| Common Name: | TOUCH N SEAL GUN FOAM II FIRE BLOCKING FOAM (ORANGE) |
| Manufacturer: | CONVENIENCE PRODUCTS |
| SDS Revision Date: | 4/30/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 444A73 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
CP
CONVENIENCE PRODUCTS
SAFETY DATA SHEET
ACCORDING TO 1907/2006/EC (REACH), 1272/2008/EC (CLP), AND GHS
PRINTING DATE: 30.04.2014
REVISION: 30.04.2014
| 1 IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1 PRODUCT IDENTIFIER:
TRADE NAME: TOUCH N SEAL GUN FOAM II FIRE BLOCKING FOAM (ORANGE)
ARTICLE NUMBER: EHS 9450
1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
APPLICATION OF THE SUBSTANCE / THE MIXTURE: SEALANT
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER/SUPPLIER:
CONVENIENCE PRODUCTS, DIVISION OF CLAYTON CORP.
866 HORAN DRIVE
FENTON, MO 63026-2416
PHONE: 636-349-5855
1.4 EMERGENCY TELEPHONE NUMBER:
CHEMTEL INC.
(800)255-3924
+1 (813)248-0585
| 2 HAZARDS IDENTIFICATION | |
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLASSIFICATION ACCORDING TO REGULATION (EC) NO 1272/2008:
THE FOLLOWING HAZARD STATEMENTS ARE APPLICABLE ONLY TO THE EU REGULATIONS
AND NOT THE US GHS REGULATION: H222-H229.
THE FOLLOWING HAZARD STATEMENTS ARE APPLICABLE ONLY TO THE GENERAL GHS
REGULATIONS AND NOT THE SPECIFIC CLP REGULATION: H222.
H222: EXTREMELY FLAMMABLE AEROSOL.
FLAME
FLAM. AEROSOL 1:
H222-H229: EXTREMELY FLAMMABLE AEROSOL.
PRESSURISED CONTAINER: MAY BURST IF HEATED.
HEALTH HAZARD
RESP. SENS. 1:
H334:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
STOT RE 2:
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
EXCLAMATION MARK
ACUTE TOX. 4:
H332: HARMFUL IF INHALED.
SKIN IRRIT. 2:
H315: CAUSES SKIN IRRITATION.
EYE IRRIT. 2:
H319: CAUSES SERIOUS EYE IRRITATION.
SKIN SENS. 1:
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
STOT SE 3:
H335: MAY CAUSE RESPIRATORY IRRITATION.
CLASSIFICATION ACCORDING TO DIRECTIVE 67/548/EEC OR DIRECTIVE 1999/45/EC:
XN; HARMFUL
R20: HARMFUL BY INHALATION.
XN; SENSITISING:
R42/43: MAY CAUSE SENSITISATION BY INHALATION AND SKIN CONTACT.
XI; IRRITANT:
R36/37/38: IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
F+; EXTREMELY FLAMMABLE
R12: EXTREMELY FLAMMABLE.
INFORMATION CONCERNING PARTICULAR HAZARDS FOR HUMAN AND ENVIRONMENT:
THE PRODUCT HAS TO BE LABELLED DUE TO THE CALCULATION PROCEDURE OF THE
"GENERAL CLASSIFICATION GUIDELINE FOR PREPARATIONS OF THE EU" IN THE
LATEST VALID VERSION.
WARNING!
PRESSURIZED CONTAINER.
CLASSIFICATION SYSTEM:
THE CLASSIFICATION IS ACCORDING TO THE LATEST EDITIONS OF THE EU-LISTS,
AND EXTENDED BY COMPANY AND LITERATURE DATA.
THE CLASSIFICATION IS IN ACCORDANCE WITH THE LATEST EDITIONS OF
INTERNATIONAL SUBSTANCES LISTS, AND IS SUPPLEMENTED BY INFORMATION
FROM TECHNICAL LITERATURE AND BY INFORMATION PROVIDED BY THE COMPANY.
2.2 LABEL ELEMENTS:
LABELLING ACCORDING TO REGULATION (EC) NO 1272/2008:
THE FOLLOWING HAZARD STATEMENTS ARE APPLICABLE ONLY TO THE EU REGULATIONS
AND NOT THE US GHS REGULATION: H222-H229.
THE FOLLOWING HAZARD STATEMENTS ARE APPLICABLE ONLY TO THE GENERAL GHS
REGULATIONS AND NOT THE SPECIFIC CLP REGULATION: H222.
THE PRODUCT IS CLASSIFIED AND LABELLED ACCORDING TO THE CLP REGULATION.
HAZARD PICTOGRAMS:
GHS02: FLAME
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
SIGNAL WORD: DANGER
HAZARD-DETERMINING COMPONENTS OF LABELLING:
DIPHENYLMETHANEDIISOCYANATE,ISOMERES AND HOMOLOGUES
4,4'-METHYLENEDIPHENYL DIISOCYANATE
HAZARD STATEMENTS:
H222: EXTREMELY FLAMMABLE AEROSOL.
H222-H229:
EXTREMELY FLAMMABLE AEROSOL. PRESSURISED CONTAINER: MAY BURST IF HEATED.
H332: HARMFUL IF INHALED.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H334:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H335: MAY CAUSE RESPIRATORY IRRITATION.
H373; MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
PRECAUTIONARY STATEMENTS:
P210: KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
P251:
PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE.
P211: DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
P280: WEAR PROTECTIVE GLOVES / EYE PROTECTION.
P260: DO NOT BREATHE MIST/VAPOURS/SPRAY.
P314: GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
P342+P311:
IF EXPERIENCING RESPIRATORY SYMPTOMS: CALL A POISON CENTER/DOCTOR.
P410+P412:
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C/122 DEG. F.
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL/
INTERNATIONAL REGULATIONS.
ADDITIONAL INFORMATION:
CONTAINS ISOCYANATES. MAY PRODUCE AN ALLERGIC REACTION.
PRESSURIZED CONTAINER: PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO
TEMPERATURES EXCEEDING 50 DEG. C. DO NOT PIERCE OR BURN, EVEN AFTER USE.
DO NOT SPRAY ON A NAKED FLAME OR ANY INCANDESCENT MATERIAL. KEEP AWAY FROM
SOURCES OF IGNITION - NO SMOKING.
BUILDUP OF EXPLOSIVE MIXTURES POSSIBLE WITHOUT SUFFICIENT VENTILATION.
HAZARD DESCRIPTION:
WHMIS-SYMBOLS:
A - COMPRESSED GAS
B5 - FLAMMABLE AEROSOL
D2A - VERY TOXIC MATERIAL CAUSING OTHER TOXIC EFFECTS
NFPA RATINGS (SCALE 0 - 4):
HEALTH 2
FIRE 4
REACTIVITY 1
HMIS-RATINGS (SCALE 0 - 4):
HEALTH 2*
FIRE 4
REACTIVITY 1
* - INDICATES A LONG TERM HEALTH HAZARD FROM REPEATED OR PROLONGED
EXPOSURES.
HMIS LONG TERM HEALTH HAZARD SUBSTANCES:
9016-87-9 DIPHENYLMETHANEDIISOCYANATE,ISOMERES AND HOMOLOGUES
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE
2.3 OTHER HAZARDS:
RESULTS OF PBT AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE.
VPVB: NOT APPLICABLE.
| 3 COMPOSITION/INFORMATION ON INGREDIENTS | |
3.2 MIXTURES:
DESCRIPTION:
MIXTURE OF SUBSTANCES LISTED BELOW WITH NONHAZARDOUS ADDITIONS.
DANGEROUS COMPONENTS:
CAS: 9016-87-9 DIPHENYLMETHANEDIISOCYANATE, 20-40%
ISOMERES AND HOMOLOGUES
XN R20; XN R42/43;
XI R36/37/38
CARC. CAT. 3
RESP. SENS. 1, H334;
STOT RE 2, H373
ACUTE TOX. 4, H332;
SKIN IRRIT. 2,
H315; EYE IRRIT. 2,
H319; SKIN SENS. 1,
H317; STOT SE 3, H335
CAS: 101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE 10-20%
EINECS: 202-966-0 XN R20; XN R42/43; XI R36/37/38
INDEX NUMBER: 615-005-00-9 CARC. CAT. 3
RESP. SENS. 1, H334; STOT RE 2, H373
ACUTE TOX. 4, H332; SKIN IRRIT. 2,
H315; EYE IRRIT. 2, H319; SKIN
SENS. 1, H317; STOT SE 3, H335
CAS: 13674-84-5 TRIS(2-CHLORISOPROPYL)-PHOSPHATE 5-10%
R52/53
AQUATIC CHRONIC 3, H412
CAS: 115-10-6 DIMETHYL ETHER 5-10%
EINECS: 204-065-8 F+ R12
INDEX NUMBER: 603-019-00-8
FLAM. GAS 1, H220
PRESS. GAS, H280
CAS: 72-28-5 ISOBUTANE 1-5%
F+ R12
FLAM. GAS 1, H220
CAS: 74-98-6 PROPANE 1-5%
EINECS: 200-827-9 F+ R12
INDEX NUMBER: 601-003-00-5
FLAM. GAS 1, H220
PRESS. GAS, H280
ADDITIONAL INFORMATION: FOR THE WORDING OF THE LISTED RISK PHRASES REFER
TO SECTION 16.
| 4 FIRST AID MEASURES | |
4.1 DESCRIPTION OF FIRST AID MEASURES:
GENERAL INFORMATION:
IMMEDIATELY REMOVE ANY CLOTHING SOILED BY THE PRODUCT.
SYMPTOMS OF POISONING MAY EVEN OCCUR AFTER SEVERAL HOURS; THEREFORE MEDICAL
OBSERVATION FOR AT LEAST 48 HOURS AFTER THE ACCIDENT.
TAKE AFFECTED PERSONS OUT INTO THE FRESH AIR.
AFTER INHALATION:
SUPPLY FRESH AIR; CONSULT DOCTOR IN CASE OF COMPLAINTS.
PROVIDE OXYGEN TREATMENT IF AFFECTED PERSON HAS DIFFICULTY BREATHING.
IN CASE OF UNCONSCIOUSNESS PLACE PATIENT STABLY IN SIDE POSITION FOR
TRANSPORTATION.
AFTER SKIN CONTACT:
IMMEDIATELY WASH WITH WATER AND SOAP AND RINSE THOROUGHLY.
DO NOT PULL SOLIDIFIED PRODUCT OFF THE SKIN.
IF SKIN IRRITATION CONTINUES, CONSULT A DOCTOR.
AFTER EYE CONTACT:
IMMEDIATELY REMOVE CONTACT LENSES IF POSSIBLE.
RINSE OPENED EYE FOR SEVERAL MINUTES UNDER RUNNING WATER. THEN CONSULT
A DOCTOR.
AFTER SWALLOWING:
RINSE OUT MOUTH AND THEN DRINK PLENTY OF WATER.
DO NOT INDUCE VOMITING; CALL FOR MEDICAL HELP IMMEDIATELY.
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
ASTHMA ATTACKS
HEADACHE
BREATHING DIFFICULTY
ALLERGIC REACTIONS
COUGHING
NAUSEA
GASTRIC OR INTESTINAL DISORDERS WHEN INGESTED.
IRRITANT TO SKIN AND MUCOUS MEMBRANES.
IRRITANT TO EYES.
DIZZINESS
DISORIENTATION
HAZARDS:
DANGER OF IMPAIRED BREATHING.
DANGER OF DISTURBED CARDIAC RHYTHM.
DANGER OF PULMONARY OEDEMA.
DANGER OF PNEUMONIA.
DANGER OF CONVULSION.
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
SEVERE ALLERGIC SKIN REACTION, BRONCHIAL SPASMS AND ANAPHYLACTIC SHOCK
ARE POSSIBLE.
TREAT SKIN AND MUCOUS MEMBRANE WITH ANTIHISTAMINE AND CORTICOID
PREPARATIONS.
IN CASES OF IRRITATION TO THE LUNGS, INITIAL TREATMENT WITH CORTICAL
STEROID INHALANTS.
MONITOR CIRCULATION.
IF NECESSARY OXYGEN RESPIRATION TREATMENT.
MEDICAL SUPERVISION FOR AT LEAST 48 HOURS.
CONTAINS ISOCYANATES. MAY PRODUCE AN ALLERGIC REACTION.
| 5 FIREFIGHTING MEASURES | |
5.1 EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING AGENTS:
CO2, POWDER OR WATER SPRAY. FIGHT LARGER FIRES WITH WATER SPRAY OR ALCOHOL
RESISTANT FOAM.
WATER IN FLOODING QUANTITIES.
FOR SAFETY REASONS UNSUITABLE EXTINGUISHING AGENTS: NONE.
5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
DANGER OF RECEPTACLES BURSTING BECAUSE OF HIGH VAPOUR PRESSURE WHEN HEATED.
DURING HEATING OR IN CASE OF FIRE POISONOUS GASES ARE PRODUCED.
5.3 ADVICE FOR FIREFIGHTERS:
PROTECTIVE EQUIPMENT:
WEAR SELF-CONTAINED RESPIRATORY PROTECTIVE DEVICE.
WEAR FULLY PROTECTIVE SUIT.
ADDITIONAL INFORMATION:
LEAKING GAS FIRE: DO NOT EXTINGUISH, UNLESS LEAK CAN BE STOPPED SAFELY.
ELIMINATE ALL IGNITION SOURCES IF SAFE TO DO SO.
COOL ENDANGERED RECEPTACLES WITH WATER SPRAY.
| 6 ACCIDENTAL RELEASE MEASURES | |
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE RESPIRATORY PROTECTIVE DEVICE AGAINST THE EFFECTS OF
FUMES/DUST/AEROSOL.
WEAR PROTECTIVE EQUIPMENT. KEEP UNPROTECTED PERSONS AWAY.
ENSURE ADEQUATE VENTILATION
KEEP AWAY FROM IGNITION SOURCES.
PROTECT FROM HEAT.
ISOLATE AREA AND PREVENT ACCESS.
KEEP PEOPLE AT A DISTANCE AND STAY ON THE WINDWARD SIDE.
6.2 ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW TO ENTER SEWERS/ SURFACE OR GROUND WATER.
6.3 METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
ALLOW TO SOLIDIFY. PICK UP MECHANICALLY.
SEND FOR RECOVERY OR DISPOSAL IN SUITABLE RECEPTACLES.
DISPOSE CONTAMINATED MATERIAL AS WASTE ACCORDING TO ITEM 13.
6.4 REFERENCE TO OTHER SECTIONS
SEE SECTION 7 FOR INFORMATION ON SAFE HANDLING.
SEE SECTION 8 FOR INFORMATION ON PERSONAL PROTECTION EQUIPMENT.
SEE SECTION 13 FOR DISPOSAL INFORMATION.
| 7 HANDLING AND STORAGE | |
7.1 PRECAUTIONS FOR SAFE HANDLING:
KEEP AWAY FROM HEAT AND DIRECT SUNLIGHT.
HANDLE WITH CARE. AVOID JOLTING, FRICTION AND IMPACT.
USE ONLY IN WELL VENTILATED AREAS.
INFORMATION ABOUT FIRE - AND EXPLOSION PROTECTION:
KEEP IGNITION SOURCES AWAY - DO NOT SMOKE.
PROTECT AGAINST ELECTROSTATIC CHARGES.
KEEP RESPIRATORY PROTECTIVE DEVICE AVAILABLE.
PRESSURIZED CONTAINER: PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO
TEMPERATURES EXCEEDING 50 DEG. C, I.E.
ELECTRIC LIGHTS. DO NOT PIERCE OR BURN, EVEN AFTER USE.
DO NOT SPRAY ONTO A NAKED FLAME OR ANY INCANDESCENT MATERIAL.
EMERGENCY COOLING MUST BE AVAILABLE IN CASE OF NEARBY FIRE.
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
REQUIREMENTS TO BE MET BY STOREROOMS AND RECEPTACLES:
STORE IN A COOL LOCATION.
OBSERVE OFFICIAL REGULATIONS ON STORING PACKAGINGS WITH PRESSURIZED
CONTAINERS.
PROVIDE VENTILATION FOR RECEPTACLES.
AVOID STORAGE NEAR EXTREME HEAT, IGNITION SOURCES OR OPEN FLAME.
INFORMATION ABOUT STORAGE IN ONE COMMON STORAGE FACILITY:
STORE AWAY FROM FOODSTUFFS.
STORE AWAY FROM OXIDIZING AGENTS.
FURTHER INFORMATION ABOUT STORAGE CONDITIONS:
PROTECT FROM HEAT AND DIRECT SUNLIGHT.
STORE IN A COOL PLACE. HEAT WILL INCREASE PRESSURE AND MAY LEAD TO THE
RECEPTACLE BURSTING.
7.3 SPECIFIC END USE(S): NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
ADDITIONAL INFORMATION ABOUT DESIGN OF TECHNICAL FACILITIES:
NO FURTHER DATA; SEE ITEM 7.
8.1 CONTROL PARAMETERS:
INGREDIENTS WITH LIMIT VALUES THAT REQUIRE MONITORING AT THE WORKPLACE:
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE:
PEL (USA):
CEILING LIMIT: 0,2 MG/M3, 0,02 PPM
REL (USA):
LONG-TERM VALUE: 0,05 MG/M3, 0,005 PPM
CEILING LIMIT: 0,2* MG/M3, 0,02* PPM
*10-MIN
TLV (USA):
LONG-TERM VALUE: 0,051 MG/M3, 0,005 PPM
EL (CANADA):
SHORT-TERM VALUE: C 0,01 PPM
LONG-TERM VALUE: 0,005 PPM
SKIN; S
EV (CANADA):
LONG-TERM VALUE: 0,005 PPM
115-10-6 DIMETHYL ETHER:
IOELV (EU):
LONG-TERM VALUE: 1920 MG/M3, 1000 PPM
WEEL (USA):
LONG-TERM VALUE: 1000 PPM
EL (CANADA):
LONG-TERM VALUE: 1000 PPM
72-28-5 ISOBUTANE:
REL (USA):
LONG-TERM VALUE: 1900 MG/M3, 800 PPM
TLV (USA):
SHORT-TERM VALUE: 2370 MG/M3, 1000 PPM
EL (CANADA):
SHORT-TERM VALUE: 750 PPM
LONG-TERM VALUE: 600 PPM
EV (CANADA) LONG-TERM VALUE: 800 PPM
74-98-6 PROPANE:
PEL (USA):
LONG-TERM VALUE: 1800 MG/M3, 1000 PPM
REL (USA):
LONG-TERM VALUE: 1800 MG/M3, 1000 PPM
TLV (USA):
REFER TO APPENDIX F: MINIMAL OXYGEN CONTENT
EL (CANADA):
LONG-TERM VALUE: 1000 PPM
EV (CANADA):
LONG-TERM VALUE: 1,000 PPM
DNELS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
PNECS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
ADDITIONAL INFORMATION:
THE LISTS VALID DURING THE MAKING WERE USED AS BASIS.
8.2 EXPOSURE CONTROLS:
PERSONAL PROTECTIVE EQUIPMENT:
GENERAL PROTECTIVE AND HYGIENIC MEASURES:
THE USUAL PRECAUTIONARY MEASURES ARE TO BE ADHERED TO WHEN HANDLING
CHEMICALS.
KEEP AWAY FROM FOODSTUFFS, BEVERAGES AND FEED.
IMMEDIATELY REMOVE ALL SOILED AND CONTAMINATED CLOTHING.
WASH HANDS BEFORE BREAKS AND AT THE END OF WORK.
DO NOT INHALE GASES / FUMES / AEROSOLS.
AVOID CONTACT WITH THE EYES AND SKIN.
CLEAN SKIN THOROUGHLY IMMEDIATELY AFTER HANDLING THE PRODUCT.
RESPIRATORY PROTECTION:
COMBINED ORGANIC VAPOR AND PARTICULATE RESPIRATOR IS RECOMMENDED FOR USE
DURING ALL PROCESSING ACTIVITIES.
PROTECTION OF HANDS: PROTECTIVE GLOVES
THE GLOVE MATERIAL HAS TO BE IMPERMEABLE AND RESISTANT TO THE PRODUCT/ THE
SUBSTANCE/ THE PREPARATION.
SELECTION OF THE GLOVE MATERIAL ON CONSIDERATION OF THE PENETRATION TIMES,
RATES OF DIFFUSION AND THE DEGRADATION.
MATERIAL OF GLOVES:
THE SELECTION OF THE SUITABLE GLOVES DOES NOT ONLY DEPEND ON THE MATERIAL,
BUT ALSO ON FURTHER MARKS OF QUALITY AND VARIES FROM MANUFACTURER TO
MANUFACTURER. AS THE PRODUCT IS A PREPARATION OF SEVERAL SUBSTANCES, THE
RESISTANCE OF THE GLOVE MATERIAL CAN NOT BE CALCULATED IN ADVANCE AND HAS
THEREFORE TO BE CHECKED PRIOR TO THE APPLICATION.
PENETRATION TIME OF GLOVE MATERIAL:
THE EXACT BREAK THROUGH TIME HAS TO BE FOUND OUT BY THE MANUFACTURER OF
THE PROTECTIVE GLOVES AND HAS TO BE OBSERVED.
EYE PROTECTION: SAFETY GLASSES
BODY PROTECTION: PROTECTIVE WORK CLOTHING
LIMITATION AND SUPERVISION OF EXPOSURE INTO THE ENVIRONMENT:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
RISK MANAGEMENT MEASURES:
SEE SECTION 7 FOR ADDITIONAL INFORMATION.
NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 9 PHYSICAL AND CHEMICAL PROPERTIES | |
9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL INFORMATION:
APPEARANCE:
FORM: AEROSOL
COLOUR: AMBER COLOURED
ODOUR:
LIGHT
PETROLEUM-LIKE
ODOUR THRESHOLD: NOT DETERMINED.
PH-VALUE: NOT DETERMINED.
CHANGE IN CONDITION:
MELTING POINT/MELTING RANGE: NOT DETERMINED.
BOILING POINT/BOILING RANGE: -44 DEG. F / -42 DEG. C (PROPELLANT)
FLASH POINT: -155 DEG. F / -104 DEG. C (PROPELLANT)
FLAMMABILITY (SOLID, GASEOUS): NOT APPLICABLE.
AUTO/SELF-IGNITION TEMPERATURE: NOT DETERMINED.
DECOMPOSITION TEMPERATURE: NOT DETERMINED.
SELF-IGNITING: PRODUCT IS NOT SELF-IGNITING.
DANGER OF EXPLOSION:
PRODUCT IS NOT EXPLOSIVE. HOWEVER, FORMATION OF EXPLOSIVE AIR/
VAPOUR MIXTURES ARE POSSIBLE.
EXPLOSION LIMITS:
LOWER: NOT DETERMINED.
UPPER: NOT DETERMINED.
VAPOUR PRESSURE: NOT DETERMINED.
DENSITY AT 20 DEG. C: 1,05 G/CM3
RELATIVE DENSITY: NOT DETERMINED.
VAPOUR DENSITY: NOT DETERMINED.
EVAPORATION RATE: NOT APPLICABLE.
SOLUBILITY IN / MISCIBILITY WITH WATER: NOT MISCIBLE OR DIFFICULT TO MIX.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT DETERMINED.
VISCOSITY:
DYNAMIC: NOT DETERMINED.
KINEMATIC: NOT DETERMINED.
SOLVENT CONTENT:
VOC (US EPA METHOD 24): 155 G/L
9.2 OTHER INFORMATION: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 10 STABILITY AND REACTIVITY | |
10.1 REACTIVITY:
10.2 CHEMICAL STABILITY:
THERMAL DECOMPOSITION / CONDITIONS TO BE AVOIDED:
NO DECOMPOSITION IF USED AND STORED ACCORDING TO SPECIFICATIONS.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS:
DEVELOPS READILY FLAMMABLE GASES/FUMES.
FLAMMABLE.
REACTS WITH OXIDIZING AGENTS.
CAN FORM EXPLOSIVE MIXTURES IN AIR IF HEATED ABOVE FLASH POINT AND/OR WHEN
SPRAYED OR ATOMISED.
DANGER OF RECEPTACLES BURSTING BECAUSE OF HIGH VAPOUR PRESSURE WHEN HEATED.
CONTACT WITH ACIDS RELEASES TOXIC GASES.
TOXIC FUMES MAY BE RELEASED IF HEATED ABOVE THE DECOMPOSITION POINT.
10.4 CONDITIONS TO AVOID:
KEEP IGNITION SOURCES AWAY - DO NOT SMOKE.
STORE AWAY FROM OXIDIZING AGENTS.
10.5 INCOMPATIBLE MATERIALS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
10.6 HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON MONOXIDE AND CARBON DIOXIDE
NITROGEN OXIDES (NOX)
HYDROGEN CYANIDE (PRUSSIC ACID)
PHOSPHORUS OXIDES (E.G. P2O5)
| 11 TOXICOLOGICAL INFORMATION | |
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
LD/LC50 VALUES RELEVANT FOR CLASSIFICATION:
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE:
ORAL LD50: 2200 MG/KG (MOUSE)
PRIMARY IRRITANT EFFECT:
ON THE SKIN: IRRITANT TO SKIN AND MUCOUS MEMBRANES.
ON THE EYE: IRRITATING EFFECT.
SENSITIZATION:
SENSITIZATION POSSIBLE THROUGH INHALATION.
SENSITIZATION POSSIBLE THROUGH SKIN CONTACT.
SUBACUTE TO CHRONIC TOXICITY:
INHALATION OF CONCENTRATED VAPOURS AS WELL AS ORAL INTAKE WILL LEAD TO
ANAESTHESIA-LIKE CONDITIONS AND HEADACHE, DIZZINESS, ETC.
ADDITIONAL TOXICOLOGICAL INFORMATION:
THE PRODUCT SHOWS THE FOLLOWING DANGERS ACCORDING TO THE CALCULATION
METHOD OF THE GENERAL EU CLASSIFICATION GUIDELINES FOR PREPARATIONS
AS ISSUED IN THE LATEST VERSION:
HARMFUL
IRRITANT
DANGER THROUGH SKIN ADSORPTION.
TOXIC AND/OR CORROSIVE EFFECTS MAY BE DELAYED UP TO 24 HOURS.
IN ADDITION TO LOCAL IRRITANT MANIFESTATIONS, THERE IS A NARCOTIC EFFECT
WHEN INHALING HIGH CONCENTRATIONS, WITH HIGH DANGER OF CENTRAL RESPIRATORY
ARREST.
ACUTE EFFECTS (ACUTE TOXICITY, IRRITATION AND CORROSIVITY):
VAPOURS HAVE NARCOTIC EFFECT.
REPEATED DOSE TOXICITY:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
REPEATED EXPOSURES MAY RESULT IN SKIN AND/OR RESPIRATORY SENSITIVITY.
| 12 ECOLOGICAL INFORMATION | |
12.1 TOXICITY:
AQUATIC TOXICITY: NO FURTHER RELEVANT INFORMATION AVAILABLE.
12.2 PERSISTENCE AND DEGRADABILITY:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
12.3 BIOACCUMULATIVE POTENTIAL: NO FURTHER RELEVANT INFORMATION AVAILABLE.
12.4 MOBILITY IN SOIL: NO FURTHER RELEVANT INFORMATION AVAILABLE.
ADDITIONAL ECOLOGICAL INFORMATION:
GENERAL NOTES:
WATER HAZARD CLASS 1 (GERMAN REGULATION) (SELF-ASSESSMENT): SLIGHTLY
HAZARDOUS FOR WATER DO NOT ALLOW UNDILUTED PRODUCT OR LARGE QUANTITIES
OF IT TO REACH GROUND WATER, WATER COURSE OR SEWAGE SYSTEM.
12.5 RESULTS OF PBT AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE.
VPVB: NOT APPLICABLE.
12.6 OTHER ADVERSE EFFECTS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 13 DISPOSAL CONSIDERATIONS | |
13.1 WASTE TREATMENT METHODS:
RECOMMENDATION:
MUST NOT BE DISPOSED TOGETHER WITH HOUSEHOLD GARBAGE. DO NOT ALLOW PRODUCT
TO REACH SEWAGE SYSTEM. CAN BE DISPOSED OF WITH HOUSEHOLD GARBAGE AFTER
SOLIDIFICATION FOLLOWING CONSULTATION WITH THE WASTE DISPOSAL FACILITY
OPERATOR AND THE PERTINENT AUTHORITIES AND ADHERING TO THE NECESSARY
TECHNICAL REGULATIONS.
UNCLEANED PACKAGING:
RECOMMENDATION: DISPOSAL MUST BE MADE ACCORDING TO OFFICIAL REGULATIONS.
| 14 TRANSPORT INFORMATION | |
14.1 UN-NUMBER:
DOT, ADR, IMDG, IATA: UN1950
14.2 UN PROPER SHIPPING NAME:
DOT: AEROSOLS, FLAMMABLE
ADR: 1950 AEROSOLS, FLAMMABLE
IMDG, IATA: AEROSOLS, FLAMMABLE
14.3 TRANSPORT HAZARD CLASS(ES):
DOT: FLAMMABLE GAS, CLASS/DIVISION 2.1
CLASS: 2.1
LABEL: 2.1
ADR: CLASS 2.1, FLAMMABLE GASES
CLASS: 2 5F GASES.
LABEL: 2.1
IMDG, IATA: CLASS 2.1 - FLAMMABLE GASES
CLASS: 2.1
LABEL: 2.1
14.4 PACKING GROUP:
DOT, ADR, IMDG, IATA: NOT REGULATED
14.5 ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO
14.6 SPECIAL PRECAUTIONS FOR USER:
WARNING: GASES.
DANGER CODE (KEMLER):
EMS NUMBER: F-D,S-U
14.7 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC
CODE: NOT APPLICABLE.
TRANSPORT/ADDITIONAL INFORMATION:
ADR:
LIMITED QUANTITIES (LQ): 1L
TRANSPORT CATEGORY: 2
TUNNEL RESTRICTION CODE: D
UN "MODEL REGULATION": UN1950, AEROSOLS, FLAMMABLE, 2.1
| 15 REGULATORY INFORMATION | |
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR
THE SUBSTANCE OR MIXTURE:
UNITED STATES (USA):
SARA:
SECTION 355 (EXTREMELY HAZARDOUS SUBSTANCES):
NONE OF THE INGREDIENTS IS LISTED.
SECTION 313 (SPECIFIC TOXIC CHEMICAL LISTINGS):
9016-87-9 DIPHENYLMETHANEDIISOCYANATE,ISOMERES AND HOMOLOGUES
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE
TSCA (TOXIC SUBSTANCES CONTROL ACT): ALL INGREDIENTS ARE LISTED.
PROPOSITION 65 (CALIFORNIA):
CHEMICALS KNOWN TO CAUSE CANCER: NONE OF THE INGREDIENTS IS LISTED.
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR FEMALES:
NONE OF THE INGREDIENTS IS LISTED.
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR MALES:
NONE OF THE INGREDIENTS IS LISTED.
CHEMICALS KNOWN TO CAUSE DEVELOPMENTAL TOXICITY:
NONE OF THE INGREDIENTS IS LISTED.
CARCINOGENIC CATEGORIES:
EPA (ENVIRONMENTAL PROTECTION AGENCY):
9016-87-9 DIPHENYLMETHANEDIISOCYANATE,ISOMERES AND HOMOLOGUES CBD
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE D, CBD
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
9016-87-9 DIPHENYLMETHANEDIISOCYANATE,ISOMERES AND HOMOLOGUES 3
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE 3
TLV (THRESHOLD LIMIT VALUE ESTABLISHED BY ACGIH):
NONE OF THE INGREDIENTS IS LISTED.
NIOSH-CA (NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH):
NONE OF THE INGREDIENTS IS LISTED.
CANADA:
CANADIAN DOMESTIC SUBSTANCES LIST (DSL): ALL INGREDIENTS ARE LISTED.
CANADIAN INGREDIENT DISCLOSURE LIST (LIMIT 0.1%):
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE
CANADIAN INGREDIENT DISCLOSURE LIST (LIMIT 1%):
NONE OF THE INGREDIENTS IS LISTED.
OTHER REGULATIONS, LIMITATIONS AND PROHIBITIVE REGULATIONS:
SUBSTANCES OF VERY HIGH CONCERN (SVHC) ACCORDING TO REACH, ARTICLE 57:
NONE OF THE INGREDIENTS IS LISTED.
15.2 CHEMICAL SAFETY ASSESSMENT:
A CHEMICAL SAFETY ASSESSMENT HAS NOT BEEN CARRIED OUT.
| 16 OTHER INFORMATION | |
THIS INFORMATION IS BASED ON OUR PRESENT KNOWLEDGE. HOWEVER, THIS SHALL
NOT CONSTITUTE A GUARANTEE FOR ANY SPECIFIC PRODUCT FEATURES AND SHALL
NOT ESTABLISH A LEGALLY VALID CONTRACTUAL RELATIONSHIP.
RELEVANT PHRASES:
H220: EXTREMELY FLAMMABLE GAS.
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
H315: CAUSES SKIN IRRITATION.
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H319: CAUSES SERIOUS EYE IRRITATION.
H332: HARMFUL IF INHALED.
H334:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
H335: MAY CAUSE RESPIRATORY IRRITATION.
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
R12: EXTREMELY FLAMMABLE.
R20: HARMFUL BY INHALATION.
R36/37/38: IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
R42/43: MAY CAUSE SENSITISATION BY INHALATION AND SKIN CONTACT.
R52/53:
HARMFUL TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE
AQUATIC ENVIRONMENT.
ABBREVIATIONS AND ACRONYMS:
ADR:
ACCORD EUROPEEN SUR LE TRANSPORT DES MARCHANDISES DANGEREUSES PAR ROUTE
(EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS
GOODS BY ROAD)
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
DOT: US DEPARTMENT OF TRANSPORTATION
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
EINECS: EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES
ELINCS: EUROPEAN LIST OF NOTIFIED CHEMICAL SUBSTANCES
CAS:
CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY)
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION (USA)
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (USA)
WHMIS: WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (CANADA)
DNEL: DERIVED NO-EFFECT LEVEL (REACH)
PNEC: PREDICTED NO-EFFECT CONCENTRATION (REACH)
LC50: LETHAL CONCENTRATION, 50 PERCENT
LD50: LETHAL DOSE, 50 PERCENT
FLAM. GAS 1: FLAMMABLE GASES, HAZARD CATEGORY 1
FLAM. AEROSOL 1: FLAMMABLE AEROSOLS, HAZARD CATEGORY 1
PRESS. GAS:
GASES UNDER PRESSURE: COMPRESSED GAS
ACUTE TOX. 4: ACUTE TOXICITY, HAZARD CATEGORY 4
SKIN IRRIT. 2: SKIN CORROSION/IRRITATION, HAZARD CATEGORY 2
EYE IRRIT. 2: SERIOUS EYE DAMAGE/EYE IRRITATION, HAZARD CATEGORY 2
RESP. SENS. 1: SENSITISATION - RESPIRAT., HAZARD CATEGORY 1
SKIN SENS. 1: SENSITISATION - SKIN, HAZARD CATEGORY 1
STOT SE 3:
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE, HAZARD CATEGORY 3
STOT RE 2:
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE, HAZARD CATEGORY 2
AQUATIC CHRONIC 3:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - CHRONIC HAZARD, CATEGORY 3
SOURCES:
SDS PREPARED BY:
CHEMTEL INC.
1305 NORTH FLORIDA AVENUE
TAMPA, FLORIDA 33602-2902
USA
TOLL FREE NORTH AMERICA: 1-888-255-3924
INTL.: +01 813-248-0573
WEBSITE: WWW.CHEMTELINC.COM