| Common Name: | CAL-BLUE PLUS PRESSURIZED SPRAY (4182-35) |
| Manufacturer: | NU-CALGON WHOLESALER |
| SDS Revision Date: | 1/27/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 410X89 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
SAFETY DATA SHEET
NU-CALGON
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT IDENTIFIER: CAL-BLUE PLUS PRESSURIZED SPRAY (4182-35)
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE
RECOMMENDED USE: GAS LEAK DETECTOR
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER INFORMATION:
NU-CALGON
2008 ALTOM COURT
ST. LOUIS, MO 63146
US
PHONE: 314-469-7000 / 800-554-5499
EMERGENCY PHONE: 1-800-424-9300 (CHEMTREC)
SUPPLIER: SEE ABOVE.
| 2. HAZARDS IDENTIFICATION | |
PHYSICAL HAZARDS:
GASES UNDER PRESSURE: COMPRESSED GAS
HEALTH HAZARDS: NOT CLASSIFIED.
ENVIRONMENTAL HAZARDS: NOT CLASSIFIED.
WHMIS 2015 DEFINED HAZARDS: NOT CLASSIFIED
LABEL ELEMENTS: GAS CYLINDER
SIGNAL WORD: WARNING
HAZARD STATEMENT: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
PRECAUTIONARY STATEMENT:
PREVENTION: OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES.
RESPONSE: WASH HANDS AFTER HANDLING.
STORAGE:
PROTECT FROM SUNLIGHT. STORE IN A WELL-VENTILATED PLACE. STORE AWAY FROM
INCOMPATIBLE MATERIALS.
DISPOSAL:
DISPOSE OF WASTE AND RESIDUES IN ACCORDANCE WITH LOCAL AUTHORITY
REQUIREMENTS.
WHMIS 2015: HEALTH HAZARD(S) NOT OTHERWISE CLASSIFIED (HHNOC)
NONE KNOWN
WHMIS 2015: PHYSICAL HAZARD(S) NOT OTHERWISE CLASSIFIED (PHNOC)
NONE KNOWN
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN.
SUPPLEMENTAL INFORMATION: NOT APPLICABLE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURE:
CHEMICAL NAME COMMON NAME AND SYNONYMS CAS NUMBER %
1,2-PROPANEDIOL 57-55-6 25
ALL CONCENTRATIONS ARE IN PERCENT BY WEIGHT UNLESS INGREDIENT IS A GAS. GAS
CONCENTRATIONS ARE IN PERCENT BY VOLUME.
| 4. FIRST AID MEASURES | |
INHALATION:
IF SYMPTOMS DEVELOP MOVE VICTIM TO FRESH AIR. GET MEDICAL ATTENTION IF
SYMPTOMS PERSIST.
SKIN CONTACT:
FLUSH WITH COOL WATER. WASH WITH SOAP AND WATER. OBTAIN MEDICAL ATTENTION
IF IRRITATION PERSISTS.
EYE CONTACT:
FLUSH WITH COOL WATER. REMOVE CONTACT LENSES, IF APPLICABLE, AND CONTINUE
FLUSHING. OBTAIN MEDICAL ATTENTION IF IRRITATION PERSISTS.
INGESTION:
DO NOT INDUCE VOMITING. IF VOMITING OCCURS NATURALLY, HAVE VICTIM LEAN
FORWARD TO REDUCE RISK OF ASPIRATION. NEVER GIVE ANYTHING BY MOUTH IF
VICTIM IS UNCONSCIOUS, OR IS CONVULSING. OBTAIN MEDICAL ATTENTION.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
DIRECT CONTACT WITH EYES MAY CAUSE TEMPORARY IRRITATION.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY.
GENERAL INFORMATION:
IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED, AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES. SHOW THIS SAFETY DATA SHEET TO THE
DOCTOR IN ATTENDANCE. AVOID CONTACT WITH EYES AND SKIN. KEEP OUT OF REACH
OF CHILDREN.
| 5. FIRE FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
ALCOHOL RESISTANT FOAM. WATER FOG. CARBON DIOXIDE.
UNSUITABLE EXTINGUISHING MEDIA: NOT AVAILABLE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
DURING FIRE, GASES HAZARDOUS TO HEALTH MAY BE FORMED.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING MUST BE
WORN IN CASE OF FIRE.
FIRE-FIGHTING EQUIPMENT/INSTRUCTIONS:
IN CASE OF FIRE: STOP LEAK IF SAFE TO DO SO.
SPECIFIC METHODS:
USE STANDARD FIREFIGHTING PROCEDURES AND CONSIDER THE HAZARDS OF OTHER
INVOLVED MATERIALS. COOL CONTAINERS EXPOSED TO FLAMES WITH WATER UNTIL WELL
AFTER THE FIRE IS OUT.
GENERAL FIRE HAZARDS:
CONTENTS UNDER PRESSURE. PRESSURIZED CONTAINER MAY EXPLODE WHEN EXPOSED TO
HEAT OR FLAME. NO UNUSUAL FIRE OR EXPLOSION HAZARDS NOTED.
HAZARDOUS COMBUSTION PRODUCTS:
MAY INCLUDE AND ARE NOT LIMITED TO: OXIDES OF CARBON. OXIDES OF NITROGEN.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. KEEP OUT OF LOW AREAS. MANY GASES ARE HEAVIER THAN AIR AND
WILL SPREAD ALONG GROUND AND COLLECT IN LOW OR CONFINED AREAS (SEWERS,
BASEMENTS, TANKS). WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND CLOTHING
DURING CLEAN-UP. EMERGENCY PERSONNEL NEED SELF-CONTAINED BREATHING
EQUIPMENT. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS
WEARING APPROPRIATE PROTECTIVE CLOTHING. VENTILATE CLOSED SPACES BEFORE
ENTERING THEM. LOCAL AUTHORITIES SHOULD BE ADVISED IF SIGNIFICANT SPILLAGES
CANNOT BE CONTAINED. FOR PERSONAL PROTECTION, SEE SECTION 8 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
USE WATER SPRAY TO REDUCE VAPORS OR DIVERT VAPOR CLOUD DRIFT. ISOLATE AREA
UNTIL GAS HAS DISPERSED. PREVENT ENTRY INTO WATERWAYS, SEWER, BASEMENTS OR
CONFINED AREAS.
LARGE SPILLS:
STOP THE FLOW OF MATERIAL, IF THIS IS WITHOUT RISK. DIKE THE SPILLED
MATERIAL, WHERE THIS IS POSSIBLE. COVER WITH PLASTIC SHEET TO PREVENT
SPREADING. ABSORB IN VERMICULITE, DRY SAND OR EARTH AND PLACE INTO
CONTAINERS.
SMALL SPILLS:
WIPE UP WITH ABSORBENT MATERIAL (E.G. CLOTH, FLEECE). CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
NEVER RETURN SPILLS TO ORIGINAL CONTAINERS FOR RE-USE. FOR WASTE DISPOSAL,
SEE SECTION 13 OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
AVOID DISCHARGE INTO DRAINS, WATER COURSES OR ONTO THE GROUND. DO NOT
DISCHARGE INTO LAKES, STREAMS, PONDS OR PUBLIC WATERS.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
AVOID CONTACT WITH EYES AND SKIN. WASH HANDS THOROUGHLY AFTER HANDLING.
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. PROVIDE
ADEQUATE VENTILATION. AVOID PROLONGED EXPOSURE. WEAR APPROPRIATE PERSONAL
PROTECTIVE EQUIPMENT. USE CARE IN HANDLING/STORAGE. ENSURE ADEQUATE
VENTILATION. USE GOOD INDUSTRIAL HYGIENE PRACTICES IN HANDLING THIS
MATERIAL. WHEN USING DO NOT EAT OR DRINK.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE LOCKED UP. PROTECT FROM SUNLIGHT. STORE IN A COOL, DRY PLACE OUT OF
DIRECT SUNLIGHT. STORE IN A WELL-VENTILATED PLACE. CYLINDERS SHOULD BE
STORED UPRIGHT, WITH VALVE PROTECTION CAP IN PLACE, AND FIRMLY SECURED TO
PREVENT FALLING OR BEING KNOCKED OVER. KEEP AWAY FROM HEAT, OPEN FLAMES OR
OTHER SOURCES OF IGNITION. DO NOT EXPOSE TO TEMPERATURES EXCEEDING 120 DEG.
F (49 DEG. C).
KEEP OUT OF REACH OF CHILDREN.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
CANADA. ONTARIO OELS. (CONTROL OF EXPOSURE TO BIOLOGICAL OR CHEMICAL
AGENTS):
COMPONENTS TYPE VALUE FORM
1,2-PROPANEDIOL TWA 155 MG/M3 VAPOR AND AEROSOL.
(CAS 57-55-6) 10 MG/M3 AEROSOL.
50 PPM VAPOR AND AEROSOL.
US. AIHA WORKPLACE ENVIRONMENTAL EXPOSURE LEVEL (WEEL) GUIDES:
COMPONENTS TYPE VALUE FORM
1,2-PROPANEDIOL TWA 10 MG/M3 AEROSOL.
(CAS 57-55-6)
BIOLOGICAL LIMIT VALUES:
NO BIOLOGICAL EXPOSURE LIMITS NOTED FOR THE INGREDIENT(S).
EXPOSURE GUIDELINES: SEE ABOVE
CANADA - ALBERTA OELS: SKIN DESIGNATION
1,4-DIOXANE (CAS 123-91-1) CAN BE ABSORBED THROUGH THE SKIN.
CANADA - BRITISH COLUMBIA OELS: SKIN DESIGNATION
1,4-DIOXANE (CAS 123-91-1) CAN BE ABSORBED THROUGH THE SKIN.
CANADA - MANITOBA OELS: SKIN DESIGNATION
1,4-DIOXANE (CAS 123-91-1) CAN BE ABSORBED THROUGH THE SKIN.
CANADA - ONTARIO OELS: SKIN DESIGNATION
1,4-DIOXANE (CAS 123-91-1) CAN BE ABSORBED THROUGH THE SKIN.
CANADA - QUEBEC OELS: SKIN DESIGNATION
1,4-DIOXANE (CAS 123-91-1) CAN BE ABSORBED THROUGH THE SKIN.
CANADA - SASKATCHEWAN OELS: SKIN DESIGNATION
1,4-DIOXANE (CAS 123-91-1) CAN BE ABSORBED THROUGH THE SKIN.
US ACGIH THRESHOLD LIMIT VALUES: SKIN DESIGNATION
1,4-DIOXANE (CAS 123-91-1) CAN BE ABSORBED THROUGH THE SKIN.
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
1,4-DIOXANE (CAS 123-91-1) CAN BE ABSORBED THROUGH THE SKIN.
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE
USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE,
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
IF EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS
TO AN ACCEPTABLE LEVEL.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
SKIN PROTECTION:
HAND PROTECTION: RUBBER GLOVES. CONFIRM WITH A REPUTABLE SUPPLIER FIRST.
OTHER: AS REQUIRED BY EMPLOYER CODE. WEAR SUITABLE PROTECTIVE CLOTHING.
RESPIRATORY PROTECTION:
WHERE EXPOSURE GUIDELINE LEVELS MAY BE EXCEEDED, USE AN APPROVED NIOSH
RESPIRATOR. RESPIRATOR SHOULD BE SELECTED BY AND USED UNDER THE DIRECTION
OF A TRAINED HEALTH AND SAFETY PROFESSIONAL FOLLOWING REQUIREMENTS FOUND IN
OSHA'S RESPIRATOR STANDARD (29 CFR 1910.134), CAN/CSA-Z94.4 AND ANSI'S
STANDARD FOR RESPIRATORY PROTECTION (Z88.2).
THERMAL HAZARDS: NOT APPLICABLE.
GENERAL HYGIENE CONSIDERATIONS:
ALWAYS OBSERVE GOOD PERSONAL HYGIENE MEASURES, SUCH AS WASHING AFTER
HANDLING THE MATERIAL AND BEFORE EATING, DRINKING, AND/OR SMOKING.
ROUTINELY WASH WORK CLOTHING AND PROTECTIVE EQUIPMENT TO REMOVE
CONTAMINANTS. WHEN USING DO NOT EAT OR DRINK.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: CLEAR
PHYSICAL STATE: GAS.
FORM: COMPRESSED GAS. SPRAY
COLOR: BLUE
ODOR: NEUTRAL
ODOR THRESHOLD: NOT AVAILABLE.
PH: 8.1 - 8.5 (LIQUID)
MELTING POINT/FREEZING POINT: 15 DEG. F (-9.44 DEG. C) (LIQUID)
INITIAL BOILING POINT AND BOILING RANGE: NOT AVAILABLE.
POUR POINT: NOT AVAILABLE.
SPECIFIC GRAVITY: NOT AVAILABLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE
FLASH POINT: NOT AVAILABLE.
EVAPORATION RATE: NOT AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): NOT AVAILABLE
FLAMMABILITY LIMIT - UPPER (%): NOT AVAILABLE
EXPLOSIVE LIMIT - LOWER (%) NOT AVAILABLE.
EXPLOSIVE LIMIT - UPPER (%) NOT AVAILABLE.
VAPOR PRESSURE: 150 PSI
VAPOR DENSITY: NOT AVAILABLE
RELATIVE DENSITY: NOT AVAILABLE.
SOLUBILITY(IES): NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: 325 - 425 CPS (LIQUID)
OTHER INFORMATION:
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE.
OXIDIZING PROPERTIES: NOT OXIDIZING.
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: THIS PRODUCT MAY REACT WITH STRONG OXIDIZING AGENTS.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
CONDITIONS TO AVOID: HEAT. DO NOT MIX WITH OTHER CHEMICALS.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
MAY INCLUDE AND ARE NOT LIMITED TO: OXIDES OF CARBON. OXIDES OF NITROGEN.
| 11. TOXICOLOGICAL INFORMATION | |
ROUTES OF EXPOSURE: EYE, SKIN CONTACT, INHALATION, INGESTION.
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INGESTION:
EXPECTED TO BE A LOW INGESTION HAZARD. MAY CAUSE STOMACH DISTRESS, NAUSEA
OR VOMITING.
INHALATION: PROLONGED INHALATION MAY BE HARMFUL.
SKIN CONTACT: NO ADVERSE EFFECTS DUE TO SKIN CONTACT ARE EXPECTED.
EYE CONTACT: DIRECT CONTACT WITH EYES MAY CAUSE TEMPORARY IRRITATION.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS: DIRECT CONTACT WITH EYES MAY CAUSE TEMPORARY IRRITATION.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
COMPONENTS SPECIES TEST RESULTS
1,2-PROPANEDIOL (CAS 57-55-6)
ACUTE:
DERMAL:
LD50 RABBIT 20800 MG/KG
INHALATION:
LC50 NOT AVAILABLE
ORAL:
LD50 DOG 19000 MG/KG
GUINEA PIG 184000 MG/KG
MOUSE 23900 MG/KG
RABBIT 14800 MG/KG
RAT 20000 MG/KG
SKIN CORROSION/IRRITATION:
PROLONGED SKIN CONTACT MAY CAUSE TEMPORARY IRRITATION.
EXPOSURE MINUTES: NOT AVAILABLE.
ERYTHEMA VALUE: NOT AVAILABLE.
OEDEMA VALUE: NOT AVAILABLE.
SERIOUS EYE DAMAGE/EYE IRRITATION:
DIRECT CONTACT WITH EYES MAY CAUSE TEMPORARY IRRITATION.
CORNEAL OPACITY VALUE: NOT AVAILABLE.
IRIS LESION VALUE: NOT AVAILABLE.
CONJUNCTIVAL REDDENING VALUE: NOT AVAILABLE.
CONJUNCTIVAL OEDEMA VALUE: NOT AVAILABLE.
RECOVER DAYS: NOT AVAILABLE.
RESPIRATORY OR SKIN SENSITIZATION:
ACGIH SENSITIZATION:
FORMALDEHYDE (CAS 50-00-0) DERMAL SENSITIZATION
RESPIRATORY SENSITIZATION
CANADA - BRITISH COLUMBIA OELS: RESPIRATORY OR SKIN SENSITIZER
FORMALDEHYDE (CAS 50-00-0) CAPABLE OF CAUSING RESPIRATORY, DERMAL OR
CONJUNCTIVAL SENSITIZATION.
CANADA - MANITOBA OELS HAZARD: DERMAL SENSITIZATION
FORMALDEHYDE (CAS 50-00-0) DERMAL SENSITIZATION
CANADA - MANITOBA OELS HAZARD: RESPIRATORY SENSITIZATION
FORMALDEHYDE (CAS 50-00-0) RESPIRATORY SENSITIZATION
CANADA - SASKATCHEWAN OELS HAZARD DATA: SENSITIZER
FORMALDEHYDE (CAS 50-00-0) SENSITIZER.
RESPIRATORY SENSITIZATION: NOT A RESPIRATORY SENSITIZER.
SKIN SENSITIZATION:
THIS PRODUCT IS NOT EXPECTED TO CAUSE SKIN SENSITIZATION.
MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
CARCINOGENICITY:
THIS PRODUCT IS NOT CONSIDERED TO BE A CARCINOGEN BY IARC, NTP, OR OSHA.
SEE BELOW.
ACGIH CARCINOGENS:
1,4-DIOXANE (CAS 123-91-1) A3 CONFIRMED ANIMAL CARCINOGEN WITH UNKNOWN
RELEVANCE TO HUMANS.
FORMALDEHYDE (CAS 50-00-0) A2 SUSPECTED HUMAN CARCINOGEN.
CANADA - ALBERTA OELS: CARCINOGEN CATEGORY
FORMALDEHYDE (CAS 50-00-0) SUSPECTED HUMAN CARCINOGEN.
CANADA - MANITOBA OELS: CARCINOGENICITY
1,4-DIOXANE (CAS 123-91-1) CONFIRMED ANIMAL CARCINOGEN WITH UNKNOWN
RELEVANCE TO HUMANS.
FORMALDEHYDE (CAS 50-00-0) SUSPECTED HUMAN CARCINOGEN.
CANADA - QUEBEC OELS: CARCINOGEN CATEGORY
1,4-DIOXANE (CAS 123-91-1) DETECTED CARCINOGENIC EFFECT IN ANIMALS.
FORMALDEHYDE (CAS 50-00-0) SUSPECTED CARCINOGENIC EFFECT IN HUMANS.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY:
1,4-DIOXANE (CAS 123-91-1) VOLUME 11, SUPPLEMENT 7, VOLUME 71 - 2B
POSSIBLY CARCINOGENIC TO HUMANS.
FORMALDEHYDE (CAS 50-00-0) VOLUME 88, VOLUME 100F 1 CARCINOGENIC TO
HUMANS.
US - CALIFORNIA PROPOSITION 65 - CRT: LISTED DATE/CARCINOGENIC SUBSTANCE
1,4-DIOXANE (CAS 123-91-1)
FORMALDEHYDE (CAS 50-00-0)
US NTP REPORT ON CARCINOGENS: ANTICIPATED CARCINOGEN
1,4-DIOXANE (CAS 123-91-1) REASONABLY ANTICIPATED TO BE A HUMAN
CARCINOGEN.
US NTP REPORT ON CARCINOGENS: KNOWN CARCINOGEN
FORMALDEHYDE (CAS 50-00-0) KNOWN TO BE HUMAN CARCINOGEN.
US. OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
FORMALDEHYDE (CAS 50-00-0) CANCER
REPRODUCTIVE TOXICITY:
THIS PRODUCT IS NOT EXPECTED TO CAUSE REPRODUCTIVE OR DEVELOPMENTAL
EFFECTS.
TERATOGENICITY: NOT AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NOT CLASSIFIED.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED.
ASPIRATION HAZARD: NOT AN ASPIRATION HAZARD.
CHRONIC EFFECTS: PROLONGED INHALATION MAY BE HARMFUL.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: SEE BELOW
ECOTOXICOLOGICAL DATA:
COMPONENTS SPECIES TEST RESULTS
1,2-PROPANEDIOL (CAS 57-55-6)
CRUSTACEA EC50 DAPHNIA 10000 MG/L, 48 HOURS
AQUATIC:
CRUSTACEA EC50 WATER FLEA (DAPHNIA MAGNA) >10000 MG/L, 48 HOURS
FISH LC50 FATHEAD MINNOW (PIMEPHALES 710 MG/L, 96 HOURS
PROMELAS)
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF THIS PRODUCT.
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE.
MOBILITY IN SOIL: NO DATA AVAILABLE.
MOBILITY IN GENERAL: NOT AVAILABLE.
OTHER ADVERSE EFFECTS:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION, PHOTOCHEMICAL
OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION, GLOBAL WARMING POTENTIAL)
ARE EXPECTED FROM THIS COMPONENT.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS:
COLLECT AND RECLAIM OR DISPOSE IN SEALED CONTAINERS AT LICENSED WASTE
DISPOSAL SITE. DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
LOCAL DISPOSAL REGULATIONS:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE:
THE WASTE CODE SHOULD BE ASSIGNED IN DISCUSSION BETWEEN THE USER, THE
PRODUCER AND THE WASTE DISPOSAL COMPANY.
WASTE FROM RESIDUES / UNUSED PRODUCTS:
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS. EMPTY CONTAINERS OR LINERS
MAY RETAIN SOME PRODUCT RESIDUES. THIS MATERIAL AND ITS CONTAINER MUST BE
DISPOSED OF IN A SAFE MANNER (SEE: DISPOSAL INSTRUCTIONS).
CONTAMINATED PACKAGING:
SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS
EVEN AFTER CONTAINER IS EMPTIED. EMPTY CONTAINERS SHOULD BE TAKEN TO AN
APPROVED WASTE HANDLING SITE FOR RECYCLING OR DISPOSAL.
| 14. TRANSPORT INFORMATION | |
TRANSPORT OF DANGEROUS GOODS (TDG) PROOF OF CLASSIFICATION:
IN ACCORDANCE WITH PART 2.2.1 (SOR/2014-152) OF THE TRANSPORTATION OF
DANGEROUS GOODS REGULATIONS, WE CERTIFY THAT THE CLASSIFICATION OF THIS
PRODUCT IS CORRECT AS OF THE SDS DATE OF ISSUE.
U.S. DEPARTMENT OF TRANSPORTATION (DOT):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1950
PROPER SHIPPING NAME:
AEROSOLS, NON-FLAMMABLE, (EACH NOT EXCEEDING 1 L CAPACITY)
HAZARD CLASS: LIMITED QUANTITY - US
PACKAGING NON BULK: NONE
PACKAGING BULK: NONE
TRANSPORTATION OF DANGEROUS GOODS (TDG - CANADA):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1950
PROPER SHIPPING NAME: AEROSOLS, NON-FLAMMABLE
HAZARD CLASS: LIMITED QUANTITY - CANADA
SPECIAL PROVISIONS: 80, 107
IATA/ICAO (AIR):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1950
PROPER SHIPPING NAME: AEROSOLS, NON-FLAMMABLE
HAZARD CLASS: LIMITED QUANTITY - IATA
IMDG (MARINE TRANSPORT):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1950
PROPER SHIPPING NAME: AEROSOLS
HAZARD CLASS: LIMITED QUANTITY - IMDG
DOT; IMDG; TDG:
LIMITED QUANTITY FOR PACKAGES NOT PREPARED FOR AIR TRANSPORT
IATA: LIMITED QUANTITY MARKING FOR PACKAGES PREPARED FOR AIR TRANSPORT
| 15. REGULATORY INFORMATION | |
CANADIAN FEDERAL REGULATIONS:
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF
THE HPR AND THE SDS CONTAINS ALL THE INFORMATION REQUIRED BY THE HPR.
CANADA CEPA SCHEDULE I: LISTED SUBSTANCE
FORMALDEHYDE (CAS 50-00-0) LISTED.
CANADA DSL CHALLENGE SUBSTANCES: LISTED SUBSTANCE
1,4-DIOXANE (CAS 123-91-1) LISTED.
CANADA NPRI VOCS WITH ADDITIONAL REPORTING REQUIREMENTS: MASS REPORTING
THRESHOLD/IDENTIFICATION NUMBER
FORMALDEHYDE (CAS 50-00-0) 1 TONNES
CANADA PRIORITY SUBSTANCES LIST (SECOND LIST): LISTED SUBSTANCE
FORMALDEHYDE (CAS 50-00-0) LISTED.
EXPORT CONTROL LIST (CEPA 1999, SCHEDULE 3): NOT LISTED.
GREENHOUSE GASES: NOT LISTED.
PRECURSOR CONTROL REGULATIONS: NOT REGULATED.
WHMIS 2015 EXEMPTIONS: NOT APPLICABLE
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4):
1,4-DIOXANE (CAS 123-91-1) LISTED.
FORMALDEHYDE (CAS 50-00-0) LISTED.
US EPCRA SECTION 304 EXTREMELY HAZ. SUBS. & CERCLA HAZ. SUBS.: SECTION 304
EHS REPORTABLE QUANTITY:
FORMALDEHYDE (CAS 50-00-0) 100 LBS
US. OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
FORMALDEHYDE (CAS 50-00-0) CANCER
SKIN SENSITIZATION
RESPIRATORY SENSITIZATION
EYE IRRITATION
SKIN IRRITATION
RESPIRATORY TRACT IRRITATION
ACUTE TOXICITY
FLAMMABILITY
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
HAZARD CATEGORIES:
IMMEDIATE HAZARD: YES
DELAYED HAZARD: NO
FIRE HAZARD: NO
REACTIVITY HAZARD: NO
PRESSURE HAZARD: YES
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NO
SARA 311/312 HAZARDOUS CHEMICAL: NO
SARA 313 (TRI REPORTING): NOT REGULATED.
OTHER FEDERAL REGULATIONS:
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
1,4-DIOXANE (CAS 123-91-1)
FORMALDEHYDE (CAS 50-00-0)
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION (40 CFR
68.130): FORMALDEHYDE (CAS 50-00-0)
US STATE REGULATIONS:
US - CALIFORNIA HAZARDOUS SUBSTANCES (DIRECTOR'S): LISTED SUBSTANCE
1,4-DIOXANE (CAS 123-91-1) LISTED.
FORMALDEHYDE (CAS 50-00-0) LISTED.
US - ILLINOIS CHEMICAL SAFETY ACT: LISTED SUBSTANCE
1,4-DIOXANE (CAS 123-91-1)
FORMALDEHYDE (CAS 50-00-0)
US - LOUISIANA SPILL REPORTING: LISTED SUBSTANCE
1,4-DIOXANE (CAS 123-91-1) LISTED.
FORMALDEHYDE (CAS 50-00-0) LISTED.
US - MINNESOTA HAZ SUBS: LISTED SUBSTANCE
1,2-PROPANEDIOL (CAS 57-55-6) LISTED.
1,4-DIOXANE (CAS 123-91-1) LISTED.
FORMALDEHYDE (CAS 50-00-0) LISTED.
US - NEW JERSEY RTK - SUBSTANCES: LISTED SUBSTANCE
1,2-PROPANEDIOL (CAS 57-55-6)
1,4-DIOXANE (CAS 123-91-1)
FORMALDEHYDE (CAS 50-00-0)
US - NORTH CAROLINA TOXIC AIR POLLUTANTS: LISTED SUBSTANCE
1,4-DIOXANE (CAS 123-91-1)
FORMALDEHYDE (CAS 50-00-0)
US - PENNSYLVANIA RTK - HAZARDOUS SUBSTANCES: SPECIAL HAZARD
1,4-DIOXANE (CAS 123-91-1)
FORMALDEHYDE (CAS 50-00-0)
US - TEXAS EFFECTS SCREENING LEVELS: LISTED SUBSTANCE
1,2-PROPANEDIOL (CAS 57-55-6) LISTED.
1,4-DIOXANE (CAS 123-91-1) LISTED.
FORMALDEHYDE (CAS 50-00-0) LISTED.
US - WASHINGTON CHEMICAL OF HIGH CONCERN TO CHILDREN: LISTED SUBSTANCE
1,4-DIOXANE (CAS 123-91-1)
FORMALDEHYDE (CAS 50-00-0)
US. MASSACHUSETTS RTK - SUBSTANCE LIST:
1,4-DIOXANE (CAS 123-91-1)
FORMALDEHYDE (CAS 50-00-0)
US. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
1,4-DIOXANE (CAS 123-91-1)
FORMALDEHYDE (CAS 50-00-0)
US. PENNSYLVANIA WORKER AND COMMUNITY RIGHT-TO-KNOW LAW:
1,2-PROPANEDIOL (CAS 57-55-6)
1,4-DIOXANE (CAS 123-91-1)
FORMALDEHYDE (CAS 50-00-0)
US. RHODE ISLAND RTK:
1,4-DIOXANE (CAS 123-91-1)
FORMALDEHYDE (CAS 50-00-0)
US. CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
US - CALIFORNIA PROPOSITION 65 - CRT: LISTED DATE/CARCINOGENIC SUBSTANCE
1,4-DIOXANE (CAS 123-91-1) LISTED: JANUARY 1, 1988
FORMALDEHYDE (CAS 50-00-0) LISTED: JANUARY 1, 1988
INVENTORY STATUS:
COUNTRY(S) OR REGION INVENTORY NAME ON INVENTORY
(YES/NO)*
CANADA DOMESTIC SUBSTANCES LIST (DSL) YES
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) NO
UNITED STATES & TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
PUERTO RICO INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
| 16. OTHER INFORMATION | |
LEGEND:
SEVERE 4
SERIOUS 3
MODERATE 2
SLIGHT 1
MINIMAL 0
HEALTH / 1
FLAMMABILITY 0
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA:
1
0
0
DISCLAIMER:
THE INFORMATION IN THE SHEET WAS WRITTEN BASED ON THE BEST KNOWLEDGE AND
EXPERIENCE CURRENTLY AVAILABLE. INFORMATION CONTAINED HEREIN WAS OBTAINED
FROM SOURCES CONSIDERED TECHNICALLY ACCURATE AND RELIABLE. WHILE EVERY
EFFORT HAS BEEN MADE TO ENSURE FULL DISCLOSURE OF PRODUCT HAZARDS, IN SOME
CASES DATA IS NOT AVAILABLE AND IS SO STATED. SINCE CONDITIONS OF ACTUAL
PRODUCT USE ARE BEYOND CONTROL OF THE SUPPLIER, IT IS ASSUMED THAT USERS OF
THIS MATERIAL HAVE BEEN FULLY TRAINED ACCORDING TO THE REQUIREMENTS OF ALL
APPLICABLE LEGISLATION AND REGULATORY INSTRUMENTS. NO WARRANTY, EXPRESSED
OR IMPLIED, IS MADE AND SUPPLIER WILL NOT BE LIABLE FOR ANY LOSSES,
INJURIES OR CONSEQUENTIAL DAMAGES WHICH MAY RESULT FROM THE USE OF OR
RELIANCE ON ANY INFORMATION CONTAINED IN THIS DOCUMENT.
ISSUE DATE: 27-JANUARY-2017
VERSION #: 01
EFFECTIVE DATE: 27-JANUARY-2017
PREPARED BY:
NU-CALGON TECHNICAL SERVICE PHONE: (314) 469-7000
OTHER INFORMATION:
FOR AN UPDATED SDS, PLEASE CONTACT THE SUPPLIER/MANUFACTURER LISTED IN THE
BEGINNING OF THIS DOCUMENT.
#27777
4182-35 (CANADA/US GHS)