| Common Name: | XX-1346 MARKING FLUID, BLACK |
| Manufacturer: | CARCO |
| SDS Revision Date: | 2/1/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 40LG08 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
CARCO, INC
SAFETY DATA SHEET
XX-1346 MARKING FLUID, BLACK
SDS REVISION DATE: 2/1/2017
| 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
PRODUCT IDENTITY: XX-1346 MARKING FLUID, BLACK
ALTERNATE NAMES: XX-1346 MARKING FLUID, BLACK
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
INTENDED USE: SEE TECHNICAL DATA SHEET.
APPLICATION METHOD: SEE TECHNICAL DATA SHEET.
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
COMPANY NAME:
CARCO, INC
10333 SHOEMAKER
P.O. BOX 13859
DETROIT, MICHIGAN, 48213
USA
EMERGENCY:
24 HOUR EMERGENCY TELEPHONE NO.:
CHEMTEL: 1-800-255-3924 (MIS0001475)
INTERNATIONAL: +01-813-248-0585
CUSTOMER SERVICE: CARCO, INC
PHONE: +1 (313) 925-9000
FAX: +1 (313) 925-9602
EMAIL: SALES@CARCOUSA.NET
| 2. HAZARD IDENTIFICATION OF THE PRODUCT | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAM. LIQ. 2; H225: HIGHLY FLAMMABLE LIQUID AND VAPOR.
ACUTE TOX. 5; H303: MAY BE HARMFUL IF SWALLOWED. (NOT ADOPTED BY US OSHA)
ACUTE TOX. 5; H313:
MAY BE HARMFUL IN CONTACT WITH SKIN. (NOT ADOPTED BY US OSHA)
EYE IRRIT. 2; H319: CAUSES SERIOUS EYE IRRITATION.
STOT SE 3; H336: MAY CAUSE DROWSINESS OR DIZZINESS.
2.2. LABEL ELEMENTS:
USING THE TOXICITY DATA LISTED IN SECTION 11 AND 12 THE PRODUCT IS LABELED
AS FOLLOWS.
FLAME
EXCLAMATION MARK
DANGER
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR.
H303: MAY BE HARMFUL IF SWALLOWED.
H313: MAY BE HARMFUL IN CONTACT WITH SKIN.
H319: CAUSES SERIOUS EYE IRRITATION.
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
[PREVENTION]:
P210:
KEEP AWAY FROM HEAT / SPARKS / OPEN FLAMES / HOT SURFACES - NO SMOKING.
P241: USE EXPLOSION-PROOF ELECTRICAL / VENTILATING / LIGHT / EQUIPMENT.
P264: WASH THOROUGHLY AFTER HANDLING.
P280: WEAR PROTECTIVE GLOVES / EYE PROTECTION / FACE PROTECTION.
[RESPONSE]:
P303+361+353:
IF ON SKIN (OR HAIR):
REMOVE / TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER / SHOWER.
P305+351+338:
IF IN EYES:
RINSE CONTINUOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES IF
PRESENT AND EASY TO DO - CONTINUE RINSING.
P312: CALL A POISON CENTER OR DOCTOR / PHYSICIAN IF YOU FEEL UNWELL.
P337+313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE / ATTENTION.
P370+378:
IN CASE OF FIRE:
USE EXTINGUISHING MEDIA LISTED IN SECTION 5 OF SDS FOR EXTINCTION.
[STORAGE]:
P403+233: STORE IN A WELL VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
[DISPOSAL]:
P501:
DISPOSE OF CONTENTS / CONTAINER IN ACCORDANCE WITH LOCAL / NATIONAL
REGULATIONS.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES THAT PRESENT A HAZARD
WITHIN THE MEANING OF THE RELEVANT STATE AND FEDERAL HAZARDOUS SUBSTANCES
REGULATIONS.
INGREDIENT/CHEMICAL DESIGNATIONS WEIGHT % GHS CLASSIFICATION NOTES
ACETONE 75 - 100 FLAM. LIQ. 2; H225 [1][2]
CAS NUMBER: 0000067-64-1 EYE IRRIT. 2; H319
STOT SE 3; H336
N-BUTYL ACETATE 1.0 - 10 FLAM. LIQ. 3;H226 [1][2]
CAS NUMBER: 0000123-86-4 STOT SE 3; H336
ETHANOL 1.0 - 10 FLAM. LIQ. 2; H225 [1][2]
CAS NUMBER: 0000064-17-5
CELLULOSE NITRATE 1.0 - 10 EXPL. 1.1; H201 [1]
CAS NUMBER: 0009004-70-0
ISOPROPYL ALCOHOL 1.0 - 10 FLAM. LIQ. 2; H225 [1][2]
CAS NUMBER: 0000067-63-0 EYE IRRIT. 2; H319
STOT SE 3; H336
ETHYL ACETATE 1.0 - 10 FLAM. LIQ. 2; H225 [1][2]
CAS NUMBER: 0000141-78-6 EYE IRRIT. 2; H319
STOT SE 3; H336
CARBON BLACK 1.0 - 10 [1][2]
CAS NUMBER: 0001333-86-4
[1] SUBSTANCE CLASSIFIED WITH A HEALTH OR ENVIRONMENTAL HAZARD.
[2] SUBSTANCE WITH A WORKPLACE EXPOSURE LIMIT.
[3] PBT-SUBSTANCE OR VPVB-SUBSTANCE.
*THE FULL TEXTS OF THE PHRASES ARE SHOWN IN SECTION 16.
| 4. FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
GENERAL:
IN ALL CASES OF DOUBT, OR WHEN SYMPTOMS PERSIST, SEEK MEDICAL ATTENTION.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
INHALATION:
MOVE THE EXPOSED PERSON TO FRESH AIR AT ONCE. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. GIVE OXYGEN. GET MEDICAL ATTENTION IF ANY
DISCOMFORT CONTINUES
EYES:
MAKE SURE TO REMOVE ANY CONTACT LENSES FROM THE EYES BEFORE RINSING.
PROMPTLY WASH EYES WITH PLENTY OF WATER WHILE LIFTING THE EYE LIDS.
CONTINUE TO RINSE FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION IF ANY
DISCOMFORT CONTINUES.
SKIN:
REMOVE CONTAMINATED CLOTHING. WASH SKIN THOROUGHLY WITH SOAP AND WATER OR
USE A RECOGNIZED SKIN CLEANSER.
INGESTION:
DO NOT INDUCE VOMITING!
IF SWALLOWED, VOMITING MAY OCCUR SPONTANEOUSLY. IF VOMITING OCCURS, KEEP
HEAD BELOW HIPS TO PREVENT ASPIRATION INTO LUNGS. RINSE MOUTH THOROUGHLY.
GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
OVERVIEW:
INGESTION:
MAY CAUSE STOMACH PAIN OR VOMITING. EXPOSURE TO SOLVENT VAPOR
CONCENTRATIONS FROM THE COMPONENT SOLVENTS IN EXCESS OF THE STATED
OCCUPATIONAL EXPOSURE LIMITS MAY RESULT IN ADVERSE HEALTH EFFECTS SUCH AS
MUCOUS MEMBRANE AND RESPIRATORY SYSTEM IRRITATION AND ADVERSE EFFECTS ON
THE KIDNEYS, LIVER AND CENTRAL NERVOUS SYSTEM. SYMPTOMS INCLUDE HEADACHE,
NAUSEA, DIZZINESS, FATIGUE, MUSCULAR WEAKNESS, DROWSINESS AND IN EXTREME
CASES, LOSS OF CONSCIOUSNESS.
REPEATED OR PROLONGED CONTACT WITH THE PREPARATION MAY CAUSE REMOVAL OF
NATURAL FAT FROM THE SKIN RESULTING IN DRYNESS, IRRITATION AND POSSIBLE
NON-ALLERGIC CONTACT DERMATITIS. SOLVENTS MAY ALSO BE ABSORBED THROUGH THE
SKIN. SPLASHES OF LIQUID IN THE EYES MAY CAUSE IRRITATION AND SORENESS WITH
POSSIBLE REVERSIBLE DAMAGE. SEE SECTION 2 FOR FURTHER DETAILS.
INHALATION: MAY CAUSE DROWSINESS OR DIZZINESS.
EYES: CAUSES SERIOUS EYE IRRITATION.
SKIN: MAY BE HARMFUL IN CONTACT WITH SKIN. (NOT ADOPTED BY US OSHA)
INGESTION: MAY BE HARMFUL IF SWALLOWED. (NOT ADOPTED BY US OSHA)
| 5. FIRE-LIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
USE FOAM, EXTINGUISHING POWDER, DRY CHEMICALS, OR CARBON DIOXIDE. WATER
MAY BE INEFFECTIVE. WATER MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
HAZARDOUS DECOMPOSITION:
OXIDES OF CARBON AND NITROGEN, LOW MOLECULAR WEIGHT HYDROCARBONS AND
ORGANIC ACIDS.
KEEP AWAY FROM HEAT / SPARKS / OPEN FLAMES / HOT SURFACES - NO SMOKING.
USE EXPLOSION-PROOF ELECTRICAL / VENTILATING / LIGHT / EQUIPMENT.
5.3. ADVICE FOR FIRE-FIGHTERS:
IN THE EVENT OF FIRE, WEAR FULL PROTECTIVE CLOTHING AND NIOSH APPROVED
SELF-CONTAINED BREATHING APPARATUS WITH FULL FACE PIECE OPERATED IN THE
PRESSURE DEMAND OR OTHER POSITIVE PRESSURE MODE. MOVE CONTAINER FROM FIRE
AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER TO KEEP FIRE EXPOSED
CONTAINERS COOL AND DISPERSE VAPORS.
ERG GUIDE NO.: 129
| 6. ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
REMOVE SOURCES OF IGNITION, DO NOT TURN LIGHTS OR UNPROTECTED ELECTRICAL
EQUIPMENT ON OR OFF. IN CASE OF A MAJOR SPILL OR SPILLAGE IN A CONFINED
SPACE EVACUATE THE AREA AND CHECK THAT SOLVENT VAPOR LEVELS ARE BELOW THE
LOWER EXPLOSIVE LIMIT BEFORE RE-ENTERING.
6.2. ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW SPILLS TO ENTER DRAINS OR WATERWAYS.
USE GOOD PERSONAL HYGIENE PRACTICES. WASH HANDS BEFORE EATING, DRINKING,
SMOKING OR USING TOILET. PROMPTLY REMOVE SOILED CLOTHING AND WASH
THOROUGHLY BEFORE REUSE.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
AVOID SPARKS, FLAMES, HEAT AND SMOKING. VENTILATE. WEAR NECESSARY
PROTECTIVE EQUIPMENT. ABSORB IN VERMICULITE, DRY SAND OR EARTH AND PLACE
INTO CONTAINERS.
SMALL SPILL:
USE A NON-COMBUSTIBLE MATERIAL LIKE VERMICULITE, SAND OR EARTH TO SOAK UP
PRODUCT AND PLACE IN A CONTAINER FOR LATER DISPOSAL.
| 7. HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
KEEP IN CONTAINERS LIGHTLY CLOSED IN A COOL, WELL VENTILATED PLACE. DO NOT
STORE WITH OXIDIZING AGENTS OR ACIDS. KEEP IN THE ORIGINAL CONTAINER. AVOID
DIRECT SUNLIGHT
STORE IN ACCORDANCE WITH THE NATIONAL FIRE PROTECTION ASSOCIATION'S
PUBLICATION NFPA 30, FLAMMABLE AND COMBUSTIBLE LIQUIDS CODE. 29 CFR
1910.106 APPLIES TO THE HANDLING, STORAGE, AND USE OF FLAMMABLE AND
COMBUSTIBLE LIQUIDS.
SEE SECTION 2 FOR FURTHER DETAILS. - [PREVENTION]:
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
HANDLE CONTAINERS CAREFULLY TO PREVENT DAMAGE AND SPILLAGE.
STORE IN A COOL DRY AREA, AWAY FROM HEAT, SPARKS AND OPEN FLAME.
KEEP CONTAINERS SEALED WHEN NOT IN USE. STORE OUT OF DIRECT SUNLIGHT.
STORE IN A COOL DRY PLACE.
INCOMPATIBLE MATERIALS:
AVOID CONTACT WITH STRONG ACIDS AND BASES. CONTACT WITH STRONG OXIDIZERS
MAY CAUSE FIRE AND EXPLOSION.
STORE IN A WELL VENTILATED PLACE
SEE SECTION 2 FOR FURTHER DETAILS. - [STORAGE]:
7.3. SPECIFIC END USE(S): NO DATA AVAILABLE.
| 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
EXPOSURE:
CAS NO. INGREDIENT SOURCE VALUE
0000064-17-5 ETHANOL OSHA TWA: 1000 PPM (1900 MG/M3)
ACGIH STEL: 1000 PPM REVISED 2009,
NIOSH TWA: 1000 PPM (1900 MG/M3)
SUPPLIER NO ESTABLISHED LIMIT
0000067-63-0 ISOPROPYL OSHA TWA: 400 PPM (980 MG/M3)
ALCOHOL STEL: 500 PPM
ACGIH TWA: 200 PPM
STEL: 400 PPM REVISED 2003,
NIOSH TWA: 400 PPM (980 MG/M3)
ST: 500 PPM (1225 MG/M3)
SUPPLIER NO ESTABLISHED LIMIT
0000067-64-1 ACETONE OSHA TWA: 1000 PPM (2400 MG/M3)
STEL: 2400 MG/M3
ACGIH TWA: 250 PPM
STEL: 500 PPM SKIN
NIOSH 250 PPM (590 MG/M3) TWA
SUPPLIER NO ESTABLISHED LIMIT
0000123-86-4 N-BUTYL OSHA TWA: 150 PPM (710 MG/M3
ACETATE
ACGIH TWA: 20 PPMS
NIOSH TWA: 150 PPM (710 MG/M3)
ST: 200 PPM (950 MG/M3)
SUPPLIER NO ESTABLISHED LIMIT
0000141-78-6 ETHYL OSHA TWA: 400 PPM (1400 MG/M3)
ACETATE
ACGIH TWA: 150 PPM
NIOSH TWA: 400 PPM (1400 MG/M3)
SUPPLIER NO ESTABLISHED LIMIT
0001333-86-4 CARBON OSHA TWA: 3.5 MG/M3
BLACK
ACGIH TWA: 3 MG/M32B, REVISED 2011,
NIOSH TWA: 3.5 MG/M3 Ca
TWA:
0.1 MG PAHS/M3 [IN PRESENCE OF
POLYCYCLIC AROMATIC HYDROCARBONS
(PAHS)]
SUPPLIER NO ESTABLISHED LIMIT
0009004-70-0 CELLULOSE OSHA NO ESTABLISHED LIMIT
NITRATE
ACGIH NO ESTABLISHED LIMIT
NIOSH NO ESTABLISHED LIMIT
SUPPLIER NO ESTABLISHED LIMIT
CARCINOGEN DATA:
CAS NO. INGREDIENT SOURCE VALUE
0000064-17-5 ETHANOL OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: YES
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0000067-63-0 ISOPROPYL OSHA SELECT CARCINOGEN: NO
ALCOHOL
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: YES
GROUP 4: NO
0000067-64-1 ACETONE OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0000123-86-4 N-BUTYL OSHA SELECT CARCINOGEN: NO
ACETATE
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0000141-78-6 ETHYL OSHA SELECT CARCINOGEN: NO
ACETATE
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0001333-86-4 CARBON OSHA SELECT CARCINOGEN: NO
BLACK
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: YES
GROUP 3: NO
GROUP 4: NO
0009004-70-0 CELLULOSE OSHA SELECT CARCINOGEN: NO
NITRATE
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
8.2. EXPOSURE CONTROLS:
RESPIRATORY:
ATMOSPHERIC LEVELS SHOULD BE MAINTAINED BELOW THE EXPOSURE GUIDELINE.
WHEN RESPIRATORY PROTECTION IS REQUIRED FOR CERTAIN OPERATIONS, USE AN
APPROVED AIR-PURIFYING RESPIRATOR. THE FOLLOWING SHOULD BE EFFECTIVE TYPES
OF AIR PURIFYING RESPIRATORS: ORGANIC VAPOR CARTRIDGE.
EYES:
WEAR SAFETY EYEWEAR, E.G. SAFETY SPECTACLES, GOGGLES OR VISORS TO PROTECT
AGAINST THE SPLASH OF LIQUIDS.
SKIN:
OVERALLS WHICH COVER THE BODY, ARMS AND LEGS SHOULD BE WORN. SKIN SHOULD
NOT BE EXPOSED. ALL PARTS OF THE BODY SHOULD BE WASHED AFTER CONTACT. USE
GLOVES CHEMICALLY RESISTANT TO THIS MATERIAL WHEN PROLONGED OR FREQUENTLY
REPEATED CONTACT COULD OCCUR.
EXAMPLES OF PREFERRED GLOVE BARRIER MATERIALS INCLUDE:
BUTYL RUBBER. POLYETHYLENE/ETHYL VINYL ALCOHOL LAMINATE ("PE/EVAL").
EXAMPLES OF ACCEPTABLE GLOVE BARRIER MATERIALS INCLUDE:
NATURAL RUBBER ("LATEX"). NEOPRENE. NITRILE/BUTADIENE RUBBER ("NITRILE" OR
"NBR"). POLYVINYL CHLORIDE ("PVC" OR "VINYL"). VITON
ENGINEERING CONTROLS:
PROVIDE ADEQUATE VENTILATION. WHERE REASONABLY PRACTICABLE THIS SHOULD
BE ACHIEVED BY THE USE OF LOCAL EXHAUST VENTILATION AND GOOD GENERAL
EXTRACTION. IF THESE ARE NOT SUFFICIENT TO MAINTAIN CONCENTRATIONS OF
PARTICULATES AND ANY VAPOR BELOW OCCUPATIONAL EXPOSURE LIMITS SUITABLE
RESPIRATORY PROTECTION MUST BE WORN.
OTHER WORK PRACTICES:
DO NOT SMOKE, OR DRINK IN WORK AREA. KEEP AWAY FROM FOODSTUFFS AND
BEVERAGES. AVOID CONTACT WITH EYES AND SKIN.
USE GOOD PERSONAL HYGIENE PRACTICES. WASH HANDS BEFORE EATING, DRINKING,
SMOKING OR USING TOILET. PROMPTLY REMOVE SOILED CLOTHING AND WASH
THOROUGHLY BEFORE REUSE.
SEE SECTION 2 FOR FURTHER DETAILS. - [PREVENTION]:
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: COLORED LIQUID
ODOR: SWEET ACETONE
ODOR THRESHOLD: NOT MEASURED
PH: NOT MEASURED
MELTING POINT / FREEZING POINT: NOT MEASURED
INITIAL BOILING POINT AND BOILING RANGE:
56C
132F
FLASH POINT: -18C 0F METHOD (SETAFLASH)
EVAPORATION RATE (ETHER = 1): 5.2 (BU.AC=1)
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
LOWER EXPLOSIVE LIMIT: 2.6 (% IN AIR)
UPPER EXPLOSIVE LIMIT: 12.8 (% IN AIR)
VAPOR PRESSURE (PA): <185 (MMHg)
VAPOR DENSITY: >2 (AIR=1)
SPECIFIC GRAVITY: 0.810 G/ML TEMPERATURE (C) 20
SOLUBILITY IN WATER: 80%
PARTITION COEFFICIENT N-OCTANOL/WATER (LOG KOW): NOT MEASURED
AUTO-IGNITION TEMPERATURE: NOT MEASURED
DECOMPOSITION TEMPERATURE: NOT MEASURED
VISCOSITY (CST): NOT MEASURED
VOC %: 94 WT-% APPROXIMATELY 6.4 LBS/GAL
% VOLATILE: 75-85% (%-WT)
9.2. OTHER INFORMATION: NO OTHER RELEVANT INFORMATION.
| 10. STABILITY AND REACTIVITY | |
10.1. REACTIVITY: HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.2. CHEMICAL STABILITY: STABLE UNDER NORMAL CIRCUMSTANCES.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NO DATA AVAILABLE.
10.4. CONDITIONS TO AVOID:
AVOID CONTACT WITH OPEN FLAME, SPARKS OR HOT SURFACES.
10.5. INCOMPATIBLE MATERIALS:
AVOID CONTACT WITH STRONG ACIDS AND BASES. CONTACT WITH STRONG OXIDIZERS
MAY CAUSE FIRE AND EXPLOSION.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON AND NITROGEN, LOW MOLECULAR WEIGHT HYDROCARBONS AND
ORGANIC ACIDS.
| 11. TOXICOLOGICAL INFORMATION | |
ACUTE TOXICITY:
EXPOSURE TO SOLVENT VAPOR CONCENTRATIONS FROM THE COMPONENT SOLVENTS IN
EXCESS OF THE STATED OCCUPATIONAL EXPOSURE LIMITS MAY RESULT IN ADVERSE
HEALTH EFFECTS SUCH AS MUCOUS MEMBRANE AND RESPIRATORY SYSTEM IRRITATION
AND ADVERSE EFFECTS ON THE KIDNEYS, LIVER AND CENTRAL NERVOUS SYSTEM.
SYMPTOMS INCLUDE HEADACHE, NAUSEA, DIZZINESS, FATIGUE, MUSCULAR WEAKNESS,
DROWSINESS AND IN EXTREME CASES, LOSS OF CONSCIOUSNESS.
REPEATED OR PROLONGED CONTACT WITH THE PREPARATION MAY CAUSE REMOVAL OF
NATURAL FAT FROM THE SKIN RESULTING IN DRYNESS, IRRITATION AND POSSIBLE
NON-ALLERGIC CONTACT DERMATITIS. SOLVENTS MAY ALSO BE ABSORBED THROUGH THE
SKIN. SPLASHES OF LIQUID IN THE EYES MAY CAUSE IRRITATION AND SORENESS WITH
POSSIBLE REVERSIBLE DAMAGE.
INGREDIENT ORAL LD50, SKIN LD50,
MG/KG MG/KG
ACETONE - 2,000.00, RAT - 2,000.00, RABBIT -
(67-64-1) CATEGORY: 4 CATEGORY: 4
N-BUTYL ACETATE - 10,700.00, RAT - 17,600.00, RABBIT -
(123-86-4) CATEGORY: NA CATEGORY: NA
ETHANOL - 7,060.00, RAT - 20,000.00, RABBIT -
(64-17-5) CATEGORY: NA CATEGORY: NA
CELLULOSE NITRATE - 5,000.00, MOUSE - NO DATA AVAILABLE
(9004-70-0) CATEGORY: 5
ISOPROPYL ALCOHOL - 4,710.00, RAT - 12,800.00, RAT -
(67-63-0) CATEGORY: 5 CATEGORY: NA
ETHYL ACETATE - 5,600.00, RAT - 18,000.00, RABBIT -
(141-78-6) CATEGORY: NA CATEGORY: NA
CARBON BLACK - 8,000.00, RAT - NO DATA AVAILABLE
(1333-86-4) CATEGORY: NA
INGREDIENT INHALATION INHALATION INHALATION
VAPOR LD50, DUST/MIST LD50, GAS LD50,
MG/L/4HR MG/L/4HR PPM
ACETONE 76.00, RAT - NO DATA NO DATA
CATEGORY: NA AVAILABLE AVAILABLE
N-BUTYL ACETATE NO DATA NO DATA NO DATA
AVAILABLE AVAILABLE AVAILABLE
ETHANOL 124.70, RAT - NO DATA NO DATA
CATEGORY: NA AVAILABLE AVAILABLE
CELLULOSE NITRATE NO DATA NO DATA NO DATA
AVAILABLE AVAILABLE AVAILABLE
ISOPROPYL ALCOHOL 72.60, RAT - NO DATA NO DATA
CATEGORY: NA AVAILABLE AVAILABLE
ETHYL ACETATE 58.60, RAT - NO DATA NO DATA
CATEGORY: NA AVAILABLE AVAILABLE
CARBON BLACK NO DATA NO DATA NO DATA
AVAILABLE AVAILABLE AVAILABLE
NOTE:
WHEN NO ROUTE SPECIFIC LD50 DATA IS AVAILABLE FOR AN ACUTE TOXIN, THE
CONVERTED ACUTE TOXICITY POINT ESTIMATE WAS USED IN THE CALCULATION OF
THE PRODUCT'S ATE (ACUTE TOXICITY ESTIMATE).
CLASSIFICATION CATEGORY HAZARD DESCRIPTION
ACUTE TOXICITY (ORAL) 5 MAY BE HARMFUL IF SWALLOWED.
(NOT ADOPTED BY US OSHA)
ACUTE TOXICITY (DERMAL) 5 MAY BE HARMFUL IN CONTACT WITH
SKIN. (NOT ADOPTED BY US OSHA)
ACUTE TOXICITY (INHALATION) NOT APPLICABLE
SKIN CORROSION/IRRITATION NOT APPLICABLE
SERIOUS EYE DAMAGE/IRRITATION 2 CAUSES SERIOUS EYE IRRITATION.
RESPIRATORY SENSITIZATION NOT APPLICABLE
SKIN SENSITIZATION NOT APPLICABLE
GERM CELL MUTAGENICITY NOT APPLICABLE
CARCINOGENICITY NOT APPLICABLE
REPRODUCTIVE TOXICITY NOT APPLICABLE
STOT-SINGLE EXPOSURE 3 MAY CAUSE DROWSINESS OR
DIZZINESS.
STOT-REPEATED EXPOSURE NOT APPLICABLE
ASPIRATION HAZARD NOT APPLICABLE
| 12. ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
AQUATIC ECOTOXICITY:
INGREDIENT 96 HR LC50 FISH, 48 HR EC50 CRUSTACEA, ERC50 ALGAE,
MG/L MG/L MG/L
ACETONE - 100.00, 10.00, DAPHNIA MAGNA 20.565
(67-64-1) PIMEPHALES (72 HR),
PROMELAS ULVA PERTUSA
N-BUTYL ACETATE 18.00, 32.00, ARTEMIA 674.70
- (123-86-4) PIMEPHALES SALINA (72 HR),
PROMELAS SCENEDESMUS
SUBSPICATUS
ETHANOL - 42.00, 2.00, DAPHNIA MAGNA 17.921
(64-17-5) ONCORHYNCHUS (96 HR),
MYKISS ULVA PERTUSA
CELLULOSE NOT AVAILABLE NOT AVAILABLE 579.00
NITRATE - (96 HR),
(9004-70-0) PSEUDOKIR-
CHNERIELL A
SUBCAPITATA
ISOPROPYL 1,400.00, 100.00, DAPHNIA 100.00
ALCOHOL - LEPOMIS MAGNA (72 HR),
(67-63-0) MACROCHIRUS SCENEDESMUS
SUBSPICATUS
ETHYL ACETATE - 100.00, DANIO 100.00, DAPHNIA 100.00
(141-78-6) RERIO MAGNA (72 HR),
DESMODESMUS
SUBSPICATUS
CARBON BLACK - 1,000.00, 5,600.00, DAPHNIA 10,000.00
(1333-86-4) DANIO RERIO MAGNA (72 HR),
SCENEDESMUS
SUBSPICATUS
12.2. PERSISTENCE AND DEGRADABILITY:
THERE IS NO DATA AVAILABLE ON THE PREPARATION ITSELF.
12.3. BIOACCUMULATIVE POTENTIAL: NOT MEASURED
12.4. MOBILITY IN SOIL: NO DATA AVAILABLE.
12.5. RESULTS OF PBT AND VPVB ASSESSMENT:
THIS PRODUCT CONTAINS NO PBT/VPVB CHEMICALS.
12.6. OTHER ADVERSE EFFECTS: NO DATA AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
DO NOT ALLOW INTO DRAINS OR WATER COURSES. WASTES AND EMPTIED CONTAINERS
SHOULD BE DISPOSED OF IN ACCORDANCE WITH REGULATIONS MADE UNDER THE CONTROL
OF POLLUTION ACT AND THE ENVIRONMENTAL PROTECTION ACT.
USING INFORMATION PROVIDED IN THIS DATA SHEET ADVICE SHOULD BE OBTAINED
FROM THE WASTE REGULATION AUTHORITY, WHETHER THE SPECIAL WASTE REGULATIONS
APPLY.
| 14. TRANSPORT INFORMATION | |
DOT (DOMESTIC SURFACE IMO / IMDG (OCEAN ICAO/IATA
TRANSPORTATION) TRANSPORTATION)
14.1. UN UN1210 UN1210 UN1210
NUMBER
14.2. UN PRINTING INK PRINTING INK PRINTING INK
PROPER SHIPPING
NAME
14.3. TRANSPORT DOT HAZARD IMDG: 3 AIR CLASS:
HAZARD CLASS(ES) CLASS: 3 3 PACKING
SUB CLASS: INSTRUCTION:
DOT LABEL: 3 NOT APPLICABLE CARGO ONLY:
364
EMS: F-E, S-D PASSENGER:
353
14.4. PACKING II II II
GROUP
14.5. ENVIRONMENTAL HAZARDS:
IMDG:
MARINE POLLUTANT: YES
14.6. SPECIAL PRECAUTIONS FOR USER:
NO FURTHER INFORMATION
14.7. TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC
CODE: NOT APPLICABLE
| 15. REGULATORY INFORMATION | |
REGULATORY OVERVIEW:
THE REGULATORY DATA IN SECTION 15 IS NOT INTENDED TO BE ALL-INCLUSIVE, ONLY
SELECTED REGULATIONS ARE REPRESENTED. ALL COMPONENTS OF THIS MATERIAL ARE
EITHER LISTED OR EXEMPT FROM LISTING ON THE TSCA INVENTORY.
NFPA RANKINGS:
2
3
1
WHMIS CLASSIFICATION:
B2
D2B
B - FLAMMABLE AND COMBUSTIBLE MATERIAL
D2 - MATERIALS CAUSING OTHER TOXIC EFFECTS
US EPA TIER II HAZARDS:
FIRE: YES
SUDDEN RELEASE OF PRESSURE: NO
REACTIVE: NO
IMMEDIATE (ACUTE): YES
DELAYED (CHRONIC): NO
EPCRA 311/312 CHEMICALS AND RQS (LBS):
ACETONE (5,000.00)
ETHYL ACETATE (5,000.00)
N-BUTYL ACETATE (5,000.00)
EPCRA 302 EXTREMELY HAZARDOUS: (NO PRODUCT INGREDIENTS LISTED)
EPCRA 313 TOXIC CHEMICALS: ISOPROPYL ALCOHOL
PROPOSITION 65 - CARCINOGENS (>0.0%): CARBON BLACK
PROPOSITION 65 - DEVELOPMENTAL TOXINS (>0.0%):
(NO PRODUCT INGREDIENTS LISTED)
PROPOSITION 65 - FEMALE REPRO TOXINS (>0.0%):
(NO PRODUCT INGREDIENTS LISTED)
PROPOSITION 65 - MALE REPRO TOXINS (>0.0%):
(NO PRODUCT INGREDIENTS LISTED)
N.J. RTK SUBSTANCES (>1%):
ACETONE
CARBON BLACK
CELLULOSE NITRATE
ETHANOL
ETHYL ACETATE
ISOPROPYL ALCOHOL
N-BUTYL ACETATE
PENN RTK SUBSTANCES (>1%):
ACETONE
CARBON BLACK
CELLULOSE NITRATE
ETHANOL
ETHYL ACETATE
ISOPROPYL ALCOHOL
N-BUTYL ACETATE
| 16. OTHER INFORMATION | |
THE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED UPON DATA
BELIEVED TO BE CORRECT. HOWEVER, NO GUARANTEE OR WARRANTY OF ANY KIND,
EXPRESSED OR IMPLIED, IS MADE WITH RESPECT TO THE INFORMATION CONTAINED
HEREIN. WE ACCEPT NO RESPONSIBILITY AND DISCLAIM ALL LIABILITY FOR ANY
HARMFUL EFFECTS WHICH MAY BE CAUSED BY EXPOSURE TO OUR PRODUCTS.
CUSTOMERS/USERS OF THIS PRODUCT MUST COMPLY WITH ALL APPLICABLE HEALTH
AND SAFETY LAWS, REGULATIONS, AND ORDERS.
THE FULL TEXT OF THE PHRASES APPEARING IN SECTION 3 IS:
H201: EXPLOSIVE; MASS EXPLOSION HAZARD.
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR.
H226: FLAMMABLE LIQUID AND VAPOR.
H319: CAUSES SERIOUS EYE IRRITATION.
H336: MAY CAUSE DROWSINESS AND DIZZINESS.
THIS IS THE FIRST VERSION IN THE GHS SDS FORMAT. LISTINGS OF CHANGES FROM
PREVIOUS VERSIONS IN OTHER FORMATS ARE NOT APPLICABLE.
THIS PRODUCT IS ROHS AND REACH COMPLIANT. IT DOES NOT CONTAIN ANY OF THE
ROHS LISTED SUBSTANCES. IT DOES NOT CONTAIN ANY CHEMICAL FROM THE CANDIDATE
LIST OF SUBSTANCES OF VERY HIGH CONCERN (SVHC), ANNEX XIV, OR ANNEX XVII OF
REACH.
THIS INFORMATION IS BASED ON OUR PRESENT KNOWLEDGE. HOWEVER, IT DOES NOT
CONSTITUTE A GUARANTEE FOR ANY SPECIFIC PRODUCT PROPERTIES.
CARCO URGES THE RECIPIENT OF THIS SDS TO STUDY IT CAREFULLY AND CONSULT
APPROPRIATE EXPERTISE, AS NECESSARY OR APPROPRIATE, TO BECOME AWARE OF AND
UNDERSTAND THE DATA CONTAINED IN THIS SDS AND ANY HAZARDS ASSOCIATED WITH
THE PRODUCT. THE INFORMATION HEREIN IS PROVIDED IN GOOD FAITH AND BELIEVED
TO BE ACCURATE AS OF THE EFFECTIVE DATE SHOWN ABOVE. THE USE OF THIS
PRODUCT IS BEYOND THE CONTROL CARCO OR IT'S DISTRIBUTOR, THEREFORE, NO
WARRANTY, EXPRESS OR IMPLIED, IS GIVEN. REGULATORY REQUIREMENTS ARE
SUBJECT TO CHANGE AND MAY DIFFER BETWEEN VARIOUS LOCATIONS. IT IS THE
BUYER'S/USER'S RESPONSIBILITY TO ENSURE THAT HIS ACTIVITIES COMPLY WITH
ALL FEDERAL, STATE, PROVINCIAL OR LOCAL LAWS. THE INFORMATION PRESENTED
HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED. SINCE CONDITIONS FOR USE OF
THE PRODUCT ARE NOT UNDER THE CONTROL OF THE MANUFACTURER, IT IS THE
BUYER'S/USER'S DUTY TO DETERMINE THE CONDITIONS NECESSARY FOR THE SAFE
USE OF THIS PRODUCT.