| Common Name: | 1437 INDUSTRIAL SEALANT AND ADHESIVE CLEAR |
| Manufacturer: | DOW CORNING |
| SDS Revision Date: | 4/24/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 411M19 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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XIAMETER(R*)
FROM DOW CORNING
SAFETY DATA SHEET
DOW CORNING(R) 1437 INDUSTRIAL SEALANT AND ADHESIVE CLEAR
VERSION: 6.0
REVISION DATE: 04/24/2017
SDS NUMBER: 644437-00008
DATE OF LAST ISSUE: 10/28/2016
DATE OF FIRST ISSUE: 10/17/2014
| SECTION 1. IDENTIFICATION |  |
PRODUCT NAME: DOW CORNING(R) 1437 INDUSTRIAL SEALANT AND ADHESIVE CLEAR
PRODUCT CODE: 000000000004099409
MANUFACTURER OR SUPPLIER'S DETAILS:
COMPANY NAME OF SUPPLIER: DOW CORNING CORPORATION
ADDRESS:
SOUTH SAGINAW ROAD
MIDLAND MICHIGAN 48686
TELEPHONE: (989) 496-6000
EMERGENCY TELEPHONE:
24 HOUR EMERGENCY TELEPHONE: (989) 496-5900
CHEMTREC: (800) 424-9300
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: ADHESIVE, BINDING AGENTS
| SECTION 2. HAZARDS IDENTIFICATION | |
GHS CLASSIFICATION IN ACCORDANCE WITH 29 CFR 1910.1200:
EYE IRRITATION: CATEGORY 2A
SKIN SENSITIZATION: CATEGORY 1
REPRODUCTIVE TOXICITY: CATEGORY 2
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY - REPEATED EXPOSURE (ORAL):
CATEGORY 2 (BLOOD)
GHS LABEL ELEMENTS:
| HAZARD PICTOGRAMS:
| HEALTH HAZARD
| EXCLAMATION MARK
| SIGNAL WORD: WARNING
| HAZARD STATEMENTS:
| H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
| H319: CAUSES SERIOUS EYE IRRITATION.
| H361FD:
| SUSPECTED OF DAMAGING FERTILITY. SUSPECTED OF DAMAGING THE UNBORN CHILD.
| H373:
| MAY CAUSE DAMAGE TO ORGANS (BLOOD) THROUGH PROLONGED OR REPEATED EXPOSURE
| IF SWALLOWED.
| PRECAUTIONARY STATEMENTS:
| PREVENTION:
| P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
| P202:
| DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
| P260: DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
| P264: WASH SKIN THOROUGHLY AFTER HANDLING.
| P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
| P272:
| CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
| P280:
| WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE
| PROTECTION.
| RESPONSE:
| P302 + P352:
| IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
| P305 + P351 + P338:
| IF IN EYES:
| RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
| IF PRESENT AND EASY TO DO. CONTINUE RINSING.
| P308 + P313:
| IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
| P333 + P313:
| IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
| P337 + P313:
| IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
| P363: WASH CONTAMINATED CLOTHING BEFORE REUSE.
| STORAGE:
| P405 STORE LOCKED UP.
| DISPOSAL:
| P501: DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.
OTHER HAZARDS: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE / MIXTURE: MIXTURE
CHEMICAL NATURE: SILICONE ELASTOMER
HAZARDOUS INGREDIENTS:
CHEMICAL NAME CAS-NO. CONCENTRATION
(% W/W)
SILICON DIOXIDE 7631-86-9 >=8 - <=10
METHYLTRI(ETHYLMETHYLKETOXIME)SILANE 22984-54-9 >=3 - <=6
VINYLTRI (METHYLETHYLKETOXIME) SILANE 2224-33-1 >=1 - <=2
N-(3-(TRIMETHOXYSILYL)PROPYL) 1760-24-3 >=0.9 - <=1.3
ETHYLENEDIAMINE
OCTAMETHYLCYCLOTETRASILOXANE 556-67-2 >=0.38 - <=0.4
METHYLTRI(ETHYLMETHYLKETOXIME)SILANE NOT ASSIGNED >=0.27 - <=0.55
ISOMERS AND OLIGOMERS
DIMETHYLBIS[(1-OXONEODECYL)OXY]STANNANE 68928-76-7 >=0.15 - <=0.25
| SECTION 4. FIRST AID MEASURES | |
GENERAL ADVICE:
IN THE CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE
IMMEDIATELY.
WHEN SYMPTOMS PERSIST OR IN ALL CASES OF DOUBT SEEK MEDICAL ADVICE.
IF INHALED:
IF INHALED, REMOVE TO FRESH AIR.
GET MEDICAL ATTENTION.
IN CASE OF SKIN CONTACT:
IN CASE OF CONTACT, IMMEDIATELY FLUSH SKIN WITH SOAP AND PLENTY OF WATER.
REMOVE CONTAMINATED CLOTHING AND SHOES.
GET MEDICAL ATTENTION.
WASH CLOTHING BEFORE REUSE.
THOROUGHLY CLEAN SHOES BEFORE REUSE.
IN CASE OF EYE CONTACT:
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES.
IF EASY TO DO, REMOVE CONTACT LENS, IF WORN.
GET MEDICAL ATTENTION.
IF SWALLOWED:
IF SWALLOWED, DO NOT INDUCE VOMITING.
GET MEDICAL ATTENTION.
RINSE MOUTH THOROUGHLY WITH WATER.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
SUSPECTED OF DAMAGING FERTILITY. SUSPECTED OF DAMAGING THE UNBORN CHILD.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED
EXPOSURE IF SWALLOWED.
PROTECTION OF FIRST-AIDERS:
FIRST AID RESPONDERS SHOULD PAY ATTENTION TO SELF-PROTECTION, AND USE THE
RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT WHEN THE POTENTIAL FOR EXPOSURE
EXISTS.
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY AND SUPPORTIVELY.
| SECTION 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER SPRAY
ALCOHOL-RESISTANT FOAM
CARBON DIOXIDE (CO2)
DRY CHEMICAL
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS DURING FIRE FIGHTING:
EXPOSURE TO COMBUSTION PRODUCTS MAY BE A HAZARD TO HEALTH.
HAZARDOUS COMBUSTION PRODUCTS:
CARBON OXIDES
SILICON OXIDES
FORMALDEHYDE
NITROGEN OXIDES (NOX)
SPECIFIC EXTINGUISHING METHODS:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT.
USE WATER SPRAY TO COOL UNOPENED CONTAINERS.
REMOVE UNDAMAGED CONTAINERS FROM FIRE AREA IF IT IS SAFE TO DO SO.
EVACUATE AREA.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
IN THE EVENT OF FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS.
USE PERSONAL PROTECTIVE EQUIPMENT.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE PERSONAL PROTECTIVE EQUIPMENT.
FOLLOW SAFE HANDLING ADVICE AND PERSONAL PROTECTIVE EQUIPMENT
RECOMMENDATIONS.
ENVIRONMENTAL PRECAUTIONS:
DISCHARGE INTO THE ENVIRONMENT MUST BE AVOIDED.
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
RETAIN AND DISPOSE OF CONTAMINATED WASH WATER.
LOCAL AUTHORITIES SHOULD BE ADVISED IF SIGNIFICANT SPILLAGES CANNOT BE
CONTAINED.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SOAK UP WITH INERT ABSORBENT MATERIAL.
FOR LARGE SPILLS, PROVIDE DIKING OR OTHER APPROPRIATE CONTAINMENT TO KEEP
MATERIAL FROM SPREADING. IF DIKED MATERIAL CAN BE PUMPED, STORE RECOVERED
MATERIAL IN APPROPRIATE CONTAINER.
CLEAN UP REMAINING MATERIALS FROM SPILL WITH SUITABLE ABSORBENT.
LOCAL OR NATIONAL REGULATIONS MAY APPLY TO RELEASES AND DISPOSAL OF THIS
MATERIAL, AS WELL AS THOSE MATERIALS AND ITEMS EMPLOYED IN THE CLEANUP OF
RELEASES. YOU WILL NEED TO DETERMINE WHICH REGULATIONS ARE APPLICABLE.
SECTIONS 13 AND 15 OF THIS SDS PROVIDE INFORMATION REGARDING CERTAIN LOCAL
OR NATIONAL REQUIREMENTS.
| SECTION 7. HANDLING AND STORAGE | |
TECHNICAL MEASURES:
SEE ENGINEERING MEASURES UNDER EXPOSURE CONTROLS/PERSONAL PROTECTION
SECTION.
LOCAL/TOTAL VENTILATION: USE ONLY WITH ADEQUATE VENTILATION.
ADVICE ON SAFE HANDLING:
DO NOT GET ON SKIN OR CLOTHING.
DO NOT SWALLOW.
DO NOT GET IN EYES.
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
KEEP AWAY FROM WATER.
PROTECT FROM MOISTURE.
TAKE CARE TO PREVENT SPILLS, WASTE AND MINIMIZE RELEASE TO THE ENVIRONMENT.
CONDITIONS FOR SAFE STORAGE:
KEEP IN PROPERLY LABELED CONTAINERS.
STORE IN ACCORDANCE WITH THE PARTICULAR NATIONAL REGULATIONS.
MATERIALS TO AVOID:
DO NOT STORE WITH THE FOLLOWING PRODUCT TYPES: STRONG OXIDIZING AGENTS
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
INGREDIENTS WITH WORKPLACE CONTROL PARAMETERS:
INGREDIENTS CAS-NO. VALUE TYPE CONTROL PARAMETERS BASIS
(FORM OF / PERMISSIBLE
EXPOSURE) CONCENTRATION
| SILICON DIOXIDE 7631-86-9 TWA (DUST) 20 MILLION OSHA Z-3
| PARTICLES PER
| CUBIC FOOT
| (SILICA)
| TWA (DUST) 80 MG/M3 / %SiO2 OSHA Z-3
| (SILICA)
| TWA 6 MG/M3 (SILICA) NIOSH REL
| OCTAMETHYLCYCLO- 556-67-2 TWA 10 PPM US WEEL
| TETRASILOXANE
| DIMETHYLBIS[(1- 68928-76-7 TWA 0.1 MG/M3 (TIN) OSHA Z-1
| OXONEODECYL)
| OXY]STANNANE TWA 0.1 MG/M3 (TIN) ACGIH
| STEL 0.2 MG/M3 (TIN) ACGIH
| TWA 0.1 MG/M3 (TIN) NIOSH REL
HAZARDOUS COMPONENTS WITHOUT WORKPLACE CONTROL PARAMETERS:
INGREDIENTS CAS-NO.
METHYL-TRI(ETHYLMETHYLKETOXIME)SILANE 22984-54-9
VINYLTRI (METHYLETHYLKETOXIME) SILANE 2224-33-1
N-(3-(TRIMETHOXYSILYL)PROPYL)ETHYLENEDIAMINE 1760-24-3
METHYL-TRI(ETHYLMETHYLKETOXIME)SILANE NOT ASSIGNED
ISOMERS AND OLIGOMERS
THESE SUBSTANCE(S) ARE INEXTRICABLY BOUND IN THE PRODUCT AND THEREFORE DO
NOT CONTRIBUTE TO A DUST INHALATION HAZARD.
SILICON DIOXIDE
OCCUPATIONAL EXPOSURE LIMITS OF DECOMPOSITION PRODUCTS:
INGREDIENTS CAS-NO. VALUE TYPE CONTROL PARAMETERS BASIS
(FORM OF / PERMISSIBLE
EXPOSURE) CONCENTRATION
ETHYL METHYL KETOXIME 96-29-7 TWA 10 PPM US WEEL
METHANOL 67-56-1 TWA 200 PPM ACGIH
STEL 250 PPM ACGIH
TWA 200 PPM NIOSH REL
260 MG/M3
ST 250 PPM NIOSH REL
325 MG/M3
TWA 200 PPM OSHA Z-1
260 MG/M3
ENGINEERING MEASURES:
PROCESSING MAY FORM HAZARDOUS COMPOUNDS (SEE SECTION 10).
ENSURE ADEQUATE VENTILATION, ESPECIALLY IN CONFINED AREAS.
MINIMIZE WORKPLACE EXPOSURE CONCENTRATIONS.
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION:
GENERAL AND LOCAL EXHAUST VENTILATION IS RECOMMENDED TO MAINTAIN VAPOR
EXPOSURES BELOW RECOMMENDED LIMITS. WHERE CONCENTRATIONS ARE ABOVE
RECOMMENDED LIMITS OR ARE UNKNOWN, APPROPRIATE RESPIRATORY PROTECTION
SHOULD BE WORN. FOLLOW OSHA RESPIRATOR REGULATIONS (29 CFR 1910.134) AND
USE NIOSH/MSHA APPROVED RESPIRATORS. PROTECTION PROVIDED BY AIR PURIFYING
RESPIRATORS AGAINST EXPOSURE TO ANY HAZARDOUS CHEMICAL IS LIMITED. USE A
POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR IF THERE IS ANY POTENTIAL FOR
UNCONTROLLED RELEASE, EXPOSURE LEVELS ARE UNKNOWN, OR ANY OTHER
CIRCUMSTANCE WHERE AIR PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE
PROTECTION.
HAND PROTECTION:
MATERIAL: CHEMICAL-RESISTANT GLOVES
REMARKS:
CHOOSE GLOVES TO PROTECT HANDS AGAINST CHEMICALS DEPENDING ON THE
CONCENTRATION SPECIFIC TO PLACE OF WORK. BREAKTHROUGH TIME IS NOT
DETERMINED FOR THE PRODUCT. CHANGE GLOVES OFTEN! FOR SPECIAL APPLICATIONS,
WE RECOMMEND CLARIFYING THE RESISTANCE TO CHEMICALS OF THE AFOREMENTIONED
PROTECTIVE GLOVES WITH THE GLOVE MANUFACTURER. WASH HANDS BEFORE BREAKS AND
AT THE END OF WORKDAY.
EYE PROTECTION:
WEAR THE FOLLOWING PERSONAL PROTECTIVE EQUIPMENT: SAFETY GOGGLES
SKIN AND BODY PROTECTION:
SELECT APPROPRIATE PROTECTIVE CLOTHING BASED ON CHEMICAL RESISTANCE DATA
AND AN ASSESSMENT OF THE LOCAL EXPOSURE POTENTIAL.
SKIN CONTACT MUST BE AVOIDED BY USING IMPERVIOUS PROTECTIVE CLOTHING
(GLOVES, APRONS, BOOTS, ETC).
HYGIENE MEASURES:
ENSURE THAT EYE FLUSHING SYSTEMS AND SAFETY SHOWERS ARE LOCATED CLOSE TO
THE WORKING PLACE.
WHEN USING DO NOT EAT, DRINK OR SMOKE.
WASH CONTAMINATED CLOTHING BEFORE RE-USE.
THESE PRECAUTIONS ARE FOR ROOM TEMPERATURE HANDLING. USE AT ELEVATED
TEMPERATURE OR AEROSOL/SPRAY APPLICATIONS MAY REQUIRE ADDED PRECAUTIONS.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: PASTE
COLOR: COLORLESS TO PALE YELLOW
ODOR: SLIGHT
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT/FREEZING POINT: NO DATA AVAILABLE
INITIAL BOILING POINT AND BOILING RANGE: NOT APPLICABLE
FLASH POINT: NOT APPLICABLE
EVAPORATION RATE: NOT APPLICABLE
FLAMMABILITY (SOLID, GAS): NOT CLASSIFIED AS A FLAMMABILITY HAZARD
SELF-IGNITION:
THE SUBSTANCE OR MIXTURE IS NOT CLASSIFIED AS PYROPHORIC. THE SUBSTANCE OR
MIXTURE IS NOT CLASSIFIED AS SELF HEATING.
UPPER EXPLOSION LIMIT / UPPER FLAMMABILITY LIMIT: NO DATA AVAILABLE
LOWER EXPLOSION LIMIT / LOWER FLAMMABILITY LIMIT: NO DATA AVAILABLE
VAPOR PRESSURE: NOT APPLICABLE
RELATIVE VAPOR DENSITY: NO DATA AVAILABLE
RELATIVE DENSITY: 1.04
SOLUBILITY(IES):
WATER SOLUBILITY: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY:
VISCOSITY, DYNAMIC: NOT APPLICABLE
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE
OXIDIZING PROPERTIES:
THE SUBSTANCE OR MIXTURE IS NOT CLASSIFIED AS OXIDIZING.
MOLECULAR WEIGHT: NO DATA AVAILABLE
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY: NOT CLASSIFIED AS A REACTIVITY HAZARD.
CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
| POSSIBILITY OF HAZARDOUS REACTIONS:
| USE AT ELEVATED TEMPERATURES MAY FORM HIGHLY HAZARDOUS COMPOUNDS.
| CAN REACT WITH STRONG OXIDIZING AGENTS.
| METHYL ETHYL KETOXIME (MEKO) IS FORMED UPON CONTACT WITH WATER OR HUMID
| AIR.
| HAZARDOUS DECOMPOSITION PRODUCTS WILL BE FORMED UPON CONTACT WITH WATER
| OR HUMID AIR.
| HAZARDOUS DECOMPOSITION PRODUCTS WILL BE FORMED AT ELEVATED TEMPERATURES.
CONDITIONS TO AVOID: EXPOSURE TO MOISTURE.
INCOMPATIBLE MATERIALS:
OXIDIZING AGENTS
WATER
HAZARDOUS DECOMPOSITION PRODUCTS:
CONTACT WITH WATER OR HUMID AIR:
ETHYL METHYL KETOXIME
METHANOL
THERMAL DECOMPOSITION: FORMALDEHYDE
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
SKIN CONTACT
INGESTION
EYE CONTACT
ACUTE TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
PRODUCT:
ACUTE ORAL TOXICITY:
ACUTE TOXICITY ESTIMATE: >5,000 MG/KG
METHOD: CALCULATION METHOD
ACUTE INHALATION TOXICITY:
ACUTE TOXICITY ESTIMATE: 134.26 MG/L
EXPOSURE TIME: 4 H
TEST ATMOSPHERE: DUST/MIST
METHOD: CALCULATION METHOD
INGREDIENTS:
SILICON DIOXIDE:
| ACUTE ORAL TOXICITY:
| LD50 (RAT): >3,300 MG/KG
| ASSESSMENT: THE SUBSTANCE OR MIXTURE HAS NO ACUTE ORAL TOXICITY
| REMARKS: INFORMATION TAKEN FROM REFERENCE WORKS AND THE LITERATURE.
| ACUTE INHALATION TOXICITY:
| LC50 (RAT): >2.08 MG/L
| EXPOSURE TIME: 4 H
| TEST ATMOSPHERE: DUST/MIST
| ASSESSMENT: THE SUBSTANCE OR MIXTURE HAS NO ACUTE INHALATION TOXICITY
| REMARKS: INFORMATION TAKEN FROM REFERENCE WORKS AND THE LITERATURE.
| ACUTE DERMAL TOXICITY:
| LD50 (RABBIT): >5,000 MG/KG
| ASSESSMENT: THE SUBSTANCE OR MIXTURE HAS NO ACUTE DERMAL TOXICITY
| REMARKS: INFORMATION TAKEN FROM REFERENCE WORKS AND THE LITERATURE.
METHYLTRI(ETHYLMETHYLKETOXIME)SILANE:
| ACUTE ORAL TOXICITY:
| LD50 (RAT): >2,520 MG/KG
| ASSESSMENT: THE SUBSTANCE OR MIXTURE HAS NO ACUTE ORAL TOXICITY
| REMARKS: ON BASIS OF TEST DATA.
VINYLTRI (METHYLETHYLKETOXIME) SILANE:
| ACUTE ORAL TOXICITY:
| LD50 (RAT): >2,000 MG/KG
| ASSESSMENT: THE SUBSTANCE OR MIXTURE HAS NO ACUTE ORAL TOXICITY
| REMARKS: ON BASIS OF TEST DATA.
| ACUTE DERMAL TOXICITY:
| LD50 (RAT): >2,000 MG/KG
| ASSESSMENT: THE SUBSTANCE OR MIXTURE HAS NO ACUTE DERMAL TOXICITY
| REMARKS: ON BASIS OF TEST DATA.
N-(3-(TRIMETHOXYSILYL)PROPYL)ETHYLENEDIAMINE:
| ACUTE ORAL TOXICITY:
| LD50 (RAT): 2,295 MG/KG
| REMARKS: ON BASIS OF TEST DATA.
| ACUTE INHALATION TOXICITY:
| LC50 (RAT): >1.49 MG/L
| EXPOSURE TIME: 4 H
| TEST ATMOSPHERE: DUST/MIST
| REMARKS: ON BASIS OF TEST DATA.
| ACUTE DERMAL TOXICITY:
| LD50 (RABBIT): >2,000 MG/KG
| ASSESSMENT: THE SUBSTANCE OR MIXTURE HAS NO ACUTE DERMAL TOXICITY
| REMARKS: ON BASIS OF TEST DATA.
OCTAMETHYLCYCLOTETRASILOXANE:
| ACUTE ORAL TOXICITY:
| LD50 (RAT): >4,800 MG/KG
| ASSESSMENT: THE SUBSTANCE OR MIXTURE HAS NO ACUTE ORAL TOXICITY
| REMARKS: ON BASIS OF TEST DATA.
| ACUTE INHALATION TOXICITY:
| LC50 (RAT): 2975 PPM
| EXPOSURE TIME: 4 H
| TEST ATMOSPHERE: VAPOR
| ASSESSMENT: THE SUBSTANCE OR MIXTURE HAS NO ACUTE INHALATION TOXICITY
| REMARKS: ON BASIS OF TEST DATA.
| ACUTE DERMAL TOXICITY:
| LD50 (RABBIT): >2.5 ML/KG
| ASSESSMENT: THE SUBSTANCE OR MIXTURE HAS NO ACUTE DERMAL TOXICITY
| REMARKS: ON BASIS OF TEST DATA.
DIMETHYLBIS[(1-OXONEODECYL)OXY]STANNANE:
| ACUTE ORAL TOXICITY:
| LD50 (RAT): 894 MG/KG
| METHOD: OECD TEST GUIDELINE 401
| ACUTE DERMAL TOXICITY:
| LD50 (RAT): >2,000 MG/KG
| METHOD: OECD TEST GUIDELINE 402
| ASSESSMENT: THE SUBSTANCE OR MIXTURE HAS NO ACUTE DERMAL TOXICITY
SKIN CORROSION/IRRITATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
INGREDIENTS:
SILICON DIOXIDE:
| RESULT: NO SKIN IRRITATION
| REMARKS: INFORMATION TAKEN FROM REFERENCE WORKS AND THE LITERATURE.
METHYLTRI(ETHYLMETHYLKETOXIME)SILANE:
| SPECIES: RABBIT
| RESULT: NO SKIN IRRITATION
| REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
N-(3-(TRIMETHOXYSILYL)PROPYL)ETHYLENEDIAMINE:
| SPECIES: RABBIT
| RESULT: MILD SKIN IRRITATION
| REMARKS: ON BASIS OF TEST DATA.
OCTAMETHYLCYCLOTETRASILOXANE:
| SPECIES: RABBIT
| RESULT: NO SKIN IRRITATION
| REMARKS: ON BASIS OF TEST DATA.
DIMETHYLBIS[(1-OXONEODECYL)OXY]STANNANE:
| SPECIES: RABBIT
| METHOD: OECD TEST GUIDELINE 404
| RESULT: NO SKIN IRRITATION
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
INGREDIENTS:
SILICON DIOXIDE:
| RESULT: NO EYE IRRITATION
| REMARKS: INFORMATION TAKEN FROM REFERENCE WORKS AND THE LITERATURE.
METHYLTRI(ETHYLMETHYLKETOXIME)SILANE:
| SPECIES: RABBIT
| RESULT: IRRITATION TO EYES, REVERSING WITHIN 7 DAYS
| REMARKS: ON BASIS OF TEST DATA.
VINYLTRI (METHYLETHYLKETOXIME) SILANE:
| SPECIES: RABBIT
| RESULT: IRREVERSIBLE EFFECTS ON THE EYE
| REMARKS: ON BASIS OF TEST DATA.
N-(3-(TRIMETHOXYSILYL)PROPYL)ETHYLENEDIAMINE:
| SPECIES: RABBIT
| RESULT: IRREVERSIBLE EFFECTS ON THE EYE
| REMARKS: ON BASIS OF TEST DATA.
OCTAMETHYLCYCLOTETRASILOXANE:
| SPECIES: RABBIT
| RESULT: NO EYE IRRITATION
| REMARKS: ON BASIS OF TEST DATA.
METHYLTRI(ETHYLMETHYLKETOXIME)SILANE ISOMERS AND OLIGOMERS:
| SPECIES: RABBIT
| RESULT: IRRITATION TO EYES, REVERSING WITHIN 7 DAYS
| REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
DIMETHYLBIS[(1-OXONEODECYL)OXY]STANNANE:
| SPECIES: RABBIT
| RESULT: NO EYE IRRITATION
| METHOD: OECD TEST GUIDELINE 405
RESPIRATORY OR SKIN SENSITIZATION:
SKIN SENSITIZATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
RESPIRATORY SENSITIZATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
INGREDIENTS:
SILICON DIOXIDE:
| ASSESSMENT: DOES NOT CAUSE SKIN SENSITIZATION.
| TEST TYPE:
| SKIN: TEST TYPE NOT SPECIFIED
| SPECIES: GUINEA PIG
| RESULT: NEGATIVE
| REMARKS: INFORMATION TAKEN FROM REFERENCE WORKS AND THE LITERATURE.
METHYLTRI(ETHYLMETHYLKETOXIME)SILANE:
| ASSESSMENT: PROBABILITY OR EVIDENCE OF SKIN SENSITIZATION IN HUMANS
| TEST TYPE: MAXIMIZATION TEST
| SPECIES: GUINEA PIG
| REMARKS: ON BASIS OF TEST DATA.
VINYLTRI (METHYLETHYLKETOXIME) SILANE:
| ASSESSMENT: PROBABILITY OR EVIDENCE OF SKIN SENSITIZATION IN HUMANS
| TEST TYPE: MAXIMIZATION TEST
| SPECIES: GUINEA PIG
| REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
N-(3-(TRIMETHOXYSILYL)PROPYL)ETHYLENEDIAMINE:
| ASSESSMENT: PROBABILITY OR EVIDENCE OF SKIN SENSITIZATION IN HUMANS
| TEST TYPE: MAXIMIZATION TEST
| SPECIES: GUINEA PIG
| REMARKS: INFORMATION TAKEN FROM REFERENCE WORKS AND THE LITERATURE.
OCTAMETHYLCYCLOTETRASILOXANE:
| ASSESSMENT: DOES NOT CAUSE SKIN SENSITIZATION.
| TEST TYPE: MAXIMIZATION TEST
| SPECIES: GUINEA PIG
| RESULT: NEGATIVE
| REMARKS: ON BASIS OF TEST DATA.
METHYLTRI(ETHYLMETHYLKETOXIME)SILANE ISOMERS AND OLIGOMERS:
| ASSESSMENT: PROBABILITY OR EVIDENCE OF SKIN SENSITIZATION IN HUMANS
| TEST TYPE: MAXIMIZATION TEST
| SPECIES: GUINEA PIG
| REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
GERM CELL MUTAGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
INGREDIENTS:
SILICON DIOXIDE:
| GENOTOXICITY IN VITRO:
| RESULT: NEGATIVE
| REMARKS: INFORMATION TAKEN FROM REFERENCE WORKS AND THE LITERATURE.
| GENOTOXICITY IN VIVO:
| APPLICATION ROUTE: INGESTION
| RESULT: NEGATIVE
| REMARKS: INFORMATION TAKEN FROM REFERENCE WORKS AND THE LITERATURE.
| GERM CELL MUTAGENICITY - ASSESSMENT:
| ANIMAL TESTING DID NOT SHOW ANY MUTAGENIC EFFECTS.
METHYLTRI(ETHYLMETHYLKETOXIME)SILANE:
| GENOTOXICITY IN VITRO:
| TEST TYPE: MUTAGENICITY (IN VITRO MAMMALIAN CYTOGENETIC TEST)
| RESULT: NEGATIVE
| REMARKS: ON BASIS OF TEST DATA.
VINYLTRI (METHYLETHYLKETOXIME) SILANE:
| GENOTOXICITY IN VITRO:
| TEST TYPE: BACTERIAL REVERSE MUTATION ASSAY (AMES)
| RESULT: NEGATIVE
| REMARKS: ON BASIS OF TEST DATA.
| GENOTOXICITY IN VIVO:
| TEST TYPE: IN VIVO MICRONUCLEUS TEST
| SPECIES: MOUSE
| APPLICATION ROUTE: INTRAPERITONEAL INJECTION
| RESULT: NEGATIVE
| REMARKS: ON BASIS OF TEST DATA.
| GERM CELL MUTAGENICITY - ASSESSMENT:
| ANIMAL TESTING DID NOT SHOW ANY MUTAGENIC EFFECTS.
OCTAMETHYLCYCLOTETRASILOXANE:
| GENOTOXICITY IN VITRO:
| TEST TYPE: BACTERIAL REVERSE MUTATION ASSAY (AMES)
| RESULT: NEGATIVE
| REMARKS: ON BASIS OF TEST DATA.
| TEST TYPE: MUTAGENICITY (IN VITRO MAMMALIAN CYTOGENETIC TEST)
| RESULT: NEGATIVE
| REMARKS: ON BASIS OF TEST DATA.
| TEST TYPE: CHROMOSOME ABERRATION TEST IN VITRO
| RESULT: NEGATIVE
| REMARKS: ON BASIS OF TEST DATA.
| TEST TYPE: IN VITRO SISTER CHROMATID EXCHANGE ASSAY IN MAMMALIAN CELLS
| RESULT: NEGATIVE
| REMARKS: ON BASIS OF TEST DATA.
| TEST TYPE:
| DNA DAMAGE AND REPAIR, UNSCHEDULED DNA SYNTHESIS IN MAMMALIAN CELLS (IN
| VITRO)
| RESULT: NEGATIVE
| REMARKS: ON BASIS OF TEST DATA.
| GENOTOXICITY IN VIVO:
| TEST TYPE:
| MAMMALIAN ERYTHROCYTE MICRONUCLEUS TEST (IN VIVO CYTOGENETIC ASSAY)
| SPECIES: RAT
| APPLICATION ROUTE: INHALATION (VAPOR)
| RESULT: NEGATIVE
| REMARKS: ON BASIS OF TEST DATA.
| TEST TYPE: RODENT DOMINANT LETHAL TEST (GERM CELL) (IN VIVO)
| SPECIES: RAT
| APPLICATION ROUTE: INGESTION
| RESULT: NEGATIVE
| REMARKS: ON BASIS OF TEST DATA.
| GERM CELL MUTAGENICITY - ASSESSMENT:
| ANIMAL TESTING DID NOT SHOW ANY MUTAGENIC EFFECTS.
DIMETHYLBIS[(1-OXONEODECYL)OXY]STANNANE:
| GENOTOXICITY IN VITRO:
| TEST TYPE: BACTERIAL REVERSE MUTATION ASSAY (AMES)
| METHOD: OECD TEST GUIDELINE 471
| RESULT: NEGATIVE
CARCINOGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
IARC:
NO INGREDIENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS PROBABLE, POSSIBLE OR CONFIRMED HUMAN CARCINOGEN BY
IARC.
OSHA:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS ON OSHA'S LIST OF REGULATED CARCINOGENS.
NTP:
NO INGREDIENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
REPRODUCTIVE TOXICITY:
SUSPECTED OF DAMAGING FERTILITY. SUSPECTED OF DAMAGING THE UNBORN CHILD.
INGREDIENTS:
METHYLTRI(ETHYLMETHYLKETOXIME)SILANE:
| EFFECTS ON FERTILITY
| TEST TYPE:
| COMBINED REPEATED DOSE TOXICITY STUDY WITH THE REPRODUCTION/DEVELOPMENTAL
| TOXICITY SCREENING TEST
| SPECIES: RAT, MALE AND FEMALE
| APPLICATION ROUTE: INGESTION
| SYMPTOMS: NO EFFECTS ON FERTILITY.
| REMARKS: ON BASIS OF TEST DATA.
| EFFECTS ON FETAL DEVELOPMENT:
| TEST TYPE:
| COMBINED REPEATED DOSE TOXICITY STUDY WITH THE REPRODUCTION/DEVELOPMENTAL
| TOXICITY SCREENING TEST
| SPECIES: RAT, MALE AND FEMALE
| APPLICATION ROUTE: INGESTION
| SYMPTOMS: NO EFFECTS ON FETAL DEVELOPMENT.
| REMARKS: ON BASIS OF TEST DATA.
| REPRODUCTIVE TOXICITY - ASSESSMENT:
| NO EVIDENCE OF ADVERSE EFFECTS ON SEXUAL FUNCTION AND FERTILITY, OR ON
| DEVELOPMENT, BASED ON ANIMAL EXPERIMENTS.
N-(3-(TRIMETHOXYSILYL)PROPYL)ETHYLENEDIAMINE:
| EFFECTS ON FERTILITY:
| TEST TYPE:
| COMBINED REPEATED DOSE TOXICITY STUDY WITH THE REPRODUCTION/DEVELOPMENTAL
| TOXICITY SCREENING TEST
| APPLICATION ROUTE: INGESTION
| SYMPTOMS: NO EFFECTS ON FERTILITY.
| REMARKS: ON BASIS OF TEST DATA.
| EFFECTS ON FETAL DEVELOPMENT:
| TEST TYPE:
| COMBINED REPEATED DOSE TOXICITY STUDY WITH THE REPRODUCTION/DEVELOPMENTAL
| TOXICITY SCREENING TEST
| APPLICATION ROUTE: INGESTION
| SYMPTOMS: NO EFFECTS ON FETAL DEVELOPMENT.
| REMARKS: ON BASIS OF TEST DATA.
| REPRODUCTIVE TOXICITY - ASSESSMENT:
| NO EVIDENCE OF ADVERSE EFFECTS ON SEXUAL FUNCTION AND FERTILITY, OR ON
| DEVELOPMENT, BASED ON ANIMAL EXPERIMENTS.
OCTAMETHYLCYCLOTETRASILOXANE:
| EFFECTS ON FERTILITY:
| TEST TYPE: TWO-GENERATION REPRODUCTION TOXICITY STUDY
| SPECIES: RAT, MALE AND FEMALE
| APPLICATION ROUTE: INHALATION (VAPOR)
| SYMPTOMS: EFFECTS ON FERTILITY.
| REMARKS: ON BASIS OF TEST DATA.
| EFFECTS ON FETAL DEVELOPMENT:
| TEST TYPE: PRENATAL DEVELOPMENT TOXICITY STUDY (TERATOGENICITY)
| SPECIES: RABBIT
| APPLICATION ROUTE: INHALATION (VAPOR)
| SYMPTOMS: NO EFFECTS ON FETAL DEVELOPMENT.
| REMARKS: ON BASIS OF TEST DATA.
| REPRODUCTIVE TOXICITY - ASSESSMENT:
| SOME EVIDENCE OF ADVERSE EFFECTS ON SEXUAL FUNCTION AND FERTILITY, BASED
| ON ANIMAL EXPERIMENTS.
DIMETHYLBIS[(1-OXONEODECYL)OXY]STANNANE:
| REPRODUCTIVE TOXICITY - ASSESSMENT:
| SOME EVIDENCE OF ADVERSE EFFECTS ON DEVELOPMENT, BASED ON ANIMAL
| EXPERIMENTS.
STOT-SINGLE EXPOSURE: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
STOT-REPEATED EXPOSURE:
MAY CAUSE DAMAGE TO ORGANS (BLOOD) THROUGH PROLONGED OR REPEATED EXPOSURE
IF SWALLOWED.
INGREDIENTS:
METHYLTRI(ETHYLMETHYLKETOXIME)SILANE:
| ROUTES OF EXPOSURE: INGESTION
| TARGET ORGANS: BLOOD
| ASSESSMENT:
| SHOWN TO PRODUCE SIGNIFICANT HEALTH EFFECTS IN ANIMALS AT CONCENTRATIONS
| OF >10 TO 100 MG/KG BW.
VINYLTRI (METHYLETHYLKETOXIME) SILANE:
| ROUTES OF EXPOSURE: INGESTION
| TARGET ORGANS: BLOOD
| ASSESSMENT:
| SHOWN TO PRODUCE SIGNIFICANT HEALTH EFFECTS IN ANIMALS AT CONCENTRATIONS
| OF >10 TO 100 MG/KG BW.
N-(3-(TRIMETHOXYSILYL)PROPYL)ETHYLENEDIAMINE:
| ROUTES OF EXPOSURE: INGESTION
| ASSESSMENT:
| NO SIGNIFICANT HEALTH EFFECTS OBSERVED IN ANIMALS AT CONCENTRATIONS OF
| 100 MG/KG BW OR LESS.
OCTAMETHYLCYCLOTETRASILOXANE:
| ROUTES OF EXPOSURE: INGESTION
| ASSESSMENT:
| NO SIGNIFICANT HEALTH EFFECTS OBSERVED IN ANIMALS AT CONCENTRATIONS OF
| 100 MG/KG BW OR LESS.
| ROUTES OF EXPOSURE: INHALATION (VAPOR)
| ASSESSMENT:
| NO SIGNIFICANT HEALTH EFFECTS OBSERVED IN ANIMALS AT CONCENTRATIONS OF 1
| MG/L/6H/D OR LESS.
| ROUTES OF EXPOSURE: SKIN CONTACT
| ASSESSMENT:
| NO SIGNIFICANT HEALTH EFFECTS OBSERVED IN ANIMALS AT CONCENTRATIONS OF
| 200 MG/KG BW OR LESS.
METHYLTRI(ETHYLMETHYLKETOXIME)SILANE ISOMERS AND OLIGOMERS:
| ROUTES OF EXPOSURE: INGESTION
| TARGET ORGANS: BLOOD
| ASSESSMENT:
| SHOWN TO PRODUCE SIGNIFICANT HEALTH EFFECTS IN ANIMALS AT CONCENTRATIONS
| OF >10 TO 100 MG/KG BW.
DIMETHYLBIS[(1-OXONEODECYL)OXY]STANNANE:
| ROUTES OF EXPOSURE: INGESTION
| TARGET ORGANS: IMMUNE SYSTEM, CENTRAL NERVOUS SYSTEM
| ASSESSMENT:
| SHOWN TO PRODUCE SIGNIFICANT HEALTH EFFECTS IN ANIMALS AT CONCENTRATIONS
| OF 10 MG/KG BW OR LESS.
REPEATED DOSE TOXICITY:
INGREDIENTS:
METHYLTRI(ETHYLMETHYLKETOXIME)SILANE:
| SPECIES: RAT
| APPLICATION ROUTE: INGESTION
| TARGET ORGANS: BLOOD
| REMARKS: ON BASIS OF TEST DATA.
VINYLTRI (METHYLETHYLKETOXIME) SILANE:
| SPECIES: RAT
| APPLICATION ROUTE: INGESTION
| TARGET ORGANS: BLOOD
| REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
N-(3-(TRIMETHOXYSILYL)PROPYL)ETHYLENEDIAMINE:
| APPLICATION ROUTE: INGESTION
| REMARKS: ON BASIS OF TEST DATA.
OCTAMETHYLCYCLOTETRASILOXANE:
| SPECIES: RAT
| APPLICATION ROUTE: INGESTION
| REMARKS: ON BASIS OF TEST DATA.
| SPECIES: RAT
| APPLICATION ROUTE: INHALATION (VAPOR)
| REMARKS: ON BASIS OF TEST DATA.
| SPECIES: RABBIT
| APPLICATION ROUTE: SKIN CONTACT
| REMARKS: ON BASIS OF TEST DATA.
METHYLTRI(ETHYLMETHYLKETOXIME)SILANE ISOMERS AND OLIGOMERS:
| SPECIES: RAT
| APPLICATION ROUTE: INGESTION
| TARGET ORGANS: BLOOD
| REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
DIMETHYLBIS[(1-OXONEODECYL)OXY]STANNANE:
| SPECIES: RAT
| NOAEL: <1.6 MG/KG
| APPLICATION ROUTE: INGESTION
| EXPOSURE TIME: 90 DAYS
| REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
ASPIRATION TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
FURTHER INFORMATION:
PRODUCT:
REMARKS:
DURING USE OF THE MATERIAL, SMALL AMOUNTS OF METHYLETHYLKETOXIME (MEKO)
WILL BE RELEASED. RODENTS EXPOSED TO CHRONIC MEKO INHALATION THROUGHOUT
THEIR LIFETIMES SHOWED SIGNIFICANT INCREASES IN LIVER TUMOR RATES.
INGREDIENTS:
OCTAMETHYLCYCLOTETRASILOXANE:
| REMARKS:
| RESULTS FROM A 2 YEAR REPEATED VAPOR INHALATION EXPOSURE STUDY TO RATS OF
| OCTAMETHYLCYCLOTETRASILOXANE (D4) INDICATE EFFECTS (BENIGN UTERINE
| ADENOMAS) IN THE UTERUS OF FEMALE ANIMALS. THIS FINDING OCCURRED AT THE
| HIGHEST EXPOSURE DOSE (700 PPM) ONLY. STUDIES TO DATE HAVE NOT
| DEMONSTRATED IF THESE EFFECTS OCCUR THROUGH PATHWAYS THAT ARE RELEVANT TO
| HUMANS. REPEATED EXPOSURE IN RATS TO D4 RESULTED IN PROTOPORPHYRIN
| ACCUMULATION IN THE LIVER. WITHOUT KNOWLEDGE OF THE SPECIFIC MECHANISM
| LEADING TO THE PROTOPORPHYRIN ACCUMULATION THE RELEVANCE OF THIS FINDING
| TO HUMANS IS UNKNOWN.
| SECTION 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY
INGREDIENTS:
METHYLTRI(ETHYLMETHYLKETOXIME)SILANE:
| TOXICITY TO FISH:
| LC50 (ONCORHYNCHUS MYKISS (RAINBOW TROUT)): >120 MG/L
| EXPOSURE TIME: 96 H
| METHOD: OECD TEST GUIDELINE 203
| REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
| TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
| EC50 (DAPHNIA MAGNA (WATER FLEA)): >120 MG/L
| EXPOSURE TIME: 48 H
| METHOD: OECD TEST GUIDELINE 202
| REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
| TOXICITY TO ALGAE:
| ERC50 (SELENASTRUM CAPRICORNUTUM (GREEN ALGAE)): 94 MG/L
| EXPOSURE TIME: 72 H
| METHOD: OECD TEST GUIDELINE 201
| REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
ECOTOXICOLOGY ASSESSMENT:
| ACUTE AQUATIC TOXICITY:
| THIS PRODUCT HAS NO KNOWN ECOTOXICOLOGICAL EFFECTS.
VINYLTRI (METHYLETHYLKETOXIME) SILANE:
TOXICITY TO FISH:
| LC50 (ONCORHYNCHUS MYKISS (RAINBOW TROUT)): >120 MG/L
| EXPOSURE TIME: 96 H
| METHOD: OECD TEST GUIDELINE 203
| LC50 (ORYZIAS LATIPES (ORANGE-RED KILLIFISH)): >100 MG/L
| EXPOSURE TIME: 96 H
| METHOD: OECD TEST GUIDELINE 203
N-(3-(TRIMETHOXYSILYL)PROPYL)ETHYLENEDIAMINE:
| TOXICITY TO FISH:
| LC50 (DANIO RERIO (ZEBRA FISH)): 597 MG/L
| EXPOSURE TIME: 96 H
| METHOD: DIRECTIVE 67/548/EEC, ANNEX V, C.1.
| TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
| EC50 (DAPHNIA SP. (WATER FLEA)): 81 MG/L
| EXPOSURE TIME: 48 H
| METHOD: DIRECTIVE 67/548/EEC, ANNEX V, C.2.
| TOXICITY TO ALGAE:
| ERC50 (SELENASTRUM CAPRICORNUTUM (GREEN ALGAE)): 8.8 MG/L
| EXPOSURE TIME: 72 H
| METHOD: OECD TEST GUIDELINE 201
| NOEC (SELENASTRUM CAPRICORNUTUM (GREEN ALGAE)): 3.1 MG/L
| EXPOSURE TIME: 72 H
| METHOD: OECD TEST GUIDELINE 201
| TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES (CHRONIC TOXICITY):
| NOEC (DAPHNIA SP. (WATER FLEA)): >1 MG/L
| EXPOSURE TIME: 21 D
| TOXICITY TO MICROORGANISMS:
| EC50 (PSEUDOMONAS PUTIDA): 67 MG/L
| EXPOSURE TIME: 16 H
| METHOD: DIN 38 412 PART 8
OCTAMETHYLCYCLOTETRASILOXANE:
| TOXICITY TO FISH:
| LC50 (CYPRINODON VARIEGATUS (SHEEPSHEAD MINNOW)): >0.0063 MG/L
| EXPOSURE TIME: 336 H
| REMARKS: NO TOXICITY AT THE LIMIT OF SOLUBILITY.
| TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
| EC50 (MYSIDOPSIS BAHIA (OPOSSUM SHRIMP)): >0.0091 MG/L
| EXPOSURE TIME: 96 H
| REMARKS: NO TOXICITY AT THE LIMIT OF SOLUBILITY.
| TOXICITY TO ALGAE:
| ERC50 (PSEUDOKIRCHNERIELLA SUBCAPITATA (GREEN ALGAE)): >0.022 MG/L
| EXPOSURE TIME: 72 H
| REMARKS: NO TOXICITY AT THE LIMIT OF SOLUBILITY.
| TOXICITY TO FISH (CHRONIC TOXICITY):
| NOEC (ONCORHYNCHUS MYKISS (RAINBOW TROUT)): >/= 0.0044 MG/L
| REMARKS: ON BASIS OF TEST DATA.
| NO TOXICITY AT THE LIMIT OF SOLUBILITY.
| TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES (CHRONIC TOXICITY):
| NOEC (DAPHNIA MAGNA (WATER FLEA)): >/= 0.0079 MG/L
| EXPOSURE TIME: 21 D
| REMARKS: ON BASIS OF TEST DATA.
| NO TOXICITY AT THE LIMIT OF SOLUBILITY.
ECOTOXICOLOGY ASSESSMENT:
| CHRONIC AQUATIC TOXICITY:
| MAY CAUSE LONG LASTING HARMFUL EFFECTS TO AQUATIC LIFE.
DIMETHYLBIS[(1-OXONEODECYL)OXY]STANNANE:
| TOXICITY TO FISH:
| LC50 (DANIO RERIO (ZEBRA FISH)): >100 MG/L
| EXPOSURE TIME: 96 H
| METHOD: OECD TEST GUIDELINE 203
| REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
| TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
| EC50 (DAPHNIA MAGNA (WATER FLEA)): 17 MG/L
| EXPOSURE TIME: 48 H
| METHOD: OECD TEST GUIDELINE 202
| REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
| TOXICITY TO ALGAE:
| ERC50 (DESMODESMUS SUBSPICATUS (GREEN ALGAE)): 37 MG/L
| EXPOSURE TIME: 72 H
| METHOD: OECD TEST GUIDELINE 201
| REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
| EC10 (DESMODESMUS SUBSPICATUS (GREEN ALGAE)): 5.7 MG/L
| EXPOSURE TIME: 72 H
| METHOD: OECD TEST GUIDELINE 201
| REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
PERSISTENCE AND DEGRADABILITY:
INGREDIENTS:
METHYLTRI(ETHYLMETHYLKETOXIME)SILANE:
| BIODEGRADABILITY:
| RESULT: NOT READILY BIODEGRADABLE.
| BIODEGRADATION: 14.5%
| EXPOSURE TIME: 21 D
| METHOD: OECD TEST GUIDELINE 302B
| REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
VINYLTRI (METHYLETHYLKETOXIME) SILANE:
| BIODEGRADABILITY:
| RESULT: NOT READILY BIODEGRADABLE.
| BIODEGRADATION: 0%
| EXPOSURE TIME: 28 D
| METHOD: OECD TEST GUIDELINE 301A
| STABILITY IN WATER:
| DEGRADATION HALF LIFE: <1 MIN (2 DEG. C)
| METHOD: OECD TEST GUIDELINE 111
N-(3-(TRIMETHOXYSILYL)PROPYL)ETHYLENEDIAMINE:
| BIODEGRADABILITY:
| RESULT: NOT READILY BIODEGRADABLE.
| BIODEGRADATION: 39%
| METHOD: OECD TEST GUIDELINE 301A
| STABILITY IN WATER:
| DEGRADATION HALF LIFE: 0.025 H (24.7 DEG. C)
| PH: 7
| METHOD: OECD TEST GUIDELINE 111
OCTAMETHYLCYCLOTETRASILOXANE:
| BIODEGRADABILITY:
| RESULT: NOT READILY BIODEGRADABLE.
| BIODEGRADATION: 3.7%
| EXPOSURE TIME: 28 D
| METHOD: OECD TEST GUIDELINE 310
| STABILITY IN WATER:
| DEGRADATION HALF LIFE: 69.3 - 144 H (24.6 DEG. C)
| PH: 7
| METHOD: OECD TEST GUIDELINE 111
DIMETHYLBIS[(1-OXONEODECYL)OXY]STANNANE:
| BIODEGRADABILITY:
| RESULT: NOT READILY BIODEGRADABLE.
| BIODEGRADATION: 3%
| EXPOSURE TIME: 35 D
| METHOD: OECD TEST GUIDELINE 301F
| REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
BIOACCUMULATIVE POTENTIAL:
INGREDIENTS:
METHYLTRI(ETHYLMETHYLKETOXIME)SILANE:
| PARTITION COEFFICIENT N-OCTANOL/WATER:
| LOG POW: 11.2
N-(3-(TRIMETHOXYSILYL)PROPYL)ETHYLENEDIAMINE:
| PARTITION COEFFICIENT N-OCTANOL/WATER:
| LOG POW: -0.3
OCTAMETHYLCYCLOTETRASILOXANE:
| BIOACCUMULATION:
| SPECIES: PIMEPHALES PROMELAS (FATHEAD MINNOW)
| BIOCONCENTRATION FACTOR (BCF): 12,400
| PARTITION COEFFICIENT N-OCTANOL/WATER:
| LOG POW: 6.48 (25.1 DEG. C)
MOBILITY IN SOIL: NO DATA AVAILABLE
OTHER ADVERSE EFFECTS:
INGREDIENTS:
OCTAMETHYLCYCLOTETRASILOXANE:
| RESULTS OF PBT AND VPVB ASSESSMENT:
| REMARKS:
| OCTAMETHYLCYCLOTETRASILOXANE (D4) MEETS THE CURRENT REACH ANNEX XIII
| CRITERIA FOR PBT AND VPVB. IN CANADA, D4 HAS BEEN ASSESSED AND DEEMED TO
| MEET THE PIT CRITERIA. HOWEVER, D4 DOES NOT BEHAVE SIMILARLY TO KNOWN
| PBT/VPVB SUBSTANCES. THE WEIGHT OF SCIENTIFIC EVIDENCE FROM FIELD STUDIES
| SHOWS THAT D4 IS NOT BIOMAGNIFYING IN AQUATIC AND TERRESTRIAL FOOD WEBS.
| D4 IN AIR WILL DEGRADE BY REACTION WITH NATURALLY OCCURRING HYDROXYL
| RADICALS IN THE ATMOSPHERE. ANY D4 IN AIR THAT DOES NOT DEGRADE BY
| REACTION WITH HYDROXYL RADICALS IS NOT EXPECTED TO DEPOSIT FROM THE AIR
| TO WATER, TO LAND, OR TO LIVING ORGANISMS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS
RESOURCE CONSERVATION AND RECOVERY ACT (RCRA):
THIS PRODUCT HAS BEEN EVALUATED FOR RCRA CHARACTERISTICS AND DOES NOT MEET
THE CRITERIA OF HAZARDOUS WASTE IF DISCARDED IN ITS PURCHASED FORM.
WASTE FROM RESIDUES: DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS.
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL.
IF NOT OTHERWISE SPECIFIED: DISPOSE OF AS UNUSED PRODUCT.
| SECTION 14. TRANSPORT INFORMATION | |
INTERNATIONAL REGULATIONS:
UNRTDG: NOT REGULATED AS A DANGEROUS GOOD
IATA-DGR: NOT REGULATED AS A DANGEROUS GOOD
IMDG-CODE: NOT REGULATED AS A DANGEROUS GOOD
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT APPLICABLE FOR PRODUCT AS SUPPLIED.
DOMESTIC REGULATION:
49 CFR: NOT REGULATED AS A DANGEROUS GOOD
| SECTION 15. REGULATORY INFORMATION | |
EPCRA - EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW:
CERCLA REPORTABLE QUANTITY:
INGREDIENTS CAS-NO. COMPONENT RQ (LBS) CALCULATED PRODUCT RQ
(LBS)
| N-HEXANE 110-54-3 5000 *
| METHANOL 67-56-1 5000 *
| ETHYLENEDIAMINE 107-15-3 5000 *
*: CALCULATED RQ EXCEEDS REASONABLY ATTAINABLE UPPER LIMIT.
SARA 304 EXTREMELY HAZARDOUS SUBSTANCES REPORTABLE QUANTITY:
INGREDIENTS CAS-NO. COMPONENT RQ (LBS) CALCULATED PRODUCT RQ
(LBS)
| ETHYLENEDIAMINE 107-15-3 5000 *
*: CALCULATED RQ EXCEEDS REASONABLY ATTAINABLE UPPER LIMIT.
SARA 302 EXTREMELY HAZARDOUS SUBSTANCES THRESHOLD PLANNING QUANTITY:
THIS MATERIAL DOES NOT CONTAIN ANY COMPONENTS WITH A SECTION 302 EHS TPQ.
SARA 311/312 HAZARDS:
ACUTE HEALTH HAZARD
CHRONIC HEALTH HAZARD
SARA 313:
THIS MATERIAL DOES NOT CONTAIN ANY CHEMICAL COMPONENTS WITH KNOWN CAS
NUMBERS THAT EXCEED THE THRESHOLD (DE MINIMIS) REPORTING LEVELS ESTABLISHED
BY SARA TITLE III, SECTION 313.
US STATE REGULATIONS:
PENNSYLVANIA RIGHT TO KNOW:
DIMETHYL SILOXANE, HYDROXY-TERMINATED 70131-67-8
DIMETHYL SILOXANE, TRIMETHYLSILOXY-TERMINATED 63148-62-9
SILICON DIOXIDE 7631-86-9
METHYLTRI(ETHYLMETHYLKETOXIME)SILANE 22984-54-9
METHANOL 67-56-1
CALIFORNIA PROP. 65:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
METHANOL 67-56-1
CALIFORNIA LIST OF HAZARDOUS SUBSTANCES:
SILICON DIOXIDE 7631-86-9
CALIFORNIA PERMISSIBLE EXPOSURE LIMITS FOR CHEMICAL CONTAMINANTS
SILICON DIOXIDE 7631-86-9
THE INGREDIENTS OF THIS PRODUCT ARE REPORTED IN THE FOLLOWING INVENTORIES:
NZIOC: ALL INGREDIENTS LISTED OR EXEMPT.
REACH:
FOR PURCHASES FROM DOW CORNING EU LEGAL ENTITIES, ALL INGREDIENTS ARE
CURRENTLY PRE/REGISTERED OR EXEMPT UNDER REACH. PLEASE REFER TO SECTION 1
FOR RECOMMENDED USES. FOR PURCHASES FROM NON-EU DOW CORNING LEGAL ENTITIES
WITH THE INTENTION TO EXPORT INTO EEA PLEASE CONTACT YOUR DC
REPRESENTATIVE/LOCAL OFFICE.
TSCA:
ALL CHEMICAL SUBSTANCES IN THIS PRODUCT ARE EITHER LISTED ON THE TSCA
INVENTORY OR ARE IN COMPLIANCE WITH A TSCA INVENTORY EXEMPTION.
AICS: ALL INGREDIENTS LISTED OR EXEMPT.
IECSC: ALL INGREDIENTS LISTED OR EXEMPT.
ENCS/ISHL:
ALL COMPONENTS ARE LISTED ON ENCS/ISHL OR EXEMPTED FROM INVENTORY LISTING.
DSL:
ALL CHEMICAL SUBSTANCES IN THIS PRODUCT COMPLY WITH THE CEPA 1999 AND NSNR
AND ARE ON OR EXEMPT FROM LISTING ON THE CANADIAN DOMESTIC SUBSTANCES LIST
(DSL).
| SECTION 16. OTHER INFORMATION | |
FURTHER INFORMATION:
NFPA:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARD.
HMIS(R*) IV:
HEALTH 2*
FLAMMABILITY 1
PHYSICAL HAZARD 0
HMIS(R*) RATINGS ARE BASED ON A 0-4 RATING SCALE, WITH 0 REPRESENTING
MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING SIGNIFICANT HAZARDS OR RISKS.
THE "*" REPRESENTS A CHRONIC HAZARD, WHILE THE "/" REPRESENTS THE ABSENCE
OF A CHRONIC HAZARD.
FULL TEXT OF OTHER ABBREVIATIONS:
ACGIH: USA. ACGIH THRESHOLD LIMIT VALUES (TLV)
NIOSH REL: USA. NIOSH RECOMMENDED EXPOSURE LIMITS
OSHA Z-1:
USA. OCCUPATIONAL EXPOSURE LIMITS (OSHA) - TABLE Z-1 LIMITS FOR AIR
CONTAMINANTS
OSHA Z-3:
USA. OCCUPATIONAL EXPOSURE LIMITS (OSHA) - TABLE Z-3 MINERAL DUSTS
US WEEL: USA. WORKPLACE ENVIRONMENTAL EXPOSURE LEVELS (WEEL)
ACGIH / TWA: 8-HOUR, TIME-WEIGHTED AVERAGE
ACGIH / STEL: SHORT-TERM EXPOSURE LIMIT
NIOSH REL / TWA:
TIME-WEIGHTED AVERAGE CONCENTRATION FOR UP TO A 10-HOUR WORKDAY DURING A
40-HOUR WORKWEEK
NIOSH REL / ST:
STEL - 15-MINUTE TWA EXPOSURE THAT SHOULD NOT BE EXCEEDED AT ANY TIME
DURING A WORKDAY
OSHA Z-1 / TWA: 8-HOUR TIME WEIGHTED AVERAGE
OSHA Z-3 / TWA: 8-HOUR TIME WEIGHTED AVERAGE
US WEEL / TWA: TIME WEIGHTED AVERAGE
US WEEL / TWA: 8-HR TWA
AICS: AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES
ASTM: AMERICAN SOCIETY FOR THE TESTING OF MATERIALS
BW: BODY WEIGHT
CERCLA:
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT
CMR: CARCINOGEN, MUTAGEN OR REPRODUCTIVE TOXICANT
DIN: STANDARD OF THE GERMAN INSTITUTE FOR STANDARDIZATION
DOT: DEPARTMENT OF TRANSPORTATION
DSL: DOMESTIC SUBSTANCES LIST (CANADA)
ECX: CONCENTRATION ASSOCIATED WITH X% RESPONSE
EHS: EXTREMELY HAZARDOUS SUBSTANCE
ELX: LOADING RATE ASSOCIATED WITH X% RESPONSE
EMS: EMERGENCY SCHEDULE
ENCS: EXISTING AND NEW CHEMICAL SUBSTANCES (JAPAN)
ERCX: CONCENTRATION ASSOCIATED WITH X% GROWTH RATE RESPONSE
ERG: EMERGENCY RESPONSE GUIDE
GHS: GLOBALLY HARMONIZED SYSTEM
GLP: GOOD LABORATORY PRACTICE
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC:
INTERNATIONAL CODE FOR THE CONSTRUCTION AND EQUIPMENT OF SHIPS CARRYING
DANGEROUS CHEMICALS IN BULK
IC50: HALF MAXIMAL INHIBITORY CONCENTRATION
ICAO: INTERNATIONAL CIVIL AVIATION ORGANIZATION
IECSC: INVENTORY OF EXISTING CHEMICAL SUBSTANCES IN CHINA
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
IMO: INTERNATIONAL MARITIME ORGANIZATION
ISHL: INDUSTRIAL SAFETY AND HEALTH LAW (JAPAN)
ISO: INTERNATIONAL ORGANIZATION FOR STANDARDIZATION
KECI: KOREA EXISTING CHEMICALS INVENTORY
LC50: LETHAL CONCENTRATION TO 50% OF A TEST POPULATION
LD50: LETHAL DOSE TO 50% OF A TEST POPULATION (MEDIAN LETHAL DOSE)
MARPOL: INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS
MSHA: MINE SAFETY AND HEALTH ADMINISTRATION
N.O.S.: NOT OTHERWISE SPECIFIED
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION
NO(A)EC: NO OBSERVED (ADVERSE) EFFECT CONCENTRATION
NO(A)EL: NO OBSERVED (ADVERSE) EFFECT LEVEL
NOELR: NO OBSERVABLE EFFECT LOADING RATE
NTP: NATIONAL TOXICOLOGY PROGRAM
NZIOC: NEW ZEALAND INVENTORY OF CHEMICALS
OECD: ORGANIZATION FOR ECONOMIC CO-OPERATION AND DEVELOPMENT
OPPTS: OFFICE OF CHEMICAL SAFETY AND POLLUTION PREVENTION
PBT: PERSISTENT, BIOACCUMULATIVE AND TOXIC SUBSTANCE
PICCS: PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL SUBSTANCES
(Q)SAR: (QUANTITATIVE) STRUCTURE ACTIVITY RELATIONSHIP
RCRA: RESOURCE CONSERVATION AND RECOVERY ACT
REACH:
REGULATION (EC) NO 1907/2006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
CONCERNING THE REGISTRATION, EVALUATION, AUTHORIZATION AND RESTRICTION OF
CHEMICALS
RQ: REPORTABLE QUANTITY
SADT: SELF-ACCELERATING DECOMPOSITION TEMPERATURE
SARA: SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT
SDS: SAFETY DATA SHEET
TCSI: TAIWAN CHEMICAL SUBSTANCE INVENTORY
TSCA: TOXIC SUBSTANCES CONTROL ACT (UNITED STATES)
UN: UNITED NATIONS
UNRTDG: UNITED NATIONS RECOMMENDATIONS ON THE TRANSPORT OF DANGEROUS GOODS
VPVB: VERY PERSISTENT AND VERY BIOACCUMULATIVE
SOURCES OF KEY DATA USED TO COMPILE THE MATERIAL SAFETY DATA SHEET:
INTERNAL TECHNICAL DATA, DATA FROM RAW MATERIAL SDSS, OECD ECHEM PORTAL
SEARCH RESULTS AND EUROPEAN CHEMICALS AGENCY, HTTP://ECHA.EUROPA.EU/
REVISION DATE: 04/24/2017
ITEMS WHERE CHANGES HAVE BEEN MADE TO THE PREVIOUS VERSION ARE HIGHLIGHTED
IN THE BODY OF THIS DOCUMENT BY TWO VERTICAL LINES.
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING, USE,
PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND SHALL NOT BE
CONSIDERED A WARRANTY OR QUALITY SPECIFICATION OF ANY TYPE. THE INFORMATION
PROVIDED RELATES ONLY TO THE SPECIFIC MATERIAL IDENTIFIED AT THE TOP OF
THIS SDS AND MAY NOT BE VALID WHEN THE SDS MATERIAL IS USED IN COMBINATION
WITH ANY OTHER MATERIALS OR IN ANY PROCESS, UNLESS SPECIFIED IN THE TEXT.
MATERIAL USERS SHOULD REVIEW THE INFORMATION AND RECOMMENDATIONS IN THE
SPECIFIC CONTEXT OF THEIR INTENDED MANNER OF HANDLING, USE, PROCESSING AND
STORAGE, INCLUDING AN ASSESSMENT OF THE APPROPRIATENESS OF THE SDS MATERIAL
IN THE USER'S END PRODUCT, IF APPLICABLE.
US / Z8