NO COMPONENT OF THIS PRODUCT IS KNOWN TO HAVE OZONE DEPLETION POTENTIAL.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS:
COLLECT OR DISPOSE IN SEALED CONTAINERS AT LICENSED WASTE DISPOSAL SITE.
DISPOSE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
| SECTION 14: TRANSPORT INFORMATION | |
DOT CLASSIFICATION: NOT REGULATED FOR DOMESTIC TRANSPORT.
IATA CLASSIFICATION: NOT REGULATED FOR INTERNATIONAL TRANSPORT.
IMDG CLASSIFICATION: NOT REGULATED FOR INTERNATIONAL WATER TRANSPORT.
| SECTION 15: REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
TSCA (TOXIC SUBSTANCE CONTROL ACT): NOT REGULATED.
CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT):
NOT LISTED.
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) 304:
NOT REGULATED.
SARA 311/312 HAZARD CATEGORIES: NOT REGULATED.
SARA 313 REPORTABLE INGREDIENTS: NOT LISTED.
STATE REGULATIONS:
CALIFORNIA PROP 65:
THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER, BIRTH, OR ANY OTHER REPRODUCTIVE DEFECTS.
NEW JERSEY RTK:
GLYCERIN (CAS 56-81-5)
PROPYLENE GLYCOL (CAS 57-55-6)
TRIETHANOLAMINE (CAS 102-71-6)
MASSACHUSETTS RTK: TRIETHANOLAMINE (CAS 102-71-6)
PENNSYLVANIA RTK:
PROPYLENE GLYCOL (CAS 57-55-6)
TRIETHANOLAMINE (CAS 102-71-6)
INTERNATIONAL REGULATIONS:
COUNTRY OR INVENTORY NAME LISTED
REGION
AUSTRALIA AUSTRALIA INVENTORY OF CHEMICAL NO
SUBSTANCES
CANADA DOMESTIC SUBSTANCE LIST (DSL) YES
CANADA NON-DOMESTIC SUBSTANCE LIST (NDSL) NO
CHINA INVENTORY OF EXISTING CHEMICAL YES
SUBSTANCES IN CHINA (IECSC)
EUROPE EUROPEAN LIST OF NOTIFIED CHEMICAL YES
SUBSTANCES (EINECS)
EUROPE EUROPEAN LIST OF NOTIFIED CHEMICAL NO
SUBSTANCES (ELINCS)
JAPAN INVENTORY OF EXISTING AND NEW NO
CHEMICAL SUBSTANCES (ENCS)
KOREA EXISTING CHEMICALS LIST (ECL) YES
NEW ZEALAND NEW ZEALAND INVENTORY YES
PHILIPPINES PHILIPPINE INVENTORY OF CHEMICALS NO
AND CHEMICAL SUBSTANCES (PICCS)
UNITED STATES TOXIC SUBSTANCE CONTROL ACT (TSCA) NO
& PUERTO RICO INVENTORY
NOTE:
A "YES" INDICATES THAT ALL COMPONENTS COMPLY WITH THE INVENTORY
REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY.
A "NO" INDICATES THAT ONE OR MORE COMPONENTS OF THE PRODUCT ARE NOT LISTED
OR EXEMPT FROM LISTING ON THE INVENTORY ADMINISTERED BY THE GOVERNING
COUNTRY.
| SECTION 16: OTHER INFORMATION | |
ISSUE DATE: 08-25-2015
VERSION: 02
DISCLAIMER:
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET (SDS) IS ACCURATE TO THE
BEST OF OUR KNOWLEDGE. THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE
FOR SAFE HANDLING, USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND
RELEASE AND IS NOT TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION.
THE INFORMATION RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY
NOT BE VALID FOR SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS
OR PROCESSES.
DYNAREX CORPORATION
TILLOTSON(TM)
HEALTHCARE CORPORATION
"YOUR FIRST CHOICE FOR GLOVES"
TELEPHONE: (845) 365-8200
WEBSITE: WWW.DYNAREX.COM
TOLL FREE: (888) DYNAREX
WEBSITE: WWW.THCNET.COM
FAX: (845) 365-8201
REVIEWED ON: 1/7/15
SAFETY DATA SHEET
| SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NAME: INSTANT COLD PACKS
PRODUCT USE:
AN ECONOMICAL, ONE TIME USE DISPOSABLE PRODUCT THAT PROMOTES FASTER HEALING
FOR THE TREATMENT OF BRUISES, CUTS, LACERATIONS, SPRAINS, MINOR BURNS,
SINUS & TENSION HEADACHES, INSECT BITES AND TOOTHACHES.
PRODUCT CODES: 4511-4512-4515
RESPONSIBLE PARTY:
DYNAREX CORPORATION
10 GLENSHAW STREET
ORANGEBURG, NY 10962
EMERGENCY OR INFORMATION PHONE NO.:
(888)-DYNAREX OR 845-365-8200 (MON - FRI).
AT OTHER TIMES, CONTACT THE LOCAL POISON CONTROL CENTER.
EMERGENCY OVERVIEW:
EMERGENCY TELEPHONE NUMBERS: LOCAL EMERGENCY CENTER
HEALTH HAZARDS:
DRY CHEMICAL OF COLD PACK IS AN EYE AND SKIN IRRITANT. AVOID CONTACT WITH
EYES, SKIN AND CLOTHING. WASH THOROUGHLY AFTER HANDLING.
PHYSICAL HAZARDS:
DRY CHEMICAL IS AN OXIDIZER. OXIDIZERS CAN SUPPORT COMBUSTION. CONTACT MAY
INCREASE FLAMMABILITY OF OTHER MATERIALS. AVOID CONTACT WITH CLOTHING AND
OTHER COMBUSTIBLE MATERIAL.
PHYSICAL FORM: SOLID/LIQUID
APPEARANCE: WHITE SOLID IN WATER BAG
ODOR: NONE
NFPA HAZARD CLASS:
HEALTH 1 (SLIGHT)
FLAMMABILITY 0 (LEAST)
REACTIVITY 3 (HIGH)
OTHER OXY (OXIDIZER)
| SECTION 2. HAZARDS IDENTIFICATION | |
POTENTIAL HEALTH EFFECTS: KEEP OUT OF REACH OF CHILDREN. (S2)
PRIMARY ROUTE(S) OF ENTRY:
EYE AND SKIN, IF LIQUID ESCAPES FROM SEALED CONTAINER.
NO HAZARD EXPECTED WITH INTACT PRODUCT.
EYES:
LIQUID CONTENT MAY CAUSE IRRITATION TO THE EYES; R36.
AVOID CONTACT WITH EYES; S25
SKIN: LIQUID CONTENT MAY BE IRRITATING TO SKIN; R38.
INGESTION: HARMFUL IF SWALLOWED; R22.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
IN CASE OF ACCIDENTAL OVERDOSE, CONTACT A PHYSICIAN OR POISON CONTROL
CENTER.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENTS % WEIGHT EXPOSURE GUIDELINE
LIMITS AGENCY TYPE
AMMONIUM NITRATE 40-70 NOT ESTABLISHED
CAS# 6484-52-2
OTHER COMPONENTS % WEIGHT EXPOSURE GUIDELINE
LIMITS AGENCY TYPE
WATER 30-60 NOT ESTABLISHED
CAS# 7732-18-5
NOTE:
STATE, LOCAL OR OTHER AGENCIES OR ADVISORY GROUPS MAY HAVE ESTABLISHED MORE
STRINGENT LIMITS. CONSULT AN INDUSTRIAL HYGIENIST OR SIMILAR PROFESSIONAL,
OR YOU LOCAL AGENCIES, FOR FURTHER INFORMATION.
| SECTION 4. FIRST AID MEASURES | |
EYE:
MOVE VICTIM AWAY FROM EXPOSURE AND INTO FRESH AIR. IF IRRITATION OR REDNESS
DEVELOPS, FLUSH EYES WITH CLEAN WATER AND SEEK IMMEDIATE MEDICAL ATTENTION.
FOR DIRECT CONTACT, IMMEDIATELY HOLD EYELIDS APART AND FLUSH THE AFFECTED
EYE(S) WITH CLEAN WATER FOR AT LEAST 15 MINUTES. SEEK MEDICAL ATTENTION.
SKIN:
REMOVE CONTAMINATED SHOES AND CLOTHING, AND FLUSH AFFECTED AREA(S) WITH
LARGE AMOUNTS OF WATER. IF SKIN SURFACE IS DAMAGED, APPLY A CLEAN DRESSING
AND SEEK MEDICAL ATTENTION. IF SKIN SURFACE IS NOT DAMAGED, CLEANSE
AFFECTED AREA(S) THOROUGHLY BY WASHING WITH MILD SOAP OR WATER. IF
IRRITATION OR REDNESS DEVELOPS, SEEK MEDICAL ATTENTION.
INHALATION (BREATHING):
IF RESPIRATORY SYMPTOMS OR OTHER SYMPTOMS OF EXPOSURE DEVELOP, MOVE VICTIM
AWAY FROM SOURCE OF EXPOSURE AND INTO FRESH AIR. IF SYMPTOMS PERSIST, SEEK
MEDICAL ATTENTION. IF VICTIM IS NOT BREATHING, CLEAR AIRWAY AND IMMEDIATELY
BEGIN ARTIFICIAL RESPIRATION. IF BREATHING DIFFICULTIES DEVELOP, OXYGEN
SHOULD BE ADMINISTERED BY QUALIFIED PERSONNEL. SEEK IMMEDIATE MEDICAL
ATTENTION.
INGESTION (SWALLOWING):
IF SWALLOWED, SEEK EMERGENCY MEDICAL ATTENTION. IF VICTIM IS DROWSY OR
UNCONSCIOUS AND VOMITING, PLACE ON LEFT SIDE WITH THE HEAD DOWN AND DO NOT
GIVE ANYTHING BY MOUTH. IF VICTIM IS CONSCIOUS AND ALERT AND INGESTION
OCCURRED WITHIN THE LAST HOUR, VOMITING SHOULD BE INDUCED FOR INGESTION OF
LARGE AMOUNTS (MORE THAN 5 OUNCES IN AN ADULT) UNDER DIRECTION FROM A
PHYSICIAN OR POISON CENTER. IF POSSIBLE, DO NOT LEAVE VICTIM UNATTENDED AND
OBSERVE CLOSELY FOR ADEQUACY OF BREATHING.
NOTE TO PHYSICIANS:
NITRATES IN LARGE DOSES MAY CAUSE SIGNIFICANT VASODILATION AND HYPOTENSION.
PRE-EXISTING ISCHEMIC HEART DISEASE MAY BE AGGRAVATED BY THESE EFFECTS. IN
LARGE INGESTIONS NITRATES MAY CAUSE METHEMOGLOBINEMIA. METHEMOGLOBINEMIA
SHOULD BE SUSPECTED IF CYANOSIS OCCURS. METHYLENE BLUE (1-2 MG/KG I.V. OVER
SEVERAL MINUTES) IS AN EFFECTIVE ANTIDOTE FOR SYMPTOMATIC
METHEMOGLOBINEMIA.
| SECTION 5. FIRE FIGHTING MEASURES | |
FLAMMABLE PROPERTIES:
FLASH POINT: NONE
OSHA FLAMMABILITY CLASS: NOT APPLICABLE
LEL/UEL: NO DATA
AUTOIGNITION TEMPERATURE: NO DATA
UNUSUAL FIRE & EXPLOSION HAZARDS:
OXIDIZER. THE DRY CHEMICAL OF THIS MATERIAL IS AN OXIDIZER AND MAY INCREASE
INFLAMMABILITY OF ANY COMBUSTIBLE SUBSTANCE. IT IS THE NATURE OF OXIDIZERS
TO PROVIDE THEIR OWN OXYGEN SOURCE; SMOTHERING A FIRE MAY BE INEFFECTIVE.
NITRATE SALTS SUPPORT COMBUSTION UNDER CERTAIN CONDITIONS. AMMONIUM NITRATE
IS CAPABLE OF DETONATION IF HEATED UNDER CONFINEMENT OR IF SUBJECTED TO
STRONG SHOCKS. ORGANIC OR OTHER EASILY OXIDIZABLE MATTER CAN SENSITIZE IT
TO A MORE READILY EXPLODABLE STATE. DO NOT ALLOW PRODUCT TO EVAPORATE TO
DRYNESS, ESPECIALLY IN CONTACT WITH COMBUSTIBLE MATERIALS.
EXTINGUISHING MEDIA:
USE WATER ONLY. DO NOT USE DRY CHEMICAL, CARBON DIOXIDE OR FOAM.
FIRE FIGHTING INSTRUCTIONS:
FOR FIRES BEYOND THE INCIPIENT STAGE, EMERGENCY RESPONDERS IN THE IMMEDIATE
HAZARD AREA SHOULD WEAR BUNKER GEAR. WHEN THE POTENTIAL CHEMICAL HAZARD IS
UNKNOWN, IN ENCLOSED OR CONFINED SPACES, OR WHEN EXPLICITLY REQUIRED BY
DOT, A SELF-CONTAINED BREATHING APPARATUS SHOULD BE WORN. IN ADDITION, WEAR
OTHER APPROPRIATE PROTECTIVE EQUIPMENT AS CONDITIONS WARRANT (SEE SECTION
8). ISOLATE IMMEDIATE HAZARD AREA AND KEEP UNAUTHORIZED PERSONNEL OUT. STOP
SPILL/RELEASE IF IT CAN BE DONE WITH MINIMAL RISK. MOVE UNDAMAGED
CONTAINERS FROM IMMEDIATE HAZARD AREA IF IT CAN BE DONE WITH MINIMAL RISK.
WATER SPRAY MAY BE USEFUL IN MINIMIZING OR DISPERSING VAPORS. COOL
EQUIPMENT EXPOSED TO FIRE WITH WATER, IF IT CAN BE DONE WITH MINIMAL RISK.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
THE DRY CHEMICAL OF THIS MATERIAL IS AN OXIDIZER. KEEP ALL SOURCES OF
IGNITION AND HOT METAL SURFACES AWAY FROM SPILL/RELEASE. THE USE OF
EXPLOSION-PROOF EQUIPMENT IS RECOMMENDED.
STAY UPWIND AND AWAY FROM SPILL/RELEASE. NOTIFY PERSON DOWN WIND OF
SPILL/RELEASE, ISOLATE IMMEDIATE HAZARD AREA AND KEEP UNAUTHORIZED
PERSONNEL OUT. STOP SPILL/RELEASE IF IT CAN BE DONE WITH MINIMAL RISK. WEAR
APPROPRIATE PROTECTIVE EQUIPMENT INCLUDING RESPIRATORY PROTECTION AS
CONDITIONS WARRANT (SEE SECTION 8). PREVENT SPILLED MATERIAL FROM ENTERING
SEWERS, STORM DRAINS, OTHER UNAUTHORIZED TREATMENT DRAINAGE SYSTEMS, AND
NATURAL WATERWAYS. DIKE FAR AHEAD OF SPILL FOR LATER RECOVERY OR DISPOSAL.
SPILLED MATERIAL MAY BE ABSORBED INTO AN APPROPRIATE ABSORBENT MATERIAL.
NOTIFY APPROPRIATE FEDERAL, STATE, AND LOCAL AGENCIES. IMMEDIATE CLEANUP OF
ANY SPILL IS RECOMMENDED.
| SECTION 7. HANDLING AND STORAGE | |
HANDLING:
DO NOT ENTER CONFINED SPACES SUCH AS TANKS OR PITS WITHOUT FOLLOWING PROPER
ENTRY PROCEDURES SUCH AS ASTM D-4276 AND 29CFR 1910.146. THE USE OF
APPROPRIATE RESPIRATORY PROTECTION IS ADVISED WHEN CONCENTRATIONS EXCEED
ANY ESTABLISHED EXPOSURE LIMITS (SEE SECTION 2 AND 8). WASH THOROUGHLY
AFTER HANDLING. DO NOT WEAR CONTAMINATED CLOTHING OR SHOES. USE GOOD
PERSONAL HYGIENE PRACTICE.
"EMPTY" CONTAINERS RETAIN RESIDUE AND MAY BE DANGEROUS. DO NOT PRESSURIZE,
CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT,
FLAME, SPARKS, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE
INJURY OR DEATH. CONTAINER SHOULD BE DISPOSED IN AN ENVIRONMENTALLY SAFE
MANNER AND IN ACCORDANCE WITH GOVERNMENTAL REGULATIONS.
BEFORE WORKING ON OR IN TANKS WHICH CONTAIN OR HAVE CONTAINED THIS
MATERIAL, REFER TO OSHA REGULATIONS, ANSI Z49.1 AND OTHER GOVERNMENTAL AND
INDUSTRIAL REFERENCES PERTAINING TO CLEANING, WELDING, OR OTHER
CONTEMPLATED OPERATIONS.
STORAGE:
USE AND STORE THIS MATERIAL IN COOL, DRY, WELL-VENTILATED AREAS AWAY FROM
HEAT AND ALL SOURCES OF IGNITION. POST AREA "NO SMOKING OR OPEN FLAME."
SOLUTION IS CORROSIVE TO COPPER, COPPER ALLOYS, LEAD, AND ZINC. STORE TO
AVOID CONTACT WITH INCOMPATIBLE MATERIALS SUCH AS ORDINARY COMBUSTIBLES,
FLAMMABLE LIQUIDS, GREASES, AND THOSE MATERIALS, INCLUDING OTHER OXIDIZERS,
THAT COULD REACT WITH THE OXIDIZER OR CATALYZE ITS DECOMPOSITION (SEE
SECTION 10). PROHIBIT ACCUMULATION OF COMBUSTIBLE WASTE IN STORAGE AREAS.
COMBUSTIBLE CONSTRUCTION MATERIALS THAT MAY BE IN CONTACT WITH OXIDIZERS
SHALL BE PROTECTED WITH A COMPATIBLE COATING TO PREVENT IMPREGNATION OF THE
COMBUSTIBLE MATERIALS BY THE OXIDIZERS. PROTECT CONTAINER(S) AGAINST
PHYSICAL DAMAGE.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
ENGINEERING CONTROLS:
IF CURRENT VENTILATION PRACTICES ARE NOT ADEQUATE TO MINIMIZE EXPOSURE,
ADDITIONAL VENTILATION OR EXHAUST SYSTEMS MAY BE REQUIRED.
PERSONAL PROTECTIVE EQUIPMENT (PPE):
RESPIRATORY:
A NIOSH/MSHA APPROVED AIR PURIFYING RESPIRATOR WITH A N95 FILTER MAY BE
USED UNDER CONDITIONS WHERE AIRBORNE CONCENTRATIONS ARE EXPECTED TO EXCEED
EXPOSURE LIMITS (SEE SECTION 2). PROTECTION PROVIDED BY AIR PURIFYING
RESPIRATORS IS LIMITED (SEE MANUFACTURER'S RESPIRATOR SELECTION GUIDE). USE
A POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR IF THERE IS POTENTIAL FOR AN
UNCONTROLLED RELEASE, EXPOSURE LEVELS ARE NOT KNOWN, OR ANY OTHER
CIRCUMSTANCES WHERE AIR PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE
PROTECTION. A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR
1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE
CONDITIONS WARRANT A RESPIRATOR'S USE.
SKIN:
THE USE OF GLOVES IMPERMEABLE TO THE SPECIFIC MATERIAL HANDLED IS ADVISED
TO PREVENT SKIN CONTACT, POSSIBLE IRRITATION, ABSORPTION, AND SKIN DAMAGE
(SEE GLOVE MANUFACTURER LITERATURE FOR INFORMATION ON PERMEABILITY).
DEPENDING ON CONDITIONS OF USE, APRON AND/OR ARM COVERS MAY BE NECESSARY.
EYE/FACE:
APPROVED EYE PROTECTION TO SAFEGUARD AGAINST POTENTIAL EYE CONTACT,
IRRITATION, OR INJURY IS RECOMMENDED. DEPENDING ON CONDITIONS OF USE, A
FACE SHIELD MAY BE NECESSARY.
OTHER PROTECTIVE EQUIPMENT:
A SOURCE OF CLEAN WATER SHOULD BE AVAILABLE IN THE WORK AREA FOR FLUSHING
EYES AND SKIN. IMPERVIOUS CLOTHING SHOULD BE WORN AS NEEDED.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
NOTE:
UNLESS OTHERWISE STATED, VALUES ARE DETERMINED AT 20 DEG. C (68 DEG. F) AND
760 MM HG (1 ATM).
FLASH POINT: NONE
FLAMMABLE/EXPLOSIVE LIMITS (%):
LEL/UEL: NO DATA
AUTOIGNITION TEMPERATURE: NO DATA
APPEARANCE: WHITE SOLID IN WATER BAG
PHYSICAL STATE: SOLID/LIQUID
ODOR: NONE
PH: NO DATA
VAPOR PRESSURE (MM Hg): NO DATA
BOILING POINT: NO DATA
FREEZING/MELTING POINT: NO DATA
SOLUBILITY IN WATER: 100%
SPECIFIC GRAVITY: APPROX 1.3
EVAPORATION RATE (NBUAC=1): NO DATA
| SECTION 10. STABILITY AND REACTIVITY | |
CHEMICAL STABILITY:
STABLE UNDER NORMAL CONDITIONS OF STORAGE AND HANDLING. DRY CHEMICAL IS AN
OXIDIZER AND MAY PROMOTE COMBUSTION IN OTHER MATERIALS.
CONDITIONS TO AVOID:
THIS MATERIAL MAY BE AN OXIDIZER. DO NOT HEAT ABOVE 250 DEG. F. DO NOT LET
DRY CHEMICAL OR SOLUTION DRY OR CRYSTALLIZE IN CONTACT WITH ORGANIC,
REACTIVE, OR COMBUSTIBLE MATERIALS (SEE SECTIONS 7).
INCOMPATIBLE MATERIALS:
AVOID CONTACT WITH REACTIVE, COMBUSTIBLE, OR ORGANIC MATERIALS, SUCH AS
WOOD, GRAIN, ORGANIC CHEMICALS, ACIDS, CORROSIVE LIQUIDS, SULFUR, FLAMMABLE
LIQUIDS, CHLORATES, PERMANGANATES, FINELY DIVIDED MATERIALS, CHARCOAL,
COKE, CORK, OR SAWDUST. AVOID CONTACT WITH OTHER OXIDIZERS. CONTACT WITH
ALKALINE MATERIALS MAY LIBERATE AMMONIA.
HAZARDOUS DECOMPOSITION PRODUCTS:
MATERIAL WILL NOT BURN, BUT IF INVOLVED IN A FIRE, OXIDES OF NITROGEN MAY
BE GENERATED. EXPOSURE TO HEAT MAY LIBERATE AMMONIA FUMES.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
NO DEFINITIVE INFORMATION AVAILABLE ON CARCINOGENICITY, MUTAGENICITY,
TARGET ORGANS OR DEVELOPMENTAL TOXICITY.
| SECTION 12. ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION: NOT DETERMINED.
CHEMICAL FATE INFORMATION: NOT DETERMINED.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
THIS MATERIAL, IF DISCARDED AS PRODUCED, MAY BE A RCRA "CHARACTERISTIC"
HAZARDOUS WASTE DUE TO THE CHARACTERISTIC(S) OF IGNITABILITY (D001). IF THE
MATERIAL IS SPILLED TO SOIL OR WATER, CHARACTERISTIC TESTING OF THE
CONTAMINATED MATERIALS IS RECOMMENDED. TO ASSURE PROPER DISPOSAL, CONSULT
WITH STATE AND LOCAL REGULATIONS AND DISPOSAL AUTHORITIES.
| SECTION 14. TRANSPORT INFORMATION | |
PROPER SHIPPING NAME: DOT CONSUMER COMMODITY
CLASS/DIVISION: ORM-D
PACKING GROUP: NOT APPLICABLE
LABELS: ORM-D
UN/ID#: NONE
PROPER SHIPPING NAME: IATA AMMONIUM NITRATE
CLASS DIVISION: 5.1
PACKING GROUP: III
LABELS: OXIDIZER
UN/ID#: UN1942
PROPER SHIPPING NAME: IMO AMMONIUM NITRATE, LIMITED QUANTITY
CLASS/DIVISION: 5.1
PACKING GROUP: III
LABELS:
NOT REQUIRED, HOWEVER, THE WORDS "LIMITED QUANTITY" SHOULD BE MARKED ON THE
UNITIZED PACKAGE.
UN/ID#: UN1942
| SECTION 15. REGULATORY INFORMATION | |
THIS MATERIAL CONTAINS THE FOLLOWING CHEMICALS SUBJECT TO THE REPORTING
REQUIREMENTS OF SARA 313 AND 40 CFR 372.
COMPONENT CAS NUMBER
AMMONIA (INCLUDES ANHYDROUS 7664-41-7
AMMONIA AND AQUEOUS AMMONIA
FROM WATER DISSOCIABLE AMMONIUM
SALTS AND OTHER SOURCES; 10 PERCENT
OF TOTAL AQUEOUS AMMONIA IS
REPORTABLE UNDER THIS LISTING)
WATER DISSOCIABLE NITRATE COMPOUNDS NONE
WARNING:
THIS MATERIAL CONTAINS THE FOLLOWING CHEMICALS WHICH ARE KNOWN TO THE STATE
OF CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM,
AND ARE SUBJECT TO THE REQUIREMENTS OF CALIFORNIA PROPOSITION 65 (CA HEALTH
& SAFETY CODE SECTION 25249.5)
NONE KNOWN
THIS MATERIAL HAS NOT BEEN IDENTIFIED AS A CARCINOGEN BY NTP, IARC, OR
OSHA.
EPA (CERCLA) REPORTABLE QUANTITY: NONE
| SECTION 16. OTHER INFORMATION | |
DISCLAIMER:
THIS SAFETY DATA SHEET, WHICH TAKES INTO CONSIDERATION THE REQUIREMENTS OF
DIRECTIVE 76/768/EC AND SUBSEQUENT AMENDMENTS AND DIRECTIVE 1999/45/EC PLUS
SUBSEQUENT AMENDMENTS, HAS BEEN PREPARED IN ACCORDANCE WITH DIRECTIVE (EC)
1907/2006. IT IS BELIEVED TO BE CORRECT AND CORRESPONDS TO THE LATEST
SCIENTIFIC/TECHNICAL KNOWLEDGE BUT ALL DATA, INSTRUCTIONS, RECOMMENDATIONS
AND/OR SUGGESTIONS ARE MADE WITHOUT GUARANTEE. NO WARRANTY, EXPRESSED OR
IMPLIED, IS MADE AND DYNAREX CORP. ASSUMES NO LEGAL RESPONSIBILITY OR
LIABILITY RESULTING FROM ITS USE.
EXECUTIVE HEADQUARTERS:
TEN GLENSHAW STREET
ORANGEBURG, NY 10962
SAFETY DATA SHEET
REGULATION(EC) NO. 1907/2006, 1272/2008
PRINTING DATE: 21.05.2015
REVISION: 07.05.2015
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE | |
AND OF THE COMPANY/UNDERTAKING
1.1 PRODUCT IDENTIFIER:
TRADE NAME: ACTIVATOR FOR GLOW STICK
1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
APPLICATION OF THE SUBSTANCE / THE MIXTURE: TOY, PARTY ITEMS, DECORATION
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER/SUPPLIER:
XIAMEN LONG AFTERGLOW CO., LTD
NO. 1043, TONG JI ZHONG ROAD, TONG AN DISTRICT, XIAMEN
CHINA
TEL: 0592-3675699
E-MAIL: YOLANDA@GLO-NOVELTY.COM
ONLY REPRESENTATIVE / OTHER EU CONTACT POINT: NOT AVAILABLE
FURTHER INFORMATION OBTAINABLE FROM: XIAMEN LONG AFTERGLOW CO., LTD
1.4 EMERGENCY TELEPHONE NUMBER:
YOLANDA HU
TEL: 0086-592-3675699
UNITED KINGDOM
NATIONAL POISONS INFORMATION SERVICE
TEL: +44 (0) 844 892 0111
1.5 REFERENCE NUMBER: SHTY150400006246-SH; SHATY1507841901
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLASSIFICATION ACCORDING TO REGULATION (EC) NO 1272/2008:
THE PRODUCT IS NOT CLASSIFIED ACCORDING TO THE CLP REGULATION.
CLASSIFICATION ACCORDING TO DIRECTIVE 67/548/EEC OR DIRECTIVE 1999/45/EC:
NOT APPLICABLE
INFORMATION CONCERNING PARTICULAR HAZARDS FOR HUMAN AND ENVIRONMENT:
THE PRODUCT DOES NOT HAVE TO BE LABELED DUE TO THE CALCULATION PROCEDURE OF
REGULATION (EC) NO 1272/2008.
CLASSIFICATION SYSTEM:
THE CLASSIFICATION IS ACCORDING TO THE LATEST EDITION OF THE DIRECTIVES
67/548/EEC, 1999/45/EC AND REGULATION (EC) NO. 1272/2008, AND EXTENDED BY
COMPANY AND LITERATURE DATA.
2.2 LABEL ELEMENTS:
LABELING ACCORDING TO REGULATION (EC) NO 1272/2008: NOT APPLICABLE
HAZARD PICTOGRAMS: NOT APPLICABLE
SIGNAL WORD: NOT APPLICABLE
HAZARD-DETERMINING COMPONENTS OF LABELING: NOT APPLICABLE
HAZARD STATEMENTS: NOT APPLICABLE
PRECAUTIONARY STATEMENTS: NOT APPLICABLE
2.3 OTHER HAZARDS:
RESULTS OF PBT AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE
VPVB: NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.2 MIXTURES:
DESCRIPTION:
MIXTURE OF THE SUBSTANCES LISTED BELOW WITH NONHAZARDOUS ADDITIONS.
FOR THE WORDING OF THE LISTED RISK PHRASES REFER TO SECTION 16.
COMPOSITION:
CAS: 131-11-3 DIMETHYL PHTHALATE 89.5%
EINECS: 205-011-6 SUBSTANCE WITH A COMMUNITY WORKPLACE
EXPOSURE LIMIT
CAS: 7732-18-5 WATER 8.2%
EINECS: 231-791-2
CAS: 7722-84-1 HYDROGEN PEROXIDE 2.3%
EINECS: 231-765-0 C R35; XN R20/22; O R8
INDEX NUMBER: R5
008-003-00-9 OX. LIQ. 1, H271; SKIN CORR. IA, H314;
ACUTE TOX. 4. H302; ACUTE TOX. 4, H332
| SECTION 4: FIRST AID MEASURES | |
4.1 DESCRIPTION OF FIRST AID MEASURES:
AFTER INHALATION: SUPPLY FRESH AIR; CONSULT DOCTOR IN CASE OF COMPLAINTS.
AFTER SKIN CONTACT:
IMMEDIATELY WASH WITH WATER AND SOAP AND RINSE THOROUGHLY.
IF SKIN IRRITATION CONTINUES, CONSULT A DOCTOR.
AFTER EYE CONTACT:
RINSE OPENED EYE FOR SEVERAL MINUTES UNDER RUNNING WATER. IF SYMPTOMS
PERSIST, CONSULT A DOCTOR.
AFTER SWALLOWING:
RINSE OUT MOUTH WITH WATER.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
IF SYMPTOMS PERSIST CONSULT DOCTOR.
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| SECTION 5: FIREFIGHTING MEASURES | |
5.1 EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING AGENTS:
USE FIRE EXTINGUISHING METHODS SUITABLE TO SURROUNDING CONDITIONS.
5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
5.3 ADVICE FOR FIREFIGHTERS:
PROTECTIVE EQUIPMENT:
WEAR FULLY PROTECTIVE SUIT.
MOUTH RESPIRATORY PROTECTIVE DEVICE.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
WEAR PROTECTIVE EQUIPMENT. KEEP UNPROTECTED PERSONS AWAY.
ENSURE ADEQUATE VENTILATION
USE RESPIRATORY PROTECTIVE DEVICE AGAINST THE EFFECTS OF
FUMES/DUST/AEROSOL.
AVOID CONTACT WITH EYES.
AVOID CONTACT WITH SKIN.
6.2 ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW TO ENTER SEWERS/SURFACE OR GROUND WATER.
6.3 METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
ABSORB WITH LIQUID-BINDING MATERIAL (SAND, DIATOMITE, ACID BINDERS,
UNIVERSAL BINDERS, SAWDUST).
DISPOSE CONTAMINATED MATERIAL AS WASTE ACCORDING TO ITEM 13.
6.4 REFERENCE TO OTHER SECTIONS:
SEE SECTION 7 FOR INFORMATION ON SAFE HANDLING.
SEE SECTION 8 FOR INFORMATION ON PERSONAL PROTECTION EQUIPMENT.
SEE SECTION 13 FOR DISPOSAL INFORMATION.
| SECTION 7: HANDLING AND STORAGE | |
7.1 PRECAUTIONS FOR SAFE HANDLING:
ENSURE GOOD VENTILATION/EXHAUSTION AT THE WORKPLACE.
KEEP RECEPTACLES TIGHTLY SEALED.
KEEP AWAY FROM HEAT AND DIRECT SUNLIGHT.
PREVENT FORMATION OF AEROSOLS.
AVOID CONTACT WITH SKIN AND EYES.
INFORMATION ABOUT FIRE - AND EXPLOSION PROTECTION:
PROTECT FROM HEAT.
KEEP RESPIRATORY PROTECTIVE DEVICE AVAILABLE.
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
REQUIREMENTS TO BE MET BY STOREROOMS AND RECEPTACLES:
STORE IN A COOL LOCATION.
STORE ONLY IN THE ORIGINAL RECEPTACLE.
INFORMATION ABOUT STORAGE IN ONE COMMON STORAGE FACILITY:
STORE AWAY FROM FOODSTUFFS.
STORE AWAY FROM FLAMMABLE SUBSTANCES.
FURTHER INFORMATION ABOUT STORAGE CONDITIONS:
STORE IN COOL, DRY CONDITIONS IN WELL SEALED RECEPTACLES.
7.3 SPECIFIC END USE(S): NO FURTHER RELEVANT INFORMATION AVAILABLE.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1 CONTROL PARAMETERS:
INGREDIENTS WITH LIMIT VALUES THAT REQUIRE MONITORING AT THE WORKPLACE:
131-11-3 DIMETHYL PHTHALATE (89,5%):
WEL (GREAT BRITAIN):
SHORT-TERM VALUE: 10 MG/M3
LONG-TERM VALUE: 5 MG/M3
VME (FRANCE):
LONG-TERM VALUE: 5 MG/M3
7722-84-1 HYDROGEN PEROXIDE (2,3%):
MAK (GERMANY):
LONG-TERM VALUE: 0,71 MG/M3, 0,5 PPM
WEL (GREAT BRITAIN):
SHORT-TERM VALUE: 2,8 MG/M3, 2 PPM
LONG-TERM VALUE: 1,4 MG/M3, 1 PPM
VME (FRANCE):
LONG-TERM VALUE: 1,5 MG/M3, 1 PPM
DNELS: NOT APPLICABLE
PNECS: NOT APPLICABLE
ADDITIONAL INFORMATION:
THE LISTS VALID DURING THE MAKING WERE USED AS BASIS.
8.2 EXPOSURE CONTROLS:
BASED ON COMPOSITION SHOWN IN SECTION 3, THE FOLLOWING MEASURES ARE
SUGGESTED FOR OCCUPATIONAL SAFETY MEASURE:
APPROPRIATE ENGINEERING CONTROLS:
SEE SECTION 7 FOR INFORMATION ABOUT DESIGN OF TECHNICAL FACILITIES.
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION: SUITABLE RESPIRATORY PROTECTIVE DEVICE RECOMMENDED.
PROTECTION OF HANDS: PROTECTIVE GLOVES
THE GLOVE MATERIAL HAS TO BE IMPERMEABLE AND RESISTANT TO THE PRODUCT/THE
SUBSTANCE/THE PREPARATION.
DUE TO MISSING TESTS NO RECOMMENDATION TO THE GLOVE MATERIAL CAN BE GIVEN
FOR THE PRODUCT/THE PREPARATION/THE CHEMICAL MIXTURE.
SELECTION OF THE GLOVE MATERIAL ON CONSIDERATION OF THE PENETRATION TIMES,
RATES OF DIFFUSION AND THE DEGRADATION
MATERIAL OF GLOVES:
THE SELECTION OF THE SUITABLE GLOVES DOES NOT ONLY DEPEND ON THE MATERIAL,
BUT ALSO ON FURTHER MARKS OF QUALITY AND VARIES FROM MANUFACTURER TO
MANUFACTURER. AS THE PRODUCT IS A PREPARATION OF SEVERAL SUBSTANCES, THE
RESISTANCE OF THE GLOVE MATERIAL CAN NOT BE CALCULATED IN ADVANCE AND HAS
THEREFORE TO BE CHECKED PRIOR TO THE APPLICATION.
PENETRATION TIME OF GLOVE MATERIAL:
THE EXACT BREAK THROUGH TIME HAS TO BE FOUND OUT BY THE MANUFACTURER OF THE
PROTECTIVE GLOVES AND HAS TO BE OBSERVED.
EYE PROTECTION: TIGHTLY SEALED GOGGLES
ENVIRONMENTAL EXPOSURE CONTROLS:
CONTROL MEASURES MUST BE MADE IN ACCORDANCE WITH COMMUNITY ENVIRONMENTAL
PROTECTION LEGISLATION.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE:
FORM: LIQUID
COLOUR: TRANSPARENT
ODOUR: ODOURLESS
ODOUR THRESHOLD: DATA NOT AVAILABLE.
PH-VALUE: DATA NOT AVAILABLE.
CHANGE IN CONDITION:
MELTING POINT/MELTING RANGE: DATA NOT AVAILABLE.
BOILING POINT/BOILING RANGE: DATA NOT AVAILABLE
FREEZING POINT: DATA NOT AVAILABLE
FLASH POINT: DATA NOT AVAILABLE
FLAMMABILITY (SOLID, GASEOUS): NOT APPLICABLE
AUTO-IGNITION TEMPERATURE: DATA NOT AVAILABLE
DECOMPOSITION TEMPERATURE: DATE NOT AVAILABLE.
SELF-IGNITING: PRODUCT IS NOT SELFIGNITING.
EXPLOSIVE PROPERTIES: PRODUCT DOES NOT PRESENT AN EXPLOSION HAZARD.
EXPLOSION LIMITS:
LOWER: DATA NOT AVAILABLE.
UPPER: DATA NOT AVAILABLE.
OXIDIZING PROPERTIES DATA NOT AVAILABLE.
VAPOUR PRESSURE: DATA NOT AVAILABLE.
DENSITY: DATA NOT AVAILABLE.
RELATIVE DENSITY: DATA NOT AVAILABLE.
VAPOUR DENSITY: DATA NOT AVAILABLE.
EVAPORATION RATE: DATA NOT AVAILABLE.
SOLUBILITY IN / MISCIBILITY WITH WATER: DATA NOT AVAILABLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): DATA NOT AVAILABLE.
VISCOSITY:
DYNAMIC: DATA NOT AVAILABLE.
KINEMATIC: DATA NOT AVAILABLE.
9.2 OTHER INFORMATION: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| SECTION 10: STABILITY AND REACTIVITY | |
10.1 REACTIVITY: NO DECOMPOSITION IF USED ACCORDING TO SPECIFICATION.
10.2 CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS: NO DANGEROUS REACTIONS KNOWN.
10.4 CONDITIONS TO AVOID: NO FURTHER RELEVANT INFORMATION AVAILABLE.
10.5 INCOMPATIBLE MATERIALS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
10.6 HAZARDOUS DECOMPOSITION PRODUCTS:
NO DANGEROUS DECOMPOSITION PRODUCTS KNOWN.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
LD/LC50 VALUES RELEVANT FOR CLASSIFICATION:
131-11-3 DIMETHYL PHTHALATE:
ORAL LD50: 6800 MG/KG (RAT)
DERMAL LD50: >23800 MG/KG (RABBIT)
7722-84-1 HYDROGEN PEROXIDE:
ORAL LD50: 376 MG/KG (RAT)
DERMAL LD50: 3000 MG/KG (RAT)
INHALATIVE LC50/4 H: 2 MG/L (RAT)
PRIMARY IRRITANT EFFECT:
SKIN CORROSION/IRRITATION: IRRITATING EFFECT POSSIBLE.
SERIOUS EYE DAMAGE/IRRITATION: IRRITATING EFFECT POSSIBLE.
RESPIRATORY OR SKIN SENSITIZATION: IRRITATING EFFECT POSSIBLE.
ADDITIONAL TOXICOLOGICAL INFORMATION:
THE PRODUCT IS NOT SUBJECTED TO CLASSIFICATION ACCORDING TO THE CALCULATION
METHOD BASED ON THE EU DIRECTIVES 67/548/EEC, 1999/45/EC AND REGULATION
1272/2008/EC.
TOXICOKINETICS, METABOLISM AND DISTRIBUTION: DATA NOT AVAILABLE
ACUTE EFFECTS (ACUTE TOXICITY, IRRITATION AND CORROSIVITY):
DATA NOT AVAILABLE
REPEATED DOSE TOXICITY: DATA NOT AVAILABLE
CMR EFFECTS (CARCINOGENITY, MUTAGENICITY AND TOXICITY FOR REPRODUCTION):
DATA NOT AVAILABLE
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1 TOXICITY:
AQUATIC TOXICITY: NO FURTHER RELEVANT INFORMATION AVAILABLE.
12.2 PERSISTENCE AND DEGRADABILITY:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
12.3 BIOACCUMULATIVE POTENTIAL: NO FURTHER RELEVANT INFORMATION AVAILABLE.
12.4 MOBILITY IN SOIL: NO FURTHER RELEVANT INFORMATION AVAILABLE.
12.5 RESULTS OF PBT AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE.
VPVB: NOT APPLICABLE.
12.6 OTHER ADVERSE EFFECTS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
12.7 ADDITIONAL ECOLOGICAL INFORMATION:
GENERAL NOTES:
WATER HAZARD CLASS 1 (GERMAN REGULATION) (SELF-ASSESSMENT):
SLIGHTLY HAZARDOUS FOR WATER
DO NOT ALLOW UNDILUTED PRODUCT OR LARGE QUANTITIES OF IT TO REACH GROUND
WATER, WATER COURSE OR SEWAGE SYSTEM.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1 WASTE TREATMENT METHODS:
RECOMMENDATION: SMALLER QUANTITIES CAN BE DISPOSED OF WITH HOUSEHOLD WASTE.
UNCLEANED PACKAGING:
RECOMMENDATION: DISPOSAL MUST BE MADE ACCORDING TO OFFICIAL REGULATIONS.
| SECTION 14: TRANSPORT INFORMATION | |
14.1 UN-NUMBER:
ADR, IMDG, IATA: NOT APPLICABLE
14.2 UN PROPER SHIPPING NAME:
ADR, IMDG, IATA: NOT APPLICABLE
14.3 TRANSPORT HAZARD CLASS(ES):
ADR, IMDG, IATA:
CLASS: NOT APPLICABLE
14.4 PACKING GROUP:
ADR, IMDG, IATA: NOT APPLICABLE
14.5 ENVIRONMENTAL HAZARDS: NOT APPLICABLE.
MARINE POLLUTANT: NO
14.6 SPECIAL PRECAUTIONS FOR USER: NOT APPLICABLE.
14.7 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC
CODE: NOT APPLICABLE.
UN "MODEL REGULATION":
| SECTION 15: REGULATORY INFORMATION | |
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR
THE SUBSTANCE OR MIXTURE:
MAK (GERMAN MAXIMUM WORKPLACE CONCENTRATION):
7722-84-1 HYDROGEN PEROXIDE 4
NATIONAL REGULATIONS:
WATERHAZARD CLASS:
WATER HAZARD CLASS 1 (SELF-ASSESSMENT): SLIGHTLY HAZARDOUS FOR WATER.
OTHER REGULATIONS, LIMITATIONS AND PROHIBITIVE REGULATIONS:
SVHC CANDIDATE LIST OF REACH REGULATION ANNEX XIV AUTHORIZATION
(17/12/2014): NONE OF THE INGREDIENTS IS LISTED.
REACH REGULATION ANNEX XVII RESTRICTION (2/3/2015):
NONE OF THE INGREDIENTS IS LISTED.
REACH REGULATION ANNEX XIV AUTHORIZATION LIST (14/8/2014)
NONE OF THE INGREDIENTS IS LISTED.
15.2 CHEMICAL SAFETY ASSESSMENT:
A CHEMICAL SAFETY ASSESSMENT HAS NOT BEEN CARRIED OUT.
| SECTION 16: OTHER INFORMATION | |
RELEVANT HAZARD STATEMENTS:
H271: MAY CAUSE FIRE OR EXPLOSION; STRONG OXIDIZER.
H302: HARMFUL IF SWALLOWED.
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
H332: HARMFUL IF INHALED.
R20/22: HARMFUL BY INHALATION AND IF SWALLOWED.
R35: CAUSES SEVERE BURNS.
R5: HEATING MAY CAUSE AN EXPLOSION
R8: CONTACT WITH COMBUSTIBLE MATERIAL MAY CAUSE FIRE.
THE CONTENTS AND FORMAT OF THIS SDS ARE IN ACCORDANCE WITH REGULATION (EC)
NO 1272/2008, REGULATION (EC) NO 1907/2006, REGULATION (EU) NO 453/2010 AND
EU COMMISSION DIRECTIVE 1999/45/EC, 67/548/EEC.
DISCLAIMER OF LIABILITY:
THE INFORMATION IN THIS SDS WAS OBTAINED FROM SOURCES WHICH WE BELIEVE ARE
RELIABLE. HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY WARRANTY,
EXPRESS OR IMPLIED, REGARDING ITS CORRECTNESS. THE CONDITIONS OR METHODS OF
HANDLING, STORAGE, USE OR DISPOSAL OF THE PRODUCT ARE BEYOND OUR CONTROL
AND MAY BE BEYOND OUR KNOWLEDGE. FOR THIS AND OTHER REASONS, WE DO NOT
ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR LOSS, DAMAGE OR
EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED WITH THE HANDLING, STORAGE,
USE OR DISPOSAL OF THE PRODUCT. THIS SDS WAS PREPARED AND IS TO BE USED
ONLY FOR THIS PRODUCT. IF THE PRODUCT IS USED AS A COMPONENT IN ANOTHER
PRODUCT, THIS SDS INFORMATION MAY NOT BE APPLICABLE.
ABBREVIATIONS AND ACRONYMS:
ADR:
ACCORD EUROPEEN SUR LE TRANSPORT DES MARCHANDISES DANGEREUSES PAR ROUTE
(EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS
GOODS BY ROAD)
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
GHS: GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
EINECS: EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES
ELINCS: EUROPEAN LIST OF NOTIFIED CHEMICAL SUBSTANCES
CAS: CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY)
DNEL: DERIVED NO-EFFECT LEVEL (REACH)
PNEC: PREDICTED NO-EFFECT CONCENTRATION (REACH)
LC50: LETHAL CONCENTRATION, 50 PERCENT
LD50: LETHAL DOSE, 50 PERCENT
OX. LIQ. 1: OXIDIZING LIQUIDS, HAZARD CATEGORY 1
ACUTE TOX. 4: ACUTE TOXICITY, HAZARD CATEGORY 4
SKIN CORR. 1A: SKIN CORROSION/IRRITATION, HAZARD CATEGORY 1A
EU
SAFETY DATA SHEET
REGULATION(EC) NO. 1907/2006, 1272/2008
PRINTING DATE: 21.05.2015
REVISION: 07.05.2015
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE | |
AND OF THE COMPANY/UNDERTAKING
1.1 PRODUCT IDENTIFIER:
TRADE NAME: CHEMILUMINESCER FOR GREEN GLOW STICK
1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
APPLICATION OF THE SUBSTANCE / THE MIXTURE: TOY, PARTY ITEMS, DECORATION
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER/SUPPLIER:
XIAMEN LONG AFTERGLOW CO., LTD
NO. 1043, TONG JI ZHONG ROAD
TONG AN DISTRICT, XIAMEN
CHINA
TEL: 0592-3675699
E-MAIL: YOLANDA@GLO-NOVELTY.COM
ONLY REPRESENTATIVE / OTHER EU CONTACT POINT: NOT AVAILABLE
FURTHER INFORMATION OBTAINABLE FROM: XIAMEN LONG AFTERGLOW CO., LTD
1.4 EMERGENCY TELEPHONE NUMBER: YOLANDA HU
TEL: 0086-592-3675699
UNITED KINGDOM
NATIONAL POISONS INFORMATION SERVICE
TEL: +44 (0) 844 892 0111
1.5 REFERENCE NUMBER: SHTY150400006246-SH; SHATY1507841901
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLASSIFICATION ACCORDING TO REGULATION (EC) NO 1272/2008:
GHS07: EXCLAMATION MARK
ACUTE TOX. 4
H302: HARMFUL IF SWALLOWED.
SKIN IRRIT. 2
H315: CAUSES SKIN IRRITATION.
EYE IRRIT. 2
H319: CAUSES SERIOUS EYE IRRITATION.
CLASSIFICATION ACCORDING TO DIRECTIVE 67/548/EEC OR DIRECTIVE 1999/45/EC:
XN; HARMFUL
R22: HARMFUL IF SWALLOWED.
XI; IRRITANT
R36/38: IRRITATING TO EYES AND SKIN.
INFORMATION CONCERNING PARTICULAR HAZARDS FOR HUMAN AND ENVIRONMENT:
THE PRODUCT HAS TO BE LABELED DUE TO THE CALCULATION PROCEDURE OF
REGULATION (EC) NO 1272/2008.
CLASSIFICATION SYSTEM:
THE CLASSIFICATION IS ACCORDING TO THE LATEST EDITION OF THE DIRECTIVES
67/548/EEC, 1999/45/EC AND REGULATION (EC) NO. 1272/2008, AND EXTENDED BY
COMPANY AND LITERATURE DATA.
2.2 LABEL ELEMENTS:
LABELING ACCORDING TO REGULATION (EC) NO 1272/2008:
THE PRODUCT IS CLASSIFIED AND LABELED ACCORDING TO REGULATION (EC) NO
1272/2008.
HAZARD PICTOGRAMS:
GHS07: EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD-DETERMINING COMPONENTS OF LABELING: BUTYL BENZOATE
HAZARD STATEMENTS:
H302: HARMFUL IF SWALLOWED.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
PRECAUTIONARY STATEMENTS:
P101: IF MEDICAL ADVICE IS NEEDED, HAVE PRODUCT CONTAINER OR LABEL AT HAND.
P102: KEEP OUT OF REACH OF CHILDREN.
P103: READ LABEL BEFORE USE.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P321: SPECIFIC TREATMENT (SEE ON THIS LABEL).
P301+P312:
IF SWALLOWED: CALL A POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
P332+P313:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3 OTHER HAZARDS:
RESULTS OF PBT AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE
VPVB: NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.2 MIXTURES:
DESCRIPTION:
MIXTURE OF THE SUBSTANCES LISTED BELOW WITH NONHAZARDOUS ADDITIONS.
FOR THE WORDING OF THE LISTED RISK PHRASES REFER TO SECTION 16.
COMPOSITION:
CAS: 136-60-7 BUTYL BENZOATE 85,4%
EINECS: 205-252-7 XN R22; XI R36/38
ACUTE TOX. 4, H302; SKIN IRRIT.
2, H315; EYE IRRIT. 2, H319
CAS: 75203-51-9 BIS(2,3,5-TRICHLORO-6- 14,0%
EINECS: 278-124-1 ((PENTYLOXY)CARBONYL)PHENYL)
OXALATE
CAS: 10075-85-1 9,10-BIS(PHENYLVINYL)ANTHRACENE 0,6%
XI R36/37/38
SKIN IRRIT. 2, H315; EYE IRRIT.
2, H319; STOT SE 3, H335
| SECTION 4: FIRST AID MEASURES | |
4.1 DESCRIPTION OF FIRST AID MEASURES:
GENERAL INFORMATION:
SYMPTOMS OF POISONING MAY EVEN OCCUR AFTER SEVERAL HOURS; THEREFORE MEDICAL
OBSERVATION FOR AT LEAST 48 HOURS AFTER THE ACCIDENT.
AFTER INHALATION:
SUPPLY FRESH AIR AND TO BE SURE CALL FOR A DOCTOR. IN CASE OF
UNCONSCIOUSNESS PLACE PATIENT STABLY IN SIDE POSITION FOR TRANSPORTATION.
AFTER SKIN CONTACT:
IMMEDIATELY WASH WITH WATER AND SOAP AND RINSE THOROUGHLY.
IF SKIN IRRITATION CONTINUES, CONSULT A DOCTOR.
AFTER EYE CONTACT:
RINSE OPENED EYE FOR SEVERAL MINUTES UNDER RUNNING WATER. IF SYMPTOMS
PERSIST, CONSULT A DOCTOR.
AFTER SWALLOWING:
RINSE OUT MOUTH WITH WATER.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
CALL FOR A DOCTOR IMMEDIATELY.
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| SECTION 5: FIREFIGHTING MEASURES | |
5.1 EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING AGENTS:
USE FIRE EXTINGUISHING METHODS SUITABLE TO SURROUNDING CONDITIONS.
5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
5.3 ADVICE FOR FIREFIGHTERS:
PROTECTIVE EQUIPMENT:
WEAR FULLY PROTECTIVE SUIT.
WEAR SELF-CONTAINED RESPIRATORY PROTECTIVE DEVICE.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
WEAR PROTECTIVE EQUIPMENT. KEEP UNPROTECTED PERSONS AWAY.
ENSURE ADEQUATE VENTILATION
KEEP AWAY FROM IGNITION SOURCES.
USE RESPIRATORY PROTECTIVE DEVICE AGAINST THE EFFECTS OF
FUMES/DUST/AEROSOL.
AVOID CONTACT WITH EYES.
AVOID CONTACT WITH SKIN.
6.2 ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW TO ENTER SEWERS/ SURFACE OR GROUND WATER.
6.3 METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
ABSORB WITH LIQUID-BINDING MATERIAL (SAND, DIATOMITE, ACID BINDERS,
UNIVERSAL BINDERS, SAWDUST).
DISPOSE CONTAMINATED MATERIAL AS WASTE ACCORDING TO ITEM 13.
ENSURE ADEQUATE VENTILATION.
6.4 REFERENCE TO OTHER SECTIONS:
SEE SECTION 7 FOR INFORMATION ON SAFE HANDLING.
SEE SECTION 8 FOR INFORMATION ON PERSONAL PROTECTION EQUIPMENT.
SEE SECTION 13 FOR DISPOSAL INFORMATION.
| SECTION 7: HANDLING AND STORAGE | |
7.1 PRECAUTIONS FOR SAFE HANDLING:
ENSURE GOOD VENTILATION/EXHAUSTION AT THE WORKPLACE.
KEEP RECEPTACLES TIGHTLY SEALED.
KEEP AWAY FROM HEAT AND DIRECT SUNLIGHT.
PREVENT FORMATION OF AEROSOLS.
AVOID CONTACT WITH SKIN AND EYES.
INFORMATION ABOUT FIRE - AND EXPLOSION PROTECTION:
NORMAL MEASURES FOR PREVENTIVE FIRE PROTECTION.
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
REQUIREMENTS TO BE MET BY STOREROOMS AND RECEPTACLES:
STORE IN A COOL LOCATION.
STORE ONLY IN THE ORIGINAL RECEPTACLE.
INFORMATION ABOUT STORAGE IN ONE COMMON STORAGE FACILITY:
STORE AWAY FROM FOODSTUFFS.
STORE AWAY FROM FLAMMABLE SUBSTANCES.
STORE AWAY FROM OXIDIZING AGENTS.
DO NOT STORE TOGETHER WITH ALKALINE MATERIALS.
FURTHER INFORMATION ABOUT STORAGE CONDITIONS:
KEEP CONTAINER TIGHTLY SEALED.
STORE IN COOL, DRY CONDITIONS IN WELL SEALED RECEPTACLES.
7.3 SPECIFIC END USE(S): NO FURTHER RELEVANT INFORMATION AVAILABLE.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1 CONTROL PARAMETERS:
INGREDIENTS WITH LIMIT VALUES THAT REQUIRE MONITORING AT THE WORKPLACE:
THE PRODUCT DOES NOT CONTAIN ANY RELEVANT QUANTITIES OF MATERIALS WITH
CRITICAL VALUES THAT HAVE TO BE MONITORED AT THE WORKPLACE.
DNELS: NOT APPLICABLE
PNECS: NOT APPLICABLE
ADDITIONAL INFORMATION:
THE LISTS VALID DURING THE MAKING WERE USED AS BASIS.
8.2 EXPOSURE CONTROLS:
BASED ON COMPOSITION SHOWN IN SECTION 3, THE FOLLOWING MEASURES ARE
SUGGESTED FOR OCCUPATIONAL SAFETY MEASURE:
APPROPRIATE ENGINEERING CONTROLS:
KEEP AWAY FROM FOODSTUFFS, BEVERAGES AND FEED.
IMMEDIATELY REMOVE ALL SOILED AND CONTAMINATED CLOTHING
WASH HANDS BEFORE BREAKS AND AT THE END OF WORK.
AVOID CONTACT WITH THE EYES AND SKIN.
SEE SECTION 7 FOR INFORMATION ABOUT DESIGN OF TECHNICAL FACILITIES.
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION:
IN CASE OF BRIEF EXPOSURE OR LOW POLLUTION USE RESPIRATORY FILTER DEVICE.
IN CASE OF INTENSIVE OR LONGER EXPOSURE USE SELF-CONTAINED RESPIRATORY
PROTECTIVE DEVICE.
PROTECTION OF HANDS: PROTECTIVE GLOVES
THE GLOVE MATERIAL HAS TO BE IMPERMEABLE AND RESISTANT TO THE PRODUCT/THE
SUBSTANCE/THE PREPARATION. DUE TO MISSING TESTS NO RECOMMENDATION TO THE
GLOVE MATERIAL CAN BE GIVEN FOR THE PRODUCT/THE PREPARATION/THE CHEMICAL
MIXTURE.
SELECTION OF THE GLOVE MATERIAL ON CONSIDERATION OF THE PENETRATION TIMES,
RATES OF DIFFUSION AND THE DEGRADATION
MATERIAL OF GLOVES:
THE SELECTION OF THE SUITABLE GLOVES DOES NOT ONLY DEPEND ON THE MATERIAL,
BUT ALSO ON FURTHER MARKS OF QUALITY AND VARIES FROM MANUFACTURER TO
MANUFACTURER. AS THE PRODUCT IS A PREPARATION OF SEVERAL SUBSTANCES, THE
RESISTANCE OF THE GLOVE MATERIAL CAN NOT BE CALCULATED IN ADVANCE AND HAS
THEREFORE TO BE CHECKED PRIOR TO THE APPLICATION.
PENETRATION TIME OF GLOVE MATERIAL:
THE EXACT BREAK THROUGH TIME HAS TO BE FOUND OUT BY THE MANUFACTURER OF THE
PROTECTIVE GLOVES AND HAS TO BE OBSERVED.
EYE PROTECTION: TIGHTLY SEALED GOGGLES
ENVIRONMENTAL EXPOSURE CONTROLS:
CONTROL MEASURES MUST BE MADE IN ACCORDANCE WITH COMMUNITY ENVIRONMENTAL
PROTECTION LEGISLATION.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE:
FORM: LIQUID
COLOUR: GREEN
ODOUR: ODOURLESS
ODOUR THRESHOLD: DATA NOT AVAILABLE.
PH-VALUE: DATA NOT AVAILABLE.
CHANGE IN CONDITION:
MELTING POINT/MELTING RANGE: DATA NOT AVAILABLE.
BOILING POINT/BOILING RANGE: DATA NOT AVAILABLE
FREEZING POINT: DATA NOT AVAILABLE
FLASH POINT: DATA NOT AVAILABLE
FLAMMABILITY (SOLID, GASEOUS): NOT APPLICABLE
AUTO-IGNITION TEMPERATURE: DATA NOT AVAILABLE
DECOMPOSITION TEMPERATURE: DATE NOT AVAILABLE.
SELF-IGNITING: PRODUCT IS NOT SELFIGNITING.
EXPLOSIVE PROPERTIES: PRODUCT DOES NOT PRESENT AN EXPLOSION HAZARD.
EXPLOSION LIMITS:
LOWER: DATA NOT AVAILABLE.
UPPER: DATA NOT AVAILABLE.
OXIDIZING PROPERTIES: DATA NOT AVAILABLE.
VAPOUR PRESSURE: DATA NOT AVAILABLE.
DENSITY: DATA NOT AVAILABLE.
RELATIVE DENSITY: DATA NOT AVAILABLE.
VAPOUR DENSITY: DATA NOT AVAILABLE.
EVAPORATION RATE: DATA NOT AVAILABLE.
SOLUBILITY IN / MISCIBILITY WITH WATER: DATA NOT AVAILABLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): DATA NOT AVAILABLE.
VISCOSITY:
DYNAMIC: DATA NOT AVAILABLE.
KINEMATIC: DATA NOT AVAILABLE.
9.2 OTHER INFORMATION: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| SECTION 10: STABILITY AND REACTIVITY | |
10.1 REACTIVITY: NO DECOMPOSITION IF USED ACCORDING TO SPECIFICATION.
10.2 CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS: NO DANGEROUS REACTIONS KNOWN.
10.4 CONDITIONS TO AVOID: NO FURTHER RELEVANT INFORMATION AVAILABLE.
10.5 INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS, STRONG BASES
10.6 HAZARDOUS DECOMPOSITION PRODUCTS:
NO DANGEROUS DECOMPOSITION PRODUCTS KNOWN.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
LD/LC50 VALUES RELEVANT FOR CLASSIFICATION:
136-60-7 BUTYL BENZOATE:
ORAL LD50: 735 MG/KG (RAT)
DERMAL LD50: 4000 MG/KG (RABBIT)
PRIMARY IRRITANT EFFECT:
SKIN CORROSION/IRRITATION: IRRITANT TO SKIN AND MUCOUS MEMBRANES.
SERIOUS EYE DAMAGE/IRRITATION: IRRITATING EFFECT.
RESPIRATORY OR SKIN SENSITIZATION: SENSITIZATION POSSIBLE.
ADDITIONAL TOXICOLOGICAL INFORMATION:
THE PRODUCT IS NOT SUBJECTED TO CLASSIFICATION ACCORDING TO THE CALCULATION
METHOD BASED ON THE EU DIRECTIVES 67/548/EEC, 1999/45/EC AND REGULATION
1272/2008/EC.
HARMFUL
IRRITANT
TOXICOKINETICS, METABOLISM AND DISTRIBUTION: DATA NOT AVAILABLE
ACUTE EFFECTS (ACUTE TOXICITY, IRRITATION AND CORROSIVITY):
DATA NOT AVAILABLE
REPEATED DOSE TOXICITY: DATA NOT AVAILABLE
CMR EFFECTS (CARCINOGENITY, MUTAGENICITY AND TOXICITY FOR REPRODUCTION):
DATA NOT AVAILABLE
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1 TOXICITY:
AQUATIC TOXICITY: NO FURTHER RELEVANT INFORMATION AVAILABLE.
12.2 PERSISTENCE AND DEGRADABILITY:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
12.3 BIOACCUMULATIVE POTENTIAL: NO FURTHER RELEVANT INFORMATION AVAILABLE.
12.4 MOBILITY IN SOIL: NO FURTHER RELEVANT INFORMATION AVAILABLE.
12.5 RESULTS OF PBT AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE.
VPVB: NOT APPLICABLE.
12.6 OTHER ADVERSE EFFECTS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
12.7 ADDITIONAL ECOLOGICAL INFORMATION:
GENERAL NOTES:
WATER HAZARD CLASS 2 (GERMAN REGULATION) (SELF-ASSESSMENT):
HAZARDOUS FOR WATER
DO NOT ALLOW PRODUCT TO REACH GROUND WATER, WATER COURSE OR SEWAGE SYSTEM.
DANGER TO DRINKING WATER IF EVEN SMALL QUANTITIES LEAK INTO THE GROUND.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1 WASTE TREATMENT METHODS:
RECOMMENDATION
MUST NOT BE DISPOSED TOGETHER WITH HOUSEHOLD GARBAGE. DO NOT ALLOW PRODUCT
TO REACH SEWAGE SYSTEM.
UNCLEANED PACKAGING:
RECOMMENDATION: DISPOSAL MUST BE MADE ACCORDING TO OFFICIAL REGULATIONS.
| SECTION 14: TRANSPORT INFORMATION | |
14.1 UN-NUMBER:
ADR, IMDG, IATA: NOT APPLICABLE
14.2 UN PROPER SHIPPING NAME:
ADR, IMDG, IATA: NOT APPLICABLE
14.3 TRANSPORT HAZARD CLASS(ES):
ADR, IMDG, IATA:
CLASS: NOT APPLICABLE
14.4 PACKING GROUP:
ADR, IMDG, IATA: NOT APPLICABLE
14.5 ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO
14.6 SPECIAL PRECAUTIONS FOR USER: NOT APPLICABLE.
14.7 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC
CODE: NOT APPLICABLE.
UN "MODEL REGULATION":
| SECTION 15: REGULATORY INFORMATION | |
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR
THE SUBSTANCE OR MIXTURE:
MAK (GERMAN MAXIMUM WORKPLACE CONCENTRATION):
NONE OF THE INGREDIENTS IS LISTED.
NATIONAL REGULATIONS:
WATERHAZARD CLASS:
WATER HAZARD CLASS 2 (SELF-ASSESSMENT): HAZARDOUS FOR WATER.
OTHER REGULATIONS, LIMITATIONS AND PROHIBITIVE REGULATIONS:
SVHC CANDIDATE LIST OF REACH REGULATION ANNEX XIV AUTHORIZATION
(17/12/2014): NONE OF THE INGREDIENTS IS LISTED.
REACH REGULATION ANNEX XVII RESTRICTION (2/3/2015):
NONE OF THE INGREDIENTS IS LISTED.
REACH REGULATION ANNEX XIV AUTHORIZATION LIST (14/8/2014):
NONE OF THE INGREDIENTS IS LISTED.
15.2 CHEMICAL SAFETY ASSESSMENT:
A CHEMICAL SAFETY ASSESSMENT HAS NOT BEEN CARRIED OUT.
| SECTION 16: OTHER INFORMATION | |
RELEVANT PHRASES:
H302: HARMFUL IF SWALLOWED.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
R22: HARMFUL IF SWALLOWED.
R36/38: IRRITATING TO EYES AND SKIN.
THE CONTENTS AND FORMAT OF THIS SDS ARE IN ACCORDANCE WITH REGULATION (EC)
NO 1272/2008, REGULATION (EC) NO 1907/2006, REGULATION (EU) NO 453/2010 AND
EU COMMISSION DIRECTIVE 1999/45/ EC, 67/548/EEC.
DISCLAIMER OF LIABILITY:
THE INFORMATION IN THIS SDS WAS OBTAINED FROM SOURCES WHICH WE BELIEVE ARE
RELIABLE. HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY WARRANTY,
EXPRESS OR IMPLIED, REGARDING ITS CORRECTNESS. THE CONDITIONS OR METHODS OF
HANDLING, STORAGE, USE OR DISPOSAL OF THE PRODUCT ARE BEYOND OUR CONTROL
AND MAY BE BEYOND OUR KNOWLEDGE. FOR THIS AND OTHER REASONS, WE DO NOT
ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR LOSS, DAMAGE OR
EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED WITH THE HANDLING, STORAGE,
USE OR DISPOSAL OF THE PRODUCT. THIS SDS WAS PREPARED AND IS TO BE USED
ONLY FOR THIS PRODUCT. IF THE PRODUCT IS USED AS A COMPONENT IN ANOTHER
PRODUCT, THIS SDS INFORMATION MAY NOT BE APPLICABLE.
ABBREVIATIONS AND ACRONYMS:
ADR:
ACCORD EUROPEEN SUR LE TRANSPORT DES MARCHANDISES DANGEREUSES PAR ROUTE
(EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS
GOODS BY ROAD)
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
GHS: GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
EINECS: EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES
ELINCS: EUROPEAN LIST OF NOTIFIED CHEMICAL SUBSTANCES
CAS: CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY)
DNEL: DERIVED NO-EFFECT LEVEL (REACH)
PNEC: PREDICTED NO-EFFECT CONCENTRATION (REACH)
LC50: LETHAL CONCENTRATION, 50 PERCENT
LD50: LETHAL DOSE, 50 PERCENT
ACUTE TOX. 4: ACUTE TOXICITY, HAZARD CATEGORY 4
SKIN IRRIT. 2: SKIN CORROSION/IRRITATION, HAZARD CATEGORY 2
EYE IRRIT. 2: SERIOUS EYE DAMAGE/EYE IRRITATION, HAZARD CATEGORY 2
EU
SANFACON INDUSTRIES
MATERIAL SAFETY DATA SHEET
JANUARY, 2008
TOWELETTE, PRE-MOISTENED, LEMON-SCENTED
| SECTION I: IDENTIFICATION | |
IDENTITY (AS USED ON LABEL AND LIST):
MOIST TOWELETTE WITH LEMON FRAGRANCE
INGREDIENTS:
98.8% WATER
1% LEMON FRAGRANCE
0.01% BZK (BENZALKONIUM)
0.01% SOAP
PHYSICAL DESCRIPTION:
A PRE-MOISTENED TOWELETTE MADE WITH VIRGIN PAPER,
INDIVIDUALLY PACKAGED IN A MOISTURE-PROOF POUCH.
MANUFACTURER'S NAME: SANFACON INDUSTRIES INC.
ADDRESS:
1980 5TH STREET
ST-ROMUALD, QUEBEC, CANADA
G6W 5M6
| SECTION II: HAZARDOUS INGREDIENTS | |
HAZARDOUS COMPONENTS: N/A
| SECTION III: PHYSICAL/CHEMICAL CHARACTERISTICS | |
BOILING POINT: N/A
SPECIFIC GRAVITY: +/- 1.0
VAPOUR PRESSURE: N/A
MELTING POINT: N/A
VAPOUR DENSITY: N/A
EVAPORATION RATE: N/A
SOLUBILITY IN WATER: COMPLETE
APPEARANCE AND COLOUR: CLEAR LIQUID WITH LEMON SCENT
| SECTION IV: FIRE AND EXPLOSION HAZARD DATA | |
FLASH POINT: N/A
FLAMMABLE LIMITS: N/A
EXTINGUISHING MEDIA: N/A
SPECIAL FIRE FIGHTING PROCEDURES: NONE
UNUSUAL FIRE & EXPLOSION HAZARDS: NONE
| SECTION V: HEALTH HAZARD DATA | |
ROUTES OF ENTRY:
INHALATION: N/A
SKIN: TOPICALLY APPLIED
INGESTION: N/A
HEALTH HAZARDS: N/A
CARCINOGENICITY: N/A
INFORMATION/EMERGENCY:
MONDAY THROUGH FRIDAY, 8 A.M. TO 5 P.M., (800) 463-5591 OR CONTACT THE
LOCAL POISON CONTROL CENTRE.
CAUTION:
IF ACCIDENTALLY SPLASHED IN EYES, RINSE THOROUGHLY WITH COLD WATER; MAY
CAUSE DISCOMFORT. NO NEED FOR FIRST AID IF SWALLOWED OR INHALED.
SIGNS AND SYMPTOMS OF EXPOSURE: SAFE AS A TOPICAL SKIN CLEANSER
DISCLAIMER:
SANFACON ACKNOWLEDGES HAT THE INFORMATION CONTAINED HEREIN IS ASSUMED
ACCURATE AND COMPLETE, AND ILLUSTRATES THE PRODUCT TO THE BEST OF THEIR
KNOWLEDGE. NO WARRANTY, EXPRESSED OR IMPLIED, IS MADE AND SANFACON ASSUMES
NO LEGAL RESPONSIBILITY OR LIABILITY RESULTING FROM ITS USE.
DISPENSING SOLUTIONS.(R*)
(R*)JAMES ALEXANDER CORPORATION
MEDICAINE(R*) STING AND BITE RELIEF
SAFETY DATA SHEET
ACCORDING TO THE FEDERAL FINAL RULE OF HAZARD COMMUNICATION REVISED ON 2012
(HAZCOM 2012)
DATE OF ISSUE: 06/02/2014
VERSION: 1.0
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE | |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
PRODUCT FORM: MIXTURE
TRADE NAME: MEDICAINE(R*) STING AND BITE RELIEF
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE OF THE SUBSTANCE/MIXTURE: OTC DRUG USED AS A TOPICAL ANALGESIC
USE OF THE SUBSTANCE/MIXTURE: FOR PROFESSIONAL USE ONLY
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
JAMES ALEXANDER CORPORATION
845 ROUTE 94 BLAIRSTOWN
NJ 07825
TEL: (908) 362-9266
NOTE:
THE CHEMTREC EMERGENCY NUMBER IS TO BE USED ONLY IN THE EVENT OF CHEMICAL
EMERGENCIES INVOLVING A SPILL, LEAK, FIRE, EXPOSURE, OR ACCIDENT INVOLVING
CHEMICALS. ALL NON-EMERGENCY QUESTIONS SHOULD BE DIRECTED TO JAC AT (908)
362-9266.
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER: CHEMTREC (800) 424-9300
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-US CLASSIFICATION:
FLAM. LIQ. 2 H225
EYE IRRIT. 2A H319
STOT SE 3 H335
STOT SE 3 H336
2.2. LABEL ELEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS02: FLAME
GHS07: EXCLAMATION MARK
SIGNAL WORD (GHS-US): DANGER
HAZARD STATEMENTS (GHS-US):
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR
H319: CAUSES SERIOUS EYE IRRITATION
H335: MAY CAUSE RESPIRATORY IRRITATION
H336: MAY CAUSE DROWSINESS OR DIZZINESS
PRECAUTIONARY STATEMENTS (GHS-US):
P210: KEEP AWAY FROM HEAT, HOT SURFACES, OPEN FLAMES, SPARKS. - NO SMOKING
P233: KEEP CONTAINER TIGHTLY CLOSED
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT
P241: USE EXPLOSION-PROOF ELECTRICAL, LIGHTING, VENTILATING EQUIPMENT
P242: USE ONLY NON-SPARKING TOOLS
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE
P261: AVOID BREATHING DUST, FUME, MIST, SPRAY, VAPOURS
P264: WASH HANDS THOROUGHLY AFTER HANDLING
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA
P280: WEAR EYE PROTECTION, PROTECTIVE CLOTHING, PROTECTIVE GLOVES
P303+P361+P353:
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER
P304+P340:
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
P312: CALL A POISON CENTER/DOCTOR/PHYSICIAN IF YOU FEEL UNWELL
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION
P370+P378:
IN CASE OF FIRE: USE DRY CHEMICAL, FOAM, CARBON DIOXIDE FOR EXTINCTION
P403+P233: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED
P403+P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL
P405: STORE LOCKED UP
P501:
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH APPLICABLE LOCAL, NATIONAL AND
INTERNATIONAL REGULATION.
2.3. OTHER HAZARDS: NO ADDITIONAL INFORMATION AVAILABLE
2.4. UNKNOWN ACUTE TOXICITY (GHS-US): NO DATA AVAILABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCE: NOT APPLICABLE
FULL TEXT OF H-PHRASES: SEE SECTION 16
3.2. MIXTURE:
NAME PRODUCT IDENTIFIER % GHS-US CLASSIFICATION
POLYETHYLENE GLYCOL (CAS NO) 25322-68-3 50 - 55 STOT SE 3, H335
ISOPROPYL ALCOHOL (CAS NO) 67-63-0 20 - 25 FLAM. LIQ. 2, H225
EYE IRRIT. 2A, H319
STOT SE 3, H336
L-MENTHOL (CAS NO) 2216-51-5 1 SKIN IRRIT. 2, H315
EYE IRRIT. 2A, H319
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF YOU FEEL UNWELL,
SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
FIRST-AID MEASURES AFTER INHALATION:
REMOVE TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF BREATHING STOPS, GIVE ARTIFICIAL RESPIRATION. IN CASE OF
BREATHING DIFFICULTIES ADMINISTER OXYGEN. BY TRAINED PERSONNEL. SEEK
MEDICAL ATTENTION IMMEDIATELY.
FIRST-AID MEASURES AFTER SKIN CONTACT:
IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. DO NOT RUB THE SKIN
AND EYES AFTER DIRECT CONTACT WITH THE PRODUCT. SEEK MEDICAL ATTENTION
IMMEDIATELY. WASH CONTAMINATED CLOTHING BEFORE REUSE.
FIRST-AID MEASURES AFTER EYE CONTACT:
IN CASE OF CONTACT WITH EYES FLUSH IMMEDIATELY WITH PLENTY OF FLOWING WATER
FOR 10 TO 15 MINUTES HOLDING EYELIDS APART AND CONSULT AN OPHTHALMOLOGIST.
REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IMMEDIATELY GET MEDICAL ATTENTION.
FIRST-AID MEASURES AFTER INGESTION:
CONTACT A POISON CONTROL CENTER IMMEDIATELY. GIVE NO MORE THAN 2 GLASSES OF
WATER AND INDUCE VOMITING BY GIVING 30 CC (2 TABLESPOONS) OF SYRUP OF
IPECAC. IF VICTIM IS A CHILD, GIVE NO MORE THAN 1 GLASS OF WATER AND 15CC
(1 TABLESPOON) SYRUP OF IPECAC. IF SYRUP OF IPECAC IS UNAVAILABLE, GIVE 2
GLASSES OF WATER AND INDUCE VOMITING BY TOUCHING FINGER TO BACK OF VICTIM'S
THROAT. DO NOT GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSING
PERSON. GET IMMEDIATE MEDICAL ATTENTION. IMMEDIATELY CALL A POISON CENTER
OR DOCTOR/PHYSICIAN.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS/INJURIES AFTER INHALATION:
MAY CAUSE RESPIRATORY IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS.
DEPRESSION OF THE CENTRAL NERVOUS SYSTEM, HEADACHES, DIZZINESS, DROWSINESS,
LOSS OF COORDINATION.
SYMPTOMS/INJURIES AFTER SKIN CONTACT:
REPEATED OR PROLONGED SKIN CONTACT MAY CAUSE IRRITATION.
SYMPTOMS/INJURIES AFTER EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
SYMPTOMS/INJURIES AFTER INGESTION:
IRRITATING TO THE GASTROINTESTINAL TRACT. MAY CAUSE ABDOMINAL PAIN AND
VOMITING (SOMETIMES BLOODY). INGESTION MAY CAUSE CENTRAL NERVOUS SYSTEM
DEPRESSION, LOW BLOOD PRESSURE, RAPID HEART BEAT AND LIVER DAMAGEEARLY TO
MODERATE CENTRAL NERVOUS SYSTEM DEPRESSION MAY BE EVIDENCED BY GIDDINESS,
HEADACHE, DIZZINESS AND NAUSEA. IN EXTREME CASES, UNCONSCIOUSNESS,
RESPIRATORY DEPRESSION AND DEATH MAY OCCUR. LIVER DAMAGE MAY BE EVIDENCED
BY LOSS OF APPETITE, JAUNDICE (YELLOWISH SKIN COLOR) AND SOMETIMES PAIN IN
THE UPPER ABDOMEN ON THE RIGHT SIDE.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
INDIVIDUALS WITH PRE-EXISTING SKIN DISORDERS, EYE PROBLEMS, OR IMPAIRED
RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF
OVEREXPOSURE.
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
ALCOHOL RESISTANT FOAM. DRY POWDER. CARBON DIOXIDE. SAND.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE A HEAVY WATER STREAM.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
FIRE HAZARD: HIGHLY FLAMMABLE LIQUID AND VAPOUR.
EXPLOSION HAZARD: MAY FORM FLAMMABLE/EXPLOSIVE VAPOUR-AIR MIXTURE.
REACTIVITY:
THERMAL DECOMPOSITION GENERATES: CORROSIVE VAPOURS. REACTS VIOLENTLY WITH
ACIDS. AN EXOTHERMIC REACTION MAY OCCUR.
5.3. ADVICE FOR FIREFIGHTERS:
FIREFIGHTING INSTRUCTIONS:
USE WATER SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS. EXERCISE CAUTION
WHEN FIGHTING ANY CHEMICAL FIRE. PREVENT FIRE-FIGHTING WATER FROM ENTERING
ENVIRONMENT.
PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
OTHER INFORMATION:
CONTAINERS MAY SWELL AND BURST DURING A FIRE DUE TO INTERNAL PRESSURE
CAUSED BY HEAT. VAPOURS ARE HEAVIER THAN AIR AND MAY TRAVEL CONSIDERABLE
DISTANCE TO AN IGNITION SOURCE AND FLASH BACK TO SOURCE OF VAPOURS.
ALCOHOLS BURN WITH A PALE BLUE FLAME WHICH MAY BE EXTREMELY HARD TO SEE
UNDER NORMAL LIGHTING CONDITIONS. PERSONNEL MAY BE ABLE TO FEEL THE HEAT OF
THE FIRE WITHOUT SEEING FLAMES. EXTREME CAUTION MUST BE EXERCISED IN
FIGHTING ALCOHOL FIRES.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
ELIMINATE ALL IGNITION SOURCES IF SAFE TO DO SO. USE SPECIAL CARE TO AVOID
STATIC ELECTRIC CHARGES. NO NAKED LIGHTS. NO SMOKING. STOP LEAK IF SAFE TO
DO SO. NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT
SUITABLE TRAINING. WEAR PROTECTIVE CLOTHING. FOR FURTHER INFORMATION REFER
TO SECTION 8: EXPOSURE-CONTROLS/PERSONAL PROTECTION.
6.1.1. FOR NON-EMERGENCY PERSONNEL:
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT: EQUIP CLEANUP CREW WITH PROPER PROTECTION.
EMERGENCY PROCEDURES: VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY TO SEWERS AND PUBLIC WATERS. NOTIFY AUTHORITIES IF LIQUID
ENTERS SEWERS OR PUBLIC WATERS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CLEANING UP:
SOAK UP SPILLS WITH INERT SOLIDS, SUCH AS CLAY OR DIATOMACEOUS EARTH AS
SOON AS POSSIBLE. COLLECT SPILLAGE. STORE AWAY FROM OTHER MATERIALS.
CONTAIN ANY SPILLS WITH DIKES OR ABSORBENTS TO PREVENT MIGRATION AND ENTRY
INTO SEWERS OR STREAMS. CONSULT THE APPROPRIATE AUTHORITIES ABOUT WASTE
DISPOSAL. ENSURE ALL NATIONAL/LOCAL REGULATIONS ARE OBSERVED.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
ADDITIONAL HAZARDS WHEN PROCESSED:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPOURS ARE FLAMMABLE.
PRECAUTIONS FOR SAFE HANDLING:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. PERSONAL PROTECTIVE EQUIPMENT
SHOULD BE SELECTED BASED UPON THE CONDITIONS UNDER WHICH THIS PRODUCT IS
HANDLED OR USED. USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED. PROVIDE
GOOD VENTILATION IN PROCESS AREA TO PREVENT FORMATION OF VAPOUR. DO NOT
BREATHE GAS, FUMES, VAPOUR OR SPRAY. NO NAKED LIGHTS. NO SMOKING. USE ONLY
NON-SPARKING TOOLS. NEVER USE PRESSURE TO EMPTY CONTAINER. GROUND/BOND
CONTAINER AND RECEIVING EQUIPMENT. TAKE CARE TO ALLOW INTERNAL PRESSURE TO
ESCAPE FROM CONTAINER BEFORE RELEASING CLOSURES. REMOVE CLOSURE CAREFULLY;
INTERNAL PRESSURE MAY BE PRESENT. KEEP CLOSURE UP TO PREVENT LEAKAGE. WASH
HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK.
HYGIENE MEASURES:
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK. WASH CONTAMINATED CLOTHING
BEFORE REUSE. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES:
USE EXPLOSION-PROOF MACHINERY, APPARATUS, VENTILATION FACILITIES, TOOLS
ETC. ENSURE THE VENTILATION SYSTEM IS REGULARLY MAINTAINED AND TESTED.
PROVIDE EXHAUST VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP THE
AIRBORNE CONCENTRATIONS OF MISTS AND/OR VAPORS BELOW THE RECOMMENDED
EXPOSURE LIMITS. PROPER GROUNDING PROCEDURES TO AVOID STATIC ELECTRICITY
SHOULD BE FOLLOWED. GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT. A
WASHING FACILITY/WATER FOR EYE AND SKIN CLEANING PURPOSES SHOULD BE
PRESENT. COMPLY WITH APPLICABLE REGULATIONS.
STORAGE CONDITIONS:
KEEP ONLY IN THE ORIGINAL CONTAINER IN A COOL WELL VENTILATED PLACE. KEEP
IN FIREPROOF PLACE. KEEP CONTAINER TIGHTLY CLOSED. PROTECT CONTAINERS
AGAINST PHYSICAL DAMAGE. DETACHED OUTSIDE STORAGE IS PREFERABLE. INSIDE
STORAGE SHOULD BE IN AN NFPA APPROVED FLAMMABLE LIQUIDS STORAGE ROOM OR
CABINET. STORE IN CORROSION-PROOF AREA AT TEMPERATURES BELOW 77 DEG. F (25
DEG. C). STORE AWAY FROM DIRECT SUNLIGHT OR OTHER HEAT SOURCES.
INCOMPATIBLE MATERIALS:
AVOID MIXING WITH ACIDS, MOST COMMON METALS, STRONG OXIDIZING AGENTS,
BRASS, ZINC, CHLORINE, ALUMINUM, COPPER, BRONZE, MERCURY, DIMETHYL SULFATE
AND ACETYL CHLORIDE.
STORAGE TEMPERATURE:
<25 DEG. C STORE AT TEMPERATURES BELOW 77 DEG. F (25 DEG. C)
7.3. SPECIFIC END USE(S): NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
ISOPROPYL ALCOHOL (67-63-0):
USA ACGIH:
ACGIH TWA (PPM): 200 PPM
USA ACGIH:
ACGIH STEL (PPM): 400 PPM
USA OSHA:
OSHA PEL (TWA) (MG/M3): 980 MG/M3
USA OSHA:
OSHA PEL (TWA) (PPM): 400 PPM
8.2. EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS AND SAFETY SHOWERS SHOULD BE AVAILABLE IN THE
IMMEDIATE VICINITY OF ANY POTENTIAL EXPOSURE. PROVIDE EXHAUST VENTILATION
OR OTHER ENGINEERING CONTROLS TO KEEP THE AIRBORNE CONCENTRATIONS OF MISTS
AND/OR VAPORS BELOW THE RECOMMENDED EXPOSURE LIMITS. USE EXPLOSION-PROOF
VENTILATING EQUIPMENT.
PERSONAL PROTECTIVE EQUIPMENT:
AVOID ALL UNNECESSARY EXPOSURE. A HAZARD ASSESSMENT OF THE WORK AREA FOR
PPE REQUIREMENTS SHOULD BE CONDUCTED BY A QUALIFIED PROFESSIONAL PURSUANT
TO OSHA REGULATIONS. FOR CERTAIN OPERATIONS, ADDITIONAL PERSONAL PROTECTION
EQUIPMENT (PPE) MAY BE REQUIRED. PROTECTIVE GOGGLES. GLOVES. PROTECTIVE
CLOTHING.
HAND PROTECTION:
WEAR PROTECTIVE GLOVES. RUBBER GLOVES. FOR SPECIAL PURPOSES, IT IS
RECOMMENDED TO CHECK THE RESISTANCE TO CHEMICALS OF THE PROTECTIVE
GLOVES MENTIONED ABOVE TOGETHER WITH THE SUPPLIER OF THESE GLOVES.
EYE PROTECTION: CHEMICAL GOGGLES OR FACE SHIELD.
SKIN AND BODY PROTECTION:
WEAR SUITABLE PROTECTIVE CLOTHING. CHEMICAL RESISTANT SAFETY SHOES.
RESPIRATORY PROTECTION:
WEAR A SELF-CONTAINED BREATHING APPARATUS AND APPROPRIATE PERSONAL
PROTECTIVE EQUIPMENT (PPE). SUGGESTIONS PROVIDED IN THIS SECTION FOR
EXPOSURE CONTROL AND SPECIFIC TYPES OF PROTECTIVE EQUIPMENT ARE BASED ON
READILY AVAILABLE INFORMATION. USERS SHOULD CONSULT WITH THE SPECIFIC
MANUFACTURER TO CONFIRM THE PERFORMANCE OF THEIR PROTECTIVE EQUIPMENT.
SPECIFIC SITUATIONS MAY REQUIRE CONSULTATION WITH INDUSTRIAL HYGIENE,
SAFETY, OR ENGINEERING PROFESSIONALS. CARE MUST BE TAKEN TO ASSURE THAT ANY
RESPIRATOR CHOSEN IS CAPABLE OF PROTECTING THE USER FROM BOTH AMMONIA AND
ETHYL ALCOHOL VAPORS.
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE DURING USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: CLEAR.
COLOUR: GREEN.
ODOUR: ODOR OF ISOPROPYL ALCOHOL, RESIDUAL ODOR OF MENTHOL.
ODOUR THRESHOLD: NO DATA AVAILABLE
PH: 8.5
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: >35 DEG. C (>95 DEG. F)
FLASH POINT: 16.6 DEG. C (62 DEG. F)
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
VAPOUR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOUR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
DENSITY: 1.029 (SPECIFIC GRAVITY @ 25 DEG. C)
SOLUBILITY: SOLUBLE IN WATER.
LOG POW: NO DATA AVAILABLE
LOG KOW: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
EXPLOSIVE LIMITS: NO DATA AVAILABLE
9.2. OTHER INFORMATION: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THERMAL DECOMPOSITION GENERATES:
CORROSIVE VAPOURS. REACTS VIOLENTLY WITH ACIDS. AN EXOTHERMIC REACTION MAY
OCCUR.
10.2. CHEMICAL STABILITY: NOT ESTABLISHED.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NOT ESTABLISHED.
10.4. CONDITIONS TO AVOID:
DIRECT SUNLIGHT. EXTREMELY HIGH OR LOW TEMPERATURES. OPEN FLAME.
10.5. INCOMPATIBLE MATERIALS:
AVOID MIXING WITH ACIDS, MOST COMMON METALS, STRONG OXIDIZING AGENTS,
BRASS, ZINC, CHLORINE, ALUMINUM, COPPER, BRONZE, MERCURY, DIMETHYL SULFATE
AND ACETYL CHLORIDE.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
THERMAL DECOMPOSITION GENERATES:
FUME. CARBON MONOXIDE. CARBON DIOXIDE. MAY RELEASE FLAMMABLE GASES.
CORROSIVE VAPOURS. AMMONIA. NITROGEN OXIDES. RELEASE OF HIGHLY FLAMMABLE
GASES/VAPOURS HYDROGEN.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NOT CLASSIFIED
(BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET)
ISOPROPYL ALCOHOL (67-63-0):
LD50 ORAL RAT: 4396 MG/KG
LD50 DERMAL RABBIT: 12800 MG/KG
LC50 INHALATION RAT (PPM): 16000 PPM (EXPOSURE TIME: 8 H)
ATE CLP (ORAL): 4396.000 MG/KG BODYWEIGHT
ATE CLP (DERMAL): 12800.000 MG/KG BODYWEIGHT
L-MENTHOL (2216-51-5):
LD50 ORAL RAT: 3300 MG/KG
ATE CLP (ORAL): 3300.000 MG/KG BODYWEIGHT
POLYETHYLENE GLYCOL (25322-68-3):
LD50 DERMAL RABBIT: >20 ML/KG
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
(BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET)
PH: 8.5
SERIOUS EYE DAMAGE/IRRITATION: CAUSES SERIOUS EYE IRRITATION.
PH: 8.5
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
(BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET)
GERM CELL MUTAGENICITY: NOT CLASSIFIED
(BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET)
CARCINOGENICITY: NOT CLASSIFIED
(BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET)
ISOPROPYL ALCOHOL (67-63-0):
IARC GROUP: 3 - NOT CLASSIFIABLE
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
(BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET)
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
MAY CAUSE RESPIRATORY IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT CLASSIFIED
(BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET)
ASPIRATION HAZARD: NOT CLASSIFIED
(BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET)
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
SYMPTOMS/INJURIES AFTER INHALATION:
MAY CAUSE RESPIRATORY IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS.
DEPRESSION OF THE CENTRAL NERVOUS SYSTEM, HEADACHES, DIZZINESS, DROWSINESS,
LOSS OF COORDINATION.
SYMPTOMS/INJURIES AFTER SKIN CONTACT:
REPEATED OR PROLONGED SKIN CONTACT MAY CAUSE IRRITATION.
SYMPTOMS/INJURIES AFTER EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
SYMPTOMS/INJURIES AFTER INGESTION:
IRRITATING TO THE GASTROINTESTINAL TRACT. MAY CAUSE ABDOMINAL PAIN AND
VOMITING (SOMETIMES BLOODY). INGESTION MAY CAUSE CENTRAL NERVOUS SYSTEM
DEPRESSION, LOW BLOOD PRESSURE, RAPID HEART BEAT AND LIVER DAMAGEEARLY TO
MODERATE CENTRAL NERVOUS SYSTEM DEPRESSION MAY BE EVIDENCED BY GIDDINESS,
HEADACHE, DIZZINESS AND NAUSEA. IN EXTREME CASES, UNCONSCIOUSNESS,
RESPIRATORY DEPRESSION AND DEATH MAY OCCUR. LIVER DAMAGE MAY BE EVIDENCED
BY LOSS OF APPETITE, JAUNDICE (YELLOWISH SKIN COLOR) AND SOMETIMES PAIN IN
THE UPPER ABDOMEN ON THE RIGHT SIDE.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ISOPROPYL ALCOHOL (67-63-0):
LC50 FISHES 1:
9640 MG/L (EXPOSURE TIME: 96 H - SPECIES: PIMEPHALES PROMELAS
[FLOW-THROUGH])
EC50 DAPHNIA 1:
13299 MG/L (EXPOSURE TIME: 48 H - SPECIES: DAPHNIA MAGNA)
LC50 FISH 2:
11130 MG/L (EXPOSURE TIME: 96 H - SPECIES: PIMEPHALES PROMELAS [STATIC])
L-MENTHOL (2216-51-5):
LC50 FISHES 1:
18.9 MG/L (EXPOSURE TIME: 96 H - SPECIES: PIMEPHALES PROMELAS
[FLOW-THROUGH])
12.2. PERSISTENCE AND DEGRADABILITY:
MEDICAINE(R*) STING AND BITE RELIEF:
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
12.3. BIOACCUMULATIVE POTENTIAL:
MEDICAINE(R*) STING AND BITE RELIEF:
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
ISOPROPYL ALCOHOL (67-63-0):
LOG POW: 0.05 (AT 25 DEG. C)
12.4. MOBILITY IN SOIL: NO ADDITIONAL INFORMATION AVAILABLE
12.5. OTHER ADVERSE EFFECTS:
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
DO NOT RE-USE EMPTY CONTAINERS. ENSURE ALL NATIONAL/LOCAL REGULATIONS ARE
OBSERVED. CONSULT THE APPROPRIATE AUTHORITIES ABOUT WASTE DISPOSAL.
ADDITIONAL INFORMATION:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPOURS ARE FLAMMABLE.
ECOLOGY - WASTE MATERIALS: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 14: TRANSPORT INFORMATION | |
IN ACCORDANCE WITH DOT:
TRANSPORT DOCUMENT DESCRIPTION:
UN1993 FLAMMABLE LIQUIDS, N.O.S. (CONTAINS ISOPROPANOL), 3, II
UN-NO.(DOT): 1993
DOT NA NO.: UN1993
DOT PROPER SHIPPING NAME: FLAMMABLE LIQUIDS, N.O.S. (CONTAINS ISOPROPANOL)
DEPARTMENT OF TRANSPORTATION (DOT) HAZARD CLASSES:
3 - CLASS 3 - FLAMMABLE AND COMBUSTIBLE LIQUID 49 CFR 173.120
HAZARD LABELS (DOT): 3 - FLAMMABLE LIQUID
DOT SYMBOLS: G - IDENTIFIES PSN REQUIRING A TECHNICAL NAME
PACKING GROUP (DOT): II - MEDIUM DANGER
DOT SPECIAL PROVISIONS (49 CFR 172.102):
IB2 - AUTHORIZED IBCS:
METAL (31A, 31B AND 31N); RIGID PLASTICS (31H1 AND 31H2); COMPOSITE
(31HZ1).
ADDITIONAL REQUIREMENT:
ONLY LIQUIDS WITH A VAPOR PRESSURE LESS THAN OR EQUAL TO 110 KPA AT 50 C
(1.1 BAR AT 122 F), OR 130 KPA AT 55 C (1.3 BAR AT 131 F) ARE AUTHORIZED.
T7 - 4 178.274(D)(2) NORMAL............. 178.275(D)(3)
TP1 - THE MAXIMUM DEGREE OF FILLING MUST NOT EXCEED THE DEGREE OF FILLING
DETERMINED BY THE FOLLOWING: DEGREE OF FILLING = 97 / (1 + A (TR - TF))
WHERE: TR IS THE MAXIMUM MEAN BULK TEMPERATURE DURING TRANSPORT, AND TF IS
THE TEMPERATURE IN DEGREES CELSIUS OF THE LIQUID DURING FILLING.
TP8 - A PORTABLE TANK HAVING A MINIMUM TEST PRESSURE OF 1.5 BAR (150 KPA)
MAY BE USED WHEN THE FLASH POINT OF THE HAZARDOUS MATERIAL TRANSPORTED IS
GREATER THAN 0 C (32 F).
TP28 - A PORTABLE TANK HAVING A MINIMUM TEST PRESSURE OF 2.65 BAR (265 KPA)
MAY BE USED PROVIDED THE CALCULATED TEST PRESSURE IS 2.65 BAR OR LESS BASED
ON THE MAWP OF THE HAZARDOUS MATERIAL, AS DEFINED IN 178.275 OF THIS
SUBCHAPTER, WHERE THE TEST PRESSURE IS 1.5 TIMES THE MAWP.
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 150
DOT PACKAGING NON BULK (49 CFR 173.XXX): 202
DOT PACKAGING BULK (49 CFR 173.XXX): 242
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 173.27): 5 L
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 175.75): 60 L
DOT VESSEL STOWAGE LOCATION:
B - (I) THE MATERIAL MAY BE STOWED "ON DECK" OR "UNDER DECK" ON A CARGO
VESSEL AND ON A PASSENGER VESSEL CARRYING A NUMBER OF PASSENGERS LIMITED TO
NOT MORE THAN THE LARGER OF 25 PASSENGERS, OR ONE PASSENGER PER EACH 3 M OF
OVERALL VESSEL LENGTH; AND (II) "ON DECK ONLY" ON PASSENGER VESSELS IN
WHICH THE NUMBER OF PASSENGERS SPECIFIED IN PARAGRAPH (K)(2)(I) OF THIS
SECTION IS EXCEEDED.
ADDITIONAL INFORMATION:
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
ADR: TRANSPORT DOCUMENT DESCRIPTION
TRANSPORT BY SEA: NO ADDITIONAL INFORMATION AVAILABLE
AIR TRANSPORT: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
ISOPROPYL ALCOHOL (67-63-0):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
LISTED ON SARA SECTION 313 (SPECIFIC TOXIC CHEMICAL LISTINGS)
EPA TSCA REGULATORY FLAG:
T - T - INDICATES A SUBSTANCE THAT IS THE SUBJECT OF A SECTION 4 TEST RULE
UNDER TSCA.
SARA SECTION 313 - EMISSION REPORTING:
1.0% (ONLY IF MANUFACTURED BY THE STRONG ACID PROCESS, NO SUPPLIER
NOTIFICATION)
L-MENTHOL (2216-51-5):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
POLYETHYLENE GLYCOL (25322-68-3):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
15.2. INTERNATIONAL REGULATIONS:
CANADA:
ISOPROPYL ALCOHOL (67-63-0):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
WHMIS CLASSIFICATION:
CLASS B DIVISION 2 - FLAMMABLE LIQUID
CLASS D DIVISION 2 SUBDIVISION B - TOXIC MATERIAL CAUSING OTHER TOXIC
EFFECTS
L-MENTHOL (2216-51-5):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
POLYETHYLENE GLYCOL (25322-68-3):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
EU-REGULATIONS:
ISOPROPYL ALCOHOL (67-63-0):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES) SUBSTANCES.
L-MENTHOL (2216-51-5):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES) SUBSTANCES.
POLYETHYLENE GLYCOL (25322-68-3):
LISTED ON THE EU - NO-LONGER POLYMERS LIST (67/548/EEC)
CLASSIFICATION ACCORDING TO REGULATION (EC) NO. 1272/2008 [CLP]:
NOT CLASSIFIED
CLASSIFICATION ACCORDING TO DIRECTIVE 67/548/EEC OR 1999/45/EC:
NOT CLASSIFIED
15.2.2. NATIONAL REGULATIONS:
ISOPROPYL ALCOHOL (67-63-0):
LISTED ON THE AICS (THE AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES)
LISTED ON INVENTORY OF EXISTING CHEMICAL SUBSTANCES (IECSC)
LISTED ON THE JAPANESE ENCS (EXISTING & NEW CHEMICALS SUBSTANCES)
INVENTORY.
LISTED ON INDUSTRIAL SAFETY AND HEALTH LAW SUBSTANCES (ISHL)
LISTED ON THE KOREAN ECL (EXISTING CHEMICAL LIST) INVENTORY.
LISTED ON NEW ZEALAND - INVENTORY OF CHEMICALS (NZIOC)
LISTED ON INVENTORY OF CHEMICALS AND CHEMICAL SUBSTANCES (PICCS)
LISTED ON THE CANADIAN INGREDIENT DISCLOSURE LIST
L-MENTHOL (2216-51-5):
LISTED ON THE AICS (THE AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES)
LISTED ON INVENTORY OF EXISTING CHEMICAL SUBSTANCES (IECSC)
LISTED ON THE JAPANESE ENCS (EXISTING & NEW CHEMICALS SUBSTANCES)
INVENTORY.
LISTED ON INDUSTRIAL SAFETY AND HEALTH LAW SUBSTANCES (ISHL)
LISTED ON THE KOREAN ECL (EXISTING CHEMICAL LIST) INVENTORY.
LISTED ON NEW ZEALAND - INVENTORY OF CHEMICALS (NZIOC)
LISTED ON INVENTORY OF CHEMICALS AND CHEMICAL SUBSTANCES (PICCS)
POLYETHYLENE GLYCOL (25322-68-3):
LISTED ON THE AICS (THE AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES)
LISTED ON INVENTORY OF EXISTING CHEMICAL SUBSTANCES (IECSC)
LISTED ON THE JAPANESE ENCS (EXISTING & NEW CHEMICALS SUBSTANCES)
INVENTORY.
LISTED ON THE KOREAN ECL (EXISTING CHEMICAL LIST) INVENTORY.
LISTED ON NEW ZEALAND - INVENTORY OF CHEMICALS (NZIOC)
LISTED ON INVENTORY OF CHEMICALS AND CHEMICAL SUBSTANCES (PICCS)
15.3. US STATE REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 16: OTHER INFORMATION | |
OTHER INFORMATION: NONE.
FULL TEXT OF H-PHRASES: SEE SECTION 16
EYE IRRIT. 2A: SERIOUS EYE DAMAGE/EYE IRRITATION, CATEGORY 2A
FLAM. LIQ. 2: FLAMMABLE LIQUIDS CATEGORY 2
SKIN IRRIT. 2: SKIN CORROSION/IRRITATION CATEGORY 2
STOT SE 3: SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CATEGORY 3
STOT SE 3: SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CATEGORY 3
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR
H315: CAUSES SKIN IRRITATION
H319: CAUSES SERIOUS EYE IRRITATION
H335: MAY CAUSE RESPIRATORY IRRITATION
H336: MAY CAUSE DROWSINESS OR DIZZINESS
NFPA HEALTH HAZARD 2 - INTENSE OR CONTINUED EXPOSURE COULD CAUSE TEMPORARY
INCAPACITATION OR POSSIBLE RESIDUAL INJURY UNLESS
PROMPT MEDICAL ATTENTION IS GIVEN.
NFPA FIRE HAZARD 3 - LIQUIDS AND SOLIDS THAT CAN BE IGNITED UNDER ALMOST
ALL AMBIENT CONDITIONS.
NFPA REACTIVITY 0 - NORMALLY STABLE, EVEN UNDER FIRE EXPOSURE
CONDITIONS, AND ARE NOT REACTIVE WITH WATER.
SDS US (GHS HAZCOM 2012)
THIS MATERIAL SAFETY DATA SHEET IS INTENDED ONLY AS A GUIDE TO THE
APPROPRIATE PRECAUTIONARY HANDLING OF THE MATERIAL BY A PERSON TRAINED IN,
OR SUPERVISED BY A PERSON TRAINED IN, THE SAFE HANDLING OF CHEMICAL
MATERIALS. JAMES ALEXANDER CORPORATION (JAC), EXPRESSLY DISCLAIMS ALL
EXPRESS OR IMPLIED WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A
PARTICULAR PURPOSE WITH RESPECT TO THE PRODUCT OR INFORMATION PROVIDED
HEREIN. ALL INFORMATION APPEARING HEREIN IS BASED UPON DATA OBTAINED FROM
THE MANUFACTURER(S) AND/OR RECOGNIZED TECHNICAL SOURCES. WHILE THE
INFORMATION IS BELIEVED TO BE ACCURATE, JAC MAKES NO REPRESENTATIONS AS TO
ITS ACCURACY OR SUFFICIENCY. CONDITIONS OF USE ARE BEYOND JAC'S CONTROL AND
THEREFORE, USERS ARE RESPONSIBLE TO VERIFY THIS DATA UNDER THEIR OWN
OPERATING CONDITIONS TO DETERMINE WHETHER THE PRODUCT IS SUITABLE FOR THEIR
PARTICULAR PURPOSES AND THEY ASSUME ALL RISKS OF THEIR USE, HANDLING, AND
DISPOSAL OF THE PRODUCT, OR FROM THE PUBLICATION OR USE OF, OR RELIANCE
UPON, INFORMATION CONTAINED HEREIN. THIS INFORMATION RELATES ONLY TO THE
PRODUCT DESIGNATED HEREIN AND DOES NOT RELATE TO ITS USE IN COMBINATION
WITH ANY OTHER MATERIAL OR IN ANY OTHER PROCESS.
06/06/2014
EN (ENGLISH)
ORION(R*)
THE BRIGHTEST NAME IN SAFETY
SAFETY DATA SHEET
| 1. PRODUCT AND COMPANY IDENTIFICATION | |
IDENTIFICATION: RED EMERGENCY FLARE - NO PERCHLORATE (NPC) FORMULATION
SYNONYMS:
EMERGENCY ROAD FLARE
RAILWAY FLARE
NSN#: 1370-01-009-2593
THE NPC FLARE WILL HAVE THE FOLLOWING SYMBOL ON IT:
IMPROVED ECO-FRIENDLY FORMULA
IDENTIFIED USE: EMERGENCY SIGNAL
USE ADVISED AGAINST: DO NOT USE INDOORS OR INSIDE A VEHICLE
MANUFACTURERS INFORMATION:
ORION SAFETY PRODUCTS
28320 ST. MICHAELS RD
EASTON, MD 21601
800-637-7807
410-822-0318
EMERGENCY CHEMTREC: 1-800-424-9300
| 2. HAZARDS IDENTIFICATION | |
GHS CLASSIFICATIONS:
SKIN IRRITATION: CATEGORY 2
H315
EYE IRRITATION: CATEGORY 2A
H319
STOT - SINGLE EXPOSURE: CATEGORY 3
H335
GHS LABEL ELEMENTS:
PICTOGRAMS: EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD STATEMENTS
H315 /319: CAUSES SKIN AND SERIOUS EYE IRRITATION
H335 MAY: CAUSE RESPIRATORY IRRITATION
PRECAUTIONARY STATEMENTS:
P103: KEEP OUT OF REACH OF CHILDREN
P261: AVOID BREATHING DUST/SMOKE.
P264: WASH HANDS THOROUGHLY AFTER HANDLING.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P280: WEAR PROTECTIVE EYE PROTECTION
P370:
IN CASE OF FIRE: USE WATER DELUGE
P501:
DISPOSE OF CONTENTS / CONTAINER IN ACCORDANCE WITH LOCAL AND NATIONAL
REGULATIONS.
P301/315:
IF SWALLOWED: GET IMMEDIATE MEDICAL ADVICE /ATTENTION.
P302/352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P304/340/342:
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING IF EXPERIENCING RESPIRATORY SYMPTOMS: CALL A POISON CENTER OR
DOCTOR / PHYSICIAN.
P305/338/351:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P333/313:
IF SKIN IRRITATION OR RASH OCCURS, GET MEDICAL ADVICE / ATTENTION.
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): PRODUCES HOT FLAME
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
COMPONENT CAS # EINCS # %AGE
STRONTIUM NITRATE 10042-76-9 233-131-9 <75%
SULFUR 7704-34-9 231-722-6 <25%
POTASSIUM NITRATE 7757-79-1 231-818-8 <25%
PARAFFINIC OIL 64742-54-7 232-384-2 <10%
POTASSIUM CHLORATE 3811-04-9 231-100-4 <5%
WAXY SAWDUST MIXTURE NONE <5%
POLYVINYL CHLORIDE 9002-86-2 200-831-0 <5%
SHELLAC MIXTURE NONE <1%
CHARCOAL 1333-86-4 231-153-3 <1%
NOTE:
DUE TO CONFIDENTIAL BUSINESS INFORMATION I. E "TRADE SECRETS", THE EXACT
PERCENTAGE OF EACH INGREDIENT HAS NOT BEEN DISCLOSED. CBI INFORMATION WILL
BE SHARED WITH APPROPRIATE AUTHORITIES IF CIRCUMSTANCES WARRANT.
| 4. FIRST AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
IF CONTENTS ARE INHALED, REMOVE TO FRESH AIR. WATCH FOR SIGNS OF ALLERGIC
REACTION. IF OTHER SYMPTOMS DEVELOP, GET MEDICAL AID IMMEDIATELY.
SKIN:
IF CONTENTS ARE CONTACTED, WASH WITH AREA WITH SOAP AND WATER FOR 15
MINUTES. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. GET MEDICAL
AID IMMEDIATELY IF BURNED OR IRRITATION OCCURS.
EYES:
IF CONTENTS GET INTO EYE, FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES, OCCASIONALLY LIFTING THE UPPER AND LOWER LIDS. REMOVE CONTACT
LENSES IF EASILY POSSIBLE. DO NOT USE BORIC ACID TO RINSE WITH; SULFUR IS
AN ACID IRRITANT. GET MEDICAL AID IMMEDIATELY.
INGESTION: GET MEDICAL AID IMMEDIATELY.
MOST IMPORTANT SYMPTOMS AND EFFECTS BOTH ACUTE AND DELAYED:
SEE SECTION 2 LABELING AND SECTION 11
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
BURNING FLARE CAN CAUSE SEVERE BURNS IF IN CONTACT WITH BODY. FOR BURNS TO
SKIN, COOL WITH WATER AND BANDAGE APPROPRIATELY. SEEK MEDICAL ATTENTION. IF
EYE IS BURNED, COVER EYE AND GET MEDICAL AID IMMEDIATELY
| 5. FIREFIGHTING MEASURES | |
EXTINGUISHING MEDIA: WATER DELUGE
UNSUITABLE EXTINGUISHING MEDIA:
FOAM AND DRY CHEMICAL EXTINGUISHERS AND SUFFOCATION ARE INEFFECTIVE.
PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
WEAR FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING
APPARATUS WITH FULL FACE PIECE OPERATED IN THE PRESSURE DEMAND OR OTHER
POSITIVE PRESSURE MODE. PREVENT FURTHER PROPAGATION OF FIRE BY SPRAYING
UNBURNT NEARBY PRODUCT WITH WATER. COMBAT FIRE FROM A SHELTERED POSITION.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
USE COPIOUS AMOUNTS OF WATER TO EXTINGUISH FIRE COMPRISED OF FLARES. FLARES
CONTAIN OXIDIZERS AND WILL CONTINUE TO BURN UNLESS A SIGNIFICANT AMOUNT OF
WATER IS USED. DO NOT BREATHE SMOKE.
FURTHER INFORMATION: NO DATA AVAILABLE
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS / PROTECTIVE EQUIPMENT / EMERGENCY PROCEDURES:
DO NOT BREATHE CONTENTS AND AVOID CONTACT WITH SKIN AND EYES. WEAR FLAME
RETARDANT CLOTHING WITH LONG SLEEVES, DUST MASK, RUBBER OR NITRILE GLOVES,
SAFETY GOGGLES, SAFETY SHOES. AVOID FRICTION ON THE RELEASED PRODUCT. KEEP
AWAY FROM IGNITION SOURCES.
ENVIRONMENTAL PRECAUTIONS:
PREVENT DISPERSION OF CONTENTS ON SOIL AND IN WATER. PREVENT CONTENTS FROM
SPREADING OR ENTERING INTO DRAINS, DITCHES, GROUNDWATER OR RIVERS BY USING
APPROPRIATE BARRIERS.
METHODS FOR CONTAINMENT AND CLEAN-UP:
USE CAUTION WHEN CLEANING UP SPILLED PRODUCT CONTENTS. REMOVE HEAT, FLAMES,
SPARKS AND OTHER SOURCES OF IGNITION. USE NON-SPARKING TOOLS AND EQUIPMENT.
PREVENT BUILDUP OF ELECTROSTATIC CHARGES BY GROUNDING. CLEAN SPILLS IN A
MANNER THAT DOES NOT DISPERSE DUST INTO THE AIR. DO NOT ABSORB IN SAWDUST
OR OTHER COMBUSTIBLE ABSORBENTS. PICK UP SPILL FOR RECOVERY OR DISPOSAL AND
PLACE IN AN APPROVED CONTAINER. WASH AWAY REMAINDER WITH PLENTY OF WATER.
COLLECT WASH WATER FOR APPROVED DISPOSAL.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
HOLD AND POINT FLARE AWAY FROM BODY WHEN IGNITING. EXERCISE CAUTION WHEN
USING THIS PRODUCT SINCE MOLTEN FLECKS MAY BE EMITTED. PRODUCES HOT FLAME.
BURNING FLARE CAN CAUSE SEVERE BURNS IF IN CONTACT WITH BODY. AVOID CONTACT
WITH CLOTHING AND OTHER COMBUSTIBLE MATERIALS. WEAR EYE PROTECTION DURING
USE. FOLLOW INSTRUCTIONS ON PACKAGE. USE OUTDOORS ONLY! DO NOT IGNITE OR
BURN PRODUCT INSIDE A VEHICLE OR BUILDING. AVOID INHALATION OF SMOKE. DO
NOT DISMANTLE. DO NOT ALLOW CONTENTS TO TOUCH EYES, SKIN OR CLOTHING. DO
NOT INGEST CONTENTS AS THEY MAY BE HARMFUL IF SWALLOWED. WASH THOROUGHLY
AFTER HANDLING. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. AVOID
CONTACT WITH HEAT, SPARKS, AND FLAME.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE AWAY FROM DIRECT SUNLIGHT, HEAT AND INCOMPATIBLE MATERIALS. SEE
SECTION 10. STORE AWAY FROM FOOD AND BEVERAGES. STORE AWAY FROM FLAMMABLE
MATERIALS, SOURCES OF HEAT, FLAME AND SPARKS. STORE AT AMBIENT TEMPERATURE.
DO NOT STORE PARTIALLY BURNED FLARES IN A VEHICLE, WAREHOUSE, OR ANY OTHER
BUILDING. PLASTIC BAGS ARE PROVIDED FOR MOISTURE PROTECTION. KEEP PARTIALLY
USED BAGS SEALED AT ALL TIMES.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE LIMITS OSHA PEL ACGIH TLV
STRONTIUM NITRATE NOT ESTABLISHED NOT ESTABLISHED
SULFUR NOT ESTABLISHED NOT ESTABLISHED
POTASSIUM NITRATE NUISANCE DUST 15 MG/M3. NUISANCE DUST 15 MG/M3.
PARAFFINIC OIL 5 MG/M3 TWA: 5 MG/M3
POTASSIUM CHLORATE NO AIRBORNE EXPOSURE LIMITS NO AIRBORNE EXPOSURE
ESTABLISHED LIMITS ESTABLISHED
WAXY SAWDUST NOT ESTABLISHED NOT ESTABLISHED
POLYVINYL CHLORIDE NO KNOWN HAZARDOUS COMPONENTS NO KNOWN HAZARDOUS
ABOVE REGULATORY THRESHOLDS COMPONENTS ABOVE
IN THIS PRODUCT. REGULATORY THRESHOLDS IN
THIS PRODUCT.
SHELLAC NOT ESTABLISHED NOT ESTABLISHED
CHARCOAL NUISANCE DUST 15 MG/M3. NUISANCE DUST 15 MG/M3.
EXPOSURE CONTROLS:
ENGINEERING CONTROLS:
USE PRODUCT OUTDOORS ONLY! WHEN CLEANING UP CONTENTS, USE LOCAL AND/OR
GENERAL EXHAUST.
PERSONAL PROTECTIVE EQUIPMENT:
EYE / FACE PROTECTION: SAFETY GLASSES OR GOGGLES
SKIN PROTECTION:
NONE UNDER NORMAL CONDITIONS WHEN USING PRODUCT UNLESS PROLONGED HANDLING
IS ANTICIPATED. IMPERVIOUS PROTECTIVE CLOTHING, INCLUDING GLOVES, BOOTS,
AND A LAB COAT, APRON OR COVERALLS, AS APPROPRIATE, WHEN CLEANING UP
SPILLED PRODUCT. WASH HANDS AND FACE BEFORE EATING, DRINKING OR USING
TOBACCO PRODUCTS.
RESPIRATORY PROTECTION:
NONE UNDER NORMAL CONDITIONS WHEN USING PRODUCT. A PARTICULATE RESPIRATOR
(NIOSH T N95 OR BETTER FILTERS) MAY BE WORN DURING THE CLEANUP OF SPILLED
MATERIALS.
GENERAL HYGIENE:
USE PRODUCT OUTDOORS AWAY FROM COMBUSTIBLE PRODUCTS. FOR CLEANUP OF SPILLED
MATERIALS, EMERGENCY SHOWERS AND EYE WASH STATIONS SHOULD BE AVAILABLE.
EDUCATE AND TRAIN EMPLOYEES IN THE SAFE USE AND HANDLING OF HAZARDOUS
MATERIALS.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE (COLOR, PHYSICAL FORM, SHAPE): YELLOW TO GREY POWDER
PH: NOT AVAILABLE
MELTING POINT: NOT AVAILABLE
SOLUBILITY: NOT AVAILABLE
BOILING POINT / RANGE: NOT APPLICABLE
FREEZING POINT: NOT APPLICABLE
EVAPORATION RATE: NOT APPLICABLE
VAPOR PRESSURE: NOT APPLICABLE
SPECIFIC GRAVITY: NOT APPLICABLE
VAPOR DENSITY: NOT APPLICABLE
ODOR: NO DATA AVAILABLE
ODOR THRESHOLD: NO DATA AVAILABLE
FLASH POINT: NOT AVAILABLE
FLAMMABILITY: NO DATA AVAILABLE
FLAMMABILITY LIMITS: NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
PARTITION COEFFICIENT: NO DATA AVAILABLE
VISCOSITY: NO DATA AVAILABLE
AUTO IGNITION TEMPERATURE: 360 DEG. F
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
| 10. STABILITY AND REACTIVITY | |
CHEMICAL STABILITY: STABLE
REACTIVITY: NO INFORMATION AVAILABLE
POSSIBILITY OF HAZARDOUS REACTIONS: HAZARDOUS POLYMERIZATION WILL NOT OCCUR
CONDITIONS TO AVOID:
COMBUSTIBLE MATERIALS, HEAT, FLAMES, SPARKS AND OTHER SOURCES OF IGNITION.
MOISTURE.
INCOMPATIBLE MATERIALS:
STRONG ACIDS, STRONG FUELS, AMMONIA SALTS, AND STRONG BASES. STRONG
OXIDIZERS; CHLORATE SALTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON MONOXIDE, CARBON DIOXIDE, SULFUR OXIDES, AND NITROGEN OXIDES.
| 11. TOXICOLOGY INFORMATION | |
INGREDIENT ACUTE TOXICITY INFORMATION:
INGREDIENT ORAL LD50 SKIN LD50 LC50
STRONTIUM RAT: 2750 MG/KG NO INFORMATION FOUND NO INFORMATION FOUND
NITRATE
SULFUR RAT: >2000 MG/KG RAT: >2000 MG/KG RAT: 79.23 MG/L 4HR
POTASSIUM RAT: 3750 MG/KG NO INFORMATION FOUND NO INFORMATION FOUND
NITRATE
PARAFFINIC RAT: >2000 MG/KG RAT: >2000 MG/KG NO INFORMATION FOUND
OIL
POTASSIUM RAT: 1870 MG/KG RABBIT: >2000 MG/KG NO INFORMATION FOUND
CHLORATE
WAXY RAT: >5000 MG/KG NOT STATED NOT STATED
SAWDUST
POLYVINYL RAT: >5000 MG/KG NO KNOWN HAZARDOUS NO KNOWN HAZARDOUS
COMPONENTS ABOVE COMPONENTS ABOVE
CHLORIDE REGULATORY REGULATORY THRESHOLDS
THRESHOLDS IN THIS IN THIS PRODUCT.
PRODUCT.
SHELLAC RAT: 10000 MG/KG NO INFORMATION FOUND NO INFORMATION FOUND
CHARCOAL RAT: 15400 MG/KG RABBIT: 3 G/KG NO INFORMATION FOUND
PRODUCT TOXICOLOGICAL INFORMATION:
ACUTE TOXICITY:
NOT CLASSIFIED - ACUTE TOXICITY ESTIMATE YIELDS ORAL LD50 OVER 5000 MG/KG
BW
SKIN IRRITATION / CORROSION:
CATEGORY 2 - OVER 10% OF INGREDIENTS CLASSIFIED AS A CATEGORY 2
SERIOUS EYE DAMAGE / IRRITATION:
CATEGORY 2A - OVER 10% OF INGREDIENTS CLASSIFIED AS A CATEGORY 2A
RESPIRATORY / SKIN SENSITIZATION:
NOT CLASSIFIED (BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE
NOT MET)
GERM CELL MUTAGEN:
NOT CLASSIFIED (BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE
NOT MET)
CARCINOGEN:
NOT CLASSIFIED (BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE
NOT MET)
REPRODUCTIVE TOXICITY:
NOT CLASSIFIED (BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE
NOT MET)
STOT - SINGLE EXPOSURE:
CATEGORY 3 - RESPIRATORY OVER 10% OF INGREDIENTS CLASSIFIED AS A CATEGORY 3
RESPIRATORY STOT HAZARD
STOT - REPEATED EXPOSURE:
NOT CLASSIFIED (BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE
NOT MET)
ASPIRATION HAZARD:
NOT CLASSIFIED (BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE
NOT MET)
LIKELY ROUTES OF EXPOSURE: SKIN, INGESTION, INHALATION
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
CONTENTS IRRITATING TO EYES DUE TO CHEMICAL AND PHYSICAL PROPERTIES OF THE
MIXTURE. INGESTION OF CONTENTS MAY CAUSE GASTROINTESTINAL IRRITATION WITH
NAUSEA, VOMITING AND DIARRHEA. INDIVIDUALS WITH KNOWN ALLERGIES TO SULFIDE
DRUGS MAY ALSO HAVE ALLERGIC REACTIONS TO ELEMENTAL SULFUR.
DELAYED AND IMMEDIATE EFFECTS AND CHRONIC EFFECTS FROM SHORT AND LONG TERM
EXPOSURE:
INHALATION OF CONTENTS OR SMOKE FROM BURNING FLARE WILL CAUSE IRRITATION TO
THE LUNGS AND MUCUS MEMBRANE. PROLONGED OR REPEATED SKIN CONTACT WITH
CONTENTS MAY CAUSE DERMATITIS.
INTERACTIVE EFFECTS: NO INFORMATION FOUND
| 12. ECOLOGICAL INFORMATION | |
INGREDIENT TOXICITY / PERSISTENCE / DEGRADABILITY / BIOACCUMULATION /
MOBILITY IN SOIL AND WATER:
AQUATIC TOXICITY:
STRONTIUM NITRATE:
ACUTE TOXICITY: FISHES, CARASSIUS AURATUS, LC100, 9,615 MG/L
CHRONIC TOXICITY: FISHES, GASTEROSTEUS ACULEATUS, LC100, 2.912 MG/L
SULFUR:
TOXICITY TO FISH LC50:
ONCORHYNCHUS MYKISS (RAINBOW TROUT): >180 MG/L - 96 H
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
EC50 - DAPHNIA MAGNA (WATER FLEA): >5,000 MG/L - 48 H
POTASSIUM CHLORATE:
FISH:
LC50 ONCORHYNCHUS MYKISS (RAINBOW TROUT): 1750 MG/L - 96 HR
EC50 DAPHNIA MAGNA (WATER FLEA): 1093 MG/L 24 HR
PARAFFINIC OIL:
OIL MIST, MINERAL:
LEPOMIS MACROCHIRUS (LC50) 96 HOUR(S): >100 MG/L
ONCORHYNCHUS MYKISS (LC50) 96 HOUR(S): >100 MG/L
POTASSIUM NITRATE:
FISH:
GUPPY (POECILIA RETICULATA) LC50: 180 MG/L (96 H)
ZOOPLANKTON:
DAPHNIA MAGNA LC50: 490 MG/L - 48HR
PERSISTENCE / DEGRADABILITY:
POTASSIUM NITRATE:
SOLUBLE IN WATER PERSISTENCE IS UNLIKELY BASED ON INFORMATION AVAILABLE.
BIOACCUMULATION / ACCUMULATION: NO INFORMATION FOUND
MOBILITY IN ENVIRONMENTAL MEDIA:
STRONTIUM NITRATE:
WATER:
CONSIDERABLE SOLUBILITY AND MOBILITY; SOIL/SEDIMENTS NON-SIGNIFICANT
ADSORPTION
POTASSIUM NITRATE:
WILL LIKELY BE MOBILE IN THE ENVIRONMENT DUE TO ITS WATER SOLUBILITY.
OTHER ADVERSE EFFECTS: NO INFORMATION FOUND
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
FLARES SHOULD BE ALLOWED TO BURN TO COMPLETION. PARTIALLY BURNED OR
UNBURNED FLARES, SPILLED CONTENTS, AND ASH FROM BURNED FLARES SHOULD BE
DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REQUIREMENTS.
CONSULT FACTORY FOR ANY ADDITIONAL DISPOSAL CONCERNS.
| 14. TRANSPORTATION INFORMATION | |
DESCRIPTION ID NUMBER SHIPPING NAME HAZARD PACKING EX NUMBER
CLASS GROUP
DOMESTIC
SHIPMENTS:
NO INNER *NA1325 FUSEE 4.1 II EX1992090001
PACKAGING
RETAIL PACKAGING **UN3178 FLAMMABLE 4.1 II EX2002110114
SOLID,
INORGANIC
(HIGHWAY
FLARES OR
FUSEES)
INTERNATIONAL /
AIR:
INNER PACKAGING UN0373 SIGNAL 1.4S EX1992090001
(BAG) DEVICES, HAND
DESCRIPTION REPORTABLE QUANTITIES SHIPPING METHOD
DOMESTIC
SHIPMENTS:
NO INNER NONE GROUND ONLY
PACKAGING
RETAIL PACKAGING NONE GROUND ONLY
INTERNATIONAL /
AIR:
INNER PACKAGING NONE AIR / GROUND
(BAG)
* AS NOTED ON EX1992090001
** ACCORDING TO 49CFR, EXCEPTION FOR CLASS 4, FLARES PROPERLY PACKAGED AND
CLASSED AS UN3178, FLAMMABLE SOLID, INORGANIC (HIGHWAY FLARES OR FUSEES),
MAY BE RENAMED "CONSUMER COMMODITY" AND RECLASSED AS ORM-D AND OFFERED FOR
TRANSPORTATION AND TRANSPORTED IN ACCORDANCE WITH THE APPLICABLE PROVISIONS
OF THAT SUBCHAPTER.
MARINE POLLUTANT: NO
SPECIAL PRECAUTIONS FOR USER: NO INFORMATION AVAILABLE
| 15. REGULATORY INFORMATION | |
US REGULATIONS TSCA CERCLA CWA CAA SARA SARA ACUTE CHRONIC
313 302
STRONTIUM NITRATE YES NO NO NO NO NO YES NO
SULFUR YES NO NO NO NO NO YES NO
POTASSIUM NITRATE YES NO NO NO YES NO NO NO
PARAFFINIC OIL YES NO NO NO NO NO NO NO
POTASSIUM CHLORATE YES NO NO NO NO NO YES NO
WAXY SAWDUST YES NO NO NO NO NO NO NO
POLYVINYL CHLORIDE YES NO NO NO NO NO YES NO
SHELLAC MIXTURE YES NO NO NO YES NO UNKNOWN UNKNOWN
CHARCOAL YES NO NO NO NO NO NO NO
US REGULATIONS FIRE REACTIVITY PRESSURE
STRONTIUM NITRATE NO YES NO
SULFUR YES NO NO
POTASSIUM NITRATE NO YES NO
PARAFFINIC OIL NO NO NO
POTASSIUM CHLORATE NO YES NO
WAXY SAWDUST NO NO NO
POLYVINYL CHLORIDE NO NO NO
SHELLAC MIXTURE UNKNOWN UNKNOWN UNKNOWN
CHARCOAL NO NO NO
US STATES CANADA EUROPE
PROP NJ PA WHMIS DSL WGK
65
STRONTIUM NO 1743 NO C OXIDIZING YES 2
NITRATE MATERIALS D1B
TOXIC MATERIALS
D2B TOXIC
MATERIALS
SULFUR NO 1757 YES B4 FLAMMABLE SOLID YES 1 / NWG
D2B TOXIC MATERIALS
POTASSIUM NO 1574 YES C OXIDIZING YES 1
NITRATE MATERIALS
PARAFFINIC NO 1437 NO NO RESULTS YES NOT LISTED
OIL
POTASSIUM YES 1560 YES C OXIDIZING YES 2
CHLORATE MATERIALS
D1B TOXIC MATERIALS
WAXY YES NO NO NO RESULTS YES NOT LISTED
SAWDUST
POLYVINYL NO 3622 NO NO RESULTS YES NOT LISTED
CHLORIDE
SHELLAC NO NO NO NO RESULTS UNKNOWN NOT LISTED
MIXTURE
CHARCOAL YES YES YES D2A VERY TOXIC YES NWG
MATERIALS D2B
TOXIC MATERIALS
| 16. OTHER INFORMATION | |
REVISION INFORMATION: MAY 2015
NFPA RATING:
HEALTH 2
FLAMMABILITY 1
REACTIVITY 1
HMIS RATING:
HEALTH 2
FLAMMABILITY 1
PHYSICAL HAZARD 1
KEY / LEGEND:
HMIS: HAZARDOUS MATERIAL IDENTIFICATION SYSTEM
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION
CAS: CHEMICAL ABSTRACTS SERVICE NUMBER
EINECS: EUROPEAN INVENTORY OF EXISTING CHEMICAL SUBSTANCES
OSHA PEL:
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION PERMISSIBLE EXPOSURE LIMIT
NIOSH TLV:
NATIONAL INSTITUTE OF OCCUPATIONAL SAFETY AND HEALTH THRESHOLD LIMIT VALUE
TSCA: TOXIC SUBSTANCE CONTROL ACT - US
CERCLA: COMPREHENSIVE ENVIRONMENTAL RESPONSE,
COMPENSATION AND LIABILITY ACT - US
CWA: CLEAN WATER ACT - US
CAA: CLEAN AIR ACT - US
SARA: SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT - US
PROP 65: CALIFORNIA'S PROPOSITION 65 LIST
WHMIS: WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM - CANADA
DSL: DOMESTIC SUBSTANCES LIST - CANADA
WGK: WATER HAZARD CLASSES - GERMANY
LEGAL STATEMENT:
THIS INFORMATION IS ACCURATE TO THE BEST KNOWLEDGE ORION SAFETY PRODUCTS.
ORION SAFETY PRODUCTS MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER
EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, WITH RESPECT TO THE
INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION
REFERS. ACCORDINGLY, ORION SAFETY PRODUCTS WILL NOT BE RESPONSIBLE FOR
DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION. ANY PERSON
UTILIZING THIS DOCUMENT SHOULD SEEK COMPETENT PROFESSIONAL ADVICE TO VERIFY
AND ASSUME RESPONSIBILITY FOR THE SUITABILITY OF THIS INFORMATION TO THEIR
PARTICULAR SITUATION.
NO PC FLARE
04 2017