| Common Name: | LN-547 FUZE-IT |
| Manufacturer: | PPG INDUSTRIES |
| SDS Revision Date: | 12/7/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 444D86 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
PPG
DATE OF ISSUE/DATE OF REVISION: 7 DECEMBER 2016
VERSION: 4
| SECTION 1. IDENTIFICATION |  |
PRODUCT NAME: LN-547 FUZE-IT
PRODUCT CODE: 00372371
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
PRODUCT TYPE: SOLID.
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
PRODUCT USE: INDUSTRIAL APPLICATIONS.
USE OF THE SUBSTANCE/MIXTURE: ADHESIVE.
USES ADVISED AGAINST: NOT APPLICABLE.
MANUFACTURER:
PPG INDUSTRIES, INC.
ONE PPG PLACE
PITTSBURGH, PA 15272
EMERGENCY TELEPHONE NUMBER:
(412) 434-4515 (U.S.)
(514) 645-1320 (CANADA)
01-800-00-21-400 (MEXICO)
TECHNICAL PHONE NUMBER: 1-800-441-9695 (8:00 AM TO 5:00 PM EST)
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
EYE IRRITATION: CATEGORY 2A
SKIN SENSITIZATION: CATEGORY 1
CARCINOGENICITY: CATEGORY 2
TOXIC TO REPRODUCTION (FERTILITY): CATEGORY 1B
TOXIC TO REPRODUCTION (UNBORN CHILD): CATEGORY 1B
PERCENTAGE OF THE MIXTURE CONSISTING OF INGREDIENT(S) OF UNKNOWN TOXICITY:
50.3%
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS:
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
MAY DAMAGE FERTILITY OR THE UNBORN CHILD.
SUSPECTED OF CAUSING CANCER.
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. WEAR PROTECTIVE GLOVES. WEAR
EYE OR FACE PROTECTION. WEAR PROTECTIVE CLOTHING. AVOID BREATHING DUST.
WASH HANDS THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING MUST
NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
IF ON SKIN:
WASH WITH PLENTY OF SOAP AND WATER. WASH CONTAMINATED CLOTHING BEFORE
REUSE.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
SUPPLEMENTAL LABEL:
| TRIMETHOXYSILANES ARE CAPABLE OF FORMING METHANOL IF HYDROLYZED OR
| INGESTED. IF ELEMENTS SWALLOWED, METHANOL MAY BE HARMFUL OR FATAL OR
| CAUSE BLINDNESS. THIS PRODUCT EITHER CONTAINS FORMALDEHYDE OR IS CAPABLE
| OF RELEASING FORMALDEHYDE ABOVE 0.5 PPM UNDER CERTAIN CONDITIONS.
| FORMALDEHYDE IS A KNOWN CANCER HAZARD, A SKIN SENSITIZER AND A
| RESPIRATORY SENSITIZER. EMITS TOXIC FUMES WHEN HEATED.
HAZARDS NOT OTHERWISE CLASSIFIED: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
PRODUCT NAME: LN-547 FUZE-IT
INGREDIENT NAME % CAS NUMBER
| PROPRIETARY SAX 350 SILYL >/=20 - </=50 NOT AVAILABLE.
| TERMINATED POLYETHER
CALCIUM CARBONATE >/=20 - </=50 471-34-1
1,2-CYCLOHEXANEDICARBOXYLIC >/=10 - </=20 474919-59-0
ACID, 1,2-DINONYL ESTER,
BRANCHED AND LINEAR
KAOLIN >/=5.0 - </=10 1332-58-7
TITANIUM DIOXIDE >/=1.0 - </=5.0 13463-67-7
LIMESTONE >/=1.0 - </=5.0 1317-65-3
N-(3-(TRIMETHOXYSILYL)PROPYL) >/=0.10 - </=2.9 1760-24-3
ETHYLENEDIAMINE
TRIMETHOXYVINYLSILANE >/=1.0 - </=4.2 2768-02-7
DIBUTYLBIS(PENTANE-2,4-DIONATO-O,O')TIN <1.0 22673-19-4
SUB CODES REPRESENT SUBSTANCES WITHOUT REGISTERED CAS NUMBERS.
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR
IS DUE TO BATCH VARIATION.
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH OR THE ENVIRONMENT AND HENCE REQUIRE
REPORTING IN THIS SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
IF INGESTION, IRRITATION, ANY TYPE OF OVEREXPOSURE OR SYMPTOMS OF
OVEREXPOSURE OCCUR DURING OR PERSISTS AFTER USE OF THIS PRODUCT, CONTACT
A POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN IMMEDIATELY; HAVE
SAFETY DATA SHEET INFORMATION AVAILABLE. NEVER GIVE ANYTHING BY MOUTH TO
AN UNCONSCIOUS OR CONVULSING PERSON.
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
REMOVE CONTACT LENSES, IRRIGATE COPIOUSLY WITH CLEAN, FRESH WATER, HOLDING
THE EYELIDS APART FOR AT LEAST 10 MINUTES AND SEEK IMMEDIATE MEDICAL
ADVICE.
INHALATION:
REMOVE TO FRESH AIR. KEEP PERSON WARM AND AT REST. IF NOT BREATHING, IF
BREATHING IS IRREGULAR OR IF RESPIRATORY ARREST OCCURS, PROVIDE ARTIFICIAL
RESPIRATION OR OXYGEN BY TRAINED PERSONNEL.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING AND SHOES. WASH SKIN THOROUGHLY WITH SOAP AND
WATER OR USE RECOGNIZED SKIN CLEANSER. DO NOT USE SOLVENTS OR THINNERS.
INGESTION:
IF SWALLOWED, SEEK MEDICAL ADVICE IMMEDIATELY AND SHOW THIS CONTAINER OR
LABEL. KEEP PERSON WARM AND AT REST. DO NOT INDUCE VOMITING.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT: MAY CAUSE AN ALLERGIC SKIN REACTION.
INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED,
IF NECESSARY:
NOTES TO PHYSICIAN:
IN CASE OF INHALATION OF DECOMPOSITION PRODUCTS IN A FIRE, SYMPTOMS MAY BE
DELAYED.
THE EXPOSED PERSON MAY NEED TO BE KEPT UNDER MEDICAL SURVEILLANCE FOR
48 HOURS.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS.
IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION. WASH CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE
REMOVING IT, OR WEAR GLOVES.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE AN EXTINGUISHING AGENT SUITABLE FOR THE SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
VAPORS MAY ACCUMULATE IN LOW OR CONFINED AREAS OR TRAVEL A CONSIDERABLE
DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK. THIS MATERIAL IS HARMFUL
TO AQUATIC LIFE WITH LONG LASTING EFFECTS. FIRE WATER CONTAMINATED WITH
THIS MATERIAL MUST BE CONTAINED AND PREVENTED FROM BEING DISCHARGED TO
ANY WATERWAY, SEWER OR DRAIN.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
| DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON OXIDES
NITROGEN OXIDES
METAL OXIDE/OXIDES
FORMALDEHYDE.
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF
THE INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE OPERATED
IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL.
PROVIDE ADEQUATE VENTILATION. WEAR APPROPRIATE RESPIRATOR WHEN VENTILATION
IS INADEQUATE. PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALIZED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE
OF ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS.
SEE ALSO THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL
OR AIR).
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
MOVE CONTAINERS FROM SPILL AREA. AVOID DUST GENERATION. DO NOT DRY SWEEP.
VACUUM DUST WITH EQUIPMENT FITTED WITH A HEPA FILTER AND PLACE IN A CLOSED,
LABELED WASTE CONTAINER. PLACE SPILLED MATERIAL IN A DESIGNATED, LABELED
WASTE CONTAINER. DISPOSE OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
LARGE SPILL:
MOVE CONTAINERS FROM SPILL AREA. APPROACH RELEASE FROM UPWIND. PREVENT
ENTRY INTO SEWERS, WATER COURSES, BASEMENTS OR CONFINED AREAS. AVOID DUST
GENERATION. DO NOT DRY SWEEP. VACUUM DUST WITH EQUIPMENT FITTED WITH A
HEPA FILTER AND PLACE IN A CLOSED, LABELED WASTE CONTAINER. DISPOSE OF
VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). PERSONS
WITH A HISTORY OF SKIN SENSITIZATION PROBLEMS SHOULD NOT BE EMPLOYED IN
ANY PROCESS IN WHICH THIS PRODUCT IS USED. AVOID EXPOSURE - OBTAIN SPECIAL
INSTRUCTIONS BEFORE USE. AVOID EXPOSURE DURING PREGNANCY. DO NOT HANDLE
UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT GET
IN EYES OR ON SKIN OR CLOTHING. DO NOT INGEST. IF DURING NORMAL USE THE
MATERIAL PRESENTS A RESPIRATORY HAZARD, USE ONLY WITH ADEQUATE VENTILATION
OR WEAR APPROPRIATE RESPIRATOR. KEEP IN THE ORIGINAL CONTAINER OR AN
APPROVED ALTERNATIVE MADE FROM A COMPATIBLE MATERIAL, KEPT TIGHTLY CLOSED
WHEN NOT IN USE. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE AND CAN BE
HAZARDOUS. DO NOT REUSE CONTAINER.
SPECIAL PRECAUTIONS:
VAPORS MAY ACCUMULATE IN LOW OR CONFINED AREAS OR TRAVEL A CONSIDERABLE
DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK. VAPORS ARE HEAVIER THAN
AIR AND MAY SPREAD ALONG FLOORS. IF THIS MATERIAL IS PART OF A MULTIPLE
COMPONENT SYSTEM, READ THE SAFETY DATA SHEET(S) FOR THE OTHER COMPONENT OR
COMPONENTS BEFORE BLENDING AS THE RESULTING MIXTURE MAY HAVE THE HAZARDS
OF ALL OF ITS PARTS.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. REMOVE CONTAMINATED CLOTHING AND
PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS. SEE ALSO SECTION 8 FOR
ADDITIONAL INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
DO NOT STORE ABOVE THE FOLLOWING TEMPERATURE: 35 DEG. C (95 DEG. F).
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE IN ORIGINAL CONTAINER
PROTECTED FROM DIRECT SUNLIGHT IN A DRY, COOL AND WELL-VENTILATED AREA,
AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10) AND FOOD AND DRINK.
STORE LOCKED UP. KEEP CONTAINER TIGHTLY CLOSED AND SEALED UNTIL READY FOR
USE. CONTAINERS THAT HAVE BEEN OPENED MUST BE CAREFULLY RESEALED AND KEPT
UPRIGHT TO PREVENT LEAKAGE. DO NOT STORE IN UNLABELED CONTAINERS. USE
APPROPRIATE CONTAINMENT TO AVOID ENVIRONMENTAL CONTAMINATION.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT NAME EXPOSURE LIMITS
| PROPRIETARY SAX 350 SILYL NONE.
| TERMINATED POLYETHER
CALCIUM CARBONATE ACGIH TLV (UNITED STATES).
TWA: 3 MG/M3
FORM: RESPIRABLE
TWA: 10 MG/M3
FORM: TOTAL DUST
OSHA PEL (UNITED STATES).
TWA: 5 MG/M3
FORM: RESPIRABLE
TWA: 15 MG/M3
OSHA PEL (UNITED STATES, 2/2013).
TWA: 5 MG/M3 8 HOURS.
FORM: RESPIRABLE FRACTION
TWA: 15 MG/M3 8 HOURS.
FORM: TOTAL DUST
1,2-CYCLOHEXANEDICARBOXYLIC ACID, NONE.
1,2-DINONYL ESTER, BRANCHED AND
LINEAR
KAOLIN ACGIH TLV (UNITED STATES, 3/2015).
TWA: 2 MG/M3 8 HOURS.
FORM: RESPIRABLE FRACTION
OSHA PEL (UNITED STATES, 2/2013).
TWA: 5 MG/M3 8 HOURS.
FORM: RESPIRABLE FRACTION
TWA: 15 MG/M3 8 HOURS.
FORM: TOTAL DUST
TITANIUM DIOXIDE OSHA PEL (UNITED STATES, 2/2013).
TWA: 15 MG/M3 8 HOURS.
FORM: TOTAL DUST
ACGIH TLV (UNITED STATES, 3/2015).
TWA: 10 MG/M3 8 HOURS.
LIMESTONE OSHA PEL (UNITED STATES, 2/2013).
TWA: 5 MG/M3 8 HOURS.
FORM: RESPIRABLE FRACTION
TWA: 15 MG/M3 8 HOURS.
FORM: TOTAL DUST
N-(3-(TRIMETHOXYSILYL)PROPYL) NONE.
ETHYLENEDIAMINE
TRIMETHOXYVINYLSILANE NONE.
DIBUTYLBIS(PENTANE-2,4-DIONATO- ACGIH TLV (UNITED STATES).
O,O')TIN ABSORBED THROUGH SKIN.
STEL: 0.2 MG/M3
OSHA PEL (UNITED STATES).
TWA: 0.1 MG/M3, (AS SN)
TWA: 0.1 MG/M3, (AS SN)
FORM: TOTAL DUST
ACGIH TLV (UNITED STATES, 3/2015).
TWA: 2 MG/M3, (AS SN) 8 HOURS.
OSHA PEL (UNITED STATES, 2/2013).
TWA: 2 MG/M3, (AS SN) 8 HOURS.
KEY TO ABBREVIATIONS:
A = ACCEPTABLE MAXIMUM PEAK
S = POTENTIAL SKIN ABSORPTION
ACGIH = AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS.
SR = RESPIRATORY SENSITIZATION
C = CEILING LIMIT
SS = SKIN SENSITIZATION
F = FUME
STEL = SHORT TERM EXPOSURE LIMIT VALUES
IPEL = INTERNAL PERMISSIBLE EXPOSURE LIMIT
TD = TOTAL DUST
OSHA = OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION.
TLV = THRESHOLD LIMIT VALUE
R = RESPIRABLE
TWA = TIME WEIGHTED AVERAGE
Z = OSHA 29 CFR 1910.1200 SUBPART Z - TOXIC AND HAZARDOUS SUBSTANCES
CONSULT LOCAL AUTHORITIES FOR ACCEPTABLE EXPOSURE LIMITS.
RECOMMENDED MONITORING PROCEDURES:
IF THIS PRODUCT CONTAINS INGREDIENTS WITH EXPOSURE LIMITS, PERSONAL,
WORKPLACE ATMOSPHERE OR BIOLOGICAL MONITORING MAY BE REQUIRED TO DETERMINE
THE EFFECTIVENESS OF THE VENTILATION OR OTHER CONTROL MEASURES AND/OR THE
NECESSITY TO USE RESPIRATORY PROTECTIVE EQUIPMENT. REFERENCE SHOULD BE
MADE TO APPROPRIATE MONITORING STANDARDS. REFERENCE TO NATIONAL GUIDANCE
DOCUMENTS FOR METHODS FOR THE DETERMINATION OF HAZARDOUS SUBSTANCES WILL
ALSO BE REQUIRED.
APPROPRIATE ENGINEERING CONTROLS:
IF USER OPERATIONS GENERATE DUST, FUMES, GAS, VAPOR OR MIST, USE PROCESS
ENCLOSURES, LOCAL EXHAUST VENTILATION OR OTHER ENGINEERING CONTROLS TO
KEEP WORKER EXPOSURE TO AIRBORNE CONTAMINANTS BELOW ANY RECOMMENDED OR
STATUTORY LIMITS.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED
TO ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, FUME SCRUBBERS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE
WORKING PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED
OUT OF THE WORKPLACE. WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE
THAT EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION
LOCATION.
EYE/FACE PROTECTION: CHEMICAL SPLASH GOGGLES.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY. CONSIDERING THE PARAMETERS
SPECIFIED BY THE GLOVE MANUFACTURER, CHECK DURING USE THAT THE GLOVES ARE
STILL RETAINING THEIR PROTECTIVE PROPERTIES. IT SHOULD BE NOTED THAT THE
TIME TO BREAKTHROUGH FOR ANY GLOVE MATERIAL MAY BE DIFFERENT FOR DIFFERENT
GLOVE MANUFACTURERS. IN THE CASE OF MIXTURES, CONSISTING OF SEVERAL
SUBSTANCES, THE PROTECTION TIME OF THE GLOVES CANNOT BE ACCURATELY
ESTIMATED.
GLOVES: BUTYL RUBBER
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD
BE SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
RESPIRATOR SELECTION MUST BE BASED ON KNOWN OR ANTICIPATED EXPOSURE
LEVELS, THE HAZARDS OF THE PRODUCT AND THE SAFE WORKING LIMITS OF THE
SELECTED RESPIRATOR. IF WORKERS ARE EXPOSED TO CONCENTRATIONS ABOVE THE
EXPOSURE LIMIT, THEY MUST USE APPROPRIATE, CERTIFIED RESPIRATORS. USE A
PROPERLY FITTED, AIR-PURIFYING OR AIR-FED RESPIRATOR COMPLYING WITH AN
APPROVED STANDARD IF A RISK ASSESSMENT INDICATES THIS IS NECESSARY.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: SOLID.
COLOR: NOT AVAILABLE.
ODOR: MINTY.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT: NOT AVAILABLE.
BOILING POINT: NOT AVAILABLE.
FLASH POINT:
CLOSED CUP: NOT APPLICABLE. [PRODUCT DOES NOT SUSTAIN COMBUSTION.]
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS: NOT AVAILABLE.
EVAPORATION RATE: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
VAPOR DENSITY: NOT AVAILABLE.
RELATIVE DENSITY: 1.3
DENSITY (LBS/GAL): 10.85
SOLUBILITY:
INSOLUBLE IN THE FOLLOWING MATERIALS: COLD WATER.
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE.
VISCOSITY:
KINEMATIC (40 DEG. C (104 DEG. F)): NOT APPLICABLE.
VOLATILITY: 8% (V/V), 1.4% (W/W)
% SOLID. (W/W): 98.6
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NO SPECIFIC TEST DATA RELATED TO REACTIVITY AVAILABLE FOR THIS PRODUCT
OR ITS INGREDIENTS.
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID:
WHEN EXPOSED TO HIGH TEMPERATURES MAY PRODUCE HAZARDOUS DECOMPOSITION
PRODUCTS. REFER TO PROTECTIVE MEASURES LISTED IN SECTIONS 7 AND 8.
INCOMPATIBLE MATERIALS:
KEEP AWAY FROM THE FOLLOWING MATERIALS TO PREVENT STRONG EXOTHERMIC
REACTIONS: OXIDIZING AGENTS, STRONG ALKALIS, STRONG ACIDS.
HAZARDOUS DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON MONOXIDE, CARBON DIOXIDE, SMOKE, OXIDES OF NITROGEN.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
| CILCIUM CARBONATE LD50 ORAL RAT 6450 MG/KG
KAOLIN LD50 ORAL RAT >5000 MG/KG
TITANIUM DIOXIDE LD50 ORAL RAT >11 G/KG
N-(3-(TRIMETHOXYSILYL) LD50 ORAL RAT 2413 MG/KG
PROPYL) ETHYLENEDIAMINE
TRIMETHOXYVINYLSILANE LC50 INHALATION RAT >16790 MG/M3 4 HOURS
VAPOR
LD50 DERMAL RABBIT >3.4 G/KG
LD50 ORAL RAT >7.3 G/KG
DIBUTYLBIS(PENTANE-2, LD50 ORAL RAT >2 G/KG
4-DIONATO-O,O')TIN
CONCLUSION/SUMMARY: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
IRRITATION/CORROSION:
CONCLUSION/SUMMARY:
SKIN: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
EYES: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
RESPIRATORY: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
SENSITIZATION:
CONCLUSION/SUMMARY:
SKIN: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
RESPIRATORY: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
MUTAGENICITY:
CONCLUSION/SUMMARY: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
CARCINOGENICITY:
CONCLUSION/SUMMARY: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
CLASSIFICATION:
PRODUCT/INGREDIENT NAME OSHA IARC NTP
TITANIUM DIOXIDE - 2B -
CARCINOGEN CLASSIFICATION CODE:
IARC: 1, 2A, 2B, 3, 4
NTP:
KNOWN TO BE A HUMAN CARCINOGEN; REASONABLY ANTICIPATED TO BE A HUMAN
CARCINOGEN
OSHA: +
NOT LISTED/NOT REGULATED: -
REPRODUCTIVE TOXICITY:
CONCLUSION/SUMMARY: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
TERATOGENICITY:
CONCLUSION/SUMMARY: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
NAME CATEGORY
DIBUTYLBIS(PENTANE-2,4-DIONATO-O,O')TIN CATEGORY 1
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE):
NAME CATEGORY
DIBUTYLBIS(PENTANE-2,4-DIONATO-O,O')TIN CATEGORY 1
TARGET ORGANS:
CONTAINS MATERIAL WHICH CAUSES DAMAGE TO THE FOLLOWING ORGANS: EYES.
CONTAINS MATERIAL WHICH MAY CAUSE DAMAGE TO THE FOLLOWING ORGANS:
LUNGS, BLADDER, UPPER RESPIRATORY TRACT, SKIN, CENTRAL NERVOUS SYSTEM
(CNS), STOMACH.
ASPIRATION HAZARD: NOT AVAILABLE.
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT: MAY CAUSE AN ALLERGIC SKIN REACTION.
INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG
TERM EXPOSURE:
CONCLUSION/SUMMARY:
| THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF. TRIMETHOXYSILANES ARE
| CAPABLE OF FORMING METHANOL IF HYDROLYZED OR INGESTED. IF SWALLOWED,
| METHANOL MAY BE HARMFUL OR FATAL OR CAUSE BLINDNESS. THIS PRODUCT EITHER
| CONTAINS FORMALDEHYDE OR IS CAPABLE OF RELEASING FORMALDEHYDE ABOVE
| 0.5 PPM UNDER CERTAIN CONDITIONS. FORMALDEHYDE IS A KNOWN CANCER HAZARD,
| A SKIN SENSITIZER AND A RESPIRATORY SENSITIZER. INGESTION MAY CAUSE
| NAUSEA, DIARRHEA AND VOMITING. THIS TAKES INTO ACCOUNT, WHERE KNOWN,
| DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS OF COMPONENTS
| FROM SHORT-TERM AND LONG-TERM EXPOSURE BY ORAL, INHALATION AND DERMAL
| ROUTES OF EXPOSURE AND EYE CONTACT.
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS:
THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
POTENTIAL DELAYED EFFECTS:
THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS:
THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
POTENTIAL DELAYED EFFECTS:
THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
POTENTIAL CHRONIC HEALTH EFFECTS:
GENERAL:
ONCE SENSITIZED, A SEVERE ALLERGIC REACTION MAY OCCUR WHEN SUBSEQUENTLY
EXPOSED TO VERY LOW LEVELS.
CARCINOGENICITY:
SUSPECTED OF CAUSING CANCER. RISK OF CANCER DEPENDS ON DURATION AND LEVEL
OF EXPOSURE.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: MAY DAMAGE THE UNBORN CHILD.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: MAY DAMAGE FERTILITY.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY ESTIMATES:
ROUTE ATE VALUE
ORAL 52141.8 MG/KG
INHALATION (GASES) 60445.9 PPM
INHALATION (VAPORS) 147.8 MG/L
INHALATION (DUSTS AND MISTS) 20.15 MG/L
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES EXPOSURE
NAME
TITANIUM DIOXIDE ACUTE LC50: DAPHNIA - DAPHNIA MAGNA 48 HOURS
>100 MG/L
FRESH WATER
PERSISTENCE AND DEGRADABILITY: NOT AVAILABLE.
BIOACCUMULATIVE POTENTIAL: NOT AVAILABLE.
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL
TIMES COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE
DISPOSAL LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS.
DISPOSE OF SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE
DISPOSAL CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE
SEWER UNLESS FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES
WITH JURISDICTION. WASTE PACKAGING SHOULD BE RECYCLED. INCINERATION OR
LANDFILL SHOULD ONLY BE CONSIDERED WHEN RECYCLING IS NOT FEASIBLE. THIS
MATERIAL AND ITS CONTAINER MUST BE DISPOSED OF IN A SAFE WAY. CARE
SHOULD BE TAKEN WHEN HANDLING EMPTIED CONTAINERS THAT HAVE NOT BEEN
CLEANED OR RINSED OUT. EMPTY CONTAINERS OR LINERS MAY RETAIN SOME PRODUCT
RESIDUES. AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH
SOIL, WATERWAYS, DRAINS AND SEWERS.
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND
LOCAL LAWS AND REGULATIONS.
REFER TO SECTION 7: HANDLING AND STORAGE AND SECTION 8: EXPOSURE
CONTROLS/PERSONAL PROTECTION FOR ADDITIONAL HANDLING INFORMATION AND
PROTECTION OF EMPLOYEES. SECTION 6. ACCIDENTAL RELEASE MEASURES
| SECTION 14. TRANSPORT INFORMATION | |
DOT IMDG IATA
UN NUMBER NOT REGULATED. NOT REGULATED. NOT REGULATED.
UN PROPER SHIPPING
NAME
TRANSPORT HAZARD
CLASS (ES)
PACKING GROUP
ENVIRONMENTAL HAZARDS NO. NO. NO.
MARINE POLLUTANT NOT APPLICABLE. NOT APPLICABLE. NOT APPLICABLE.
SUBSTANCES
ADDITIONAL INFORMATION
DOT: NONE IDENTIFIED.
IMDG: NONE IDENTIFIED.
IATA: NONE IDENTIFIED.
SPECIAL PRECAUTIONS FOR USER:
TRANSPORT WITHIN USER'S PREMISES:
ALWAYS TRANSPORT IN CLOSED CONTAINERS THAT ARE UPRIGHT AND SECURE. ENSURE
THAT PERSONS TRANSPORTING THE PRODUCT KNOW WHAT TO DO IN THE EVENT OF AN
ACCIDENT OR SPILLAGE.
| SECTION 15. REGULATORY INFORMATION | |
UNITED STATES:
UNITED STATES INVENTORY (TSCA 8B):
ALL COMPONENTS ARE LISTED OR EXEMPTED.
SARA 302/304:
SARA 304 RQ: NOT APPLICABLE.
COMPOSITION/INFORMATION ON INGREDIENTS: NO PRODUCTS WERE FOUND.
SARA 311/312:
CLASSIFICATION:
IMMEDIATE (ACUTE) HEALTH HAZARD
DELAYED (CHRONIC) HEALTH HAZARD
COMPOSITION/INFORMATION ON INGREDIENTS:
NAME FIRE SUDDEN REACTIVE IMMEDIATE DELAYED
HAZARD RELEASE OF (ACUTE) (CHRONIC)
PRESSURE HEALTH HEALTH
HAZARD HAZARD
PROPRIETARY SAX 350 YES. NO. NO. YES. NO.
SILYL TERMINATED
POLYETHER
1,2-CYCLOHEXANEDI- YES. NO. NO. YES. NO.
CARBOXYLIC ACID,
1, 2-DINONYL
ESTER, BRANCHED
AND LINEAR
TITANIUM DIOXIDE NO. NO. NO. NO. YES.
N-(3-(TRIMETHOXY- NO. NO. NO. YES. NO.
SILYL)PROPYL)
ETHYLENEDIAMINE
TRIMETHOXYVINYL- YES. NO. NO. YES. NO.
SILANE
DIBUTYLBIS(PENTANE- NO. NO. NO. YES. YES.
2,4-DIONATO-
O,O')TIN
ADDITIONAL ENVIRONMENTAL INFORMATION IS CONTAINED ON THE ENVIRONMENTAL
DATA SHEET FOR THIS PRODUCT, WHICH CAN BE OBTAINED FROM YOUR PPG
REPRESENTATIVE.
| SECTION 16. OTHER INFORMATION | |
HAZARDOUS MATERIAL INFORMATION SYSTEM (U.S.A.):
HEALTH 3*
FLAMMABILITY 0
PHYSICAL HAZARDS 0
(*) - CHRONIC EFFECTS
CAUTION:
HMIS(R*) RATINGS ARE BASED ON A 0-4 RATING SCALE, WITH 0 REPRESENTING
MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING SIGNIFICANT HAZARDS OR RISKS
ALTHOUGH HMIS(R*) RATINGS ARE NOT REQUIRED ON MSDSS UNDER 29 CFR 1910.1200,
THE PREPARER MAY CHOOSE TO PROVIDE THEM. HMIS(R*) RATINGS ARE TO BE USED
WITH A FULLY IMPLEMENTED HMIS(R*) PROGRAM. HMIS(R*) IS A REGISTERED MARK
OF THE NATIONAL PAINT & COATINGS ASSOCIATION (NPCA). HMIS(R*) MATERIALS
MAY BE PURCHASED EXCLUSIVELY FROM J. J. KELLER (800) 327-6868.
THE CUSTOMER IS RESPONSIBLE FOR DETERMINING THE PPE CODE FOR THIS MATERIAL.
NATIONAL FIRE PROTECTION ASSOCIATION (U.S.A.):
HEALTH 3
FLAMMABILITY 0
INSTABILITY 0
DATE OF PREVIOUS ISSUE: 5/1/2016
ORGANIZATION THAT PREPARED THE MSDS: EHS
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
IATA: INTERNATIONAL AIR T RANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS, 1973
AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
UN: UNITED NATIONS
| INDICATES INFORMATION THAT HAS CHANGED FROM PREVIOUSLY ISSUED VERSION.
DISCLAIMER:
THE INFORMATION CONTAINED IN THIS DATA SHEET IS BASED ON PRESENT SCIENTIFIC
AND TECHNICAL KNOWLEDGE. THE PURPOSE OF THIS INFORMATION IS TO DRAW
ATTENTION TO THE HEALTH AND SAFETY ASPECTS CONCERNING THE PRODUCTS SUPPLIED
BY PPG, AND TO RECOMMEND PRECAUTIONARY MEASURES FOR THE STORAGE AND
HANDLING OF THE PRODUCTS. NO WARRANTY OR GUARANTEE IS GIVEN IN RESPECT OF
THE PROPERTIES OF THE PRODUCTS. NO LIABILITY CAN BE ACCEPTED FOR ANY
FAILURE TO OBSERVE THE PRECAUTIONARY MEASURES DESCRIBED IN THIS DATA SHEET
OR FOR ANY MISUSE OF THE PRODUCTS.
UNITED STATES