| Common Name: | WS-860 MARKING INK (ALL COLORS) |
| Manufacturer: | CARCO |
| SDS Revision Date: | 2/7/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 40LF89, 40LF90, 40LF91, 40LF92, 40LF93 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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CARCO, INC
SAFETY DATA SHEET
WS-860 MARKING INK (ALL COLORS)
SDS REVISION DATE: 2/7/2017
| 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
PRODUCT IDENTITY: WS-860 MARKING INK (ALL COLORS)
ALTERNATE NAMES: WS-860 MARKING INK (ALL COLORS)
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
INTENDED USE: SEE TECHNICAL DATA SHEET.
APPLICATION METHOD: SEE TECHNICAL DATA SHEET.
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
COMPANY NAME:
CARCO, INC
10333 SHOEMAKER
P.O. BOX 13859
DETROIT, MICHIGAN, 48213
USA
EMERGENCY:
24 HOUR EMERGENCY TELEPHONE NO.:
CHEMTEL: 1-800-255-3924 (MIS0001475)
INTERNATIONAL: +01-813-248-0585
CUSTOMER SERVICE: CARCO, INC
PHONE: +1 (313) 925-9000
FAX: +1 (313) 925-9602
EMAIL: SALES@CARCOUSA.NET
| 2. HAZARD IDENTIFICATION OF THE PRODUCT | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
SKIN IRRIT. 3;H316: CAUSES MILD SKIN IRRITATION. (NOT ADOPTED BY US OSHA)
2.2. LABEL ELEMENTS:
USING THE TOXICITY DATA LISTED IN SECTION 11 AND 12 THE PRODUCT IS LABELED
AS FOLLOWS.
WARNING:
H316: CAUSES MILD SKIN IRRITATION.
[PREVENTION]: NO GHS PREVENTION STATEMENTS
[RESPONSE]:
P332+313:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE / ATTENTION.
[STORAGE]: NO GHS STORAGE STATEMENTS
[DISPOSAL]: NO GHS DISPOSAL STATEMENTS
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES THAT PRESENT A HAZARD
WITHIN THE MEANING OF THE RELEVANT STATE AND FEDERAL HAZARDOUS SUBSTANCES
REGULATIONS.
INGREDIENT/CHEMICAL DESIGNATIONS WEIGHT % GHS CLASSIFICATION NOTES
ACETIC ACID ETHENYL ESTER, 1.0 - 10 EYE IRRIT. 2;H319 [1]
POLYMER WITH ETHENOL
CAS NUMBER: 0025213-24-5
[1] SUBSTANCE CLASSIFIED WITH A HEALTH OR ENVIRONMENTAL HAZARD.
[2] SUBSTANCE WITH A WORKPLACE EXPOSURE LIMIT.
[3] PBT-SUBSTANCE OR VPVB-SUBSTANCE.
*THE FULL TEXTS OF THE PHRASES ARE SHOWN IN SECTION 16.
| 4. FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
GENERAL:
IN ALL CASES OF DOUBT, OR WHEN SYMPTOMS PERSIST, SEEK MEDICAL ATTENTION.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
INHALATION: NOT APPLICABLE
EYES:
MAKE SURE TO REMOVE ANY CONTACT LENSES FROM THE EYES BEFORE RINSING.
PROMPTLY WASH EYES WITH PLENTY OF WATER WHILE LIFTING THE EYE LIDS.
CONTINUE TO RINSE FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION IF ANY
DISCOMFORT CONTINUES.
SKIN:
REMOVE CONTAMINATED CLOTHING. WASH SKIN THOROUGHLY WITH SOAP AND WATER OR
USE A RECOGNIZED SKIN CLEANSER.
INGESTION: NOT APPLICABLE
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
OVERVIEW:
INGESTION:
MAY CAUSE STOMACH PAIN OR VOMITING. SEE SECTION 2 FOR FURTHER DETAILS.
SKIN: CAUSES MILD SKIN IRRITATION. (NOT ADOPTED BY US OSHA)
| 5. FIRE-FIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA: NONE-NON-FLAMMABLE.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
HAZARDOUS DECOMPOSITION: NONE
5.3. ADVICE FOR FIRE-FIGHTERS: NONE
ERG GUIDE NO.:
| 6. ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
AVOID EXCESSIVE SKIN CONTACT.
6.2. ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW SPILLS TO ENTER DRAINS OR WATERWAYS.
USE GOOD PERSONAL HYGIENE PRACTICES. WASH HANDS BEFORE EATING, DRINKING,
SMOKING OR USING TOILET. PROMPTLY REMOVE SOILED CLOTHING AND WASH
THOROUGHLY BEFORE REUSE.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
ABSORB IN VERMICULITE, DRY SAND OR EARTH AND PLACE INTO CONTAINERS.
| 7. HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
KEEP IN CONTAINERS LIGHTLY CLOSED IN A COOL, WELL VENTILATED PLACE. DO NOT
STORE WITH OXIDIZING AGENTS OR ACIDS. KEEP IN THE ORIGINAL CONTAINER.
AVOID DIRECT SUNLIGHT
SEE SECTION 2 FOR FURTHER DETAILS. - [PREVENTION]:
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
HANDLE CONTAINERS CAREFULLY TO PREVENT DAMAGE AND SPILLAGE.
STORE IN A COOL DRY AREA, AWAY FROM HEAT, SPARKS AND OPEN FLAME. KEEP
CONTAINERS SEALED WHEN NOT IN USE. STORE OUT OF DIRECT SUNLIGHT.
STORE IN A COOL DRY PLACE.
INCOMPATIBLE MATERIALS: STORE AWAY FROM OXIDIZERS AND ACIDS.
SEE SECTION 2 FOR FURTHER DETAILS. - [STORAGE]:
7.3. SPECIFIC END USE(S): NO DATA AVAILABLE.
| 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
EXPOSURE:
CAS NO. INGREDIENT SOURCE VALUE
0025213-24-5 ACETIC ACID ETHENYL ESTER, OSHA NO ESTABLISHED LIMIT
POLYMER WITH ETHENOL
ACGIH NO ESTABLISHED LIMIT
NIOSH NO ESTABLISHED LIMIT
SUPPLIER NO ESTABLISHED LIMIT
CARCINOGEN DATA:
CAS NO. INGREDIENT SOURCE VALUE
0025213-24-5 ACETIC ACID ETHENYL ESTER, OSHA SELECT CARCINOGEN: NO
POLYMER WITH ETHENOL
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
8.2. EXPOSURE CONTROLS:
RESPIRATORY: NONE NORMALLY REQUIRED
EYES:
WEAR SAFETY EYEWEAR, E.G. SAFETY SPECTACLES, GOGGLES OR VISORS TO PROTECT
AGAINST THE SPLASH OF LIQUIDS.
SKIN: NONE NORMALLY REQUIRED
ENGINEERING CONTROLS: NONE REQUIRED.
OTHER WORK PRACTICES:
DO NOT SMOKE, OR DRINK IN WORK AREA. KEEP AWAY FROM FOODSTUFFS AND
BEVERAGES. AVOID CONTACT WITH EYES AND SKIN.
USE GOOD PERSONAL HYGIENE PRACTICES. WASH HANDS BEFORE EATING, DRINKING,
SMOKING OR USING TOILET. PROMPTLY REMOVE SOILED CLOTHING AND WASH
THOROUGHLY BEFORE REUSE.
SEE SECTION 2 FOR FURTHER DETAILS. - [PREVENTION]:
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: COLORED LIQUID
ODOR: EXTREMELY MILD, SOAP LIKE ODOR
ODOR THRESHOLD: NOT MEASURED
PH: NA
MELTING POINT / FREEZING POINT: 0C 32F
INITIAL BOILING POINT AND BOILING RANGE:
100C
212F
FLASH POINT: NONE - NON FLAMMABLE
EVAPORATION RATE (ETHER = 1) (H2O=1): 1.00
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
LOWER EXPLOSIVE LIMIT: NA
UPPER EXPLOSIVE LIMIT: NA
VAPOR PRESSURE (PA) (MMHg): <10
VAPOR DENSITY (AIR=1): >1
SPECIFIC GRAVITY: 1.1 G/ML
SOLUBILITY IN WATER: 100%
PARTITION COEFFICIENT N-OCTANOL/WATER (LOG KOW): NOT MEASURED
AUTO-IGNITION TEMPERATURE: NA
DECOMPOSITION TEMPERATURE: NA
VISCOSITY (CST): NA
THE FOLLOWING COLORS CONTAIN VOC:
VOC CONTENT:
WHITE & PASTELS: 0.33 LBS/GAL
BLUE, GREEN, YELLOW, PURPLE: 0.17 LBS/GAL
% VOLATILE: 85%
9.2. OTHER INFORMATION: NO OTHER RELEVANT INFORMATION.
| 10. STABILITY AND REACTIVITY | |
10.1. REACTIVITY: HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.2. CHEMICAL STABILITY: STABLE UNDER NORMAL CIRCUMSTANCES.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NO DATA AVAILABLE.
10.4. CONDITIONS TO AVOID: HIGH TEMPERATURES AND FIRES.
10.5. INCOMPATIBLE MATERIALS: STORE AWAY FROM OXIDIZERS AND ACIDS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS: NONE
| 11. TOXICOLOGICAL INFORMATION | |
ACUTE TOXICITY:
INGREDIENT ORAL LD50, SKIN LD50,
MG/KG MG/KG
ACETIC ACID ETHENYL ESTER, POLYMER 5,000.00, NO DATA AVAILABLE
WITH ETHENOL - (25213-24-5) RAT - CATEGORY: 5
INGREDIENT INHALATION INHALATION INHALATION
VAPOR LD50, DUST/MIST LD50, GAS LD50,
MG/L/4HR MG/L/4HR PPM
ACETIC ACID ETHENYL ESTER, NO DATA NO DATA NO DATA
POLYMER WITH ETHENOL AVAILABLE AVAILABLE AVAILABLE
NOTE:
WHEN NO ROUTE SPECIFIC LD50 DATA IS AVAILABLE FOR AN ACUTE TOXIN, THE
CONVERTED ACUTE TOXICITY POINT ESTIMATE WAS USED IN THE CALCULATION OF
THE PRODUCT'S ATE (ACUTE TOXICITY ESTIMATE).
CLASSIFICATION CATEGORY HAZARD DESCRIPTION
ACUTE TOXICITY (ORAL) NOT APPLICABLE
ACUTE TOXICITY (DERMAL) NOT APPLICABLE
ACUTE TOXICITY (INHALATION) NOT APPLICABLE
SKIN CORROSION/IRRITATION 3 CAUSES MILD SKIN IRRITATION.
(NOT ADOPTED BY US OSHA)
SERIOUS EYE DAMAGE/IRRITATION NOT APPLICABLE
RESPIRATORY SENSITIZATION NOT APPLICABLE
SKIN SENSITIZATION NOT APPLICABLE
GERM CELL MUTAGENICITY NOT APPLICABLE
CARCINOGENICITY NOT APPLICABLE
REPRODUCTIVE TOXICITY NOT APPLICABLE
STOT-SINGLE EXPOSURE NOT APPLICABLE
STOT-REPEATED EXPOSURE NOT APPLICABLE
ASPIRATION HAZARD NOT APPLICABLE
| 12. ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
NO ADDITIONAL INFORMATION PROVIDED FOR THIS PRODUCT. SEE SECTION 3 FOR
CHEMICAL SPECIFIC DATA.
AQUATIC ECOTOXICITY:
INGREDLENT 96 HR LC50 48 HR EC50 ERC50 ALGAE,
FISH, MG/L CRUSTACEA, MG/L MG/L
ACETIC ACID ETHENYL NOT AVAILABLE NOT AVAILABLE NOT AVAILABLE
ESTER, POLYMER WITH
ETHENOL - (25213-24-5)
12.2. PERSISTENCE AND DEGRADABILITY:
THERE IS NO DATA AVAILABLE ON THE PREPARATION ITSELF.
12.3. BIOACCUMULATIVE POTENTIAL: NOT MEASURED
12.4. MOBILITY IN SOIL: NO DATA AVAILABLE.
12.5. RESULTS OF PBT AND VPVB ASSESSMENT:
THIS PRODUCT CONTAINS NO PBT/VPVB CHEMICALS.
12.6. OTHER ADVERSE EFFECTS: NO DATA AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS WHEN DISPOSING OF THIS
SUBSTANCE.
| 14. TRANSPORT INFORMATION | |
DOT (DOMESTIC IMO / IMDG (OCEAN ICAO/IATA
SURFACE TRANSPORTATION)
TRANSPORTATION)
14.1. UN NUMBER NOT APPLICABLE NOT REGULATED NOT REGULATED
14.2. UN PROPER NOT REGULATED NOT REGULATED NOT REGULATED
SHIPPING NAME
14.3. TRANSPORT DOT HAZARD CLASS: IMDG: AIR CLASS:
HAZARD CLASS(ES) NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE
DOT LABEL: SUB CLASS: NOT APPLICABLE
NOT APPLICABLE
EMS:
NOT APPLICABLE
14.4. PACKING GROUP NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE
14.5. ENVIRONMENTAL HAZARDS:
IMDG:
MARINE POLLUTANT: NO
14.6. SPECIAL PRECAUTIONS FOR USER: NO FURTHER INFORMATION
14.7. TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC
CODE: NOT APPLICABLE
| 15. REGULATORY INFORMATION | |
REGULATORY OVERVIEW:
THE REGULATORY DATA IN SECTION 15 IS NOT INTENDED TO BE ALL-INCLUSIVE,
ONLY SELECTED REGULATIONS ARE REPRESENTED. ALL COMPONENTS OF THIS MATERIAL
ARE EITHER LISTED OR EXEMPT FROM LISTING ON THE TSCA INVENTORY.
NFPA RANKINGS:
0
0
0
WHMIS CLASSIFICATION: NOT REGULATED
US EPA TIER II HAZARDS:
FIRE: NO
SUDDEN RELEASE OF PRESSURE: NO
REACTIVE: NO
IMMEDIATE (ACUTE): YES
DELAYED (CHRONIC): NO
EPCRA 311/312 CHEMICALS AND RQS:
TO THE BEST OF OUR KNOWLEDGE, THERE ARE NO CHEMICALS AT LEVELS WHICH
REQUIRE REPORTING UNDER THIS STATUTE.
EPCRA 302 EXTREMELY HAZARDOUS:
TO THE BEST OF OUR KNOWLEDGE, THERE ARE NO CHEMICALS AT LEVELS WHICH
REQUIRE REPORTING UNDER THIS STATUTE.
EPCRA 313 TOXIC CHEMICALS:
TO THE BEST OF OUR KNOWLEDGE, THERE ARE NO CHEMICALS AT LEVELS WHICH
REQUIRE REPORTING UNDER THIS STATUTE.
PROPOSITION 65 - CARCINOGENS (>0.0%):
TO THE BEST OF OUR KNOWLEDGE, THERE ARE NO CHEMICALS AT LEVELS WHICH
REQUIRE REPORTING UNDER THIS STATUTE.
PROPOSITION 65 - DEVELOPMENTAL TOXINS (>0.0%):
TO THE BEST OF OUR KNOWLEDGE, THERE ARE NO CHEMICALS AT LEVELS WHICH
REQUIRE REPORTING UNDER THIS STATUTE.
PROPOSITION 65 - FEMALE REPRO TOXINS (>0.0%):
TO THE BEST OF OUR KNOWLEDGE, THERE ARE NO CHEMICALS AT LEVELS WHICH
REQUIRE REPORTING UNDER THIS STATUTE.
PROPOSITION 65 - MALE REPRO TOXINS (>0.0%):
TO THE BEST OF OUR KNOWLEDGE, THERE ARE NO CHEMICALS AT LEVELS WHICH
REQUIRE REPORTING UNDER THIS STATUTE.
N.J. RTK SUBSTANCES (>1%):
TO THE BEST OF OUR KNOWLEDGE, THERE ARE NO CHEMICALS AT LEVELS WHICH
REQUIRE REPORTING UNDER THIS STATUTE.
PENN RTK SUBSTANCES (>1%):
TO THE BEST OF OUR KNOWLEDGE, THERE ARE NO CHEMICALS AT LEVELS WHICH
REQUIRE REPORTING UNDER THIS STATUTE.
| 16. OTHER INFORMATION | |
THE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED UPON DATA
BELIEVED TO BE CORRECT. HOWEVER, NO GUARANTEE OR WARRANTY OF ANY KIND,
EXPRESSED OR IMPLIED, IS MADE WITH RESPECT TO THE INFORMATION CONTAINED
HEREIN. WE ACCEPT NO RESPONSIBILITY AND DISCLAIM ALL LIABILITY FOR ANY
HARMFUL EFFECTS WHICH MAY BE CAUSED BY EXPOSURE TO OUR PRODUCTS.
CUSTOMERS/USERS OF THIS PRODUCT MUST COMPLY WITH ALL APPLICABLE HEALTH
AND SAFETY LAWS, REGULATIONS, AND ORDERS.
THE FULL TEXT OF THE PHRASES APPEARING IN SECTION 3 IS:
H319: CAUSES SERIOUS EYE IRRITATION.
THIS IS THE FIRST VERSION IN THE GHS SDS FORMAT. LISTINGS OF CHANGES FROM
PREVIOUS VERSIONS IN OTHER FORMATS ARE NOT APPLICABLE.
THIS PRODUCT IS ROHS AND REACH COMPLIANT. IT DOES NOT CONTAIN ANY OF THE
ROHS LISTED SUBSTANCES. IT DOES NOT CONTAIN ANY CHEMICAL FROM THE CANDIDATE
LIST OF SUBSTANCES OF VERY HIGH CONCERN (SVHC), ANNEX XIV, OR ANNEX XVII OF
REACH.
THIS INFORMATION IS BASED ON OUR PRESENT KNOWLEDGE. HOWEVER, IT DOES NOT
CONSTITUTE A GUARANTEE FOR ANY SPECIFIC PRODUCT PROPERTIES.
CARCO URGES THE RECIPIENT OF THIS SDS TO STUDY IT CAREFULLY AND CONSULT
APPROPRIATE EXPERTISE, AS NECESSARY OR APPROPRIATE, TO BECOME AWARE OF AND
UNDERSTAND THE DATA CONTAINED IN THIS SDS AND ANY HAZARDS ASSOCIATED WITH
THE PRODUCT. THE INFORMATION HEREIN IS PROVIDED IN GOOD FAITH AND BELIEVED
TO BE ACCURATE AS OF THE EFFECTIVE DATE SHOWN ABOVE. THE USE OF THIS
PRODUCT IS BEYOND THE CONTROL CARCO OR ITS DISTRIBUTOR, THEREFORE, NO
WARRANTY, EXPRESS OR IMPLIED, IS GIVEN. REGULATORY REQUIREMENTS ARE
SUBJECT TO CHANGE AND MAY DIFFER BETWEEN VARIOUS LOCATIONS. IT IS THE
BUYER'S/USER'S RESPONSIBILITY TO ENSURE THAT HIS ACTIVITIES COMPLY WITH
ALL FEDERAL, STATE, PROVINCIAL OR LOCAL LAWS. THE INFORMATION PRESENTED
HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED. SINCE CONDITIONS FOR USE OF
THE PRODUCT ARE NOT UNDER THE CONTROL OF THE MANUFACTURER, IT IS THE
BUYER'S/USER'S DUTY TO DETERMINE THE CONDITIONS NECESSARY FOR THE SAFE USE
OF THIS PRODUCT.