Grainger SDS Lookup

AND OF THE COMPANY/UNDERTAKING

1.1. PRODUCT IDENTIFIER:

PRODUCT IDENTITY: 1044 SOLVENT

ALTERNATE NAMES: 1044 SOLVENT

1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:

INTENDED USE: SEE TECHNICAL DATA SHEET.

APPLICATION METHOD: SEE TECHNICAL DATA SHEET.

1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:

COMPANY NAME:
CARCO, INC
10333 SHOEMAKER
P.O. BOX 13859
DETROIT, MICHIGAN, 48213
USA

EMERGENCY:

24 HOUR EMERGENCY TELEPHONE NO.:
CHEMTEL: 1-800-255-3924 (MIS0001475)
INTERNATIONAL: +01-813-248-0585

CUSTOMER SERVICE: CARCO, INC

PHONE: +1 (313) 925-9000

FAX: +1 (313) 925-9602

EMAIL: SALES@CARCOUSA.NET

2. HAZARD IDENTIFICATION OF THE PRODUCT

2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAM. LIQ. 2; H225: HIGHLY FLAMMABLE LIQUID AND VAPOR.
ACUTE TOX. 4; H302: HARMFUL IF SWALLOWED.
ACUTE TOX. 4; H312: HARMFUL IN CONTACT WITH SKIN.
EYE IRRIT. 2; H319: CAUSES SERIOUS EYE IRRITATION.
STOT SE 3; H336: MAY CAUSE DROWSINESS OR DIZZINESS.

2.2. LABEL ELEMENTS:
USING THE TOXICITY DATA LISTED IN SECTION 11 AND 12 THE PRODUCT IS LABELED
AS FOLLOWS.

FLAME
EXCLAMATION MARK

DANGER:

H225: HIGHLY FLAMMABLE LIQUID AND VAPOR.
H302: HARMFUL IF SWALLOWED.
H312: HARMFUL IN CONTACT WITH SKIN.
H319: CAUSES SERIOUS EYE IRRITATION.

[PREVENTION]:
P210:
KEEP AWAY FROM HEAT / SPARKS / OPEN FLAMES / HOT SURFACES - NO SMOKING.

P241: USE EXPLOSION-PROOF ELECTRICAL / VENTILATING / LIGHT / EQUIPMENT.

P264: WASH THOROUGHLY AFTER HANDLING.

P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.

P280: WEAR PROTECTIVE GLOVES / EYE PROTECTION / FACE PROTECTION.

[RESPONSE]:
P301+312:
IF SWALLOWED:
CALL A POISON CENTER OR DOCTOR / PHYSICIAN IF YOU FEEL UNWELL.

P302+352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.

P303+361+353:
IF ON SKIN (OR HAIR):
REMOVE / TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER / SHOWER.

P305+351+338:
IF IN EYES:
RINSE CONTINUOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES IF
PRESENT AND EASY TO DO - CONTINUE RINSING.

P322: SPECIFIC MEASURES (SEE INFORMATION ON THIS LABEL).

P330: RINSE MOUTH.

P337+313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE / ATTENTION.

P363: WASH CONTAMINATED CLOTHING BEFORE REUSE.

P370+378:
IN CASE OF FIRE:
USE EXTINGUISHING MEDIA LISTED IN SECTION 5 OF SDS FOR EXTINCTION.

[STORAGE]:
P403+233: STORE IN A WELL VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.

[DISPOSAL]:
P501:
DISPOSE OF CONTENTS / CONTAINER IN ACCORDANCE WITH LOCAL / NATIONAL
REGULATIONS.

3. COMPOSITION/INFORMATION ON INGREDIENTS

THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES THAT PRESENT A HAZARD WITHIN
THE MEANING OF THE RELEVANT STATE AND FEDERAL HAZARDOUS SUBSTANCES
REGULATIONS.

INGREDIENT/CHEMICAL        WEIGHT %   GHS CLASSIFICATION     NOTES
DESIGNATIONS

ACETONE                    100        FLAM. LIQ. 2; H225     [1][2]
CAS NUMBER: 0000067-64-1              EYE IRRIT. 2; H319
                                      STOT SE 3; H336

[1] SUBSTANCE CLASSIFIED WITH A HEALTH OR ENVIRONMENTAL HAZARD.

[2] SUBSTANCE WITH A WORKPLACE EXPOSURE LIMIT.

[3] PBT-SUBSTANCE OR VPVB-SUBSTANCE.

*THE FULL TEXTS OF THE PHRASES ARE SHOWN IN SECTION 16.

4. FIRST AID MEASURES

4.1. DESCRIPTION OF FIRST AID MEASURES:

GENERAL:
MOVE VICTIM TO FRESH AIR.

CALL 911 OR EMERGENCY MEDICAL SERVICE IF DEEMED NECESSARY.

GIVE ARTIFICIAL RESPIRATION IF VICTIM IS NOT BREATHING.

ADMINISTER OXYGEN IF BREATHING IS DIFFICULT.

REMOVE AND ISOLATE CONTAMINATED CLOTHING AND SHOES.

IN CASE OF CONTACT WITH SUBSTANCE, IMMEDIATELY FLUSH SKIN OR EYES WITH
RUNNING WATER FOR AT LEAST 20 MINUTES.

WASH SKIN WITH SOAP AND WATER.

IN CASE OF BURNS, IMMEDIATELY COOL AFFECTED SKIN FOR AS LONG AS POSSIBLE
WITH COLD WATER. DO NOT REMOVE CLOTHING IF ADHERING TO SKIN.

KEEP VICTIM WARM AND QUIET.

ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES.

INHALATION:
REMOVE TO FRESH AIR, KEEP PATIENT WARM AND AT REST. IF BREATHING IS
IRREGULAR OR STOPPED, GIVE ARTIFICIAL RESPIRATION. IF UNCONSCIOUS PLACE IN
THE RECOVERY POSITION AND OBTAIN IMMEDIATE MEDICAL ATTENTION. GIVE NOTHING
BY MOUTH.

EYES:
MAKE SURE TO REMOVE ANY CONTACT LENSES FROM THE EYES BEFORE RINSING.
PROMPTLY WASH EYES WITH PLENTY OF WATER WHILE LIFTING THE EYE LIDS.
CONTINUE TO RINSE FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION IF
ANY DISCOMFORT CONTINUES.

SKIN:
REMOVE AND ISOLATE CONTAMINATED CLOTHING AND SHOES. CLOTHING FROZEN TO
THE SKIN SHOULD BE THAWED BEFORE BEING REMOVED. IN CASE OF CONTACT WITH
LIQUEFIED GAS, THAW FROSTED PARTS WITH LUKEWARM WATER.

INGESTION:

DO NOT INDUCE VOMITING!

IF SWALLOWED, VOMITING MAY OCCUR SPONTANEOUSLY. IF VOMITING OCCURS, KEEP
HEAD BELOW HIPS TO PREVENT ASPIRATION INTO LUNGS. RINSE MOUTH THOROUGHLY.
GET MEDICAL ATTENTION.

4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:

OVERVIEW:

EFFECTS OF OVEREXPOSURE - EYE CONTACT:
LIQUID, AEROSOLS AND VAPORS OF THIS PRODUCT ARE IRRITATING AND CAN CAUSE
PAIN, TEARING, REDDENING AND SWELLING ACCOMPANIED BY A STINGING SENSATION
AND/OR A FEELING LIKE THAT OF FINE DUST IN THE EYES.

EFFECTS OF OVEREXPOSURE - SKIN CONTACT:
PROLONGED OR REPEATED CONTACT CAN RESULT IN DEFATTING AND DRYING OF THE
SKIN WHICH MAY RESULT IN SKIN IRRITATION AND DERMATITIS (RASH).

EFFECTS OF OVEREXPOSURE - INHALATION:
HARMFUL IF INHALED. HEADACHES, DIZZINESS, NAUSEA, DECREASED BLOOD PRESSURE,
CHANGES IN HEART RATE AND CYANOSIS MAY RESULT FROM OVER-EXPOSURE TO VAPOR
OR SKIN EXPOSURE. BREATHING SATURATED VAPORS FOR A FEW MINUTES MAY BE
FATAL. SATURATED VAPORS CAN BE ENCOUNTERED IN CONFINED SPACES AND/OR UNDER
CONDITIONS OF POOR VENTILATION. PROLONGED INHALATION MAY BE HARMFUL.

EFFECTS OF OVEREXPOSURE - INGESTION:
THIS MATERIAL MAY BE HARMFUL OR FATAL IF SWALLOWED.

EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS:
OVEREXPOSURE MAY CAUSE LUNG DAMAGE.

EXPOSURE TO SOLVENT VAPOR CONCENTRATIONS FROM THE COMPONENT SOLVENTS IN
EXCESS OF THE STATED OCCUPATIONAL EXPOSURE LIMITS MAY RESULT IN ADVERSE
HEALTH EFFECTS SUCH AS MUCOUS MEMBRANE AND RESPIRATORY SYSTEM IRRITATION
AND ADVERSE EFFECTS ON THE KIDNEYS, LIVER AND CENTRAL NERVOUS SYSTEM.
SYMPTOMS INCLUDE HEADACHE, NAUSEA, DIZZINESS, FATIGUE, MUSCULAR WEAKNESS,
DROWSINESS AND IN EXTREME CASES, LOSS OF CONSCIOUSNESS.

REPEATED OR PROLONGED CONTACT WITH THE PREPARATION MAY CAUSE REMOVAL OF
NATURAL FAT FROM THE SKIN RESULTING IN DRYNESS, IRRITATION AND POSSIBLE
NON-ALLERGIC CONTACT DERMATITIS. SOLVENTS MAY ALSO BE ABSORBED THROUGH THE
SKIN. SPLASHES OF LIQUID IN THE EYES MAY CAUSE IRRITATION AND SORENESS WITH
POSSIBLE REVERSIBLE DAMAGE. SEE SECTION 2 FOR FURTHER DETAILS.

INHALATION: MAY CAUSE DROWSINESS OR DIZZINESS.

EYES: CAUSES SERIOUS EYE IRRITATION.

SKIN: HARMFUL IN CONTACT WITH SKIN.

INGESTION: HARMFUL IF SWALLOWED.

5. FIRE-FIGHTING MEASURES

5.1. EXTINGUISHING MEDIA: DRY CHEMICAL, FOAM, WATER FOG

5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:

HAZARDOUS DECOMPOSITION:
OXIDES OF CARBON AND NITROGEN, LOW MOLECULAR WEIGHT HYDROCARBONS AND
ORGANIC ACIDS.

KEEP AWAY FROM HEAT / SPARKS / OPEN FLAMES / HOT SURFACES - NO SMOKING.

USE EXPLOSION-PROOF ELECTRICAL / VENTILATING / LIGHT / EQUIPMENT.

5.3. ADVICE FOR FIRE-FIGHTERS:
WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA).

STRUCTURAL FIREFIGHTERS' PROTECTIVE CLOTHING WILL ONLY PROVIDE LIMITED
PROTECTION.

HIGHLY FLAMMABLE: WILL BE EASILY IGNITED BY HEAT, SPARKS OR FLAMES.

VAPORS MAY FORM EXPLOSIVE MIXTURES WITH AIR.

VAPORS MAY TRAVEL TO SOURCE OF IGNITION AND FLASH BACK.

MOST VAPORS ARE HEAVIER THAN AIR. THEY WILL SPREAD ALONG GROUND AND COLLECT
IN LOW OR CONFINED AREAS (SEWERS, BASEMENTS, TANKS).

VAPOR EXPLOSION HAZARD INDOORS, OUTDOORS OR IN SEWERS. RUNOFF TO SEWER MAY
CREATE FIRE OR EXPLOSION HAZARD.

CONTAINERS MAY EXPLODE WHEN HEATED.

MANY LIQUIDS ARE LIGHTER THAN WATER.

INHALATION OR CONTACT WITH MATERIAL MAY IRRITATE OR BURN SKIN AND EYES.

FIRE MAY PRODUCE IRRITATING, CORROSIVE AND/OR TOXIC GASES.

VAPORS MAY CAUSE DIZZINESS OR SUFFOCATION.

RUNOFF FROM FIRE CONTROL MAY CAUSE POLLUTION.

ERG GUIDE NO.: 127

6. ACCIDENTAL RELEASE MEASURES

6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
WATER SPRAY MAY REDUCE VAPOR; BUT MAY NOT PREVENT IGNITION IN CLOSED
SPACES.

6.2. ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW SPILLS TO ENTER DRAINS OR WATERCOURSES.

USE GOOD PERSONAL HYGIENE PRACTICES. WASH HANDS BEFORE EATING, DRINKING,
SMOKING OR USING TOILET. PROMPTLY REMOVE SOILED CLOTHING AND WASH
THOROUGHLY BEFORE REUSE.

6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:

LARGE SPILL:
AS AN IMMEDIATE PRECAUTIONARY MEASURE, ISOLATE SPILL OR LEAK AREA FOR AT
LEAST 50 METERS (150 FEET) IN ALL DIRECTIONS. KEEP UNAUTHORIZED PERSONNEL
AWAY.

STAY UPWIND.

KEEP OUT OF LOW AREAS.

VENTILATE CLOSED SPACES BEFORE ENTERING.

SMALL SPILL:
USE A NON-COMBUSTIBLE MATERIAL LIKE VERMICULITE, SAND OR EARTH TO SOAK UP
PRODUCT AND PLACE IN A CONTAINER FOR LATER DISPOSAL.

7. HANDLING AND STORAGE

7.1. PRECAUTIONS FOR SAFE HANDLING:
KEEP IN THE ORIGINAL CONTAINER.

STORE IN ACCORDANCE WITH THE NATIONAL FIRE PROTECTION ASSOCIATION'S
PUBLICATION NFPA 30, FLAMMABLE AND COMBUSTIBLE LIQUIDS CODE. 29 CFR
1910.106 APPLIES TO THE HANDLING, STORAGE, AND USE OF FLAMMABLE AND
COMBUSTIBLE LIQUIDS.

SEE SECTION 2 FOR FURTHER DETAILS. - [PREVENTION]:

7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
HANDLE CONTAINERS CAREFULLY TO PREVENT DAMAGE AND SPILLAGE.

STORE IN A COOL DRY AREA, AWAY FROM HEAT, SPARKS AND OPEN FLAME. KEEP
CONTAINERS SEALED WHEN NOT IN USE. STORE OUT OF DIRECT SUNLIGHT.

STORE IN A COOL DRY PLACE.

INCOMPATIBLE MATERIALS:
AVOID CONTACT WITH STRONG ACIDS AND BASES. CONTACT WITH STRONG OXIDIZERS
MAY CAUSE FIRE AND EXPLOSION.

SEE SECTION 2 FOR FURTHER DETAILS. - [STORAGE]:

7.3. SPECIFIC END USE(S): NO DATA AVAILABLE.

8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

8.1. CONTROL PARAMETERS:

EXPOSURE:

CAS NO.         INGREDIENT      SOURCE      VALUE

0000067-64-1    ACETONE         OSHA        TWA: 1000 PPM (2400 MG/M3)
                                            STEL: 2400 MG/M3

                                ACGIH       TWA: 250 PPM
                                            STEL: 500 PPM SKIN

                                NIOSH       250 PPM (590 MG/M3) TWA

                                SUPPLIER    NO ESTABLISHED LIMIT

CARCINOGEN DATA:

CAS NO.         INGREDIENT      SOURCE      VALUE

0000067-64-1    ACETONE         OSHA        SELECT CARCINOGEN: NO

                                NTP         KNOWN: NO
                                            SUSPECTED: NO

                                IARC        GROUP 1: NO
                                            GROUP 2A: NO
                                            GROUP 2B: NO
                                            GROUP 3: NO
                                            GROUP 4: NO

8.2. EXPOSURE CONTROLS:

RESPIRATORY:
ATMOSPHERIC LEVELS SHOULD BE MAINTAINED BELOW THE EXPOSURE GUIDELINE. WHEN
RESPIRATORY PROTECTION IS REQUIRED FOR CERTAIN OPERATIONS, USE AN APPROVED
AIR-PURIFYING RESPIRATOR.

THE FOLLOWING SHOULD BE EFFECTIVE TYPES OF AIR PURIFYING RESPIRATORS:
ORGANIC VAPOR CARTRIDGE.

EYES:
WEAR SAFETY EYEWEAR, E.G. SAFETY SPECTACLES, GOGGLES OR VISORS TO PROTECT
AGAINST THE SPLASH OF LIQUIDS.

SKIN:
OVERALLS WHICH COVER THE BODY, ARMS AND LEGS SHOULD BE WORN. SKIN SHOULD
NOT BE EXPOSED. ALL PARTS OF THE BODY SHOULD BE WASHED AFTER CONTACT. USE
GLOVES CHEMICALLY RESISTANT TO THIS MATERIAL WHEN PROLONGED OR FREQUENTLY
REPEATED CONTACT COULD OCCUR.

EXAMPLES OF PREFERRED GLOVE BARRIER MATERIALS INCLUDE:
BUTYL RUBBER. POLYETHYLENE/ETHYL VINYL ALCOHOL LAMINATE ("PE/EVAL").

EXAMPLES OF ACCEPTABLE GLOVE BARRIER MATERIALS INCLUDE:
NATURAL RUBBER ("LATEX"). NEOPRENE. NITRILE/BUTADIENE RUBBER ("NITRILE" OR
"NBR"). POLYVINYL CHLORIDE ("PVC" OR "VINYL"). VITON

ENGINEERING CONTROLS:
PROVIDE ADEQUATE VENTILATION. WHERE REASONABLY PRACTICABLE THIS SHOULD BE
ACHIEVED BY THE USE OF LOCAL EXHAUST VENTILATION AND GOOD GENERAL
EXTRACTION. IF THESE ARE NOT SUFFICIENT TO MAINTAIN CONCENTRATIONS OF
PARTICULATES AND ANY VAPOR BELOW OCCUPATIONAL EXPOSURE LIMITS SUITABLE
RESPIRATORY PROTECTION MUST BE WORN.

OTHER WORK PRACTICES:
USE GOOD PERSONAL HYGIENE PRACTICES. WASH HANDS BEFORE EATING, DRINKING,
SMOKING OR USING TOILET. PROMPTLY REMOVE SOILED CLOTHING AND WASH
THOROUGHLY BEFORE REUSE.

SEE SECTION 2 FOR FURTHER DETAILS. - [PREVENTION]:

9. PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE: CLEAR LIQUID

ODOR: SWEET PUNGENT

ODOR THRESHOLD: NOT MEASURED

PH: NOT MEASURED

MELTING POINT / FREEZING POINT: NOT MEASURED

INITIAL BOILING POINT AND BOILING RANGE:
56C
133F

FLASH POINT:
-18C
0F

EVAPORATION RATE (ETHER = 1): 5.2(BU.AC=1)

FLAMMABILITY (SOLID, GAS): NOT APPLICABLE

UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
LOWER EXPLOSIVE LIMIT: 2.5
UPPER EXPLOSIVE LIMIT: 12.8

VAPOR PRESSURE (PA): 184 (MMHg)

VAPOR DENSITY: >2(AIR=1)

SPECIFIC GRAVITY: 0.79G/ML@20

SOLUBILITY IN WATER: 100%

PARTITION COEFFICIENT N-OCTANOL/WATER (LOG KOW): NOT MEASURED

AUTO-IGNITION TEMPERATURE: NOT MEASURED

DECOMPOSITION TEMPERATURE: NOT MEASURED

VISCOSITY (CST): NOT MEASURED

VOC %: 100WT%

% VOLATILE: 100%

9.2. OTHER INFORMATION: NO OTHER RELEVANT INFORMATION.

10. STABILITY AND REACTIVITY

10.1. REACTIVITY: HAZARDOUS POLYMERIZATION WILL NOT OCCUR.

10.2. CHEMICAL STABILITY: STABLE UNDER NORMAL CIRCUMSTANCES.

10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NO DATA AVAILABLE.

10.4. CONDITIONS TO AVOID:
AVOID CONTACT WITH OPEN FLAME, SPARKS OR HOT SURFACES.

10.5. INCOMPATIBLE MATERIALS:
AVOID CONTACT WITH STRONG ACIDS AND BASES. CONTACT WITH STRONG OXIDIZERS
MAY CAUSE FIRE AND EXPLOSION.

10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON AND NITROGEN, LOW MOLECULAR WEIGHT HYDROCARBONS AND
ORGANIC ACIDS.

11. TOXICOLOGICAL INFORMATION

ACUTE TOXICITY:
EXPOSURE TO SOLVENT VAPOR CONCENTRATIONS FROM THE COMPONENT SOLVENTS IN
EXCESS OF THE STATED OCCUPATIONAL EXPOSURE LIMITS MAY RESULT IN ADVERSE
HEALTH EFFECTS SUCH AS MUCOUS MEMBRANE AND RESPIRATORY SYSTEM IRRITATION
AND ADVERSE EFFECTS ON THE KIDNEYS, LIVER AND CENTRAL NERVOUS SYSTEM.
SYMPTOMS INCLUDE HEADACHE, NAUSEA, DIZZINESS, FATIGUE, MUSCULAR WEAKNESS,
DROWSINESS AND IN EXTREME CASES, LOSS OF CONSCIOUSNESS.

REPEATED OR PROLONGED CONTACT WITH THE PREPARATION MAY CAUSE REMOVAL OF
NATURAL FAT FROM THE SKIN RESULTING IN DRYNESS, IRRITATION AND POSSIBLE
NON-ALLERGIC CONTACT DERMATITIS. SOLVENTS MAY ALSO BE ABSORBED THROUGH THE
SKIN. SPLASHES OF LIQUID IN THE EYES MAY CAUSE IRRITATION AND SORENESS WITH
POSSIBLE REVERSIBLE DAMAGE.

INGREDIENT                     ORAL LD50, MG/KG    SKIN LD50, MG/KG

ACETONE - (67-64-1)            2,000.00, RAT -     2,000.00, RABBIT -
                               CATEGORY: 4         CATEGORY: 4

INGREDIENT                    INHALATION      INHALATION        INHALATION
                              VAPOR LD50,     DUST/MIST LD50,   GAS LD50,
                              MG/L/4HR        MG/L/4HR          PPM

ACETONE                       76.00, RAT -    NO DATA           NO DATA
                              CATEGORY: NA    AVAILABLE         AVAILABLE

NOTE:
WHEN NO ROUTE SPECIFIC LD50 DATA IS AVAILABLE FOR AN ACUTE TOXIN, THE
CONVERTED ACUTE TOXICITY POINT ESTIMATE WAS USED IN THE CALCULATION OF THE
PRODUCT'S ATE (ACUTE TOXICITY ESTIMATE).

CLASSIFICATION                   CATEGORY    HAZARD DESCRIPTION

ACUTE TOXICITY (ORAL)            4           HARMFUL IF SWALLOWED.

ACUTE TOXICITY (DERMAL)          4           HARMFUL IN CONTACT WITH SKIN.

ACUTE TOXICITY (INHALATION)                  NOT APPLICABLE

SKIN CORROSION/IRRITATION                    NOT APPLICABLE

SERIOUS EYE DAMAGE/IRRITATION    2           CAUSES SERIOUS EYE IRRITATION.

RESPIRATORY SENSITIZATION                    NOT APPLICABLE

SKIN SENSITIZATION                           NOT APPLICABLE

GERM CELL MUTAGENICITY                       NOT APPLICABLE

CARCINOGENICITY                              NOT APPLICABLE

REPRODUCTIVE TOXICITY                        NOT APPLICABLE

STOT-SINGLE EXPOSURE             3           MAY CAUSE DROWSINESS OR
                                             DIZZINESS.

STOT-REPEATED EXPOSURE                       NOT APPLICABLE

ASPIRATION HAZARD                            NOT APPLICABLE

12. ECOLOGICAL INFORMATION

12.1. TOXICITY:

AQUATIC ECOTOXICITY:

INGREDIENT            96 HR LC50    48 HR EC50        ERC50 ALGAE,
                      FISH, MG/L    CRUSTACEA, MG/L   MG/L

ACETONE - (67-64-1)   100.00,       10.00, DAPHNIA    20.565 (72 HR),
                      PIMEPHALES    MAGNA             ULVA PERTUSA
                      PROMELAS

12.2. PERSISTENCE AND DEGRADABILITY:
THERE IS NO DATA AVAILABLE ON THE PREPARATION ITSELF.

12.3. BIOACCUMULATIVE POTENTIAL: NOT MEASURED

12.4. MOBILITY IN SOIL: NO DATA AVAILABLE.

12.5. RESULTS OF PBT AND VPVB ASSESSMENT:
THIS PRODUCT CONTAINS NO PBT/VPVB CHEMICALS.

12.6. OTHER ADVERSE EFFECTS: NO DATA AVAILABLE.

13. DISPOSAL CONSIDERATIONS

13.1. WASTE TREATMENT METHODS:
DO NOT ALLOW INTO DRAINS OR WATER COURSES. WASTES AND EMPTIED CONTAINERS
SHOULD BE DISPOSED OF IN ACCORDANCE WITH REGULATIONS MADE UNDER THE CONTROL
OF POLLUTION ACT AND THE ENVIRONMENTAL PROTECTION ACT.

USING INFORMATION PROVIDED IN THIS DATA SHEET ADVICE SHOULD BE OBTAINED
FROM THE WASTE REGULATION AUTHORITY, WHETHER THE SPECIAL WASTE REGULATIONS
APPLY.

14. TRANSPORT INFORMATION

                 DOT (DOMESTIC       IMO / IMDG (OCEAN   ICAO/IATA
                 SURFACE             TRANSPORTATION)
                 TRANSPORTATION)

14.1. UN NUMBER  UN1090              UN1090              UN1090

14.2. UN PROPER  ACETONE             ACETONE             ACETONE
SHIPPING NAME

14.3. TRANSPORT  DOT HAZARD CLASS:   IMDG: 3             AIR CLASS: 3
HAZARD           3
CLASS(ES)                            SUB CLASS:          PACKING
                 DOT LABEL: 3        NOT APPLICABLE      INSTRUCTION:
                                                         CARGO ONLY - 364,
                                     EMS: F-E, S-D       PASSENGER - 353

14.4. PACKING    II                  II                  II
GROUP

14.5. ENVIRONMENTAL HAZARDS:

IMDG:
MARINE POLLUTANT: YES

14.6. SPECIAL PRECAUTIONS FOR USER: NO FURTHER INFORMATION

14.7. TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC
CODE: NOT APPLICABLE

15. REGULATORY INFORMATION

REGULATORY OVERVIEW:
THE REGULATORY DATA IN SECTION 15 IS NOT INTENDED TO BE ALL-INCLUSIVE, ONLY
SELECTED REGULATIONS ARE REPRESENTED. ALL INGREDIENTS OF THIS PRODUCT ARE
LISTED ON THE TSCA (TOXIC SUBSTANCE CONTROL ACT) INVENTORY OR ARE NOT
REQUIRED TO BE LISTED ON THE TSCA INVENTORY.

NFPA RANKINGS:
1
3
0

WHMIS CLASSIFICATION:
B2
D2B

B - FLAMMABLE AND COMBUSTIBLE MATERIAL
D2 - MATERIALS CAUSING OTHER TOXIC EFFECTS

US EPA TIER II HAZARDS:
FIRE: YES
SUDDEN RELEASE OF PRESSURE: NO
REACTIVE: NO
IMMEDIATE (ACUTE): YES
DELAYED (CHRONIC): NO

EPCRA 311/312 CHEMICALS AND RQS (LBS): ACETONE (5,000.00)

EPCRA 302 EXTREMELY HAZARDOUS: (NO PRODUCT INGREDIENTS LISTED)

EPCRA 313 TOXIC CHEMICALS: (NO PRODUCT INGREDIENTS LISTED)

PROPOSITION 65 - CARCINOGENS (>0.0%): (NO PRODUCT INGREDIENTS LISTED)

PROPOSITION 65 - DEVELOPMENTAL TOXINS (>0.0%):
(NO PRODUCT INGREDIENTS LISTED)

PROPOSITION 65 - FEMALE REPRO TOXINS (>0.0%):
(NO PRODUCT INGREDIENTS LISTED)

PROPOSITION 65 - MALE REPRO TOXINS (>0.0%): (NO PRODUCT INGREDIENTS LISTED)

N.J. RTK SUBSTANCES (>1%): ACETONE

PENN RTK SUBSTANCES (>1%): ACETONE

16. OTHER INFORMATION

THE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED UPON DATA
BELIEVED TO BE CORRECT. HOWEVER, NO GUARANTEE OR WARRANTY OF ANY KIND,
EXPRESSED OR IMPLIED, IS MADE WITH RESPECT TO THE INFORMATION CONTAINED
HEREIN. WE ACCEPT NO RESPONSIBILITY AND DISCLAIM ALL LIABILITY FOR ANY
HARMFUL EFFECTS WHICH MAY BE CAUSED BY EXPOSURE TO OUR PRODUCTS.
CUSTOMERS/USERS OF THIS PRODUCT MUST COMPLY WITH ALL APPLICABLE HEALTH
AND SAFETY LAWS, REGULATIONS, AND ORDERS.

THE FULL TEXT OF THE PHRASES APPEARING IN SECTION 3 IS:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR.
H319: CAUSES SERIOUS EYE IRRITATION.
H336: MAY CAUSE DROWSINESS AND DIZZINESS.

THIS IS THE FIRST VERSION IN THE GHS SDS FORMAT. LISTINGS OF CHANGES FROM
PREVIOUS VERSIONS IN OTHER FORMATS ARE NOT APPLICABLE.

THIS PRODUCT IS ROHS AND REACH COMPLIANT. IT DOES NOT CONTAIN ANY OF THE
ROHS LISTED SUBSTANCES. IT DOES NOT CONTAIN ANY CHEMICAL FROM THE CANDIDATE
LIST OF SUBSTANCES OF VERY HIGH CONCERN (SVHC), ANNEX XIV, OR ANNEX XVII OF
REACH.

THIS INFORMATION IS BASED ON OUR PRESENT KNOWLEDGE. HOWEVER, IT DOES NOT
CONSTITUTE A GUARANTEE FOR ANY SPECIFIC PRODUCT PROPERTIES.

CARCO URGES THE RECIPIENT OF THIS SDS TO STUDY IT CAREFULLY AND CONSULT
APPROPRIATE EXPERTISE, AS NECESSARY OR APPROPRIATE, TO BECOME AWARE OF AND
UNDERSTAND THE DATA CONTAINED IN THIS SDS AND ANY HAZARDS ASSOCIATED WITH
THE PRODUCT. THE INFORMATION HEREIN IS PROVIDED IN GOOD FAITH AND BELIEVED
TO BE ACCURATE AS OF THE EFFECTIVE DATE SHOWN ABOVE. THE USE OF THIS
PRODUCT IS BEYOND THE CONTROL CARCO OR IT'S DISTRIBUTOR, THEREFORE, NO
WARRANTY, EXPRESS OR IMPLIED, IS GIVEN. REGULATORY REQUIREMENTS A RE
SUBJECT TO CHANGE AND MAY DIFFER BETWEEN VARIOUS LOCATIONS. IT IS THE
BUYER'S/USER'S RESPONSIBILITY TO ENSURE THAT HIS ACTIVITIES COMPLY WITH ALL
FEDERAL, STATE, PROVINCIAL OR LOCAL LAWS. THE INFORMATION PRESENTED HERE
PERTAINS ONLY TO THE PRODUCT AS SHIPPED. SINCE CONDITIONS FOR USE OF THE
PRODUCT ARE NOT UNDER THE CONTROL OF THE MANUFACTURER, IT IS THE
BUYER'S/USER'S DUTY TO DETERMINE THE CONDITIONS NECESSARY FOR THE SAFE USE
OF THIS PRODUCT.