| Common Name: | LN-2000 LIQUID NAILS FUZE IT |
| Manufacturer: | PPG INDUSTRIES |
| SDS Revision Date: | 1/3/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 444D87 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
PPG
DATE OF ISSUE/DATE OF REVISION: 3 JANUARY 2017
VERSION: 5.02
| SECTION 1. IDENTIFICATION |  |
PRODUCT NAME: LN-2000 LIQUID NAILS FUZE IT
PRODUCT CODE: 00378931
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
PRODUCT TYPE: SOLID.
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
PRODUCT USE: INDUSTRIAL APPLICATIONS.
USE OF THE SUBSTANCE/MIXTURE: ADHESIVE.
USES ADVISED AGAINST: NOT APPLICABLE.
MANUFACTURER:
PPG INDUSTRIES, INC.
ONE PPG PLACE
PITTSBURGH, PA 15272
EMERGENCY TELEPHONE NUMBER:
(412) 434-4515 (U.S.)
(514) 645-1320 (CANADA)
01-800-00-21-400 (MEXICO)
TECHNICAL PHONE NUMBER: 1-800-441-9695 (8:00 AM TO 5:00 PM EST)
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
EYE IRRITATION: CATEGORY 2A
SKIN SENSITIZATION: CATEGORY 1
TOXIC TO REPRODUCTION (FERTILITY): CATEGORY 1B
TOXIC TO REPRODUCTION (UNBORN CHILD): CATEGORY 1B
PERCENTAGE OF THE MIXTURE CONSISTING OF INGREDIENT(S) OF UNKNOWN TOXICITY:
74.4%
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS:
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
MAY DAMAGE FERTILITY OR THE UNBORN CHILD.
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. WEAR PROTECTIVE GLOVES. WEAR EYE
OR FACE PROTECTION. WEAR PROTECTIVE CLOTHING. AVOID BREATHING DUST. WASH
HANDS THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING MUST NOT BE
ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
IF ON SKIN:
WASH WITH PLENTY OF SOAP AND WATER. WASH CONTAMINATED CLOTHING BEFORE
REUSE.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
SUPPLEMENTAL LABEL:
TRIMETHOXYSILANES ARE CAPABLE OF FORMING METHANOL IF HYDROLYZED OR
INGESTED. IF ELEMENTS SWALLOWED, METHANOL MAY BE HARMFUL OR FATAL OR CAUSE
BLINDNESS. THIS PRODUCT EITHER CONTAINS FORMALDEHYDE OR IS CAPABLE OF
RELEASING FORMALDEHYDE ABOVE 0.5 PPM UNDER CERTAIN CONDITIONS. FORMALDEHYDE
IS A KNOWN CANCER HAZARD, A SKIN SENSITIZER AND A RESPIRATORY SENSITIZER.
EMITS TOXIC FUMES WHEN HEATED.
HAZARDS NOT OTHERWISE CLASSIFIED: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
PRODUCT NAME: LN-2000 LIQUID NAILS FUZE IT
INGREDIENT NAME % CAS NUMBER
LIMESTONE >/=50 - </=75 1317-65-3
PROPRIETARY TRADE SECRET ORGANIC >/=20 - </=38 NOT
AVAILABLE.
PROPRIETARY AMIDE WAX >/=1.0 - </=5.0 NOT
AVAILABLE.
N-(3-(TRIMETHOXYSILYL)PROPYL)ETHYLENEDIAMINE >/=1.0 - <3.0 1760-24-3
DIBUTYLBIS(PENTANE-2,4-DIONATO-O,O')TIN <1.0 22673-19-4
SUB CODES REPRESENT SUBSTANCES WITHOUT REGISTERED CAS NUMBERS.
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS DUE
TO BATCH VARIATION.
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH OR THE ENVIRONMENT AND HENCE REQUIRE
REPORTING IN THIS SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
IF INGESTION, IRRITATION, ANY TYPE OF OVEREXPOSURE OR SYMPTOMS OF
OVEREXPOSURE OCCUR DURING OR PERSISTS AFTER USE OF THIS PRODUCT, CONTACT A
POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN IMMEDIATELY; HAVE SAFETY
DATA SHEET INFORMATION AVAILABLE. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS OR CONVULSING PERSON.
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
REMOVE CONTACT LENSES, IRRIGATE COPIOUSLY WITH CLEAN, FRESH WATER, HOLDING
THE EYELIDS APART FOR AT LEAST 10 MINUTES AND SEEK IMMEDIATE MEDICAL
ADVICE.
INHALATION:
REMOVE TO FRESH AIR. KEEP PERSON WARM AND AT REST. IF NOT BREATHING, IF
BREATHING IS IRREGULAR OR IF RESPIRATORY ARREST OCCURS, PROVIDE ARTIFICIAL
RESPIRATION OR OXYGEN BY TRAINED PERSONNEL.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING AND SHOES. WASH SKIN THOROUGHLY WITH SOAP AND
WATER OR USE RECOGNIZED SKIN CLEANSER. DO NOT USE SOLVENTS OR THINNERS.
INGESTION:
IF SWALLOWED, SEEK MEDICAL ADVICE IMMEDIATELY AND SHOW THIS CONTAINER OR
LABEL. KEEP PERSON WARM AND AT REST. DO NOT INDUCE VOMITING.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT: MAY CAUSE AN ALLERGIC SKIN REACTION.
INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF
NECESSARY:
NOTES TO PHYSICIAN:
IN CASE OF INHALATION OF DECOMPOSITION PRODUCTS IN A FIRE, SYMPTOMS MAY BE
DELAYED. THE EXPOSED PERSON MAY NEED TO BE KEPT UNDER MEDICAL SURVEILLANCE
FOR 48 HOURS.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS. IT
MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION. WASH CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE
REMOVING IT, OR WEAR GLOVES.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE AN EXTINGUISHING AGENT SUITABLE FOR THE SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
VAPORS MAY ACCUMULATE IN LOW OR CONFINED AREAS OR TRAVEL A CONSIDERABLE
DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK. THIS MATERIAL IS HARMFUL
TO AQUATIC LIFE WITH LONG LASTING EFFECTS. FIRE WATER CONTAMINATED WITH
THIS MATERIAL MUST BE CONTAINED AND PREVENTED FROM BEING DISCHARGED TO ANY
WATERWAY, SEWER OR DRAIN.
HAZARDOUS THERMAL:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
DECOMPOSITION PRODUCTS
CARBON OXIDES
NITROGEN OXIDES
METAL OXIDE/OXIDES
FORMALDEHYDE.
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF
THE INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE
OPERATED IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL.
PROVIDE ADEQUATE VENTILATION. WEAR APPROPRIATE RESPIRATOR WHEN VENTILATION
IS INADEQUATE. PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALIZED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE OF
ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE ALSO
THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL OR
AIR).
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
MOVE CONTAINERS FROM SPILL AREA. AVOID DUST GENERATION. DO NOT DRY SWEEP.
VACUUM DUST WITH EQUIPMENT FITTED WITH A HEPA FILTER AND PLACE IN A CLOSED,
LABELED WASTE CONTAINER. PLACE SPILLED MATERIAL IN A DESIGNATED, LABELED
WASTE CONTAINER. DISPOSE OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
LARGE SPILL:
MOVE CONTAINERS FROM SPILL AREA. APPROACH RELEASE FROM UPWIND. PREVENT
ENTRY INTO SEWERS, WATER COURSES, BASEMENTS OR CONFINED AREAS. AVOID DUST
GENERATION. DO NOT DRY SWEEP. VACUUM DUST WITH EQUIPMENT FITTED WITH A HEPA
FILTER AND PLACE IN A CLOSED, LABELED WASTE CONTAINER. DISPOSE OF VIA A
LICENSED WASTE DISPOSAL CONTRACTOR.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). PERSONS
WITH A HISTORY OF SKIN SENSITIZATION PROBLEMS SHOULD NOT BE EMPLOYED IN ANY
PROCESS IN WHICH THIS PRODUCT IS USED. AVOID EXPOSURE - OBTAIN SPECIAL
INSTRUCTIONS BEFORE USE. AVOID EXPOSURE DURING PREGNANCY. DO NOT HANDLE
UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT GET IN
EYES OR ON SKIN OR CLOTHING. DO NOT INGEST. IF DURING NORMAL USE THE
MATERIAL PRESENTS A RESPIRATORY HAZARD, USE ONLY WITH ADEQUATE VENTILATION
OR WEAR APPROPRIATE RESPIRATOR. KEEP IN THE ORIGINAL CONTAINER OR AN
APPROVED ALTERNATIVE MADE FROM A COMPATIBLE MATERIAL, KEPT TIGHTLY CLOSED
WHEN NOT IN USE. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE AND CAN BE
HAZARDOUS. DO NOT REUSE CONTAINER.
SPECIAL PRECAUTIONS:
VAPORS MAY ACCUMULATE IN LOW OR CONFINED AREAS OR TRAVEL A CONSIDERABLE
DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK. VAPORS ARE HEAVIER THAN
AIR AND MAY SPREAD ALONG FLOORS. IF THIS MATERIAL IS PART OF A MULTIPLE
COMPONENT SYSTEM, READ THE SAFETY DATA SHEET(S) FOR THE OTHER COMPONENT OR
COMPONENTS BEFORE BLENDING AS THE RESULTING MIXTURE MAY HAVE THE HAZARDS OF
ALL OF ITS PARTS.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. REMOVE CONTAMINATED CLOTHING AND
PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS. SEE ALSO SECTION 8 FOR
ADDITIONAL INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
| DO NOT STORE ABOVE THE FOLLOWING TEMPERATURE: 50 DEG. C (122 DEG. F).
| STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE IN ORIGINAL CONTAINER
| PROTECTED FROM DIRECT SUNLIGHT IN A DRY, COOL AND WELL-VENTILATED AREA,
| AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10) AND FOOD AND DRINK.
| STORE LOCKED UP. KEEP CONTAINER TIGHTLY CLOSED AND SEALED UNTIL READY
| FOR USE. CONTAINERS THAT HAVE BEEN OPENED MUST BE CAREFULLY RESEALED
| AND KEPT UPRIGHT TO PREVENT LEAKAGE. DO NOT STORE IN UNLABELED
| CONTAINERS. USE APPROPRIATE CONTAINMENT TO AVOID ENVIRONMENTAL
| CONTAMINATION.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT NAME EXPOSURE LIMITS
LIMESTONE OSHA PEL (UNITED STATES, 2/2013).
TWA: 5 MG/M3 8 HOURS.
FORM: RESPIRABLE FRACTION
TWA: 15 MG/M3 8 HOURS.
FORM: TOTAL DUST
PROPRIETARY TRADE SECRET ORGANIC ACGIH TLV (UNITED STATES).
ABSORBED THROUGH SKIN.
TWA: 50 PPM
PROPRIETARY AMIDE WAX ACGIH TLV (UNITED STATES).
TWA: 3 MG/M3
FORM: RESPIRABLE DUST
TWA: 10 MG/M3
FORM: INHALABLE DUST
N-(3-(TRIMETHOXYSILYL)PROPYL) NONE.
ETHYLENEDIAMINE
DIBUTYLBIS(PENTANE-2,4- ACGIH TLV (UNITED STATES).
DIONATO-O,O')TIN ABSORBED THROUGH SKIN.
STEL: 0.2 MG/M3
OSHA PEL (UNITED STATES).
TWA: 0.1 MG/M3, (AS Sn)
TWA: 0.1 MG/M3, (AS Sn)
FORM: TOTAL DUST
ACGIH TLV (UNITED STATES, 3/2015).
TWA: 2 MG/M3, (AS Sn) 8 HOURS.
OSHA PEL (UNITED STATES, 2/2013).
TWA: 2 MG/M3, (AS Sn) 8 HOURS.
KEY TO ABBREVIATIONS
A = ACCEPTABLE MAXIMUM PEAK
ACGIH = AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS.
C = CEILING LIMIT
F = FUME
IPEL = INTERNAL PERMISSIBLE EXPOSURE LIMIT
OSHA = OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION.
R = RESPIRABLE
S = POTENTIAL SKIN ABSORPTION
SR = RESPIRATORY SENSITIZATION
SS = SKIN SENSITIZATION
STEL = SHORT TERM EXPOSURE LIMIT VALUES
TD = TOTAL DUST
TLV = THRESHOLD LIMIT VALUE
TWA = TIME WEIGHTED AVERAGE
Z = OSHA 29 CFR 1910.1200 SUBPART Z - TOXIC AND HAZARDOUS SUBSTANCES
CONSULT LOCAL AUTHORITIES FOR ACCEPTABLE EXPOSURE LIMITS.
RECOMMENDED MONITORING PROCEDURES:
IF THIS PRODUCT CONTAINS INGREDIENTS WITH EXPOSURE LIMITS, PERSONAL,
WORKPLACE ATMOSPHERE OR BIOLOGICAL MONITORING MAY BE REQUIRED TO DETERMINE
THE EFFECTIVENESS OF THE VENTILATION OR OTHER CONTROL MEASURES AND/OR THE
NECESSITY TO USE RESPIRATORY PROTECTIVE EQUIPMENT. REFERENCE SHOULD BE MADE
TO APPROPRIATE MONITORING STANDARDS. REFERENCE TO NATIONAL GUIDANCE
DOCUMENTS FOR METHODS FOR THE DETERMINATION OF HAZARDOUS SUBSTANCES WILL
ALSO BE REQUIRED.
APPROPRIATE ENGINEERING CONTROLS:
IF USER OPERATIONS GENERATE DUST, FUMES, GAS, VAPOR OR MIST, USE PROCESS
ENCLOSURES, LOCAL EXHAUST VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP
WORKER EXPOSURE TO AIRBORNE CONTAMINANTS BELOW ANY RECOMMENDED OR STATUTORY
LIMITS.
ENVIRONMENTAL EXPOSURE:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED
TO ENSURE CONTROLS THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL
PROTECTION LEGISLATION. IN SOME CASES, FUME SCRUBBERS, FILTERS OR
ENGINEERING MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY
TO REDUCE EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT
OF THE WORKPLACE. WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE THAT
EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION LOCATION.
EYE/FACE PROTECTION: CHEMICAL SPLASH GOGGLES.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY. CONSIDERING THE PARAMETERS
SPECIFIED BY THE GLOVE MANUFACTURER, CHECK DURING USE THAT THE GLOVES ARE
STILL RETAINING THEIR PROTECTIVE PROPERTIES. IT SHOULD BE NOTED THAT THE
TIME TO BREAKTHROUGH FOR ANY GLOVE MATERIAL MAY BE DIFFERENT FOR DIFFERENT
GLOVE MANUFACTURERS. IN THE CASE OF MIXTURES, CONSISTING OF SEVERAL
SUBSTANCES, THE PROTECTION TIME OF THE GLOVES CANNOT BE ACCURATELY
ESTIMATED.
GLOVES: BUTYL RUBBER
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD BE
SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
RESPIRATOR SELECTION MUST BE BASED ON KNOWN OR ANTICIPATED EXPOSURE LEVELS,
THE HAZARDS OF THE PRODUCT AND THE SAFE WORKING LIMITS OF THE SELECTED
RESPIRATOR. IF WORKERS ARE EXPOSED TO CONCENTRATIONS ABOVE THE EXPOSURE
LIMIT, THEY MUST USE APPROPRIATE, CERTIFIED RESPIRATORS. USE A PROPERLY
FITTED, AIR-PURIFYING OR AIR-FED RESPIRATOR COMPLYING WITH AN APPROVED
STANDARD IF A RISK ASSESSMENT INDICATES THIS IS NECESSARY.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: SOLID.
| COLOR: GRAY.
ODOR: CHARACTERISTIC.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT: NOT AVAILABLE.
BOILING POINT: NOT AVAILABLE.
FLASH POINT:
CLOSED CUP: NOT APPLICABLE. [PRODUCT DOES NOT SUSTAIN COMBUSTION.]
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
| LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS: NOT AVAILABLE.
EVAPORATION RATE: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
VAPOR DENSITY: NOT AVAILABLE.
RELATIVE DENSITY: 1.47
DENSITY (LBS / GAL): 12.27
SOLUBILITY:
INSOLUBLE IN THE FOLLOWING MATERIALS: COLD WATER.
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE.
VISCOSITY:
KINEMATIC (40 DEG. C (104 DEG. F)): NOT APPLICABLE.
VOLATILITY: 1% (V/V), 0.028% (W/W)
% SOLID. (W/W): 99.972
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NO SPECIFIC TEST DATA RELATED TO REACTIVITY AVAILABLE FOR THIS PRODUCT OR
ITS INGREDIENTS.
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID:
WHEN EXPOSED TO HIGH TEMPERATURES MAY PRODUCE HAZARDOUS DECOMPOSITION
PRODUCTS.
REFER TO PROTECTIVE MEASURES LISTED IN SECTIONS 7 AND 8.
INCOMPATIBLE MATERIALS:
KEEP AWAY FROM THE FOLLOWING MATERIALS TO PREVENT STRONG EXOTHERMIC
REACTIONS: OXIDIZING AGENTS, STRONG ALKALIS, STRONG ACIDS.
HAZARDOUS DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON MONOXIDE, CARBON DIOXIDE, SMOKE, OXIDES OF NITROGEN.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
PROPRIETARY TRADE LC50 INHALATION RAT 48000 PPM 4 HOURS
SECRET ORGANIC GAS.
LD50 DERMAL RABBIT 3000 MG/KG
N-(3-(TRIMETHOXYSILYL) LD50 ORAL RAT 2413 MG/KG
PROPYL) ETHYLENEDIAMINE
DIBUTYLBIS(PENTANE- LD50 ORAL RAT >2 G/KG
2,4-DIONATO-O,O')TIN
CONCLUSION/SUMMARY: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
IRRITATION/CORROSION:
CONCLUSION/SUMMARY:
SKIN: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
EYES: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
RESPIRATORY: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
SENSITIZATION:
CONCLUSION/SUMMARY:
SKIN: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
RESPIRATORY: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
MUTAGENICITY:
CONCLUSION/SUMMARY: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
CARCINOGENICITY:
CONCLUSION/SUMMARY: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
REPRODUCTIVE TOXICITY:
CONCLUSION/SUMMARY: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
TERATOGENICITY:
CONCLUSION/SUMMARY: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
NAME CATEGORY
DIBUTYLBIS(PENTANE-2,4-DIONATO-O,O')TIN CATEGORY 1
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE):
NAME CATEGORY
| DIBUTYLBIS(PENTANE-2,4-DIONATO-O,O')TIN CATEGORY 1
TARGET ORGANS:
CONTAINS MATERIAL WHICH MAY CAUSE DAMAGE TO THE FOLLOWING ORGANS:
LUNGS, UPPER RESPIRATORY TRACT, SKIN, EYES.
ASPIRATION HAZARD: NOT AVAILABLE.
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT: MAY CAUSE AN ALLERGIC SKIN REACTION.
INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG
TERM EXPOSURE:
CONCLUSION/SUMMARY:
THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF. TRIMETHOXYSILANES ARE
CAPABLE OF FORMING METHANOL IF HYDROLYZED OR INGESTED. IF SWALLOWED,
METHANOL MAY BE HARMFUL OR FATAL OR CAUSE BLINDNESS. THIS PRODUCT EITHER
CONTAINS FORMALDEHYDE OR IS CAPABLE OF RELEASING FORMALDEHYDE ABOVE 0.5 PPM
UNDER CERTAIN CONDITIONS. FORMALDEHYDE IS A KNOWN CANCER HAZARD, A SKIN
SENSITIZER AND A RESPIRATORY SENSITIZER. INGESTION MAY CAUSE NAUSEA,
DIARRHEA AND VOMITING. THIS TAKES INTO ACCOUNT, WHERE KNOWN, DELAYED AND
IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS OF COMPONENTS FROM SHORT-TERM
AND LONG-TERM EXPOSURE BY ORAL, INHALATION AND DERMAL ROUTES OF EXPOSURE
AND EYE CONTACT.
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS:
THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
POTENTIAL DELAYED EFFECTS:
THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS:
THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
POTENTIAL DELAYED EFFECTS:
THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
POTENTIAL CHRONIC HEALTH EFFECTS:
GENERAL:
ONCE SENSITIZED, A SEVERE ALLERGIC REACTION MAY OCCUR WHEN SUBSEQUENTLY
EXPOSED TO VERY LOW LEVELS.
CARCINOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: MAY DAMAGE THE UNBORN CHILD.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: MAY DAMAGE FERTILITY.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY ESTIMATES:
ROUTE ATE VALUE
ORAL 54445.8 MG/KG
DERMAL 3659 MG/KG
INHALATION (GASES) 101535.9 PPM
INHALATION (VAPORS) 248.2 MG/L
INHALATION (DUSTS AND MISTS) 33.85 MG/L
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES EXPOSURE
PROPRIETARY AMIDE WAX EC50: 29 TO 43 MG/L ALGAE 72 HOURS
EC50: 94 MG/L DAPHNIA 48 HOURS
PERSISTENCE AND DEGRADABILITY:
PRODUCT/INGREDIENT NAME TEST RESULT DOSE INOCULUM
PROPRIETARY AMIDE WAX 63% - READILY - 28 DAYS
PRODUCT/INGREDIENT NAME AQUATIC HALF-LIFE PHOTOLYSIS BIODEGRADABILITY
PROPRIETARY AMIDE WAX READILY
BIOACCUMULATIVE POTENTIAL: NOT AVAILABLE.
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL TIMES
COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE DISPOSAL
LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE OF
SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL
CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE SEWER UNLESS
FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH JURISDICTION.
WASTE PACKAGING SHOULD BE RECYCLED. INCINERATION OR LANDFILL SHOULD ONLY BE
CONSIDERED WHEN RECYCLING IS NOT FEASIBLE. THIS MATERIAL AND ITS CONTAINER
MUST BE DISPOSED OF IN A SAFE WAY. CARE SHOULD BE TAKEN WHEN HANDLING
EMPTIED CONTAINERS THAT HAVE NOT BEEN CLEANED OR RINSED OUT. EMPTY
CONTAINERS OR LINERS MAY RETAIN SOME PRODUCT RESIDUES. AVOID DISPERSAL OF
SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL, WATERWAYS, DRAINS AND
SEWERS.
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND
LOCAL LAWS AND REGULATIONS.
REFER TO SECTION 7: HANDLING AND STORAGE AND SECTION 8: EXPOSURE
CONTROLS/PERSONAL PROTECTION FOR ADDITIONAL HANDLING INFORMATION AND
PROTECTION OF EMPLOYEES. SECTION 6. ACCIDENTAL RELEASE MEASURES
| SECTION 14. TRANSPORT INFORMATION | |
DOT IMDG IATA
UN NUMBER NOT REGULATED. NOT REGULATED. NOT REGULATED.
UN PROPER
SHIPPING NAME
TRANSPORT
HAZARD
CLASS(ES)
PACKING GROUP
ENVIRONMENTAL NO. NO. NO.
HAZARDS
MARINE NOT APPLICABLE. NOT APPLICABLE. NOT APPLICABLE.
POLLUTANT
SUBSTANCES
ADDITIONAL INFORMATION:
DOT: NONE IDENTIFIED.
IMDG: NONE IDENTIFIED.
IATA: NONE IDENTIFIED.
SPECIAL PRECAUTIONS FOR USER:
TRANSPORT WITHIN USER'S PREMISES:
ALWAYS TRANSPORT IN CLOSED CONTAINERS THAT ARE UPRIGHT AND SECURE. ENSURE
THAT PERSONS TRANSPORTING THE PRODUCT KNOW WHAT TO DO IN THE EVENT OF AN
ACCIDENT OR SPILLAGE.
| SECTION 15. REGULATORY INFORMATION | |
UNITED STATES:
UNITED STATES INVENTORY (TSCA 8B): ALL COMPONENTS ARE LISTED OR EXEMPTED.
SARA 302/304:
SARA 304 RQ: NOT APPLICABLE.
COMPOSITION/INFORMATION ON INGREDIENTS: NO PRODUCTS WERE FOUND.
SARA 311/312:
CLASSIFICATION:
IMMEDIATE (ACUTE) HEALTH HAZARD
DELAYED (CHRONIC) HEALTH HAZARD
COMPOSITION/INFORMATION ON INGREDIENTS:
NAME FIRE SUDDEN REACTIVE IMMEDIATE DELAYED
HAZARD RELEASE OF (ACUTE) (CHRONIC)
PRESSURE HEALTH HEALTH
HAZARD HAZARD
PROPRIETARY TRADE YES. NO. NO. NO. NO.
SECRET ORGANIC
PROPRIETARY AMIDE YES. NO. NO. YES. NO.
WAX
N-(3-(TRIMETHOXY- NO. NO. NO. YES. NO.
SILYL)PROPYL)
ETHYLENEDIAMINE
DIBUTYLBIS(PENTANE- NO. NO. NO. YES. YES.
2,4-DIONATO-O,O')
TIN
ADDITIONAL ENVIRONMENTAL INFORMATION IS CONTAINED ON THE ENVIRONMENTAL DATA
SHEET FOR THIS PRODUCT, WHICH CAN BE OBTAINED FROM YOUR PPG REPRESENTATIVE.
| SECTION 16. OTHER INFORMATION | |
HAZARDOUS MATERIAL INFORMATION SYSTEM (U.S.A.):
HEALTH 2*
FLAMMABILITY 0
PHYSICAL HAZARDS 0
(*) - CHRONIC EFFECTS
CAUTION:
HMIS(R*) RATINGS ARE BASED ON A 0-4 RATING SCALE, WITH 0 REPRESENTING
MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING SIGNIFICANT HAZARDS OR RISKS
ALTHOUGH HMIS(R*) RATINGS ARE NOT REQUIRED ON MSDSS UNDER 29 CFR 1910.1200,
THE PREPARER MAY CHOOSE TO PROVIDE THEM. HMIS(R*) RATINGS ARE TO BE USED
WITH A FULLY IMPLEMENTED HMIS(R*) PROGRAM. HMIS(R*) IS A REGISTERED MARK OF
THE NATIONAL PAINT & COATINGS ASSOCIATION (NPCA). HMIS(R*) MATERIALS MAY BE
PURCHASED EXCLUSIVELY FROM J. J. KELLER (800) 327-6868.
THE CUSTOMER IS RESPONSIBLE FOR DETERMINING THE PPE CODE FOR THIS MATERIAL.
NATIONAL FIRE PROTECTION ASSOCIATION (U.S.A.):
HEALTH 2
FLAMMABILITY 0
INSTABILITY 0
DATE OF PREVIOUS ISSUE: 12/9/2016
ORGANIZATION THAT PREPARED THE MSDS: EHS
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS, 1973
AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
UN: UNITED NATIONS
| INDICATES INFORMATION THAT HAS CHANGED FROM PREVIOUSLY ISSUED VERSION.
DISCLAIMER:
THE INFORMATION CONTAINED IN THIS DATA SHEET IS BASED ON PRESENT SCIENTIFIC
AND TECHNICAL KNOWLEDGE. THE PURPOSE OF THIS INFORMATION IS TO DRAW
ATTENTION TO THE HEALTH AND SAFETY ASPECTS CONCERNING THE PRODUCTS SUPPLIED
BY PPG, AND TO RECOMMEND PRECAUTIONARY MEASURES FOR THE STORAGE AND
HANDLING OF THE PRODUCTS. NO WARRANTY OR GUARANTEE IS GIVEN IN RESPECT OF
THE PROPERTIES OF THE PRODUCTS. NO LIABILITY CAN BE ACCEPTED FOR ANY
FAILURE TO OBSERVE THE PRECAUTIONARY MEASURES DESCRIBED IN THIS DATA SHEET
OR FOR ANY MISUSE OF THE PRODUCTS.
UNITED STATES