| Common Name: | TITEBOND ROOF PLUS SEALANT, 3241 |
| Manufacturer: | FRANKLIN INTERNATIONAL |
| SDS Revision Date: | 5/26/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 40JM93 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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FRANKLIN INTERNATIONAL
SAFETY DATA SHEET
TITEBOND ROOF PLUS SEALANT
| SECTION 1. IDENTIFICATION |  |
GHS PRODUCT IDENTIFIER: TITEBOND ROOF PLUS SEALANT
PRODUCT TYPE: LIQUID.
ADDRESS:
FRANKLIN INTERNATIONAL
2020 BRUCK STREET
COLUMBUS, OH 43207
CONTACT PERSON: FRANKLIN TECHNICAL SERVICES
TELEPHONE: (800) 877-4583
IN CASE OF EMERGENCY:
FRANKLIN SECURITY: (614) 445-1300
REFERENCE NUMBER: 00
PRODUCT CODE: 3241
DATE OF REVISION: 5/26/2015.
PRINT DATE: 5/27/2015.
CHEMTREC (24 HOUR): (800) 424 - 9300
CHEMTREC INTERNATIONAL: (703) 527 - 3887
CHEMICAL FAMILY: ADHESIVE.
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST NOT APPLICABLE.
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
CARCINOGENICITY (ORAL): CATEGORY 1B
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (RESPIRATORY TRACT
IRRITATION): CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (EARS) (ORAL):
CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (EARS) (DERMAL):
CATEGORY 2
PERCENTAGE OF THE MIXTURE CONSISTING OF INGREDIENT(S) OF UNKNOWN TOXICITY:
15%
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS:
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
CAUSES SERIOUS EYE IRRITATION.
CAUSES SKIN IRRITATION.
MAY CAUSE CANCER IF SWALLOWED.
MAY CAUSE RESPIRATORY IRRITATION.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE IF
SWALLOWED. (EARS)
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE IN
CONTACT WITH SKIN. (EARS)
PRECAUTIONARY STATEMENTS:
GENERAL:
READ LABEL BEFORE USE. KEEP OUT OF REACH OF CHILDREN. IF MEDICAL ADVICE IS
NEEDED, HAVE PRODUCT CONTAINER OR LABEL AT HAND.
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. USE PERSONAL PROTECTIVE
EQUIPMENT AS REQUIRED. WEAR PROTECTIVE GLOVES. WEAR EYE OR FACE PROTECTION.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. DO NOT BREATHE VAPOR.
WASH HANDS THOROUGHLY AFTER HANDLING.
RESPONSE: GET MEDICAL ATTENTION IF YOU FEEL UNWELL.
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
IF ON SKIN:
WASH WITH PLENTY OF SOAP AND WATER. TAKE OFF CONTAMINATED CLOTHING. WASH
CONTAMINATED CLOTHING BEFORE REUSE.
IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
SUPPLEMENTAL LABEL ELEMENTS:
AVOID CONTACT WITH SKIN AND CLOTHING. WASH THOROUGHLY AFTER HANDLING.
HAZARDS NOT OTHERWISE CLASSIFIED:
PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
HAZARDOUS INGREDIENTS:
UNITED STATES:
NAME CAS NUMBER %
XYLENE 1330-20-7 25 - 50
ETHYLBENZENE 100-41-4 5 - 10
DISTILLATES (PETROLEUM), HYDROTREATED 64742-52-5 1 - 5
HEAVY NAPHTHENIC
CANADA:
NAME CAS NUMBER %
XYLENE 1330-20-7 25 - 50
ETHYLBENZENE 100-41-4 5 - 10
DISTILLATES (PETROLEUM), HYDROTREATED 64742-46-7 1 - 5
MIDDLE
WHITE MINERAL OIL (PETROLEUM) 8042-47-5 1 - 5
DISTILLATES (PETROLEUM), HYDROTREATED 64742-52-5 1 - 5
HEAVY NAPHTHENIC
LUBRICATING OILS (PETROLEUM), C20-50, 72623-85-9 1 - 5
HYDROTREATED NEUTRAL OIL-BASED,
HIGH-VISCOSITY
LUBRICATING OILS (PETROLEUM), C15-30, 72623-86-0 1 - 5
HYDROTREATED NEUTRAL OIL-BASED
LUBRICATING OILS (PETROLEUM), C20-50, 72623-87-1 1 - 5
HYDROTREATED NEUTRAL OIL-BASED
DISTILLATES (PETROLEUM), HYDROTREATED 64742-54-7 1 - 5
HEAVY PARAFFINIC
MEXICO:
NAME CAS NUMBER UN NUMBER % IDLH CLASSIFICATION
H F R SPECIAL
XYLENE 1330-20-7 UN1993 25 - 50 900 PPM 2 3 0
ETHYLBENZENE 100-41-4 UN1993 5 - 10 800 PPM 2 3 0
DISTILLATES 64742-46-7 NOT 1 - 5 2 2 0
(PETROLEUM), AVAILABLE.
HYDROTREATED
MIDDLE
DISTILLATES 64742-52-5 NOT 1 - 5 2500 2 1 0
(PETROLEUM), AVAILABLE. MG/M3
HYDROTREATED
HEAVY
NAPHTHENIC
SILICA, 112945-52-5 NOT 1 - 5 0 0 0
AMORPHOUS, AVAILABLE.
FUMED,
CRYST.-FREE
WHITE 8042-47-5 NOT 1 - 5 2500 0 1 0
MINERAL OIL AVAILABLE. MG/M3
(PETROLEUM)
LUBRICATING 72623-85-9 NOT 1 - 5 2500 0 1 0
OILS AVAILABLE. MG/M3
(PETROLEUM),
C20-50,
HYDROTREATED
NEUTRAL
OIL-BASED,
HIGH-
VISCOSITY
LUBRICATING 72623-86-0 NOT 1 - 5 2500 0 1 0
OILS AVAILABLE. MG/M3
(PETROLEUM),
C15-30,
HYDROTREATED
NEUTRAL
OIL-BASED
LUBRICATING 72623-87-1 NOT 1 - 5 2500 0 1 0
OILS AVAILABLE. MG/M3
(PETROLEUM),
C20-50,
HYDROTREATED
NEUTRAL
OIL-BASED
DISTILLATES 64742-54-7 NOT 1 - 5 2500 0 1 0
(PETROLEUM), AVAILABLE. MG/M3
HYDROTREATED
HEAVY
PARAFFINIC
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS DUE
TO BATCH VARIATION.
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH OR THE ENVIRONMENT AND HENCE REQUIRE
REPORTING IN THIS SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE UPPER
AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. CONTINUE TO
RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL ATTENTION.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS.
IF NOT BREATHING, IF BREATHING IS IRREGULAR OR IF RESPIRATORY ARREST
OCCURS, PROVIDE ARTIFICIAL RESPIRATION OR OXYGEN BY TRAINED PERSONNEL.
IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION. GET MEDICAL ATTENTION. IF NECESSARY, CALL A POISON CENTER
OR PHYSICIAN. IF UNCONSCIOUS, PLACE IN RECOVERY POSITION AND GET MEDICAL
ATTENTION IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN TIGHT CLOTHING SUCH
AS A COLLAR, TIE, BELT OR WAISTBAND.
SKIN CONTACT:
WASH SKIN THOROUGHLY WITH SOAP AND WATER OR USE RECOGNIZED SKIN CLEANSER.
REMOVE CONTAMINATED CLOTHING AND SHOES. WASH CONTAMINATED CLOTHING
THOROUGHLY WITH WATER BEFORE REMOVING IT, OR WEAR GLOVES. CONTINUE TO RINSE
FOR AT LEAST 10 MINUTES. GET MEDICAL ATTENTION. WASH CLOTHING BEFORE REUSE.
CLEAN SHOES THOROUGHLY BEFORE REUSE.
INGESTION:
WASH OUT MOUTH WITH WATER. REMOVE DENTURES IF ANY. REMOVE VICTIM TO FRESH
AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR BREATHING. IF MATERIAL
HAS BEEN SWALLOWED AND THE EXPOSED PERSON IS CONSCIOUS, GIVE SMALL
QUANTITIES OF WATER TO DRINK. STOP IF THE EXPOSED PERSON FEELS SICK AS
VOMITING MAY BE DANGEROUS. DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO
BY MEDICAL PERSONNEL. IF VOMITING OCCURS, THE HEAD SHOULD BE KEPT LOW SO
THAT VOMIT DOES NOT ENTER THE LUNGS. GET MEDICAL ATTENTION. NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF UNCONSCIOUS, PLACE IN
RECOVERY POSITION AND GET MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN OPEN
AIRWAY. LOOSEN TIGHT CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION: MAY CAUSE RESPIRATORY IRRITATION.
SKIN CONTACT: CAUSES SKIN IRRITATION. DEFATTING TO THE SKIN.
INGESTION: IRRITATING TO MOUTH, THROAT AND STOMACH.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
DRYNESS
CRACKING
INGESTION: NO SPECIFIC DATA.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF
NECESSARY:
NOTES TO PHYSICIAN:
TREAT SYMPTOMATICALLY. CONTACT POISON TREATMENT SPECIALIST IMMEDIATELY IF
LARGE QUANTITIES HAVE BEEN INGESTED OR INHALED.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS.
IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION. WASH CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE
REMOVING IT, OR WEAR GLOVES.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE AN EXTINGUISHING AGENT SUITABLE FOR THE SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
IN A FIRE OR IF HEATED, A PRESSURE INCREASE WILL OCCUR AND THE CONTAINER
MAY BURST.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON DIOXIDE
CARBON MONOXIDE
METAL OXIDE/OXIDES
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF THE
INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE OPERATED
IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL.
AVOID BREATHING VAPOR OR MIST. PROVIDE ADEQUATE VENTILATION. WEAR
APPROPRIATE RESPIRATOR WHEN VENTILATION IS INADEQUATE. PUT ON APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALISED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE OF
ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE ALSO
THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL OR
AIR).
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. DILUTE WITH
WATER AND MOP UP IF WATER-SOLUBLE. ALTERNATIVELY, OR IF WATER-INSOLUBLE,
ABSORB WITH AN INERT DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE
DISPOSAL CONTAINER. DISPOSE OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
LARGE SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. APPROACH
RELEASE FROM UPWIND. PREVENT ENTRY INTO SEWERS, WATER COURSES, BASEMENTS OR
CONFINED AREAS. WASH SPILLAGES INTO AN EFFLUENT TREATMENT PLANT OR PROCEED
AS FOLLOWS. CONTAIN AND COLLECT SPILLAGE WITH NON-COMBUSTIBLE, ABSORBENT
MATERIAL E.G. SAND, EARTH, VERMICULITE OR DIATOMACEOUS EARTH AND PLACE IN
CONTAINER FOR DISPOSAL ACCORDING TO LOCAL REGULATIONS (SEE SECTION 13).
DISPOSE OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR. CONTAMINATED ABSORBENT
MATERIAL MAY POSE THE SAME HAZARD AS THE SPILLED PRODUCT.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). AVOID
EXPOSURE - OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL
SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT GET IN EYES OR ON
SKIN OR CLOTHING. DO NOT BREATHE VAPOR OR MIST. DO NOT INGEST. USE ONLY
WITH ADEQUATE VENTILATION. WEAR APPROPRIATE RESPIRATOR WHEN VENTILATION IS
INADEQUATE. KEEP IN THE ORIGINAL CONTAINER OR AN APPROVED ALTERNATIVE MADE
FROM A COMPATIBLE MATERIAL, KEPT TIGHTLY CLOSED WHEN NOT IN USE. EMPTY
CONTAINERS RETAIN PRODUCT RESIDUE AND CAN BE HAZARDOUS. DO NOT REUSE
CONTAINER.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. REMOVE CONTAMINATED CLOTHING AND
PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS. SEE ALSO SECTION 8 FOR
ADDITIONAL INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE IN ORIGINAL CONTAINER
PROTECTED FROM DIRECT SUNLIGHT IN A DRY, COOL AND WELL-VENTILATED AREA,
AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10) AND FOOD AND DRINK. STORE
LOCKED UP. KEEP CONTAINER TIGHTLY CLOSED AND SEALED UNTIL READY FOR USE.
CONTAINERS THAT HAVE BEEN OPENED MUST BE CAREFULLY RESEALED AND KEPT
UPRIGHT TO PREVENT LEAKAGE. DO NOT STORE IN UNLABELED CONTAINERS. USE
APPROPRIATE CONTAINMENT TO AVOID ENVIRONMENTAL CONTAMINATION.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
UNITED STATES:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT NAME EXPOSURE LIMITS
XYLENE ACGIH TLV (UNITED STATES, 4/2014).
TWA: 100 PPM 8 HOURS.
TWA: 434 MG/M3 8 HOURS.
STEL: 150 PPM 15 MINUTES.
STEL: 651 MG/M3 15 MINUTES.
OSHA PEL 1989 (UNITED STATES, 3/1989).
TWA: 100 PPM 8 HOURS.
TWA: 435 MG/M3 8 HOURS.
STEL: 150 PPM 15 MINUTES.
STEL: 655 MG/M3 15 MINUTES.
OSHA PEL (UNITED STATES, 2/2013).
TWA: 100 PPM 8 HOURS.
TWA: 435 MG/M3 8 HOURS.
ETHYLBENZENE ACGIH TLV (UNITED STATES, 4/2014).
TWA: 20 PPM 8 HOURS.
OSHA PEL 1989 (UNITED STATES, 3/1989).
TWA: 100 PPM 8 HOURS.
TWA: 435 MG/M3 8 HOURS.
STEL: 125 PPM 15 MINUTES.
STEL: 545 MG/M3 15 MINUTES.
NIOSH REL (UNITED STATES, 10/2013).
TWA: 100 PPM 10 HOURS.
TWA: 435 MG/M3 10 HOURS.
STEL: 125 PPM 15 MINUTES.
STEL: 545 MG/M3 15 MINUTES.
OSHA PEL (UNITED STATES, 2/2013).
TWA: 100 PPM 8 HOURS.
TWA: 435 MG/M3 8 HOURS.
DISTILLATES (PETROLEUM), ACGIH TLV (UNITED STATES, 4/2014).
HYDROTREATED HEAVY NAPHTHENIC TWA: 5 MG/M3 8 HOURS.
FORM: INHALABLE FRACTION
OSHA PEL (UNITED STATES).
TWA: 5 MG/M3
FORM: MIST
ACGIH TLV (UNITED STATES).
TWA: 5 MG/M3
FORM: MIST
STEL: 10 MG/M3
FORM: MIST
NIOSH REL (UNITED STATES, 10/2013).
TWA: 5 MG/M3 10 HOURS.
FORM: MIST
STEL: 10 MG/M3 15 MINUTES.
FORM: MIST
OSHA PEL (UNITED STATES, 2/2013).
TWA: 5 MG/M3 8 HOURS.
CANADA:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT LIST NAME TWA (8 HOURS) STEL (15 MINS)
PPM MG/M3 OTHER PPM MG/M3 OTHER
XYLENE US ACGIH 4/2014 100 434 150 651
AB 4/2009 100 434 150 651
BC 4/2014 100 150
ON 1/2013 100 434 150 651
QC 1/2014 100 434 150 651
ETHYLBENZENE US ACGIH 4/2014 20
AB 4/2009 100 434 125 543
BC 4/2014 20
ON 1/2013 20
QC 1/2014 100 434 125 543
DISTILLATES US ACGIH 5 10
(PETROLEUM),
HYDROTREATED
MIDDLE
WHITE MINERAL US ACGIH 4/2014 5
OIL (PETROLEUM) AB 4/2009 5 10
BC 4/2014 1
ON 1/2013 5 10
QC 1/2014 5 10
DISTILLATES US ACGIH 4/2014 5
(PETROLEUM), US ACGIH 5 10
HYDROTREATED AB 4/2009 5 10
HEAVY ON 1/2013 5 10
NAPHTHENIC QC 1/2014 5 10
LUBRICATING US ACGIH 4/2014 5
OILS (PETROLEUM), AB 4/2009 5 10
C20-50, ON 1/2013 5 10
HYDROTREATED QC 1/2014 5 10
NEUTRAL
OIL-BASED,
HIGH-VISCOSITY
LUBRICATING US ACGIH 4/2014 5
OILS (PETROLEUM), AB 4/2009 5 10
C15-30, ON 1/2013 5 10
HYDROTREATED QC 1/2014 5 10
NEUTRAL
OIL-BASED
LUBRICATING OILS AB 4/2009 5 10
(PETROLEUM), ON 1/2013 5 10
C20-50, QC 1/2014 5 10
HYDROTREATED
NEUTRAL
OIL-BASED
DISTILLATES US ACGIH 4/2014 5
(PETROLEUM), AB 4/2009 5 10
HYDROTREATED ON 1/2013 5 10
HEAVY QC 1/2014 5 10
PARAFFINIC
INGREDIENT LIST NAME CEILING NOTATIONS
PPM MG/M3 OTHER
XYLENE US ACGIH 4/2014
AB 4/2009
BC 4/2014
ON 1/2013
QC 1/2014
ETHYLBENZENE US ACGIH 4/2014
AB 4/2009
BC 4/2014
ON 1/2013
QC 1/2014
DISTILLATES US ACGIH [A]
(PETROLEUM),
HYDROTREATED
MIDDLE
WHITE MINERAL OIL US ACGIH 4/2014 [B]
(PETROLEUM) AB 4/2009 [A]
BC 4/2014
ON 1/2013 [C]
QC 1/2014 [C]
DISTILLATES US ACGIH 4/2014 [B]
(PETROLEUM), US ACGIH [A]
HYDROTREATED AB 4/2009 [A]
HEAVY NAPHTHENIC ON 1/2013 [C]
QC 1/2014 [C]
LUBRICATING OILS US ACGIH 4/2014 [B]
(PETROLEUM), C20-50, AB 4/2009 [A]
HYDROTREATED NEUTRAL ON 1/2013 [C]
OIL-BASED, QC 1/2014 [C]
HIGH-VISCOSITY
LUBRICATING OILS US ACGIH 4/2014 [B]
(PETROLEUM), C15-30, AB 4/2009 [A]
HYDROTREATED ON 1/2013 [C]
NEUTRAL OIL-BASED QC 1/2014 [C]
LUBRICATING OILS AB 4/2009 [A]
(PETROLEUM), C20-50, ON 1/2013 [C]
HYDROTREATED QC 1/2014 [C]
NEUTRAL OIL-BASED
DISTILLATES US ACGIH 4/2014 [B]
(PETROLEUM), AB 4/2009 [A]
HYDROTREATED ON 1/2013 [C]
HEAVY PARAFFINIC QC 1/2014 [C]
FORM:
[A]MIST
[B]INHALABLE FRACTION
[C]MIST
MEXICO:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT EXPOSURE LIMITS
XYLENE NOM-010-STPS (MEXICO, 9/2000).
LMPE-PPT: 100 PPM 8 HOURS.
LMPE-PPT: 435 MG/M3 8 HOURS.
LMPE-CT: 655 MG/M3 15 MINUTES.
LMPE-CT: 150 PPM 15 MINUTES.
ETHYLBENZENE NOM-010-STPS (MEXICO, 9/2000).
LMPE-PPT: 100 PPM 8 HOURS.
LMPE-PPT: 435 MG/M3 8 HOURS.
LMPE-CT: 545 MG/M3 15 MINUTES.
LMPE-CT: 125 PPM 15 MINUTES.
SILICA, AMORPHOUS, FUMED, CRYST.-FREE NOM-010-STPS (MEXICO, 9/2000).
LMPE-PPT: 3 MG/M3 8 HOURS.
FORM: BREATHABLE PARTICULATES
LMPE-PPT: 10 MG/M3 8 HOURS.
FORM: INHALABLE PARTICULATES
DISTILLATES (PETROLEUM), HYDROTREATED ACGIH TLV (UNITED STATES).
MIDDLE TWA: 5 MG/M3
FORM: MIST
STEL: 10 MG/M3
FORM: MIST
WHITE MINERAL OIL (PETROLEUM) NOM-010-STPS (MEXICO, 9/2000).
LMPE-PPT: 5 MG/M3 8 HOURS.
FORM: MIST
LMPE-CT: 10 MG/M3 15 MINUTES.
FORM: MIST
DISTILLATES (PETROLEUM), HYDROTREATED NOM-010-STPS (MEXICO, 9/2000).
HEAVY NAPHTHENIC LMPE-PPT: 5 MG/M3 8 HOURS.
FORM: MIST
LMPE-CT: 10 MG/M3 15 MINUTES.
FORM: MIST
LUBRICATING OILS (PETROLEUM), C20-50, NOM-010-STPS (MEXICO, 9/2000).
HYDROTREATED NEUTRAL OIL-BASED, LMPE-PPT: 5 MG/M3 8 HOURS.
HIGH-VISCOSITY FORM: MIST
LMPE-CT: 10 MG/M3 15 MINUTES.
FORM: MIST
LUBRICATING OILS (PETROLEUM), C15-30, NOM-010-STPS (MEXICO, 9/2000).
HYDROTREATED NEUTRAL OIL-BASED LMPE-PPT: 5 MG/M3 8 HOURS.
FORM: MIST
LMPE-CT: 10 MG/M3 15 MINUTES.
FORM: MIST
LUBRICATING OILS (PETROLEUM), C20-50, NOM-010-STPS (MEXICO, 9/2000).
HYDROTREATED NEUTRAL OIL-BASED LMPE-PPT: 5 MG/M3 8 HOURS.
FORM: MIST
LMPE-CT: 10 MG/M3 15 MINUTES.
FORM: MIST
DISTILLATES (PETROLEUM), HYDROTREATED NOM-010-STPS (MEXICO, 9/2000).
HEAVY PARAFFINIC LMPE-PPT: 5 MG/M3 8 HOURS.
FORM: MIST
LMPE-CT: 10 MG/M3 15 MINUTES.
FORM: MIST
CONSULT LOCAL AUTHORITIES FOR ACCEPTABLE EXPOSURE LIMITS.
APPROPRIATE ENGINEERING CONTROLS:
USE ONLY WITH ADEQUATE VENTILATION. IF USER OPERATIONS GENERATE DUST,
FUMES, GAS, VAPOR OR MIST, USE PROCESS ENCLOSURES, LOCAL EXHAUST
VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP WORKER EXPOSURE TO
AIRBORNE CONTAMINANTS BELOW ANY RECOMMENDED OR STATUTORY LIMITS.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED TO
ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, FUME SCRUBBERS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING. WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE
THAT EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION
LOCATION.
EYE/FACE PROTECTION:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN A
RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO LIQUID
SPLASHES, MISTS, GASES OR DUSTS. IF CONTACT IS POSSIBLE, THE FOLLOWING
PROTECTION SHOULD BE WORN, UNLESS THE ASSESSMENT INDICATES A HIGHER DEGREE
OF PROTECTION: CHEMICAL SPLASH GOGGLES.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY. CONSIDERING THE PARAMETERS
SPECIFIED BY THE GLOVE MANUFACTURER, CHECK DURING USE THAT THE GLOVES ARE
STILL RETAINING THEIR PROTECTIVE PROPERTIES. IT SHOULD BE NOTED THAT THE
TIME TO BREAKTHROUGH FOR ANY GLOVE MATERIAL MAY BE DIFFERENT FOR DIFFERENT
GLOVE MANUFACTURERS. IN THE CASE OF MIXTURES, CONSISTING OF SEVERAL
SUBSTANCES, THE PROTECTION TIME OF THE GLOVES CANNOT BE ACCURATELY
ESTIMATED.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD BE
SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
USE A PROPERLY FITTED, AIR-PURIFYING OR AIR-FED RESPIRATOR COMPLYING WITH
AN APPROVED STANDARD IF A RISK ASSESSMENT INDICATES THIS IS NECESSARY.
RESPIRATOR SELECTION MUST BE BASED ON KNOWN OR ANTICIPATED EXPOSURE LEVELS,
THE HAZARDS OF THE PRODUCT AND THE SAFE WORKING LIMITS OF THE SELECTED
RESPIRATOR.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID. [PASTE.]
COLOR: CLEAR.
ODOR: SOLVENT(S)
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT: NOT AVAILABLE.
BOILING POINT: NOT AVAILABLE.
FLASH POINT:
CLOSED CUP: 26.667 DEG. C (80 DEG. F)
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS:
LOWER: 1%
UPPER: 6.7%
VOC (LESS WATER, LESS EXEMPT SOLVENTS): 315 G/L
VAPOR DENSITY: >1 [AIR = 1]
RELATIVE DENSITY: 0.98
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NO SPECIFIC TEST DATA RELATED TO REACTIVITY AVAILABLE FOR THIS PRODUCT OR
ITS INGREDIENTS.
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID: NO SPECIFIC DATA.
INCOMPATIBLE MATERIALS: NO SPECIFIC DATA.
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
XYLENE LC50 INHALATION RAT 5000 PPM 4 HOURS
GAS.
LD50 ORAL RAT 4300 MG/KG
ETHYLBENZENE LD50 DERMAL RABBIT >5000 MG/KG
LD50 ORAL RAT 3500 MG/KG
DISTILLATES (PETROLEUM), LD50 ORAL RAT >5000 MG/KG
HYDROTREATED HEAVY
NAPHTHENIC
CONCLUSION/SUMMARY: NOT AVAILABLE.
IRRITATION/CORROSION:
PRODUCT/INGREDIENT RESULT SPECIES SCORE EXPOSURE OBSERVATION
NAME
XYLENE EYES: RABBIT 87 MILLIGRAMS
MILD
IRRITANT
EYES: EYES: RABBIT 24 HOURS
SEVERE IRRITANT SEVERE 5 MILLIGRAMS
IRRITANT
SKIN: SKIN: RAT 8 HOURS
MILD IRRITANT MILD 60 MICROLITERS
IRRITANT
SKIN: SKIN: RABBIT 24 HOURS
MODERATE IRRITANT MODERATE 500 MILLIGRAMS
IRRITANT
SKIN: SKIN: RABBIT 100 PERCENT
MODERATE IRRITANT MODERATE
IRRITANT
ETHYLBENZENE EYES: RABBIT 500 MILLIGRAMS
SEVERE
IRRITANT
SKIN: SKIN: RABBIT 24 HOURS
MILD IRRITANT MILD 15 MILLIGRAMS
IRRITANT
DISTILLATES SKIN: RABBIT 500 MILLIGRAMS
(PETROLEUM), SEVERE
HYDROTREATED IRRITANT
HEAVY
NAPHTHENIC
CONCLUSION/SUMMARY:
SKIN: NOT AVAILABLE.
EYES: NOT AVAILABLE.
RESPIRATORY: NOT AVAILABLE.
ASPIRATION HAZARD:
NAME RESULT
ETHYLBENZENE ASPIRATION HAZARD - CATEGORY 1
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE:
ROUTES OF ENTRY ANTICIPATED: ORAL, DERMAL, INHALATION.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION: MAY CAUSE RESPIRATORY IRRITATION.
SKIN CONTACT: CAUSES SKIN IRRITATION. DEFATTING TO THE SKIN.
INGESTION: IRRITATING TO MOUTH, THROAT AND STOMACH.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
DRYNESS
CRACKING
INGESTION: NO SPECIFIC DATA.
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG
TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES EXPOSURE
NAME
XYLENE ACUTE LC50: CRUSTACEANS - 48 HOURS
8500 (MICRO)G/L PALAEMONETES PUGIO
MARINE WATER
ACUTE LC50: FISH - PIMEPHALES 96 HOURS
13400 (MICRO)G/L PROMELAS
FRESH WATER
ETHYLBENZENE ACUTE EC50: ALGAE - 72 HOURS
4600 (MICRO)G/L PSEUDOKIRCHNERIELLA
FRESH WATER SUBCAPITATA
ACUTE EC50: ALGAE - 96 HOURS
3600 (MICRO)G/L PSEUDOKIRCHNERIELLA
FRESH WATER SUBCAPITATA
ACUTE EC50: DAPHNIA - DAPHNIA 48 HOURS
2930 TO 4400 MAGNA - NEONATE
(MICRO)G/L
FRESH WATER
ACUTE LC50: CRUSTACEANS - CANCER 48 HOURS
40000 (MICRO)G/L MAGISTER -ZOEA
MARINE WATER
ACUTE LC50: FISH - ONCORHYNCHUS 96 HOURS
4200 (MICRO)G/L MYKISS
FRESH WATER
CONCLUSION/SUMMARY: NOT AVAILABLE.
PERSISTENCE AND DEGRADABILITY: NOT AVAILABLE.
BIOACCUMULATIVE POTENTIAL:
PRODUCT/INGREDIENT NAME LOGPOW BCF POTENTIAL
XYLENE 3.12 8.1 TO 25.9 LOW
ETHYLBENZENE 3.6 LOW
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL TIMES
COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE DISPOSAL
LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE OF
SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL
CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE SEWER UNLESS
FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH JURISDICTION.
WASTE PACKAGING SHOULD BE RECYCLED. INCINERATION OR LANDFILL SHOULD ONLY BE
CONSIDERED WHEN RECYCLING IS NOT FEASIBLE. THIS MATERIAL AND ITS CONTAINER
MUST BE DISPOSED OF IN A SAFE WAY. CARE SHOULD BE TAKEN WHEN HANDLING
EMPTIED CONTAINERS THAT HAVE NOT BEEN CLEANED OR RINSED OUT. EMPTY
CONTAINERS OR LINERS MAY RETAIN SOME PRODUCT RESIDUES. AVOID DISPERSAL OF
SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL, WATERWAYS, DRAINS AND
SEWERS.
UNITED STATES - RCRA TOXIC HAZARDOUS WASTE "U" LIST:
INGREDIENT CAS # STATUS REFERENCE NUMBER
XYLENE 1330-20-7 LISTED U239
| SECTION 14. TRANSPORT INFORMATION | |
DOT TDG MEXICO
CLASSIFICATION CLASSIFICATION CLASSIFICATION
UN NUMBER 1133 1133 1133
UN PROPER SHIPPING ADHESIVES, ADHESIVES, ADHESIVES,
NAME CONTAINING CONTAINING CONTAINING
FLAMMABLE FLAMMABLE FLAMMABLE
LIQUID LIQUID LIQUID
TRANSPORT HAZARD 3 3 3
CLASS(ES)
FLAMMABLE LIQUID, CLASS 3, CLASS 3,
CLASS/DIVISION FLAMMABLE LIQUIS FLAMMABLE LIQUIS
3.1, 3.2, 3.3
PACKING GROUP III III III
ENVIRONMENTAL NO. NO. NO.
HAZARDS
ADDITIONAL REPORTABLE REMARKS: REMARKS:
INFORMATION QUANTITY: LIMITED QUANTITY LIMITED QUANTITY
363.64 LBS /
165.09 KG
[44.502 GAL /
168. 46 L]
PACKAGE SIZES
SHIPPED IN
QUANTITIES LESS
THAN THE
PRODUCT
REPORTABLE
QUANTITY ARE
NOT SUBJECT TO
THE RQ
(REPORTABLE
QUANTITY)
TRANSPORTATION
REQUIREMENTS.
REMARKS:
LIMITED QUANTITY
ADR/RID IMDG IATA
UN NUMBER 1133 1133 1133
UN PROPER SHIPPING NAME ADHESIVES, ADHESIVES, ADHESIVES,
CONTAINING CONTAINING CONTAINING
FLAMMABLE FLAMMABLE FLAMMABLE
LIQUID LIQUID LIQUID
TRANSPORT HAZARD 3 3 3
CLASS(ES)
CLASS 3, CLASS 3 - CLASS 3,
FLAMMABLE FLAMMABLE FLAMMABLE
LIQUIDS LIQUIDS LIQUIS
PACKING GROUP III III III
ENVIRONMENTAL HAZARDS NO. NO. NO.
ADDITIONAL SPECIAL REMARKS: REMARKS:
INFORMATION PROVISIONS: LIMITED LIMITED
640 (E) QUANTITY QUANTITY
TUNNEL CODE:
(D/E)
SPECIAL PRECAUTIONS FOR USER:
TRANSPORT WITHIN USER'S PREMISES:
ALWAYS TRANSPORT IN CLOSED CONTAINERS THAT ARE UPRIGHT AND SECURE. ENSURE
THAT PERSONS TRANSPORTING THE PRODUCT KNOW WHAT TO DO IN THE EVENT OF AN
ACCIDENT OR SPILLAGE.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT AVAILABLE.
| SECTION 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
TSCA 8(A) CDR EXEMPT/PARTIAL EXEMPTION: NOT DETERMINED
UNITED STATES INVENTORY (TSCA 8B): ALL COMPONENTS ARE LISTED OR EXEMPTED.
CLEAN AIR ACT SECTION 112 (B) HAZARDOUS AIR POLLUTANTS (HAPS): LISTED
CLEAN AIR ACT SECTION 602 CLASS I SUBSTANCES: NOT LISTED
CLEAN AIR ACT SECTION 602 CLASS II SUBSTANCES: NOT LISTED
SARA 302/304:
COMPOSITION/INFORMATION ON INGREDIENTS: NO PRODUCTS WERE FOUND.
SARA 304 RQ: NOT APPLICABLE.
SARA 311/312:
CLASSIFICATION:
IMMEDIATE (ACUTE) HEALTH HAZARD
DELAYED (CHRONIC) HEALTH HAZARD
COMPOSITION/INFORMATION ON INGREDIENTS:
NAME % FIRE SUDDEN REACTIVE IMMEDIATE DELAYED
HAZARD RELEASE OF (ACUTE) (CHRONIC)
PRESSURE HEALTH HEALTH
HAZARD HAZARD
XYLENE 25 - 50 YES. NO. NO. YES. NO.
ETHYLBENZENE 5 - 10 YES. NO. NO. YES. YES.
DISTILLATES 1 - 5 NO. NO. NO. YES. NO.
(PETROLEUM),
HYDROTREATED
HEAVY
NAPHTHENIC
SARA 313:
PRODUCT NAME CAS NUMBER %
FORM R - REPORTING REQUIREMENTS:
XYLENE 1330-20-7 25 - 50
ETHYLBENZENE 100-41-4 5 - 10
SUPPLIER NOTIFICATION:
XYLENE 1330-20-7 25 - 50
ETHYLBENZENE 100-41-4 5 - 10
SARA 313 NOTIFICATIONS MUST NOT BE DETACHED FROM THE SDS AND ANY COPYING
AND REDISTRIBUTION OF THE SDS SHALL INCLUDE COPYING AND REDISTRIBUTION OF
THE NOTICE ATTACHED TO COPIES OF THE SDS SUBSEQUENTLY REDISTRIBUTED.
STATE REGULATIONS:
MASSACHUSETTS:
THE FOLLOWING COMPONENTS ARE LISTED: XYLENE; ETHYL BENZENE
NEW YORK:
THE FOLLOWING COMPONENTS ARE LISTED: XYLENE (MIXED); ETHYLBENZENE
NEW JERSEY:
THE FOLLOWING COMPONENTS ARE LISTED: XYLENES; BENZENE, DIMETHYL-; ETHYL
BENZENE; BENZENE, ETHYL-; MINERAL OIL (UNTREATED AND MILDLY TREATED);
MINERAL OIL (UNTREATED AND MILDLY TREATED); MINERAL OIL (UNTREATED AND
MILDLY TREATED); MINERAL OIL (UNTREATED AND MILDLY TREATED); MINERAL OIL
(UNTREATED AND MILDLY TREATED); MINERAL OIL (UNTREATED AND MILDLY TREATED)
PENNSYLVANIA:
THE FOLLOWING COMPONENTS ARE LISTED: BENZENE, DIMETHYL-; BENZENE, ETHYL-
CALIFORNIA PROP. 65:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
INGREDIENT NAME CANCER REPRODUCTIVE NO SIGNIFICANT MAXIMUM
RISK LEVEL ACCEPTABLE
DOSAGE LEVEL
ETHYLBENZENE YES. NO. 41 (MICRO)G/DAY NO.
(INGESTION)
54 (MICRO)G/DAY
(INHALATION)
CANADA:
CANADIAN LISTS:
CANADIAN NPRI:
THE FOLLOWING COMPONENTS ARE LISTED:
XYLENE (ALL ISOMERS); ETHYLBENZENE; WHITE MINERAL OIL
CEPA TOXIC SUBSTANCES: NONE OF THE COMPONENTS ARE LISTED.
CANADA INVENTORY: ALL COMPONENTS ARE LISTED OR EXEMPTED.
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF
THE CONTROLLED PRODUCTS REGULATIONS AND THE MSDS CONTAINS ALL THE
INFORMATION REQUIRED BY THE CONTROLLED PRODUCTS REGULATIONS.
MEXICO:
CLASSIFICATION:
HEALTH 2
FLAMMABILITY 3
REACTIVITY 0
SPECIAL
INTERNATIONAL REGULATIONS:
INTERNATIONAL LISTS:
AUSTRALIA INVENTORY (AICS): ALL COMPONENTS ARE LISTED OR EXEMPTED.
CHINA INVENTORY (IECSC): ALL COMPONENTS ARE LISTED OR EXEMPTED.
JAPAN INVENTORY: NOT DETERMINED.
KOREA INVENTORY: ALL COMPONENTS ARE LISTED OR EXEMPTED.
MALAYSIA INVENTORY (EHS REGISTER): NOT DETERMINED.
NEW ZEALAND INVENTORY OF CHEMICALS (NZIOC):
ALL COMPONENTS ARE LISTED OR EXEMPTED.
PHILIPPINES INVENTORY (PICCS): ALL COMPONENTS ARE LISTED OR EXEMPTED.
TAIWAN INVENTORY (CSNN): NOT DETERMINED.
EUROPE: NOT DETERMINED.
CHEMICAL WEAPONS CONVENTION LIST SCHEDULE I CHEMICALS: NOT LISTED
CHEMICAL WEAPONS CONVENTION LIST SCHEDULE II CHEMICALS: NOT LISTED
CHEMICAL WEAPONS CONVENTION LIST SCHEDULE III CHEMICALS: NOT LISTED
| SECTION 16. OTHER INFORMATION | |
HAZARDOUS MATERIAL INFORMATION SYSTEM (U.S.A.):
HEALTH 2*
FLAMMABILITY 3
PHYSICAL HAZARDS 0
CAUTION:
HMIS(R*) RATINGS ARE BASED ON A 0-4 RATING SCALE, WITH 0 REPRESENTING
MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING SIGNIFICANT HAZARDS OR RISKS
ALTHOUGH HMIS(R*) RATINGS ARE NOT REQUIRED ON SDSS UNDER 29 CFR 1910.1200,
THE PREPARER MAY CHOOSE TO PROVIDE THEM. HMIS(R*) RATINGS ARE TO BE USED
WITH A FULLY IMPLEMENTED HMIS(R*) PROGRAM. HMIS(R*) IS A REGISTERED MARK OF
THE NATIONAL PAINT & COATINGS ASSOCIATION (NPCA). HMIS(R*) MATERIALS MAY BE
PURCHASED EXCLUSIVELY FROM J. J. KELLER (800) 327-6868.
THE CUSTOMER IS RESPONSIBLE FOR DETERMINING THE PPE CODE FOR THIS MATERIAL.
NATIONAL FIRE PROTECTION ASSOCIATION (U.S.A.):
HEALTH 2
FLAMMABILITY 3
INSTABILITY/REACTIVITY 0
SPECIAL
REPRINTED WITH PERMISSION FROM NFPA 704-2001, IDENTIFICATION OF THE HAZARDS
OF MATERIALS FOR EMERGENCY RESPONSE COPYRIGHT (C)1997, NATIONAL FIRE
PROTECTION ASSOCIATION, QUINCY, MA 02269. THIS REPRINTED MATERIAL IS NOT
THE COMPLETE AND OFFICIAL POSITION OF THE NATIONAL FIRE PROTECTION
ASSOCIATION, ON THE REFERENCED SUBJECT WHICH IS REPRESENTED ONLY BY THE
STANDARD IN ITS ENTIRETY.
COPYRIGHT (C)2001, NATIONAL FIRE PROTECTION ASSOCIATION, QUINCY, MA 02269.
THIS WARNING SYSTEM IS INTENDED TO BE INTERPRETED AND APPLIED ONLY BY
PROPERLY TRAINED INDIVIDUALS TO IDENTIFY FIRE, HEALTH AND REACTIVITY
HAZARDS OF CHEMICALS. THE USER IS REFERRED TO CERTAIN LIMITED NUMBER OF
CHEMICALS WITH RECOMMENDED CLASSIFICATIONS IN NFPA 49 AND NFPA 325, WHICH
WOULD BE USED AS A GUIDELINE ONLY. WHETHER THE CHEMICALS ARE CLASSIFIED BY
NFPA OR NOT, ANYONE USING THE 704 SYSTEMS TO CLASSIFY CHEMICALS DOES SO AT
THEIR OWN RISK.
HISTORY:
DATE OF PRINTING: 5/27/2015.
DATE OF ISSUE/DATE OF REVISION: 5/26/2015.
DATE OF PREVIOUS ISSUE: NO PREVIOUS VALIDATION.
VERSION: 4
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL 73/78:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS, 1973
AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
UN: UNITED NATIONS
REFERENCES: NOT AVAILABLE.
| INDICATES INFORMATION THAT HAS CHANGED FROM PREVIOUSLY ISSUED VERSION.
NOTICE TO READER:
TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS ACCURATE.
HOWEVER, NEITHER THE ABOVE-NAMED SUPPLIER, NOR ANY OF ITS SUBSIDIARIES,
ASSUMES ANY LIABILITY WHATSOEVER FOR THE ACCURACY OR COMPLETENESS OF THE
INFORMATION CONTAINED HEREIN.
FINAL DETERMINATION OF SUITABILITY OF ANY MATERIAL IS THE SOLE
RESPONSIBILITY OF THE USER. ALL MATERIALS MAY PRESENT UNKNOWN HAZARDS AND
SHOULD BE USED WITH CAUTION. ALTHOUGH CERTAIN HAZARDS ARE DESCRIBED HEREIN,
WE CANNOT GUARANTEE THAT THESE ARE THE ONLY HAZARDS THAT EXIST.