| Common Name: | TOUCH N SEAL QUICK CURE POLYURETHANE FOAM SEALANT HY (HIGH YIELD) |
| Manufacturer: | CONVENIENCE PRODUCTS |
| SDS Revision Date: | 4/27/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 444A78, 444A79 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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CP
CONVENIENCE PRODUCTS
SAFETY DATA SHEET
ACCORDING TO 1907/2006/EC (REACH), 1272/2008/EC (CLP), AND GHS
PRINTING DATE: 04.27.2017
REVISION: 04.27.2017
| 1 IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1 PRODUCT IDENTIFIER:
TRADE NAME:
TOUCH N SEAL QUICK CURE POLYURETHANE FOAM SEALANT HY (HIGH YIELD)
ARTICLE NUMBER: EHS 9464
1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
APPLICATION OF THE SUBSTANCE / THE MIXTURE: SEALANT
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER/SUPPLIER:
CONVENIENCE PRODUCTS, DIVISION OF CLAYTON CORP.
866 HORAN DRIVE
FENTON, MO 63026-2416
PHONE: 636-349-5855
1.4 EMERGENCY TELEPHONE NUMBER:
CHEMTEL INC.
(800)255-3924
+1 (813)248-0585
| 2 HAZARDS IDENTIFICATION | |
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLASSIFICATION ACCORDING TO REGULATION (EC) NO 1272/2008:
T HE FOLLOWING HAZARD STATEM ENTS ARE APPLICABLE ONLY TO THE EU
REGULATIONS AND NOT THE US GHS REGULATION: H412.
MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION. (USA GHS ONLY)
GAS CYLINDER
PRESS. GAS:
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
HEALTH HAZARD
RESP. SENS. 1:
H334:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
CARC. 2:
H351: SUSPECTED OF CAUSING CANCER.
STOT RE 2:
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
EXCLAMATION MARK
ACUTE TOX. 4:
H332: HARMFUL IF INHALED. SKIN IRRIT. 2 H315 CAUSES SKIN IRRITATION.
EYE IRRIT. 2:
H319: CAUSES SERIOUS EYE IRRITATION.
SKIN SENS. 1:
H317:
MAY CAUSE AN ALLERGIC SKIN REACTION. STOT SE 3 H335 MAY CAUSE RESPIRATORY
IRRITATION.
AQUATIC CHRONIC 3:
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
CLASSIFICATION ACCORDING TO DIRECTIVE 67/548/EEC OR DIRECTIVE 1999/45/EC:
XN; HARMFUL:
R20-40: HARMFUL BY INHALATION. LIMITED EVIDENCE OF A CARCINOGENIC EFFECT.
XN; SENSITISING:
R42/43: MAY CAUSE SENSITISATION BY INHALATION AND SKIN CONTACT.
XI; IRRITANT:
R36/37/38: IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
R52/53:
HARM FUL TO AQUATIC ORGANISM S, M AY CAUSE LONG-TERM ADVERSE EF FECTS IN
THE AQUATIC ENVIRONMENT.
INFORMATION CONCERNING PARTICULAR HAZARDS FOR HUMAN AND ENVIRONMENT:
THE PRODUCT HAS TO BE LABELLED DUE TO THE CALCULATION PROCEDURE OF THE
"GENERAL CLASSIFICATION GUIDELINE FOR PREPARATIONS OF THE EU" IN THE
LATEST VALID VERSION.
CLASSIFICATION SYSTEM:
T HE CLASSIFICATION IS ACCORDING TO THE LATEST EDITIONS OF THE EU-LISTS,
AND EXTENDED BY COM PANY AND LITERATURE DATA.
THE CLASSIFICATION IS IN ACCORDANCE WITH THE LATEST EDITIONS OF
INTERNATIONAL SUBSTANCES LISTS, AND IS SUPPLEMENTED BY INFORMATION
FROM TECHNICAL LITERATURE AND BY INFORMATION PROVIDED BY THE COMPANY.
2.2 LABEL ELEMENTS:
LABELLING ACCORDING TO REGULATION (EC) NO 1272/2008:
T HE FOLLOWING HAZARD STATEM ENTS ARE APPLICABLE ONLY TO THE EU REGULATIONS
AND NOT THE US GHS REGULATION: H229, H412.
THE PRODUCT IS CLASSIFIED AND LABELLED ACCORDING TO THE CLP REGULATION.
HAZARD PICTOGRAMS:
GHS04: GAS CYLINDER
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
SIGNAL WORD: DANGER
HAZARD-DETERMINING COMPONENTS OF LABELLING:
DIPHENYLMETHANEDIISOCYANATE,ISOMERES AND HOMOLOGUES
TRIS[2-CHLORO-1-(CHLOROMETHYL)ETHYL] PHOSPHATE
4,4'-METHYLENEDIPHENYL DIISOCYANATE
TRANS-DICHLOROETHYLENE
HAZARD STATEMENTS:
THE FOLLOWING HAZARD STATEM ENTS ARE APPLICABLE ONLY TO THE EU
REGULATIONS AND NOT THE US GHS REGULATION: H412.
MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION. (USA GHS ONLY)
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
H332: HARMFUL IF INHALED.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H334:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H351: SUSPECTED OF CAUSING CANCER.
H335: MAY CAUSE RESPIRATORY IRRITATION.
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENTS:
P285: IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
P281: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P260: DO NOT BREATHE MIST/VAPOURS/SPRAY.
P314: GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
P342+P311:
IF EXPERIENCING RESPIRATORY SYMPTOMS: CALL A POISON CENTER/DOCTOR.
ADDITIONAL INFORMATION:
CONTAINS ISOCYANATES. MAY PRODUCE AN ALLERGIC REACTION.
PRESSURIZED CONTAINER: PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO
TEMPERATURES EXCEEDING 50 DEG. C. DO NOT PIERCE OR BURN, EVEN AFTER USE.
3,3 % BY MASS OF THE CONTENTS ARE FLAMMABLE
HAZARD DESCRIPTION:
WHMIS-SYMBOLS:
A - COMPRESSED GAS
D2A - VERY TOXIC MATERIAL CAUSING OTHER TOXIC EFFECTS
NFPA RATINGS (SCALE 0 - 4):
HEALTH 2
FIRE 1
REACTIVITY 0
HMIS-RATINGS (SCALE 0 - 4):
HEALTH 2*
FIRE 1
REACTIVITY 0
* - INDICATES A LONG TERM HEALTH HAZARD FROM REPEATED OR PROLONGED
EXPOSURES.
HMIS LONG TERM HEALTH HAZARD SUBSTANCES:
9016-87-9 DIPHENYLMETHANEDIISOCYANATE,ISOMERES AND HOMOLOGUES
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE
2.3 OTHER HAZARDS:
RESULTS OF PBT AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE.
VPVB: NOT APPLICABLE.
| 3 COMPOSITION/INFORMATION ON INGREDIENTS | |
3.2 MIXTURES:
DESCRIPTION:
MIXTURE OF SUBSTANCES LISTED BELOW WITH NONHAZARDOUS ADDITIONS.
DANGEROUS COMPONENTS:
CAS: 9016-87-9 DIPHENYLMETHANEDIISOCYANATE, 20-40%
ISOMERES AND HOMOLOGUES
XN R20; XN R42/43; XI R36/37/38
CARC. CAT. 3
RESP. SENS. 1, H334; STOT RE 2, H373
ACUTE TOX. 4, H332; SKIN IRRIT. 2,
H315; EYE IRRIT. 2, H319; SKIN
SENS. 1, H317; STOT SE 3, H335
CAS: 811-97-2 NORFLURANE 10-20%
EINECS: 212-377-0 PRESS. GAS, H280
CAS: 101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE 10-20%
EINECS: 202-966-0 XN R20; XN R42/43; XI R36/37/38
INDEX NUMBER: 615-005-00-9 CARC. CAT. 3
RESP. SENS. 1, H334; STOT RE 2, H373
ACUTE TOX. 4, H332; SKIN IRRIT. 2,
H315; EYE IRRIT. 2, H319; SKIN
SENS. 1, H317; STOT SE 3, H335
CAS: 13674-84-5 TRIS(2-CHLORISOPROPYL)-PHOSPHATE 10-20%
R52/53
AQUATIC CHRONIC 3, H412
CAS: 13674-87-8 TRIS[2-CHLORO-1-(CHLOROMETHYL)ETHYL] 5-10%
EINECS: 237-159-2 PHOSPHATE
INDEX NUMBER: 015-199-00-X XN R40; N R51/53
CARC. 2, H351
AQUATIC CHRONIC 2, H411
CAS: 156-60-5 TRANS-DICHLOROETHYLENE 1-5%
EINECS: 205-860-2 XN R20; F R11 R52/53
INDEX NUMBER: 602-026-00-3
FLAM. LIQ. 2, H225
ACUTE TOX. 4, H332
AQUATIC CHRONIC 3, H412
ADDITIONAL INFORMATION:
FOR THE WORDING OF THE LISTED RISK PHRASES REFER TO SECTION 16.
| 4 FIRST AID MEASURES | |
4.1 DESCRIPTION OF FIRST AID MEASURES:
GENERAL INFORMATION:
IMMEDIATELY REMOVE ANY CLOTHING SOILED BY THE PRODUCT.
SYMPTOMS OF POISONING MAY EVEN OCCUR AFTER SEVERAL HOURS; THEREFORE
MEDICAL OBSERVATION FOR AT LEAST 48 HOURS AFTER THE ACCIDENT.
TAKE AFFECTED PERSONS OUT INTO THE FRESH AIR.
AFTER INHALATION:
SUPPLY FRESH AIR; CONSULT DOCTOR IN CASE OF COMPLAINTS.
PROVIDE OXYGEN TREATMENT IF AFFECTED PERSON HAS DIFFICULTY BREATHING.
IN CASE OF UNCONSCIOUSNESS PLACE PATIENT STABLY IN SIDE POSITION FOR
TRANSPORTATION.
AFTER SKIN CONTACT:
IMMEDIATELY WASH WITH WATER AND SOAP AND RINSE THOROUGHLY.
DO NOT PULL SOLIDIFIED PRODUCT OFF THE SKIN.
IF SKIN IRRITATION CONTINUES, CONSULT A DOCTOR.
AFTER EYE CONTACT:
IMMEDIATELY REMOVE CONTACT LENSES IF POSSIBLE.
RINSE OPENED EYE FOR SEVERAL MINUTES UNDER RUNNING WATER.
THEN CONSULT A DOCTOR.
AFTER SWALLOWING:
RINSE OUT MOUTH AND THEN DRINK PLENTY OF WATER.
DO NOT INDUCE VOMITING; CALL FOR MEDICAL HELP IMMEDIATELY.
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
ASTHMA ATTACKS
HEADACHE
BREATHING DIFFICULTY
ALLERGIC REACTIONS
COUGHING
NAUSEA
GASTRIC OR INTESTINAL DISORDERS WHEN INGESTED.
IRRITANT TO SKIN AND MUCOUS MEMBRANES.
IRRITANT TO EYES.
DIZZINESS
DISORIENTATION
HAZARDS:
DANGER OF IMPAIRED BREATHING.
DANGER OF DISTURBED CARDIAC RHYTHM.
ANGER OF PNEUMONIA.
DANGER OF PULMONARY OEDEMA.
DANGER OF CONVULSION.
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
SEVERE ALLERGIC SKIN REACTION, BRONCHIAL SPASMS AND ANAPHYLACTIC SHOCK
ARE POSSIBLE.
TREAT SKIN AND MUCOUS MEMBRANE WITH ANTIHISTAMINE AND CORTICOID
PREPARATIONS.
IN CASES OF IRRITATION TO THE LUNGS, INITIAL TREATMENT WITH CORTICAL
STEROID INHALANTS.
MONITOR CIRCULATION.
IF NECESSARY OXYGEN RESPIRATION TREATMENT.
MEDICAL SUPERVISION FOR AT LEAST 48 HOURS.
CONTAINS ISOCYANATES. MAY PRODUCE AN ALLERGIC REACTION.
| 5 FIREFIGHTING MEASURES | |
5.1 EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING AGENTS:
CO2, POWDER OR WATER SPRAY. FIGHT LARGER FIRES WITH WATER SPRAY OR ALCOHOL
RESISTANT FOAM.
WATER IN FLOODING QUANTITIES.
FOR SAFETY REASONS UNSUITABLE EXTINGUISHING AGENTS: NONE.
5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
DANGER OF RECEPTACLES BURSTING BECAUSE OF HIGH VAPOUR PRESSURE WHEN HEATED.
DURING HEATING OR IN CASE OF FIRE POISONOUS GASES ARE PRODUCED.
5.3 ADVICE FOR FIREFIGHTERS:
PROTECTIVE EQUIPMENT:
WEAR SELF-CONTAINED RESPIRATORY PROTECTIVE DEVICE.
WEAR FULLY PROTECTIVE SUIT.
ADDITIONAL INFORMATION: COOL ENDANGERED RECEPTACLES WITH WATER SPRAY.
| 6 ACCIDENTAL RELEASE MEASURES | |
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE RESPIRATORY PROTECTIVE DEVICE AGAINST THE EFFECTS OF
FUMES/DUST/AEROSOL.
WEAR PROTECTIVE EQUIPMENT. KEEP UNPROTECTED PERSONS AWAY.
ENSURE ADEQUATE VENTILATION
PROTECT FROM HEAT.
ISOLATE AREA AND PREVENT ACCESS.
KEEP PEOPLE AT A DISTANCE AND STAY ON THE WINDWARD SIDE.
6.2 ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW TO ENTER SEWERS/ SURFACE OR GROUND WATER.
6.3 METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
ALLOW TO SOLIDIFY. PICK UP MECHANICALLY.
SEND FOR RECOVERY OR DISPOSAL IN SUITABLE RECEPTACLES.
DISPOSE CONTAMINATED MATERIAL AS WASTE ACCORDING TO ITEM 13.
6.4 REFERENCE TO OTHER SECTIONS
SEE SECTION 7 FOR INFORMATION ON SAFE HANDLING.
SEE SECTION 8 FOR INFORMATION ON PERSONAL PROTECTION EQUIPMENT.
SEE SECTION 13 FOR DISPOSAL INFORMATION.
| 7 HANDLING AND STORAGE | |
7.1 PRECAUTIONS FOR SAFE HANDLING:
KEEP AWAY FROM HEAT AND DIRECT SUNLIGHT.
USE ONLY IN WELL VENTILATED AREAS.
INFORMATION ABOUT FIRE - AND EXPLOSION PROTECTION:
KEEP RESPIRATORY PROTECTIVE DEVICE AVAILABLE.
PRESSURIZED CONTAINER: PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO TEM
PERATURES EXCEEDING 50 DEG. C, I.E. ELECTRIC LIGHTS. DO NOT PIERCE OR
BURN, EVEN AFTER USE.
DO NOT SPRAY ONTO A NAKED FLAME OR ANY INCANDESCENT MATERIAL.
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
REQUIREMENTS TO BE MET BY STOREROOMS AND RECEPTACLES:
STORE IN A COOL LOCATION.
OBSERVE OFFICIAL REGULATIONS ON STORING PACKAGINGS WITH PRESSURIZED
CONTAINERS.
PROVIDE VENTILATION FOR RECEPTACLES.
AVOID STORAGE NEAR EXTREME HEAT, IGNITION SOURCES OR OPEN FLAME.
INFORMATION ABOUT STORAGE IN ONE COMMON STORAGE FACILITY:
STORE AWAY FROM FOODSTUFFS.
STORE AWAY FROM OXIDIZING AGENTS.
FURTHER INFORMATION ABOUT STORAGE CONDITIONS:
PROTECT FROM HEAT AND DIRECT SUNLIGHT.
STORE IN A COOL PLACE. HEAT WILL INCREASE PRESSURE AND MAY LEAD TO THE
RECEPTACLE BURSTING.
7.3 SPECIFIC END USE(S): NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
ADDITIONAL INFORMATION ABOUT DESIGN OF TECHNICAL FACILITIES:
NO FURTHER DATA; SEE ITEM 7.
8.1 CONTROL PARAMETERS:
INGREDIENTS WITH LIMIT VALUES THAT REQUIRE MONITORING AT THE WORKPLACE:
811-97-2 NORFLURANE:
W EEL (USA):
LONG-TERM VALUE: 1000 PPM
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE:
PEL (USA):
CEILING LIMIT: 0,2 MG/M3, 0,02 PPM
REL (USA):
LONG-TERM VALUE: 0,05 MG/M3, 0,005 PPM
CEILING LIMIT: 0,2* MG/M3, 0,02* PPM
*10-MIN
TLV (USA):
LONG-TERM VALUE: 0,051 MG/M3, 0,005 PPM
EL (CANADA):
SHORT-TERM VALUE: C 0,01 PPM
LONG-TERM VALUE: 0,005 PPM
SKIN; S
EV (CANADA):
LONG-TERM VALUE: 0,005 PPM
156-60-5 TRANS-DICHLOROETHYLENE:
PEL (USA):
LONG-TERM VALUE: 790 MG/M3, 200 PPM
REL (USA):
LONG-TERM VALUE: 790 MG/M3, 200 PPM
TLV (USA):
LONG-TERM VALUE: 793 MG/M3, 200 PPM
EL (CANADA):
LONG-TERM VALUE: 200 PPM
EV (CANADA):
SHORT-TERM VALUE: 990 MG/M3, 250 PPM
LONG-TERM VALUE: 790 MG/M3, 200 PPM
DNELS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
PNECS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
ADDITIONAL INFORMATION:
THE LISTS VALID DURING THE MAKING WERE USED AS BASIS.
8.2 EXPOSURE CONTROLS:
PERSONAL PROTECTIVE EQUIPMENT:
GENERAL PROTECTIVE AND HYGIENIC MEASURES:
THE USUAL PRECAUTIONARY MEASURES ARE TO BE ADHERED TO WHEN HANDLING
CHEMICALS.
KEEP AWAY FROM FOODSTUFFS, BEVERAGES AND FEED.
IMMEDIATELY REMOVE ALL SOILED AND CONTAMINATED CLOTHING.
WASH HANDS BEFORE BREAKS AND AT THE END OF WORK.
DO NOT INHALE GASES / FUMES / AEROSOLS.
AVOID CONTACT WITH THE EYES AND SKIN.
CLEAN SKIN THOROUGHLY IMMEDIATELY AFTER HANDLING THE PRODUCT.
RESPIRATORY PROTECTION:
COM BINED ORGANIC VAPOR AND PARTICULATE RESPIRATOR IS RECOMM ENDED FOR USE
DURING ALL PROCESSING ACTIVITIES.
PROTECTION OF HANDS: PROTECTIVE GLOVES
THE GLOVE MATERIAL HAS TO BE IMPERMEABLE AND RESISTANT TO THE PRODUCT/
THE SUBSTANCE/ THE PREPARATION. SELECTION OF THE GLOVE M ATERIAL ON
CONSIDERATION OF THE PENETRATION TIM ES, RATES OF DIFFUSION AND THE
DEGRADATION.
MATERIAL OF GLOVES:
THE SELECTION OF THE SUITABLE GLOVES DOES NOT ONLY DEPEND ON THE MATERIAL,
BUT ALSO ON FURTHER MARKS OF QUALITY AND VARIES F ROM M ANUF ACTURER TO
MANUFACTURER. AS THE PRODUCT IS A PREPARATION OF SEVERAL SUBSTANCES, THE
RESISTANCE OF THE GLOVE MATERIAL CAN NOT BE CALCULATED IN ADVANCE AND HAS
THEREFORE TO BE CHECKED PRIOR TO THE APPLICATION.
PENETRATION TIME OF GLOVE MATERIAL:
THE EXACT BREAK THROUGH TIME HAS TO BE FOUND OUT BY THE MANUFACTURER OF
THE PROTECTIVE GLOVES AND HAS TO BE OBSERVED.
EYE PROTECTION: SAFETY GLASSES
BODY PROTECTION: PROTECTIVE WORK CLOTHING
LIMITATION AND SUPERVISION OF EXPOSURE INTO THE ENVIRONMENT:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
RISK MANAGEMENT MEASURES:
SEE SECTION 7 FOR ADDITIONAL INFORMATION.
NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 9 PHYSICAL AND CHEMICAL PROPERTIES | |
9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL INFORMATION:
APPEARANCE:
FORM: AEROSOLIZED LIQUID WITH COMPRESSED GAS IN CYLINDERS
COLOUR: AMBER COLOU
ODOUR:
LIGHT
PETROLEUM-LIKE
ODOUR THRESHOLD: NOT DETERMINED.
PH-VALUE: NOT DETERMINED.
CHANGE IN CONDITION:
MELTING POINT/MELTING RANGE: NOT DETERMINED.
BOILING POINT/BOILING RANGE: -15 DEG. F / -26 DEG. C
FLASH POINT: NOT APPLICABLE, AS AEROSOL.
FLAMMABILITY (SOLID, GASEOUS): NOT APPLICABLE.
AUTO/SELF-IGNITION TEMPERATURE: NOT DETERMINED.
DECOMPOSITION TEMPERATURE: NOT DETERMINED.
SELF-IGNITING: PRODUCT IS NOT SELF-IGNITING.
DANGER OF EXPLOSION:
PRODUCT IS NOT EXPLOSIVE. HOWEVER, FORMATION OF EXPLOSIVE AIR/VAPOUR
MIXTURES ARE POSSIBLE.
EXPLOSION LIMITS:
LOWER: NOT DETERMINED.
UPPER: NOT DETERMINED.
VAPOUR PRESSURE: NOT DETERMINED.
DENSITY AT 20 DEG. C: 1,02 G/CM3
RELATIVE DENSITY NOT DETERMINED.
VAPOUR DENSITY NOT DETERMINED.
EVAPORATION RATE NOT APPLICABLE.
SOLUBILITY IN / MISCIBILITY WITH WATER: NOT MISCIBLE OR DIFFICULT TO MIX.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT DETERMINED.
VISCOSITY:
DYNAMIC: NOT DETERMINED.
KINEMATIC: NOT DETERMINED.
SOLVENT CONTENT:
VOC (US EPA METHOD 24) 0 G/L
9.2 OTHER INFORMATION: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 10 STABILITY AND REACTIVITY | |
10.1 REACTIVITY:
10.2 CHEMICAL STABILITY:
THERMAL DECOMPOSITION / CONDITIONS TO BE AVOIDED:
NO DECOMPOSITION IF USED AND STORED ACCORDING TO SPECIFICATIONS.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS:
DEVELOPS READILY FLAMMABLE GASES/FUMES.
REACTS WITH OXIDIZING AGENTS.
CAN FORM EXPLOSIVE MIXTURES IN AIR IF HEATED ABOVE FLASH POINT AND/OR
WHEN SPRAYED OR ATOMISED.
CONTACT WITH ACIDS RELEASES TOXIC GASES.
DANGER OF RECEPTACLES BURSTING BECAUSE OF HIGH VAPOUR PRESSURE WHEN
HEATED.
10.4 CONDITIONS TO AVOID:
KEEP IGNITION SOURCES AWAY - DO NOT SMOKE.
STORE AWAY FROM OXIDIZING AGENTS.
10.5 INCOMPATIBLE MATERIALS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
10.6 HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON MONOXIDE AND CARBON DIOXIDE
NITROGEN OXIDES (NOX)
HYDROGEN CYANIDE (PRUSSIC ACID)
PHOSPHORUS OXIDES (E.G. P2O5)
CHLORINE
| 11 TOXICOLOGICAL INFORMATION | |
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
LD/LC50 VALUES RELEVANT FOR CLASSIFICATION:
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE:
ORAL LD50: 2200 MG/KG (MOUSE)
13674-87-8 TRIS[2-CHLORO-1-(CHLOROMETHYL)ETHYL] PHOSPHATE:
ORAL LD50: >2000 MG/KG (RAT)
DERMAL LD50: >2000 MG/KG (RABBIT)
PRIMARY IRRITANT EFFECT:
ON THE SKIN: IRRITANT TO SKIN AND MUCOUS MEMBRANES.
ON THE EYE: IRRITATING EFFECT.
SENSITIZATION:
SENSITIZATION POSSIBLE THROUGH INHALATION.
SENSITIZATION POSSIBLE THROUGH SKIN CONTACT.
SUBACUTE TO CHRONIC TOXICITY:
INHALATION OF CONCENTRATED VAPOURS AS WELL AS ORAL INTAKE WILL LEAD TO
ANAESTHESIA-LIKE CONDITIONS AND HEADACHE, DIZZINESS, ETC.
ADDITIONAL TOXICOLOGICAL INFORMATION:
T HE PRODUCT SHOWS THE F OLLOWING DANGERS ACCORDING TO THE CALCULATION
METHOD OF THE GENERAL EU CLASSIFICATION GUIDELINES FOR PREPARATIONS AS
ISSUED IN THE LATEST VERSION:
HARMFUL
IRRITANT
DANGER THROUGH SKIN ADSORPTION.
TOXIC AND/OR CORROSIVE EFFECTS MAY BE DELAYED UP TO 24 HOURS. SUSPECTED
OF CAUSING CANCER.
IN ADDITION TO LOCAL IRRITANT MANIFESTATIONS, THERE IS A NARCOTIC EFFECT
WHEN INHALING HIGH CONCENTRATIONS, WITH THE DANGER OF CENTRAL RESPIRATORY
ARREST.
ASPHYXIANT GAS.
ACUTE EFFECTS (ACUTE TOXICITY, IRRITATION AND CORROSIVITY):
VAPOURS HAVE NARCOTIC EFFECT.
REPEATED DOSE TOXICITY:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
REPEATED EXPOSURES MAY RESULT IN SKIN AND/OR RESPIRATORY SENSITIVITY.
CMR EFFECTS (CARCINOGENITY, MUTAGENICITY AND TOXICITY FOR REPRODUCTION):
CARC. 2
| 12 ECOLOGICAL INFORMATION | |
12.1 TOXICITY:
AQUATIC TOXICITY:
THE PRODUCT CONTAINS MATERIALS THAT ARE HARMFUL TO THE ENVIRONMENT.
13674-87-8 TRIS[2-CHLORO-1-(CHLOROMETHYL)ETHYL] PHOSPHATE:
LC50: 1,1 MG/L (ONCORHYNCHUS MYKISS) 96 H
12.2 PERSISTENCE AND DEGRADABILITY:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
12.3 BIOACCUMULATIVE POTENTIAL:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
12.4 MOBILITY IN SOIL: NO FURTHER RELEVANT INFORMATION AVAILABLE.
ECOTOXICAL EFFECTS:
REMARK: HARMFUL TO FISH
ADDITIONAL ECOLOGICAL INFORMATION:
GENERAL NOTES:
AVOID TRANSFER INTO THE ENVIRONMENT.
WATER HAZARD CLASS 2 (GERMAN REGULATION) (SELF-ASSESSMENT):
HAZARDOUS FOR WATER
DO NOT ALLOW PRODUCT TO REACH GROUND WATER, WATER COURSE OR SEWAGE SYSTEM.
DANGER TO DRINKING WATER IF EVEN SMALL QUANTITIES LEAK INTO THE GROUND.
HARMFUL TO AQUATIC ORGANISMS
DUE TO AVAILABLE DATA ON ELIM INABILITY/DECOM POSITION AND BIOACCUM
ULATION POTENTIAL PROLONGED TERM DAMAGE OF THE ENVIRONMENT CAN NOT
BE EXCLUDED.
12.5 RESULTS OF PBT AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE.
VPVB: NOT APPLICABLE.
12.6 OTHER ADVERSE EFFECTS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 13 DISPOSAL CONSIDERATIONS | |
13.1 WASTE TREATMENT METHODS:
RECOMMENDATION:
MUST NOT BE DISPOSED TOGETHER WITH HOUSEHOLD GARBAGE. DO NOT ALLOW PRODUCT
TO REACH SEWAGE SYSTEM.
CAN BE DISPOSED OF WITH HOUSEHOLD GARBAGE AFTER SOLIDIFICATION FOLLOWING
CONSULTATION WITH THE WASTE DISPOSAL FACILITY OPERATOR AND THE PERTINENT
AUTHORITIES AND ADHERING TO THE NECESSARY TECHNICAL REGULATIONS.
UNCLEANED PACKAGING:
RECOMMENDATION: DISPOSAL MUST BE MADE ACCORDING TO OFFICIAL REGULATIONS.
| 14 TRANSPORT INFORMATION | |
14.1 UN-NUMBER:
DOT, ADR, IMDG, IATA: UN3500
14.2 UN PROPER SHIPPING NAME:
DOT:
3500 CHEMICAL UNDER PRESSURE, N.O.S. (FLUORINATED HYDROCARBON, NITROGEN)
IMDG, IATA:
14.3 TRANSPORT HAZARD CLASS(ES):
DOT: NON-FLAMMABLE GAS, CLASS/DIVISION 2.2
CLASS: 2.2
LABEL: 2.2
ADR: CLASS 2.2, NON-FLAMMABLE AND NON-TOXIC GASES
CLASS: 2 8A GASES.
LABEL: 2.2
IMDG, IATA: CLASS 2.2 - NON-FLAMMABLE GASES
CLASS: 2.2
LABEL: 2.2
14.4 PACKING GROUP:
DOT, ADR, IMDG, IATA: NOT REGULATED
14.5 ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO
14.6 SPECIAL PRECAUTIONS FOR USER:
WARNING: GASES.
DANGER CODE (KEMLER): 20
EMS NUMBER: F-C, S-V
14.7 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC
CODE: NOT APPLICABLE.
TRANSPORT/ADDITIONAL INFORMATION:
ADR:
LIMITED QUANTITIES (LQ): 0
TRANSPORT CATEGORY: 3
TUNNEL RESTRICTION CODE: C/E
UN "MODEL REGULATION": UN3500, CHEMICAL UNDER PRESSURE, N.O.S.
| 15 REGULATORY INFORMATION | |
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR
THE SUBSTANCE OR MIXTURE:
UNITED STATES (USA):
SARA:
SECTION 355 (EXTREMELY HAZARDOUS SUBSTANCES):
NONE OF THE INGREDIENTS IS LISTED.
SECTION 313 (SPECIFIC TOXIC CHEMICAL LISTINGS):
9016-87-9 DIPHENYLMETHANEDIISOCYANATE,ISOMERES AND HOMOLOGUES
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE
TSCA (TOXIC SUBSTANCES CONTROL ACT): ALL INGREDIENTS ARE LISTED.
PROPOSITION 65 (CALIFORNIA):
CHEMICALS KNOWN TO CAUSE CANCER:
13674-87-8 TRIS[2-CHLORO-1-(CHLOROMETHYL)ETHYL] PHOSPHATE
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR FEMALES:
NONE OF THE INGREDIENTS IS LISTED.
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR MALES:
NONE OF THE INGREDIENTS IS LISTED.
CHEMICALS KNOWN TO CAUSE DEVELOPMENTAL TOXICITY:
NONE OF THE INGREDIENTS IS LISTED.
CARCINOGENIC CATEGORIES:
EPA (ENVIRONMENTAL PROTECTION AGENCY):
9016-87-9 DIPHENYLMETHANEDIISOCYANATE,ISOMERES AND HOMOLOGUES CBD
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE D, CBD
156-60-5 TRANS-DICHLOROETHYLENE II
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
9016-87-9 DIPHENYLMETHANEDIISOCYANATE,ISOMERES AND HOMOLOGUES 3
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE 3
TLV (THRESHOLD LIMIT VALUE ESTABLISHED BY ACGIH):
NONE OF THE INGREDIENTS IS LISTED.
NIOSH-CA (NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH):
NONE OF THE INGREDIENTS IS LISTED.
CANADA:
CANADIAN DOMESTIC SUBSTANCES LIST (DSL): ALL INGREDIENTS ARE LISTED.
CANADIAN INGREDIENT DISCLOSURE LIST (LIMIT 0.1%):
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE
CANADIAN INGREDIENT DISCLOSURE LIST (LIMIT 1%):
NONE OF THE INGREDIENTS IS LISTED.
OTHER REGULATIONS, LIMITATIONS AND PROHIBITIVE REGULATIONS:
SUBSTANCES OF VERY HIGH CONCERN (SVHC) ACCORDING TO REACH, ARTICLE 57:
NONE OF THE INGREDIENTS IS LISTED.
15.2 CHEMICAL SAFETY ASSESSMENT:
A CHEMICAL SAFETY ASSESSMENT HAS NOT BEEN CARRIED OUT.
| 16 OTHER INFORMATION | |
THIS INFORMATION IS BASED ON OUR PRESENT KNOWLEDGE. HOWEVER, THIS SHALL
NOT CONSTITUTE A GUARANTEE FOR ANY SPECIFIC PRODUCT FEATURES AND SHALL
NOT ESTABLISH A LEGALLY VALID CONTRACTUAL RELATIONSHIP.
RELEVANT PHRASES:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR.
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
H315: CAUSES SKIN IRRITATION.
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H319: CAUSES SERIOUS EYE IRRITATION.
H332: HARMFUL IF INHALED.
H334:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
H335: MAY CAUSE RESPIRATORY IRRITATION.
H351: SUSPECTED OF CAUSING CANCER.
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
H411: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
R11: HIGHLY FLAMMABLE.
R20: HARMFUL BY INHALATION.
R36/37/38: IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
R40: LIMITED EVIDENCE OF A CARCINOGENIC EFFECT.
R42/43: MAY CAUSE SENSITISATION BY INHALATION AND SKIN CONTACT.
R51/53:
TOXIC TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE
AQUATIC ENVIRONMENT.
R52/53:
HARMFUL TO AQUATIC ORGANISMS, MAY CAUSE LONG- TERM ADVERSE EFFECTS IN THE
AQUATIC ENVIRONMENT.
ABBREVIATIONS AND ACRONYMS:
ADR:
ACCORD EUROPEEN SUR LE TRANSPORT DES MARCHANDISES DANGEREUSES PAR ROUTE
(EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS
GOODS BY ROAD)
IMDG:
INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
DOT: US DEPARTMENT OF TRANSPORTATION
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
EINECS: EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES
ELINCS: EUROPEAN LIST OF NOTIFIED CHEMICAL SUBSTANCES
CAS:
CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY)
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION (USA)
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (USA)
WHMIS: W ORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (CANADA)
DNEL: DERIVED NO-EFFECT LEVEL (REACH)
PNEC: PREDICTED NO-EFFECT CONCENTRATION (REACH)
LC50: LETHAL CONCENTRATION, 50 PERCENT
LD50: LETHAL DOSE, 50 PERCENT
PRESS. GAS:
GASES UNDER PRESSURE: COMPRESSED GAS
PRESS. GAS:
GASES UNDER PRESSURE: DISSOLVED GAS
FLAM. LIQ. 2: FLAMMABLE LIQUIDS, HAZARD CATEGORY 2
ACUTE TOX. 4: ACUTE TOXICITY, HAZARD CATEGORY 4
SKIN IRRIT. 2: SKIN CORROSION/IRRITATION, HAZARD CATEGORY 2
EYE IRRIT. 2: SERIOUS EYE DAMAGE/EYE IRRITATION, HAZARD CATEGORY 2
RESP. SENS. 1: SENSITISATION - RESPIRAT., HAZARD CATEGORY 1
SKIN SENS. 1: SENSITISATION - SKIN, HAZARD CATEGORY 1
CARC. 2: CARCINOGENICITY, HAZARD CATEGORY 2
STOT SE 3:
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE, HAZARD CATEGORY 3
STOT RE 2:
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE, HAZARD CATEGORY 2
AQUATIC CHRONIC 2:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - CHRONIC HAZARD, CATEGORY 2
AQUATIC CHRONIC 3:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - CHRONIC HAZARD, CATEGORY 3
SOURCES:
SDS PREPARED BY:
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