| Common Name: | F-224 MARKING FLUID RED |
| Manufacturer: | CARCO |
| SDS Revision Date: | 1/6/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 40LF68 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
CARCO, INC
F-224 MARKING FLUID RED
SDS REVISION DATE: 1/6/2017
| 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
PRODUCT IDENTITY: F-224 MARKING FLUID RED
ALTERNATE NAMES: F-224 MARKING FLUID RED
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
INTENDED USE: SEE TECHNICAL DATA SHEET.
APPLICATION METHOD: SEE TECHNICAL DATA SHEET.
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
COMPANY NAME:
CARCO, INC
10333 SHOEMAKER
P.O. BOX 13859
DETROIT, MICHIGAN, 48213
USA
EMERGENCY:
24 HOUR EMERGENCY TELEPHONE NO.:
CHEMTEL: 1-800-255-3924 (MIS0001475)
INTERNATIONAL: +01-813-248-0585
CUSTOMER SERVICE: CARCO, INC
PHONE: +1 (313) 925-9000
FAX: +1 (313) 925-9602
EMAIL: SALES@CARCOUSA.NET
| 2. HAZARD IDENTIFICATION OF THE PRODUCT | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
COMBUSTIBLE LIQUID; H227: COMBUSTIBLE LIQUID.
SKIN IRRIT. 3; H316: CAUSES MILD SKIN IRRITATION. (NOT ADOPTED BY US OSHA)
2.2. LABEL ELEMENTS:
USING THE TOXICITY DATA LISTED IN SECTION 11 AND 12 THE PRODUCT IS LABELED
AS FOLLOWS.
WARNING:
H227: COMBUSTIBLE LIQUID.
H316: CAUSES MILD SKIN IRRITATION.
[PREVENTION]:
P210:
KEEP AWAY FROM HEAT / SPARKS / OPEN FLAMES / HOT SURFACES - NO SMOKING.
P280: WEAR PROTECTIVE GLOVES / EYE PROTECTION / FACE PROTECTION.
[RESPONSE]:
P332+313:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE / ATTENTION.
[STORAGE]:
P403+235: STORE IN A WELL VENTILATED PLACE. KEEP COOL.
[DISPOSAL]:
P501:
DISPOSE OF CONTENTS / CONTAINER IN ACCORDANCE WITH LOCAL / NATIONAL
REGULATIONS.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES THAT PRESENT A HAZARD WITHIN
THE MEANING OF THE RELEVANT STATE AND FEDERAL HAZARDOUS SUBSTANCES
REGULATIONS.
INGREDIENT/CHEMICAL WEIGHT % GHS CLASSIFICATION NOTES
DESIGNATIONS
(2-METHOXYMETHYLETHOXY) 50 - 75 [1] [2]
PROPANOL
CAS NUMBER: 0034590-94-8
1,2,4-TRIMETHYLBENZEEN 1.0 - 10 FLAM. LIQ. 3; H226 [1][2]
CAS NUMBER: 0000095-63-6 ACUTE TOX. 4; H332
EYE IRRIT. 2; H319
STOT SE 3; H335
SKIN IRRIT. 2; H315
AQUATIC CHRONIC 2; H411
PM ACETATE 1.0 - 10 FLAM. LIQ. 3; H226 [1]
CAS NUMBER: 0000108-65-6
PETROLEUM DISTILLATES, 1.0 - 10 ASP. TOX. 1; H304 [1]
HYDROTREATED LIGHT
CAS NUMBER: 0064742-47-8
ROSIN, FUMERIC 1.0 - 10 [1]
CAS NUMBER: 800680-57-9
1,3,5-TRIMETHYLBENZENE 1.0 - 10 FLAM. LIQ. 3; H226 [1][2]
CAS NUMBER: 0000108-67-8 STOT SE 3; H335
AQUATIC CHRONIC 2; H411
CELLULOSE NITRATE 1.0 - 10 EXPL. 1.1;H201 [1]
CAS NUMBER: 0009004-70-0
[1] SUBSTANCE CLASSIFIED WITH A HEALTH OR ENVIRONMENTAL HAZARD.
[2] SUBSTANCE WITH A WORKPLACE EXPOSURE LIMIT.
[3] PBT-SUBSTANCE OR VPVB-SUBSTANCE.
*THE FULL TEXTS OF THE PHRASES ARE SHOWN IN SECTION 16.
| 4. FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
GENERAL:
IN ALL CASES OF DOUBT, OR WHEN SYMPTOMS PERSIST, SEEK MEDICAL ATTENTION.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
INHALATION:
MOVE THE EXPOSED PERSON TO FRESH AIR AT ONCE. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. GIVE OXYGEN. GET MEDICAL ATTENTION IF ANY
DISCOMFORT CONTINUES
EYES:
MAKE SURE TO REMOVE ANY CONTACT LENSES FROM THE EYES BEFORE RINSING.
PROMPTLY WASH EYES WITH PLENTY OF WATER WHILE LIFTING THE EYE LIDS.
CONTINUE TO RINSE FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION IF
ANY DISCOMFORT CONTINUES.
SKIN:
REMOVE CONTAMINATED CLOTHING. WASH SKIN THOROUGHLY WITH SOAP AND WATER OR
USE A RECOGNIZED SKIN CLEANSER.
INGESTION:
DO NOT INDUCE VOMITING!
IF SWALLOWED, VOMITING MAY OCCUR SPONTANEOUSLY. IF VOMITING OCCURS, KEEP
HEAD BELOW HIPS TO PREVENT ASPIRATION INTO LUNGS. RINSE MOUTH THOROUGHLY.
GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
OVERVIEW:
INGESTION:
MAY CAUSE STOMACH PAIN OR VOMITING. EXPOSURE TO SOLVENT VAPOR
CONCENTRATIONS FROM THE COMPONENT SOLVENTS IN EXCESS OF THE STATED
OCCUPATIONAL EXPOSURE LIMITS MAY RESULT IN ADVERSE HEALTH EFFECTS SUCH AS
MUCOUS MEMBRANE AND RESPIRATORY SYSTEM IRRITATION AND ADVERSE EFFECTS ON
THE KIDNEYS, LIVER AND CENTRAL NERVOUS SYSTEM. SYMPTOMS INCLUDE HEADACHE,
NAUSEA, DIZZINESS, FATIGUE, MUSCULAR WEAKNESS, DROWSINESS AND IN EXTREME
CASES, LOSS OF CONSCIOUSNESS.
REPEATED OR PROLONGED CONTACT WITH THE PREPARATION MAY CAUSE REMOVAL OF
NATURAL FAT FROM THE SKIN RESULTING IN DRYNESS, IRRITATION AND POSSIBLE
NON-ALLERGIC CONTACT DERMATITIS. SOLVENTS MAY ALSO BE ABSORBED THROUGH THE
SKIN. SPLASHES OF LIQUID IN THE EYES MAY CAUSE IRRITATION AND SORENESS WITH
POSSIBLE REVERSIBLE DAMAGE. SEE SECTION 2 FOR FURTHER DETAILS.
SKIN: CAUSES MILD SKIN IRRITATION. (NOT ADOPTED BY US OSHA)
| 5. FIRE-FIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
USE FOAM, EXTINGUISHING POWDER, DRY CHEMICALS, OR CARBON DIOXIDE. WATER MAY
BE INEFFECTIVE. WATER MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
HAZARDOUS DECOMPOSITION: NO HAZARDOUS DECOMPOSITION DATA AVAILABLE.
KEEP AWAY FROM HEAT / SPARKS / OPEN FLAMES / HOT SURFACES - NO SMOKING.
5.3. ADVICE FOR FIRE-FIGHTERS:
IN THE EVENT OF FIRE, WEAR FULL PROTECTIVE CLOTHING AND NIOSH APPROVED
SELF-CONTAINED BREATHING APPARATUS WITH FULL FACE PIECE OPERATED IN THE
PRESSURE DEMAND OR OTHER POSITIVE PRESSURE MODE. MOVE CONTAINER FROM FIRE
AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER TO KEEP FIRE EXPOSED
CONTAINERS COOL AND DISPERSE VAPORS.
ERG GUIDE NO.:
| 6. ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
REMOVE SOURCES OF IGNITION, DO NOT TURN LIGHTS OR UNPROTECTED ELECTRICAL
EQUIPMENT ON OR OFF. IN CASE OF A MAJOR SPILL OR SPILLAGE IN A CONFINED
SPACE EVACUATE THE AREA AND CHECK THAT SOLVENT VAPOR LEVELS ARE BELOW THE
LOWER EXPLOSIVE LIMIT BEFORE RE-ENTERING.
6.2. ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW SPILLS TO ENTER DRAINS OR WATERWAYS.
USE GOOD PERSONAL HYGIENE PRACTICES. WASH HANDS BEFORE EATING, DRINKING,
SMOKING OR USING TOILET. PROMPTLY REMOVE SOILED CLOTHING AND WASH
THOROUGHLY BEFORE REUSE.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
AVOID SPARKS, FLAMES, HEAT AND SMOKING. VENTILATE. WEAR NECESSARY
PROTECTIVE EQUIPMENT. ABSORB IN VERMICULITE, DRY SAND OR EARTH AND PLACE
INTO CONTAINERS.
SMALL SPILL:
USE A NON-COMBUSTIBLE MATERIAL LIKE VERMICULITE, SAND OR EARTH TO SOAK UP
PRODUCT AND PLACE IN A CONTAINER FOR LATER DISPOSAL.
| 7. HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
KEEP IN CONTAINERS LIGHTLY CLOSED IN A COOL, WELL VENTILATED PLACE. DO NOT
STORE WITH OXIDIZING AGENTS OR ACIDS. KEEP IN THE ORIGINAL CONTAINER. AVOID
DIRECT SUNLIGHT
STORE IN ACCORDANCE WITH THE NATIONAL FIRE PROTECTION ASSOCIATION'S
PUBLICATION NFPA 30, FLAMMABLE AND COMBUSTIBLE LIQUIDS CODE. 29 CFR
1910.106 APPLIES TO THE HANDLING, STORAGE, AND USE OF FLAMMABLE AND
COMBUSTIBLE LIQUIDS.
SEE SECTION 2 FOR FURTHER DETAILS. - [PREVENTION]:
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
HANDLE CONTAINERS CAREFULLY TO PREVENT DAMAGE AND SPILLAGE.
STORE IN A COOL DRY AREA, AWAY FROM HEAT, SPARKS AND OPEN FLAME. KEEP
CONTAINERS SEALED WHEN NOT IN USE. STORE OUT OF DIRECT SUNLIGHT.
STORE IN A COOL DRY PLACE.
INCOMPATIBLE MATERIALS: STORE AWAY FROM OXIDIZERS AND ACIDS.
SEE SECTION 2 FOR FURTHER DETAILS. - [STORAGE]:
7.3. SPECIFIC END USE(S): NO DATA AVAILABLE.
| 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
EXPOSURE:
CAS NO. INGREDIENT SOURCE VALUE
0000095-63-6 1,2,4-TRIMETHYLBENZEEN OSHA NO ESTABLISHED LIMIT
ACGIH NO ESTABLISHED LIMIT
NIOSH TWA: 25 PPM (125 MG/M3)
SUPPLIER NO ESTABLISHED LIMIT
0000108-65-6 PM ACETATE OSHA NO ESTABLISHED LIMIT
ACGIH TWA: 50 PPM
STEL: 75 PPM
NIOSH NO ESTABLISHED LIMIT
SUPPLIER NO ESTABLISHED LIMIT
0000108-67-8 1,3,5-TRIMETHYLBENZENE OSHA NO ESTABLISHED LIMIT
ACGIH NO ESTABLISHED LIMIT
NIOSH TWA: 25 PPM (125 MG/M3)
SUPPLIER NO ESTABLISHED LIMIT
0009004-70-0 CELLULOSE NITRATE OSHA NO ESTABLISHED LIMIT
ACGIH NO ESTABLISHED LIMIT
NIOSH NO ESTABLISHED LIMIT
SUPPLIER NO ESTABLISHED LIMIT
0034590-94-8 (2-METHOXYMETHYLETHOXY) OSHA TWA:
PROPANOL 100 PPM (600 MG/M3)
[SKIN]
ACGIH TWA: 100 PPM
STEL: 150 PPM SKIN
NIOSH TWA: 100 PPM (600 MG/M3)
ST:
150 PPM (900 MG/M3)
[SKIN]
SUPPLIER NO ESTABLISHED LIMIT
0064742-47-8 PETROLEUM DISTILLATES, OSHA NO ESTABLISHED LIMIT
HYDROTREATED LIGHT
ACGIH NO ESTABLISHED LIMIT
NIOSH NO ESTABLISHED LIMIT
SUPPLIER RECOMMENDED: 300 PPM PEL
800680-57-9 ROSIN, FUMERIC OSHA NO ESTABLISHED LIMIT
ACGIH NO ESTABLISHED LIMIT
NIOSH NO ESTABLISHED LIMIT
SUPPLIER NO ESTABLISHED LIMIT
CARCINOGEN DATA:
CAS NO. INGREDIENT SOURCE VALUE
0000095-63-6 1,2,4-TRIMETHYLBENZEEN OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0000108-65-6 PM ACETATE OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0000108-67-8 1,3,5-TRIMETHYLBENZENE OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0009004-70-0 CELLULOSE NITRATE OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0034590-94-8 (2-METHOXYMETHYL- OSHA SELECT CARCINOGEN: NO
ETHOXY)PROPANOL
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0064742-47-8 PETROLEUM DISTILLATES, OSHA SELECT CARCINOGEN: NO
HYDROTREATED LIGHT
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
800680-57-9 ROSIN, FUMERIC OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
8.2. EXPOSURE CONTROLS:
RESPIRATORY:
ATMOSPHERIC LEVELS SHOULD BE MAINTAINED BELOW THE EXPOSURE GUIDELINE. WHEN
RESPIRATORY PROTECTION IS REQUIRED FOR CERTAIN OPERATIONS, USE AN APPROVED
AIR-PURIFYING RESPIRATOR.
THE FOLLOWING SHOULD BE EFFECTIVE TYPES OF AIR PURIFYING RESPIRATORS:
ORGANIC VAPOR CARTRIDGE.
EYES:
WEAR SAFETY EYEWEAR, E.G. SAFETY SPECTACLES, GOGGLES OR VISORS TO PROTECT
AGAINST THE SPLASH OF LIQUIDS.
SKIN:
OVERALLS WHICH COVER THE BODY, ARMS AND LEGS SHOULD BE WORN. SKIN SHOULD
NOT BE EXPOSED. ALL PARTS OF THE BODY SHOULD BE WASHED AFTER CONTACT. USE
GLOVES CHEMICALLY RESISTANT TO THIS MATERIAL WHEN PROLONGED OR FREQUENTLY
REPEATED CONTACT COULD OCCUR.
EXAMPLES OF PREFERRED GLOVE BARRIER MATERIALS INCLUDE:
BUTYL RUBBER. POLYETHYLENE/ETHYL VINYL ALCOHOL LAMINATE ("PE/EVAL").
EXAMPLES OF ACCEPTABLE GLOVE BARRIER MATERIALS INCLUDE:
NATURAL RUBBER ("LATEX"). NEOPRENE. NITRILE/BUTADIENE RUBBER ("NITRILE" OR
"NBR"). POLYVINYL CHLORIDE ("PVC" OR "VINYL"). VITON
ENGINEERING CONTROLS:
PROVIDE ADEQUATE VENTILATION. WHERE REASONABLY PRACTICABLE THIS SHOULD BE
ACHIEVED BY THE USE OF LOCAL EXHAUST VENTILATION AND GOOD GENERAL
EXTRACTION. IF THESE ARE NOT SUFFICIENT TO MAINTAIN CONCENTRATIONS OF
PARTICULATES AND ANY VAPOR BELOW OCCUPATIONAL EXPOSURE LIMITS SUITABLE
RESPIRATORY PROTECTION MUST BE WORN.
OTHER WORK PRACTICES:
DO NOT SMOKE, OR DRINK IN WORK AREA. KEEP AWAY FROM FOODSTUFFS AND
BEVERAGES. AVOID CONTACT WITH EYES AND SKIN.
USE GOOD PERSONAL HYGIENE PRACTICES. WASH HANDS BEFORE EATING, DRINKING,
SMOKING OR USING TOILET. PROMPTLY REMOVE SOILED CLOTHING AND WASH
THOROUGHLY BEFORE REUSE.
SEE SECTION 2 FOR FURTHER DETAILS. - [PREVENTION]:
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: COLORED LIQUID
ODOR: SWEET ALCOHOL
ODOR THRESHOLD: NOT MEASURED
PH: NOT MEASURED
MELTING POINT / FREEZING POINT: NOT MEASURED
INITIAL BOILING POINT AND BOILING RANGE:
171 C
340 C
FLASH POINT:
61-63 C
141-145 F METHOD (SETAFLASH)
EVAPORATION RATE (ETHER = 1): 0.03
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
LOWER EXPLOSIVE LIMIT: 1.3
UPPER EXPLOSIVE LIMIT: 13.1
VAPOR PRESSURE (PA): <3MM
VAPOR DENSITY: >3
SPECIFIC GRAVITY: 0.810 G/ML TEMPERATURE (C) 20
SOLUBILITY IN WATER: NOT MEASURED
PARTITION COEFFICIENT N-OCTANOL/WATER (LOG KOW): NOT MEASURED
AUTO-IGNITION TEMPERATURE: NOT MEASURED
DECOMPOSITION TEMPERATURE: NOT MEASURED
VISCOSITY (CST): NOT MEASURED
VOC %:
70-80 WT-%
APPROXIMATELY 5.9 LBS/GAL
WATER SOLUBILITY: 90%
9.2. OTHER INFORMATION: NO OTHER RELEVANT INFORMATION.
| 10. STABILITY AND REACTIVITY | |
10.1. REACTIVITY: HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.2. CHEMICAL STABILITY: STABLE UNDER NORMAL CIRCUMSTANCES.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NO DATA AVAILABLE.
10.4. CONDITIONS TO AVOID: HIGH TEMPERATURES, FIRES, AND INCOMPATIBLES.
10.5. INCOMPATIBLE MATERIALS: STORE AWAY FROM OXIDIZERS AND ACIDS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
NO HAZARDOUS DECOMPOSITION DATA AVAILABLE.
| 11. TOXICOLOGICAL INFORMATION | |
ACUTE TOXICITY:
EXPOSURE TO SOLVENT VAPOR CONCENTRATIONS FROM THE COMPONENT SOLVENTS IN
EXCESS OF THE STATED OCCUPATIONAL EXPOSURE LIMITS MAY RESULT IN ADVERSE
HEALTH EFFECTS SUCH AS MUCOUS MEMBRANE AND RESPIRATORY SYSTEM IRRITATION
AND ADVERSE EFFECTS ON THE KIDNEYS, LIVER AND CENTRAL NERVOUS SYSTEM.
SYMPTOMS INCLUDE HEADACHE, NAUSEA, DIZZINESS, FATIGUE, MUSCULAR WEAKNESS,
DROWSINESS AND IN EXTREME CASES, LOSS OF CONSCIOUSNESS.
REPEATED OR PROLONGED CONTACT WITH THE PREPARATION MAY CAUSE REMOVAL OF
NATURAL FAT FROM THE SKIN RESULTING IN DRYNESS, IRRITATION AND POSSIBLE
NON-ALLERGIC CONTACT DERMATITIS. SOLVENTS MAY ALSO BE ABSORBED THROUGH THE
SKIN. SPLASHES OF LIQUID IN THE EYES MAY CAUSE IRRITATION AND SORENESS WITH
POSSIBLE REVERSIBLE DAMAGE.
INGREDIENT ORAL LD50, MG/KG SKIN LD50, MG/KG
(2-METHOXYMETHYLETHOXY) 3,500.00, RAT - 19,000.00, RABBIT -
PROPANOL - (34590-94-8) CATEGORY: 5 CATEGORY: NA
1,2,4-TRIMETHYLBENZEEN 3,400.00, RAT - 3,160.00, RABBIT -
- (95-63-6) CATEGORY: 5 CATEGORY: 5
PM ACETATE - (108-65-6) 8,532.00, RAT - 5,000.00, RABBIT -
CATEGORY: NA CATEGORY: 5
PETROLEUM DISTILLATES, 5,000.00, RAT - >2,000.00, RABBIT -
HYDROTREATED LIGHT - CATEGORY: 5 CATEGORY: 5
(64742-47-8)
ROSIN, FUMERIC - NO DATA AVAILABLE NO DATA AVAILABLE
(800680-57-9)
1,3,5-TRIMETHYLBENZENE NO DATA AVAILABLE NO DATA AVAILABLE
- (108-67-8)
CELLULOSE NITRATE 5,000.00, MOUSE - NO DATA AVAILABLE
- (9004-70-0) CATEGORY: 5
INGREDIENT INHALATION INHALATION INHALATION
VAPOR LD50, DUST/MIST LD50, GAS LD50,
MG/L/4HR MG/L/4HR PPM
(2-METHOXYMETHYLETHOXY) NO DATA NO DATA NO DATA
PROPANOL AVAILABLE AVAILABLE AVAILABLE
1,2,4-TRIMETHYLBENZEEN 18.00, RAT - NO DATA NO DATA
CATEGORY: 4 AVAILABLE AVAILABLE
PM ACETATE NO DATA NO DATA 4,345.00,
AVAILABLE AVAILABLE RAT -
CATEGORY: NA
PETROLEUM DISTILLATES, NO DATA NO DATA NO DATA
HYDROTREATED LIGHT AVAILABLE AVAILABLE AVAILABLE
ROSIN, FUMERIC NO DATA NO DATA NO DATA
AVAILABLE AVAILABLE AVAILABLE
1,3,5-TRIMETHYLBENZENE 24.00, RAT - NO DATA NO DATA
CATEGORY: NA AVAILABLE AVAILABLE
CELLULOSE NITRATE NO DATA NO DATA NO DATA
AVAILABLE AVAILABLE AVAILABLE
NOTE:
WHEN NO ROUTE SPECIFIC LD50 DATA IS AVAILABLE FOR AN ACUTE TOXIN, THE
CONVERTED ACUTE TOXICITY POINT ESTIMATE WAS USED IN THE CALCULATION OF
THE PRODUCT'S ATE (ACUTE TOXICITY ESTIMATE).
CLASSIFICATION CATEGORY HAZARD DESCRIPTION
ACUTE TOXICITY (ORAL) NOT APPLICABLE
ACUTE TOXICITY (DERMAL) NOT APPLICABLE
ACUTE TOXICITY (INHALATION) NOT APPLICABLE
SKIN CORROSION/IRRITATION 3 CAUSES MILD SKIN
IRRITATION. (NOT ADOPTED BY
US OSHA)
SERIOUS EYE DAMAGE/IRRITATION NOT APPLICABLE
RESPIRATORY SENSITIZATION NOT APPLICABLE
SKIN SENSITIZATION NOT APPLICABLE
GERM CELL MUTAGENICITY NOT APPLICABLE
CARCINOGENICITY NOT APPLICABLE
REPRODUCTIVE TOXICITY NOT APPLICABLE
STOT-SINGLE EXPOSURE NOT APPLICABLE
STOT-REPEATED EXPOSURE NOT APPLICABLE
ASPIRATION HAZARD NOT APPLICABLE
| 12. ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
NO ADDITIONAL INFORMATION PROVIDED FOR THIS PRODUCT. SEE SECTION 3 FOR
CHEMICAL SPECIFIC DATA.
AQUATIC ECOTOXICITY:
INGREDIENT 96 HR LC50 48 HR EC50 ERC50 ALGAE,
FISH, MG/L CRUSTACEA, MG/L MG/L
(2-METHOXYMETHYLETHOXY) 10,000.00, 1,919.00, 969.00
PROPANOL - (34590-94-8) PIMEPHALES DAPHNIA MAGNA (72 HR), ALGAE
PROMELAS
1,2,4-TRIMETHYLBENZEEN 7.72, 3.60, DAPHNIA NOT AVAILABLE
- (95-63-6) PIMEPHALES MAGNA
PROMELAS
PM ACETATE - (108-65-6) 100.00, 500.00, DAPHNIA NOT AVAILABLE
SALMO MAGNA
GAIRDNERI
PETROLEUM DISTILLATES, NOT AVAILABLE NOT AVAILABLE NOT AVAILABLE
HYDROTREATED LIGHT -
(64742-47-8)
ROSIN, FUMERIC - NOT AVAILABLE NOT AVAILABLE NOT AVAILABLE
(800680-57-9)
1,3,5-TRIMETHYLBENZENE 12.52, 6.00, DAPHNIA 25.00 (48 HR),
- (108-67-8) CARASSIUS MAGNA SCENEDESMUS
AURATUS SUBSPICATUS
CELLULOSE NITRATE NOT AVAILABLE NOT AVAILABLE 579.00 (96 HR),
- (9004-70-0) PSEUDOKIR-
CHNERIELLA
SUBCAPITATA
12.2. PERSISTENCE AND DEGRADABILITY:
THERE IS NO DATA AVAILABLE ON THE PREPARATION ITSELF.
12.3. BIOACCUMULATIVE POTENTIAL: NOT MEASURED
12.4. MOBILITY IN SOIL: NO DATA AVAILABLE.
12.5. RESULTS OF PBT AND VPVB ASSESSMENT:
THIS PRODUCT CONTAINS NO PBT/VPVB CHEMICALS.
12.6. OTHER ADVERSE EFFECTS: NO DATA AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
DO NOT ALLOW INTO DRAINS OR WATER COURSES. WASTES AND EMPTIED CONTAINERS
SHOULD BE DISPOSED OF IN ACCORDANCE WITH REGULATIONS MADE UNDER THE CONTROL
OF POLLUTION ACT AND THE ENVIRONMENTAL PROTECTION ACT.
USING INFORMATION PROVIDED IN THIS DATA SHEET ADVICE SHOULD BE OBTAINED
FROM THE WASTE REGULATION AUTHORITY, WHETHER THE SPECIAL WASTE REGULATIONS
APPLY.
| 14. TRANSPORT INFORMATION | |
DOT (DOMESTIC IMO / IMDG (OCEAN ICAO/IATA
SURFACE TRANSPORTATION)
TRANSPORTATION)
14.1. UN NUMBER NOT APPLICABLE NOT REGULATED NOT REGULATED
14.2. UN PROPER NOT REGULATED NOT REGULATED NOT REGULATED
SHIPPING NAME
14.3. TRANSPORT DOT HAZARD CLASS: IMDG: AIR CLASS:
HAZARD CLASS(ES) NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE
DOT LABEL: SUB CLASS: NOT APPLICABLE
NOT APPLICABLE
EMS:
NOT APPLICABLE
14.4. PACKING GROUP NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE
14.5. ENVIRONMENTAL HAZARDS:
IMDG:
MARINE POLLUTANT: NO
14.6. SPECIAL PRECAUTIONS FOR USER: NO FURTHER INFORMATION
14.7. TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC
CODE: NOT APPLICABLE
| 15. REGULATORY INFORMATION | |
REGULATORY OVERVIEW:
THE REGULATORY DATA IN SECTION 15 IS NOT INTENDED TO BE ALL-INCLUSIVE, ONLY
SELECTED REGULATIONS ARE REPRESENTED. ALL COMPONENTS OF THIS MATERIAL ARE
EITHER LISTED OR EXEMPT FROM LISTING ON THE TSCA INVENTORY.
NFPA RANKINGS:
2
2
0
WHMIS CLASSIFICATION: B3
B - FLAMMABLE AND COMBUSTIBLE MATERIAL
US EPA TIER II HAZARDS:
FIRE: YES
SUDDEN RELEASE OF PRESSURE: NO
REACTIVE: NO
IMMEDIATE (ACUTE): YES
DELAYED (CHRONIC): NO
EPCRA 311/312 CHEMICALS AND RQS: (NO PRODUCT INGREDIENTS LISTED)
EPCRA 302 EXTREMELY HAZARDOUS: (NO PRODUCT INGREDIENTS LISTED)
EPCRA 313 TOXIC CHEMICALS:
(2-METHOXYMETHYLETHOXY)PROPANOL
1,2,4-TRIMETHYLBENZEEN
PROPOSITION 65 - CARCINOGENS (>0.0%): (NO PRODUCT INGREDIENTS LISTED)
PROPOSITION 65 - DEVELOPMENTAL TOXINS (>0.0%):
(NO PRODUCT INGREDIENTS LISTED)
PROPOSITION 65 - FEMALE REPRO TOXINS (>0.0%):
(NO PRODUCT INGREDIENTS LISTED)
PROPOSITION 65 - MALE REPRO TOXINS (>0.0%):
(NO PRODUCT INGREDIENTS LISTED)
N.J. RTK SUBSTANCES (>1%):
(2-METHOXYMETHYLETHOXY)PROPANOL
1,2,4-TRIMETHYLBENZEEN
CELLULOSE NITRATE
PENN RTK SUBSTANCES (>1%):
(2-METHOXYMETHYLETHOXY)PROPANOL
1,2,4-TRIMETHYLBENZEEN
CELLULOSE NITRATE
| 16. OTHER INFORMATION | |
THE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED UPON DATA
BELIEVED TO BE CORRECT. HOWEVER, NO GUARANTEE OR WARRANTY OF ANY KIND,
EXPRESSED OR IMPLIED, IS MADE WITH RESPECT TO THE INFORMATION CONTAINED
HEREIN. WE ACCEPT NO RESPONSIBILITY AND DISCLAIM ALL LIABILITY FOR ANY
HARMFUL EFFECTS WHICH MAY BE CAUSED BY EXPOSURE TO OUR PRODUCTS.
CUSTOMERS/USERS OF THIS PRODUCT MUST COMPLY WITH ALL APPLICABLE HEALTH
AND SAFETY LAWS, REGULATIONS, AND ORDERS.
THE FULL TEXT OF THE PHRASES APPEARING IN SECTION 3 IS:
H201: EXPLOSIVE; MASS EXPLOSION HAZARD.
H226: FLAMMABLE LIQUID AND VAPOR.
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H332: HARMFUL IF INHALED.
H335: MAY CAUSE RESPIRATORY IRRITATION.
H411: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
THIS IS THE FIRST VERSION IN THE GHS SDS FORMAT. LISTINGS OF CHANGES FROM
PREVIOUS VERSIONS IN OTHER FORMATS ARE NOT APPLICABLE.
THIS PRODUCT IS ROHS AND REACH COMPLIANT. IT DOES NOT CONTAIN ANY OF THE
ROHS LISTED SUBSTANCES. IT DOES NOT CONTAIN ANY CHEMICAL FROM THE CANDIDATE
LIST OF SUBSTANCES OF VERY HIGH CONCERN (SVHC), ANNEX XIV, OR ANNEX XVII OF
REACH.
THIS INFORMATION IS BASED ON OUR PRESENT KNOWLEDGE. HOWEVER, IT DOES NOT
CONSTITUTE A GUARANTEE FOR ANY SPECIFIC PRODUCT PROPERTIES.
CARCO URGES THE RECIPIENT OF THIS SDS TO STUDY IT CAREFULLY AND CONSULT
APPROPRIATE EXPERTISE, AS NECESSARY OR APPROPRIATE, TO BECOME AWARE OF AND
UNDERSTAND THE DATA CONTAINED IN THIS SDS AND ANY HAZARDS ASSOCIATED WITH
THE PRODUCT. THE INFORMATION HEREIN IS PROVIDED IN GOOD FAITH AND BELIEVED
TO BE ACCURATE AS OF THE EFFECTIVE DATE SHOWN ABOVE. THE USE OF THIS
PRODUCT IS BEYOND THE CONTROL CARCO OR IT'S DISTRIBUTOR, THEREFORE, NO
WARRANTY, EXPRESS OR IMPLIED, IS GIVEN. REGULATORY REQUIREMENTS ARE SUBJECT
TO CHANGE AND MAY DIFFER BETWEEN VARIOUS LOCATIONS. IT IS THE
BUYER'S/USER'S RESPONSIBILITY TO ENSURE THAT HIS ACTIVITIES COMPLY WITH ALL
FEDERAL, STATE, PROVINCIAL OR LOCAL LAWS. THE INFORMATION PRESENTED HERE
PERTAINS ONLY TO THE PRODUCT AS SHIPPED. SINCE CONDITIONS FOR USE OF THE
PRODUCT ARE NOT UNDER THE CONTROL OF THE MANUFACTURER, IT IS THE
BUYER'S/USER'S DUTY TO DETERMINE THE CONDITIONS NECESSARY FOR THE SAFE USE
OF THIS PRODUCT.