| Common Name: | SPLASH ALL-SEASON 4-IN-1 WINDSHIELD WASH -25 DEG. F |
| Manufacturer: | FMP |
| SDS Revision Date: | 12/7/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 40X939, 40Z938 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SPLASH(R*) SEE SAFELY.(TM)
SAFETY DATA SHEET
ISSUE DATE: 05-DEC-2018
REVISION DATE: 07-DEC-2018
VERSION: 1
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT NAME: SPLASH ALL-SEASON 4-IN-1 WINDSHIELD WASH -25 DEG. F
OTHER MEANS OF IDENTIFICATION:
SDS/PART #: 234192
UN/ID NO: UN1993
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: FOR INDUSTRIAL USE.
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER ADDRESS:
FMP
1380 CORPORATE CENTER CURVE, SUITE 200
EAGAN, MN 55121
PHONE: 888-784-0802
EMERGENCY TELEPHONE NUMBER:
EMERGENCY TELEPHONE:
INFOTRAC:
1-352-323-3500 (INTERNATIONAL)
1-800-535-5053 (NORTH AMERICA)
| 2. HAZARDS IDENTIFICATION | |
APPEARANCE: PURPLE LIQUID
PHYSICAL STATE: LIQUID
ODOR: SLIGHT ALCOHOL
CLASSIFICATION:
ACUTE TOXICITY - ORAL: CATEGORY 4
ACUTE TOXICITY - DERMAL: CATEGORY 3
ACUTE TOXICITY - INHALATION (VAPORS): CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 1
FLAMMABLE LIQUIDS: CATEGORY 3
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
HARMFUL IF SWALLOWED
TOXIC IN CONTACT WITH SKIN
TOXIC IF INHALED
CAUSES DAMAGE TO ORGANS
FLAMMABLE LIQUID AND VAPOR
SKULLS AND CROSSBONES
HEALTH HAZARD
FLAME
PRECAUTIONARY STATEMENTS - PREVENTION:
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING
KEEP CONTAINER TIGHTLY CLOSED
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT
USE EXPLOSION-PROOF EQUIPMENT
USE ONLY NON-SPARKING TOOLS
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE
KEEP COOL
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION
PRECAUTIONARY STATEMENTS - RESPONSE:
IF EXPOSED: CALL A POISON CENTER OR DOCTOR
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER
WASH CONTAMINATED CLOTHING BEFORE REUSE
CALL A POISON CENTER OR DOCTOR IF YOU FEEL UNWELL
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING
CALL A POISON CENTER OR DOCTOR
IF SWALLOWED: CALL A POISON CENTER OR DOCTOR IF YOU FEEL UNWELL
RINSE MOUTH
IN CASE OF FIRE: USE CO2, DRY CHEMICAL, OR FOAM TO EXTINGUISH
PRECAUTIONARY STATEMENTS - STORAGE:
STORE LOCKED UP
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS NO WEIGHT-%
METHANOL 67-56-1 30-35
**IF CHEMICAL NAME/CAS NO IS "PROPRIETARY" AND/OR WEIGHT-% IS LISTED AS A
RANGE, THE SPECIFIC CHEMICAL IDENTITY AND/OR PERCENTAGE OF COMPOSITION HAS
BEEN WITHHELD AS A TRADE SECRET.**
| 4. FIRST AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
GENERAL ADVICE:
IF EXPOSED: CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
EYE CONTACT:
RINSE THOROUGHLY WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES, LIFTING
LOWER AND UPPER EYELIDS. CONSULT A PHYSICIAN.
SKIN CONTACT:
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER. WASH CONTAMINATED CLOTHING BEFORE REUSE. CALL A POISON CENTER
OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
INHALATION:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER OR DOCTOR/PHYSICIAN.
INGESTION:
CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL. RINSE MOUTH.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS:
HARMFUL IF SWALLOWED. TOXIC IN CONTACT WITH SKIN. TOXIC IF INHALED. CAUSES
DAMAGE TO ORGANS.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
USE CO2, DRY CHEMICAL, OR FOAM FOR EXTINCTION.
UNSUITABLE EXTINGUISHING MEDIA: NOT DETERMINED.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL: FLAMMABLE LIQUID AND VAPOR.
PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
ENVIRONMENTAL PRECAUTIONS:
ENVIRONMENTAL PRECAUTIONS:
SEE SECTION 12 FOR ADDITIONAL ECOLOGICAL INFORMATION.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
METHODS FOR CLEAN-UP: KEEP IN SUITABLE, CLOSED CONTAINERS FOR DISPOSAL.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
ADVICE ON SAFE HANDLING:
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING. DO NOT
EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. USE ONLY OUTDOORS OR IN A
WELL-VENTILATED AREA. DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY. KEEP
AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. KEEP
CONTAINER TIGHTLY CLOSED. GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
USE EXPLOSION PROOF EQUIPMENT. USE ONLY NON-SPARKING TOOLS. TAKE
PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGES. KEEP COOL. WEAR
PROTECTIVE GLOVES/PROTECTIVE CLOTHING AND EYE/FACE PROTECTION.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
STORE LOCKED UP. STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY
CLOSED.
INCOMPATIBLE MATERIALS: NONE KNOWN BASED ON INFORMATION SUPPLIED.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
EXPOSURE GUIDELINES
CHEMICAL NAME ACGIH TLV OSHA PEL NIOSH IDLH
METHANOL STEL: 250 PPM TWA: 200 PPM IDLH: 6000 PPM
67-56-1 TWA: 200 PPM TWA: 260 MG/M3 TWA: 200 PPM
S* (VACATED) TWA: 200 PPM TWA: 260 MG/M3
(VACATED) TWA: STEL: 250 PPM
260 MG/M3 STEL: 325 MG/M3
(VACATED) STEL: 250 PPM
(VACATED) STEL: 325 MG/M3
(VACATED) S*
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING CONTROLS:
APPLY TECHNICAL MEASURES TO COMPLY WITH THE OCCUPATIONAL EXPOSURE LIMITS.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
REFER TO 29 CFR 1910.133 FOR EYE AND FACE PROTECTION REGULATIONS.
SKIN AND BODY PROTECTION:
REFER TO 29 CFR 1910.138 FOR APPROPRIATE SKIN AND BODY PROTECTION.
RESPIRATORY PROTECTION:
REFER TO 29 CFR 1910.134 FOR RESPIRATORY PROTECTION REQUIREMENTS.
GENERAL HYGIENE CONSIDERATIONS:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: PURPLE LIQUID
COLOR: PURPLE
ODOR: SLIGHT ALCOHOL
ODOR THRESHOLD: NOT DETERMINED
PROPERTY VALUES REMARKS - METHOD
PH 8.0
MELTING POINT / FREEZING POINT -32 DEG. C / -25.6 DEG. F
BOILING POINT / BOILING RANGE 83 DEG. C / 181.4 DEG. F
FLASH POINT 30 DEG. C / 86 DEG. F
EVAPORATION RATE NOT DETERMINED
FLAMMABILITY (SOLID, GAS) LIQUID-NOT APPLICABLE
FLAMMABILITY LIMIT IN AIR:
UPPER FLAMMABILITY OR NOT DETERMINED
EXPLOSIVE LIMITS
LOWER FLAMMABILITY OR NOT DETERMINED
EXPLOSIVE LIMITS
VAPOR PRESSURE NOT DETERMINED
VAPOR DENSITY NOT DETERMINED
RELATIVE DENSITY 0.948
WATER SOLUBILITY NOT DETERMINED
SOLUBILITY IN OTHER SOLVENTS NOT DETERMINED
PARTITION COEFFICIENT NOT DETERMINED
AUTOIGNITION TEMPERATURE NOT DETERMINED
DECOMPOSITION TEMPERATURE NOT DETERMINED
KINEMATIC VISCOSITY NOT DETERMINED
DYNAMIC VISCOSITY NOT DETERMINED
EXPLOSIVE PROPERTIES NOT DETERMINED
OXIDIZING PROPERTIES NOT DETERMINED
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NOT REACTIVE UNDER NORMAL CONDITIONS.
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
CONDITIONS TO AVOID: KEEP OUT OF REACH OF CHILDREN.
INCOMPATIBLE MATERIALS: NONE KNOWN BASED ON INFORMATION SUPPLIED.
HAZARDOUS DECOMPOSITION PRODUCTS: NONE KNOWN BASED ON INFORMATION SUPPLIED.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRODUCT INFORMATION:
EYE CONTACT: AVOID CONTACT WITH EYES.
SKIN CONTACT: TOXIC IN CONTACT WITH SKIN.
INHALATION: TOXIC IF INHALED.
INGESTION: HARMFUL IF SWALLOWED.
COMPONENT INFORMATION:
CHEMICAL NAME ORAL LD50 DERMAL LD50 INHALATION LC50
METHANOL = 6200 MG/KG = 15840 MG/KG = 22500 PPM (RAT) 8 H
67-56-1 (RAT) (RABBIT) = 64000 PPM (RAT) 4 H
= 15800 MG/KG
(RABBIT)
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
SYMPTOMS: PLEASE SEE SECTION 4 OF THIS SDS FOR SYMPTOMS.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
CARCINOGENICITY:
BASED ON THE INFORMATION PROVIDED, THIS PRODUCT DOES NOT CONTAIN ANY
CARCINOGENS OR POTENTIAL CARCINOGENS AS LISTED BY OSHA, IARC OR NTP.
STOT - SINGLE EXPOSURE: CAUSES DAMAGE TO ORGANS.
NUMERICAL MEASURES OF TOXICITY:
THE FOLLOWING VALUES ARE CALCULATED BASED ON CHAPTER 3.1 OF THE GHS
DOCUMENT.
ORAL LD50: 311.53 MG/KG
DERMAL LD50: 934.60 MG/KG
ATEMIX (INHALATION-DUST/MIST): 1.56 MG/L
ATEMIX (INHALATION-VAPOR): 9.35 MG/L
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
THE PRODUCT IS NOT CLASSIFIED AS ENVIRONMENTALLY HAZARDOUS. HOWEVER, THIS
DOES NOT EXCLUDE THE POSSIBILITY THAT LARGE OR FREQUENT SPILLS CAN HAVE A
HARMFUL OR DAMAGING EFFECT ON THE ENVIRONMENT.
COMPONENT INFORMATION:
CHEMICAL NAME ALGAE/AQUATIC FISH CRUSTACEA
PLANTS
METHANOL 18 - 20: 96 H ONCORHYNCHUS
67-56-1 MYKISS ML/L LC50 STATIC
19500 - 20700: 96 H
ONCORHYNCHUS MYKISS MG/L
LC50 FLOW-THROUGH 28200:
96 H PIMEPHALES PROMELAS
MG/L LC50 FLOW-THROUGH
100: 96 H PIMEPHALES
PROMELAS MG/L LC50
STATIC 13500 - 17600:
96 H LEPOMIS MACROCHIRUS
MG/L LC50 FLOW-THROUGH
PERSISTENCE/DEGRADABILITY: NOT DETERMINED.
BIOACCUMULATION: THERE IS NO DATA FOR THIS PRODUCT.
MOBILITY:
CHEMICAL NAME PARTITION COEFFICIENT
METHANOL -0.77
67-56-1
OTHER ADVERSE EFFECTS: NOT DETERMINED
| 13. DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
DISPOSAL OF WASTES:
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND
LOCAL LAWS AND REGULATIONS.
CONTAMINATED PACKAGING:
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND
LOCAL LAWS AND REGULATIONS.
US EPA WASTE NUMBER:
CHEMICAL NAME RCRA RCRA - BASIS FOR RCRA - D SERIES RCRA - U SERIES
LISTING WASTES WASTES
METHANOL INCLUDED IN U154
67-56-1 WASTE STREAM:
F039
CALIFORNIA HAZARDOUS WASTE STATUS:
CHEMICAL NAME CALIFORNIA HAZARDOUS WASTE STATUS
METHANOL TOXIC
67-56-1 IGNITABLE
| 14. TRANSPORT INFORMATION | |
NOTE:
PLEASE SEE CURRENT SHIPPING PAPER FOR MOST UP TO DATE SHIPPING INFORMATION,
INCLUDING EXEMPTIONS AND SPECIAL CIRCUMSTANCES.
DOT:
UN/ID NO: UN1993
PROPER SHIPPING NAME: FLAMMABLE LIQUIDS, N.O.S. (METHANOL)
HAZARD CLASS: 3
PACKING GROUP: III
IATA:
UN NUMBER: UN1992
PROPER SHIPPING NAME: FLAMMABLE LIQUID, TOXIC, N.O.S. (METHANOL)
TRANSPORT HAZARD CLASS(ES): 3
SUBSIDIARY HAZARD CLASS: 6.1
PACKING GROUP: III
IMDG:
UN NUMBER: UN1992
PROPER SHIPPING NAME: FLAMMABLE LIQUID, TOXIC, N.O.S. (METHANOL)
TRANSPORT HAZARD CLASS(ES): 3
SUBSIDIARY HAZARD CLASS: 6.1
PACKING GROUP: III
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
CHEMICAL NAME TSCA DSL/ EINECS/ ENCS IECSC KECL PICCS AICS
NDSL ELINCS
METHANOL X X X X X X X X
LEGEND:
TSCA: UNITED STATES TOXIC SUBSTANCES CONTROL ACT SECTION 8(B) INVENTORY
DSL/NDSL: CANADIAN DOMESTIC SUBSTANCES LIST/NON-DOMESTIC SUBSTANCES LIST
EINECS/ELINCS:
EUROPEAN INVENTORY OF EXISTING CHEMICAL SUBSTANCES/EUROPEAN LIST OF
NOTIFIED CHEMICAL SUBSTANCES
ENCS: JAPAN EXISTING AND NEW CHEMICAL SUBSTANCES
IECSC: CHINA INVENTORY OF EXISTING CHEMICAL SUBSTANCES
KECL: KOREAN EXISTING AND EVALUATED CHEMICAL SUBSTANCES
PICCS: PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL SUBSTANCES
AICS: AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES
US FEDERAL REGULATIONS:
CERCLA:
CHEMICAL NAME HAZARDOUS SUBSTANCES CERCLA/SARA RQ REPORTABLE QUANTITY
RQS (RQ)
METHANOL 5000 LB RQ 5000 LB FINAL RQ
67-56-1 RQ 2270 KG FINAL RQ
SARA 313:
CHEMICAL NAME CAS NO WEIGHT-% SARA 313 - THRESHOLD VALUES %
METHANOL - 67-56-1 67-56-1 30-35 1.0
CWA (CLEAN WATER ACT):
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS POLLUTANTS
PURSUANT TO THE CLEAN WATER ACT (40 CFR 122.21 AND 40 CFR 122.42)
US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS THE FOLLOWING PROPOSITION 65 CHEMICALS.
CHEMICAL NAME CALIFORNIA PROPOSITION 65
METHANOL - 67-56-1 DEVELOPMENTAL
U.S. STATE RIGHT-TO-KNOW REGULATIONS:
CHEMICAL NAME NEW JERSEY MASSACHUSETTS PENNSYLVANIA
METHANOL X X X
67-56-1
| 16. OTHER INFORMATION | |
NFPA:
HEALTH HAZARDS NOT DETERMINED
FLAMMABILITY NOT DETERMINED
INSTABILITY NOT DETERMINED
SPECIAL HAZARDS NOT DETERMINED
HMIS:
HEALTH HAZARDS NOT DETERMINED
FLAMMABILITY NOT DETERMINED
PHYSICAL HAZARDS NOT DETERMINED
PERSONAL PROTECTION NOT DETERMINED
ISSUE DATE: 05-DEC-2018
REVISION DATE: 07-DEC-2018
REVISION NOTE: NEW FORMAT
DISCLAIMER:
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT.