| Common Name: | E-WELD PLASMA |
| Manufacturer: | WALTER SURFACE TECHNOLOGIES |
| SDS Revision Date: | 1/15/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 444A35 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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CONFORMS TO HAZCOM 2012/UNITED STATES
W
WALTER
SURFACE TECHNOLOGIES
SAFETY DATA SHEET
E-WELD PLASMA
| SECTION 1. IDENTIFICATION |  |
GHS PRODUCT IDENTIFIER: E-WELD PLASMA
PRODUCT CODE: 53F605 (10 KG)
SDS NO.: L-142E
PRODUCT TYPE: LIQUID.
IDENTIFIED USES: LONG LASTING ANTI-SPATTER SOLUTION.
MANUFACTURER:
WALTER SURFACE TECHNOLOGIES INC.
810 DAY HILL ROAD
WINDSOR, CT 06095
UNITED STATES
GENERAL INFORMATION: 18665925837
INFO.US@WALTER.COM
WWW.WALTER.COM
EMERGENCY TELEPHONE NUMBER (WITH HOURS OF OPERATION):
INFOTRAC(R*): 1-800-535-5053
OUTSIDE U.S.A. CALL COLLECT: 1-352-323-3500 24 HOURS/DAY, 7 DAYS/WEEK.
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
AQUATIC HAZARD (ACUTE): CATEGORY 2
AQUATIC HAZARD (LONG-TERM): CATEGORY 3
GHS LABEL ELEMENTS:
SIGNAL WORD: NO SIGNAL WORD.
HAZARD STATEMENTS:
H401: TOXIC TO AQUATIC LIFE.
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENTS:
PREVENTION:
P273: AVOID RELEASE TO THE ENVIRONMENT.
RESPONSE: NOT APPLICABLE.
STORAGE: NOT APPLICABLE.
DISPOSAL:
P501:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
HAZARDS NOT OTHERWISE CLASSIFIED: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
PRODUCT CODE: 53F605 (10 KG)
CAS NUMBER/OTHER IDENTIFIERS:
CAS NUMBER: NOT APPLICABLE.
INGREDIENT NAME % CAS NUMBER
BARIUM SULFATE 5 - 10 7727-43-7
TITANIUM DIOXIDE 1 - 5 13463-67-7
2-BUTOXYETHANOL 1 - 5 111-76-2
TRIZINC BIS(ORTHOPHOSPHATE) 1 - 5 7779-90-0
ZINC OXIDE <0.1 1314-13-2
1,2-BENZISOTHIAZOL-3(2H)-ONE <0.1 2634-33-5
SINCE THE CARCINOGENIC INGREDIENTS IN THIS COMPOUND ARE IN A PASTE, THE
RISK OF EXPOSURE BY INHALATION IS MINIMAL, THIS IS WHY THE RELATED HAZARD
STATEMENTS ARE NOT SHOWN IN THIS SDS.
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS DUE
TO BATCH VARIATION.
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH OR THE ENVIRONMENT AND HENCE REQUIRE
REPORTING IN THIS SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE
UPPER AND LOWER EYELIDS. CONTINUE TO RINSE FOR AT LEAST 20 MINUTES. GET
MEDICAL ATTENTION.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF NOT BREATHING, IF BREATHING IS IRREGULAR OR IF RESPIRATORY
ARREST OCCURS, PROVIDE ARTIFICIAL RESPIRATION OR OXYGEN BY TRAINED
PERSONNEL. IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE
MOUTH-TO-MOUTH RESUSCITATION. GET MEDICAL ATTENTION. IF UNCONSCIOUS, PLACE
IN RECOVERY POSITION AND GET MEDICAL ATTENTION IMMEDIATELY.
SKIN CONTACT:
FLUSH CONTAMINATED SKIN WITH PLENTY OF WATER. GET MEDICAL ATTENTION IF
SYMPTOMS OCCUR. WASH CLOTHING BEFORE REUSE. CLEAN SHOES THOROUGHLY BEFORE
REUSE.
INGESTION:
WASH OUT MOUTH WITH WATER. REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN
A POSITION COMFORTABLE FOR BREATHING. IF MATERIAL HAS BEEN SWALLOWED AND
THE EXPOSED PERSON IS CONSCIOUS, GIVE SMALL QUANTITIES OF WATER TO DRINK.
STOP IF THE EXPOSED PERSON FEELS SICK AS VOMITING MAY BE DANGEROUS. DO NOT
INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL. GET MEDICAL
ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF
UNCONSCIOUS, PLACE IN RECOVERY POSITION AND GET MEDICAL ATTENTION
IMMEDIATELY.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED,
IF NECESSARY:
NOTES TO PHYSICIAN:
IN CASE OF INHALATION OF DECOMPOSITION PRODUCTS IN A FIRE, SYMPTOMS MAY
BE DELAYED. THE EXPOSED PERSON MAY NEED TO BE KEPT UNDER MEDICAL
SURVEILLANCE FOR 48 HOURS.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE
MOUTH-TO-MOUTH RESUSCITATION.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE, USE FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
THIS MATERIAL IS TOXIC TO AQUATIC LIFE. THIS MATERIAL IS HARMFUL TO
AQUATIC LIFE WITH LONG LASTING EFFECTS. FIRE WATER CONTAMINATED WITH THIS
MATERIAL MUST BE CONTAINED AND PREVENTED FROM BEING DISCHARGED TO ANY
WATERWAY, SEWER OR DRAIN.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON DIOXIDE
CARBON MONOXIDE
NITROGEN OXIDES
SULFUR OXIDES
PHOSPHORUS OXIDES
METAL OXIDE/OXIDES
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL MEASURES ARE REQUIRED.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE
OPERATED IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. KEEP UNNECESSARY AND UNPROTECTED PERSONNEL FROM ENTERING. DO NOT
TOUCH OR WALK THROUGH SPILLED MATERIAL. AVOID BREATHING VAPOR OR MIST.
PROVIDE ADEQUATE VENTILATION. WEAR APPROPRIATE RESPIRATOR WHEN VENTILATION
IS INADEQUATE. PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALIZED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE
OF ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE
ALSO THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL OR
AIR). WATER POLLUTING MATERIAL. MAY BE HARMFUL TO THE ENVIRONMENT IF
RELEASED IN LARGE QUANTITIES.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. DILUTE WITH
WATER AND MOP UP IF WATER-SOLUBLE. ALTERNATIVELY, OR IF WATER-INSOLUBLE,
ABSORB WITH AN INERT DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE
DISPOSAL CONTAINER. DISPOSE OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
LARGE SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. APPROACH
RELEASE FROM UPWIND. PREVENT ENTRY INTO SEWERS, WATER COURSES, BASEMENTS
OR CONFINED AREAS. WASH SPILLAGES INTO AN EFFLUENT TREATMENT PLANT OR
PROCEED AS FOLLOWS. CONTAIN AND COLLECT SPILLAGE WITH NON-COMBUSTIBLE,
ABSORBENT MATERIAL E.G. SAND, EARTH, VERMICULITE OR DIATOMACEOUS EARTH
AND PLACE IN CONTAINER FOR DISPOSAL ACCORDING TO LOCAL REGULATIONS
(SEE SECTION 13). DISPOSE OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
CONTAMINATED ABSORBENT MATERIAL MAY POSE THE SAME HAZARD AS THE SPILLED
PRODUCT.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). DO NOT
INGEST. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID BREATHING VAPOR
OR MIST. AVOID RELEASE TO THE ENVIRONMENT. KEEP IN THE ORIGINAL CONTAINER
OR AN APPROVED ALTERNATIVE MADE FROM A COMPATIBLE MATERIAL, KEPT TIGHTLY
CLOSED WHEN NOT IN USE. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE AND CAN
BE HAZARDOUS. DO NOT REUSE CONTAINER.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. SEE ALSO SECTION 8 FOR ADDITIONAL
INFORMATION ON HYGIENE MEASURES. REMOVE CONTAMINATED CLOTHING AND
PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE IN ORIGINAL CONTAINER
PROTECTED FROM DIRECT SUNLIGHT IN A DRY, COOL AND WELL-VENTILATED AREA,
AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10) AND FOOD AND DRINK. KEEP
CONTAINER TIGHTLY CLOSED AND SEALED UNTIL READY FOR USE. CONTAINERS THAT
HAVE BEEN OPENED MUST BE CAREFULLY RESEALED AND KEPT UPRIGHT TO PREVENT
LEAKAGE. DO NOT STORE IN UNLABELED CONTAINERS. USE APPROPRIATE CONTAINMENT
TO AVOID ENVIRONMENTAL CONTAMINATION.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT NAME EXPOSURE LIMITS
BARIUM SULFATE ACGIH TLV (UNITED STATES, 3/2016).
TWA: 5 MG/M3 8 HOURS.
FORM: INHALABLE FRACTION
NIOSH REL (UNITED STATES, 10/2013).
TWA: 5 MG/M3 10 HOURS.
FORM: RESPIRABLE FRACTION
TWA: 10 MG/M3 10 HOURS.
FORM: TOTAL
OSHA PEL (UNITED STATES, 6/2016).
TWA: 5 MG/M3 8 HOURS.
FORM: RESPIRABLE FRACTION
TWA: 15 MG/M3 8 HOURS.
FORM: TOTAL DUST
TITANIUM DIOXIDE ACGIH TLV (UNITED STATES, 3/2016).
TWA: 10 MG/M3 8 HOURS.
OSHA PEL (UNITED STATES, 6/2016).
TWA: 15 MG/M3 8 HOURS.
FORM: TOTAL DUST
2-BUTOXYETHANOL ACGIH TLV (UNITED STATES, 3/2016).
TWA: 20 PPM 8 HOURS.
NIOSH REL (UNITED STATES, 10/2013).
ABSORBED THROUGH SKIN.
TWA: 5 PPM 10 HOURS.
TWA: 24 MG/M3 10 HOURS.
OSHA PEL (UNITED STATES, 6/2016).
ABSORBED THROUGH SKIN.
TWA: 50 PPM 8 HOURS.
TWA: 240 MG/M3 8 HOURS.
ZINC OXIDE NIOSH REL (UNITED STATES, 10/2013).
CEIL: 15 MG/M3
FORM: DUST
TWA: 5 MG/M3 10 HOURS.
FORM: DUST AND FUMES
STEL: 10 MG/M3 15 MINUTES.
FORM: FERTILIZER AND/OR INDUSTRIAL USE.
OSHA PEL (UNITED STATES, 6/2016).
TWA: 5 MG/M3 8 HOURS.
FORM: FERTILIZER AND/OR INDUSTRIAL USE.
TWA: 5 MG/M3 8 HOURS.
FORM: RESPIRABLE FRACTION
TWA: 15 MG/M3 8 HOURS.
FORM: TOTAL DUST
ACGIH TLV (UNITED STATES, 3/2016).
TWA: 2 MG/M3 8 HOURS.
FORM: RESPIRABLE FRACTION
STEL: 10 MG/M3 15 MINUTES.
FORM: RESPIRABLE FRACTION
APPROPRIATE ENGINEERING CONTROLS:
NO PERSONAL RESPIRATORY PROTECTIVE EQUIPMENT NORMALLY REQUIRED. AVOID
BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY. WHEN WORKERS ARE FACING
CONCENTRATIONS ABOVE THE EXPOSURE LIMIT THEY MUST USE APPROPRIATE
CERTIFIED RESPIRATORS.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED
TO ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING.
EYE/FACE PROTECTION:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN A
RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO LIQUID
SPLASHES, MISTS, GASES OR DUSTS. IF CONTACT IS POSSIBLE, THE FOLLOWING
PROTECTION SHOULD BE WORN, UNLESS THE ASSESSMENT INDICATES A HIGHER DEGREE
OF PROTECTION: FACE SHIELD
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY. CONSIDERING THE PARAMETERS
SPECIFIED BY THE GLOVE MANUFACTURER, CHECK DURING USE THAT THE GLOVES ARE
STILL RETAINING THEIR PROTECTIVE PROPERTIES. IT SHOULD BE NOTED THAT THE
TIME TO BREAKTHROUGH FOR ANY GLOVE MATERIAL MAY BE DIFFERENT FOR DIFFERENT
GLOVE MANUFACTURERS. IN THE CASE OF MIXTURES, CONSISTING OF SEVERAL
SUBSTANCES, THE PROTECTION TIME OF THE GLOVES CANNOT BE ACCURATELY
ESTIMATED.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON
THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED
BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD
BE SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
USE A NIOSH/MSHA APPROVED RESPIRATOR IF THERE IS A RISK OF EXPOSURE
AT LEVELS EXCEEDING THE EXPOSURE LIMITS. ADVICE SHOULD BE SOUGHT FROM
RESPIRATORY PROTECTION SPECIALISTS.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
COLOR: WHITE.
ODOR: CHARACTERISTIC.
ODOR THRESHOLD: NOT AVAILABLE.
PH: 7 TO 8
MELTING POINT: NOT AVAILABLE.
BOILING POINT: 100 DEG. C (212 DEG. F)
FLASH POINT: NOT AVAILABLE.
EVAPORATION RATE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
VAPOR DENSITY: NOT AVAILABLE.
DENSITY: 1.65 G/ML @ 20 DEG. C (68 DEG. F)
SOLUBILITY: NOT AVAILABLE.
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY:
DYNAMIC (@ 20 DEG. C (68 DEG. F)): 300 MPA S (300 CP)
VOC CONTENT: 2.9% (W/W)
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NO SPECIFIC TEST DATA RELATED TO REACTIVITY AVAILABLE FOR THIS PRODUCT OR
ITS INGREDIENTS.
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID: NO SPECIFIC DATA.
INCOMPATIBLE MATERIALS:
REACTIVE OR INCOMPATIBLE WITH THE FOLLOWING MATERIALS: OXIDIZING MATERIALS.
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES DOSE EXPOSURE
NAME
2-BUTOXYETHANOL LC50 INHALATION GAS. RAT 450 PPM 4 HOURS
LD50 DERMAL RABBIT 220 MG/KG
LD50 ORAL RAT 250 MG/KG
1,2-BENZISOTHIAZOL- LD50 ORAL RAT 1020 MG/KG
3(2H)-ONE
IRRITATION/CORROSION:
PRODUCT/ RESULT SPECIES SCORE EXPOSURE OBSERVATION
INGREDIENT
NAME
2-BUTOXYETHANOL EYES: RABBIT 24 HOURS
MODERATE 100 MG
IRRITANT
EYES: RABBIT 100 MG
SEVERE
IRRITANT
SKIN: RABBIT 500 MG
MILD IRRITANT
1,2-BENZISOTHIAZOL- SKIN: HUMAN 48 HOURS
3(2H)-ONE MILD IRRITANT 5%
SENSITIZATION: THERE IS NO DATA AVAILABLE.
CARCINOGENICITY:
CLASSIFICATION:
PRODUCT/INGREDIENT NAME OSHA IARC NTP ACGIH EPA NIOSH
ALUMINIUM HYDROXIDE A4
TALC, NOT CONTAINING ASBESTIFORM 3 A4
FIBRES
TITANIUM DIOXIDE 2B A4 +
2-BUTOXYETHANOL 3 A3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
THERE IS NO DATA AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE):
THERE IS NO DATA AVAILABLE.
ASPIRATION HAZARD: THERE IS NO DATA AVAILABLE.
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE:
DERMAL CONTACT. EYE CONTACT. INHALATION. INGESTION.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND
LONG TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS:
NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
POTENTIAL DELAYED EFFECTS:
NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS:
NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
POTENTIAL DELAYED EFFECTS:
NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
POTENTIAL CHRONIC HEALTH EFFECTS:
GENERAL: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
CARCINOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY ESTIMATES:
ROUTE ATE VALUE
ORAL 16666.7 MG/KG
DERMAL 36666.7 MG/KG
INHALATION (GASES) 150000 PPM
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES EXPOSURE
NAME
BARIUM SULFATE ACUTE EC50: CRUSTACEANS - CYPRIS 48 HOURS
634 MG/L SUBGLOBOSA
FRESH WATER
ACUTE EC50: DAPHNIA - DAPHNIA 48 HOURS
32000 (MICRO)G/L MAGNA
FRESH WATER
TITANIUM DIOXIDE ACUTE LC50: CRUSTACEANS - 48 HOURS
3 MG/L CERIODAPHNIA
FRESH WATER DUBIA - NEONATE
ACUTE LC50: DAPHNIA - DAPHNIA 48 HOURS
6.5 MG/L PULEX - NEONATE
FRESH WATER
ACUTE LC50: FISH - FUNDULUS 96 HOURS
>1000000 (MICRO)G/L HETEROCLITUS
MARINE WATER
2-BUTOXYETHANOL ACUTE EC50: DAPHNIA - DAPHNIA 48 HOURS
>1000 MG/L MAGNA
FRESH WATER
ACUTE LC50: CRUSTACEANS - CRANGON 48 HOURS
800000 (MICRO)G/L CRANGON
MARINE WATER
ACUTE LC50: FISH - MENIDIA 96 HOURS
1250000 (MICRO)G/L BERYLLINA
MARINE WATER
TRIZINC BIS ACUTE LC50: FISH - ONCORHYNCHUS 96 HOURS
(ORTHOPHOSPHATE) 90 (MICRO)G/L MYKISS
FRESH WATER
ZINC OXIDE ACUTE IC50: ALGAE - SKELETONEMA 96 HOURS
1.85 MG/L COSTATUM
MARINE WATER
ACUTE IC50: ALGAE - 72 HOURS
46 (MICRO)G/L PSEUDOKIRCHNERIELLA
FRESH WATER SUBCAPITATA -
EXPONENTIAL GROWTH
PHASE
ACUTE LC50: DAPHNIA - DAPHNIA 48 HOURS
98 (MICRO)G/L MAGNA - NEONATE
FRESH WATER
ACUTE LC50: FISH - ONCORHYNCHUS 96 HOURS
1.1 PPM MYKISS
FRESH WATER
1,2-BENZISOTHIAZOL- ACUTE EC50: DAPHNIA - DAPHNIA 48 HOURS
3(2H)-ONE 97 PPB MAGNA
FRESH WATER
ACUTE LC50: CRUSTACEANS - 48 HOURS
10 TO 20 MG/L CERIODAPHNIA DUBIA
FRESH WATER
ACUTE LC50: FISH - ONCORHYNCHUS 96 HOURS
167 PPB MYKISS
FRESH WATER
PERSISTENCE AND DEGRADABILITY: THERE IS NO DATA AVAILABLE.
BIOACCUMULATIVE POTENTIAL:
PRODUCT/INGREDIENT NAME LOGPOW BCF POTENTIAL
2-BUTOXYETHANOL 0.81 LOW
TRIZINC BIS(ORTHOPHOSPHATE) 60960 HIGH
ZINC OXIDE 60960 HIGH
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE.
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD COMPLY
WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE DISPOSAL
LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE OF
SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL
CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE SEWER UNLESS
FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH JURISDICTION.
WASTE PACKAGING SHOULD BE RECYCLED. INCINERATION OR LANDFILL SHOULD ONLY
BE CONSIDERED WHEN RECYCLING IS NOT FEASIBLE. THIS MATERIAL AND ITS
CONTAINER MUST BE DISPOSED OF IN A SAFE WAY. CARE SHOULD BE TAKEN WHEN
HANDLING EMPTY CONTAINERS THAT HAVE NOT BEEN CLEANED OR RINSED OUT. EMPTY
CONTAINERS OR LINERS MAY RETAIN SOME PRODUCT RESIDUES. AVOID DISPERSAL OF
SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL, WATERWAYS, DRAINS AND
SEWERS.
| SECTION 14. TRANSPORT INFORMATION | |
DOT CLASSIFICATION IMDG IATA
UN NUMBER NOT REGULATED. NOT REGULATED. NOT REGULATED.
UN PROPER SHIPPING
NAME
TRANSPORT HAZARD
CLASS(ES)
PACKING GROUP
ENVIRONMENTAL NO. NO. NO.
HAZARDS
ADDITIONAL
INFORMATION
AERG: NOT APPLICABLE.
SPECIAL PRECAUTIONS FOR USER:
TRANSPORT WITHIN USER'S PREMISES:
ALWAYS TRANSPORT IN CLOSED CONTAINERS THAT ARE UPRIGHT AND SECURE. ENSURE
THAT PERSONS TRANSPORTING THE PRODUCT KNOW WHAT TO DO IN THE EVENT OF AN
ACCIDENT OR SPILLAGE. PROTECT FROM FREEZING. FREEZING WILL DAMAGE PRODUCT
AND RENDER IT UNUSABLE.
| SECTION 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
TSCA 8(A) PAIR: TRIS(2-ETHYLHEXYL) PHOSPHATE
TSCA 8(C) CALLS FOR RECORD OF SAR: TRIS(2-ETHYLHEXYL) PHOSPHATE
UNITED STATES INVENTORY (TSCA 8B): ALL COMPONENTS ARE LISTED OR EXEMPTED.
CLEAN WATER ACT (CWA) 307: ZINC OXIDE; TRIZINC BIS(ORTHOPHOSPHATE)
CLEAN AIR ACT SECTION 112 (B) HAZARDOUS AIR POLLUTANTS (HAPS): NOT LISTED
CLEAN AIR ACT SECTION 602 CLASS I SUBSTANCES: NOT LISTED
CLEAN AIR ACT SECTION 602 CLASS II SUBSTANCES: NOT LISTED
DEA LIST I CHEMICALS (PRECURSOR CHEMICALS): NOT LISTED
DEA LIST II CHEMICALS (ESSENTIAL CHEMICALS): NOT LISTED
SARA 302/304:
COMPOSITION/INFORMATION ON INGREDIENTS: NO PRODUCTS WERE FOUND.
SARA 304 RQ: NOT APPLICABLE.
SARA 311/312:
CLASSIFICATION: NOT APPLICABLE.
COMPOSITION/INFORMATION ON INGREDIENTS:
NAME % FIRE SUDDEN REACTIVE IMMEDIATE DELAYED
HAZARD RELEASE OF (ACUTE) (CHRONIC)
PRESSURE HEALTH HEALTH
HAZARD HAZARD
TITANIUM DIOXIDE 1 - 5 NO. NO. NO. NO. YES.
2-BUTOXYETHANOL 1 - 5 YES. NO. NO. YES. NO.
1,2- <0.1 NO. NO. NO. YES. NO.
BENZISOTHIAZOL-
3(2H)-ONE
SARA 313:
PRODUCT NAME CAS NUMBER %
FORM R - REPORTING REQUIREMENTS:
2-BUTOXYETHANOL 111-76-2 1 - 5
TRIZINC BIS(ORTHOPHOSPHATE) 7779-90-0 1 - 5
SUPPLIER NOTIFICATION:
2-BUTOXYETHANOL 111-76-2 1 - 5
TRIZINC BIS(ORTHOPHOSPHATE) 7779-90-0 1 - 5
SARA 313 NOTIFICATIONS MUST NOT BE DETACHED FROM THE SDS AND ANY COPYING
AND REDISTRIBUTION OF THE SDS SHALL INCLUDE COPYING AND REDISTRIBUTION OF
THE NOTICE ATTACHED TO COPIES OF THE SDS SUBSEQUENTLY REDISTRIBUTED.
STATE REGULATIONS:
MASSACHUSETTS:
THE FOLLOWING COMPONENTS ARE LISTED:
2-BUTOXYETHANOL; TITANIUM DIOXIDE; BARIUM SULFATE; LIMESTONE;
TALC, NOT CONTAINING ASBESTIFORM FIBRES
NEW YORK: NONE OF THE COMPONENTS ARE LISTED.
NEW JERSEY:
THE FOLLOWING COMPONENTS ARE LISTED:
2-BUTOXYETHANOL; TITANIUM DIOXIDE; TRIZINC BIS(ORTHOPHOSPHATE);
BARIUM SULFATE; LIMESTONE; TALC, NOT CONTAINING ASBESTIFORM FIBRES
PENNSYLVANIA:
THE FOLLOWING COMPONENTS ARE LISTED:
2-BUTOXYETHANOL; TITANIUM DIOXIDE; TRIZINC BIS(ORTHOPHOSPHATE);
BARIUM SULFATE; LIMESTONE; TALC, NOT CONTAINING ASBESTIFORM FIBRES
CALIFORNIA PROP. 65:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
INGREDIENT NAME CANCER REPRODUCTIVE NO SIGNIFICANT MAXIMUM ACCEPTABLE
RISK LEVEL DOSAGE LEVEL
TITANIUM DIOXIDE YES. NO. NO. NO.
SINCE THE CARCINOGENIC INGREDIENTS IN THIS COMPOUND ARE IN A PASTE, THE
RISK OF EXPOSURE BY INHALATION IS MINIMAL.
INTERNATIONAL LISTS:
NATIONAL INVENTORY:
AUSTRALIA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
CANADA:
AT LEAST ONE COMPONENT IS NOT LISTED IN DSL BUT ALL SUCH COMPONENTS ARE
LISTED IN NDSL.
CHINA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
TAIWAN: ALL COMPONENTS ARE LISTED OR EXEMPTED.
| SECTION 16. OTHER INFORMATION | |
HISTORY:
DATE OF ISSUE MM/DD/YYYY: 01/15/2017
VERSION: 1
PREPARED BY: KMK REGULATORY SERVICES INC.
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS, 1973
AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
UN: UNITED NATIONS
NOTICE TO READER:
TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS ACCURATE.
HOWEVER, NEITHER THE ABOVE-NAMED SUPPLIER, NOR ANY OF ITS SUBSIDIARIES,
ASSUMES ANY LIABILITY WHATSOEVER FOR THE ACCURACY OR COMPLETENESS OF THE
INFORMATION CONTAINED HEREIN.
FINAL DETERMINATION OF SUITABILITY OF ANY MATERIAL IS THE SOLE
RESPONSIBILITY OF THE USER. ALL MATERIALS MAY PRESENT UNKNOWN HAZARDS AND
SHOULD BE USED WITH CAUTION. ALTHOUGH CERTAIN HAZARDS ARE DESCRIBED
HEREIN, WE CANNOT GUARANTEE THAT THESE ARE THE ONLY HAZARDS THAT EXIST.
KMK
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