| Common Name: | TKO HC 4-1GL |
| Manufacturer: | ZEP MANUFACTURING |
| SDS Revision Date: | 9/14/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 449W33 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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ZEP INC
SAFETY DATA SHEET
ZEP TKO HC 4-1GL
VERSION: 1.2
REVISION DATE: 09/14/2017
PRINT DATE: 01/10/2018
| SECTION 1. PRODUCT AND COMPANY IDENTIFICATION |  |
MATERIAL NAME: ZEP TKO HC 4-1GL
MATERIAL NUMBER: R54824
MANUFACTURER OR SUPPLIER'S DETAILS:
COMPANY: ZEP INC.
ADDRESS:
350 JOE FRANK HARRIS PARKWAY, SE
EMERSON, GA 30137
TELEPHONE: 404-352-1680
EMERGENCY TELEPHONE NUMBERS:
FOR SDS INFORMATION:
COMPLIANCE SERVICES: 1-877-428-9937
FOR A MEDICAL EMERGENCY: 877-541-2016 TOLL FREE - ALL CALLS RECORDED
FOR A TRANSPORTATION EMERGENCY:
CHEMTREC: 800-424-9300 - ALL CALLS RECORDED.
IN THE DISTRICT OF COLUMBIA: 202-483-7616
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: HAND CARE
| SECTION 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
APPEARANCE: VISCOUS
COLOUR: LIGHT BLUE
ODOUR: CHARACTERISTIC
GHS CLASSIFICATION:
EYE IRRITATION: CATEGORY 2A
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS: EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
H319: CAUSES SERIOUS EYE IRRITATION.
PRECAUTIONARY STATEMENTS:
PREVENTION:
P264: WASH SKIN THOROUGHLY AFTER HANDLING.
P280: WEAR EYE PROTECTION/FACE PROTECTION.
RESPONSE:
P305 + P351 + P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P337 + P313:
IF EYE IRRITATION PERSISTS:
GET MEDICAL ADVICE/ATTENTION.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE / MIXTURE: MIXTURE
HAZARDOUS COMPONENTS:
CHEMICAL NAME CAS-NO. CONCENTRATION [%]
SULFONIC ACIDS, C14-16-ALKANE HYDROXY 68439-57-6 >=5 - <10
AND C14-16-ALKENE, SODIUM SALTS
1-PROPANAMINIUM, N-(3-AMINOPROPYL)- 68139-30-0 >=1 - <5
2-HYDROXY-N,N-DIMETHYL-3-SULFO-,
N-COCO ACYL DERIVS., HYDROXIDES,
INNER SALTS
ALCOHOLS, C9-11, ETHOXYLATED 68439-46-3 >=1 - <3
FULLER'S EARTH 8031-18-3 >=1 - <5
THE EXACT PERCENTAGES OF DISCLOSED SUBSTANCES ARE WITHHELD AS TRADE
SECRETS.
| SECTION 4. FIRST AID MEASURES | |
GENERAL ADVICE: DO NOT LEAVE THE VICTIM UNATTENDED.
IF INHALED:
IF UNCONSCIOUS, PLACE IN RECOVERY POSITION AND SEEK MEDICAL ADVICE.
IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
IN CASE OF SKIN CONTACT:
THIS PRODUCT IS FORMULATED FOR USE ON SKIN BUT SHOULD ALWAYS BE IMMEDIATELY
WASHED OFF WITH PLENTY OF WATER. DISCONTINUE USE IF IRRITATION AND REDNESS
DEVELOP. IF CONDITIONS PERSIST FOR MORE THAN 72 HOURS, CONSULT A PHYSICIAN.
IN CASE OF EYE CONTACT:
REMOVE CONTACT LENSES.
PROTECT UNHARMED EYE.
IF EYE IRRITATION PERSISTS, CONSULT A SPECIALIST.
IF SWALLOWED:
KEEP RESPIRATORY TRACT CLEAR.
DO NOT GIVE MILK OR ALCOHOLIC BEVERAGES.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
EFFECTS ARE IMMEDIATE AND DELAYED.
SYMPTOMS MAY INCLUDE IRRITATION, REDNESS, PAIN, AND RASH.
CAUSES SERIOUS EYE IRRITATION.
REVIEW SECTION 2 OF SDS TO SEE ALL POTENTIAL HAZARDS.
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY. SYMPTOMS MAY BE DELAYED.
| SECTION 5. FIREFIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
DRY CHEMICAL
FOAM
ALCOHOL-RESISTANT FOAM
CARBON DIOXIDE (CO2)
UNSUITABLE EXTINGUISHING MEDIA: HIGH VOLUME WATER JET
HAZARDOUS COMBUSTION PRODUCTS:
CARBON DIOXIDE (CO2)
CARBON MONOXIDE
SMOKE
NITROGEN OXIDES (NOX)
SPECIFIC EXTINGUISHING METHODS:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT.
FURTHER INFORMATION: STANDARD PROCEDURE FOR CHEMICAL FIRES.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
WEAR SELF-CONTAINED BREATHING APPARATUS FOR FIREFIGHTING IF NECESSARY.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
MATERIAL CAN CREATE SLIPPERY CONDITIONS.
USE NON-SLIP SAFETY SHOES IN AREAS WHERE SPILLS OR LEAKS CAN OCCUR.
REFER TO PROTECTIVE MEASURES LISTED IN SECTIONS 7 AND 8.
ENVIRONMENTAL PRECAUTIONS:
PREVENT PRODUCT FROM ENTERING DRAINS.
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
IF THE PRODUCT CONTAMINATES RIVERS AND LAKES OR DRAINS INFORM RESPECTIVE
AUTHORITIES.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND, SILICA GEL, ACID BINDER,
UNIVERSAL BINDER, SAWDUST).
KEEP IN SUITABLE, CLOSED CONTAINERS FOR DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
ADVICE ON SAFE HANDLING:
FOR PERSONAL PROTECTION SEE SECTION 8.
SMOKING, EATING AND DRINKING SHOULD BE PROHIBITED IN THE APPLICATION AREA.
DISPOSE OF RINSE WATER IN ACCORDANCE WITH LOCAL AND NATIONAL REGULATIONS.
AVOID CONTACT WITH EYES.
CONDITIONS FOR SAFE STORAGE:
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE.
CONTAINERS WHICH ARE OPENED MUST BE CAREFULLY RESEALED AND KEPT UPRIGHT TO
PREVENT LEAKAGE.
MATERIALS TO AVOID: NO MATERIALS TO BE ESPECIALLY MENTIONED.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
COMPONENTS WITH WORKPLACE CONTROL PARAMETERS:
CONTAINS NO SUBSTANCES WITH OCCUPATIONAL EXPOSURE LIMIT VALUES.
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION:
NO PERSONAL RESPIRATORY PROTECTIVE EQUIPMENT NORMALLY REQUIRED.
HAND PROTECTION:
REMARKS: NO SPECIAL PROTECTION IS REQUIRED.
EYE PROTECTION:
EYE PROTECTION IS NOT REQUIRED WHILE WASHING WITH THIS PRODUCT.
IN THE WORKPLACE, THE USE OF SAFETY GLASSES IS RECOMMENDED TO AVOID EYE
EXPOSURE DURING THE HANDLING OF CONTAINERS OR DURING SPILL CLEAN-UP.
SKIN AND BODY PROTECTION: NO SPECIAL PROTECTION IS REQUIRED.
HYGIENE MEASURES:
WHEN USING DO NOT EAT OR DRINK.
WHEN USING DO NOT SMOKE.
WASH HANDS BEFORE BREAKS AND IMMEDIATELY AFTER HANDLING THE PRODUCT.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: VISCOUS
COLOUR: LIGHT BLUE
ODOUR: CHARACTERISTIC
ODOUR THRESHOLD: NO DATA AVAILABLE
PH: 5.5 - 6.5
MELTING POINT/FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: 100 DEG. C
FLASH POINT: DOES NOT FLASH
EVAPORATION RATE: 1
UPPER EXPLOSION LIMIT: NO DATA AVAILABLE
LOWER EXPLOSION LIMIT: NO DATA AVAILABLE
VAPOUR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOUR DENSITY: NO DATA AVAILABLE
DENSITY: 1.102 G/CM3
SOLUBILITY(IES):
WATER SOLUBILITY: SOLUBLE
SOLUBILITY IN OTHER SOLVENTS: NOT DETERMINED
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NOT DETERMINED
THERMAL DECOMPOSITION: NO DATA AVAILABLE
VISCOSITY:
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY: STABLE
CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
NO HAZARDS TO BE SPECIALLY MENTIONED.
CONDITIONS TO AVOID: NO DATA AVAILABLE
INCOMPATIBLE MATERIALS: NONE.
HAZARDOUS DECOMPOSITION PRODUCTS: CARBON OXIDES
| SECTION 11. TOXICOLOGICAL INFORMATION | |
POTENTIAL HEALTH EFFECTS:
AGGRAVATED MEDICAL CONDITION: NONE KNOWN.
SYMPTOMS OF OVEREXPOSURE:
EFFECTS ARE IMMEDIATE AND DELAYED.
SYMPTOMS MAY INCLUDE IRRITATION, REDNESS, PAIN, AND RASH.
CARCINOGENICITY:
IARC:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS PROBABLE, POSSIBLE OR CONFIRMED HUMAN CARCINOGEN BY
IARC.
ACGIH:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY ACGIH.
OSHA:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS ON OSHA'S LIST OF REGULATED CARCINOGENS.
NTP:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
ACUTE TOXICITY:
PRODUCT:
ACUTE ORAL TOXICITY:
ACUTE TOXICITY ESTIMATE: >5,000 MG/KG
METHOD: CALCULATION METHOD
ACUTE INHALATION TOXICITY:
ACUTE TOXICITY ESTIMATE: 59.11 MG/L
EXPOSURE TIME: 4 H
TEST ATMOSPHERE: VAPOUR
METHOD: CALCULATION METHOD
COMPONENTS:
ALCOHOLS, C9-11, ETHOXYLATED:
ACUTE ORAL TOXICITY:
LD50 ORAL RAT: 1,400 MG/KG
SKIN CORROSION/IRRITATION:
PRODUCT:
RESULT: NO SKIN IRRITATION
SERIOUS EYE DAMAGE/EYE IRRITATION:
PRODUCT:
RESULT: IRRITATING TO EYES.
RESPIRATORY OR SKIN SENSITISATION: NO DATA AVAILABLE
GERM CELL MUTAGENICITY: NO DATA AVAILABLE
CARCINOGENICITY: NO DATA AVAILABLE
REPRODUCTIVE TOXICITY: NO DATA AVAILABLE
STOT - SINGLE EXPOSURE: NO DATA AVAILABLE
STOT - REPEATED EXPOSURE: NO DATA AVAILABLE
ASPIRATION TOXICITY: NO DATA AVAILABLE
FURTHER INFORMATION:
PRODUCT:
REMARKS: NO DATA AVAILABLE
| SECTION 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: NO DATA AVAILABLE
PERSISTENCE AND DEGRADABILITY: NO DATA AVAILABLE
BIOACCUMULATIVE POTENTIAL:
PRODUCT:
PARTITION COEFFICIENT N-OCTANOL/WATER:
REMARKS: NO DATA AVAILABLE
MOBILITY IN SOIL: NO DATA AVAILABLE
OTHER ADVERSE EFFECTS: NO DATA AVAILABLE
PRODUCT:
REGULATION:
40 CFR PROTECTION OF ENVIRONMENT; PART 82 PROTECTION OF STRATOSPHERIC
OZONE - CAA SECTION 602 CLASS I SUBSTANCES
REMARKS:
THIS PRODUCT NEITHER CONTAINS, NOR WAS MANUFACTURED WITH A CLASS I OR CLASS
II ODS AS DEFINED BY THE U.S. CLEAN AIR ACT SECTION 602 (40 CFR 82, SUBPT.
A, APP.A + B).
ADDITIONAL ECOLOGICAL INFORMATION: NO DATA AVAILABLE
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
WASTE FROM RESIDUES: DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS.
CONTAMINATED PACKAGING:
EMPTY REMAINING CONTENTS.
DISPOSE OF AS UNUSED PRODUCT.
DO NOT RE-USE EMPTY CONTAINERS.
| SECTION 14. TRANSPORT INFORMATION | |
TRANSPORTATION REGULATION:
49 CFR (USA): NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
TRANSPORTATION REGULATION:
IMDG (VESSEL): NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
TRANSPORTATION REGULATION:
IATA (CARGO AIR): NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
TRANSPORTATION REGULATION:
IATA (PASSENGER AIR):
NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
TRANSPORTATION REGULATION:
TDG (CANADA): NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
THE PRODUCT AS DELIVERED TO THE CUSTOMER CONFORMS TO PACKAGING REQUIREMENTS
FOR SHIPMENT BY ROAD UNDER US DEPARTMENT OF TRANSPORTATION (DOT)
REGULATIONS. ADDITIONAL TRANSPORTATION CLASSIFICATIONS NOTED ABOVE ARE FOR
REFERENCE ONLY, AND NOT A CERTIFICATION OR WARRANTY OF THE SUITABILITY OF
THE PACKAGING FOR SHIPMENT UNDER THESE ALTERNATIVE TRANSPORT REGULATIONS.
| SECTION 15. REGULATORY INFORMATION | |
TSCA LIST:
NO SUBSTANCES ARE SUBJECT TO A SIGNIFICANT NEW USE RULE.
NO SUBSTANCES ARE SUBJECT TO TSCA 12(B) EXPORT NOTIFICATION REQUIREMENTS.
EPCRA - EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT:
CERCLA REPORTABLE QUANTITY:
COMPONENTS CAS-NO. COMPONENT RQ CALCULATED PRODUCT RQ
(LBS) (LBS)
METHANOL 67-56-1 5000 *
*: CALCULATED RQ EXCEEDS REASONABLY ATTAINABLE UPPER LIMIT.
SARA 304 EXTREMELY HAZARDOUS SUBSTANCES REPORTABLE QUANTITY:
THIS MATERIAL DOES NOT CONTAIN ANY COMPONENTS WITH A SECTION 304 EHS RQ.
SARA 311/312 HAZARDS: SERIOUS EYE DAMAGE OR EYE IRRITATION
SARA 302:
NO CHEMICALS IN THIS MATERIAL ARE SUBJECT TO THE REPORTING REQUIREMENTS OF
SARA TITLE III, SECTION 302.
SARA 313:
THIS MATERIAL DOES NOT CONTAIN ANY CHEMICAL COMPONENTS WITH KNOWN CAS
NUMBERS THAT EXCEED THE THRESHOLD (DE MINIMIS) REPORTING LEVELS ESTABLISHED
BY SARA TITLE III, SECTION 313.
CALIFORNIA PROP. 65:
THIS PRODUCT CONTAINS A CHEMICAL THAT IS AT OR BELOW CALIFORNIA
PROPOSITIONS 65'S "SAFE HARBOR LEVEL" AS DETERMINED VIA A RISK ASSESSMENT.
THEREFORE, THE CHEMICAL IS NOT REQUIRED TO BE LISTED AS A PROP 65 CHEMICAL
ON THE SDS OR LABEL.
THE COMPONENTS OF THIS PRODUCT ARE REPORTED IN THE FOLLOWING INVENTORIES:
DSL:
THIS PRODUCT CONTAINS ONE OR MORE COMPONENTS THAT ARE LISTED ON THE
CANADIAN NDSL. ALL OTHER COMPONENTS ARE ON THE CANADIAN DSL.
TSCA: ON TSCA INVENTORY
FOR INFORMATION ON THE COUNTRY NOTIFICATION STATUS FOR OTHER REGIONS PLEASE
CONTACT THE MANUFACTURER'S REGULATORY GROUP.
INVENTORY ACRONYM AND VALIDITY AREA LEGEND:
TSCA (USA), DSL (CANADA), NDSL (CANADA)
| SECTION 16. OTHER INFORMATION | |
FURTHER INFORMATION:
NFPA:
HEALTH 2
FLAMMABILITY 0
INSTABILITY 0
SPECIAL HAZARD.
HMIS III:
HEALTH 2
FLAMMABILITY 0
PHYSICAL HAZARD 0
0 = NOT SIGNIFICANT
1 = SLIGHT
2 = MODERATE
3 = HIGH
4 = EXTREME
* = CHRONIC
OSHA - GHS LABEL INFORMATION:
HAZARD PICTOGRAMS: EXCLAMATION MARK
SIGNAL WORD:
WARNING:
HAZARD STATEMENTS: CAUSES SERIOUS EYE IRRITATION.
PRECAUTIONARY STATEMENTS:
PREVENTION:
WASH SKIN THOROUGHLY AFTER HANDLING. WEAR EYE PROTECTION/FACE PROTECTION.
RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY W ITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
VERSION: 1.2
REVISION DATE: 09/14/2017
PRINT DATE: 01/10/2018
WE BELIEVE THE STATEMENTS, TECHNICAL INFORMATION AND RECOMMENDATIONS
CONTAINED HEREIN ARE RELIABLE, BUT THEY ARE GIVEN WITHOUT WARRANTY OR
GUARANTEE OF ANY KIND. THE INFORMATION IN THIS DOCUMENT APPLIES TO THIS
SPECIFIC MATERIAL AS SUPPLIED. IT MAY NOT BE VALID FOR THIS MATERIAL IF IT
IS USED IN COMBINATION WITH ANY OTHER MATERIALS. USERS SHOULD MAKE THEIR
OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY AND APPLICABILITY OF THE
INFORMATION FOR THEIR PARTICULAR PURPOSES.
THIS SDS HAS BEEN PREPARED BY THE COMPLIANCE SERVICES ORGANIZATION
SUPPORTING THIS MANUFACTURER, SUPPLIER OR DISTRIBUTOR.
ZEP INC. MARKETS PRODUCTS UNDER WELL RECOGNIZED AND ESTABLISHED BRAND NAMES
SUCH AS ZEP(R*), ZEP COMMERCIAL(R*),ZEP PROFESSIONAL(R*), ENFORCER(R*),
NATIONAL CHEMICAL(TM), SELIG(TM), MISTY(R*), NEXT DIMENSION(TM), PETRO(R*),
I-CHEM(R*), TIMEMIST(R*), TIMEWICK(TM), MICROBEMAX(R*), COUNTRY VET(R*),
KONK(R*), ORIGINAL BIKE SPIRITS(R*), BLUE CORAL(R*), BLACK MAGIC(R*),
RAIN-X(R*), NIAGARA NATIONAL(TM), FC FORWARD CHEMICALS(R*),REXODAN(R*),
MYKAL(TM), AND A NUMBER OF PRIVATE LABELED BRANDS.