| Common Name: | ACCOLADE EXTERIOR 100% ACRYLIC WATERBORNE EGGSHELL, BASE 1 |
| Manufacturer: | PRATT & LAMBERT PAINTS |
| SDS Revision Date: | 1/15/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 40UE80, 40UF45, 40UG95, 40UJ64 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
RZ4291
| SECTION 1. IDENTIFICATION |  |
PRODUCT NAME: ACCOLADE(R*) EXTERIOR 100% ACRYLIC WATERBORNE EGGSHELL BASE 1
PRODUCT CODE: RZ4291
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
PRODUCT TYPE: LIQUID.
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST: NOT APPLICABLE.
MANUFACTURER:
PRATT & LAMBERT PAINTS
101 W. PROSPECT AVENUE
CLEVELAND, OH 44115
EMERGENCY TELEPHONE NUMBER OF THE COMPANY: (216) 566-2917
PRODUCT INFORMATION TELEPHONE NUMBER: (800) 289-7728
REGULATORY INFORMATION TELEPHONE NUMBER: (216) 566-2902
TRANSPORTATION EMERGENCY TELEPHONE NUMBER: (800) 424-9300
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
SKIN SENSITIZATION: CATEGORY 1
CARCINOGENICITY: CATEGORY 2
PERCENTAGE OF THE MIXTURE CONSISTING OF INGREDIENT(S) OF UNKNOWN ORAL
TOXICITY: 17.4%
PERCENTAGE OF THE MIXTURE CONSISTING OF INGREDIENT(S) OF UNKNOWN DERMAL
TOXICITY: 17.4%
PERCENTAGE OF THE MIXTURE CONSISTING OF INGREDIENT(S) OF UNKNOWN INHALATION
TOXICITY: 17. 4%
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS:
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
MAY CAUSE AN ALLERGIC SKIN REACTION.
SUSPECTED OF CAUSING CANCER.
PRECAUTIONARY STATEMENTS:
GENERAL:
READ LABEL BEFORE USE. KEEP OUT OF REACH OF CHILDREN. IF MEDICAL ADVICE IS
NEEDED, HAVE PRODUCT CONTAINER OR LABEL AT HAND.
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. WEAR PROTECTIVE GLOVES. WEAR EYE
OR FACE PROTECTION.
WEAR PROTECTIVE CLOTHING. AVOID BREATHING VAPOR. CONTAMINATED WORK CLOTHING
MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
IF ON SKIN:
WASH WITH PLENTY OF SOAP AND WATER. WASH CONTAMINATED CLOTHING BEFORE
REUSE.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
SUPPLEMENTAL LABEL ELEMENTS:
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
THIS PRODUCT CONTAINS A SIGNIFICANT NEW USE RULE (SNUR) CHEMICAL. DO NOT
ALLOW THIS PRODUCT TO ENTER DRAINS, SEWERS, WASTEWATER TREATMENT SYSTEMS,
GROUNDWATER, STREAMS, LAKES OR PONDS. SEE ENVIRONMENTAL DATA SHEET (EDS)
FOR ADDITIONAL DETAILS.
PLEASE REFER TO THE SDS FOR ADDITIONAL INFORMATION. KEEP OUT OF REACH OF
CHILDREN. DO NOT TRANSFER CONTENTS TO OTHER CONTAINERS FOR STORAGE.
HAZARDS NOT OTHERWISE CLASSIFIED: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
CAS NUMBER/OTHER IDENTIFIERS:
INGREDIENT NAME % BY WEIGHT CAS NUMBER
TITANIUM DIOXIDE 15.1 13463-67-7
ZINC OXIDE 2.29 1314-13-2
3-IODO-2-PROPYNYL BUTYL CARBAMATE 0.15 55406-53-6
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS DUE
TO BATCH VARIATION.
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH AND HENCE REQUIRE REPORTING IN THIS
SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE UPPER
AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. CONTINUE TO
RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL ATTENTION.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF NOT BREATHING, IF BREATHING IS IRREGULAR OR IF RESPIRATORY
ARREST OCCURS, PROVIDE ARTIFICIAL RESPIRATION OR OXYGEN BY TRAINED
PERSONNEL. IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE
MOUTH-TO-MOUTH RESUSCITATION. GET MEDICAL ATTENTION. IF UNCONSCIOUS, PLACE
IN RECOVERY POSITION AND GET MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN
OPEN AIRWAY. LOOSEN TIGHT CLOTHING SUCH AS A COLLAR, TIE, BELT OR
WAISTBAND.
SKIN CONTACT:
WASH WITH PLENTY OF SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND SHOES.
WASH CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE REMOVING IT, OR
WEAR GLOVES. CONTINUE TO RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL
ATTENTION. IN THE EVENT OF ANY COMPLAINTS OR SYMPTOMS, AVOID FURTHER
EXPOSURE. WASH CLOTHING BEFORE REUSE. CLEAN SHOES THOROUGHLY BEFORE REUSE.
INGESTION:
WASH OUT MOUTH WITH WATER. REMOVE DENTURES IF ANY. REMOVE VICTIM TO FRESH
AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR BREATHING. IF MATERIAL
HAS BEEN SWALLOWED AND THE EXPOSED PERSON IS CONSCIOUS, GIVE SMALL
QUANTITIES OF WATER TO DRINK. STOP IF THE EXPOSED PERSON FEELS SICK AS
VOMITING MAY BE DANGEROUS. DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO
BY MEDICAL PERSONNEL. IF VOMITING OCCURS, THE HEAD SHOULD BE KEPT LOW SO
THAT VOMIT DOES NOT ENTER THE LUNGS. GET MEDICAL ATTENTION. NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF UNCONSCIOUS, PLACE IN
RECOVERY POSITION AND GET MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN OPEN
AIRWAY. LOOSEN TIGHT CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT: MAY CAUSE AN ALLERGIC SKIN REACTION.
INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT: NO SPECIFIC DATA.
INHALATION: NO SPECIFIC DATA.
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
INGESTION: NO SPECIFIC DATA.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF
NECESSARY:
NOTES TO PHYSICIAN:
TREAT SYMPTOMATICALLY. CONTACT POISON TREATMENT SPECIALIST IMMEDIATELY IF
LARGE QUANTITIES HAVE BEEN INGESTED OR INHALED.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE
MOUTH-TO-MOUTH RESUSCITATION. WASH CONTAMINATED CLOTHING THOROUGHLY WITH
WATER BEFORE REMOVING IT, OR WEAR GLOVES.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE AN EXTINGUISHING AGENT SUITABLE FOR THE SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
IN A FIRE OR IF HEATED, A PRESSURE INCREASE WILL OCCUR AND THE CONTAINER
MAY BURST.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
METAL OXIDE/OXIDES
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF
THE INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE
OPERATED IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL.
AVOID BREATHING VAPOR OR MIST. PROVIDE ADEQUATE VENTILATION. WEAR
APPROPRIATE RESPIRATOR WHEN VENTILATION IS INADEQUATE. PUT ON APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALIZED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE OF
ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE ALSO
THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
THIS PRODUCT CONTAINS A SIGNIFICANT NEW USE RULE (SNUR) CHEMICAL. DO NOT
ALLOW THIS PRODUCT TO ENTER DRAINS, SEWERS, WASTEWATER TREATMENT SYSTEMS,
GROUNDWATER, STREAMS, LAKES OR PONDS. SEE ENVIRONMENTAL DATA SHEET (EDS)
FOR ADDITIONAL DETAILS.
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL
OR AIR).
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. DILUTE WITH
WATER AND MOP UP IF WATER-SOLUBLE. ALTERNATIVELY, OR IF WATER-INSOLUBLE,
ABSORB WITH AN INERT DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE
DISPOSAL CONTAINER. DISPOSE OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
LARGE SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. APPROACH
RELEASE FROM UPWIND. PREVENT ENTRY INTO SEWERS, WATER COURSES, BASEMENTS
OR CONFINED AREAS. WASH SPILLAGES INTO AN EFFLUENT TREATMENT PLANT OR
PROCEED AS FOLLOWS. CONTAIN AND COLLECT SPILLAGE WITH NON-COMBUSTIBLE,
ABSORBENT MATERIAL E.G. SAND, EARTH, VERMICULITE OR DIATOMACEOUS EARTH
AND PLACE IN CONTAINER FOR DISPOSAL ACCORDING TO LOCAL REGULATIONS (SEE
SECTION 13). DISPOSE OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
CONTAMINATED ABSORBENT MATERIAL MAY POSE THE SAME HAZARD AS THE SPILLED
PRODUCT.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). PERSONS
WITH A HISTORY OF SKIN SENSITIZATION PROBLEMS SHOULD NOT BE EMPLOYED IN ANY
PROCESS IN WHICH THIS PRODUCT IS USED. AVOID EXPOSURE - OBTAIN SPECIAL
INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE
BEEN READ AND UNDERSTOOD. DO NOT GET IN EYES OR ON SKIN OR CLOTHING. DO
NOT INGEST. AVOID BREATHING VAPOR OR MIST. IF DURING NORMAL USE THE
MATERIAL PRESENTS A RESPIRATORY HAZARD, USE ONLY WITH ADEQUATE VENTILATION
OR WEAR APPROPRIATE RESPIRATOR. KEEP IN THE ORIGINAL CONTAINER OR AN
APPROVED ALTERNATIVE MADE FROM A COMPATIBLE MATERIAL, KEPT TIGHTLY CLOSED
WHEN NOT IN USE. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE AND CAN BE
HAZARDOUS. DO NOT REUSE CONTAINER.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. REMOVE CONTAMINATED CLOTHING AND
PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS. SEE ALSO SECTION 8 FOR
ADDITIONAL INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE IN ORIGINAL CONTAINER
PROTECTED FROM DIRECT SUNLIGHT IN A DRY, COOL AND WELL-VENTILATED AREA,
AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10) AND FOOD AND DRINK.
STORE LOCKED UP. KEEP CONTAINER TIGHTLY CLOSED AND SEALED UNTIL READY FOR
USE. CONTAINERS THAT HAVE BEEN OPENED MUST BE CAREFULLY RESEALED AND KEPT
UPRIGHT TO PREVENT LEAKAGE. DO NOT STORE IN UNLABELED CONTAINERS.
USE APPROPRIATE CONTAINMENT TO AVOID ENVIRONMENTAL CONTAMINATION. SEE
SECTION 10 FOR INCOMPATIBLE MATERIALS BEFORE HANDLING OR USE.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS (OSHA UNITED STATES):
INGREDIENT NAME EXPOSURE LIMITS
TITANIUM DIOXIDE ACGIH TLV (UNITED STATES, 3/2016).
TWA: 10 MG/M3 8 HOURS.
OSHA PEL (UNITED STATES, 6/2016).
TWA: 15 MG/M3 8 HOURS.
FORM: TOTAL DUST
ZINC OXIDE NIOSH REL (UNITED STATES, 10/2016).
CEIL: 15 MG/M3
FORM: DUST
TWA: 5 MG/M3 10 HOURS.
FORM: DUST AND FUMES
STEL: 10 MG/M3 15 MINUTES.
FORM: FUME
OSHA PEL (UNITED STATES, 6/2016).
TWA: 5 MG/M3 8 HOURS.
FORM: FUME
TWA: 5 MG/M3 8 HOURS.
FORM: RESPIRABLE FRACTION
TWA: 15 MG/M3 8 HOURS.
FORM: TOTAL DUST
ACGIH TLV (UNITED STATES, 3/2016).
TWA: 2 MG/M3 8 HOURS.
FORM: RESPIRABLE FRACTION
STEL: 10 MG/M3 15 MINUTES.
FORM: RESPIRABLE FRACTION
3-IODO-2-PROPYNYL BUTYLCARBAMATE NONE.
OCCUPATIONAL EXPOSURE LIMITS (CANADA):
INGREDIENT NAME EXPOSURE LIMITS
ZINC OXIDE CA ALBERTA PROVINCIAL (CANADA, 4/2009).
8 HRS OEL: 2 MG/M3 8 HOURS.
FORM: RESPIRABLE
15 MIN OEL: 10 MG/M3 15 MINUTES.
FORM: RESPIRABLE
CA BRITISH COLUMBIA PROVINCIAL
(CANADA, 7/2016).
TWA: 2 MG/M3 8 HOURS.
FORM: RESPIRABLE
STEL: 10 MG/M3 15 MINUTES.
FORM: RESPIRABLE
CA ONTARIO PROVINCIAL (CANADA, 7/2015).
TWA: 2 MG/M3 8 HOURS.
FORM: RESPIRABLE FRACTION.
STEL: 10 MG/M3 15 MINUTES.
FORM: RESPIRABLE FRACTION.
CA QUEBEC PROVINCIAL (CANADA, 1/2014).
TWAEV: 5 MG/M3 8 HOURS.
FORM: FUME
STEV: 10 MG/M3 15 MINUTES.
FORM: FUME
CA SASKATCHEWAN PROVINCIAL
(CANADA, 7/2013).
STEL: 10 MG/M3 15 MINUTES.
FORM: RESPIRABLE DUST AND FUME
TWA: 2 MG/M3 8 HOURS.
FORM: RESPIRABLE DUST AND FUME
OCCUPATIONAL EXPOSURE LIMITS (MEXICO):
INGREDIENT NAME EXPOSURE LIMITS
ZINC OXIDE NOM-010-STPS-2014 (MEXICO, 4/2016).
TWA: 2 MG/M3 8 HOURS.
FORM: RESPIRABLE FRACTION
STEL: 10 MG/M3 15 MINUTES.
FORM: RESPIRABLE FRACTION
APPROPRIATE ENGINEERING CONTROLS:
IF USER OPERATIONS GENERATE DUST, FUMES, GAS, VAPOR OR MIST, USE PROCESS
ENCLOSURES, LOCAL EXHAUST VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP
WORKER EXPOSURE TO AIRBORNE CONTAMINANTS BELOW ANY RECOMMENDED OR STATUTORY
LIMITS.
ENVIRONMENTAL EXPOSURE CONTROLS:
THIS PRODUCT CONTAINS A SIGNIFICANT NEW USE RULE (SNUR) CHEMICAL. DO NOT
ALLOW THIS PRODUCT TO ENTER DRAINS, SEWERS, WASTEWATER TREATMENT SYSTEMS,
GROUNDWATER, STREAMS, LAKES OR PONDS. SEE ENVIRONMENTAL DATA SHEET (EDS)
FOR ADDITIONAL DETAILS.
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED
TO ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, FUME SCRUBBERS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD.
APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY CONTAMINATED
CLOTHING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE
WORKPLACE. WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE THAT EYEWASH
STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION LOCATION.
EYE/FACE PROTECTION:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN A
RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO LIQUID
SPLASHES, MISTS, GASES OR DUSTS. IF CONTACT IS POSSIBLE, THE FOLLOWING
PROTECTION SHOULD BE WORN, UNLESS THE ASSESSMENT INDICATES A HIGHER DEGREE
OF PROTECTION: SAFETY GLASSES WITH SIDE-SHIELDS.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY. CONSIDERING THE PARAMETERS
SPECIFIED BY THE GLOVE MANUFACTURER, CHECK DURING USE THAT THE GLOVES ARE
STILL RETAINING THEIR PROTECTIVE PROPERTIES. IT SHOULD BE NOTED THAT THE
TIME TO BREAKTHROUGH FOR ANY GLOVE MATERIAL MAY BE DIFFERENT FOR DIFFERENT
GLOVE MANUFACTURERS. IN THE CASE OF MIXTURES, CONSISTING OF SEVERAL
SUBSTANCES, THE PROTECTION TIME OF THE GLOVES CANNOT BE ACCURATELY
ESTIMATED.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD BE
SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
BASED ON THE HAZARD AND POTENTIAL FOR EXPOSURE, SELECT A RESPIRATOR THAT
MEETS THE APPROPRIATE STANDARD OR CERTIFICATION. RESPIRATORS MUST BE USED
ACCORDING TO A RESPIRATORY PROTECTION PROGRAM TO ENSURE PROPER FITTING,
TRAINING, AND OTHER IMPORTANT ASPECTS OF USE.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
COLOR: NOT AVAILABLE.
ODOR: NOT AVAILABLE.
ODOR THRESHOLD: NOT AVAILABLE.
PH: 9.3
MELTING POINT: NOT AVAILABLE.
BOILING POINT: 100 DEG. C (212 DEG. F)
FLASH POINT:
CLOSED CUP: >93.3 DEG. C (>199.9 DEG. F)
EVAPORATION RATE: 0.09 (BUTYL ACETATE = 1)
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS: NOT AVAILABLE.
VAPOR PRESSURE: 2.3 KPA (17.5 MMHG) [AT 20 DEG. C]
VAPOR DENSITY: 1 [AIR = 1]
RELATIVE DENSITY: 1.31
SOLUBILITY: NOT AVAILABLE.
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY:
KINEMATIC (40 DEG. C (104 DEG. F)): >0.205 CM2/S (>20.5 CST)
MOLECULAR WEIGHT: NOT APPLICABLE.
AEROSOL PRODUCT:
HEAT OF COMBUSTION: 0.882 KJ/G
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NO SPECIFIC TEST DATA RELATED TO REACTIVITY AVAILABLE FOR THIS PRODUCT OR
ITS INGREDIENTS.
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID: NO SPECIFIC DATA.
INCOMPATIBLE MATERIALS: NO SPECIFIC DATA.
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
3-IODO-2-PROPYNYL LD50 ORAL RAT 1470 MG/KG
BUTYLCARBAMATE
IRRITATION/CORROSION:
PRODUCT/INGREDIENT RESULT SPECIES SCORE EXPOSURE OBSERVATION
NAME
TITANIUM DIOXIDE SKIN: HUMAN 72 HOURS
MILD 300 MICROGRAMS
IRRITANT INTERMITTENT
ZINC OXIDE EYES: RABBIT 24 HOURS
MILD 500 MILLIGRAMS
IRRITANT
SKIN: RABBIT 24 HOURS
MILD 500 MILLIGRAMS
IRRITANT
SENSITIZATION: NOT AVAILABLE.
MUTAGENICITY: NOT AVAILABLE.
CARCINOGENICITY: NOT AVAILABLE.
CLASSIFICATION:
PRODUCT/INGREDIENT NAME OSHA IARC NTP
TITANIUM DIOXIDE 2B
REPRODUCTIVE TOXICITY: NOT AVAILABLE.
TERATOGENICITY: NOT AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE):
NAME CATEGORY ROUTE OF EXPOSURE TARGET ORGANS
3-IODO-2-PROPYNYL CATEGORY 1 NOT DETERMINED LARYNX
BUTYLCARBAMATE
ASPIRATION HAZARD: NOT AVAILABLE.
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE: NOT AVAILABLE.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT: MAY CAUSE AN ALLERGIC SKIN REACTION.
INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT: NO SPECIFIC DATA.
INHALATION: NO SPECIFIC DATA.
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
INGESTION: NO SPECIFIC DATA.
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG
TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
POTENTIAL CHRONIC HEALTH EFFECTS: NOT AVAILABLE.
GENERAL:
ONCE SENSITIZED, A SEVERE ALLERGIC REACTION MAY OCCUR WHEN SUBSEQUENTLY
EXPOSED TO VERY LOW LEVELS.
CARCINOGENICITY:
SUSPECTED OF CAUSING CANCER. RISK OF CANCER DEPENDS ON DURATION AND LEVEL
OF EXPOSURE.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY ESTIMATES: NOT AVAILABLE.
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES EXPOSURE
NAME
TITANIUM DIOXIDE ACUTE LC50: FISH - FUNDULUS 96 HOURS
>1000000 (MICRO)G/L HETEROCLITUS
MARINE WATER
ZINC OXIDE ACUTE IC50: ALGAE - SKELETONEMA 96 HOURS
1.85 MG/L COSTATUM
MARINE WATER
ACUTE IC50: ALGAE - 72 HOURS
46 (MICRO)G/L PSEUDOKIRCHNERIELLA
FRESH WATER SUBCAPITATA -
EXPONENTIAL GROWTH
PHASE
ACUTE LC50: DAPHNIA - DAPHNIA 48 HOURS
98 (MICRO)G/L MAGNA - NEONATE
FRESH WATER
ACUTE LC50: FISH - ONCORHYNCHUS 96 HOURS
1.1 PPM MYKISS
FRESH WATER
3-IODO-2-PROPYNYL ACUTE LC50: CRUSTACEANS - 48 HOURS
BUTYLCARBAMATE 500 PPB HYALELLA AZTECA
FRESH WATER
ACUTE LC50: DAPHNIA - DAPHNIA 48 HOURS
40 PPB MAGNA
FRESH WATER
ACUTE LC50: FISH - ONCORHYNCHUS 96 HOURS
67 (MICRO)G/L MYKISS - JUVENILE
FRESH WATER (FLEDGLING,
HATCHLING, WEANLING)
CHRONIC NOEC: FISH - PIMEPHALES 35 DAYS
8.4 PPB PROMELAS
PERSISTENCE AND DEGRADABILITY: NOT AVAILABLE.
BIOACCUMULATIVE POTENTIAL:
PRODUCT/INGREDIENT NAME LOGPOW BCF POTENTIAL
ZINC OXIDE 60960 HIGH
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE.
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THIS PRODUCT CONTAINS A SIGNIFICANT NEW USE RULE (SNUR) CHEMICAL. DO NOT
ALLOW THIS PRODUCT TO ENTER DRAINS, SEWERS, WASTEWATER TREATMENT SYSTEMS,
GROUNDWATER, STREAMS, LAKES OR PONDS. SEE ENVIRONMENTAL DATA SHEET (EDS)
FOR ADDITIONAL DETAILS.
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER
POSSIBLE. DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD
AT ALL TIMES COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND
WASTE DISPOSAL LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS.
DISPOSE OF SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE
DISPOSAL CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE
SEWER UNLESS FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH
JURISDICTION. WASTE PACKAGING SHOULD BE RECYCLED. INCINERATION OR LANDFILL
SHOULD ONLY BE CONSIDERED WHEN RECYCLING IS NOT FEASIBLE. THIS MATERIAL AND
ITS CONTAINER MUST BE DISPOSED OF IN A SAFE WAY. CARE SHOULD BE TAKEN WHEN
HANDLING EMPTIED CONTAINERS THAT HAVE NOT BEEN CLEANED OR RINSED OUT. EMPTY
CONTAINERS OR LINERS MAY RETAIN SOME PRODUCT RESIDUES. AVOID DISPERSAL OF
SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL, WATERWAYS, DRAINS AND
SEWERS.
| SECTION 14. TRANSPORT INFORMATION | |
DOT TDG MEXICO
CLASSIFICATION CLASSIFICATION CLASSIFICATION
UN NUMBER NOT REGULATED. NOT REGULATED. NOT REGULATED.
UN PROPER SHIPPING NAME
TRANSPORT HAZARD
CLASS(ES)
PACKING GROUP
ENVIRONMENTAL HAZARDS NO. NO. NO.
ADDITIONAL INFORMATION
IATA IMDG
UN NUMBER NOT REGULATED. NOT REGULATED.
UN PROPER SHIPPING NAME
TRANSPORT HAZARD CLASS(ES)
PACKING GROUP
ENVIRONMENTAL HAZARDS NO. NO.
ADDITIONAL INFORMATION
SPECIAL PRECAUTIONS FOR USER:
MULTI-MODAL SHIPPING DESCRIPTIONS ARE PROVIDED FOR INFORMATIONAL PURPOSES
AND DO NOT CONSIDER CONTAINER SIZES. THE PRESENCE OF A SHIPPING DESCRIPTION
FOR A PARTICULAR MODE OF TRANSPORT (SEA, AIR, ETC.), DOES NOT INDICATE THAT
THE PRODUCT IS PACKAGED SUITABLY FOR THAT MODE OF TRANSPORT. ALL PACKAGING
MUST BE REVIEWED FOR SUITABILITY PRIOR TO SHIPMENT, AND COMPLIANCE WITH THE
APPLICABLE REGULATIONS IS THE SOLE RESPONSIBILITY OF THE PERSON OFFERING
THE PRODUCT FOR TRANSPORT. PEOPLE LOADING AND UNLOADING DANGEROUS GOODS
MUST BE TRAINED ON ALL OF THE RISKS DERIVING FROM THE SUBSTANCES AND ON
ALL ACTIONS IN CASE OF EMERGENCY SITUATIONS.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL AND THE IBC CODE:
NOT AVAILABLE.
PROPER SHIPPING NAME: NOT AVAILABLE.
SHIP TYPE: NOT AVAILABLE.
POLLUTION CATEGORY: NOT AVAILABLE.
| SECTION 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
TSCA 5(A)2 FINAL SIGNIFICANT NEW USE RULES:
NONYLPHENOXYPOLY(ETHOXY)ETHANOL
THIS PRODUCT CONTAINS A SIGNIFICANT NEW USE RULE (SNUR) CHEMICAL. DO NOT
ALLOW THIS PRODUCT TO ENTER DRAINS, SEWERS, WASTEWATER TREATMENT SYSTEMS,
GROUNDWATER, STREAMS, LAKES OR PONDS. SEE ENVIRONMENTAL DATA SHEET (EDS)
FOR ADDITIONAL DETAILS.
SARA 313:
SARA 313 (40 CFR 372.45) SUPPLIER NOTIFICATION CAN BE FOUND ON THE
ENVIRONMENTAL DATA SHEET.
CALIFORNIA PROP. 65:
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
| SECTION 16. OTHER INFORMATION | |
HAZARDOUS MATERIAL INFORMATION SYSTEM (U.S.A.):
HEALTH 1*
FLAMMABILITY 0
PHYSICAL HAZARDS 0
THE CUSTOMER IS RESPONSIBLE FOR DETERMINING THE PPE CODE FOR THIS MATERIAL.
FOR MORE INFORMATION ON HMIS(R*) PERSONAL PROTECTIVE EQUIPMENT (PPE) CODES,
CONSULT THE HMIS(R*) IMPLEMENTATION MANUAL.
CAUTION:
HMIS(R*) RATINGS ARE BASED ON A 0-4 RATING SCALE, WITH 0 REPRESENTING
MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING SIGNIFICANT HAZARDS OR RISKS.
ALTHOUGH HMIS(R*) RATINGS AND THE ASSOCIATED LABEL ARE NOT REQUIRED ON SDSS
OR PRODUCTS LEAVING A FACILITY UNDER 29 CFR 1910.1200, THE PREPARER MAY
CHOOSE TO PROVIDE THEM. HMIS(R*) RATINGS ARE TO BE USED WITH A FULLY
IMPLEMENTED HMIS(R*) PROGRAM. HMIS(R*) IS A REGISTERED TRADEMARK AND
SERVICE MARK OF THE AMERICAN COATINGS ASSOCIATION, INC.
PROCEDURE USED TO DERIVE THE CLASSIFICATION:
CLASSIFICATION JUSTIFICATION
SKIN SENSITIZATION - CATEGORY 1 CALCULATION METHOD
CARCINOGENICITY - CATEGORY 2 CALCULATION METHOD
HISTORY:
DATE OF PRINTING: 1/15/2018
DATE OF ISSUE/DATE OF REVISION: 1/15/2018
DATE OF PREVIOUS ISSUE: 9/8/2017
VERSION: 6.01
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS,
1973 AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
UN: UNITED NATIONS
NOTICE TO READER:
IT IS RECOMMENDED THAT EACH CUSTOMER OR RECIPIENT OF THIS SAFETY DATA
SHEET (SDS) STUDY IT CAREFULLY AND CONSULT RESOURCES, AS NECESSARY OR
APPROPRIATE, TO BECOME AWARE OF AND UNDERSTAND THE DATA CONTAINED IN THIS
SDS AND ANY HAZARDS ASSOCIATED WITH THE PRODUCT. THIS INFORMATION IS
PROVIDED IN GOOD FAITH AND BELIEVED TO BE ACCURATE AS OF THE EFFECTIVE DATE
HEREIN. HOWEVER, NO WARRANTY, EXPRESS OR IMPLIED, IS GIVEN. THE INFORMATION
PRESENTED HERE APPLIES ONLY TO THE PRODUCT AS SHIPPED. THE ADDITION OF ANY
MATERIAL CAN CHANGE THE COMPOSITION, HAZARDS AND RISKS OF THE PRODUCT.
PRODUCTS SHALL NOT BE REPACKAGED, MODIFIED, OR TINTED EXCEPT AS
SPECIFICALLY INSTRUCTED BY SHERWIN-WILLIAMS, INCLUDING BUT NOT LIMITED TO
THE INCORPORATION OF NON SHERWIN-WILLIAMS PRODUCTS OR THE USE OR ADDITION
OF PRODUCTS IN PROPORTIONS NOT SPECIFIED BY SHERWIN-WILLIAMS. REGULATORY
REQUIREMENTS ARE SUBJECT TO CHANGE AND MAY DIFFER BETWEEN VARIOUS LOCATIONS
AND JURISDICTIONS. THE CUSTOMER/BUYER/USER IS RESPONSIBLE TO ENSURE THAT
HIS ACTIVITIES COMPLY WITH ALL COUNTRY, FEDERAL, STATE, PROVINCIAL OR LOCAL
LAWS. THE CONDITIONS FOR USE OF THE PRODUCT ARE NOT UNDER THE CONTROL OF
THE MANUFACTURER; THE CUSTOMER/BUYER/USER IS RESPONSIBLE TO DETERMINE THE
CONDITIONS NECESSARY FOR THE SAFE USE OF THIS PRODUCT. THE
CUSTOMER/BUYER/USER SHOULD NOT USE THE PRODUCT FOR ANY PURPOSE OTHER THAN
THE PURPOSE SHOWN IN THE APPLICABLE SECTION OF THIS SDS WITHOUT FIRST
REFERRING TO THE SUPPLIER AND OBTAINING WRITTEN HANDLING INSTRUCTIONS. DUE
TO THE PROLIFERATION OF SOURCES FOR INFORMATION SUCH AS
MANUFACTURER-SPECIFIC SDS, THE MANUFACTURER CANNOT BE RESPONSIBLE FOR SDSS
OBTAINED FROM ANY OTHER SOURCE.