| Common Name: | E-NOX CLEAN |
| Manufacturer: | WALTER SURFACE TECHNOLOGIES |
| SDS Revision Date: | 11/30/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 328XU4, 328XU5, 444C67 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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CONFORMS TO HAZCOM 2012/UNITED STATES
BIO-CIRCLE(R*)
A DIVISION OF WALTER SURFACE TECHNOLOGIES
SAFETY DATA SHEET
E-NOX CLEAN
| SECTION 1. IDENTIFICATION |  |
GHS PRODUCT IDENTIFIER: E-NOX CLEAN
PRODUCT CODE:
53-G 303 (500 ML), 53-G 306 (5L), 53-G 307 (20L), 53-G 308 (208L)
SDS NO.: L-59E
PRODUCT TYPE: LIQUID.
IDENTIFIED USES: HIGH STRENGTH STAINLESS STEEL CLEANER.
MANUFACTURER:
WALTER SURFACE TECHNOLOGIES INC.
BIO-CIRCLE - A DIVISION OF WALTER SURFACE TECHNOLOGIES INC.
810 DAY HILL ROAD
WINDSOR, CT 06095
UNITED STATES
GENERAL INFORMATION: 18665925837
INFO.US@WALTER.COM
WWW.WALTER.COM
EMERGENCY TELEPHONE NUMBER (WITH HOURS OF OPERATION):
INFOTRAC(R*): 1-800-535-5053
OUTSIDE U.S.A. CALL COLLECT: 1-352-323-3500 24 HOURS/DAY, 7 DAYS/WEEK.
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
SKIN CORROSION/IRRITATION: CATEGORY 1
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 1
AQUATIC HAZARD (ACUTE): CATEGORY 3
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS: CORROSION
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
H402: HARMFUL TO AQUATIC LIFE.
PRECAUTIONARY STATEMENTS:
PREVENTION:
P280:
WEAR PROTECTIVE GLOVES. WEAR EYE OR FACE PROTECTION. WEAR PROTECTIVE
CLOTHING.
P273: AVOID RELEASE TO THE ENVIRONMENT.
P264: WASH HANDS THOROUGHLY AFTER HANDLING.
RESPONSE:
P304 + P340 + P310:
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN.
P301 + P310 + P330 + P331:
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. RINSE MOUTH. DO NOT INDUCE
VOMITING.
P303 + P361 + P353 + P363 + P310:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER OR
SHOWER. WASH CONTAMINATED CLOTHING BEFORE REUSE. IMMEDIATELY CALL A POISON
CENTER OR PHYSICIAN.
P305 + P351 + P338 + P310:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON CENTER
OR PHYSICIAN.
STORAGE:
P405: STORE LOCKED UP.
DISPOSAL:
P501:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
HAZARDS NOT OTHERWISE CLASSIFIED: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
PRODUCT CODE:
53-G 303 (500 ML), 53-G 306 (5L), 53-G 307 (20L), 53-G 308 (208L)
CAS NUMBER/OTHER IDENTIFIERS:
CAS NUMBER: NOT APPLICABLE.
INGREDIENT NAME % CAS NUMBER
PHOSPHORIC ACID 10 - 30 7664-38-2
BENZENESULFONIC ACID, C10-13-ALKYL DERIVS., 1 - 5 68411-30-3
SODIUM SALTS
ALCOHOLS, C12-14, ETHOXYLATED 0.1 - 1 68439-50-9
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS DUE
TO BATCH VARIATION.
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH OR THE ENVIRONMENT AND HENCE REQUIRE
REPORTING IN THIS SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
GET MEDICAL ATTENTION IMMEDIATELY. CALL A POISON CENTER OR PHYSICIAN.
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE UPPER
AND LOWER EYELIDS. CONTINUE TO RINSE FOR AT LEAST 20 MINUTES. CHEMICAL
BURNS MUST BE TREATED PROMPTLY BY A PHYSICIAN.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF NOT BREATHING, IF BREATHING IS IRREGULAR OR IF RESPIRATORY
ARREST OCCURS, PROVIDE ARTIFICIAL RESPIRATION OR OXYGEN BY TRAINED
PERSONNEL. IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE
MOUTH-TO-MOUTH RESUSCITATION. GET MEDICAL ATTENTION IF ADVERSE HEALTH
EFFECTS PERSIST OR ARE SEVERE. IF UNCONSCIOUS, PLACE IN RECOVERY POSITION
AND GET MEDICAL ATTENTION IMMEDIATELY. IN CASE OF INHALATION OF
DECOMPOSITION PRODUCTS IN A FIRE, SYMPTOMS MAY BE DELAYED. THE EXPOSED
PERSON MAY NEED TO BE KEPT UNDER MEDICAL SURVEILLANCE FOR 48 HOURS.
SKIN CONTACT:
GET MEDICAL ATTENTION IMMEDIATELY. CALL A POISON CENTER OR PHYSICIAN. WASH
CONTAMINATED SKIN WITH SOAP AND WATER. WASH CONTAMINATED CLOTHING
THOROUGHLY WITH WATER BEFORE REMOVING IT, OR WEAR GLOVES. CONTINUE TO RINSE
FOR AT LEAST 20 MINUTES. CHEMICAL BURNS MUST BE TREATED PROMPTLY BY A
PHYSICIAN. WASH CLOTHING BEFORE REUSE. CLEAN SHOES THOROUGHLY BEFORE REUSE.
INGESTION:
GET MEDICAL ATTENTION IMMEDIATELY. CALL A POISON CENTER OR PHYSICIAN. WASH
OUT MOUTH WITH WATER. REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A
POSITION COMFORTABLE FOR BREATHING. IF MATERIAL HAS BEEN SWALLOWED AND THE
EXPOSED PERSON IS CONSCIOUS, GIVE SMALL QUANTITIES OF WATER TO DRINK. STOP
IF THE EXPOSED PERSON FEELS SICK AS VOMITING MAY BE DANGEROUS. DO NOT
INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL. CHEMICAL
BURNS MUST BE TREATED PROMPTLY BY A PHYSICIAN. NEVER GIVE ANYTHING BY MOUTH
TO AN UNCONSCIOUS PERSON. IF UNCONSCIOUS, PLACE IN RECOVERY POSITION AND
GET MEDICAL ATTENTION IMMEDIATELY.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INHALATION:
MAY GIVE OFF GAS, VAPOR OR DUST THAT IS VERY IRRITATING OR CORROSIVE TO THE
RESPIRATORY SYSTEM.
SKIN CONTACT: CAUSES SEVERE BURNS.
INGESTION: MAY CAUSE BURNS TO MOUTH, THROAT AND STOMACH.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN
WATERING
REDNESS
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
REDNESS
BLISTERING MAY OCCUR
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING: STOMACH PAINS
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF
NECESSARY:
NOTES TO PHYSICIAN:
TREAT SYMPTOMATICALLY. CONTACT POISON TREATMENT SPECIALIST IMMEDIATELY IF
LARGE QUANTITIES HAVE BEEN INGESTED OR INHALED.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS.
IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION. WASH CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE
REMOVING IT, OR WEAR GLOVES.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE AN EXTINGUISHING AGENT SUITABLE FOR THE SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
THIS MATERIAL IS HARMFUL TO AQUATIC LIFE. FIRE WATER CONTAMINATED WITH THIS
MATERIAL MUST BE CONTAINED AND PREVENTED FROM BEING DISCHARGED TO ANY
WATERWAY, SEWER OR DRAIN.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON DIOXIDE
CARBON MONOXIDE
SULFUR OXIDES
PHOSPHORUS OXIDES
METAL OXIDE/OXIDES
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL MEASURES ARE REQUIRED.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE OPERATED
IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL. DO
NOT BREATHE VAPOR OR MIST. PROVIDE ADEQUATE VENTILATION. WEAR APPROPRIATE
RESPIRATOR WHEN VENTILATION IS INADEQUATE. PUT ON APPROPRIATE PERSONAL
PROTECTIVE EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALIZED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE OF
ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE ALSO
THE INFORMATION IN "FOR NONEMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL OR
AIR). WATER POLLUTING MATERIAL. MAY BE HARMFUL TO THE ENVIRONMENT IF
RELEASED IN LARGE QUANTITIES.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. DILUTE WITH
WATER AND MOP UP IF WATER-SOLUBLE. ALTERNATIVELY, OR IF WATER-INSOLUBLE,
ABSORB WITH AN INERT DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE
DISPOSAL CONTAINER. DISPOSE OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
LARGE SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. APPROACH
RELEASE FROM UPWIND. PREVENT ENTRY INTO SEWERS, WATER COURSES, BASEMENTS OR
CONFINED AREAS. WASH SPILLAGES INTO AN EFFLUENT TREATMENT PLANT OR PROCEED
AS FOLLOWS. CONTAIN AND COLLECT SPILLAGE WITH NON-COMBUSTIBLE, ABSORBENT
MATERIAL E.G. SAND, EARTH, VERMICULITE OR DIATOMACEOUS EARTH AND PLACE IN
CONTAINER FOR DISPOSAL ACCORDING TO LOCAL REGULATIONS (SEE SECTION 13).
THE SPILLED MATERIAL MAY BE NEUTRALIZED WITH SODIUM CARBONATE, SODIUM
BICARBONATE OR SODIUM HYDROXIDE. DISPOSE OF VIA A LICENSED WASTE DISPOSAL
CONTRACTOR. CONTAMINATED ABSORBENT MATERIAL MAY POSE THE SAME HAZARD AS THE
SPILLED PRODUCT.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). DO NOT
GET IN EYES OR ON SKIN OR CLOTHING. DO NOT BREATHE VAPOR OR MIST. DO NOT
INGEST. AVOID RELEASE TO THE ENVIRONMENT. IF DURING NORMAL USE THE MATERIAL
PRESENTS A RESPIRATORY HAZARD, USE ONLY WITH ADEQUATE VENTILATION OR WEAR
APPROPRIATE RESPIRATOR. KEEP IN THE ORIGINAL CONTAINER OR AN APPROVED
ALTERNATIVE MADE FROM A COMPATIBLE MATERIAL, KEPT TIGHTLY CLOSED WHEN NOT
IN USE. KEEP AWAY FROM ALKALIS. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE AND
CAN BE HAZARDOUS. DO NOT REUSE CONTAINER.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. SEE ALSO SECTION 8 FOR ADDITIONAL
INFORMATION ON HYGIENE MEASURES. REMOVE CONTAMINATED CLOTHING AND
PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE IN ORIGINAL CONTAINER
PROTECTED FROM DIRECT SUNLIGHT IN A DRY, COOL AND WELL-VENTILATED AREA,
AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10) AND FOOD AND DRINK. STORE
LOCKED UP. SEPARATE FROM ALKALIS. KEEP CONTAINER TIGHTLY CLOSED AND SEALED
UNTIL READY FOR USE. CONTAINERS THAT HAVE BEEN OPENED MUST BE CAREFULLY
RESEALED AND KEPT UPRIGHT TO PREVENT LEAKAGE. DO NOT STORE IN UNLABELED
CONTAINERS. USE APPROPRIATE CONTAINMENT TO AVOID ENVIRONMENTAL
CONTAMINATION.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT NAME EXPOSURE LIMITS
PHOSPHORIC ACID ACGIH TLV (UNITED STATES, 4/2014).
STEL: 3 MG/M3 15 MINUTES.
TWA: 1 MG/M3 8 HOURS.
NIOSH REL (UNITED STATES, 10/2013).
STEL: 3 MG/M3 15 MINUTES.
TWA: 1 MG/M3 10 HOURS.
OSHA PEL (UNITED STATES, 2/2013).
TWA: 1 MG/M3 8 HOURS.
APPROPRIATE ENGINEERING CONTROLS:
NO PERSONAL RESPIRATORY PROTECTIVE EQUIPMENT NORMALLY REQUIRED. AVOID
BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY. WHEN WORKERS ARE FACING
CONCENTRATIONS ABOVE THE EXPOSURE LIMIT THEY MUST USE APPROPRIATE
CERTIFIED RESPIRATORS.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED TO
ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING. WASH CONTAMINATED CLOTHING BEFORE REUSING.
EYE/FACE PROTECTION:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN A
RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO LIQUID
SPLASHES, MISTS, GASES OR DUSTS.
IF CONTACT IS POSSIBLE, THE FOLLOWING PROTECTION SHOULD BE WORN, UNLESS
THE ASSESSMENT INDICATES A HIGHER DEGREE OF PROTECTION:
CHEMICAL SPLASH GOGGLES AND/OR FACE SHIELD. IF INHALATION HAZARDS EXIST, A
FULL-FACE RESPIRATOR MAY BE REQUIRED INSTEAD.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY. CONSIDERING THE PARAMETERS
SPECIFIED BY THE GLOVE MANUFACTURER, CHECK DURING USE THAT THE GLOVES ARE
STILL RETAINING THEIR PROTECTIVE PROPERTIES. IT SHOULD BE NOTED THAT THE
TIME TO BREAKTHROUGH FOR ANY GLOVE MATERIAL MAY BE DIFFERENT FOR DIFFERENT
GLOVE MANUFACTURERS. IN THE CASE OF MIXTURES, CONSISTING OF SEVERAL
SUBSTANCES, THE PROTECTION TIME OF THE GLOVES CANNOT BE ACCURATELY
ESTIMATED.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD BE
SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
USE A NIOSH/MSHA APPROVED RESPIRATOR IF THERE IS A RISK OF EXPOSURE AT
LEVELS EXCEEDING THE EXPOSURE LIMITS. ADVICE SHOULD BE SOUGHT FROM
RESPIRATORY PROTECTION SPECIALISTS.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID. [CLEAR.]
COLOR: YELLOW.
ODOR: CHARACTERISTIC.
ODOR THRESHOLD: NOT AVAILABLE.
PH: 0 TO 1
MELTING POINT: 0 DEG. C (32 DEG. F)
BOILING POINT: 98 DEG. C (208.4 DEG. F)
FLASH POINT: NOT APPLICABLE.
EVAPORATION RATE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE.
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS: NOT APPLICABLE.
VAPOR PRESSURE: NOT AVAILABLE.
VAPOR DENSITY: NOT AVAILABLE.
DENSITY: 1.05 TO 1.15 G/ML @ 20 DEG. C (68 DEG. F)
SOLUBILITY:
SOLUBLE IN THE FOLLOWING MATERIALS: COLD WATER AND HOT WATER.
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT APPLICABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: NOT AVAILABLE.
VOC CONTENT (G/L): 0
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NO SPECIFIC TEST DATA RELATED TO REACTIVITY AVAILABLE FOR THIS PRODUCT OR
ITS INGREDIENTS.
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID: NO SPECIFIC DATA.
INCOMPATIBLE MATERIALS:
REACTIVE OR INCOMPATIBLE WITH THE FOLLOWING MATERIALS:
OXIDIZING MATERIALS, METALS AND ALKALIS.
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
PHOSPHORIC ACID LD50 ORAL RAT 1.25 G/KG
BENZENESULFONIC ACID, LD50 ORAL RAT 404 MG/KG
C10-13-ALKYL DERIVS.,
SODIUM SALTS
IRRITATION/CORROSION:
PRODUCT/INGREDIENT RESULT SPECIES SCORE EXPOSURE OBSERVATION
NAME
BENZENESULFONIC SKIN: RABBIT 0.5 ML
ACID, C10-13-ALKYL MODERATE
DERIVS., SODIUM IRRITANT
SALTS
SENSITIZATION: THERE IS NO DATA AVAILABLE.
CARCINOGENICITY: THERE IS NO DATA AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
THERE IS NO DATA AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE):
THERE IS NO DATA AVAILABLE.
ASPIRATION HAZARD: THERE IS NO DATA AVAILABLE.
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE:
DERMAL CONTACT. EYE CONTACT. INHALATION. INGESTION.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INHALATION:
MAY GIVE OFF GAS, VAPOR OR DUST THAT IS VERY IRRITATING OR CORROSIVE
TO THE RESPIRATORY SYSTEM.
SKIN CONTACT: CAUSES SEVERE BURNS.
INGESTION: MAY CAUSE BURNS TO MOUTH, THROAT AND STOMACH.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN
WATERING
REDNESS
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
REDNESS
BLISTERING MAY OCCUR
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING: STOMACH PAINS
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG
TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS:
NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
POTENTIAL DELAYED EFFECTS:
NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS:
NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
POTENTIAL DELAYED EFFECTS:
NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
POTENTIAL CHRONIC HEALTH EFFECTS:
GENERAL: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
CARCINOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY ESTIMATES:
ROUTE ATE VALUE
ORAL 12511 MG/KG
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES EXPOSURE
NAME
PHOSPHORIC ACID ACUTE LC50: FISH - GAMBUSIA AFFINIS 96 HOURS
138 PPM - ADULT
FRESH WATER
BENZENESULFONIC ACID, ACUTE LC50: FISH - ORYZIAS LATIPES 96 HOURS
C10-13-ALKYL DERIVS., 7300
SODIUM SALTS (MICRO)G/L
PERSISTENCE AND DEGRADABILITY:
PRODUCT/INGREDIENT AQUATIC HALF-LIFE PHOTOLYSIS BIODEGRADABILITY
NAME
E-NOX CLEAN >80%; 28 TO READILY
100 DAY(S)
BIOACCUMULATIVE POTENTIAL:
PRODUCT/INGREDIENT NAME LOGPOW BCF POTENTIAL
BENZENESULFONIC ACID, C10-13-ALKYL 3.32 LOW
DERIVS., SODIUM SALTS
ALCOHOLS, C12-14, ETHOXYLATED 237 LOW
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE.
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD COMPLY WITH
THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE DISPOSAL LEGISLATION
AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE OF SURPLUS AND
NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL CONTRACTOR. WASTE
SHOULD NOT BE DISPOSED OF UNTREATED TO THE SEWER UNLESS FULLY COMPLIANT
WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH JURISDICTION. WASTE PACKAGING
SHOULD BE RECYCLED. INCINERATION OR LANDFILL SHOULD ONLY BE CONSIDERED WHEN
RECYCLING IS NOT FEASIBLE. THIS MATERIAL AND ITS CONTAINER MUST BE DISPOSED
OF IN A SAFE WAY. CARE SHOULD BE TAKEN WHEN HANDLING EMPTY CONTAINERS THAT
HAVE NOT BEEN CLEANED OR RINSED OUT. EMPTY CONTAINERS OR LINERS MAY RETAIN
SOME PRODUCT RESIDUES. AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND
CONTACT WITH SOIL, WATERWAYS, DRAINS AND SEWERS.
| SECTION 14. TRANSPORT INFORMATION | |
DOT CLASSIFICATION IMDG IATA
UN NUMBER UN3264 UN3264 UN3264
UN PROPER CORROSIVE LIQUID, CORROSIVE LIQUID, CORROSIVE LIQUID,
SHIPPING NAME ACIDIC, INORGANIC, ACIDIC, ACIDIC,
N.O.S. (PHOSPHORIC INORGANIC, N.O.S. INORGANIC, N.O.S.
ACID) RQ (PHOSPHORIC ACID) (PHOSPHORIC ACID)
(PHOSPHORIC ACID)
TRANSPORT 8 8 8
HAZARD
CLASS(ES) CORROSIVE, CLASS 8 - CLASS 8, CORROSIVE
CLASS/DIVISION 8 CORROSIVE
PACKING GROUP III III III
ENVIRONMENTAL NO. NO. NO.
HAZARDS
ADDITIONAL REPORTABLE
INFORMATION QUANTITY:
33761 LBS /
15327.5 KG
[3681 GAL /
13934. 1 L]
PACKAGE SIZES
SHIPPED IN
QUANTITIES LESS
THAN THE PRODUCT
REPORTABLE
QUANTITY ARE
NOT SUBJECT TO
THE RQ
(REPORTABLE
QUANTITY)
TRANSPORTATION
REQUIREMENTS.
AERG: 154
DOT-RQ DETAILS:
PHOSPHORIC ACID: 5000 LBS / 2270 KG [374.79 GAL / 1418.7 L]
SPECIAL PRECAUTIONS FOR USER:
TRANSPORT WITHIN USER'S PREMISES:
ALWAYS TRANSPORT IN CLOSED CONTAINERS THAT ARE UPRIGHT AND SECURE. ENSURE
THAT PERSONS TRANSPORTING THE PRODUCT KNOW WHAT TO DO IN THE EVENT OF AN
ACCIDENT OR SPILLAGE. PROTECT FROM FREEZING. FREEZING WILL DAMAGE PRODUCT
AND RENDER IT UNUSABLE.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL AND THE IBC CODE:
NOT AVAILABLE.
| SECTION 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
TSCA 8(A) CDR EXEMPT/PARTIAL EXEMPTION: NOT DETERMINED
UNITED STATES INVENTORY (TSCA 8B): ALL COMPONENTS ARE LISTED OR EXEMPTED.
CLEAN WATER ACT (CWA) 311: PHOSPHORIC ACID
CLEAN AIR ACT SECTION 112 (B) HAZARDOUS AIR POLLUTANTS (HAPS): NOT LISTED
CLEAN AIR ACT SECTION 602 CLASS I SUBSTANCES: NOT LISTED
CLEAN AIR ACT SECTION 602 CLASS II SUBSTANCES: NOT LISTED
DEA LIST I CHEMICALS (PRECURSOR CHEMICALS): NOT LISTED
DEA LIST II CHEMICALS (ESSENTIAL CHEMICALS): NOT LISTED
SARA 302/304:
COMPOSITION/INFORMATION ON INGREDIENTS: NO PRODUCTS WERE FOUND.
SARA 304 RQ: NOT APPLICABLE.
SARA 311/312:
CLASSIFICATION: IMMEDIATE (ACUTE) HEALTH HAZARD
COMPOSITION/INFORMATION ON INGREDIENTS:
NAME % FIRE SUDDEN REACTIVE IMMEDIATE DELAYED
HAZARD RELEASE (ACUTE) (CHRONIC)
OF HEALTH HEALTH
PRESSURE HAZARD HAZARD
PHOSPHORIC ACID 10 - 30 NO. NO. NO. YES. NO.
BENZENESULFONIC 1 - 5 NO. NO. NO. YES. NO.
ACID,
C10-13-ALKYL
DERIVS.,
SODIUM SALTS
ALCOHOLS, 0.1 - 1 NO. NO. NO. YES. NO.
C12-14,
ETHOXYLATED
SARA 313: NO PRODUCTS WERE FOUND.
STATE REGULATIONS:
MASSACHUSETTS:
THE FOLLOWING COMPONENTS ARE LISTED: PHOSPHORIC ACID
NEW YORK:
THE FOLLOWING COMPONENTS ARE LISTED: PHOSPHORIC ACID
NEW JERSEY:
THE FOLLOWING COMPONENTS ARE LISTED: PHOSPHORIC ACID
PENNSYLVANIA:
THE FOLLOWING COMPONENTS ARE LISTED: PHOSPHORIC ACID
CALIFORNIA PROP. 65: NO PRODUCTS WERE FOUND.
INTERNATIONAL LISTS:
NATIONAL INVENTORY:
AUSTRALIA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
CANADA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
CHINA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
EUROPE: ALL COMPONENTS ARE LISTED OR EXEMPTED.
REPUBLIC OF KOREA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
| SECTION 16. OTHER INFORMATION | |
HISTORY:
DATE OF ISSUE MM/DD/YYYY: 11/30/2015
DATE OF PREVIOUS ISSUE: 08/01/2015
VERSION: 1.2
REVISED SECTION(S): 2, 8, 16.
PREPARED BY: KMK REGULATORY SERVICES INC.
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS, 1973
AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
UN: UNITED NATIONS
NOTICE TO READER:
TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS ACCURATE.
HOWEVER, NEITHER THE ABOVE-NAMED SUPPLIER, NOR ANY OF ITS SUBSIDIARIES,
ASSUMES ANY LIABILITY WHATSOEVER FOR THE ACCURACY OR COMPLETENESS OF THE
INFORMATION CONTAINED HEREIN.
FINAL DETERMINATION OF SUITABILITY OF ANY MATERIAL IS THE SOLE
RESPONSIBILITY OF THE USER. ALL MATERIALS MAY PRESENT UNKNOWN HAZARDS AND
SHOULD BE USED WITH CAUTION. ALTHOUGH CERTAIN HAZARDS ARE DESCRIBED HEREIN,
WE CANNOT GUARANTEE THAT THESE ARE THE ONLY HAZARDS THAT EXIST.
KMK
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