| Common Name: | 1509 WOOD AND BAMBOO FLOORING ADHESIVE |
| Manufacturer: | ROBERTS CONSOLIDATED INDUSTRIES |
| SDS Revision Date: | 5/12/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 43Z142 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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R
ROBERTS(R*)
SAFETY DATA SHEET
REVISION DATE: 5/12/2017
| SECTION 1: IDENTIFICATION AND COMPANY DETAILS |  |
PRODUCT NAME: 1509 WOOD AND BAMBOO FLOORING ADHESIVE
PRODUCT CODE: R1509
MANUFACTURER/ SUPPLIER: ROBERTS CONSOLIDATED INDUSTRIES, INC.
ADDRESS:
300 CROSS PLAINS BLVD.
DALTON, GA 30721
EMERGENCY PHONE: (800) 424-9300 (24-HOUR RESPONSE / CHEMTREC)
PRODUCT INFORMATION: (706) 277-5294
RECOMMENDED USE: ADHESIVE
| SECTION 2: HAZARD(S) IDENTIFICATION | |
OSHA / HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS UNDER THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200)
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
RESPIRATORY SENSITIZATION: CATEGORY 1
SKIN SENSITIZATION: CATEGORY 1
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
MAY CAUSE AN ALLERGIC SKIN REACTION.
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED
HAZARD PICTOGRAMS: HEALTH HAZARD
PRECAUTIONARY STATEMENTS:
AVOID BREATHING VAPORS. WEAR EYE PROTECTION, PROTECTIVE GLOVES.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION
UNKNOWN ACUTE TOXICITY: NOT APPLICABLE
| SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS | |
NAME PRODUCT IDENTIFIER % CLASSIFICATION (GHS-US)
CALCIUM CARBONATE (CAS NO): 1317-65-3 61 - 63 NOT CLASSIFIED
DIISONONYL (CAS NO): 68515-48-0 15 - 17 NOT CLASSIFIED
PHTHALATE
POLYETHER POLYOL (CAS NO): 25322-69-4 15 - 17 NOT CLASSIFIED
POLYMERIC (CAS NO): 9016-87-9 5 - 7 SKIN IRRIT. 2, H315
DIPHENYLMETHANE SKIN SENS. 1, H317
DIISOCYANATE
SILOXANES AND (CAS NO): 67762-90-7 <1 NOT CLASSIFIED
SILICONES
PALMITIC ACID (CAS NO): 57-10-3 <1 NOT CLASSIFIED
STEARIC ACID (CAS NO): 57-11-4 <1 NOT CLASSIFIED
PTSI, TOSYL (CAS NO): 4083-64-1 <1 SKIN IRRIT. 2, H315
ISOCYANATE RESP. SENS. 1, H334
STOT SE 3, H335
2,2-DIMORPHOLINO- (CAS NO): 6425-39-4 <1 NOT CLASSIFIED
DICTHYLETHER
MYRISTIC ACID (CAS NO): 544-63-8 <1 NOT CLASSIFIED
HEPTADECANOIC ACID (CAS NO): 506-12-7 <1 NOT CLASSIFIED
DIBUTYLTIN (CAS NO): 77-58-7 <1 NOT CLASSIFIED
DILAURATE
| SECTION 4: FIRST AID MEASURES | |
INHALATION:
MOVE VICTIM TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. ASTHMATIC-TYPE
SYMPTOMS MAY DEVELOP IMMEDIATELY OR UP TO SEVERAL HOURS LATER. CONSULT
PHYSICIAN IF THIS OCCURS.
SKIN CONTACT:
WASH WITH SOAP AND WATER. IF SKIN IRRITATION OR RASH OCCURS, CONSULT
PHYSICIAN.
EYE CONTACT:
FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. CONSULT
PHYSICIAN.
INGESTION:
DO NOT INDUCE VOMITING. WASH MOUTH WITH WATER. CONSULT PHYSICIAN.
NOTE TO PHYSICIAN:
EYES:
STAIN FOR EVIDENCE OF CORNEAL INJURY. IF CORNEA IS BURNED, INSTILL
ANTIBIOTIC STEROID PREPARATION FREQUENTLY. WORKPLACE VAPORS HAVE PRODUCED
REVERSIBLE CORNEAL EPITHELIAL EDEMA IMPAIRING VISION.
SKIN:
THIS COMPOUND IS A KNOWN SKIN SENSITIZER. TREAT SYMPTOMATICALLY AS FOR
CONTACT DERMATITIS OR THERMAL BURNS. IF BURNED, TREAT AS THERMAL BURN.
INGESTION:
TREAT SYMPTOMATICALLY. MDI HAS A VERY LOW ORAL TOXICITY. THERE IS NO
SPECIFIC ANTIDOTE. INDUCING VOMITING IS CONTRAINDICATED BECAUSE OF THE
IRRITATING NATURE OF THIS COMPOUND.
RESPIRATORY:
THIS COMPOUND IS A KNOWN PULMONARY SENSITIZER. TREATMENT IS ESSENTIALLY
SYMPTOMATIC. AN INDIVIDUAL HAVING A SKIN OR PULMONARY SENSITIZATION
REACTION TO THIS MATERIAL SHOULD BE REMOVED FROM EXPOSURE TO ANY
ISOCYANATE.
| SECTION 5: FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
DRY CHEMICAL, CARBON DIOXIDE, FOAM, WATER SPRAY FOR LARGE FIRES.
HAZARDOUS COMBUSTION PRODUCTS:
CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF NITROGEN, TRACES OF HYDROGEN
CYANIDE, ISOCYANATE MONOMER VAPORS.
PROTECTION OF FIREFIGHTERS:
FULL EMERGENCY EQUIPMENT WITH SELF-CONTAINED BREATHING APPARATUS AND FULL
PROTECTIVE CLOTHING SHOULD BE WORN BY FIRE FIGHTERS. DURING A FIRE
ISOCYANATE MONOMER VAPORS AND OTHER IRRITATING, HIGHLY TOXIC GASES MAY BE
GENERATED BY THERMAL DECOMPOSITION.
SPECIFIC FIRE OR EXPLOSION HAZARDS:
AT TEMPERATURES GREATER THAN 400 DEG. F ISOCYANATES CAN POLYMERIZE AND
DECOMPOSE WHICH CAN CAUSE PRESSURE BUILDUP IN CLOSED CONTAINERS. EXPLOSIVE
RUPTURE IS POSSIBLE. THEREFORE, USE COLD WATER TO COOL FIRE EXPOSED
CONTAINERS.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS: WEAR FULL PROTECTION GEAR. (SEE SECTION 8)
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO GET INTO DRAINS, SOIL, OR SURFACE WATER.
METHODS OF CLEAN-UP:
EVACUATE AND VENTILATE SPILL AREA; DIKE SPILL TO PREVENT ENTRY INTO WATER
SYSTEM. WEAR FULL PROTECTIVE EQUIPMENT. ABSORB WITH INERT MATERIAL. SPILL
CAN BE NEUTRALIZED WITH THE FOLLOWING SOLUTION (90% WATER,8% AMMONIA, 2%
DETERGENT). ADD ABOUT 10 PARTS OF NEUTRALIZER PER PART OF ISOCYANATE. SCOOP
INTO DISPOSAL CONTAINERS. DO NOT SEAL WASTE CONTAINERS AS CO2 EVOLUTION CAN
CAUSE PRESSURE BUILDUP AND CONTAINER RUPTURE.
| SECTION 7: HANDLING AND STORAGE | |
STORE IN TIGHTLY CLOSED CONTAINER TO PREVENT MOISTURE CONTAMINATION. CARE
SHOULD BE TAKEN TO AVOID CONTACT WITH SKIN AND EYES. DO NOT BREATHE
AEROSOLS OR VAPORS. KEEP AWAY FROM FOOD AND DRINK.
STORAGE TEMPERATURE: 25C
MAXIMUM STORAGE PERIOD: 6 MONTHS
| SECTION 8: EXPOSURE CONTROL / PERSONAL PROTECTION | |
EXPOSURE GUIDELINES:
POLYMERIC DIPHENYLMETHANE DIISOCYANATE (9016-87-9):
ACGIH:
ACGIH TWA (PPM): 0.005 PPM
OSHA:
OSHA PEL (CEILING) (MG/M3): 0.2 MG/M3
OSHA:
OSHA PEL (CEILING) (PPM): 0.02 PPM
DIBUTYLTIN DILAURATE (77-58-7):
ACGIH:
ACGIH TWA (MG/M3): 0.1 MG/M3
ACGIH:
ACGIH STEL (MG/M3): 0.2 MG/M3
ENGINEERING CONTROLS:
LOCAL EXHAUST SHOULD BE USED TO KEEP AIRBORNE LEVELS BELOW TWA.
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION:
WHEN TWA IS EXCEEDED, A SELF-CONTAINED BREATHING APPARATUS OR SUPPLIED AIR
RESPIRATOR SHOULD BE USED.
SKIN PROTECTION:
PERMEATION RESISTANT GLOVES (BUTYL RUBBER, NEOPRENE, NITRILE RUBBER).
EYE/FACE PROTECTION: SAFETY GLASSES
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: LIQUID
VAPOR DENSITY: NOT DETERMINED
ODOR: SLIGHTLY MUSTY. THERE MAY BE NO ODOR WARNING PROPERTIES
RELATIVE DENSITY: NOT DETERMINED
ODOR THRESHOLD: NOT AVAILABLE
SOLUBILITY(IES): INSOLUBLE IN WATER
PH: NOT AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT DETERMINED
MELTING POINT: NOT DETERMINED
FREEZING POINT: NOT DETERMINED
AUTO-IGNITION TEMPERATURE: NOT DETERMINED
FLASH POINT: >200 DEG. C
DECOMPOSITION TEMPERATURE: NOT DETERMINED
EVAPORATION RATE: NOT DETERMINED
VISCOSITY: 80,000-120,000 CP
FLAMMABILITY (SOLID/GAS): NO DATA AVAILABLE
SPECIFIC GRAVITY: 1.6
UPPER/LOWER FLAMMABILITY: NOT DETERMINED
VOC CONTENT: 0.0 LB/GAL
VAPOR PRESSURE: <0.00001 MMHg @ 25 DEG. C (MDI)
BOILING POINT: NO DATA AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
CHEMICAL STABILITY: STABLE
CONDITIONS TO AVOID: EXCESSIVE HEAT
MATERIALS TO AVOID: WATER, AMINES, STRONG BASES, AND ALCOHOLS.
HAZARDOUS POLYMERIZATION:
MAY OCCUR THROUGH CONTACT WITH MOISTURE, OTHER MATERIALS WHICH REACT WITH
ISOCYANATES OR TEMPERATURES ABOVE 400 DEG. F MAY CAUSE POLYMERIZATION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
ACUTE TOXICITY: NOT CLASSIFIED
PTSI, TOSYL ISOCYANATE (4083-64-1):
LD50 ORAL RAT: 2600 MG/KG (RAT)
ATE US (ORAL): 2600.000 MG/KG BODY WEIGHT
POLYMERIC DIPHENYLMETHANE DIISOCYANATE (9016-87-9):
LD50 ORAL RAT: >10000 MG/KG (RAT; LITERATURE STUDY)
LD50 DERMAL RABBIT: >5000 MG/KG (RABBIT; LITERATURE STUDY)
POLYOL (25322-69-4):
LD50 ORAL RAT: >300 MG/KG (RAT)
LD50 DERMAL RABBIT: >2000 MG/KG (RABBIT)
CALCIUM CARBONATE (1317-65-3):
LD50 ORAL REAT 6450 MG/KG (RAT; LITERATURE STUDY)
ATE US (ORAL): 6450.000 MG/KG BODY WEIGHT
DIBUTYLTIN DILAURATE (77-58-7):
LD50 ORAL RAT:
2071 MG/KG BODY WEIGHT (RAT; EQUIVALENT OR SIMILAR TO OECD 401;
EXPERIMENTAL VALUE)
LD50 DERMAL RAT:
>2000 MG/KG BODY WEIGHT (RAT; EXPERIMENTAL VALUE; OECD 402: ACUTE DERMAL
TOXICITY)
ATE US (ORAL): 2071.000 MG/KG BODY WEIGHT
PALMITIC ACID (57-10-3):
LD50 ORAL RAT: >10000 MG/KG (RAT)
STEARIC ACID (57-11-4):
LD50 ORAL RAT: >5000 MG/KG (RAT)
LD50 DERMAL RABBIT: >5000 MG/KG (RABBIT)
MYRISTIC ACID (544-63-8):
LD50 ORAL RAT: >10000 MG/KG (RAT)
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
RESPIRATORY OR SKIN SENSITIZATION:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
MAY CAUSE AN ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
POLYMERIC DIPHENYLMETHANE DIISOCYANATE (9016-87-9):
IARC GROUP: 3 - NOT CLASSIFIABLE
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
SYMPTOMS/INJURIES AFTER SKIN CONTACT: CAUSES SKIN IRRITATION.
SYMPTOMS/INJURIES AFTER EYE CONTACT: CAUSES EYE IRRITATION.
| SECTION 12: ECOLOGICAL INFORMATION | |
MOBILITY AND BIOACCUMULATION POTENTIAL:
DEGRADATION: NOT DETERMINED
AQUATIC TOXICITY: NOT DETERMINED
LC50 - 24 HOUR (STATIC):
GREATER THAN 500 MG/LITER FOR DAPHNIA MAGNIA, LIMAEA STAGNALIS, AND ZEBRA
FISH FOR POLYMERIC MDI.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
DISPOSAL:
INCINERATE OR BURY IN LANDFILL IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATIONS. INCINERATION IS THE PREFERRED METHOD OF DISPOSAL.
WASTES OR RESIDUES: SAME AS ABOVE.
CONTAMINATED PACKAGING:
EMPTY CONTAINERS MUST BE HANDLED WITH CARE DUE TO PRODUCT RESIDUE.
DECONTAMINATE CONTAINERS PRIOR TO DISPOSAL. EMPTY DECONTAMINATED CONTAINERS
SHOULD BE CRUSHED TO PREVENT REUSE. DO NOT HEAT OR CUT EMPTY CONTAINER WITH
ELECTRIC OR GAS TORCH. (SEE FIRE FIGHTING MEASURES AND STABILITY &
REACTIVITY). GASES MAY BE HIGHLY TOXIC.
| SECTION 14: TRANSPORT INFORMATION | |
ROAD:
DOT PROPER SHIPPING NAME: NON-REGULATED
DOT PACKING GROUP: N/A
DOT LABEL: N/A
UN NUMBER: N/A
OCEAN:
PROPER SHIPPING NAME: NON-REGULATED
SEA - IMO/IMDG CLASS: N/A
UN NUMBER: N/A
LABEL: N/A
PACKING GROUP: N/A
MARINE POLLUTANT: N/A
EMS: N/A
AIR:
PROPER SHIPPING NAME: NON-REGULATED
AIR - ICAO/IATA CLASS: N/A
UN NUMBER: N/A
LABEL: N/A
SUB CLASS: N/A
PACKING GROUP: N/A
PACK INSTR. PASSENGER: N/A
PACK INSTR. CARGO: N/A
| SECTION 15: REGULATORY INFORMATION | |
STATUS ON SUBSTANCE LISTS:
THE CONCENTRATIONS SHOWN IN THIS DOCUMENT ARE MAXIMUM LEVELS (WEIGHT %) TO
BE USED FOR REGULATIONS.
TSCA:
THE COMPONENTS OF THIS PRODUCT ARE CONTAINED ON THE CHEMICAL SUBSTANCE
INVENTORY LIST.
OSHA:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200
IARC: NOT CARCINOGENIC
FEDERAL EPA:
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT OF
1980 (CERCLA):
REQUIRES NOTIFICATION OF THE NATIONAL RESPONSE CENTER OF RELEASE OF
QUANTITIES OF HAZARDOUS SUBSTANCES EQUAL TO OR GREATER THAN THE REPORTABLE
QUANTITIES (RQ'S) IN 40 CFR 302.4. COMPONENTS PRESENT IN THIS PRODUCT AT
LEVEL WHICH COULD REQUIRE REPORTING UNDER THE STATUTE ARE:
CHEMICAL NAME CAS NUMBER % BY WEIGHT RQ
NONE NONE NONE NONE
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA) TITLE III:
SECTIONS 301-304 REQUIRE EMERGENCY PLANNING BASED ON THRESHOLD PLANNING
QUANTITIES (TPQS) AND RELEASE REPORTING BASED ON REPORTABLE QUANTITIES (RQ)
IN 40 CFR 355. COMPONENTS PRESENT IN THIS PRODUCT AT LEVEL WHICH COULD
REQUIRE REPORTING UNDER THIS STATUE ARE:
CHEMICAL NAME CAS NUMBER % BY WEIGHT RQ
NONE NONE NONE NONE
SECTION 311-312 REQUIRE PRODUCTS BE REVIEWED AND APPLICABLE EPA HAZARD
DEFINITIONS BE IDENTIFIED AND MADE KNOWN.
EPA HAZARD CLASSIFICATIONS:
ACUTE HAZARD: YES
CHRONIC HAZARD: YES
FIRE HAZARD: NO
PRESSURE HAZARD: NO
REACTIVE HAZARD: NO
SECTION 313 REQUIRES SUBMISSION OF ANNUAL REPORTS OF RELEASE OF TOXIC
CHEMICALS THAT APPEAR IN 40 CFR 372 (FOR SARA 313). THIS INFORMATION MUST
BE INCLUDED IN ALL SDSS THAT ARE DISTRIBUTED FOR THIS MATERIAL. COMPONENTS
PRESENT IN THIS PRODUCT AT LEVEL WHICH COULD REQUIRE REPORTING UNDER THE
STATUTE ARE:
CHEMICAL NAME CAS NUMBER % BY WEIGHT
POLYMERIC DIPHENYLMETHANE 9016-87-9 <1% UNREACTED
DIISOCYANATE
TSCA INVENTORY UPDATE REPORTING (40)CFR 7109(C)):
PALMITIC ACID (57-10-3) IS A SUBSTANCE THAT IS THE SUBJECT OF A SECTION 4
TEST RULE UNDER TSCA
CANADA DSL: THIS MATERIAL IS LISTED OR EXEMPTED.
CANADA WHMIS 2015: THIS IS A HAZARDOUS PRODUCT AS DEFINED BY THE HPR
CALIFORNIA PROPOSITION 65:
DOES NOT CONTAIN ANY LISTED CHEMICAL TO THE BEST OF OUR KNOWLEDGE.
| SECTION 16: OTHER INFORMATION | |
HMIS:
H 2
F 1
R 0
PERSONAL PROTECTION B
(* CHRONIC)
THE INFORMATION HEREIN IS GIVEN IN GOOD FAITH, BUT NO WARRANTY EXPRESSED OR
IMPLIED IS MADE. ROBERTS URGES USERS OF THIS PRODUCT TO EVALUATE ITS
SUITABILITY AND COMPLIANCE WITH LOCAL REGULATIONS AS ROBERTS CANNOT FORESEE
THE FINAL USE OF THE PRODUCT, NOR THE FINAL LOCATION OF USAGE
DATE OF ISSUE: MAY 12, 2017