SDS Table of Contents Click the desired link below to jump directly to that section in the SDS. ASHLAND(R*) SAFETY DATA SHEET REVISION DATE: 05/26/2015 PRINT DATE: 6/2/2015 SDS NUMBER: A-204 PLIOBOND(TM) 35 ADHESIVE (TM) TRADEMARK, ASHLAND OR ITS SUBSIDIARIES, REGISTERED IN VARIOUS COUNTRIES 167510 29 CFR 1910.1200 (OSHA HAZCOM 2012)
PRODUCT IDENTIFIER: TRADE NAME: PLIOBOND(TM) 35 ADHESIVE (TM) TRADEMARK, ASHLAND OR ITS SUBSIDIARIES, REGISTERED IN VARIOUS COUNTRIES PACKAGED AND MARKETED BY: THE RUSCOE COMPANY 485 KENMORE BLVD. AKRON OHIO 44301 PH: 330-253-8148 TOLL FREE: 800-293-8148 FAX: 330-253-2933 RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE: DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET: ASHLAND P.O. BOX 2219 COLUMBUS, OH 43216 UNITED STATES OF AMERICA EMERGENCY TELEPHONE NUMBER: 1-800-ASHLAND (1-800-274-5263) REGULATORY INFORMATION NUMBER: 1-800-325-3751 PRODUCT INFORMATION: 614-790-3333 EHS CUSTOMER REQUESTS@ASHLAND.COM
GHS CLASSIFICATION: FLAMMABLE LIQUIDS: CATEGORY 2 EYE IRRITATION: CATEGORY 2A SKIN SENSITIZATION: CATEGORY 1 CARCINOGENICITY: CATEGORY 1B SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY - SINGLE EXPOSURE: CATEGORY 3 (CENTRAL NERVOUS SYSTEM) GHS LABEL ELEMENT: HAZARD PICTOGRAMS: FLAME HEALTH HAZARD EXCLAMATION MARK SIGNAL WORD: DANGER HAZARD STATEMENTS: HIGHLY FLAMMABLE LIQUID AND VAPOR. MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES SERIOUS EYE IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS. MAY CAUSE CANCER. PRECAUTIONARY STATEMENTS: PREVENTION: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. KEEP CONTAINER TIGHTLY CLOSED. GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT. USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING/EQUIPMENT. USE ONLY NON-SPARKING TOOLS. TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE. AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY. WASH SKIN THOROUGHLY AFTER HANDLING. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION. RESPONSE: IF ON SKIN (OR HAIR): TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER/SHOWER. IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL. IF IN EYES: RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION. IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION. IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE. IN CASE OF FIRE: USE DRY SAND, DRY CHEMICAL OR ALCOHOL-RESISTANT FOAM TO EXTINGUISH. STORAGE: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE IN A WELL-VENTILATED PLACE. KEEP COOL. STORE LOCKED UP. DISPOSAL: DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT. OTHER HAZARDS: NONE KNOWN.
SUBSTANCE/MIXTURE: MIXTURE CHEMICAL NATURE: DEFATTER HAZARDOUS COMPONENTS: CHEMICAL NAME CAS-NO. CLASSIFICATION CONCENTRATION (%) ACETONE 67-64-1 FLAM. LIQ. 2; H225 62.21 EYE IRRIT. 2A; H319 STOT SE 3; H336 METHYL ETHYL KETONE 78-93-3 FLAM. LIQ. 2; H225 7.00 EYE IRRIT. 2A; H319 STOT SE 3; H336 CALCIUM CARBONATE 471-34-1 3.80 BENZOTHIAZYL 120-78-5 SKIN SENS. 1; H317 0.12 DISULFIDE FORMALDEHYDE 50-00-0 FLAM. LIQ. 4; H227 0.10 ACUTE TOX. 3; H301 ACUTE TOX. 3; H331 ACUTE TOX. 3; H311 SKIN CORR. 1B; H314 EYE DAM. 1; H318 SKIN SENS. 1; H317 CARC. 1B; H350
GENERAL ADVICE: MOVE OUT OF DANGEROUS AREA. CALL A POISON CENTRE OR DOCTOR/PHYSICIAN IF EXPOSED OR YOU FEEL UNWELL. SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE. DO NOT LEAVE THE VICTIM UNATTENDED. IF INHALED: MOVE TO FRESH AIR. IF UNCONSCIOUS PLACE IN RECOVERY POSITION AND SEEK MEDICAL ADVICE. CONSULT A PHYSICIAN AFTER SIGNIFICANT EXPOSURE. IN CASE OF SKIN CONTACT: REMOVE CONTAMINATED CLOTHING. IF IRRITATION DEVELOPS, GET MEDICAL ATTENTION. IF ON SKIN, RINSE WELL WITH WATER. FIRST AID IS NOT NORMALLY REQUIRED. HOWEVER, IT IS RECOMMENDED THAT EXPOSED AREAS BE CLEANED BY WASHING WITH SOAP AND WATER. WASH CONTAMINATED CLOTHING BEFORE RE-USE. IF ON CLOTHES, REMOVE CLOTHES. IN CASE OF EYE CONTACT: IMMEDIATELY FLUSH EYE(S) WITH PLENTY OF WATER. REMOVE CONTACT LENSES. PROTECT UNHARMED EYE. IF SWALLOWED: OBTAIN MEDICAL ATTENTION. DO NOT GIVE MILK OR ALCOHOLIC BEVERAGES. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF SYMPTOMS PERSIST, CALL A PHYSICIAN. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED: THIS MATERIAL (OR A COMPONENT) HAS PRODUCED HYPERGLYCEMIA AND KETOSIS FOLLOWING SUBSTANTIAL INGESTION. INGESTION OF LARGE AMOUNTS OR OTHER SIGNIFICANT EXPOSURE TO THIS MATERIAL (OR A COMPONENT) MAY CAUSE ALKALOSIS. EXCESSIVE CALCIUM INTAKE MAY CAUSE GASTROINTESTINAL SYMPTOMS, HYPERTENSION, HYPERCALCEMIA, KIDNEY STONES, AND MAY INHIBIT ABSORPTION OF IRON, ZINC, AND POSSIBLY OTHER TRACE ELEMENTS. SIGNS AND SYMPTOMS OF EXPOSURE TO THIS MATERIAL THROUGH BREATHING, SWALLOWING, AND/OR PASSAGE OF THE MATERIAL THROUGH THE SKIN MAY INCLUDE: STOMACH OR INTESTINAL UPSET (NAUSEA, VOMITING, DIARRHEA) IRRITATION (NOSE, THROAT, AIRWAYS) MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES SERIOUS EYE IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS. MAY CAUSE CANCER. NOTES TO PHYSICIAN: NO HAZARDS WHICH REQUIRE SPECIAL FIRST AID MEASURES.
SUITABLE EXTINGUISHING MEDIA: USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND THE SURROUNDING ENVIRONMENT. WATER SPRAY FOAM ALCOHOL-RESISTANT FOAM CARBON DIOXIDE (CO2) DRY CHEMICAL UNSUITABLE EXTINGUISHING MEDIA: HIGH VOLUME WATER JET SPECIFIC HAZARDS DURING FIREFIGHTING: NEVER USE WELDING OR CUTTING TORCH ON OR NEAR DRUM (EVEN EMPTY) BECAUSE PRODUCT (EVEN JUST RESIDUE) CAN IGNITE EXPLOSIVELY. BEWARE OF VAPOURS ACCUMULATING TO FORM EXPLOSIVE CONCENTRATIONS. VAPOURS CAN ACCUMULATE IN LOW AREAS. DO NOT ALLOW RUN-OFF FROM FIRE FIGHTING TO ENTER DRAINS OR WATER COURSES. HAZARDOUS COMBUSTION PRODUCTS: CARBON DIOXIDE AND CARBON MONOXIDE HYDROGEN CYANIDE (HYDROCYANIC ACID) NITROGEN OXIDES (NOX) CALCIUM OXIDE SPECIFIC EXTINGUISHING METHODS: PRODUCT IS COMPATIBLE WITH STANDARD FIRE-FIGHTING AGENTS. FURTHER INFORMATION: FIRE RESIDUES AND CONTAMINATED FIRE EXTINGUISHING WATER MUST BE DISPOSED OF IN ACCORDANCE WITH LOCAL REGULATIONS. USE A WATER SPRAY TO COOL FULLY CLOSED CONTAINERS. SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS: IN THE EVENT OF FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS.
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES: EVACUATE PERSONNEL TO SAFE AREAS. REMOVE ALL SOURCES OF IGNITION. USE PERSONAL PROTECTIVE EQUIPMENT. ENSURE ADEQUATE VENTILATION. BEWARE OF VAPOURS ACCUMULATING TO FORM EXPLOSIVE CONCENTRATIONS. VAPOURS CAN ACCUMULATE IN LOW AREAS. PERSONS NOT WEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED. ENVIRONMENTAL PRECAUTIONS: PREVENT PRODUCT FROM ENTERING DRAINS. PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. IF THE PRODUCT CONTAMINATES RIVERS AND LAKES OR DRAINS INFORM RESPECTIVE AUTHORITIES. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP: CONTAIN SPILLAGE, AND THEN COLLECT WITH NON-COMBUSTIBLE ABSORBENT MATERIAL, (E.G. SAND, EARTH, DIATOMACEOUS EARTH, VERMICULITE) AND PLACE IN CONTAINER FOR DISPOSAL ACCORDING TO LOCAL / NATIONAL REGULATIONS (SEE SECTION 13). OTHER INFORMATION: COMPLY WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL REGULATIONS.
ADVICE ON SAFE HANDLING: OPEN DRUM CAREFULLY AS CONTENT MAY BE UNDER PRESSURE. AVOID FORMATION OF AEROSOL. PROVIDE SUFFICIENT AIR EXCHANGE AND/OR EXHAUST IN WORK ROOMS. DO NOT BREATHE VAPOURS/DUST. DO NOT SMOKE. PERSONS SUSCEPTIBLE TO SKIN SENSITISATION PROBLEMS OR ASTHMA, ALLERGIES, CHRONIC OR RECURRENT RESPIRATORY DISEASE SHOULD NOT BE EMPLOYED IN ANY PROCESS IN WHICH THIS MIXTURE IS BEING USED. CONTAINER HAZARDOUS WHEN EMPTY. TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGES. AVOID EXPOSURE - OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. AVOID CONTACT WITH SKIN AND EYES. SMOKING, EATING AND DRINKING SHOULD BE PROHIBITED IN THE APPLICATION AREA. FOR PERSONAL PROTECTION SEE SECTION 8. DISPOSE OF RINSE WATER IN ACCORDANCE WITH LOCAL AND NATIONAL REGULATIONS. CONDITIONS FOR SAFE STORAGE: KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE. CONTAINERS WHICH ARE OPENED MUST BE CAREFULLY RESEALED AND KEPT UPRIGHT TO PREVENT LEAKAGE. OBSERVE LABEL PRECAUTIONS. NO SMOKING. ELECTRICAL INSTALLATIONS / WORKING MATERIALS MUST COMPLY WITH THE TECHNOLOGICAL SAFETY STANDARDS.
COMPONENTS WITH WORKPLACE CONTROL PARAMETERS: COMPONENTS CAS-NO. VALUE TYPE CONTROL BASIS (FORM OF PARAMETERS/ EXPOSURE) PERMISSIBLE CONCENTRATION ACETONE 67-64-1 TWA 500 PPM ACGIH STEL 750 PPM ACGIH REL 250 PPM NIOSH/GUIDE 590 MG/M3 PEL 1,000 PPM OSHA_TRANS 2,400 MG/M3 TWA 250 PPM ACGIHLIS_P STEL 500 PPM ACGIHLIS_P TWA 750 PPM Z1A 1,800 MG/M3 STEL 1,000 PPM Z1A 2,400 MG/M3 METHYL ETHYL KETONE 78-93-3 TWA 200 PPM ACGIH STEL 300 PPM ACGIH REL 200 PPM NIOSH/GUIDE 590 MG/M3 STEL 300 PPM NIOSH/GUIDE 885 MG/M3 PEL 200 PPM OSHA_TRANS 590 MG/M3 CALCIUM CARBONATE 471-34-1 PEL 5 MG/M3 OSHA_TRANS RESPIRABLE FRACTION. PEL 15 MG/M3 OSHA_TRANS TOTAL DUST. REL 5 MG/M3 NIOSH/GUIDE RESPIRABLE. REL 10 MG/M3 NIOSH/GUIDE TOTAL FORMALDEHYDE 50-00-0 CEILING 0.3 PPM ACGIH REL 0.016 PPM NIOSH/GUIDE CEIL_TIME 0.1 PPM NIOSH/GUIDE TWA 0.75 PPM OSHASP STEL 2 PPM OSHASP OSHA_ACT 0.5 PPM OSHASP CEILING 0.3 PPM ACGIHLIS_P BIOLOGICAL OCCUPATIONAL EXPOSURE LIMITS: COMPONENTS CAS-NO. CONTROL BIOLOGICAL SAMPLING PERMISSIBLE BASIS PARAMETERS SPECIMEN TIME CONCENTRATION ACETONE 67-64-1 ACETONE URINE SAMPLING 50 MG/L TIME: END OF SHIFT. REMARKS NONSPECIFIC METHYL 78-93-3 METHYL- URINE SAMPLING 2 MG/L ACGIH ETHYL ETHYL TIME: BEI KETONE KETONE END OF SHIFT. REMARKS NONSPECIFIC ENGINEERING MEASURES: PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW EXPOSURE GUIDELINES (IF APPLICABLE) OR BELOW LEVELS THAT CAUSE KNOWN, SUSPECTED OR APPARENT ADVERSE EFFECTS. PERSONAL PROTECTIVE EQUIPMENT: RESPIRATORY PROTECTION: IN THE CASE OF VAPOUR FORMATION USE A RESPIRATOR WITH AN APPROVED FILTER. A NIOSH-APPROVED AIR-PURIFYING RESPIRATOR WITH AN APPROPRIATE CARTRIDGE AND/OR FILTER MAY BE PERMISSIBLE UNDER CERTAIN CIRCUMSTANCES WHERE AIRBORNE CONCENTRATIONS ARE EXPECTED TO EXCEED EXPOSURE LIMITS (IF APPLICABLE) OR IF OVEREXPOSURE HAS OTHERWISE BEEN DETERMINED. PROTECTION PROVIDED BY AIR-PURIFYING RESPIRATORS IS LIMITED. USE A POSITIVE PRESSURE, AIR-SUPPLIED RESPIRATOR IF THERE IS ANY POTENTIAL FOR UNCONTROLLED RELEASE, EXPOSURE LEVELS ARE NOT KNOWN OR ANY OTHER CIRCUMSTANCES WHERE AN AIR-PURIFYING RESPIRATOR MAY NOT PROVIDE ADEQUATE PROTECTION. HAND PROTECTION: REMARKS: THE SUITABILITY FOR A SPECIFIC WORKPLACE SHOULD BE DISCUSSED WITH THE PRODUCERS OF THE PROTECTIVE GLOVES. EYE PROTECTION: WEAR CHEMICAL SPLASH GOGGLES WHEN THERE IS THE POTENTIAL FOR EXPOSURE OF THE EYES TO LIQUID, VAPOR OR MIST. SKIN AND BODY PROTECTION: WEAR AS APPROPRIATE: IMPERVIOUS CLOTHING SAFETY SHOES FLAME-RESISTANT CLOTHING CHOOSE BODY PROTECTION ACCORDING TO THE AMOUNT AND CONCENTRATION OF THE DANGEROUS SUBSTANCE AT THE WORK PLACE. DISCARD GLOVES THAT SHOW TEARS, PINHOLES, OR SIGNS OF WEAR. WEAR RESISTANT GLOVES (CONSULT YOUR SAFETY EQUIPMENT SUPPLIER). HYGIENE MEASURES: WASH HANDS BEFORE BREAKS AND AT THE END OF WORKDAY. WHEN USING DO NOT EAT OR DRINK. WHEN USING DO NOT SMOKE.
PHYSICAL STATE: LIQUID COLOUR: TAN ODOUR: NO DATA AVAILABLE ODOUR THRESHOLD: NO DATA AVAILABLE PH: NO DATA AVAILABLE MELTING POINT/FREEZING POINT: NO DATA AVAILABLE BOILING POINT/BOILING RANGE: NO DATA AVAILABLE FLASH POINT: <19 DEG. F/<-7 DEG. C METHOD: SETA CLOSED CUP EVAPORATION RATE: NO DATA AVAILABLE FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE UPPER EXPLOSION LIMIT: NO DATA AVAILABLE LOWER EXPLOSION LIMIT: NO DATA AVAILABLE VAPOUR PRESSURE: NO DATA AVAILABLE RELATIVE VAPOUR DENSITY: <1AIR=1 RELATIVE DENSITY: 0.89 (77.00 DEG. F) DENSITY: 0.89 G/CM3 (77.00 DEG. F) SOLUBILITY(IES): WATER SOLUBILITY: NO DATA AVAILABLE SOLUBILITY IN OTHER SOLVENTS: NO DATA AVAILABLE PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE THERMAL DECOMPOSITION: NO DATA AVAILABLE VISCOSITY: VISCOSITY, DYNAMIC: NO DATA AVAILABLE VISCOSITY, KINEMATIC: NO DATA AVAILABLE OXIDIZING PROPERTIES: NO DATA AVAILABLE
REACTIVITY: NO DECOMPOSITION IF STORED AND APPLIED AS DIRECTED. CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS. POSSIBILITY OF HAZARDOUS REACTIONS: VAPOURS MAY FORM EXPLOSIVE MIXTURE WITH AIR. FORMALDEHYDE REACTS WITH PEROXIDES, PHENOL, STRONG ACIDS, AMINES AND STRONG OXIDIZING AGENTS. FORMALDEHYDE REACTS VIOLENTLY WITH NITROGEN DIOXIDE, NITROMETHANE, PERCHLORIC ACID, PERCHLORIC ACID-ANILINE MIXTURES, OR PEROXYFORMIC ACID TO YIELD EXPLOSIVE COMPOUNDS.IT REACTS WITH HYDROCHLORIC ACID OR TO ORGANIC CHLORIDES TO FORM THE CARCINOGEN, BIS(CHLOROMETHYL)ETHER. CONDITIONS TO AVOID: HEAT, FLAMES AND SPARKS. INCOMPATIBLE MATERIALS: ACIDS ALKALIS AMMONIUM SALTS ALUMINUM SALTS AMINES AMMONIA COPPER COPPER ALLOYS HALOGENS PEROXIDES REDUCING AGENTS STRONG ALKALIS STRONG OXIDIZING AGENTS HAZARDOUS DECOMPOSITION PRODUCTS: CALCIUM OXIDE CARBON DIOXIDE AND CARBON MONOXIDE
INFORMATION ON LIKELY ROUTES OF EXPOSURE: INHALATION SKIN CONTACT EYE CONTACT INGESTION ACUTE TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION. COMPONENTS: ACETONE: ACUTE ORAL TOXICITY: LD 50 (RAT, FEMALE): 5,800 MG/KG ACUTE INHALATION TOXICITY: LC 50 (RAT, FEMALE): 76 MG/L EXPOSURE TIME: 4 H ACUTE DERMAL TOXICITY: LD 50 (RABBIT): >7,426 MG/KG METHYL ETHYL KETONE: ACUTE ORAL TOXICITY: LD 50 (RAT): 2,300 - 3,500 MG/KG ACUTE DERMAL TOXICITY: LD 50 (RABBIT): >5 G/KG CALCIUM CARBONATE: ACUTE ORAL TOXICITY: LD 50 (RAT): 6,450 MG/KG ACUTE INHALATION TOXICITY: LC 50 (RAT): >3 MG/L EXPOSURE TIME: 4 H METHOD: OECD TEST GUIDELINE 403 ASSESSMENT: NOT CLASSIFIED AS ACUTELY TOXIC BY INHALATION UNDER GHS. REMARKS: AEROSOL ACUTE DERMAL TOXICITY: LD 50 (RAT): >2,000 MG/KG METHOD: OECD TEST GUIDELINE 402 BENZOTHIAZYL DISULFIDE: ACUTE ORAL TOXICITY: LD 50 (RAT): >12 G/KG ACUTE DERMAL TOXICITY: LD 50 (RABBIT): >7,940 MG/KG FORMALDEHYDE: ACUTE ORAL TOXICITY: LD 50 (GUINEA PIG): 260 MG/KG LD 50 (RAT): 100 MG/KG LD 50 (RAT, MALE): 800 MG/KG ASSESSMENT: THE COMPONENT/MIXTURE IS CLASSIFIED AS ACUTE ORAL TOXICITY, CATEGORY 3. ACUTE INHALATION TOXICITY: LC 50 (RAT): 588 MG/M3 EXPOSURE TIME: 4 H TEST ATMOSPHERE: GAS ASSESSMENT: THE COMPONENT/MIXTURE IS CLASSIFIED AS ACUTE INHALATION TOXICITY, CATEGORY 3. ACUTE DERMAL TOXICITY: LD 50 (RABBIT): 288 MG/KG SKIN CORROSION/IRRITATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION. PRODUCT: RESULT: REPEATED EXPOSURE MAY CAUSE SKIN DRYNESS OR CRACKING. REMARKS: MAY CAUSE SKIN IRRITATION IN SUSCEPTIBLE PERSONS. COMPONENTS: ACETONE: RESULT: MILDLY IRRITATING TO SKIN RESULT: REPEATED EXPOSURE MAY CAUSE SKIN DRYNESS OR CRACKING. METHYL ETHYL KETONE: RESULT: NOT IRRITATING TO SKIN CALCIUM CARBONATE: RESULT: NOT IRRITATING TO SKIN BENZOTHIAZYL DISULFIDE: RESULT: MILDLY IRRITATING TO SKIN FORMALDEHYDE: RESULT: CAUSES BURNS. SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION. PRODUCT: REMARKS: VAPOURS MAY CAUSE IRRITATION TO THE EYES, RESPIRATORY SYSTEM AND THE SKIN., CAUSES SERIOUS EYE IRRITATION. COMPONENTS: ACETONE: RESULT: IRRITATING TO EYES METHYL ETHYL KETONE: RESULT: IRRITATING TO EYES CALCIUM CARBONATE: RESULT: NOT IRRITATING TO EYES BENZOTHIAZYL DISULFIDE: RESULT: MILDLY IRRITATING TO EYES FORMALDEHYDE: RESULT: CORROSIVE TO EYES RESPIRATORY OR SKIN SENSITISATION: SKIN SENSITISATION: MAY CAUSE AN ALLERGIC SKIN REACTION. RESPIRATORY SENSITISATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION. COMPONENTS: BENZOTHIAZYL DISULFIDE: ASSESSMENT: MAY CAUSE SENSITIZATION BY SKIN CONTACT. FORMALDEHYDE: RESULT: DOES NOT CAUSE RESPIRATORY SENSITISATION. RESULT: MAY CAUSE SENSITISATION BY SKIN CONTACT. GERM CELL MUTAGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION. COMPONENTS: FORMALDEHYDE: GENOTOXICITY IN VITRO: TEST TYPE: AMES TEST TEST SPECIES: SALMONELLA TYPHIMURIUM METABOLIC ACTIVATION: WITHOUT METABOLIC ACTIVATION RESULT: POSITIVE TEST TYPE: CHROMOSOME ABERRATION TEST IN VITRO TEST SPECIES: MOUSE LYMPHOMA CELLS METABOLIC ACTIVATION: WITH AND WITHOUT METABOLIC ACTIVATION RESULT: POSITIVE TEST TYPE: IN VITRO MAMMALIAN CELL GENE MUTATION TEST TEST SPECIES: CHINESE HAMSTER FIBROBLASTS METABOLIC ACTIVATION: WITH AND WITHOUT METABOLIC ACTIVATION RESULT: NEGATIVE TEST TYPE: IN VITRO ASSAY TEST SPECIES: HUMAN LYMPHOCYTES METABOLIC ACTIVATION: WITH AND WITHOUT METABOLIC ACTIVATION RESULT: CONFLICTING RESULTS HAVE BEEN SEEN IN DIFFERENT STUDIES. GENOTOXICITY IN VIVO: TEST TYPE: MICRONUCLEUS TEST TEST SPECIES: MOUSE APPLICATION ROUTE: ORAL RESULT: NEGATIVE TEST TYPE: MICRONUCLEUS TEST TEST SPECIES: MOUSE APPLICATION ROUTE: INHALATION (GAS) RESULT: NEGATIVE TEST TYPE: IN VIVO ASSAY TEST SPECIES: RAT APPLICATION ROUTE: INHALATION (GAS) RESULT: NEGATIVE TEST TYPE: MOUSE SPECIFIC LOCUS TEST TEST SPECIES: MOUSE APPLICATION ROUTE: INHALATION (GAS) RESULT: NEGATIVE TEST TYPE: MAMMALIAN BONE MARROW SISTER CHROMATID EXCHANGE TEST SPECIES: RAT APPLICATION ROUTE: INHALATION (GAS) RESULT: NEGATIVE TEST TYPE: COMET ASSAY TEST SPECIES: RAT APPLICATION ROUTE: INHALATION (GAS) RESULT: NEGATIVE CARCINOGENICITY: MAY CAUSE CANCER. COMPONENTS: FORMALDEHYDE: SPECIES: RAT APPLICATION ROUTE: INGESTION RESULT: NEGATIVE SPECIES: MOUSE APPLICATION ROUTE: DERMAL RESULT: NEGATIVE SPECIES: RAT APPLICATION ROUTE: INHALATION RESULT: POSITIVE CARCINOGENICITY-ASSESSMENT: PRESUMED TO HAVE CARCINOGENIC POTENTIAL FOR HUMANS REPRODUCTIVE TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION. COMPONENTS: FORMALDEHYDE: EFFECTS ON FERTILITY: REMARKS: NO DATA AVAILABLE EFFECTS ON FOETAL DEVELOPMENT: SPECIES: RAT RESULT: NO TERATOGENIC EFFECTS STOT - SINGLE EXPOSURE: MAY CAUSE DROWSINESS OR DIZZINESS. COMPONENTS: ACETONE: EXPOSURE ROUTES: INHALATION TARGET ORGANS: NERVOUS SYSTEM ASSESSMENT: MAY CAUSE DROWSINESS OR DIZZINESS. METHYL ETHYL KETONE: ASSESSMENT: MAY CAUSE DROWSINESS OR DIZZINESS. STOT - REPEATED EXPOSURE: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION. REPEATED DOSE TOXICITY: COMPONENTS: FORMALDEHYDE: SPECIES: RAT NO OBSERVED ADVERSE EFFECT LEVEL: 82 MG/KG APPLICATION ROUTE: INGESTION SPECIES: RAT NO OBSERVED ADVERSE EFFECT LEVEL: 1.2 MG/M3 APPLICATION ROUTE: INHALATION (GAS) TARGET ORGANS: NOSE, UPPER RESPIRATORY TRACT ASPIRATION TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION. PRODUCT: NO ASPIRATION TOXICITY CLASSIFICATION COMPONENTS: ACETONE: MAY BE HARMFUL IF SWALLOWED AND ENTERS AIRWAYS. METHYL ETHYL KETONE: MAY BE HARMFUL IF SWALLOWED AND ENTERS AIRWAYS. FURTHER INFORMATION: PRODUCT: REMARKS: SYMPTOMS OF OVEREXPOSURE MAY BE HEADACHE, DIZZINESS, TIREDNESS, NAUSEA AND VOMITING., CONCENTRATIONS SUBSTANTIALLY ABOVE THE TLV VALUE MAY CAUSE NARCOTIC EFFECTS., SOLVENTS MAY DEGREASE THE SKIN. COMPONENTS: METHYL ETHYL KETONE: REMARKS: CENTRAL NERVOUS SYSTEM CARCINOGENICITY: IARC: GROUP 1: CARCINOGENIC TO HUMANS FORMALDEHYDE 50-00-0 OSHA: OSHA SPECIFICALLY REGULATED CARCINOGEN FORMALDEHYDE 50-00-0 NTP: KNOWN TO BE HUMAN CARCINOGEN FORMALDEHYDE 50-00-0
ECOTOXICITY: COMPONENTS: ACETONE: TOXICITY TO FISH: LC 50 (RAINBOW TROUT,DONALDSON TROUT (ONCORHYNCHUS MYKISS)): 4,740 - 6,330 MG/L EXPOSURE TIME: 96 H TEST TYPE: STATIC TEST LC 50 (FATHEAD MINNOW (PIMEPHALES PROMELAS)): 8,733 - 9,482 MG/L EXPOSURE TIME: 96 H TEST TYPE: FLOW-THROUGH TEST TOXICITY TO ALGAE: NOEC (MICROCYSTIS AERUGINOSA): 530 MG/L EXPOSURE TIME: 8 D TEST TYPE: STATIC TEST TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES (CHRONIC TOXICITY): NOEC (DAPHNIA MAGNA (WATER FLEA)): 2,112 MG/L EXPOSURE TIME: 28 D TEST TYPE: FLOW-THROUGH TEST METHYL ETHYL KETONE: TOXICITY TO FISH: LC 50 (FATHEAD MINNOW (PIMEPHALES PROMELAS)): 3,130 - 3,320 MG/L EXPOSURE TIME: 96 H TEST TYPE: FLOW-THROUGH TEST TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES: EC 50 (WATER FLEA (DAPHNIA MAGNA)): 4,025 - 6,440 MG/L EXPOSURE TIME: 48 H TEST TYPE: STATIC TEST REMARKS: INTOXICATION CALCIUM CARBONATE: TOXICITY TO FISH: LC 50 (GAMBUSIA AFFINIS (MOSQUITO FISH)): >56,000 MG/L EXPOSURE TIME: 96 H TEST TYPE: STATIC TEST FORMALDEHYDE: TOXICITY TO FISH: LC 50 (DANIO RERIO (ZEBRA FISH)): 41 MG/L EXPOSURE TIME: 96 H METHOD: STATIC REMARKS: MORTALITY LC 50 (STRIPED BASS (MORONE SAXATILIS)): 6.7 MG/L EXPOSURE TIME: 96 H METHOD: STATIC TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES: EC 50 (WATER FLEA (DAPHNIA MAGNA)): 29 MG/L EXPOSURE TIME: 48 H METHOD: STATIC REMARKS: INTOXICATION EC 50 (WATER FLEA (DAPHNIA PULEX)): 5.8 MG/L EXPOSURE TIME: 48 H TOXICITY TO ALGAE: ERC50 (DESMODESMUS SUBSPICATUS): 4.89 MG/L EXPOSURE TIME: 72 H TOXICITY TO BACTERIA: EC 50 (ACTIVATED SLUDGE): 19 MG/L EXPOSURE TIME: 3 H TEST TYPE: RESPIRATION INHIBITION PERSISTENCE AND DEGRADABILITY: COMPONENTS: ACETONE: BIODEGRADABILITY: RESULT: READILY BIODEGRADABLE BIODEGRADATION: 90.9% EXPOSURE TIME: 28 D METHOD: OECD TEST GUIDELINE 301B FORMALDEHYDE: BIODEGRADABILITY: AEROBIC RESULT: READILY BIODEGRADABLE BIODEGRADATION: 90% EXPOSURE TIME: 28 D METHOD: OECD TEST GUIDELINE 301D AEROBIC RESULT: READILY BIODEGRADABLE BIODEGRADATION: >90% EXPOSURE TIME: 2 WEEKS METHOD: OECD TEST GUIDELINE 301C PHOTODEGRADATION: BIOACCUMULATIVE POTENTIAL: COMPONENTS: ACETONE: PARTITION COEFFICIENT N-OCTANOL/WATER: LOG POW: -0.24 METHYL ETHYL KETONE: PARTITION COEFFICIENT N-OCTANOL/WATER: LOG POW: 0.29 FORMALDEHYDE: BIOACCUMULATION: REMARKS: NO BIOACCUMULATION IS TO BE EXPECTED (LOG POW <=4). PARTITION COEFFICIENT N-OCTANOL/WATER: LOG POW: 0.35 (25 DEG. C) MOBILITY IN SOIL: COMPONENTS: NO DATA AVAILABLE OTHER ADVERSE EFFECTS: PRODUCT: ADDITIONAL ECOLOGICAL INFORMATION: NO DATA AVAILABLE COMPONENTS: FORMALDEHYDE: RESULTS OF PBT AND VPVB ASSESSMENT: THIS SUBSTANCE IS NOT CONSIDERED TO BE PERSISTENT, BIOACCUMULATING AND TOXIC (PBT). THIS SUBSTANCE IS NOT CONSIDERED TO BE VERY PERSISTENT AND VERY BIOACCUMULATING (VPVB).
DISPOSAL METHODS: GENERAL ADVICE: DO NOT DISPOSE OF WASTE INTO SEWER. DO NOT CONTAMINATE PONDS, WATERWAYS OR DITCHES WITH CHEMICAL OR USED CONTAINER. SEND TO A LICENSED WASTE MANAGEMENT COMPANY. DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS. CONTAMINATED PACKAGING: EMPTY REMAINING CONTENTS. DISPOSE OF AS UNUSED PRODUCT. EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR RECYCLING OR DISPOSAL. DO NOT RE-USE EMPTY CONTAINERS. DO NOT BURN, OR USE A CUTTING TORCH ON, THE EMPTY DRUM.
INTERNATIONAL TRANSPORT REGULATIONS: REGULATION: ID NUMBER PROPER SHIPPING NAME *HAZARD SUBSIDIARY PACKING MARINE CLASS HAZARDS GROUP POLLUTANT/ LTD. QTY. U.S. DOT - ROAD: UN 1133 ADHESIVES 3 II U.S. DOT - RAIL: UN 1133 ADHESIVES 3 II U.S. DOT - INLAND WATERWAYS: UN 1133 ADHESIVES 3 II TRANSPORT CANADA - ROAD: UN 1133 ADHESIVES 3 IL TRANSPORT CANADA - RAIL: UN 1133 ADHESIVES 3 II TRANSPORT CANADA - INLAND WATERWAYS: UN 1133 ADHESIVES 3 II INTERNATIONAL MARITIME DANGEROUS GOODS: UN 1133 ADHESIVES 3 II INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO: UN 1133 ADHESIVES 3 II INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER: UN 1133 ADHESIVES 3 II MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND WASTES: UN 1133 ADHESIVOS 3 II *ORM = ORM-D CBL = COMBUSTIBLE LIQUID MARINE POLLUTANT: NO DANGEROUS GOODS DESCRIPTIONS (IF INDICATED ABOVE) MAY NOT REFLECT QUANTITY, END-USE OR REGION-SPECIFIC EXCEPTIONS THAT CAN BE APPLIED. CONSULT SHIPPING DOCUMENTS FOR DESCRIPTIONS THAT ARE SPECIFIC TO THE SHIPMENT.
EPCRA - EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT: CERCLA REPORTABLE QUANTITY: COMPONENTS CAS-NO. COMPONENT RQ CALCULATED PRODUCT RQ (LBS) (LBS) ACETONE 67-64-1 5000 8036.517938 SARA 311/312 HAZARDS: FIRE HAZARD ACUTE HEALTH HAZARD CHRONIC HEALTH HAZARD SARA 313 COMPONENT(S): FORMALDEHYDE 50-00-0 0.10% CALIFORNIA PROP 65: WARNING! THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER. FORMALDEHYDE 50-00-0 VINYLCYCLOHEXENE, 4- 100-40-3 BENZENE 71-43-2 ACRYLONITRILE 107-13-1 1,3, BUTADIENE 106-99-0 WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. VINYLCYCLOHEXENE, 4- 100-40-3 BENZENE 71-43-2 1,3, BUTADIENE 106-99-0 THE COMPONENTS OF THIS PRODUCT ARE REPORTED IN THE FOLLOWING INVENTORIES: TSCA: ON TSCA INVENTORY DSL: ALL COMPONENTS OF THIS PRODUCT ARE ON THE CANADIAN DSL. AUSTR: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY ENCS: NOT IN COMPLIANCE WITH THE INVENTORY KECL: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY PICCS: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY IECSC: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY INVENTORIES: AICS (AUSTRALIA), DSL (CANADA), IECSC (CHINA), REACH (EUROPEAN UNION), ENCS (JAPAN), ISHL (JAPAN), KECI (KOREA), NZIOC (NEW ZEALAND), PICCS (PHILIPPINES), TSCA (USA)
FURTHER INFORMATION: REVISION DATE: 05/26/2015 NFPA: HEALTH 3 FLAMMABILITY INSTABILITY 0 SPECIAL HAZARD. HMIS III: HEALTH 2* FLAMMABILITY 3 PHYSICAL HAZARD 0 0 = NOT SIGNIFICANT 1 = SLIGHT 2 = MODERATE 3 = HIGH 4 = EXTREME * = CHRONIC NFPA FLAMMABLE AND COMBUSTIBLE LIQUIDS CLASSIFICATION: NOT DETERMINED FULL TEXT OF H-STATEMENTS REFERRED TO UNDER SECTIONS 2 AND 3.: H225: HIGHLY FLAMMABLE LIQUID AND VAPOR. H227: COMBUSTIBLE LIQUID. H301: TOXIC IF SWALLOWED. H311: TOXIC IN CONTACT WITH SKIN. H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE. H317: MAY CAUSE AN ALLERGIC SKIN REACTION. H318: CAUSES SERIOUS EYE DAMAGE. H319: CAUSES SERIOUS EYE IRRITATION. H331: TOXIC IF INHALED. H336: MAY CAUSE DROWSINESS OR DIZZINESS. H350: MAY CAUSE CANCER. SOURCES OF KEY DATA USED TO COMPILE THE SAFETY DATA SHEET ASHLAND INTERNAL DATA INCLUDING OWN AND SPONSORED TEST REPORTS THE UNECE ADMINISTERS REGIONAL AGREEMENTS IMPLEMENTING HARMONISED CLASSIFICATION FOR LABELLING (GHS) AND TRANSPORT. THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT IS NOT WARRANTED TO BE WHETHER ORIGINATING WITH THE COMPANY OR NOT. RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT, APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCES. THIS SDS HAS BEEN PREPARED BY ASHLAND'S ENVIRONMENTAL HEALTH AND SAFETY DEPARTMENT (1-800-325-3751). LIST OF ABBREVIATIONS AND ACRONYMS THAT COULD BE, BUT NOT NECESSARILY ARE, USED IN THIS SAFETY DATA SHEET: ACGIH: AMERICAN CONFERENCE OF INDUSTRIAL HYGIENISTS BEI: BIOLOGICAL EXPOSURE INDEX CAS: CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY). CMR: CARCINOGENIC, MUTAGENIC OR TOXIC FOR REPRODUCTION FG: FOOD GRADE GHS: GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS. H-STATEMENT: HAZARD STATEMENT IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION. IATA-DGR: DANGEROUS GOODS REGULATION BY THE "INTERNATIONAL AIR TRANSPORT ASSOCIATION" (IATA). ICAO: INTERNATIONAL CIVIL AVIATION ORGANIZATION ICAO-TI (ICAO): TECHNICAL INSTRUCTIONS BY THE "INTERNATIONAL CIVIL AVIATION ORGANIZATION" IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS ISO: INTERNATIONAL ORGANIZATION FOR STANDARDIZATION LOGPOW: OCTANOL-WATER PARTITION COEFFICIENT LCXX: LETHAL CONCENTRATION, FOR XX PERCENT OF TEST POPULATION LDXX: LETHAL DOSE, FORXX PERCENT OF TEST POPULATION. ICXX: INHIBITORY CONCENTRATION FOR XX OF A SUBSTANCE ECXX: EFFECTIVE CONCENTRATION OF XX N.O.S.: NOT OTHERWISE SPECIFIED OECD: ORGANIZATION FOR ECONOMIC CO-OPERATION AND DEVELOPMENT OEL: OCCUPATIONAL EXPOSURE LIMIT P-STATEMENT: PRECAUTIONARY STATEMENT PBT: PERSISTENT, BIOACCUMULATIVEAND TOXIC PPE: PERSONAL PROTECTIVE EQUIPMENT STEL: SHORT-TERM EXPOSURE LIMIT STOT: SPECIFIC TARGET ORGAN TOXICITY TLV: THRESHOLD LIMIT VALUE TWA: TIME-WEIGHTED AVERAGE VPVB: VERY PERSISTENT AND VERY BIOACCUMULATIVE WEL: WORKPLACE EXPOSURE LEVEL CERCLA: COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT DOT: DEPARTMENT OF TRANSPORTATION FIFRA: FEDERAL INSECTICIDE, FUNGICIDE, AND RODENTICIDE ACT HMIRC: HAZARDOUS MATERIALS INFORMATION REVIEW COMMISSION HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM NFPA: NATIONAL FIRE PROTECTION ASSOCIATION NIOSH: NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION PMRA: HEALTH CANADA PEST MANAGEMENT REGULATORY AGENCY RTK: RIGHT TO KNOW WHMIS: WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM |