| Common Name: | MARKING FLUID BLACK |
| Manufacturer: | CARCO |
| SDS Revision Date: | 1/10/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 40LF81 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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CARCO, INC
SAFETY DATA SHEET
MM-150 MARKING FLUID BLACK
SDS REVISION DATE: 1/10/2017
| 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
PRODUCT IDENTITY: MARKING FLUID BLACK
ALTERNATE NAMES: MM-150 MARKING FLUID BLACK
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
INTENDED USE: SEE TECHNICAL DATA SHEET.
APPLICATION METHOD: SEE TECHNICAL DATA SHEET.
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
COMPANY NAME:
CARCO, INC
10333 SHOEMAKER
P.O. BOX 13859
DETROIT, MICHIGAN 48213
USA
EMERGENCY:
24 HOUR EMERGENCY TELEPHONE NO.:
CHEMTEL: 1-800-255-3924 (MIS0001475)
INTERNATIONAL: +01-813-248-0585
CUSTOMER SERVICE: CARCO, INC
PHONE: +1 (313) 925-9000
FAX: +1 (313) 925-9602
EMAIL: SALES@CARCOUSA.NET
| 2. HAZARD IDENTIFICATION OF THE PRODUCT | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAM. LIQ. 2; H225: HIGHLY FLAMMABLE LIQUID AND VAPOR.
EYE IRRIT. 2; H319: CAUSES SERIOUS EYE IRRITATION.
STOT SE 3; H336: MAY CAUSE DROWSINESS OR DIZZINESS.
2.2. LABEL ELEMENTS:
USING THE TOXICITY DATA LISTED IN SECTION 11 AND 12 THE PRODUCT IS LABELED
AS FOLLOWS.
FLAME
EXCLAMATION MARK
DANGER
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR.
H319: CAUSES SERIOUS EYE IRRITATION.
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
[PREVENTION]:
P210:
KEEP AWAY FROM HEAT / SPARKS / OPEN FLAMES / HOT SURFACES - NO SMOKING.
P241: USE EXPLOSION-PROOF ELECTRICAL / VENTILATING / LIGHT / EQUIPMENT.
P264: WASH THOROUGHLY AFTER HANDLING.
P280: WEAR PROTECTIVE GLOVES / EYE PROTECTION / FACE PROTECTION.
[RESPONSE]:
P303+361+353:
IF ON SKIN (OR HAIR):
REMOVE / TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER / SHOWER.
P305+351+338:
IF IN EYES:
RINSE CONTINUOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES
IF PRESENT AND EASY TO DO - CONTINUE RINSING.
P337+313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE / ATTENTION.
P370+378:
IN CASE OF FIRE:
USE EXTINGUISHING MEDIA LISTED IN SECTION 5 OF SDS FOR EXTINCTION.
[STORAGE]:
P403+233:
STORE IN A WELL VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
[DISPOSAL]:
P501:
DISPOSE OF CONTENTS / CONTAINER IN ACCORDANCE WITH LOCAL / NATIONAL
REGULATIONS.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES THAT PRESENT A HAZARD WITHIN
THE MEANING OF THE RELEVANT STATE AND FEDERAL HAZARDOUS SUBSTANCES
REGULATIONS.
INGREDIENT/CHEMICAL DESIGNATIONS WEIGHT % GHS CLASSIFICATION NOTES
ISOPROPYL ALCOHOL 50 - 75 FLAM. LIQ. 2; H225 [1] [2]
CAS NUMBER: 0000067-63-0 EYE IRRIT. 2; H319
STOT SE 3; H336
1-METHOXY-2-PROPANOL 10 - 25 FLAM. LIQ. 3; H226 [1][2]
CAS NUMBER: 0000107-98-2 STOT SE 3; H336
ETHANOL 1.0 - 10 FLAM. LIQ. 2; H225 [1][2]
CAS NUMBER: 0000064-17-5
ETHYL ACETATE 1.0 - 10 FLAM. LIQ. 2; H225 [1][2]
CAS NUMBER: 0000141-78-6 EYE IRRIT. 2; H319
STOT SE 3; H336
CARBON BLACK 1.0 - 10 [1][2]
CAS NUMBER: 0001333-86-4
CELLULOSE NITRATE 1.0 - 10 EXPL. 1.1; H201 [1]
CAS NUMBER: 0009004-70-0
ROSIN, FUMERIC 1.0 - 10 [1]
CAS NUMBER: 800680-57-9
ACETIC ACID, 1-METHYLETHYL ESTER 1.0 - 10 FLAM. LIQ. 2; H225 [1][2]
CAS NUMBER: 0000108-21-4 EYE IRRIT. 2; H319
STOT SE 3; H336
[1] SUBSTANCE CLASSIFIED WITH A HEALTH OR ENVIRONMENTAL HAZARD.
[2] SUBSTANCE WITH A WORKPLACE EXPOSURE LIMIT.
[3] PBT-SUBSTANCE OR VPVB-SUBSTANCE.
*THE FULL TEXTS OF THE PHRASES ARE SHOWN IN SECTION 16.
| 4. FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
GENERAL IN ALL CASES OF DOUBT, OR WHEN SYMPTOMS PERSIST, SEEK MEDICAL
ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
INHALATION:
MOVE THE EXPOSED PERSON TO FRESH AIR AT ONCE. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. GIVE OXYGEN. GET MEDICAL ATTENTION IF ANY
DISCOMFORT CONTINUES EYES MAKE SURE TO REMOVE ANY CONTACT LENSES FROM
THE EYES BEFORE RINSING. PROMPTLY WASH EYES WITH PLENTY OF WATER WHILE
LIFTING THE EYE LIDS. CONTINUE TO RINSE FOR AT LEAST 15 MINUTES. GET
MEDICAL ATTENTION IF ANY DISCOMFORT CONTINUES.
SKIN:
REMOVE CONTAMINATED CLOTHING. WASH SKIN THOROUGHLY WITH SOAP AND WATER
OR USE A RECOGNIZED SKIN CLEANSER.
INGESTION:
DO NOT INDUCE VOMITING!
IF SWALLOWED, VOMITING MAY OCCUR SPONTANEOUSLY. IF VOMITING OCCURS, KEEP
HEAD BELOW HIPS TO PREVENT ASPIRATION INTO LUNGS. RINSE MOUTH THOROUGHLY.
GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
OVERVIEW INGESTION:
MAY CAUSE STOMACH PAIN OR VOMITING. EXPOSURE TO SOLVENT VAPOR
CONCENTRATIONS FROM THE COMPONENT SOLVENTS IN EXCESS OF THE STATED
OCCUPATIONAL EXPOSURE LIMITS MAY RESULT IN ADVERSE HEALTH EFFECTS SUCH AS
MUCOUS MEMBRANE AND RESPIRATORY SYSTEM IRRITATION AND ADVERSE EFFECTS ON
THE KIDNEYS, LIVER AND CENTRAL NERVOUS SYSTEM. SYMPTOMS INCLUDE HEADACHE,
NAUSEA, DIZZINESS, FATIGUE, MUSCULAR WEAKNESS, DROWSINESS AND IN EXTREME
CASES, LOSS OF CONSCIOUSNESS.
REPEATED OR PROLONGED CONTACT WITH THE PREPARATION MAY CAUSE REMOVAL OF
NATURAL FAT FROM THE SKIN RESULTING IN DRYNESS, IRRITATION AND POSSIBLE
NON-ALLERGIC CONTACT DERMATITIS. SOLVENTS MAY ALSO BE ABSORBED THROUGH THE
SKIN. SPLASHES OF LIQUID IN THE EYES MAY CAUSE IRRITATION AND SORENESS
WITH POSSIBLE REVERSIBLE DAMAGE. SEE SECTION 2 FOR FURTHER DETAILS.
INHALATION: MAY CAUSE DROWSINESS OR DIZZINESS.
EYES: CAUSES SERIOUS EYE IRRITATION.
| 5. FIRE-LIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
USE FOAM, EXTINGUISHING POWDER, DRY CHEMICALS, OR CARBON DIOXIDE. WATER
MAY BE INEFFECTIVE. WATER MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS
COOL.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
HAZARDOUS DECOMPOSITION: NONE
KEEP AWAY FROM HEAT / SPARKS / OPEN FLAMES / HOT SURFACES - NO SMOKING.
USE EXPLOSION-PROOF ELECTRICAL / VENTILATING / LIGHT / EQUIPMENT.
5.3. ADVICE FOR FIRE-FIGHTERS:
IN THE EVENT OF FIRE, WEAR FULL PROTECTIVE CLOTHING AND NIOSH APPROVED
SELF-CONTAINED BREATHING APPARATUS WITH FULL FACE PIECE OPERATED IN THE
PRESSURE DEMAND OR OTHER POSITIVE PRESSURE MODE. MOVE CONTAINER FROM FIRE
AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER TO KEEP FIRE EXPOSED
CONTAINERS COOL AND DISPERSE VAPORS.
ERG GUIDE NO.: 129
| 6. ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
REMOVE SOURCES OF IGNITION, DO NOT TURN LIGHTS OR UNPROTECTED ELECTRICAL
EQUIPMENT ON OR OFF. IN CASE OF A MAJOR SPILL OR SPILLAGE IN A CONFINED
SPACE EVACUATE THE AREA AND CHECK THAT SOLVENT VAPOR LEVELS ARE BELOW THE
LOWER EXPLOSIVE LIMIT BEFORE RE-ENTERING.
6.2. ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW SPILLS TO ENTER DRAINS OR WATERWAYS.
USE GOOD PERSONAL HYGIENE PRACTICES. WASH HANDS BEFORE EATING, DRINKING,
SMOKING OR USING TOILET. PROMPTLY REMOVE SOILED CLOTHING AND WASH
THOROUGHLY BEFORE REUSE.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
AVOID SPARKS, FLAMES, HEAT AND SMOKING. VENTILATE. WEAR NECESSARY
PROTECTIVE EQUIPMENT. ABSORB IN VERMICULITE, DRY SAND OR EARTH AND PLACE
INTO CONTAINERS.
SMALL SPILL:
USE A NON-COMBUSTIBLE MATERIAL LIKE VERMICULITE, SAND OR EARTH TO SOAK UP
PRODUCT AND PLACE IN A CONTAINER FOR LATER DISPOSAL.
| 7. HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
KEEP IN CONTAINERS LIGHTLY CLOSED IN A COOL, WELL VENTILATED PLACE. DO NOT
STORE WITH OXIDIZING AGENTS OR ACIDS. KEEP IN THE ORIGINAL CONTAINER. AVOID
DIRECT SUNLIGHT
STORE IN ACCORDANCE WITH THE NATIONAL FIRE PROTECTION ASSOCIATION'S
PUBLICATION NFPA 30, FLAMMABLE AND COMBUSTIBLE LIQUIDS CODE. 29 CFR
1910.106 APPLIES TO THE HANDLING, STORAGE, AND USE OF FLAMMABLE AND
COMBUSTIBLE LIQUIDS.
SEE SECTION 2 FOR FURTHER DETAILS. - [PREVENTION]:
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
HANDLE CONTAINERS CAREFULLY TO PREVENT DAMAGE AND SPILLAGE.
STORE IN A COOL DRY AREA, AWAY FROM HEAT, SPARKS AND OPEN FLAME. KEEP
CONTAINERS SEALED WHEN NOT IN USE. STORE OUT OF DIRECT SUNLIGHT.
STORE IN A COOL DRY PLACE.
INCOMPATIBLE MATERIALS: STORE AWAY FROM OXIDIZERS AND ACIDS.
SEE SECTION 2 FOR FURTHER DETAILS. - [STORAGE]:
7.3. SPECIFIC END USE(S): NO DATA AVAILABLE.
| 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
EXPOSURE:
CAS NO. INGREDIENT SOURCE VALUE
0000064-17-5 ETHANOL OSHA TWA: 1000 PPM (1900 MG/M3)
ACGIH STEL: 1000 PPM REVISED 2009,
NIOSH TWA: 1000 PPM (1900 MG/M3)
SUPPLIER NO ESTABLISHED LIMIT
0000067-63-0 ISOPROPYL ALCOHOL OSHA TWA: 400 PPM (980 MG/M3)
STEL: 500 PPM
ACGIH TWA: 200 PPM
STEL: 400 PPM REVISED 2003,
NIOSH TWA: 400 PPM (980 MG/M3)
ST: 500 PPM (1225 MG/M3)
SUPPLIER NO ESTABLISHED LIMIT
0000107-98-2 1-METHOXY- OSHA NO ESTABLISHED LIMIT
2-PROPANOL
ACGIH TWA: 50 PPM
STEL: 75 PPM
NIOSH TWA: 100 PPM (360 MG/M3)
ST: 150 PPM (540 MG/M3)
SUPPLIER NO ESTABLISHED LIMIT
0000108-21-4 ACETIC ACID, OSHA TWA: 250 PPM (950 MG/M3)
1-METHYLETHYL
ESTER ACGIH TWA: 100 PPM
STEL: 200 PPM REVISED 2003,
NIOSH NO ESTABLISHED RELS
SUPPLIER NO ESTABLISHED LIMIT
0000141-78-6 ETHYL ACETATE OSHA TWA: 400 PPM (1400 MG/M3)
ACGIH TWA: 150 PPM
NIOSH TWA 400 PPM (1400 MG/M3)
SUPPLIER NO ESTABLISHED LIMIT
0001333-86-4 CARBON BLACK OSHA TWA: 3.5 MG/M3
ACGIH TWA: 3 MG/M32B, REVISED 2011,
NIOSH TWA: 3.5 MG/M3 Ca
TWA:
0.1 MG PAHS/M3 [IN PRESENCE
OF POLYCYCLIC AROMATIC
HYDROCARBONS (PAHS)]
SUPPLIER NO ESTABLISHED LIMIT
0009004-70-0 CELLULOSE NITRATE OSHA NO ESTABLISHED LIMIT
ACGIH NO ESTABLISHED LIMIT
NIOSH NO ESTABLISHED LIMIT
SUPPLIER NO ESTABLISHED LIMIT
800680-57-9 ROSIN, FUMERIC OSHA NO ESTABLISHED LIMIT
ACGIH NO ESTABLISHED LIMIT
NIOSH NO ESTABLISHED LIMIT
SUPPLIER NO ESTABLISHED LIMIT
CARCINOGEN DATA:
CAS NO. INGREDIENT SOURCE VALUE
0000064-17-5 ETHANOL OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: YES
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0000067-63-0 ISOPROPYL ALCOHOL OSHA SELECT CARCINOGEN: NO
NTP NOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: YES
GROUP 4: NO
0000107-98-2 1-METHOXY- OSHA SELECT CARCINOGEN: NO
2-PROPANOL
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0000108-21-4 ACETIC ACID, OSHA SELECT CARCINOGEN: NO
1-METHYLETHYL
ESTER NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0000141-78-6 ETHYL ACETATE OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0001333-86-4 CARBON BLACK OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: YES
GROUP 3: NO
GROUP 4: NO
0009004-70-0 CELLULOSE NITRATE OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
800680-57-9 ROSIN, FUMERIC OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
8.2. EXPOSURE CONTROLS:
RESPIRATORY:
ATMOSPHERIC LEVELS SHOULD BE MAINTAINED BELOW THE EXPOSURE GUIDELINE. WHEN
RESPIRATORY PROTECTION IS REQUIRED FOR CERTAIN OPERATIONS, USE AN APPROVED
AIR-PURIFYING RESPIRATOR. THE FOLLOWING SHOULD BE EFFECTIVE TYPES OF AIR
PURIFYING RESPIRATORS: ORGANIC VAPOR CARTRIDGE.
EYES:
WEAR SAFETY EYEWEAR, E.G. SAFETY SPECTACLES, GOGGLES OR VISORS TO PROTECT
AGAINST THE SPLASH OF LIQUIDS.
SKIN:
OVERALLS WHICH COVER THE BODY, ARMS AND LEGS SHOULD BE WORN. SKIN SHOULD
NOT BE EXPOSED. ALL PARTS OF THE BODY SHOULD BE WASHED AFTER CONTACT. USE
GLOVES CHEMICALLY RESISTANT TO THIS MATERIAL WHEN PROLONGED OR FREQUENTLY
REPEATED CONTACT COULD OCCUR.
EXAMPLES OF PREFERRED GLOVE BARRIER MATERIALS INCLUDE:
BUTYL RUBBER. POLYETHYLENE/ETHYL VINYL ALCOHOL LAMINATE ("PE/EVAL").
EXAMPLES OF ACCEPTABLE GLOVE BARRIER MATERIALS INCLUDE:
NATURAL RUBBER ("LATEX"). NEOPRENE. NITRILE/BUTADIENE RUBBER ("NITRILE" OR
"NBR"). POLYVINYL CHLORIDE ("PVC" OR "VINYL"). VITON
ENGINEERING CONTROLS:
PROVIDE ADEQUATE VENTILATION. WHERE REASONABLY PRACTICABLE THIS SHOULD BE
ACHIEVED BY THE USE OF LOCAL EXHAUST VENTILATION AND GOOD GENERAL
EXTRACTION. IF THESE ARE NOT SUFFICIENT TO MAINTAIN CONCENTRATIONS OF
PARTICULATES AND ANY VAPOR BELOW OCCUPATIONAL EXPOSURE LIMITS SUITABLE
RESPIRATORY PROTECTION MUST BE WORN.
OTHER WORK PRACTICES:
DO NOT SMOKE, OR DRINK IN WORK AREA. KEEP AWAY FROM FOODSTUFFS AND
BEVERAGES. AVOID CONTACT WITH EYES AND SKIN.
USE GOOD PERSONAL HYGIENE PRACTICES. WASH HANDS BEFORE EATING, DRINKING,
SMOKING OR USING TOILET. PROMPTLY REMOVE SOILED CLOTHING AND WASH
THOROUGHLY BEFORE REUSE.
SEE SECTION 2 FOR FURTHER DETAILS. - [PREVENTION]:
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: COLORED LIQUID
ODOR: SWEET ALCOHOL
ODOR THRESHOLD: NOT MEASURED
PH: NOT MEASURED
MELTING POINT / FREEZING POINT: NOT MEASURED
INITIAL BOILING POINT AND BOILING RANGE:
82 C
160 F
FLASH POINT:
13-15C
55-60F
METHOD (SETAFLASH)
EVAPORATION RATE (ETHER = 1): 1.5
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
LOWER EXPLOSIVE LIMIT: 3.0
UPPER EXPLOSIVE LIMIT: 19.0
VAPOR PRESSURE (PA): 4.16 KPA
TEMPERATURE (C): 20
VAPOR DENSITY: >2
SPECIFIC GRAVITY: 0.95
SOLUBILITY IN WATER: 80%
PARTITION COEFFICIENT N-OCTANOL/WATER (LOG KOW): NOT MEASURED
AUTO-IGNITION TEMPERATURE: NOT MEASURED
DECOMPOSITION TEMPERATURE: NOT MEASURED
VISCOSITY (CST): NOT MEASURED
VOC %:
75 WT-%: 90% VOL APPROXIMATELY 6.0 LBS/GAL
9.2. OTHER INFORMATION: NO OTHER RELEVANT INFORMATION.
| 10. STABILITY AND REACTIVITY | |
10.1. REACTIVITY: HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.2. CHEMICAL STABILITY: STABLE UNDER NORMAL CIRCUMSTANCES.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NO DATA AVAILABLE.
10.4. CONDITIONS TO AVOID: HIGH TEMPERATURES, FIRES, AND INCOMPATIBLES.
10.5. INCOMPATIBLE MATERIALS: STORE AWAY FROM OXIDIZERS AND ACIDS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS: NONE
| 11. TOXICOLOGICAL INFORMATION | |
ACUTE TOXICITY:
EXPOSURE TO SOLVENT VAPOR CONCENTRATIONS FROM THE COMPONENT SOLVENTS IN
EXCESS OF THE STATED OCCUPATIONAL EXPOSURE LIMITS MAY RESULT IN ADVERSE
HEALTH EFFECTS SUCH AS MUCOUS MEMBRANE AND RESPIRATORY SYSTEM IRRITATION
AND ADVERSE EFFECTS ON THE KIDNEYS, LIVER AND CENTRAL NERVOUS SYSTEM.
SYMPTOMS INCLUDE HEADACHE, NAUSEA, DIZZINESS, FATIGUE, MUSCULAR WEAKNESS,
DROWSINESS AND IN EXTREME CASES, LOSS OF CONSCIOUSNESS.
REPEATED OR PROLONGED CONTACT WITH THE PREPARATION MAY CAUSE REMOVAL OF
NATURAL FAT FROM THE SKIN RESULTING IN DRYNESS, IRRITATION AND POSSIBLE
NON-ALLERGIC CONTACT DERMATITIS. SOLVENTS MAY ALSO BE ABSORBED THROUGH
THE SKIN. SPLASHES OF LIQUID IN THE EYES MAY CAUSE IRRITATION AND SORENESS
WITH POSSIBLE REVERSIBLE DAMAGE.
INGREDIENT ORAL LD50, SKIN LD50,
MG/KG MG/KG
ISOPROPYL ALCOHOL - 4,710.00, RAT - 12,800.00, RAT -
(67-63-0) CATEGORY: 5 CATEGORY: NA
1-METHOXY-2-PROPANOL - 5,000.00, RAT - 13,000.00, RABBIT -
(107-98-2) CATEGORY: 5 CATEGORY: NA
ETHANOL - (64-17-5) 7,060.00, RAT - 20,000.00, RABBIT -
CATEGORY: NA CATEGORY: NA
ETHYL ACETATE - 5,600.00, RAT - 18,000.00, RABBIT -
(141-78-6) CATEGORY: NA CATEGORY: NA
CARBON BLACK - 8,000.00, RAT - NO DATA AVAILABLE
(1333-86-4) CATEGORY: NA
CELLULOSE NITRATE - 5,000.00, MOUSE - NO DATA AVAILABLE
(9004-70-0) CATEGORY: 5
ROSIN, FUMERIC - NO DATA AVAILABLE NO DATA AVAILABLE
(800680-57-9)
ACETIC ACID, 1- 6,750.00, RAT - 20,000.00, RABBIT -
METHYLETHYL ESTER - CATEGORY: NA CATEGORY: NA
(108-21-4)
INGREDIENT INHALATION INHALATION INHALATION
VAPOR LD50, DUST/MIST LD50, GAS LD50,
MG/L/4HR MG/L/4HR PPM
ISOPROPYL ALCOHOL 72.60, RAT - NO DATA NO DATA
CATEGORY: NA AVAILABLE AVAILABLE
1-METHOXY-2-PROPANOL NO DATA NO DATA NO DATA
AVAILABLE AVAILABLE AVAILABLE
ETHANOL 124.70, RAT - NO DATA NO DATA
CATEGORY: NA AVAILABLE AVAILABLE
ETHYL ACETATE 58.60, RAT - NO DATA NO DATA
CATEGORY: NA AVAILABLE AVAILABLE
CARBON BLACK NO DATA NO DATA NO DATA
AVAILABLE AVAILABLE AVAILABLE
CELLULOSE NITRATE NO DATA NO DATA NO DATA
AVAILABLE AVAILABLE AVAILABLE
ROSIN, FUMERIC NO DATA NO DATA NO DATA
AVAILABLE AVAILABLE AVAILABLE
ACETIC ACID, 1- 17,129.60, NO DATA NO DATA
METHYLETHYL ESTER RABBIT - AVAILABLE AVAILABLE
CATEGORY: NA
NOTE:
WHEN NO ROUTE SPECIFIC LD50 DATA IS AVAILABLE FOR AN ACUTE TOXIN, THE
CONVERTED ACUTE TOXICITY POINT ESTIMATE WAS USED IN THE CALCULATION OF
THE PRODUCT'S ATE (ACUTE TOXICITY ESTIMATE).
CLASSIFICATION CATEGORY HAZARD DESCRIPTION
ACUTE TOXICITY (ORAL) NOT APPLICABLE
ACUTE TOXICITY (DERMAL) NOT APPLICABLE
ACUTE TOXICITY (INHALATION) NOT APPLICABLE
SKIN CORROSION/IRRITATION NOT APPLICABLE
SERIOUS EYE DAMAGE/IRRITATION 2 CAUSES SERIOUS EYE IRRITATION.
RESPIRATORY SENSITIZATION NOT APPLICABLE
SKIN SENSITIZATION NOT APPLICABLE
GERM CELL MUTAGENICITY NOT APPLICABLE
CARCINOGENICITY NOT APPLICABLE
REPRODUCTIVE TOXICITY NOT APPLICABLE
STOT-SINGLE EXPOSURE 3 MAY CAUSE DROWSINESS
OR DIZZINESS.
STOT-REPEATED EXPOSURE NOT APPLICABLE
ASPIRATION HAZARD NOT APPLICABLE
| 12. ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
NO ADDITIONAL INFORMATION PROVIDED FOR THIS PRODUCT. SEE SECTION 3 FOR
CHEMICAL SPECIFIC DATA.
AQUATIC ECOTOXICITY:
INGREDIENT 96 HR LC50 FISH, 48 HR EC50 CRUSTACEA, ERC50 ALGAE,
MG/L MG/L MG/L
ISOPROPYL ALCOHOL 1,400.00, 100.00, DAPHNIA 100.00
- (67-63-0) LEPOMIS MAGNA (72 HR),
MACROCHIRUS SCENEDESMUS
SUBSPICATUS
1-METHOXY-2- 1,000.00, 500.00, DAPHNIA 1,000.00
PROPANOL - ONCORHYNCHUS MAGNA (96 HR),
(107-98-2) MYKISS SELENASTRUM
CAPRICORNUTUM
ETHANOL - 42.00, 2.00, DAPHNIA 17.921
(64-17-5) ONCORHYNCHUS MAGNA (96 HR), ULVA
MYKISS PERTUSA
ETHYL ACETATE - 100.00, DANIO 100.00, DAPHNIA 100.00
(141-78-6) RERIO MAGNA (72 HR),
DESMODESMUS
SUBSPICATUS
CARBON BLACK - 1,000.00, 5,600.00, DAPHNIA 10,000.00
(1333-86-4) DANIO RERIO MAGNA (72 HR),
SCENEDESMUS
SUBSPICATUS
CELLULOSE NOT AVAILABLE NOT AVAILABLE 579.00
NITRATE - (96 HR),
(9004-70-0) PSEUDOKIR-
CHNERIELLA
SUBCAPITATA
ROSIN, FUMERIC - NOT AVAILABLE NOT AVAILABLE NOT AVAILABLE
(800680-57-9)
ACETIC ACID, 1- NOT AVAILABLE NOT AVAILABLE NOT AVAILABLE
METHYLETHYL ESTER
- (108-21-4)
12.2. PERSISTENCE AND DEGRADABILITY:
THERE IS NO DATA AVAILABLE ON THE PREPARATION ITSELF.
12.3. BIOACCUMULATIVE POTENTIAL: NOT MEASURED
12.4. MOBILITY IN SOIL: NO DATA AVAILABLE.
12.5. RESULTS OF PBT AND VPVB ASSESSMENT:
THIS PRODUCT CONTAINS NO PBT/VPVB CHEMICALS.
12.6. OTHER ADVERSE EFFECTS: NO DATA AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
DO NOT ALLOW INTO DRAINS OR WATER COURSES. WASTES AND EMPTIED CONTAINERS
SHOULD BE DISPOSED OF IN ACCORDANCE WITH REGULATIONS MADE UNDER THE CONTROL
OF POLLUTION ACT AND THE ENVIRONMENTAL PROTECTION ACT.
USING INFORMATION PROVIDED IN THIS DATA SHEET ADVICE SHOULD BE OBTAINED
FROM THE WASTE REGULATION AUTHORITY, WHETHER THE SPECIAL WASTE REGULATIONS
APPLY.
| 14. TRANSPORT INFORMATION | |
DOT (DOMESTIC SURFACE IMO / IMDG (OCEAN ICAO/IATA
TRANSPORTATION) TRANSPORTATION)
14.1. UN UN1210 UN1210 UN1210
NUMBER
14.2. UN
PROPER SHIPPING PRINTING INK PRINTING INK PRINTING INK
NAME
14.3. TRANSPORT DOT HAZARD CLASS: 3 IMDG: 3 AIR CLASS: 3
HAZARD CLASS(ES) DOT LABEL: 3
SUB CLASS: PACKING
NOT APPLICABLE INSTRUCTION:
EMS: F-E, S-D CARGO ONLY: 364
PASSENGER: 353
14.4. PACKING II II II
GROUP
14.5. ENVIRONMENTAL HAZARDS:
IMDG:
MARINE POLLUTANT: YES
14.6. SPECIAL PRECAUTIONS FOR USER: NO FURTHER INFORMATION
14.7. TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC
CODE: NOT APPLICABLE
| 15. REGULATORY INFORMATION | |
REGULATORY OVERVIEW:
THE REGULATORY DATA IN SECTION 15 IS NOT INTENDED TO BE ALL-INCLUSIVE,
ONLY SELECTED REGULATIONS ARE REPRESENTED. ALL COMPONENTS OF THIS MATERIAL
ARE EITHER LISTED OR EXEMPT FROM LISTING ON THE TSCA INVENTORY.
NFPA RANKINGS:
2
3
0
WHMIS CLASSIFICATION:
B2
D2B
B- FLAMMABLE AND COMBUSTIBLE MATERIAL
D2 - MATERIALS CAUSING OTHER TOXIC EFFECTS
US EPA TIER II HAZARDS:
FIRE: YES
SUDDEN RELEASE OF PRESSURE: NO
REACTIVE: NO
IMMEDIATE (ACUTE): YES
DELAYED (CHRONIC): NO
EPCRA 311/312 CHEMICALS AND RQS (LBS):
ETHYL ACETATE (5,000.00)
EPCRA 302 EXTREMELY HAZARDOUS: (NO PRODUCT INGREDIENTS LISTED)
EPCRA 313 TOXIC CHEMICALS: ISOPROPYL ALCOHOL
PROPOSITION 65 - CARCINOGENS (>0.0%): CARBON BLACK
PROPOSITION 65 - DEVELOPMENTAL TOXINS (>0.0%):
(NO PRODUCT INGREDIENTS LISTED)
PROPOSITION 65 - FEMALE REPRO TOXINS (>0.0%):
(NO PRODUCT INGREDIENTS LISTED)
PROPOSITION 65 - MALE REPRO TOXINS (>0.0%):
(NO PRODUCT INGREDIENTS LISTED)
N.J. RTK SUBSTANCES (>1%):
1-METHOXY-2-PROPANOL
ACETIC ACID, 1-METHYLETHYL ESTER
CARBON BLACK
CELLULOSE NITRATE
ETHANOL
ETHYL ACETATE
ISOPROPYL ALCOHOL
PENN RTK SUBSTANCES (>1%):
1-METHOXY-2-PROPANOL
ACETIC ACID, 1-METHYLETHYL ESTER
CARBON BLACK
CELLULOSE NITRATE
ETHANOL
ETHYL ACETATE
ISOPROPYL ALCOHOL
| 16. OTHER INFORMATION | |
THE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED UPON DATA
BELIEVED TO BE CORRECT. HOWEVER, NO GUARANTEE OR WARRANTY OF ANY KIND,
EXPRESSED OR IMPLIED, IS MADE WITH RESPECT TO THE INFORMATION CONTAINED
HEREIN. WE ACCEPT NO RESPONSIBILITY AND DISCLAIM ALL LIABILITY FOR ANY
HARMFUL EFFECTS WHICH MAY BE CAUSED BY EXPOSURE TO OUR PRODUCTS.
CUSTOMERS/USERS OF THIS PRODUCT MUST COMPLY WITH ALL APPLICABLE HEALTH
AND SAFETY LAWS, REGULATIONS, AND ORDERS.
THE FULL TEXT OF THE PHRASES APPEARING IN SECTION 3 IS:
H201: EXPLOSIVE; MASS EXPLOSION HAZARD.
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR.
H226: FLAMMABLE LIQUID AND VAPOR.
H319: CAUSES SERIOUS EYE IRRITATION.
H336: MAY CAUSE DROWSINESS AND DIZZINESS.
THIS IS THE FIRST VERSION IN THE GHS SDS FORMAT. LISTINGS OF CHANGES FROM
PREVIOUS VERSIONS IN OTHER FORMATS ARE NOT APPLICABLE.
THIS PRODUCT IS ROHS AND REACH COMPLIANT. IT DOES NOT CONTAIN ANY OF THE
ROHS LISTED SUBSTANCES. IT DOES NOT CONTAIN ANY CHEMICAL FROM THE CANDIDATE
LIST OF SUBSTANCES OF VERY HIGH CONCERN (SVHC), ANNEX XIV, OR ANNEX XVII
OF CREACH.
THIS INFORMATION IS BASED ON OUR PRESENT KNOWLEDGE. HOWEVER, IT DOES NOT
CONSTITUTE A GUARANTEE FOR ANY SPECIFIC PRODUCT PROPERTIES.
CARCO URGES THE RECIPIENT OF THIS SDS TO STUDY IT CAREFULLY AND CONSULT
APPROPRIATE EXPERTISE, AS NECESSARY OR APPROPRIATE, TO BECOME AWARE OF AND
UNDERSTAND THE DATA CONTAINED IN THIS SDS AND ANY HAZARDS ASSOCIATED WITH
THE PRODUCT. THE INFORMATION HEREIN IS PROVIDED IN GOOD FAITH AND BELIEVED
TO BE ACCURATE AS OF THE EFFECTIVE DATE SHOWN ABOVE. THE USE OF THIS
PRODUCT IS BEYOND THE CONTROL CARCO OR IT'S DISTRIBUTOR, THEREFORE, NO
WARRANTY, EXPRESS OR IMPLIED, IS GIVEN. REGULATORY REQUIREMENTS ARE SUBJECT
TO CHANGE AND MAY DIFFER BETWEEN VARIOUS LOCATIONS. IT IS THE
BUYER'S/USER'S RESPONSIBILITY TO ENSURE THAT HIS ACTIVITIES COMPLY WITH
ALL FEDERAL, STATE, PROVINCIAL OR LOCAL LAWS. THE INFORMATION PRESENTED
HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED. SINCE CONDITIONS FOR USE
OF THE PRODUCT ARE NOT UNDER THE CONTROL OF THE MANUFACTURER, IT IS THE
BUYER'S/USER'S DUTY TO DETERMINE THE CONDITIONS NECESSARY FOR THE SAFE
USE OF THIS PRODUCT.