| Common Name: | SHELL SHOCK 4-1GL |
| Manufacturer: | ZEP MANUFACTURING |
| SDS Revision Date: | 11/16/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 43NR78 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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ZEP INC
SAFETY DATA SHEET
ZEP SHELL SHOCK 4-1GL
VERSION: 2.2
REVISION DATE: 11/16/2015
PRINT DATE: 01/18/2016
| SECTION 1. PRODUCT AND COMPANY IDENTIFICATION |  |
MATERIAL NAME: ZEP SHELL SHOCK 4-1GL
MATERIAL NUMBER: 000000000000084923
MANUFACTURER OR SUPPLIER'S DETAILS:
COMPANY: ZEP INC.
ADDRESS:
1310 SEABOARD INDUSTRIAL BLVD., NW
ATLANTA, GA 30318
TELEPHONE: 404-352-1680
EMERGENCY TELEPHONE NUMBERS:
FOR SDS INFORMATION:
COMPLIANCE SERVICES: 1-877-428-9937
FOR A MEDICAL EMERGENCY: 877-541-2016 TOLL FREE - ALL CALLS RECORDED
FOR A TRANSPORTATION EMERGENCY:
CHEMTREC:
800-424-9300 - ALL CALLS RECORDED.
IN THE DISTRICT OF COLUMBIA 202-483-7616
| SECTION 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
APPEARANCE: GEL
COLOUR: TAN, OPAQUE
ODOUR: CINNAMON-LIKE, LIKE FRUIT
GHS CLASSIFICATION: NOT A HAZARDOUS SUBSTANCE OR MIXTURE.
GHS LABEL ELEMENT: NOT A HAZARDOUS SUBSTANCE OR MIXTURE.
POTENTIAL HEALTH EFFECTS:
CARCINOGENICITY:
IARC:
GROUP 2B: POSSIBLY CARCINOGENIC TO HUMANS
TITANIUM DIOXIDE 13463-67-7
ACGIH:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY ACGIH.
OSHA:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY OSHA.
NTP:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE / MIXTURE: MIXTURE
HAZARDOUS COMPONENTS:
CHEMICAL NAME CAS-NO. CONCENTRATION [%]
ALCOHOLS, C12-16, ETHOXYLATED 68551-12-2 >=1 - <5
2-METHYLPENTANE-2,4-DIOL 107-41-5 >=1 - <5
TITANIUM DIOXIDE 13463-67-7 >=1 - <5
2,2',2"-NITRILOTRIETHANOL 102-71-6 >=1 - <5
THE EXACT PERCENTAGES OF DISCLOSED SUBSTANCES ARE WITHHELD AS TRADE
SECRETS.
| SECTION 4. FIRST AID MEASURES | |
GENERAL ADVICE:
DO NOT LEAVE THE VICTIM UNATTENDED.
SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE.
MOVE OUT OF DANGEROUS AREA.
IF INHALED:
IF UNCONSCIOUS PLACE IN RECOVERY POSITION AND SEEK MEDICAL ADVICE.
IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
IN CASE OF SKIN CONTACT:
THIS PRODUCT IS FORMULATED FOR USE ON SKIN BUT SHOULD ALWAYS BE IMMEDIATELY
WASHED OFF WITH PLENTY OF WATER. DISCONTINUE USE IF IRRITATION AND REDNESS
DEVELOP. IF CONDITIONS PERSIST FOR MORE THAN 72 HOURS, CONSULT A PHYSICIAN.
IN CASE OF EYE CONTACT:
REMOVE CONTACT LENSES.
PROTECT UNHARMED EYE.
KEEP EYE WIDE OPEN WHILE RINSING.
IF EYE IRRITATION PERSISTS, CONSULT A SPECIALIST.
RINSE IMMEDIATELY WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.
IF SWALLOWED:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY A PHYSICIAN OR POISON
CONTROL CENTER.
KEEP RESPIRATORY TRACT CLEAR.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF SYMPTOMS PERSIST,
CALL A PHYSICIAN.
| SECTION 5. FIREFIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
DRY CHEMICAL
WATER SPRAY JET
CARBON DIOXIDE (CO2)
ALCOHOL-RESISTANT FOAM
UNSUITABLE EXTINGUISHING MEDIA: HIGH VOLUME WATER JET
SPECIFIC HAZARDS DURING FIREFIGHTING:
DO NOT ALLOW RUN-OFF FROM FIRE FIGHTING TO ENTER DRAINS OR WATER COURSES.
HAZARDOUS COMBUSTION PRODUCTS:
CARBON DIOXIDE (CO2)
CARBON MONOXIDE
SMOKE
NITROGEN OXIDES (NOX)
SPECIFIC EXTINGUISHING METHODS:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT.
FURTHER INFORMATION: STANDARD PROCEDURE FOR CHEMICAL FIRES.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
WEAR SELF-CONTAINED BREATHING APPARATUS FOR FIREFIGHTING IF NECESSARY.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
MATERIAL CAN CREATE SLIPPERY CONDITIONS.
USE NON-SLIP SAFETY SHOES IN AREAS WHERE SPILLS OR LEAKS CAN OCCUR.
REFER TO PROTECTIVE MEASURES LISTED IN SECTIONS 7 AND 8.
ENVIRONMENTAL PRECAUTIONS:
PREVENT PRODUCT FROM ENTERING DRAINS.
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
IF THE PRODUCT CONTAMINATES RIVERS AND LAKES OR DRAINS INFORM RESPECTIVE
AUTHORITIES.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND, SILICA GEL, ACID BINDER,
UNIVERSAL BINDER, SAWDUST).
KEEP IN SUITABLE, CLOSED CONTAINERS FOR DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
ADVICE ON SAFE HANDLING:
FOR PERSONAL PROTECTION SEE SECTION 8.
SMOKING, EATING AND DRINKING SHOULD BE PROHIBITED IN THE APPLICATION AREA.
DISPOSE OF RINSE WATER IN ACCORDANCE WITH LOCAL AND NATIONAL REGULATIONS.
AVOID CONTACT WITH EYES.
CONDITIONS FOR SAFE STORAGE:
CONTAINERS WHICH ARE OPENED MUST BE CAREFULLY RESEALED AND KEPT UPRIGHT
TO PREVENT LEAKAGE.
KEEP CONTAINERS TIGHTLY CLOSED IN A COOL, WELL-VENTILATED PLACE.
MATERIALS TO AVOID:
OXIDIZING AGENTS
STORE AND KEEP AWAY FROM BASES AND ALKALIES.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
COMPONENTS WITH WORKPLACE CONTROL PARAMETERS:
COMPONENTS CAS-NO. VALUE TYPE CONTROL BASIS
(FORM OF PARAMETERS /
EXPOSURE) PERMISSIBLE
CONCENTRATION
2-METHYLPENTANE- 107-41-5 C 25 PPM ACGIH
2,4-DIOL
C 25 PPM NIOSH REL
125 MG/M3
C 25 PPM OSHA P0
125 MG/M3
TITANIUM DIOXIDE 13463-67-7 TWA 10 MG/M3 ACGIH
TWA 15 MG/M3 OSHA Z-1
(TOTAL
DUST)
2,2',2"- 102-71-6 TWA 5 MG/M3 ACGIH
NITRILOTRIETHANOL
ENGINEERING MEASURES: NOT APPLICABLE
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION:
IN CASE OF INSUFFICIENT VENTILATION, WEAR SUITABLE RESPIRATORY EQUIPMENT.
HAND PROTECTION:
REMARKS: NO SPECIAL PROTECTION IS REQUIRED.
EYE PROTECTION:
EYE PROTECTION IS NOT REQUIRED WHILE WASHING WITH THIS PRODUCT. IN THE
WORKPLACE, THE USE OF SAFETY GLASSES IS RECOMMENDED TO AVOID EYE
EXPOSURE DURING THE HANDLING OF CONTAINERS OR DURING SPILL CLEAN-UP.
SKIN AND BODY PROTECTION: NO SPECIAL PROTECTION IS REQUIRED.
HYGIENE MEASURES:
WASH HANDS BEFORE BREAKS AND AT THE END OF WORKDAY.
WHEN USING DO NOT SMOKE.
WHEN USING DO NOT EAT OR DRINK.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: GEL
COLOUR: TAN, OPAQUE
ODOUR: CINNAMON-LIKE, LIKE FRUIT
ODOUR THRESHOLD: NO DATA AVAILABLE
PH: 7 - 8
MELTING POINT/FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: 100 DEG. C
FLASH POINT: NOT APPLICABLE
EVAPORATION RATE: >1
UPPER EXPLOSION LIMIT: NO DATA AVAILABLE
LOWER EXPLOSION LIMIT: NO DATA AVAILABLE
VAPOUR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOUR DENSITY: NO DATA AVAILABLE
DENSITY: 1.024 G/CM3
SOLUBILITY(IES):
WATER SOLUBILITY: PARTLY SOLUBLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NOT DETERMINED
THERMAL DECOMPOSITION: NO DATA AVAILABLE
VISCOSITY:
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY: STABLE
CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
NO HAZARDS TO BE SPECIALLY MENTIONED.
CONDITIONS TO AVOID: NO DATA AVAILABLE
INCOMPATIBLE MATERIALS:
BASES
OXIDIZING AGENTS
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON OXIDES
NITROGEN OXIDES (NOX)
| SECTION 11. TOXICOLOGICAL INFORMATION | |
ACUTE TOXICITY:
PRODUCT:
ACUTE ORAL TOXICITY:
ACUTE TOXICITY ESTIMATE: > 5,000 MG/KG
METHOD: CALCULATION METHOD
COMPONENTS:
2-METHYLPENTANE-2,4-DIOL:
ACUTE ORAL TOXICITY:
LD50 ORAL RAT: 3,700 MG/KG
2,2',2"-NITRILOTRIETHANOL:
ACUTE ORAL TOXICITY:
LD50 RAT: 6,400 MG/KG
ACUTE DERMAL TOXICITY:
LD50 RABBIT: >2,000 MG/KG
SKIN CORROSION/IRRITATION:
PRODUCT:
RESULT: NO SKIN IRRITATION
SERIOUS EYE DAMAGE/EYE IRRITATION: NO DATA AVAILABLE
RESPIRATORY OR SKIN SENSITISATION: NO DATA AVAILABLE
GERM CELL MUTAGENICITY: NO DATA AVAILABLE
CARCINOGENICITY:
PRODUCT:
CARCINOGENICITY - ASSESSMENT: NOT CLASSIFIABLE AS A HUMAN CARCINOGEN.
REPRODUCTIVE TOXICITY: NO DATA AVAILABLE
ALCOHOLS, C12-16, ETHOXYLATED:
2-METHYLPENTANE-2,4-DIOL:
TITANIUM DIOXIDE:
2,2',2"-NITRILOTRIETHANOL:
STOT - SINGLE EXPOSURE: NO DATA AVAILABLE
STOT - REPEATED EXPOSURE: NO DATA AVAILABLE
ASPIRATION TOXICITY: NO DATA AVAILABLE
FURTHER INFORMATION:
PRODUCT:
REMARKS: NO DATA AVAILABLE
| SECTION 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: NO DATA AVAILABLE
PERSISTENCE AND DEGRADABILITY: NO DATA AVAILABLE
BIOACCUMULATIVE POTENTIAL:
PRODUCT:
PARTITION COEFFICIENT N-OCTANOL/WATER:
REMARKS: NO DATA AVAILABLE
COMPONENTS:
2-METHYLPENTANE-2,4-DIOL:
PARTITION COEFFICIENT N-OCTANOL/WATER:
POW: 0.58
2,2',2"-NITRILOTRIETHANOL:
PARTITION COEFFICIENT N-OCTANOL/WATER:
POW: 1
MOBILITY IN SOIL: NO DATA AVAILABLE
OTHER ADVERSE EFFECTS: NO DATA AVAILABLE
PRODUCT:
REGULATION:
40 CFR PROTECTION OF ENVIRONMENT; PART 82 PROTECTION OF STRATOSPHERIC
OZONE - CAA SECTION 602 CLASS I SUBSTANCES
REMARKS:
THIS PRODUCT NEITHER CONTAINS, NOR WAS MANUFACTURED WITH A CLASS I OR
CLASS II ODS AS DEFINED BY THE U.S. CLEAN AIR ACT SECTION 602 (40 CFR 82,
SUBPT. A, APP.A + B).
ADDITIONAL ECOLOGICAL INFORMATION: NO DATA AVAILABLE
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
WASTE FROM RESIDUES:
DO NOT DISPOSE OF WASTE INTO SEWER.
DO NOT CONTAMINATE PONDS, WATERWAYS OR DITCHES WITH CHEMICAL OR USED
CONTAINER.
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS.
CONTAMINATED PACKAGING:
DISPOSE OF AS UNUSED PRODUCT.
EMPTY REMAINING CONTENTS.
DO NOT RE-USE EMPTY CONTAINERS.
| SECTION 14. TRANSPORT INFORMATION | |
TRANSPORTATION REGULATION 49 CFR (USA):
NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
TRANSPORTATION REGULATION IMDG (VESSEL):
NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
TRANSPORTATION REGULATION IATA (CARGO AIR):
NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
TRANSPORTATION REGULATION IATA (PASSENGER AIR):
NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
TRANSPORTATION REGULATION TDG (CANADA):
NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
| SECTION 15. REGULATORY INFORMATION | |
EPCRA - EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT:
CERCLA REPORTABLE QUANTITY:
COMPONENTS CAS-NO. COMPONENT RQ CALCULATED PRODUCT RQ
(LBS) (LBS)
2,2'-IMINODIETHANOL 111-42-2 100 *
*: CALCULATED RQ EXCEEDS REASONABLY ATTAINABLE UPPER LIMIT.
CERCLA REPORTABLE QUANTITY:
THIS MATERIAL DOES NOT CONTAIN ANY COMPONENTS WITH A CERCLA RQ.
SARA 304 EXTREMELY HAZARDOUS SUBSTANCES REPORTABLE QUANTITY:
THIS MATERIAL DOES NOT CONTAIN ANY COMPONENTS WITH A SECTION 304 EHS RQ.
SARA 311/312 HAZARDS: NO SARA HAZARDS
SARA 302:
NO CHEMICALS IN THIS MATERIAL ARE SUBJECT TO THE REPORTING REQUIREMENTS OF
SARA TITLE III, SECTION 302.
SARA 313:
THIS MATERIAL DOES NOT CONTAIN ANY CHEMICAL COMPONENTS WITH KNOWN CAS
NUMBERS THAT EXCEED THE THRESHOLD (DE MINIMIS) REPORTING LEVELS
ESTABLISHED BY SARA TITLE III, SECTION 313.
CALIFORNIA PROP 65:
WARNING!
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
2,2'-IMINODIETHANOL 111-42-2
THE COMPONENTS OF THIS PRODUCT ARE REPORTED IN THE FOLLOWING INVENTORIES:
TSCA: ON TSCA INVENTORY
DSL: ALL COMPONENTS OF THIS PRODUCT ARE ON THE CANADIAN DSL
AICS: NOT IN COMPLIANCE WITH THE INVENTORY
NZIOC: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
PICCS: NOT IN COMPLIANCE WITH THE INVENTORY
IECSC: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
INVENTORY ACRONYM AND VALIDITY AREA LEGEND:
AICS (AUSTRALIA), DSL (CANADA), IECSC (CHINA), REACH (EUROPEAN UNION),
ENCS (JAPAN), ISHL (JAPAN), KECI (KOREA), NZIOC (NEW ZEALAND), PICCS
(PHILIPPINES), TCSI (TAIWAN), TSCA (USA)
| SECTION 16. OTHER INFORMATION | |
FURTHER INFORMATION:
NFPA:
HEALTH 0
FLAMMABILITY 0
INSTABILITY 0
SPECIAL HAZARD.
HMIS III:
HEALTH 0
FLAMMABILITY 0
PHYSICAL HAZARD 0
0 = NOT SIGNIFICANT
1 =SLIGHT
2 = MODERATE
3 = HIGH
4 = EXTREME
* = CHRONIC
OSHA GHS LABEL INFORMATION: NOT A HAZARDOUS SUBSTANCE OR MIXTURE.
VERSION: 2.2
REVISION DATE: 11/16/2015
PRINT DATE: 01/18/2016
WE BELIEVE THE STATEMENTS, TECHNICAL INFORMATION AND RECOMMENDATIONS
CONTAINED HEREIN ARE RELIABLE, BUT THEY ARE GIVEN WITHOUT WARRANTY OR
GUARANTEE OF ANY KIND. THE INFORMATION IN THIS DOCUMENT APPLIES TO THIS
SPECIFIC MATERIAL AS SUPPLIED. IT MAY NOT BE VALID FOR THIS MATERIAL IF IT
IS USED IN COMBINATION WITH ANY OTHER MATERIALS. USERS SHOULD MAKE THEIR
OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY AND APPLICABILITY OF THE
INFORMATION FOR THEIR PARTICULAR PURPOSES. THIS SDS HAS BEEN PREPARED BY
THE COMPLIANCE SERVICES ORGANIZATION SUPPORTING THIS MANUFACTURER,
SUPPLIER OR DISTRIBUTOR.
ZEP INC. MARKETS PRODUCTS UNDER WELL RECOGNIZED AND ESTABLISHED BRAND
NAMES SUCH AS ZEP(R*), ZEP COMMERCIAL(R*),ZEP PROFESSIONAL(R*),
ENFORCER(R*), NATIONAL CHEMICAL(TM), SELIG(TM), MISTY(R*), NEXT
DIMENSION(TM), PETRO(R*), I-CHEM(R*), TIMEMIST(R*), TIMEWICK(TM),
MICROBEMAX(R*), COUNTRY VET(R*), KONK(R*), ORIGINAL BIKE SPIRITS(R*),
BLUE CORAL(R*), BLACK MAGIC(R*), RAIN-X(R*), NIAGARA NATIONAL(TM), FC
FORWARD CHEMICALS(R*),REXODAN(R*), MYKAL(TM), AND A NUMBER OF PRIVATE
LABELED BRANDS.