| Common Name: | SPLASH CONCENTRATE WINDSHIELD WASH |
| Manufacturer: | FMP |
| SDS Revision Date: | 8/17/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 40Z941 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SPLASH(R*)
SEE SAFELY.(TM)
SAFETY DATA SHEET
ISSUE DATE: 15-AUG-2018
REVISION DATE: 17-AUG-2018
VERSION: 1
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT NAME: SPLASH CONCENTRATE WINDSHIELD WASH
OTHER MEANS OF IDENTIFICATION:
SDS/PART #: 100234
UN/ID NO: UN1230
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: GAS LINE ANTI-FREEZE.
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER ADDRESS:
FMP
1380 CORPORATE CENTER CURVE, SUITE 200
EAGAN, MN 55121
PHONE: 888-784-0802
EMERGENCY TELEPHONE NUMBER:
EMERGENCY TELEPHONE:
INFOTRAC:
1-352-323-3500 (INTERNATIONAL)
1-800-535-5053 (NORTH AMERICA)
| 2. HAZARDS IDENTIFICATION | |
APPEARANCE: CLEAR COLORLESS
PHYSICAL STATE: LIQUID
ODOR: VERY, SLIGHT ALCOHOL SMELL
CLASSIFICATION:
ACUTE TOXICITY - ORAL: CATEGORY 3
ACUTE TOXICITY - DERMAL: CATEGORY 3
ACUTE TOXICITY - INHALATION (VAPORS): CATEGORY 3
ACUTE TOXICITY - INHALATION (DUSTS/MISTS): CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 1
FLAMMABLE LIQUIDS: CATEGORY 2
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
TOXIC IF SWALLOWED
TOXIC IN CONTACT WITH SKIN
TOXIC IF INHALED
CAUSES DAMAGE TO ORGANS
HIGHLY FLAMMABLE LIQUID AND VAPOR
SKULLS AND CROSSBONES
HEALTH HAZARD
FLAME
PRECAUTIONARY STATEMENTS - PREVENTION:
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING
KEEP CONTAINER TIGHTLY CLOSED
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT
USE EXPLOSION-PROOF EQUIPMENT
USE ONLY NON-SPARKING TOOLS
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE
KEEP COOL
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION
PRECAUTIONARY STATEMENTS - RESPONSE:
IF EXPOSED: CALL A POISON CENTER OR DOCTOR
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER
WASH CONTAMINATED CLOTHING BEFORE REUSE
CALL A POISON CENTER OR DOCTOR IF YOU FEEL UNWELL
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING
CALL A POISON CENTER OR DOCTOR
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER OR DOCTOR
RINSE MOUTH
IN CASE OF FIRE: USE CO2, DRY CHEMICAL, OR FOAM TO EXTINGUISH
PRECAUTIONARY STATEMENTS - STORAGE:
STORE LOCKED UP
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS NO. WEIGHT-%
METHANOL 67-56-1 90-100
IF CHEMICAL NAME/CAS NO IS "PROPRIETARY" AND/OR WEIGHT-% IS LISTED AS A
RANGE, THE SPECIFIC CHEMICAL IDENTITY AND/OR PERCENTAGE OF COMPOSITION
HAS BEEN WITHHELD AS A TRADE SECRET.
| 4. FIRST AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
GENERAL ADVICE:
IF EXPOSED: CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
EYE CONTACT:
RINSE THOROUGHLY WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES, LIFTING
LOWER AND UPPER EYELIDS. CONSULT A PHYSICIAN.
SKIN CONTACT:
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER. WASH CONTAMINATED CLOTHING BEFORE REUSE. CALL A POISON
CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
INHALATION:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER OR DOCTOR/PHYSICIAN.
INGESTION:
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN. RINSE MOUTH.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS:
TOXIC IF SWALLOWED. TOXIC IN CONTACT WITH SKIN. TOXIC IF INHALED. CAUSES
DAMAGE TO ORGANS.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT.
UNSUITABLE EXTINGUISHING MEDIA: NOT DETERMINED.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
HIGHLY FLAMMABLE LIQUID AND VAPOR.
PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
ENVIRONMENTAL PRECAUTIONS:
ENVIRONMENTAL PRECAUTIONS:
SEE SECTION 12 FOR ADDITIONAL ECOLOGICAL INFORMATION.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
METHODS FOR CLEAN-UP: KEEP IN SUITABLE, CLOSED CONTAINERS FOR DISPOSAL.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
ADVICE ON SAFE HANDLING:
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING. DO NOT
EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. USE ONLY OUTDOORS OR IN A
WELL-VENTILATED AREA. DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY. KEEP
AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. KEEP
CONTAINER TIGHTLY CLOSED. GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
USE EXPLOSION PROOF EQUIPMENT. USE ONLY NON-SPARKING TOOLS. TAKE
PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGES. KEEP COOL. WEAR
PROTECTIVE GLOVES/PROTECTIVE CLOTHING AND EYE/FACE PROTECTION.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
STORE LOCKED UP. STORE IN A WELL-VENTILATED PLACE. KEEP COOL. KEEP
CONTAINER TIGHTLY CLOSED.
INCOMPATIBLE MATERIALS: NONE KNOWN BASED ON INFORMATION SUPPLIED.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
EXPOSURE GUIDELINES:
CHEMICAL NAME ACGIH TLV OSHA PEL NIOSH IDLH
METHANOL STEL: 250 PPM TWA: 200 PPM IDLH: 6000 PPM
67-56-1 TWA: 200 PPM TWA: 260 MG/M3 TWA: 200 PPM
S* (VACATED) TWA: TWA: 260 MG/M3
200 PPM STEL: 250 PPM
(VACATED) TWA: STEL: 325 MG/M3
260 MG/M3
(VACATED) STEL:
250 PPM
(VACATED) STEL:
325 MG/M3
(VACATED) S*
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING CONTROLS: SHOWERS. EYEWASH STATIONS. VENTILATION SYSTEMS.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
REFER TO 29 CFR 1910.133 FOR EYE AND FACE PROTECTION REGULATIONS.
SKIN AND BODY PROTECTION:
REFER TO 29 CFR 1910.138 FOR APPROPRIATE SKIN AND BODY PROTECTION.
RESPIRATORY PROTECTION:
REFER TO 29 CFR 1910.134 FOR RESPIRATORY PROTECTION REQUIREMENTS.
GENERAL HYGIENE CONSIDERATIONS:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: CLEAR COLORLESS
COLOR: NOT DETERMINED
ODOR: VERY, SLIGHT ALCOHOL SMELL
ODOR THRESHOLD: NOT DETERMINED
PROPERTY VALUES REMARKS -
METHOD
PH NOT DETERMINED
MELTING POINT / FREEZING POINT -97.8 DEG. C / -144 DEG. F
BOILING POINT / BOILING RANGE 64.4 DEG. C / 148 DEG. F
FLASH POINT 12.2 DEG. C / 54 DEG. F
EVAPORATION RATE NOT DETERMINED
FLAMMABILITY (SOLID, GAS) LIQUID-NOT APPLICABLE
FLAMMABILITY LIMIT IN AIR:
UPPER FLAMMABILITY OR EXPLOSIVE NOT DETERMINED
LIMITS
LOWER FLAMMABILITY OR EXPLOSIVE NOT DETERMINED
LIMITS
VAPOR PRESSURE NOT DETERMINED
VAPOR DENSITY NOT DETERMINED
RELATIVE DENSITY 0.7925
WATER SOLUBILITY NOT DETERMINED
SOLUBILITY IN OTHER SOLVENTS NOT DETERMINED
PARTITION COEFFICIENT NOT DETERMINED
AUTOIGNITION TEMPERATURE NOT DETERMINED
DECOMPOSITION TEMPERATURE NOT DETERMINED
KINEMATIC VISCOSITY NOT DETERMINED
DYNAMIC VISCOSITY NOT DETERMINED
EXPLOSIVE PROPERTIES NOT DETERMINED
OXIDIZING PROPERTIES NOT DETERMINED
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NOT REACTIVE UNDER NORMAL CONDITIONS.
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
CONDITIONS TO AVOID: KEEP OUT OF REACH OF CHILDREN.
INCOMPATIBLE MATERIALS: NONE KNOWN BASED ON INFORMATION SUPPLIED.
HAZARDOUS DECOMPOSITION PRODUCTS: NONE KNOWN BASED ON INFORMATION SUPPLIED.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRODUCT INFORMATION:
EYE CONTACT: AVOID CONTACT WITH EYES.
SKIN CONTACT: TOXIC IN CONTACT WITH SKIN.
INHALATION: TOXIC IF INHALED.
INGESTION: TOXIC IF SWALLOWED.
COMPONENT INFORMATION:
CHEMICAL NAME ORAL LD50 DERMAL LD50 INHALATION LC50
METHANOL = 6200 MG/KG = 15800 MG/KG = 22500 PPM (RAT)
67-56-1 (RAT) (RABBIT) 8 H
= 15840 MG/KG = 64000 PPM (RAT)
(RABBIT) 4 H
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
SYMPTOMS: PLEASE SEE SECTION 4 OF THIS SDS FOR SYMPTOMS.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
CARCINOGENICITY:
BASED ON THE INFORMATION PROVIDED, THIS PRODUCT DOES NOT CONTAIN ANY
CARCINOGENS OR POTENTIAL CARCINOGENS AS LISTED BY OSHA, IARC OR NTP.
STOT - SINGLE EXPOSURE: CAUSES DAMAGE TO ORGANS.
NUMERICAL MEASURES OF TOXICITY:
THE FOLLOWING VALUES ARE CALCULATED BASED ON CHAPTER 3.1 OF THE GHS
DOCUMENT.
ATEMIX (ORAL): 100.00 MG/KG
ATEMIX (DERMAL): 300.00 MG/KG
ATEMIX (INHALATION-DUST/MIST): 0.50 MG/L
ATEMIX (INHALATION-VAPOR): 3.00 MG/L
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
THE PRODUCT IS NOT CLASSIFIED AS ENVIRONMENTALLY HAZARDOUS. HOWEVER, THIS
DOES NOT EXCLUDE THE POSSIBILITY THAT LARGE OR FREQUENT SPILLS CAN HAVE A
HARMFUL OR DAMAGING EFFECT ON THE ENVIRONMENT.
COMPONENT INFORMATION:
CHEMICAL NAME ALGAE/AQUATIC FISH CRUSTACEA
PLANTS
METHANOL 18 - 20: 96 H ONCORHYNCHUS
67-56-1 MYKISS ML/L LC50 STATIC
28200: 96 H PIMEPHALES
PROMELAS MG/L LC50 FLOW-
THROUGH 100: 96 H
PIMEPHALES PROMELAS MG/L
LC50 STATIC 19500 - 20700:
96 H ONCORHYNCHUS MYKISS
MG/L LC50 FLOW-THROUGH
13500 - 17600: 96 H LEPOMIS
MACROCHIRUS MG/L LC50
FLOW-THROUGH
PERSISTENCE/DEGRADABILITY: NOT DETERMINED.
BIOACCUMULATION: THERE IS NO DATA FOR THIS PRODUCT.
MOBILITY:
CHEMICAL NAME PARTITION COEFFICIENT
METHANOL -0.77
67-56-1
OTHER ADVERSE EFFECTS: NOT DETERMINED
| 13. DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
DISPOSAL OF WASTES:
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND
LOCAL LAWS AND REGULATIONS.
CONTAMINATED PACKAGING:
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND
LOCAL LAWS AND REGULATIONS.
US EPA WASTE NUMBER:
CHEMICAL NAME RCRA RCRA - BASIS RCRA - D RCRA - U
FOR LISTING SERIES WASTES SERIES WASTES
METHANOL INCLUDED IN WASTE U154
67-56-1 STREAM: F039
CALIFORNIA HAZARDOUS WASTE STATUS:
CHEMICAL NAME CALIFORNIA HAZARDOUS WASTE STATUS
METHANOL TOXIC
67-56-1 IGNITABLE
| 14. TRANSPORT INFORMATION | |
NOTE:
PLEASE SEE CURRENT SHIPPING PAPER FOR MOST UP TO DATE SHIPPING INFORMATION,
INCLUDING EXEMPTIONS AND SPECIAL CIRCUMSTANCES.
DOT:
UN/ID NO: UN1230
PROPER SHIPPING NAME: METHANOL
HAZARD CLASS: 3
PACKING GROUP: II
IATA:
UN NUMBER: UN1230
PROPER SHIPPING NAME: METHANOL
TRANSPORT HAZARD CLASS(ES): 3
SUBSIDIARY HAZARD CLASS: 6.1
PACKING GROUP: II
IMDG:
UN NUMBER: UN1230
PROPER SHIPPING NAME: METHANOL
TRANSPORT HAZARD CLASS(ES): 3
SUBSIDIARY HAZARD CLASS: 6.1
PACKING GROUP: II
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
CHEMICAL NAME TSCA DSL/ EINECS/ ENCS IECSC KECL PICCS AICS
NDSL ELINCS
METHANOL X X X X X X X X
LEGEND:
TSCA: UNITED STATES TOXIC SUBSTANCES CONTROL ACT SECTION 8(B) INVENTORY
DSL/NDSL: CANADIAN DOMESTIC SUBSTANCES LIST/NON-DOMESTIC SUBSTANCES LIST
EINECS/ELINCS:
EUROPEAN INVENTORY OF EXISTING CHEMICAL SUBSTANCES/EUROPEAN LIST OF
NOTIFIED CHEMICAL SUBSTANCES
ENCS: JAPAN EXISTING AND NEW CHEMICAL SUBSTANCES
IECSC: CHINA INVENTORY OF EXISTING CHEMICAL SUBSTANCES
KECL: KOREAN EXISTING AND EVALUATED CHEMICAL SUBSTANCES
PICCS: PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL SUBSTANCES
AICS: AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES
US FEDERAL REGULATIONS:
CERCLA:
CHEMICAL NAME HAZARDOUS CERCLA/SARA RQ REPORTABLE
SUBSTANCES RQS QUANTITY (RQ)
METHANOL 5000 LB RQ 5000 LB FINAL RQ
67-56-1 RQ 2270 KG FINAL RQ
SARA 313:
CHEMICAL NAME CAS NO. WEIGHT-% SARA 313 - THRESHOLD VALUES %
METHANOL - 67-56-1 67-56-1 90-100 1.0
CWA (CLEAN WATER ACT):
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS POLLUTANTS
PURSUANT TO THE CLEAN WATER ACT (40 CFR 122.21 AND 40 CFR 122.42)
US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS THE FOLLOWING PROPOSITION 65 CHEMICALS.
CHEMICAL NAME CALIFORNIA PROPOSITION 65
METHANOL - 67-56-1 DEVELOPMENTAL
U.S. STATE RIGHT-TO-KNOW REGULATIONS:
CHEMICAL NAME NEW JERSEY MASSACHUSETTS PENNSYLVANIA
METHANOL X X X
67-56-1
| 16. OTHER INFORMATION | |
NFPA:
HEALTH HAZARDS NOT DETERMINED
FLAMMABILITY NOT DETERMINED
INSTABILITY NOT DETERMINED
SPECIAL HAZARDS NOT DETERMINED
HMIS:
HEALTH HAZARDS NOT DETERMINED
FLAMMABILITY NOT DETERMINED
PHYSICAL HAZARDS NOT DETERMINED
PERSONAL PROTECTION NOT DETERMINED
ISSUE DATE: 15-AUG-2018
REVISION DATE: 17-AUG-2018
REVISION NOTE: NEW FORMAT
DISCLAIMER:
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT.