| Common Name: | VP 800 P |
| Manufacturer: | VALCOOL |
| SDS Revision Date: | 11/10/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 444D23, 444D24, 444D25, 444D26, 444D27, 444D28 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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VALCOOL(R*)
VALCOOL, LLC
5230 BRITTMOORE RD.
HOUSTON, TX 77041
NAME: VP 800 P
SDS DATE: 11/10/2016
| SECTION 1: PRODUCT AND COMPANY INFORMATION |  |
PRODUCT NAME: VP 800 P
SUPPLIER:
VALCOOL, LLC
5230 BRITTMOORE RD.
HOUSTON, TX 77041
TELEPHONE: (800) 224-9004
FAX: (888) 695-6449
EMAIL: SUPPORT@VALCOOL.COM
IN CASE OF EMERGENCY:
CHEMTREC: 1-800-424-9300
PRODUCT DESCRIPTION: HEAVY-DUTY NON-CHLORINATED GENERAL PURPOSE FLUID
| SECTION 2: HAZARD IDENTIFICATION | |
GHS CLASSIFICATION:
GHS07: EXCLAMATION MARK
SKIN SENS. 1B:
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
GHS LABEL:
GHS LABEL ELEMENTS THE PRODUCT IS CLASSIFIED AND LABELED ACCORDING TO
THE GLOBALLY HARMONIZED SYSTEM (GHS).
HAZARD PICTOGRAM:
GHS07: EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD-DETERMINING COMPONENTS OF LABELING:
1,2-BENZISOTHIAZOL-3(2H)-ONE
2,2',2''-NITRILOTRIETHANOL
ETHANOL,2,2'-(CYCLOHEXYLIMINO)-BIS
NEODECANOIC ACID
HAZARD STATEMENT: MAY CAUSE AN ALLERGIC SKIN REACTION.
PRECAUTIONARY STATEMENTS:
PREVENTION:
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY
WEAR PROTECTIVE GLOVES
RESPONSE:
WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
CLASSIFICATION SYSTEM:
NFPA RATINGS (SCALE 0 - 4):
HEALTH 1
FIRE 0
REACTIVITY 0
HMIS-RATINGS (SCALE 0 - 4):
HEALTH 1
FIRE 0
REACTIVITY 0
OTHER HAZARDS:
RESULTS OF PBT AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE.
VPVB: NOT APPLICABLE.
| SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS | |
CHEMICAL CHARACTERIZATION: MIXTURE
DESCRIPTION:
MIXTURE OF THE SUBSTANCES LISTED BELOW WITH NONHAZARDOUS ADDITIONS.
COMPONENTS/INGREDIENTS CAS NO. %
DISTILLATES (PETROLEUM), HYDROTREATED 64742-52-5 2.5-<10%
HEAVY NAPHTHENIC
BORATE AMINE 26038-87-9 2.5-<10%
BORATE AMINE 26038-90-9 0.1-</=2.5%
NEODECANOIC ACID 26896-20-8 0.1-</=2.5%
2,2',2''-NITRILOTRIETHANOL 102-71-6 0.1-</=2.5%
1,1'-IMINODIPROPAN-2-OL 110-97-4 0.1-</=2.5%
ETHANOL,2,2'-(CYCLOHEXYLIMINO)-BIS 4500-29-2 0.1-</=2.5%
2-AMINOETHANOL 141-43-5 1-</=2.5%
1,2-BENZISOTHIAZOL-3(2H)-ONE 2634-33-5 0.1-<1%
| SECTION 4: FIRST AID MEASURES | |
EYE CONTACT: RINSE OPENED EYE FOR SEVERAL MINUTES UNDER RUNNING WATER.
SKIN CONTACT: IMMEDIATELY WASH WITH WATER AND SOAP AND RINSE THOROUGHLY.
INGESTION: DO NOT INDUCE VOMITING. SEEK MEDICAL ATTENTION IMMEDIATELY.
INHALATION:
SUPPLY FRESH AIR AND TO BE SURE CALL FOR A DOCTOR.
IN CASE OF UNCONSCIOUSNESS PLACE PATIENT STABLY IN SIDE POSITION FOR
TRANSPORTATION.
INFORMATION FOR DOCTOR:
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
DESCRIPTION OF NECESSARY FIRST AID MEASURES / SPECIFIC TREATMENTS:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
| SECTION 5: FIREFIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING AGENTS:
WATER, WATER SPRAY, FOAM, DRY POWDER, CARBON DIOXIDE (CO2).
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NO FURTHER RELEVANT INFORMATION AVAILABLE
SPECIAL FIRE FIGHTING INSTRUCTIONS:
FULL PROTECTIVE CLOTHING AND APPROVED SELF-CONTAINED BREATHING APPARATS
IF NECESSARY FOR FIRE FIGHTING PERSONNEL.
PROTECTIVE EQUIPMENT: NO SPECIAL MEASURES REQUIRED
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT & EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. DO NOT TOUCH OR WALK THROUGH SPILLED
MATERIAL. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS
WEARING APPROPRIATE PROTECTIVE CLOTHING.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO REACH SEWAGE SYSTEM OR ANY WATER COURSE.
INFORM RESPECTIVE AUTHORITIES IN CASE OF SEEPAGE INTO WATER COURSE
OR SEWAGE SYSTEM.
DO NOT ALLOW TO ENTER SEWERS/ SURFACE OR GROUND WATER.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
STOP LEAK IF YOU CAN DO SO WITHOUT RISK. PREVENT ENTRY INTO
WATERWAYS, SEWERS, BASEMENTS OR CONFINED AREAS.
DISPOSE CONTAMINATED MATERIAL AS WASTE ACCORDING TO ITEM 13.
ENSURE ADEQUATE VENTILATION
REFERENCE TO OTHER SECTIONS:
SEE SECTION 7 FOR INFORMATION ON SAFE HANDLING.
SEE SECTION 8 FOR INFORMATION ON PERSONAL PROTECTION EQUIPMENT.
SEE SECTION 13 FOR DISPOSAL INFORMATION.
| SECTION 7: HANDLING AND STORAGE | |
HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
ENSURE GOOD VENTILATION/EXHAUSTION AT THE WORKPLACE.
OPEN AND HANDLE RECEPTACLE WITH CARE.
PREVENT FORMATION OF AEROSOLS.
INFORMATION ABOUT PROTECTION AGAINST EXPLOSIONS AND FIRES:
KEEP RESPIRATORY PROTECTIVE DEVICE AVAILABLE.
STORAGE:
REQUIREMENTS TO BE MET BY STOREROOMS AND RECEPTACLES:
KEEP CONTAINER CLOSED WHEN NOT IN USE. STORE IN A COOL, DRY, WELL
VENTILATED PLACE AWAY FROM INCOMPATIBLE MATERIALS.
INFORMATION ABOUT STORAGE IN ONE COMMON STORAGE FACILITY:
KEEP CONTAINER TIGHTLY CLOSED IN A COOL, WELL-VENTILATED PLACE. KEEP
AWAY FROM SOURCE OF IGNITION.
FURTHER INFORMATION ABOUT STORAGE CONDITIONS:
KEEP RECEPTACLE TIGHTLY SEALED
SPECIFIC END USE(S): NO FURTHER RELEVANT INFORMATION AVAILABLE.
| SECTION 8: EXPOSURE CONTROL AND PERSONAL PROTECTION | |
ADDITIONAL INFORMATION ABOUT DESIGN OF TECHNICAL SYSTEMS:
NO FURTHER DATA; SEE ITEM 7.
CONTROL PARAMETERS:
COMPONENTS WITH LIMIT VALUES THAT REQUIRE MONITORING AT THE WORKPLACE
2,2',2"-NITRILOTRIETHANOL: 102-71-6
TLV:
LONG-TERM VALUE: 5 MG/M3
2-AMINOETHANOL: 141-43-5
PEL:
LONG-TERM VALUE: 6 MG/M3, 3 PPM
REL:
SHORT-TERM VALUE: 15 MG/M3, 6 PPM
LONG-TERM VALUE: 8 MG/M3, 3 PPM
TLV:
SHORT-TERM VALUE: 15 MG/M3, 6 PPM
LONG-TERM VALUE: 7.5 MG/M3, 3 PPM
ADDITIONAL INFORMATION:
THE LISTS THAT WERE VALID DURING THE CREATION WERE USED AS BASIS
EXPOSURE CONTROLS:
PERSONAL PROTECTIVE EQUIPMENT:
GENERAL PROTECTIVE AND HYGIENIC MEASURES:
KEEP AWAY FROM FOODSTUFFS, BEVERAGES AND FEED.
IMMEDIATELY REMOVE ALL SOILED AND CONTAMINATED CLOTHING.
WASH HANDS BEFORE BREAKS AND AT THE END OF WORK.
STORE PROTECTIVE CLOTHING SEPARATELY.
EYE / FACE PROTECTION: TIGHTLY SEALED GOGGLES
HAND PROTECTION: PROTECTIVE GLOVES
THE GLOVE MATERIAL HAS TO BE IMPERMEABLE AND RESISTANT TO THE PRODUCT/
THE SUBSTANCE/ THE PREPARATION. WHEN CONTACT IS LIKELY WEAR CHEMICAL
RESISTANT GLOVES AND BOOTS. SELECTION OF THE GLOVE MATERIAL ON
CONSIDERATION OF THE PENETRATION TIMES, RATES OF DIFFUSION AND THE
DEGRADATION
MATERIAL OF GLOVES:
THE SELECTION OF THE SUITABLE GLOVES DOES NOT ONLY DEPEND ON THE MATERIAL,
BUT ALSO ON FURTHER MARKS OF QUALITY AND VARIES FROM MANUFACTURER TO
MANUFACTURER. AS THE PRODUCT IS A PREPARATION OF SEVERAL SUBSTANCES,
THE RESISTANCE OF THE GLOVE MATERIAL CANNOT BE CALCULATED IN ADVANCE
AND HAS THEREFORE TO BE CHECKED PRIOR TO THE APPLICATION.
PENETRATION TIME OF GLOVE MATERIAL:
THE EXACT BREAK THROUGH TIME HAS TO BE FOUND OUT BY THE MANUFACTURER OF
THE PROTECTIVE GLOVES AND HAS TO BE OBSERVED.
RESPIRATORY PROTECTION:
IN CASE OF BRIEF EXPOSURE OR LOW POLLUTION USE RESPIRATORY FILTER DEVICE.
IN CASE OF INTENSIVE OR LONGER EXPOSURE USE RESPIRATORY PROTECTIVE DEVICE
THAT IS INDEPENDENT OF CIRCULATING AIR.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
FORM: LIQUID
COLOR: CLEAR TO YELLOWISH
ODOR: LIGHT
SPECIFIC GRAVITY AT 20 DEG. C (68 DEG. F): 1.01 G/CM3 (8.428 LBS/GAL)
DENSITY: N.D.
EVAPORATION RATE: NOT DETERMINED
FLASH POINT: NOT APPLICABLE.
AUTO-IGNITION TEMPERATURE: DOES NOT IGNITE.
DANGER OF EXPLOSION: NO DANGER
BOILING POINT / RANGE: <100 DEG. C (<212 DEG. F)
PH- VALUE AT 20 DEG. C (68 DEG. F): 9.3
SOLUBILITY IN WATER: SOLUBLE
VISCOSITY:
KINEMATIC AT 40 DEG. C (104 DEG. F): 5 MM2/S
ORGANIC SOLVENTS: 2.0%
VOC CONTENT: 2.0%
(NEAT): 150.2 G/L
(WORKING SOLUTION): 15 G/L
SOLIDS CONTENT: 0.4 %
OTHER INFORMATION: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| SECTION 10: STABILITY AND REACTIVITY | |
REACTIVITY: NO FURTHER RELEVANT INFORMATION AVAILABLE
CHEMICAL STABILITY:
THERMAL DECOMPOSITION CONDITIONS TO AVOID: STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: NO DANGEROUS REACTIONS KNOWN
CONDITIONS TO AVOID: NO FURTHER RELEVANT INFORMATION AVAILABLE
INCOMPATIBILITY WITH OTHER MATERIALS: DO NOT MIX WITH OXIDIZERS
HAZARDOUS DECOMPOSITION MATERIALS:
CARBON DIOXIDE AND CARBON MONOXIDE AND VARIOUS UNIDENTIFIED ORGANIC
HYDROCARBONS
| SECTION 11: TOXICOLOGICAL INFORMATION | |
ACUTE TOXICITY:
PRIMARY IRRITANT EFFECT:
EYE CONTACT:
PRODUCT IS CLASSIFIED AS MODERATELY IRRITATING TO THE EYES.
SKIN CONTACT:
THIS PRODUCT IS NOT EXPECTED TO BE TOXIC IN CONTACT WITH THE SKIN.
SENSITIZATION: SENSITIZATION POSSIBLE THROUGH SKIN CONTACT
ADDITIONAL TOXICOLOGICAL INFORMATION:
THE PRODUCT SHOWS THE FOLLOWING DANGERS ACCORDING TO INTERNALLY APPROVED
CALCULATION METHODS FOR PREPARATIONS: IRRITANT
CARCINOGENIC CATEGORIES:
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
102-71-6 2,2',2''-NITRILOTRIETHANOL 3
NTP (NATIONAL TOXICOLOGY PROGRAM): NONE OF THE INGREDIENTS IS LISTED.
OSHA-CA (OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION):
NONE OF THE INGREDIENTS IS LISTED.
| SECTION 12: ECOLOGICAL INFORMATION | |
TOXICITY:
AQUATIC TOXICITY: NO FURTHER RELEVANT INFORMATION AVAILABLE
PERSISTENCE AND DEGRADABILITY: NO FURTHER RELEVANT INFORMATION AVAILABLE
BEHAVIOR IN ENVIRONMENTAL SYSTEMS:
BIOACCUMULATIVE POTENTIAL: NO FURTHER RELEVANT INFORMATION AVAILABLE
MOBILITY IN SOIL: NO FURTHER RELEVANT INFORMATION AVAILABLE
ADDITIONAL ECOLOGICAL INFORMATION:
GENERAL NOTES:
NOT READILY BIODEGRADABLE.
DOES NOT HYDROLYSE.
RESULTS OF PBT AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE.
VPVB: NOT APPLICABLE.
OTHER ADVERSE EFFECTS: NO FURTHER RELEVANT INFORMATION AVAILABLE
| SECTION 13: DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
RECOMMENDATION:
MUST NOT BE DISPOSED OF TOGETHER WITH HOUSEHOLD GARBAGE. DO NOT ALLOW
PRODUCT TO REACH SEWAGE SYSTEM.
UNCLEANED PACKAGINGS:
RECOMMENDATION:
DISPOSAL MUST BE MADE ACCORDING TO OFFICIAL REGULATIONS.
RECOMMENDED CLEANSING AGENT: WATER, IF NECESSARY WITH CLEANSING AGENTS.
| SECTION 14: TRANSPORT INFORMATION | |
DOT CLASSIFICATION:
UN NUMBER: NOT REGULATED
UN PROPER SHIPPING NAME: NOT REGULATED
TRANSPORT HAZARD CLASS(ES): NOT REGULATED
PACKING GROUP: NOT REGULATED
ENVIRONMENTAL HAZARDS: NOT APPLICABLE.
SPECIAL PRECAUTIONS FOR USER: NOT APPLICABLE.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC CODE:
NOT APPLICABLE.
UN "MODEL REGULATION": NOT REGULATED
| SECTION 15: REGULATORY INFORMATION | |
SARA:
SECTION 355 (EXTREMELY HAZARDOUS SUBSTANCES):
NONE OF THE INGREDIENTS IS LISTED.
SECTION 313 (SPECIFIC TOXIC CHEMICAL LISTINGS):
NONE OF THE INGREDIENTS IS LISTED.
TSCA (TOXIC SUBSTANCES CONTROL ACT):
64742-52-5 DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHTHENIC
26038-87-9 BORATE AMINE
26896-20-8 NEODECANOIC ACID
102-71-6 2,2',2''-NITRILOTRIETHANOL
12645-31-7 PHOSPHORIC ACID, 2-ETHYLHEXYL ESTER
110-97-4 1,1'-IMINODIPROPAN-2-OL
4500-29-2 ETHANOL,2,2'-(CYCLOHEXYLIMINO)-BIS
141-43-5 2-AMINOETHANOL
2634-33-5 1,2-BENZISOTHIAZOL-3(2H)-ONE
PROPOSITION 65:
CHEMICALS KNOWN TO CAUSE CANCER: NONE OF THE INGREDIENTS IS LISTED.
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR FEMALES:
NONE OF THE INGREDIENTS IS LISTED.
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR MALES:
NONE OF THE INGREDIENTS IS LISTED.
CHEMICALS KNOWN TO CAUSE DEVELOPMENTAL TOXICITY:
NONE OF THE INGREDIENTS IS LISTED.
CARCINOGENIC CATEGORIES:
EPA (ENVIRONMENTAL PROTECTION AGENCY): NONE OF THE INGREDIENTS IS LISTED
TLV (THRESHOLD LIMIT VALUE ESTABLISHED BY ACGIH):
NONE OF THE INGREDIENTS IS LISTED
NIOSH-CA (NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH):
NONE OF THE INGREDIENTS IS LISTED
GHS LABEL:
GHS LABEL ELEMENTS THE PRODUCT IS CLASSIFIED AND LABELED ACCORDING TO THE
GLOBALLY HARMONIZED SYSTEM (GHS).
HAZARD PICTOGRAM:
GHS07: EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD-DETERMINING COMPONENTS OF LABELING:
1,2-BENZISOTHIAZOL-3(2H)-ONE
2,2',2''-NITRILOTRIETHANOL
ETHANOL,2,2'-(CYCLOHEXYLIMINO)-BIS
NEODECANOIC ACID
HAZARD STATEMENT: MAY CAUSE AN ALLERGIC SKIN REACTION.
PRECAUTIONARY STATEMENTS:
PREVENTION:
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY
WEAR PROTECTIVE GLOVES
RESPONSE:
WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
NATIONAL REGULATIONS:
INFORMATION ABOUT LIMITATION OF USE:
WORKERS ARE NOT ALLOWED TO BE EXPOSED TO THE HAZARDOUS CARCINOGENIC
MATERIALS CONTAINED IN THIS PREPARATION.
EXCEPTIONS CAN BE MADE BY THE AUTHORITIES IN CERTAIN CASES.
CHEMICAL SAFETY ASSESSMENT:
A CHEMICAL SAFETY ASSESSMENT HAS NOT BEEN CARRIED OUT.
| SECTION 16: OTHER INFORMATION | |
REVISION DATE: 11/10/2016 - 1
ABBREVIATIONS AND ACRONYMS:
DOT: US DEPARTMENT OF TRANSPORTATION
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
EINECS: EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES
ELINCS: EUROPEAN LIST OF NOTIFIED CHEMICAL SUBSTANCES
CAS:
CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY)
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION (USA)
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (USA)
VOC: VOLATILE ORGANIC COMPOUNDS (USA, EU)
PBT: PERSISTENT, BIOACCUMULATIVE AND TOXIC
VPVB: VERY PERSISTENT AND VERY BIOACCUMULATIVE
NIOSH: NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY
OSHA: OCCUPATIONAL SAFETY & HEALTH
TLV: THRESHOLD LIMIT VALUE
PEL: PERMISSIBLE EXPOSURE LIMIT
REL: RECOMMENDED EXPOSURE LIMIT
SKIN SENS. 1B: SENSITISATION - SKIN, HAZARD CATEGORY 1B
HMIS:
DISCLAIMER:
THE INFORMATION PRESENTED HEREIN HAS BEEN COMPILED FROM SOURCES CONSIDERED
TO BE DEPENDABLE AND IS ACCURATE AS OF THE DATE ISSUED. HOWEVER, SINCE
DATA, SAFETY STANDARDS, AND GOVERNMENT REGULATIONS ARE SUBJECT TO CHANGE
AND THE CONDITIONS OF HANDLING AND USE ARE BEYOND OUR CONTROL, WE MAKE
NO WARRANTY REGARDING THE ACCURACY OF SUCH DATA OR ITS SUITABILITY FOR
ANY USE OR FOR ANY CONSEQUENCE OF ITS USE. THE DATA IN THIS SDS RELATES
ONLY TO THE SPECIFIC MATERIAL DESIGNATED HEREIN AND DOES NOT RELATE TO
USE IN COMBINATION WITH ANY OTHER MATERIAL OR IN ANY PROCESS. SAFE
HANDLING AND USE REMAINS THE RESPONSIBILITY OF THE PURCHASER AND THE
PURCHASER HAS THE SOLE RESPONSIBILITY TO DETERMINE THE SUITABILITY OF
THE MATERIALS FOR ANY USE AND THE MANNER OF USER CONTEMPLATED. WE ASSUME
NO RESPONSIBILITY FOR INJURY TO THE RECIPIENT OR TO THIRD PERSONS OR FOR
ANY DAMAGE TO ANY PROPERTY AND THE RECIPIENT ASSUMES ALL SUCH RISKS.