| Common Name: | TOUCH 'N SEAL MINE FOAM PART A, TOUCH 'N SEAL MINE FOAM PART B |
| Manufacturer: | CONVENIENCE PRODUCTS |
| SDS Revision Date: | 4/11/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 444A99, 444C01 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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CP
CONVENIENCE PRODUCTS
SAFETY DATA SHEET
ACC. TO OSHA HCS (29 CFR 1910.1200) AND WHMIS 2015 REGULATIONS
PRINTING DATE: APRIL 11, 2017
REVISION: APRIL 11, 2017
| 1 IDENTIFICATION |  |
PRODUCT IDENTIFIER:
TRADE NAME: TOUCH 'N SEAL MINE FOAM PART A
PRODUCT CODE: EHS 2322 A
RECOMMENDED USE AND RESTRICTION ON USE:
RECOMMENDED USE: POLYURETHANE-SEALANT
RESTRICTIONS ON USE: NO RELEVANT INFORMATION AVAILABLE.
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER/SUPPLIER:
CONVENIENCE PRODUCTS
866 HORAN DRIVE
PACIFIC, MO 63026
PHONE: 636-349-5855
TOLL-FREE: 1-800-325-6180
EMERGENCY TELEPHONE NUMBER:
CHEMTEL INC.
(800)255-3924 (NORTH AMERICA)
+1 (813)248-0585 (INTERNATIONAL)
| 2 HAZARD(S) IDENTIFICATION | |
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
PRESS. GAS:
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
ACUTE TOX. 4:
H332: HARMFUL IF INHALED.
SKIN IRRIT. 2:
H315: CAUSES SKIN IRRITATION.
EYE IRRIT. 2A:
H319: CAUSES SERIOUS EYE IRRITATION.
RESP. SENS. 1:
H334:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
SKIN SENS. 1:
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
STOT SE 3:
H335: MAY CAUSE RESPIRATORY IRRITATION.
STOT RE 2:
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
LABEL ELEMENTS:
GHS LABEL ELEMENTS:
THE PRODUCT IS CLASSIFIED AND LABELED ACCORDING TO THE GLOBALLY HARMONIZED
SYSTEM (GHS).
HAZARD PICTOGRAMS:
GHS04: GAS CYLINDER
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
H332: HARMFUL IF INHALED.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H334:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H335: MAY CAUSE RESPIRATORY IRRITATION.
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
PRECAUTIONARY STATEMENTS:
P233: KEEP CONTAINER TIGHTLY CLOSED.
P260: DO NOT BREATHE MIST/VAPORS/SPRAY.
P264: WASH THOROUGHLY AFTER HANDLING.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P272: CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
P280: WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION.
P284: IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P304+P340:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
P314: GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
P333+P313:
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P342+P311:
IF EXPERIENCING RESPIRATORY SYMPTOMS: CALL A POISON CENTER/DOCTOR.
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE.
P405: STORE LOCKED UP.
P410+P403: PROTECT FROM SUNLIGHT. STORE IN A WELL-VENTILATED PLACE.
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
OTHER HAZARDS:
THERE ARE NO OTHER HAZARDS NOT OTHERWISE CLASSIFIED THAT HAVE BEEN
IDENTIFIED.
| 3 COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL CHARACTERIZATION: MIXTURES
COMPONENTS:
9016-87-9 DIPHENYLMETHANEDIISOCYANATE,ISOMERES AND HOMOLOGUES 25-50%
RESP. SENS. 1, H334; STOT RE 2, H373
ACUTE TOX. 4, H332; SKIN IRRIT. 2, H315;
EYE IRRIT. 2A, H319; SKIN SENS. 1, H317;
STOT SE 3, H335
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE 25-50%
RESP. SENS. 1, H334; STOT RE 2, H373
ACUTE TOX. 4, H332; SKIN IRRIT. 2, H315;
EYE IRRIT. 2A, H319; SKIN SENS. 1, H317;
STOT SE 3, H335
811-97-2 NORFLURANE 10-25%
PRESS. GAS, H280
SIMPLE ASPHYXIANT
HALOGENATED HYDROCARBON <10%
FLAM. LIQ. 2, H225
ACUTE TOX. 4, H332
ADDITIONAL INFORMATION:
FOR THE LISTED INGREDIENT(S), THE IDENTITY AND/OR EXACT PERCENTAGE(S)
ARE BEING WITHHELD AS A TRADE SECRET.
FOR THE WORDING OF THE LISTED HAZARD STATEMENTS REFER TO SECTION 16.
| 4 FIRST-AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
AFTER INHALATION:
SUPPLY FRESH AIR AND TO BE SURE TO CALL FOR A DOCTOR.
PROVIDE OXYGEN TREATMENT IF AFFECTED PERSON HAS DIFFICULTY BREATHING.
IN CASE OF UNCONSCIOUSNESS PLACE PATIENT STABLY IN SIDE POSITION FOR
TRANSPORTATION.
AFTER SKIN CONTACT:
DO NOT PULL SOLIDIFIED PRODUCT AWAY FROM THE SKIN.
IMMEDIATELY WASH WITH WATER AND SOAP AND RINSE THOROUGHLY.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
AFTER EYE CONTACT:
PROTECT UNHARMED EYE.
DO NOT REMOVE CONTACT LENSES IF WORN.
RINSE OPENED EYE FOR SEVERAL MINUTES UNDER RUNNING WATER. IF SYMPTOMS
PERSIST, CONSULT A DOCTOR.
SEEK IMMEDIATE MEDICAL ADVICE.
AFTER SWALLOWING:
UNLIKELY ROUTE OF EXPOSURE.
RINSE OUT MOUTH AND THEN DRINK PLENTY OF WATER.
DO NOT INDUCE VOMITING; IMMEDIATELY CALL FOR MEDICAL HELP.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
ASTHMA ATTACKS
HEADACHE
COUGHING
BREATHING DIFFICULTY
DIZZINESS
CYANOSIS
ALLERGIC REACTIONS
IRRITANT TO SKIN AND MUCOUS MEMBRANES.
CAUSES EYE IRRITATION.
DANGER:
DANGER OF IMPAIRED BREATHING.
DANGER OF PULMONARY EDEMA.
DANGER OF CONVULSION.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
CONDITION MAY DETERIORATE WITH ALCOHOL CONSUMPTION.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
IF SWALLOWED, GASTRIC IRRIGATION WITH ADDED, ACTIVATED CARBON.
IF SWALLOWED OR IN CASE OF VOMITING, DANGER OF ENTERING THE LUNGS.
CONTAINS ISOCYANATES. MAY PRODUCE AN ALLERGIC REACTION.
SEVERE ALLERGIC SKIN REACTION, BRONCHIAL SPASMS AND ANAPHYLACTIC SHOCK
ARE POSSIBLE.
TREAT SKIN AND MUCOUS MEMBRANE WITH ANTIHISTAMINE AND CORTICOID
PREPARATIONS.
MEDICAL SUPERVISION FOR AT LEAST 48 HOURS.
IF NECESSARY OXYGEN RESPIRATION TREATMENT.
LATER OBSERVATION FOR PNEUMONIA AND PULMONARY EDEMA.
| 5 FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING AGENTS:
CO2, EXTINGUISHING POWDER OR WATER SPRAY. FIGHT LARGER FIRES WITH WATER
SPRAY.
FOR SAFETY REASONS UNSUITABLE EXTINGUISHING AGENTS: NONE.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
DANGER OF RECEPTACLES BURSTING BECAUSE OF HIGH VAPOR PRESSURE IF HEATED.
FORMATION OF TOXIC GASES IS POSSIBLE DURING HEATING OR IN CASE OF FIRE.
ADVICE FOR FIREFIGHTERS:
PROTECTIVE EQUIPMENT:
WEAR SELF-CONTAINED RESPIRATORY PROTECTIVE DEVICE.
DO NOT INHALE EXPLOSION GASES OR COMBUSTION GASES.
WEAR FULLY PROTECTIVE SUIT.
ADDITIONAL INFORMATION: COOL ENDANGERED RECEPTACLES WITH WATER SPRAY.
| 6 ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE RESPIRATORY PROTECTIVE DEVICE AGAINST THE EFFECTS OF
FUMES/DUST/AEROSOL.
REMOVE PERSONS FROM DANGER AREA.
ENSURE ADEQUATE VENTILATION.
WEAR PROTECTIVE EQUIPMENT. KEEP UNPROTECTED PERSONS AWAY.
PROTECT FROM HEAT.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW UNDILUTED PRODUCT OR LARGE QUANTITIES OF IT TO REACH GROUND
WATER, WATER COURSE OR SEWAGE SYSTEM.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
ALLOW TO SOLIDIFY. PICK UP MECHANICALLY.
CLEAN THE AFFECTED AREA CAREFULLY; SUITABLE CLEANERS ARE: ORGANIC SOLVENT
REFERENCE TO OTHER SECTIONS:
SEE SECTION 7 FOR INFORMATION ON SAFE HANDLING.
SEE SECTION 8 FOR INFORMATION ON PERSONAL PROTECTION EQUIPMENT.
SEE SECTION 13 FOR DISPOSAL INFORMATION.
| 7 HANDLING AND STORAGE | |
HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
USE ONLY IN WELL VENTILATED AREAS.
KEEP AWAY FROM HEAT AND DIRECT SUNLIGHT.
AVOID CONTACT WITH THE EYES AND SKIN.
KEEP OUT OF REACH OF CHILDREN.
INFORMATION ABOUT PROTECTION AGAINST EXPLOSIONS AND FIRES:
PRESSURIZED CONTAINER:
PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO TEMPERATURES EXCEEDING
120 DEG. F / 49 DEG. C, I.E. ELECTRIC LIGHTS. DO NOT PIERCE OR BURN, EVEN
AFTER USE.
DO NOT SPRAY ON A NAKED FLAME OR ANY INCANDESCENT MATERIAL.
KEEP RESPIRATORY PROTECTIVE DEVICE AVAILABLE.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
REQUIREMENTS TO BE MET BY STOREROOMS AND RECEPTACLES:
OBSERVE OFFICIAL REGULATIONS ON STORING PACKAGINGS WITH PRESSURIZED
CONTAINERS.
INFORMATION ABOUT STORAGE IN ONE COMMON STORAGE FACILITY:
STORE AWAY FROM FOODSTUFFS.
DO NOT STORE TOGETHER WITH ACIDS.
STORE AWAY FROM OXIDIZING AGENTS.
FURTHER INFORMATION ABOUT STORAGE CONDITIONS:
STORE IN COOL, DRY CONDITIONS IN WELL SEALED RECEPTACLES.
STORE IN A COOL PLACE. HEAT WILL INCREASE PRESSURE AND MAY LEAD TO THE
RECEPTACLE BURSTING.
PROTECT FROM HEAT AND DIRECT SUNLIGHT.
SPECIFIC END USE(S): NO RELEVANT INFORMATION AVAILABLE.
| 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
COMPONENTS WITH LIMIT VALUES THAT REQUIRE MONITORING AT THE WORKPLACE:
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE:
PEL (USA):
CEILING LIMIT VALUE: 0.2 MG/M3, 0.02 PPM
REL (USA):
LONG-TERM VALUE: 0.05 MG/M3, 0.005 PPM
CEILING LIMIT VALUE: 0.2* MG/M3, 0.02* PPM
*10-MIN
TLV (USA):
LONG-TERM VALUE: 0.051 MG/M3, 0.005 PPM
EL (CANADA):
LONG-TERM VALUE: 0.005 PPM
CEILING LIMIT VALUE: 0.01 PPM
SKIN; S
EV (CANADA):
LONG-TERM VALUE: 0.005 PPM
CEILING LIMIT VALUE: 0.02 PPM
LMPE (MEXICO):
LONG-TERM VALUE: 0.005 PPM
811-97-2 NORFLURANE:
WEEL (USA):
LONG-TERM VALUE: 1000 PPM
HALOGENATED HYDROCARBON:
PEL (USA):
LONG-TERM VALUE: 790 MG/M3, 200 PPM
REL (USA):
LONG-TERM VALUE: 790 MG/M3, 200 PPM
TLV (USA):
LONG-TERM VALUE: 790 MG/M3, 200 PPM
EL (CANADA):
LONG-TERM VALUE: 200 PPM
EV (CANADA):
SHORT-TERM VALUE: 990 MG/M3, 250 PPM
LONG-TERM VALUE: 790 MG/M3, 200 PPM
LMPE (MEXICO):
LONG-TERM VALUE: 200 PPM
EXPOSURE CONTROLS:
PERSONAL PROTECTIVE EQUIPMENT:
GENERAL PROTECTIVE AND HYGIENIC MEASURES:
THE USUAL PRECAUTIONARY MEASURES FOR HANDLING CHEMICALS SHOULD BE FOLLOWED.
KEEP AWAY FROM FOODSTUFFS, BEVERAGES AND FEED.
IMMEDIATELY REMOVE ALL SOILED AND CONTAMINATED CLOTHING.
WASH HANDS BEFORE BREAKS AND AT THE END OF WORK.
DO NOT INHALE GASES / FUMES / AEROSOLS.
AVOID CONTACT WITH THE EYES AND SKIN.
ENGINEERING CONTROLS: NO RELEVANT INFORMATION AVAILABLE.
BREATHING EQUIPMENT:
COMBINED ORGANIC VAPOR AND PARTICULATE RESPIRATOR IS RECOMMENDED FOR USE
DURING ALL PROCESSING ACTIVITIES.
SUITABLE RESPIRATORY PROTECTIVE DEVICE RECOMMENDED.
PROTECTION OF HANDS:
PROTECTIVE GLOVES
THE GLOVE MATERIAL HAS TO BE IMPERMEABLE AND RESISTANT TO THE PRODUCT/THE
SUBSTANCE/THE PREPARATION.
EYE PROTECTION: SAFETY GLASSES
BODY PROTECTION: PROTECTIVE WORK CLOTHING
LIMITATION AND SUPERVISION OF EXPOSURE INTO THE ENVIRONMENT:
NO RELEVANT INFORMATION AVAILABLE.
RISK MANAGEMENT MEASURES: NO RELEVANT INFORMATION AVAILABLE.
| 9 PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE:
FORM: AEROSOLIZED LIQUID WITH COMPRESSED GAS IN CYLINDERS
COLOR: CREAM COLORED
ODOR: CHARACTERISTIC
ODOR THRESHOLD: NOT DETERMINED.
PH-VALUE: NOT DETERMINED.
MELTING POINT/MELTING RANGE: NOT APPLICABLE, AS AEROSOL.
BOILING POINT/BOILING RANGE: NOT APPLICABLE, AS AEROSOL.
FLASH POINT: NOT APPLICABLE, AS AEROSOL.
FLAMMABILITY (SOLID, GASEOUS): NOT APPLICABLE.
AUTO-IGNITION TEMPERATURE: 400 DEG. C (752 DEG. F)
DECOMPOSITION TEMPERATURE: NOT DETERMINED.
DANGER OF EXPLOSION: NOT DETERMINED.
EXPLOSION LIMITS:
LOWER: NOT DETERMINED.
UPPER: NOT DETERMINED.
OXIDIZING PROPERTIES: NOT DETERMINED.
VAPOR PRESSURE AT 20 DEG. C (68 DEG. F): 5716 HPA (4287 MMHg)
DENSITY:
RELATIVE DENSITY: 1.03
VAPOR DENSITY: NOT DETERMINED.
EVAPORATION RATE: NOT APPLICABLE.
SOLUBILITY IN / MISCIBILITY WITH WATER: NOT MISCIBLE OR DIFFICULT TO MIX.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT DETERMINED.
VISCOSITY:
DYNAMIC: NOT DETERMINED.
KINEMATIC: NOT DETERMINED.
VOC (CALIFORNIA): 32.8 G/L (EPA METHOD 24)
OTHER INFORMATION: NO RELEVANT INFORMATION AVAILABLE.
| 10 STABILITY AND REACTIVITY | |
REACTIVITY: NO RELEVANT INFORMATION AVAILABLE.
CHEMICAL STABILITY: STABLE UNDER NORMAL TEMPERATURES AND PRESSURES.
THERMAL DECOMPOSITION / CONDITIONS TO BE AVOIDED:
DANGER OF RECEPTACLES BURSTING BECAUSE OF HIGH VAPOR PRESSURE IF HEATED.
POSSIBILITY OF HAZARDOUS REACTIONS:
REACTS WITH ALCOHOLS, AMINES, AQUEOUS ACIDS AND ALKALIS.
CONTACT WITH ACIDS RELEASES TOXIC GASES.
REACTS WITH OXIDIZING AGENTS.
EXOTHERMIC POLYMERIZATION.
CONDITIONS TO AVOID: EXCESSIVE HEAT.
INCOMPATIBLE MATERIALS: CONTACT WITH ACIDS LIBERATES TOXIC GAS.
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON MONOXIDE AND CARBON DIOXIDE
AMMONIA
ISOCYANATE
NITROGEN OXIDES
| 11 TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
LD/LC50 VALUES THAT ARE RELEVANT FOR CLASSIFICATION:
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE:
ORAL:
LD50: 2200 MG/KG (MOUSE)
PRIMARY IRRITANT EFFECT:
ON THE SKIN: IRRITANT TO SKIN AND MUCOUS MEMBRANES.
ON THE EYE: IRRITATING EFFECT.
SENSITIZATION: MAY CAUSE SENSITISATION BY INHALATION AND SKIN CONTACT.
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
NONE OF THE INGREDIENTS ARE LISTED.
NTP (NATIONAL TOXICOLOGY PROGRAM): NONE OF THE INGREDIENTS ARE LISTED.
OSHA-CA (OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION):
NONE OF THE INGREDIENTS ARE LISTED.
PROBABLE ROUTE(S) OF EXPOSURE:
INHALATION.
EYE CONTACT.
SKIN CONTACT.
ACUTE EFFECTS (ACUTE TOXICITY, IRRITATION AND CORROSIVITY):
HARMFUL IF INHALED.
IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
CMR EFFECTS (CARCINOGENITY, MUTAGENICITY AND TOXICITY FOR REPRODUCTION):
GERM CELL MUTAGENICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
CARCINOGENICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
REPRODUCTIVE TOXICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
STOT-SINGLE EXPOSURE: MAY CAUSE RESPIRATORY IRRITATION.
STOT-REPEATED EXPOSURE:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
ASPIRATION HAZARD:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
| 12 ECOLOGICAL INFORMATION | |
TOXICITY:
AQUATIC TOXICITY:
THE PRODUCT CONTAINS MATERIALS THAT ARE HARMFUL TO THE ENVIRONMENT.
PERSISTENCE AND DEGRADABILITY:
THE PRODUCT IS PARTIALLY BIODEGRADABLE. SIGNIFICANT RESIDUALS REMAIN.
BIOACCUMULATIVE POTENTIAL: DOES NOT ACCUMULATE IN ORGANISMS
MOBILITY IN SOIL: NO RELEVANT INFORMATION AVAILABLE.
ADDITIONAL ECOLOGICAL INFORMATION:
GENERAL NOTES:
DUE TO THE CONSISTENCE AND THE LOW WATER SOLUBILITY OF THE PRODUCT A
BIOAVAILABILITY IS NOT PROBABLE.
DUE TO AVAILABLE DATA ON ELIMINABILITY/DECOMPOSITION AND BIOACCUMULATION
POTENTIAL PROLONGED TERM DAMAGE OF THE ENVIRONMENT CAN NOT BE EXCLUDED.
DO NOT ALLOW UNDILUTED PRODUCT OR LARGE QUANTITIES OF IT TO REACH GROUND
WATER, WATER COURSE OR SEWAGE SYSTEM.
RESULTS OF PBT AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE.
VPVB: NOT APPLICABLE.
OTHER ADVERSE EFFECTS: NO RELEVANT INFORMATION AVAILABLE.
| 13 DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
RECOMMENDATION:
CONTACT WASTE PROCESSORS FOR RECYCLING INFORMATION.
CAN BE DISPOSED OF WITH HOUSEHOLD GARBAGE AFTER SOLIDIFICATION FOLLOWING
CONSULTATION WITH THE WASTE DISPOSAL FACILITY OPERATOR AND THE PERTINENT
AUTHORITIES AND ADHERING TO THE NECESSARY TECHNICAL REGULATIONS. THE USER
OF THIS MATERIAL HAS THE RESPONSIBILITY TO DISPOSE OF UNUSED MATERIAL,
RESIDUES AND CONTAINERS IN COMPLIANCE WITH ALL RELEVANT LOCAL, STATE AND
FEDERAL LAWS AND REGULATIONS REGARDING TREATMENT, STORAGE AND DISPOSAL FOR
HAZARDOUS AND NONHAZARDOUS WASTES.
UNCLEANED PACKAGINGS:
RECOMMENDATION: DISPOSAL MUST BE MADE ACCORDING TO OFFICIAL REGULATIONS.
| 14 TRANSPORT INFORMATION | |
UN-NUMBER:
DOT, ADR, IMDG, IATA: UN3500
UN PROPER SHIPPING NAME:
DOT, IATA:
CHEMICAL UNDER PRESSURE, N.O.S. (FLUORINATED HYDROCARBON, NITROGEN)
ADR, IMDG:
CHEMICAL UNDER PRESSURE, N.O.S. (FLUORINATED HYDROCARBON, NITROGEN)
TRANSPORT HAZARD CLASS(ES):
DOT: NON-FLAMMABLE GAS, CLASS/DIVISION 2.2
CLASS: 2.2
LABEL: 2.2
ADR: CLASS 2.2, NON-FLAMMABLE AND NON-TOXIC GASES
CLASS: 2 8A GASES
LABEL: 2.2
IMDG, IATA: CLASS 2.2, NON-FLAMMABLE AND NON-TOXIC GASES
CLASS: 2 GASES
LABEL: 2.2
PACKING GROUP: THIS UN-NUMBER IS NOT ASSIGNED A PACKING GROUP.
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO
SPECIAL PRECAUTIONS FOR USER:
WARNING: GASES
DANGER CODE (KEMLER): 20
EMS NUMBER: F-C, S-V
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC CODE:
NOT APPLICABLE.
| 15 REGULATORY INFORMATION | |
SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE
SUBSTANCE OR MIXTURE:
UNITED STATES (USA):
SARA:
SECTION 302 (EXTREMELY HAZARDOUS SUBSTANCES):
NONE OF THE INGREDIENTS ARE LISTED.
SECTION 355 (EXTREMELY HAZARDOUS SUBSTANCES):
NONE OF THE INGREDIENTS ARE LISTED.
SECTION 313 (SPECIFIC TOXIC CHEMICAL LISTINGS):
9016-87-9 DIPHENYLMETHANEDIISOCYANATE,ISOMERES AND HOMOLOGUES
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE
TSCA (TOXIC SUBSTANCES CONTROL ACT): ALL INGREDIENTS ARE LISTED.
PROPOSITION 65 (CALIFORNIA):
CHEMICALS KNOWN TO CAUSE CANCER: NONE OF THE INGREDIENTS ARE LISTED.
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR FEMALES:
NONE OF THE INGREDIENTS ARE LISTED.
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR MALES:
NONE OF THE INGREDIENTS ARE LISTED.
CHEMICALS KNOWN TO CAUSE DEVELOPMENTAL TOXICITY:
NONE OF THE INGREDIENTS ARE LISTED.
CARCINOGENIC CATEGORIES:
EPA (ENVIRONMENTAL PROTECTION AGENCY):
9016-87-9 DIPHENYLMETHANEDIISOCYANATE,ISOMERES AND HOMOLOGUES CBD
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE D, CBD
HALOGENATED HYDROCARBON II
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
NONE OF THE INGREDIENTS ARE LISTED.
NIOSH-CA (NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH):
NONE OF THE INGREDIENTS ARE LISTED.
CANADIAN DOMESTIC SUBSTANCES LIST (DSL): ALL INGREDIENTS ARE LISTED.
| 16 OTHER INFORMATION | |
THIS INFORMATION IS BASED ON OUR PRESENT KNOWLEDGE. HOWEVER, THIS SHALL
NOT CONSTITUTE A GUARANTEE FOR ANY SPECIFIC PRODUCT FEATURES AND SHALL
NOT ESTABLISH A LEGALLY VALID CONTRACTUAL RELATIONSHIP.
DATE OF PREPARATION / LAST REVISION: APRIL 11, 2017 / -
ABBREVIATIONS AND ACRONYMS:
LDLO: LOWEST LETHAL DOSE OBSERVED
ADR:
EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS
GOODS BY ROAD
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
DOT: US DEPARTMENT OF TRANSPORTATION
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
CAS: CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY)
LC50: LETHAL CONCENTRATION, 50 PERCENT
LD50: LETHAL DOSE, 50 PERCENT
PBT: PERSISTENT, BIOACCUMULATIVE AND TOXIC
VPVB: VERY PERSISTENT AND VERY BIOACCUMULATIVE
NIOSH: NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY
OSHA: OCCUPATIONAL SAFETY & HEALTH
PRESS. GAS: GASES UNDER PRESSURE - COMPRESSED GAS
FLAM. LIQ. 2: FLAMMABLE LIQUIDS - CATEGORY 2
ACUTE TOX. 4: ACUTE TOXICITY - CATEGORY 4
SKIN IRRIT. 2: SKIN CORROSION/IRRITATION - CATEGORY 2
EYE IRRIT. 2A: SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 2A
RESP. SENS. 1: RESPIRATORY SENSITISATION - CATEGORY 1
SKIN SENS. 1: SKIN SENSITISATION - CATEGORY 1
STOT SE 3: SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - CATEGORY 3
STOT RE 2: SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - CATEGORY 2
SOURCES:
WEBSITE, EUROPEAN CHEMICALS AGENCY (ECHA.EUROPA.EU)
WEBSITE, US EPA SUBSTANCE REGISTRY SERVICES (OFMPUB.EPA.GOV/SOR
INTERNET/REGISTRY/SUBSTREG/HOME/OVERVIEW/HOME.DO)
WEBSITE, CHEMICAL ABSTRACTS REGISTRY, AMERICAN CHEMICAL SOCIETY
(WWW.CAS.ORG)
PATTY'S INDUSTRIAL HYGIENE, 6TH ED., ROSE, VERNON, ED. ISBN:
978-0-470-07488-6
CASARETT AND DOULL'S TOXICOLOGY:
THE BASIC SCIENCE OF POISONS, 8TH ED., KLAASEN, CURTIS D., ED., ISBN:
978-0-07-176923-5.
SAFETY DATA SHEETS, INDIVIDUAL MANUFACTURERS
SDS PREPARED BY:
CHEMTEL INC.
1305 NORTH FLORIDA AVENUE
TAMPA, FLORIDA 33602-2902
USA
TOLL FREE NORTH AMERICA: 1-888-255-3924
INTL.: +01 813-248-0573
WEBSITE: WWW.CHEMTELINC.COM
CP
CONVENIENCE PRODUCTS
SAFETY DATA SHEET
ACC. TO OSHA HCS (29 CFR 1910.1200) AND WHMIS 2015 REGULATIONS
PRINTING DATE: APRIL 11, 2017
REVISION: APRIL 11, 2017
| 1 IDENTIFICATION | |
PRODUCT IDENTIFIER:
TRADE NAME: TOUCH 'N SEAL MINE FOAM PART B
PRODUCT CODE: EHS 2322 B
RECOMMENDED USE AND RESTRICTION ON USE:
RECOMMENDED USE: POLYURETHANE-SEALANT
RESTRICTIONS ON USE: NO RELEVANT INFORMATION AVAILABLE.
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER/SUPPLIER:
CONVENIENCE PRODUCTS
866 HORAN DRIVE
PACIFIC, MO 63026
PHONE: 636-349-5855
TOLL-FREE: 1-800-325-6180
EMERGENCY TELEPHONE NUMBER:
CHEMTEL INC.
(800)255-3924 (NORTH AMERICA)
+1 (813)248-0585 (INTERNATIONAL)
| 2 HAZARD(S) IDENTIFICATION | |
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
PRESS. GAS:
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
ACUTE TOX. 4:
H302: HARMFUL IF SWALLOWED.
SKIN IRRIT. 2:
H315: CAUSES SKIN IRRITATION.
EYE IRRIT. 2A:
H319: CAUSES SERIOUS EYE IRRITATION.
MUTA. 1B:
H340: MAY CAUSE GENETIC DEFECTS.
REPR. 2:
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
STOT SE 3:
H335: MAY CAUSE RESPIRATORY IRRITATION.
LABEL ELEMENTS:
GHS LABEL ELEMENTS:
THE PRODUCT IS CLASSIFIED AND LABELED ACCORDING TO THE GLOBALLY HARMONIZED
SYSTEM (GHS).
HAZARD PICTOGRAMS:
GHS04: GAS CYLINDER
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
H302: HARMFUL IF SWALLOWED.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H340: MAY CAUSE GENETIC DEFECTS.
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
H335: MAY CAUSE RESPIRATORY IRRITATION.
PRECAUTIONARY STATEMENTS:
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P233: KEEP CONTAINER TIGHTLY CLOSED.
P261: AVOID BREATHING MIST, VAPORS, OR SPRAY.
P264: WASH THOROUGHLY AFTER HANDLING.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P280: WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION.
P301+P312:
IF SWALLOWED: CALL A POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P304+P340:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P330: RINSE MOUTH.
P332+P313:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P362+P364: TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
P405: STORE LOCKED UP.
P410+P403: PROTECT FROM SUNLIGHT. STORE IN A WELL-VENTILATED PLACE.
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
OTHER HAZARDS:
THERE ARE NO OTHER HAZARDS NOT OTHERWISE CLASSIFIED THAT HAVE BEEN
IDENTIFIED.
| 3 COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL CHARACTERIZATION: MIXTURES
COMPONENTS:
POLYETHER POLYOL 25-50%
ACUTE TOX. 4, H302; SKIN IRRIT. 2, H315;
EYE IRRIT. 2A, H319; STOT SE 3, H335
811-97-2 NORFLURANE 10-25%
PRESS. GAS, H280
SIMPLE ASPHYXIANT
68441-62-3 HALOGENATED ALIPHATIC POLYETHER POLYOL 10-25%
ACUTE TOX. 4, H302; EYE IRRIT. 2A, H319
13674-84-5 TRIS(2-CHLORISOPROPYL)-PHOSPHATE 10-20%
ACUTE TOX. 4, H302
756-79-6 DIMETHYL METHYLPHOSPHONATE <10%
MUTA. 1B, H340; REPR. 2, H361
EYE IRRIT. 2A, H319
HALOGENATED HYDROCARBON <10%
FLAM. LIQ. 2, H225
ACUTE TOX. 4, H332
ADDITIONAL INFORMATION:
FOR THE LISTED INGREDIENT(S), THE IDENTITY AND/OR EXACT PERCENTAGE(S)
ARE BEING WITHHELD AS A TRADE SECRET.
FOR THE WORDING OF THE LISTED HAZARD STATEMENTS REFER TO SECTION 16.
| 4 FIRST-AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
AFTER INHALATION:
SUPPLY FRESH AIR; CONSULT DOCTOR IN CASE OF COMPLAINTS.
PROVIDE OXYGEN TREATMENT IF AFFECTED PERSON HAS DIFFICULTY BREATHING.
AFTER SKIN CONTACT:
DO NOT PULL SOLIDIFIED PRODUCT AWAY FROM THE SKIN.
IMMEDIATELY WASH WITH WATER AND SOAP AND RINSE THOROUGHLY.
IF SKIN IRRITATION CONTINUES, CONSULT A DOCTOR.
AFTER EYE CONTACT:
REMOVE CONTACT LENSES IF WORN.
RINSE OPENED EYE FOR SEVERAL MINUTES UNDER RUNNING WATER. IF SYMPTOMS
PERSIST, CONSULT A DOCTOR.
AFTER SWALLOWING:
UNLIKELY ROUTE OF EXPOSURE.
RINSE OUT MOUTH AND THEN DRINK PLENTY OF WATER.
DO NOT INDUCE VOMITING; IMMEDIATELY CALL FOR MEDICAL HELP.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
HEADACHE
COUGHING
DIZZINESS
BREATHING DIFFICULTY
MAY CAUSE RESPIRATORY IRRITATION.
IRRITANT TO SKIN AND MUCOUS MEMBRANES.
CAUSES EYE IRRITATION.
GASTRIC OR INTESTINAL DISORDERS
DANGER:
HARMFUL IF SWALLOWED.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
MAY CAUSE GENETIC DEFECTS.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
MEDICAL SUPERVISION FOR AT LEAST 48 HOURS.
IF NECESSARY OXYGEN RESPIRATION TREATMENT.
| 5 FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING AGENTS:
CO2, EXTINGUISHING POWDER OR WATER SPRAY. FIGHT LARGER FIRES WITH WATER
SPRAY.
FOR SAFETY REASONS UNSUITABLE EXTINGUISHING AGENTS: NONE.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
DANGER OF RECEPTACLES BURSTING BECAUSE OF HIGH VAPOR PRESSURE IF HEATED.
FORMATION OF TOXIC GASES IS POSSIBLE DURING HEATING OR IN CASE OF FIRE.
ADVICE FOR FIREFIGHTERS:
PROTECTIVE EQUIPMENT:
WEAR SELF-CONTAINED RESPIRATORY PROTECTIVE DEVICE.
WEAR FULLY PROTECTIVE SUIT.
ADDITIONAL INFORMATION: COOL ENDANGERED RECEPTACLES WITH WATER SPRAY.
| 6 ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE RESPIRATORY PROTECTIVE DEVICE AGAINST THE EFFECTS OF
FUMES/DUST/AEROSOL.
ENSURE ADEQUATE VENTILATION.
WEAR PROTECTIVE EQUIPMENT. KEEP UNPROTECTED PERSONS AWAY.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW UNDILUTED PRODUCT OR LARGE QUANTITIES OF IT TO REACH GROUND
WATER, WATER COURSE OR SEWAGE SYSTEM.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
ALLOW TO SOLIDIFY. PICK UP MECHANICALLY.
SEND FOR RECOVERY OR DISPOSAL IN SUITABLE RECEPTACLES.
REFERENCE TO OTHER SECTIONS:
SEE SECTION 7 FOR INFORMATION ON SAFE HANDLING.
SEE SECTION 8 FOR INFORMATION ON PERSONAL PROTECTION EQUIPMENT.
SEE SECTION 13 FOR DISPOSAL INFORMATION.
| 7 HANDLING AND STORAGE | |
HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
USE ONLY IN WELL VENTILATED AREAS.
KEEP OUT OF REACH OF CHILDREN.
AVOID CONTACT WITH THE EYES AND SKIN.
INFORMATION ABOUT PROTECTION AGAINST EXPLOSIONS AND FIRES:
PRESSURIZED CONTAINER:
PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO TEMPERATURES EXCEEDING
120 DEG. F / 49 DEG. C, I.E. ELECTRIC LIGHTS. DO NOT PIERCE OR BURN,
EVEN AFTER USE.
DO NOT SPRAY ON A NAKED FLAME OR ANY INCANDESCENT MATERIAL.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
REQUIREMENTS TO BE MET BY STOREROOMS AND RECEPTACLES:
OBSERVE OFFICIAL REGULATIONS ON STORING PACKAGINGS WITH PRESSURIZED
CONTAINERS.
AVOID STORAGE NEAR EXTREME HEAT, IGNITION SOURCES OR OPEN FLAME.
INFORMATION ABOUT STORAGE IN ONE COMMON STORAGE FACILITY:
STORE AWAY FROM FOODSTUFFS.
DO NOT STORE TOGETHER WITH OXIDIZING AND ACIDIC MATERIALS.
FURTHER INFORMATION ABOUT STORAGE CONDITIONS:
STORE IN A COOL PLACE. HEAT WILL INCREASE PRESSURE AND MAY LEAD TO THE
RECEPTACLE BURSTING.
SPECIFIC END USE(S): NO RELEVANT INFORMATION AVAILABLE.
| 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
COMPONENTS WITH LIMIT VALUES THAT REQUIRE MONITORING AT THE WORKPLACE:
811-97-2 NORFLURANE:
WEEL (USA):
LONG-TERM VALUE: 1000 PPM
HALOGENATED HYDROCARBON:
PEL (USA):
LONG-TERM VALUE: 790 MG/M3, 200 PPM
REL (USA):
LONG-TERM VALUE: 790 MG/M3, 200 PPM
TLV (USA):
LONG-TERM VALUE: 790 MG/M3, 200 PPM
EL (CANADA):
LONG-TERM VALUE: 200 PPM
EV (CANADA):
SHORT-TERM VALUE: 990 MG/M3, 250 PPM
LONG-TERM VALUE: 790 MG/M3, 200 PPM
LMPE (MEXICO):
LONG-TERM VALUE: 200 PPM
EXPOSURE CONTROLS:
PERSONAL PROTECTIVE EQUIPMENT:
GENERAL PROTECTIVE AND HYGIENIC MEASURES:
THE USUAL PRECAUTIONARY MEASURES FOR HANDLING CHEMICALS SHOULD BE FOLLOWED.
KEEP AWAY FROM FOODSTUFFS, BEVERAGES AND FEED.
IMMEDIATELY REMOVE ALL SOILED AND CONTAMINATED CLOTHING.
PREGNANT WOMEN SHOULD STRICTLY AVOID INHALATION OR SKIN CONTACT.
WASH HANDS BEFORE BREAKS AND AT THE END OF WORK.
AVOID CONTACT WITH THE EYES AND SKIN.
ENGINEERING CONTROLS: NO RELEVANT INFORMATION AVAILABLE.
BREATHING EQUIPMENT:
USE SUITABLE RESPIRATORY PROTECTIVE DEVICE IN CASE OF INSUFFICIENT
VENTILATION.
USE SUITABLE RESPIRATORY PROTECTIVE DEVICE WHEN HIGH CONCENTRATIONS ARE
PRESENT.
PROTECTION OF HANDS: PROTECTIVE GLOVES
THE GLOVE MATERIAL HAS TO BE IMPERMEABLE AND RESISTANT TO THE PRODUCT/THE
SUBSTANCE/THE PREPARATION.
EYE PROTECTION: SAFETY GLASSES
BODY PROTECTION: PROTECTIVE WORK CLOTHING
LIMITATION AND SUPERVISION OF EXPOSURE INTO THE ENVIRONMENT:
NO RELEVANT INFORMATION AVAILABLE.
RISK MANAGEMENT MEASURES: NO RELEVANT INFORMATION AVAILABLE.
| 9 PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE:
FORM: AEROSOLIZED LIQUID WITH COMPRESSED GAS IN CYLINDERS
COLOR: NOT DETERMINED.
ODOR: SWEET
ODOR THRESHOLD: NOT DETERMINED.
PH-VALUE: NOT DETERMINED.
MELTING POINT/MELTING RANGE: NOT DETERMINED.
BOILING POINT/BOILING RANGE: -26 DEG. C (-15 DEG. F)
FLASH POINT: NOT APPLICABLE, AS AEROSOL.
FLAMMABILITY (SOLID, GASEOUS): NOT APPLICABLE.
AUTO-IGNITION TEMPERATURE: >260 DEG. C (>500 DEG. F)
DECOMPOSITION TEMPERATURE: NOT DETERMINED.
DANGER OF EXPLOSION: PRODUCT DOES NOT PRESENT AN EXPLOSION HAZARD.
EXPLOSION LIMITS:
LOWER: NOT DETERMINED.
UPPER: NOT DETERMINED.
VAPOR PRESSURE AT 20 DEG. C (68 DEG. F): 5716 HPA (4287 MMHg)
DENSITY:
RELATIVE DENSITY: NOT DETERMINED.
VAPOR DENSITY: NOT DETERMINED.
EVAPORATION RATE: NOT APPLICABLE.
SOLUBILITY IN / MISCIBILITY WITH WATER: FULLY MISCIBLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT DETERMINED.
VISCOSITY:
DYNAMIC: NOT DETERMINED.
KINEMATIC: NOT DETERMINED.
VOC CONTENT: 32.0 G/L
OTHER INFORMATION: NO RELEVANT INFORMATION AVAILABLE.
| 10 STABILITY AND REACTIVITY | |
REACTIVITY: NO RELEVANT INFORMATION AVAILABLE.
CHEMICAL STABILITY: STABLE UNDER NORMAL TEMPERATURES AND PRESSURES.
THERMAL DECOMPOSITION / CONDITIONS TO BE AVOIDED:
DANGER OF RECEPTACLES BURSTING BECAUSE OF HIGH VAPOR PRESSURE IF HEATED.
POSSIBILITY OF HAZARDOUS REACTIONS:
REACTS WITH CATALYSTS.
REACTS WITH PEROXIDES.
REACTS WITH STRONG ACIDS AND OXIDIZING AGENTS.
EXOTHERMIC POLYMERIZATION.
CONDITIONS TO AVOID: EXCESSIVE HEAT.
INCOMPATIBLE MATERIALS: OXIDIZERS
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON MONOXIDE AND CARBON DIOXIDE
HALOGENATED HYDROCARBONS
PHOSPHORUS COMPOUNDS
NITROGEN OXIDES (NOX)
CHLORINE COMPOUNDS
POISONOUS GASES/VAPORS
| 11 TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
LD/LC50 VALUES THAT ARE RELEVANT FOR CLASSIFICATION:
68441-62-3 HALOGENATED ALIPHATIC POLYETHER POLYOL:
ORAL:
LD50: 1337 MG/KG (RAT)
13674-84-5 TRIS(2-CHLORISOPROPYL)-PHOSPHATE:
ORAL:
LD50: 1101 MG/KG (RAT)
PRIMARY IRRITANT EFFECT:
ON THE SKIN: IRRITANT TO SKIN AND MUCOUS MEMBRANES.
ON THE EYE: IRRITATING EFFECT.
SENSITIZATION:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
NONE OF THE INGREDIENTS ARE LISTED.
NTP (NATIONAL TOXICOLOGY PROGRAM): NONE OF THE INGREDIENTS ARE LISTED.
OSHA-CA (OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION):
NONE OF THE INGREDIENTS ARE LISTED.
PROBABLE ROUTE(S) OF EXPOSURE:
INHALATION.
EYE CONTACT.
SKIN CONTACT.
ACUTE EFFECTS (ACUTE TOXICITY, IRRITATION AND CORROSIVITY):
HARMFUL IF SWALLOWED.
IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
CMR EFFECTS (CARCINOGENITY, MUTAGENICITY AND TOXICITY FOR REPRODUCTION):
MUTA. 1B, REPR. 2
GERM CELL MUTAGENICITY: MAY CAUSE GENETIC DEFECTS.
CARCINOGENICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
REPRODUCTIVE TOXICITY: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
STOT-SINGLE EXPOSURE: MAY CAUSE RESPIRATORY IRRITATION.
STOT-REPEATED EXPOSURE:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
ASPIRATION HAZARD:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
| 12 ECOLOGICAL INFORMATION | |
TOXICITY:
AQUATIC TOXICITY:
THE PRODUCT CONTAINS MATERIALS THAT ARE HARMFUL TO THE ENVIRONMENT.
13674-84-5 TRIS(2-CHLORISOPROPYL)-PHOSPHATE:
LC50: 51 MG/L (PIMEPHALES PROMELAS)
EC50: 131 MG/L (DAPHNIA)
PERSISTENCE AND DEGRADABILITY:
THE PRODUCT IS PARTIALLY BIODEGRADABLE. SIGNIFICANT RESIDUALS REMAIN.
BIOACCUMULATIVE POTENTIAL: NO RELEVANT INFORMATION AVAILABLE.
MOBILITY IN SOIL: NO RELEVANT INFORMATION AVAILABLE.
ECOTOXICAL EFFECTS:
REMARK:
DUE TO MECHANICAL ACTIONS OF THE PRODUCT (E.G. AGGLUTINATIONS), DAMAGES
MAY OCCUR.
ADDITIONAL ECOLOGICAL INFORMATION:
GENERAL NOTES:
DO NOT ALLOW UNDILUTED PRODUCT OR LARGE QUANTITIES OF IT TO REACH GROUND
WATER, WATER COURSE OR SEWAGE SYSTEM.
DUE TO AVAILABLE DATA ON ELIMINABILITY/DECOMPOSITION AND BIOACCUMULATION
POTENTIAL PROLONGED TERM DAMAGE OF THE ENVIRONMENT CAN NOT BE EXCLUDED.
RESULTS OF PBT AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE.
VPVB: NOT APPLICABLE.
OTHER ADVERSE EFFECTS: NO RELEVANT INFORMATION AVAILABLE.
| 13 DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
RECOMMENDATION:
CONTACT WASTE PROCESSORS FOR RECYCLING INFORMATION.
CAN BE DISPOSED OF WITH HOUSEHOLD GARBAGE AFTER SOLIDIFICATION FOLLOWING
CONSULTATION WITH THE WASTE DISPOSAL FACILITY OPERATOR AND THE PERTINENT
AUTHORITIES AND ADHERING TO THE NECESSARY TECHNICAL REGULATIONS. THE USER
OF THIS MATERIAL HAS THE RESPONSIBILITY TO DISPOSE OF UNUSED MATERIAL,
RESIDUES AND CONTAINERS IN COMPLIANCE WITH ALL RELEVANT LOCAL, STATE AND
FEDERAL LAWS AND REGULATIONS REGARDING TREATMENT, STORAGE AND DISPOSAL
FOR HAZARDOUS AND NONHAZARDOUS WASTES.
UNCLEANED PACKAGINGS:
RECOMMENDATION: DISPOSAL MUST BE MADE ACCORDING TO OFFICIAL REGULATIONS.
| 14 TRANSPORT INFORMATION | |
UN-NUMBER:
DOT, ADR, IMDG, IATA: UN3500
UN PROPER SHIPPING NAME:
DOT, IATA:
CHEMICAL UNDER PRESSURE, N.O.S. (FLUORINATED HYDROCARBON, NITROGEN)
ADR, IMDG:
CHEMICAL UNDER PRESSURE, N.O.S. (FLUORINATED HYDROCARBON, NITROGEN)
TRANSPORT HAZARD CLASS(ES):
DOT: NON-FLAMMABLE GAS, CLASS/DIVISION 2.2
CLASS: 2.2
LABEL: 2.2
ADR: CLASS 2.2, NON-FLAMMABLE AND NON-TOXIC GASES
CLASS: 2 8A GASES
LABEL: 2.2
IMDG, IATA: CLASS 2.2, NON-FLAMMABLE AND NON-TOXIC GASES
CLASS: 2 GASES
LABEL: 2.2
PACKING GROUP: THIS UN-NUMBER IS NOT ASSIGNED A PACKING GROUP.
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO
SPECIAL PRECAUTIONS FOR USER:
WARNING: GASES
DANGER CODE (KEMLER): 20
EMS NUMBER: F-C, S-V
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC CODE:
NOT APPLICABLE.
| 15 REGULATORY INFORMATION | |
SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR
THE SUBSTANCE OR MIXTURE:
UNITED STATES (USA):
SARA:
SECTION 302 (EXTREMELY HAZARDOUS SUBSTANCES):
NONE OF THE INGREDIENTS ARE LISTED.
SECTION 355 (EXTREMELY HAZARDOUS SUBSTANCES):
NONE OF THE INGREDIENTS ARE LISTED.
SECTION 313 (SPECIFIC TOXIC CHEMICAL LISTINGS):
NONE OF THE INGREDIENTS ARE LISTED.
TSCA (TOXIC SUBSTANCES CONTROL ACT): ALL INGREDIENTS ARE LISTED.
PROPOSITION 65 (CALIFORNIA):
CHEMICALS KNOWN TO CAUSE CANCER: NONE OF THE INGREDIENTS ARE LISTED.
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR FEMALES:
NONE OF THE INGREDIENTS ARE LISTED.
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR MALES:
NONE OF THE INGREDIENTS ARE LISTED.
CHEMICALS KNOWN TO CAUSE DEVELOPMENTAL TOXICITY:
NONE OF THE INGREDIENTS ARE LISTED.
CARCINOGENIC CATEGORIES:
EPA (ENVIRONMENTAL PROTECTION AGENCY):
HALOGENATED HYDROCARBON II
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
NONE OF THE INGREDIENTS ARE LISTED.
NIOSH-CA (NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH):
NONE OF THE INGREDIENTS ARE LISTED.
CANADIAN DOMESTIC SUBSTANCES LIST (DSL): ALL INGREDIENTS ARE LISTED.
| 16 OTHER INFORMATION | |
THIS INFORMATION IS BASED ON OUR PRESENT KNOWLEDGE. HOWEVER, THIS SHALL
NOT CONSTITUTE A GUARANTEE FOR ANY SPECIFIC PRODUCT FEATURES AND SHALL
NOT ESTABLISH A LEGALLY VALID CONTRACTUAL RELATIONSHIP.
DATE OF PREPARATION / LAST REVISION: APRIL 11, 2017 / -
ABBREVIATIONS AND ACRONYMS:
LDLO: LOWEST LETHAL DOSE OBSERVED
ADR:
EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS
GOODS BY ROAD
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
DOT: US DEPARTMENT OF TRANSPORTATION
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
CAS: CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY)
LC50: LETHAL CONCENTRATION, 50 PERCENT
LD50: LETHAL DOSE, 50 PERCENT
PBT: PERSISTENT, BIOACCUMULATIVE AND TOXIC
VPVB: VERY PERSISTENT AND VERY BIOACCUMULATIVE
NIOSH: NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY
OSHA: OCCUPATIONAL SAFETY & HEALTH
PRESS. GAS: GASES UNDER PRESSURE - COMPRESSED GAS
FLAM. LIQ. 2: FLAMMABLE LIQUIDS - CATEGORY 2
ACUTE TOX. 4: ACUTE TOXICITY - CATEGORY 4
SKIN IRRIT. 2: SKIN CORROSION/IRRITATION - CATEGORY 2
EYE IRRIT. 2A: SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 2A
MUTA. 1B: GERM CELL MUTAGENICITY - CATEGORY 1B
REPR. 2: REPRODUCTIVE TOXICITY - CATEGORY 2
STOT SE 3: SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - CATEGORY 3
SOURCES:
WEBSITE, EUROPEAN CHEMICALS AGENCY (ECHA.EUROPA.EU)
WEBSITE, US EPA SUBSTANCE REGISTRY SERVICES (OFMPUB.EPA.GOV/SOR
INTERNET/REGISTRY/SUBSTREG/HOME/OVERVIEW/HOME.DO)
WEBSITE, CHEMICAL ABSTRACTS REGISTRY, AMERICAN CHEMICAL SOCIETY
(WWW.CAS.ORG)
PATTY'S INDUSTRIAL HYGIENE, 6TH ED., ROSE, VERNON, ED. ISBN:
978-0-470-07488-6
CASARETT AND DOULL'S TOXICOLOGY:
THE BASIC SCIENCE OF POISONS, 8TH ED., KLAASEN, CURTIS D., ED., ISBN:
978-0-07-176923-5.
SAFETY DATA SHEETS, INDIVIDUAL MANUFACTURERS
SDS PREPARED BY:
CHEMTEL INC.
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