| Common Name: | SMARTBOND SUBFLOOR CONSTRUCTION ADHESIVE FOAM |
| Manufacturer: | DAP |
| SDS Revision Date: | 6/19/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 411G61 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SDS NUMBER: 00010127004
REVISION DATE: 6/19/2015
DAP(R*)
SAFETY DATA SHEET
24 HOUR EMERGENCY PHONE NUMBERS MEDICAL/POISON CONTROL:
IN U.S.: CALL 1-800-222-1222
OUTSIDE U.S.: CALL YOUR LOCAL POISON CONTROL CENTER
TRANSPORTATION/NATIONAL RESPONSE CENTER:
1-800-535-5053
1-352-323-3500
NOTE:
THE NATIONAL RESPONSECENTER EMERGENCY NUMBERS TO BE USED ONLY IN THE
EVENT OF CHEMICAL EMERGENCIES INVOLVING A SPILL, LEAK, FIRE, EXPOSURE
OR ACCIDENT INVOLVING CHEMICALS.
IMPORTANT:
PROVIDE THIS INFORMATION TO EMPLOYEES, CUSTOMERS, AND USERS OF THIS
PRODUCT. READ THIS SDS BEFORE HANDLING OR DISPOSING OF THIS PRODUCT.
THIS PRODUCT IS COVERED BY THE OSHA HAZARD COMMUNICATION STANDARD AND
THIS DOCUMENT HAS BEEN PREPARED IN ACCORDANCE WITH REQUIREMENTS OF THIS
STANDARD. ALL ABBREVIATED TERMS USED IN THIS MSDS ARE FURTHER DESCRIBED
IN SECTION 16.
| 1. IDENTIFICATION |  |
THIS SAFETY DATA SHEET IS AVAILABLE IN AMERICAN SPANISH UPON REQUEST.
PRODUCT NAME: SMARTBOND SUBFLOOR CONSTRUCTION ADHESIVE FOAM
PRODUCT UPC NUMBER: 00036, 00042
PRODUCT USE/CLASS: FOAM ADHESIVE
REVISION DATE: 6/19/2015
SUPERCEDES DATE: NEW SDS
SDS NO: 00010127004
MANUFACTURER:
DAP PRODUCTS INC.
2400 BOSTON STREET SUITE 200
BALTIMORE, MD 21224-4723
888-327-8477 (NON - EMERGENCY MATTERS)
PREPARER: REGULATORY DEPARTMENT
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER!
EXTREMELY FLAMMABLE LIQUID AND VAPOR. VAPORS MAY CAUSE FLASH FIRE OR
EXPLOSION. VAPORS CAN FORM AN IGNITABLE MIXTURE WITH AIR. VAPORS CAN FLOW
ALONG SURFACES TO A DISTANT IGNITION SOURCE AND FLASH BACK. DO NOT SMOKE.
EXTINGUISH ALL FLAMES AND PILOT LIGHTS, AND TURN OFF STOVES, HEATERS,
ELECTRIC MOTORS AND OTHER SOURCES OF IGNITION DURING USE AND UNTIL ALL
VAPORS ARE GONE. KEEP CONTAINER CLOSED AND AWAY FROM HEAT, SPARKS, AND
OPEN FLAME. STORE AWAY FROM CAUSTICS AND OXIDIZERS. MAY CAUSE NAUSEA,
HEADACHES, AND DIZZINESS. MAY CAUSE EYE, SKIN, NOSE, THROAT AND
RESPIRATORY TRACT IRRITATION. USE ONLY WITH ADEQUATE VENTILATION. PREVENT
BUILD-UP OF VAPORS BY OPENING ALL WINDOWS AND DOORS TO ACHIEVE CROSS-
VENTILATION. MAY CAUSE SENSITIZATION BY INHALATION AND SKIN CONTACT.
CONTENTS UNDER PRESSURE. DO NOT PUNCTURE CAN. EXPOSURE TO TEMPERATURES
ABOVE 120 DEG. F MAY CAUSE CAN TO RUPTURE. THIS PRODUCT CONTAINS ETHYLENE
GLYCOL. THE PRIMARY ADVERSE HEALTH EFFECTS OF THIS PRODUCT ARE RELATED TO
THE POLYMERIC ISOCYANATE (MDI) COMPONENT. THEREFORE, ADEQUATE VENTILATION
SHOULD BE PROVIDED TO AVOID EXCEEDING THE EXPOSURE LIMITS OF THESE
COMPONENTS (SEE SECTION 8). THE LIKELIHOOD OF EXCEEDING THESE LIMITS ARE
LOW DUE TO THE LOW CONCENTRATION OF VAPOR PRODUCED DURING NORMAL USE.
HOWEVER, IF USED INDOORS, MECHANICAL VENTILATION OR EXHAUST SHOULD BE
PROVIDED DURING USE AND UNTIL PRODUCT IS CURED. THIS PRODUCT HAS STRONG
ADHESIVE-LIKE CHARACTERISTICS AND WILL ADHERE AGGRESSIVELY TO SKIN AND
OTHER SURFACES. IF ACCIDENTAL CONTACT OCCURS, FOLLOW THE APPROPRIATE
FIRST-AID PROCEDURE DESCRIBED IN SECTION 4 OF THIS MSDS. MDI VAPOR CAN
IRRITATE THE RESPIRATORY TRACT CAUSING RUNNY NOSE, SORE THROAT, COUGHING
AND REDUCE LUNG FUNCTION.
GHS CLASSIFICATION
ACUTE TOX. 4 INHALATION, CARC. 2, COMP. GAS, FL AER, 1, FLAM. GAS 1,
RESP. SENS. 1, SKIN SENS. 1
SYMBOL(S) OF PRODUCT:
FLAME
EXCLAMATION MARK
HEALTH HAZARD
GAS CYLINDER
SIGNAL WORD: DANGER
POSSIBLE HAZARDS:
22% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE TOXICITY
GHS HAZARD STATEMENTS:
FLAMMABLE GAS, CATEGORY 1:
H220: EXTREMELY FLAMMABLE GAS.
FLAMMABLE AEROSOL, CATEGORY 1:
H222: EXTREMELY FLAMMABLE AEROSOL.
COMPRESSED GAS:
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
SKIN SENSITIZER, CATEGORY 1:
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
ACUTE TOXICITY, INHALATION, CATEGORY 4:
H332: HARMFUL IF INHALED.
RESPIRATORY SENSITIZER, CATEGORY 1:
H334:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
CARCINOGENICITY, CATEGORY 2:
H351:
SUSPECTED OF CAUSING CANCER. CLASSIFIED AS CATEGORY 2 BASED ON LIMITED
EVIDENCE ON HUMAN AND/OR ANIMAL STUDIES. MIXTURES WITH CONCENTRATIONS OF
SUSPECTED CARCINOGENS INGREDIENTS AT CONCENTRATION PRESENT BETWEEN 0.1%
AND 1.0% LABELLING THE SDS WILL BE OPTIONAL DEPENDING ON AUTHORITIES. IF
CATEGORY 2 CARCINOGENIC PRESENT AT A CONCENTRATION OF 1% OR ABOVE
LABELLING THE SDS WILL BE EXPECTED. ROUTES OF EXPOSURE ARE DEPENDANT ON
INGREDIENT FORM.
GHS LABEL PRECAUTIONARY STATEMENTS:
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P210:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING.
P211: DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
P251: DO NOT PIERCE OR BURN, EVEN AFTER USE.
P261: AVOID BREATHING DUST/FUME/GAS/MIST/VAPOURS/SPRAY.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P281: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
P285: IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P304+P341:
IF INHALED:
IF BREATHING IS DIFFICULT, REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN
A POSITION COMFORTABLE FOR BREATHING.
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P312: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P333+P313:
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
P342+P311:
IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
P377: IF EYE IRRITATION PERSISTS
P381: ELIMINATE ALL IGNITION SOURCES IF SAFE TO DO SO.
P410+P403: PROTECT FROM SUNLIGHT. STORE IN A WELL-VENTILATED PLACE.
P410+P412:
PROTECT FROM SUNLIGHT. DO NO EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C/ 122 DEG. F.
GHS ADDITIONAL INFORMATION:
H371:
CONTAINS ONE OR MORE CATEGORY 2 SPECIFIC ORGAN TOXICANTS AT GREATER THAN
1.0%. A SAFETY DATA SHEET SHALL BE AVAILABLE FOR THE MIXTURE UPON REQUEST.
GHS SDS PRECAUTIONARY STATEMENTS:
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS-NO. WT. %
TRIS(2-CHLORO-1-METHYLETHYL) PHOSPHATE 13674-84-5 10-25
4,4'-METHYLENEDIPHENYL DIISOCYANATE (MDI) 101-68-8 2.5-10
ISOBUTANE 75-28-5 2.5-10
DIMETHYL ETHER 115-10-6 2.5-10
PROPANE 74-98-6 1.0-2.5
N-BUTANE 106-97-8 1.0-2.5
ETHYLENE GLYCOL 107-21-1 1.0-2.5
CHEMICAL NAME GHS SYMBOLS GHS STATEMENTS
TRIS(2-CHLORO-1-METHYLETHYL) PHOSPHATE GHS03-GHS06 H270-302-
312-331
4,4'-METHYLENEDIPHENYL DIISOCYANATE (MDI) GHS03-GHS06- H270-315-317-
GHS08 319-330-334-
335-351-373
ISOBUTANE GHS03-GHS07- H270-332-
GHS08 336-371
DIMETHYL ETHER GHS03 H270
PROPANE GHS03-GHS07 H270-332-336
N-BUTANE GHS03-GHS07 H270-332-336
ETHYLENE GLYCOL GHS03-GHS06 H270-331
THE TEXT FOR GHS HAZARD STATEMENTS SHOWN ABOVE (IF ANY) IS GIVEN IN THE
"OTHER INFORMATION" SECTION.
| 4. FIRST-AID MEASURES | |
FIRST AID - INHALATION:
IF YOU EXPERIENCE DIFFICULTY IN BREATHING, LEAVE THE AREA TO OBTAIN FRESH
AIR. IF CONTINUED DIFFICULTY IS EXPERIENCED, GET MEDICAL ATTENTION
IMMEDIATELY.
FIRST AID - SKIN CONTACT:
WASH SKIN WITH SOAP AND WATER FOR 15 MINUTES. GET MEDICAL AID IF SYMPTOMS
PERSIST. USE A RAG TO REMOVE EXCESS FOAM FROM SKIN AND REMOVE CONTAMINATED
CLOTHING. USE OF A SOLVENT, SUCH AS ACETONE (NAIL POLISH REMOVER) OR
MINERAL SPIRITS, MAY HELP IN REMOVING UNCURED FOAM RESIDUE FROM CLOTHING
OR OTHER SURFACES (AVOID EYE CONTACT). CURED FOAM MAY BE PHYSICALLY
REMOVED BY PERSISTENT WASHING WITH SOAP AND WATER. IF IRRITATION DEVELOPS,
USE MILD SKIN CREAM. IF IRRITATION PERSISTS, OBTAIN MEDICAL ATTENTION.
FIRST AID - EYE CONTACT:
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH LARGE QUANTITIES OF WATER
FOR AT LEAST 15 MINUTES UNTIL IRRITATION SUBSIDES. GET MEDICAL ATTENTION
IMMEDIATELY.
FIRST AID - INGESTION:
IF SWALLOWED, DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION IMMEDIATELY.
| 5. FIRE-FIGHTING MEASURES | |
UNUSUAL FIRE AND EXPLOSION HAZARDS:
CLOSED CONTAINERS MAY BURST IF EXPOSED TO EXTREME HEAT OR FIRE. CONTAINERS
MAY EXPLODE IF EXPOSED TO EXTREME HEAT. EMPTY CONTAINERS RETAIN PRODUCT
RESIDUE (LIQUID AND/OR VAPOR). VAPOR CAN IGNITE POTENTIALLY CAUSING AN
EXPLOSION.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND (NIOSH APPROVED OR
EQUIVALENT) AND FULL PROTECTIVE GEAR. USE WATER SPRAY TO COOL EXPOSED
SURFACES.
EXTINGUISHING MEDIA: ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER FOG
| 6. ACCIDENTAL RELEASE MEASURES | |
ENVIRONMENTAL MEASURES: NO INFORMATION
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
NOTE:
REVIEW FIRE HAZARDS BEFORE PROCEEDING WITH CLEAN UP. IMMEDIATELY ELIMINATE
SOURCES OF IGNITION. KEEP PEOPLE AWAY FROM AND UPWIND OF SPILL/LEAK.
CONTAIN SPILLED MATERIAL AND REMOVE WITH INERT ABSORBENT. DISPOSE OF
CONTAMINATED ABSORBENT, CONTAINER AND UNUSED CONTENTS IN ACCORDANCE WITH
LOCAL, STATE AND FEDERAL REGULATIONS. SCRAPE UP DRIED MATERIAL AND PLACE
INTO CONTAINERS. PREVENT PRODUCT FROM ENTERING DRAINS. SOAK UP WITH INERT
ABSORBENT MATERIAL AND DISPOSE OF AS HAZARDOUS WASTE. USE PERSONAL
PROTECTIVE EQUIPMENT AS NECESSARY. READ ALL PRODUCT INSTRUCTIONS BEFORE
USING. PERSONAL PROTECTIVE EQUIPMENT SHOULD INCLUDE IMPERVIOUS GLOVES,
PROTECTIVE EYE WEAR, AND SUITABLE WORK CLOTHES. UNCURED PRODUCT IS VERY
STICKY, SO CAREFULLY REMOVE THE BULK OF THE FOAM BY SCRAPING IT UP AND
THEN IMMEDIATELY REMOVE RESIDUE WITH A RAG AND SOLVENT SUCH AS
POLYURETHANE CLEANER, MINERAL SPIRITS, ACETONE (NAIL POLISH REMOVER),
PAINT THINNER, ETC. ONCE THE PRODUCT HAS CURED, IT CAN ONLY BE REMOVED
PHYSICALLY BY SCRAPING, BUFFING, ETC. DISPOSE AS PLASTIC WASTE (FOAM
PLASTIC) IN ACCORDANCE WITH ALL APPLICABLE GUIDELINES AND REGULATIONS.
| 7. HANDLING AND STORAGE | |
HANDLING:
KEEP OUT OF REACH OF CHILDREN!
DO NOT TAKE INTERNALLY. REMOVE ALL SOURCES OF IGNITION. MAKE SURE
NOZZLE IS DIRECTED AWAY FROM YOURSELF PRIOR TO DISCHARGE. KEEP AWAY
FROM OPEN FLAMES, HOT SURFACES AND SOURCES OF IGNITION. PROVIDE
ADEQUATE VENTILATION. AVOID HEAT, SPARKS AND OPEN FLAMES. WEAR
APPROPRIATE PERSONAL PROTECTION. AVOID BREATHING VAPOR AND CONTACT WITH
EYES, SKIN AND CLOTHING. USE ONLY WITH ADEQUATE VENTILATION. ENSURE
FRESH AIR ENTRY DURING APPLICATION AND DRYING. EMPTY CONTAINERS RETAIN
PRODUCT RESIDUE (LIQUID AND/OR VAPOR). VAPOR CAN IGNITE POTENTIALLY
CAUSING AN EXPLOSION. WASH THOROUGHLY AFTER HANDLING. CONTAINS
ISOCYANATES. SEE INFORMATION SUPPLIED BY THE MANUFACTURER. PERSONS
ALLERGIC TO ISOCYANATES, AND PARTICULARLY THOSE SUFFERING FROM ASTHMA
OR OTHER RESPIRATORY CONDITIONS, SHOULD NOT WORK WITH ISOCYANATES.
STORAGE:
STORE AWAY FROM SOURCES OF IGNITION AND HEAT. PROTECT MATERIAL FROM DIRECT
SUNLIGHT. KEEP CONTAINERS TIGHTLY CLOSED IN A DRY, COOL AND WELL-
VENTILATED PLACE. DO NOT STORE AT TEMPERATURES ABOVE 120 DEGREES F. STORE
CONTAINERS AWAY FROM EXCESSIVE HEAT AND FREEZING. STORE AWAY FROM CAUSTICS
AND OXIDIZERS.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
INGREDIENTS WITH OCCUPATIONAL EXPOSURE LIMITS:
CHEMICAL NAME ACGIH TLV-TWA ACGIH-TLV STEL
TRIS(2-CHLORO-1-METHYLETHYL) PHOSPHATE N.E. N.E.
4,4'-METHYLENEDIPHENYL DIISOCYANATE 0.005 PPM TWA N.E.
(MDI) METHYLENE
BISPHENYL
ISOCYANATE
(MDI)
DIMETHYL ETHER N.E. N.E.
ISOBUTANE N.E. 1000 PPM STEL
N-BUTANE N.E. 1000 PPM STEL
ETHYLENE GLYCOL N.E. N.E.
PROPANE 1000 PPM TWA N.E.
ALIPHATIC
HYDROCARBON
GASES:
ALKANE C1-4
CHEMICAL NAME OSHA PEL-TWA OSHA PEL-CEILING
TRIS(2-CHLORO-1-METHYLETHYL) PHOSPHATE N.E. N.E.
4,4'-METHYLENEDIPHENYL DIISOCYANATE N.E. 0.02 PPM CEILING,
(MDI) 0.2 MG/M3 CEILING
DIMETHYL ETHER N.E. N.E.
ISOBUTANE N.E. N.E.
N-BUTANE N.E. N.E.
ETHYLENE GLYCOL N.E. N.E.
PROPANE 1000 PPM TWA, N.E.
1800 MG/M3 TWA
FURTHER ADVICE:
MEL = MAXIMUM EXPOSURE LIMIT
OES = OCCUPATIONAL EXPOSURE STANDARD
SUP = SUPPLIER'S RECOMMENDATION
SK = SKIN SENSITIZER
N.E. = NOT ESTABLISHED
PERSONAL PROTECTION:
RESPIRATORY PROTECTION:
NO PERSONAL RESPIRATORY PROTECTIVE EQUIPMENT NORMALLY REQUIRED. IF
CONCENTRATIONS EXCEED THE EXPOSURE LIMITS SPECIFIED, USE OF A
NIOSH-APPROVED SUPPLIED AIR RESPIRATOR IS RECOMMENDED. WHERE THE
PROTECTION FACTOR IS EXCEEDED, USE OF A SELF CONTAINED BREATHING
APPARATUS (SCBA) MAY BE NECESSARY. A RESPIRATORY PROTECTION PROGRAM
THAT MEETS THE OSHA 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE
FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.
SKIN PROTECTION: WEAR SOLVENT IMPERVIOUS GLOVES.
EYE PROTECTION: GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS.
OTHER PROTECTIVE EQUIPMENT:
PROVIDE EYEWASH AND SOLVENT IMPERVIOUS APRON IF BODY CONTACT MAY OCCUR.
HYGIENIC PRACTICES:
WASH HANDS BEFORE BREAKS AND AT THE END OF WORKDAY. REMOVE AND WASH
CONTAMINATED CLOTHING BEFORE RE-USE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: TAN
PHYSICAL STATE: FOAM
ODOR: SOLVENT
ODOR THRESHOLD: NOT ESTABLISHED
DENSITY, G/CM3: 0.99 - 0.99
PH: NOT APPLICABLE
FREEZE POINT, DEG. C: NOT ESTABLISHED
VISCOSITY (MPA.S): NOT ESTABLISHED
SOLUBILITY IN WATER: NO INFORMATION
PARTITION COEFF., N-OCTANOL/WATER: NOT ESTABLISHED
DECOMPOSITION TEMPERATURE, DEG. C: NOT ESTABLISHED
EXPLOSIVE LIMITS, %: N.I. - N.I.
BOILING RANGE, DEG. C: N.I. - N.I.
AUTO-IGNITION TEMPERATURE, DEG. C: NOT ESTABLISHED
MINIMUM FLASH POINT, DEG. C: NO INFORMATION
VAPOR PRESSURE, MMHG: NO INFORMATION
EVAPORATION RATE: SLOWER THAN N-BUTYL ACETATE
FLASH METHOD: NOT APPLICABLE
VAPOR DENSITY: HEAVIER THAN AIR
FLAMMABILITY: NO INFORMATION
COMBUSTIBILITY: DOES NOT SUPPORT COMBUSTION
(SEE "OTHER INFORMATION" SECTION FOR ABBREVIATION LEGEND)
(IF PRODUCT IS AN AEROSOL, THE FLASH POINT STATED ABOVE IS THAT OF THE
PROPELLANT.)
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
CONDITIONS TO AVOID:
EXCESSIVE HEAT AND FREEZING. KEEP AWAY FROM OPEN FLAMES, HOT SURFACES AND
SOURCES OF IGNITION. KEEP AWAY FROM OXIDIZING AGENTS, STRONGLY ALKALINE
AND STRONGLY ACID MATERIALS IN ORDER TO AVOID EXOTHERMIC REACTIONS.
INCOMPATIBILITY:
OPEN FLAMES, HOT SURFACES AND SOURCES OF IGNITION. INCOMPATIBLE WITH
STRONG BASES AND OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
NORMAL DECOMPOSITION PRODUCTS, I.E., COX, NOX.
| 11. TOXICOLOGICAL INFORMATION | |
EFFECT OF OVEREXPOSURE - INHALATION:
VAPORS MAY BE IRRITATING TO EYES, NOSE, THROAT, AND LUNGS. INHALATION OF
HIGH CONCENTRATIONS MAY CAUSE HEADACHE, NAUSEA, AND DIZZINESS.
EFFECT OF OVEREXPOSURE - SKIN CONTACT:
MAY CAUSE SENSITIZATION BY SKIN CONTACT. MAY CAUSE LOCALIZED IRRITATION,
REDDENING OR SWELLING. PROLONGED OR REPEATED EXPOSURE MAY LEAD TO
SENSITIZATION AND/OR CONTACT DERMATITIS. THIS PRODUCT HAS STRONG ADHESIVE-
LIKE CHARACTERISTICS AND WILL ADHERE AGGRESSIVELY TO SKIN AND OTHER
SURFACES. IF ACCIDENTAL CONTACT OCCURS, FOLLOW THE APPROPRIATE FIRST-AID
PROCEDURE DESCRIBED IN SECTION 4 OF THIS MSDS.
EFFECT OF OVEREXPOSURE - EYE CONTACT:
DIRECT EYE CONTACT MAY CAUSE IRRITATION. MIST AND VAPORS MAY CAUSE EYE
IRRITATION. FOAM CONTACT CAN CAUSE PHYSICAL DAMAGE DUE TO ADHESIVE
CHARACTER.
EFFECT OF OVEREXPOSURE - INGESTION:
INGESTION MAY CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING AND
DIARRHEA.
CARCINOGENICITY: NO INFORMATION
EFFECT OF OVEREXPOSURE - CHRONIC HAZARDS:
ETHYLENE GLYCOL MAY CAUSE KIDNEY AND LIVER DAMAGE UPON PROLONGED AND
REPEATED OVEREXPOSURES. STUDIES HAVE SHOWN THAT REPEATED INHALATION OF
ETHYLENE GLYCOL HAS PRODUCED ADVERSE CARDIOVASCULAR CHANGES IN LABORATORY
ANIMALS. ETHYLENE GLYCOL HAS BEEN SHOWN TO CAUSE BIRTH DEFECTS IN
LABORATORY ANIMALS.
PRIMARY ROUTE(S) OF ENTRY:
EYE CONTACT, INGESTION, INHALATION, SKIN CONTACT
ACUTE TOXICITY VALUES:
THE ACUTE EFFECTS OF THIS PRODUCT HAVE NOT BEEN TESTED. DATA ON INDIVIDUAL
COMPONENTS ARE TABULATED BELOW:
CAS-NO. CHEMICAL NAME ORAL LD50 DERMAL LD50 VAPOR LC50
13674-84-5 TRIS(2-CHLORO-1- 500 MG/KG RAT 1230 MG/KG 5 MG/L RAT
METHYLETHYL) RABBIT
PHOSPHATE
101-68-8 4,4'-METHYLENEDI- 31600 MG/KG 9400 MG/KG N.I.
PHENYL DIISOCYANATE RAT RABBIT
(MDI)
75-28-5 ISOBUTANE N.I. N.I. 658 MG/L RAT
115-10-6 DIMETHYL ETHER >2000 MG/KG >2000 MG/KG 308.5 MG/L
RAT
74-98-6 PROPANE NOT AN N.I. 658 MG/L RAT
EXPOSURE
ROUTE
106-97-8 N-BUTANE NOT AN N.I. 658 MG/L RAT
EXPOSURE
ROUTE
107-21-1 ETHYLENE GLYCOL 4000 MG/KG 9530 MG/KG >2.5 MG/L
RAT RABBIT RAT
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NO INFORMATION
| 13. DISPOSAL INFORMATION | |
DISPOSAL INFORMATION:
RESIDUES AND SPILLED MATERIAL ARE HAZARDOUS WASTE DUE TO IGNITABILITY.
CONTENTS UNDER PRESSURE. DISPOSE OF MATERIAL IN ACCORDANCE WITH ALL
FEDERAL, STATE AND LOCAL REGULATIONS. STATE AND LOCAL REGULATIONS/
RESTRICTIONS ARE COMPLEX AND MAY DIFFER FROM FEDERAL REGULATIONS.
RESPONSIBILITY FOR PROPER WASTE DISPOSAL IS WITH THE OWNER OF THE WASTE.
LIQUIDS CANNOT BE DISPOSED OF IN A LANDFILL. DO NOT FLUSH INTO SURFACE
WATER OR SANITARY SEWER SYSTEM. DO NOT EMPTY INTO DRAINS. DO NOT RE-USE
EMPTY CONTAINERS. THE CONTAINER FOR THIS PRODUCT CAN PRESENT EXPLOSION OR
FIRE HAZARDS, EVEN WHEN EMPTIED. TO AVOID RISK OF INJURY, DO NOT CUT,
PUNCTURE, OR WELD ON OR NEAR THIS CONTAINER. BEFORE DISPOSING OF
CONTAINERS, RELIEVE CONTAINER OF ANY REMAINING PRODUCT AND PRESSURE.
EMPTY CYLINDERS, ONCE RELIEVED OF ALL PRESSURE, CAN BE DISPOSED OF AS
NON-HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
SPECIAL TRANSPORT PRECAUTIONS: NO INFORMATION
DOT UN/NA NUMBER: UN1950
DOT PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE
DOT TECHNICAL NAME: N.A.
DOT HAZARD CLASS: 2.1
HAZARD SUBCLASS: N.A.
PACKING GROUP: N.A.
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA 'HAZARD CATEGORIES'
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
FIRE HAZARD, PRESSURE HAZARD, ACUTE HEALTH HAZARD, CHRONIC HEALTH HAZARD
SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
CHEMICAL NAME CAS-NO.
POLYMERIC DIPHENYLMETHANE DIISOCYANATE 9016-87-9
4,4'-METHYLENEDIPHENYL DIISOCYANATE (MDI) 101-68-8
ETHYLENE GLYCOL 107-21-1
TOXIC SUBSTANCES CONTROL ACT:
ALL INGREDIENTS IN THIS PRODUCT ARE EITHER ON TSCA INVENTORY LIST, OR
OTHERWISE EXEMPT.
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT TO THE
REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE UNITED STATES:
NO TSCA 12(B) COMPONENTS EXIST IN THIS PRODUCT.
CALIFORNIA PROPOSITION 65 CARCINOGENS AND REPORODUCTIVE TOXINS:
CALIFORNIA PROPOSITION 65: NO INFORMATION
INTERNATIONAL REGULATIONS: AS FOLLOWS
CANADIAN WHMIS:
THIS SDS HAS BEEN PREPARED IN COMPLIANCE WITH CONTROLLED PRODUCT
REGULATIONS EXCEPT FOR THE USE OF THE 16 HEADINGS.
WHMIS CLASS: NO INFORMATION
| 16. OTHER INFORMATION | |
REVISION DATE: 6/19/2015
SUPERSEDES DATE: NEW MSDS
REASON FOR REVISION: HAZCOM2012/GHS CONVERSION
DATASHEET PRODUCED BY: REGULATORY DEPARTMENT
HMIS RATINGS:
HEALTH 2
FLAMMABILITY 4
REACTIVITY 0
PERSONAL PROTECTION X
VOC LESS WATER LESS EXEMPT SOLVENT, G/L: 148.0
VOC MATERIAL, G/L: 148
VOC AS DEFINED BY CALIFORNIA CONSUMER PRODUCT REGULATION, WT/WT%: 9.0
TEXT FOR GHS HAZARD STATEMENTS SHOWN IN SECTION 3 DESCRIBING EACH
INGREDIENT:
H270: MAY CAUSE OR INTENSIFY FIRE; OXIDISER.
H302: HARMFUL IF SWALLOWED.
H312: HARMFUL IN CONTACT WITH SKIN.
H315: CAUSES SKIN IRRITATION.
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H319: CAUSES SERIOUS EYE IRRITATION.
H330: FATAL IF INHALED.
H331: TOXIC IF INHALED.
H332: HARMFUL IF INHALED.
H334:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
H335: MAY CAUSE RESPIRATORY IRRITATION.
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
H351:
SUSPECTED OF CAUSING CANCER. CLASSIFIED AS CATEGORY 2 BASED ON LIMITED
EVIDENCE ON HUMAN AND/OR ANIMAL STUDIES. MIXTURES WITH CONCENTRATIONS OF
SUSPECTED CARCINOGENS INGREDIENTS AT CONCENTRATION PRESENT BETWEEN 0.1%
AND 1.0% LABELLING THE SDS WILL BE OPTIONAL DEPENDING ON AUTHORITIES. IF
CATEGORY 2 CARCINOGENIC PRESENT AT A CONCENTRATION OF 1% OR ABOVE
LABELLING THE SDS WILL BE EXPECTED. ROUTES OF EXPOSURE ARE DEPENDANT ON
INGREDIENT FORM.
H371:
MAY CAUSE DAMAGE TO ORGANS. CLASSIFIED CATEGORY 2 EVIDENCE FROM ANIMAL
STUDIES SUGGEST HARMFUL. CELL DEATH, ADVERSE CHANGE IN BIOCHEMISTRY,
HAEMATOLOGY OR URINALYSIS PARAMETERS, CENTRAL OR PERIPHERAL NERVOUS
SYSTEM AND EFFECTS SENSES. MULTIFOCAL OR DIFFUSE NECROSIS, FIBROSIS OR
GRANULOMA FORMATION IN ORGANS.
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
ICONS FOR GHS PICTOGRAMS SHOWN IN SECTION 3 DESCRIBING EACH INGREDIENT:
GHS03: FLAME OVER CIRCLE
GHS06: SKULLS AND CROSSBONES
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
LEGEND:
N.A.: NOT APPLICABLE
N.E.: NOT ESTABLISHED
N.D.: NOT DETERMINED
DAP BELIEVES THE DATA AND STATEMENTS CONTAINED HEREIN ARE ACCURATE AS OF
THE DATE HEREOF. THEY ARE OFFERED IN GOOD FAITH AS TYPICAL VALUES AND NOT
AS A PRODUCT SPECIFICATION. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF
FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR
IMPLIED, IS MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE
PRODUCT TO WHICH THE INFORMATION REFERS. SINCE THISDOCUMENT IS INTENDED
ONLY AS A GUIDE TO THE APPROPRIATE USE AND PRECAUTIONARY HANDLING OF THE
REFERENCED PRODUCT BY A PROPERLY TRAINED PERSON, IT IS THEREFORE THE
RESPONSIBILITY OF THE USER TO (I) REVIEW THE RECOMMENDATIONS WITH DUE
CONSIDERATION FOR THE SPECIFIC CONTEXT OF THE INTENDED USE AND (II)
DETERMINE IF THEY ARE APPROPRIATE.