| Common Name: | 2C B2 POLYURETHANE FOAM, DUOFIX |
| Manufacturer: | HAGO CHEMOTECHNIK GERMANY |
| SDS Revision Date: | 8/26/2014 |
| SDS Format: | GHS-EU |
| Item Number(s): | 44F774 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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HAGO
SAFETY DATA SHEET
ACCORDING TO REGULATION (EC) NO 1907/2006
2C B2 POLYURETHANE FOAM, DUOFIX
PRINT DATE: 26.08.2014
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER: 2C B2 POLYURETHANE FOAM, DUOFIX
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE OF THE SUBSTANCE/MIXTURE: ADHESIVES, SEALANTS
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
COMPANY NAME: HAGO CHEMOTECHNIK GMBH & CO. KG
STREET: BODENSEESTR. 217
PLACE: D-81243 MUNCHEN
TELEPHONE: +49 (0)89 897702-0
E-MAIL: MSDS@HAGO.DE
CONTACT PERSON: CLAUDIA MEYER-PUNDSACK
TELEPHONE: -58
E-MAIL: CLAUDIA.MEYER-PUNDSACK@HAGO.DE
INTERNET: WWW.HAGO.DE
RESPONSIBLE DEPARTMENT: DEPT. DEVELOPMENT AND APPLICATION
1.4. EMERGENCY TELEPHONE NUMBER:
PUBLIC EMERGENCY NUMBER:
GIFTNOTRUF BERLIN: 030-30686-790 (24 H)
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
INDICATIONS OF DANGER:
F+ - EXTREMELY FLAMMABLE, XN - HARMFUL, XI - IRRITANT
R PHRASES:
EXTREMELY FLAMMABLE.
IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
LIMITED EVIDENCE OF A CARCINOGENIC EFFECT.
MAY CAUSE SENSITISATION BY INHALATION AND SKIN CONTACT.
HARMFUL:
DANGER OF SERIOUS DAMAGE TO HEALTH BY PROLONGED EXPOSURE THROUGH
INHALATION.
HARMFUL TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE
AQUATIC ENVIRONMENT.
GHS CLASSIFICATION:
HAZARD CATEGORIES:
AEROSOL: AEROSOL 1
SKIN CORROSION/IRRITATION: SKIN IRRIT. 2
SERIOUS EYE DAMAGE/EYE IRRITATION: EYE DAM. 1
RESPIRATORY/SKIN SENSITIZATION: RESP. SENS. 1
RESPIRATORY/SKIN SENSITIZATION: SKIN SENS. 1
CARCINOGENICITY: CARC. 2
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: STOT SE 3
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: STOT RE 2
HAZARDOUS TO THE AQUATIC ENVIRONMENT: AQUATIC CHRONIC 3
HAZARD STATEMENTS:
EXTREMELY FLAMMABLE AEROSOL.
PRESSURISED CONTAINER: MAY BURST IF HEATED.
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE DAMAGE.
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
MAY CAUSE RESPIRATORY IRRITATION.
SUSPECTED OF CAUSING CANCER.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
2.2. LABEL ELEMENTS:
HAZARDOUS COMPONENTS WHICH MUST BE LISTED ON THE LABEL:
DIPHENYLMETHANEDIISOCYANATE, ISOMERS AND HOMOLOGUES
NONYLPHENOLPOLYGLYKOLETHER
SIGNAL WORD: DANGER
PICTOGRAMS: GHS02-GHS05-GHS07-GHS08
FLAME
CORROSION
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
H222: EXTREMELY FLAMMABLE AEROSOL.
H229:
PRESSURISED CONTAINER: MAY BURST IF HEATED.
H315: CAUSES SKIN IRRITATION.
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H318: CAUSES SERIOUS EYE DAMAGE.
H334:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
H335: MAY CAUSE RESPIRATORY IRRITATION.
H351: SUSPECTED OF CAUSING CANCER.
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENTS:
P102: KEEP OUT OF REACH OF CHILDREN.
P210:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING.
P211: DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
P251: DO NOT PIERCE OR BURN, EVEN AFTER USE.
P260: DO NOT BREATHE DUST/FUME/GAS/MIST/VAPOURS/SPRAY.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P304+P340:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P410+P412:
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C/122 DEG. F.
SPECIAL LABELLING OF CERTAIN MIXTURES:
EUH204: CONTAINS ISOCYANATES. MAY PRODUCE AN ALLERGIC REACTION.
ADDITIONAL ADVICE ON LABELLING:
CONTAINS THE FOLLOWING FLUORINATED GREENHOUSE GAS RECORDED IN THE KYOTO
PROTOCOL (CHEMICAL NAME):
R134A; TOTAL QUANTITY: (PLEASE REFER TO THE MANUFACTURER)
2.3. OTHER HAZARDS:
IN CASE OF INSUFFICIENT VENTILATION AND/OR THROUGH USE, EXPLOSIVE/HIGHLY
FLAMMABLE MIXTURES MAY DEVELOP.
PERSONS ALREADY SENSITISED TO DIISOCYANATES MAY DEVELOP ALLERGIC REACTIONS
WHEN USING THIS PRODUCT. PERSONS SUFFERING FROM ASTHMA, ECZEMA OR SKIN
PROBLEMS SHOULD AVOID CONTACT, INCLUDING DERMAL CONTACT, WITH THIS
PRODUCT. THIS PRODUCT SHOULD NOT BE USED UNDER CONDITIONS OF POOR
VENTILATION UNLESS A PROTECTIVE MASK WITH AN APPROPRIATE GAS FILTER
(I.E. TYPE A1 ACCORDING TO STANDARD EN 14387) IS USED.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.2. MIXTURES:
HAZARDOUS COMPONENTS:
EC NO CHEMICAL NAME QUANTITY
CAS NO CLASSIFICATION
INDEX NO GHS CLASSIFICATION
REACH NO
DIPHENYLMETHANEDIISOCYANATE, 5 - <20%
ISOMERS AND HOMOLOGUES
9016-87-9 CARC. CAT. 3, XN - HARMFUL,
XI - IRRITANT
R20-36/37/38-40-42/43-48/20
615-005-01-6 CARC. 2, ACUTE TOX. 4, SKIN IRRIT. 2,
EYE IRRIT. 2, RESP. SENS. 1, SKIN
SENS. 1, STOT SE 3, STOT RE 2;
H351 H332 H315 H319 H334 H317 H335 H373
212-377-0 1,1,1,2-TETRAFLUOROETHANE 10 - <25%
811-97-2
LIQUEFIED GAS; H280
01-2119459374-33
237-158-7 TRIS (2-CHLOROISOPROPYL) PHOSPHATE 10 - <25%
13674-84-5 XN - HARMFUL R22
ACUTE TOX. 4; H302
01-2119486772-26
204-065-8 DIMETHYL ETHER 2.5 - <10%
115-10-6 F+ - EXTREMELY FLAMMABLE R12
603-019-00-8 FLAM. GAS 1; H220
01-2119472128-37
500-024-6 NONYLPHENOLPOLYGLYKOLETHER 2.5 - <10%
9016-45-9 XN - HARMFUL, XI - IRRITANT,
N - DANGEROUS FOR THE ENVIRONMENT
R22-41-51-53
ACUTE TOX. 4, EYE DAM. 1, AQUATIC
CHRONIC 2; H302 H318 H411
203-473-3 ETHANEDIOL, ETHYLENE GLYCOL 0.1 - <1%
107-21-1 XN - HARMFUL R22
603-027-00-1 ACUTE TOX. 4; H302
FULL TEXT OF R-, H- AND EUH-PHRASES: SEE SECTION 16.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
GENERAL INFORMATION:
MOVE VICTIM OUT OF DANGER ZONE. IN CASE OF ACCIDENT OR UNWELLNESS, SEEK
MEDICAL ADVICE IMMEDIATELY (SHOW DIRECTIONS FOR USE OR SAFETY DATA SHEET
IF POSSIBLE).
AFTER INHALATION:
PROVIDE FRESH AIR. IN CASE OF IRREGULAR BREATHING OR RESPIRATORY ARREST
PROVIDE ARTIFICIAL RESPIRATION.
AFTER CONTACT WITH SKIN:
AFTER CONTACT WITH SKIN, WASH IMMEDIATELY WITH PLENTY OF WATER AND SOAP.
IN CASE OF SKIN IRRITATION, SEEK MEDICAL TREATMENT.
AFTER CONTACT WITH EYES:
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF FLOWING
WATER FOR 10 TO 15 MINUTES HOLDING EYELIDS APART. SUBSEQUENTLY CONSULT AN
OPHTHALMOLOGIST.
AFTER INGESTION: DO NOT INDUCE VOMITING. CALL A PHYSICIAN IMMEDIATELY.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
ALLERGIC REACTIONS. MAY CAUSE SENSITIZATION BY INHALATION AND SKIN CONTACT.
DANGER OF STICKING EYES AND SKIN DUE TO CURING FOAM.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: FIRST AID, DECONTAMINATION, TREATMENT OF SYMPTOMS.
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
CARBON DIOXIDE (CO2), FOAM, EXTINGUISHING POWDER
UNSUITABLE EXTINGUISHING MEDIA: HIGH POWER WATER JET.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
IN CASE OF FIRE MAY BE LIBERATED:
CARBON MONOXIDE. CARBON DIOXIDE (CO2). NITROGEN OXIDES (NOX). HYDROGEN
CHLORIDE (HCL). HYDROCYANIC ACID (HYDROCYANIC ACID). FLUORHYDRIC ACID.
VAPOURS MAY FORM EXPLOSIVE MIXTURES WITH AIR.
5.3. ADVICE FOR FIREFIGHTERS:
IN CASE OF FIRE AND/OR EXPLOSION DO NOT BREATHE FUMES. WEAR A
SELF-CONTAINED BREATHING APPARATUS AND CHEMICAL PROTECTIVE CLOTHING.
ADDITIONAL INFORMATION:
USE WATER SPRAY JET TO PROTECT PERSONNEL AND TO COOL ENDANGERED CONTAINERS.
COLLECT CONTAMINATED FIRE EXTINGUISHING WATER SEPARATELY. DO NOT ALLOW
ENTERING DRAINS OR SURFACE WATER.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PROVIDE ADEQUATE VENTILATION. REMOVE ALL SOURCES OF IGNITION.
AVOID CONTACT WITH SKIN, EYES AND CLOTHES. DO NOT BREATHE VAPOUR/AEROSOL.
6.2. ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW TO ENTER INTO SURFACE WATER OR DRAINS. DO NOT ALLOW TO ENTER
INTO SOIL/SUBSOIL.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
PROVIDE ADEQUATE VENTILATION. ALLOW STIFFENING. TAKE UP MECHANICALLY.
6.4. REFERENCE TO OTHER SECTIONS:
TREAT THE RECOVERED MATERIAL AS PRESCRIBED IN THE SECTION ON WASTE
DISPOSAL.
HANDLING, PERSONAL PROTECTION EQUIPMENT:
SEE PROTECTIVE MEASURES UNDER POINT 7 AND 8.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
ADVICE ON SAFE HANDLING:
PROVIDE ADEQUATE VENTILATION AS WELL AS LOCAL EXHAUSTION AT CRITICAL
LOCATIONS. DO NOT USE IN ENCLOSED ROOMS.
ADVICE ON PROTECTION AGAINST FIRE AND EXPLOSION:
PRESSURIZED CONTAINER:
PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C. DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT SPRAY ON A NAKED
FLAME OR ANY INCANDESCENT MATERIAL. KEEP AWAY FROM SOURCES OF IGNITION -
NO SMOKING. KEEP OUT OF THE REACH OF CHILDREN.
VAPOURS CAN FORM EXPLOSIVE MIXTURES WITH AIR. TAKE PRECAUTIONARY MEASURES
AGAINST STATIC DISCHARGE.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
REQUIREMENTS FOR STORAGE ROOMS AND VESSELS:
KEEP IN A COOL, WELL-VENTILATED PLACE.
ADVICE ON STORAGE COMPATIBILITY:
DO NOT STORE TOGETHER WITH: OXIDISING AGENT
FURTHER INFORMATION ON STORAGE CONDITIONS:
PROTECT FROM SUNLIGHT. DO NO EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C/122 DEG. F.
RECOMMENDED STORAGE TEMPERATURE:
15 - 23 DEG. C. STORAGE ABOVE 23 DEG. C WILL REDUCE SHELF LIFE
SIGNIFICANTLY, DEPENDING ON TEMPERATURE AND DURATION.
7.3. SPECIFIC END USE(S): NOT APPLICABLE
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
EXPOSURE LIMITS (EH40):
CAS NO SUBSTANCE PPM MG/M3 FIBRES/ML CATEGORY ORIGIN
811-97-2 1,1,1,2- 1000 4240 TWA (8 H) WEL
TETRAFLUOROETHANE
(HFC 134A) STEL WEL
(15 MIN)
9016-87-9 DIPHENYLMETHANED- 0,05 TWA (8 H) AGW
IISOCYANATE,
ISOMERS AND STEL AGW
HOMOLOGUES (15 MIN)
115-10-6 DIMETHYL ETHER 400 766 TWA (8 H) WEL
500 958 STEL WEL
(15 MIN)
107-21-1 ETHANE-1,2-DIOL, 20 52 TWA (8 H) WEL
VAPOUR
40 104 STEL WEL
(15 MIN)
8.2. EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
PERSONAL PROTECTIVE EQUIPMENT HAS TO BE CHOSEN IN ACCORDANCE WITH WORKPLACE
SPECIFIC CONDITIONS, E.G. CONCENTRATION OF THE PRODUCT. CHEMICAL
RESISTANCE HAS TO BE CLARIFIED WITH THE SUPPLIER OF PROTECTIVE EQUIPMENT.
PROTECTIVE AND HYGIENE MEASURES:
WASH HANDS BEFORE BREAKS AND AFTER WORK. WHEN USING DO NOT EAT, DRINK,
SMOKE, SNIFF. REMOVE CONTAMINATED, SATURATED CLOTHING IMMEDIATELY.
EYE/FACE PROTECTION: WEAR EYE/FACE PROTECTION.
HAND PROTECTION:
SUITABLE MATERIAL: BUTYL RUBBER.
THE QUALITY OF THE PROTECTIVE GLOVES RESISTANT TO CHEMICALS MUST BE CHOSEN
AS A FUNCTION OF THE SPECIFIC WORKING PLACE CONCENTRATION AND QUANTITY OF
HAZARDOUS SUBSTANCES.
SKIN PROTECTION: WEAR ANTI-STATIC FOOTWEAR AND CLOTHING
RESPIRATORY PROTECTION:
RESPIRATORY PROTECTION NECESSARY AT: INSUFFICIENT VENTILATION.
SUITABLE RESPIRATORY PROTECTIVE EQUIPMENT:
GAS FILTERING EQUIPMENT (EN 141).
ENVIRONMENTAL EXPOSURE CONTROLS:
REFER TO CHAPTER 7. NO FURTHER ACTION IS NECESSARY.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: AEROSOL
COLOUR: LIGHT BLUE
ODOUR: CHARACTERISTIC
TEST METHOD
PH-VALUE: NOT APPLICABLE
CHANGES IN THE PHYSICAL STATE:
MELTING POINT: NOT APPLICABLE
INITIAL BOILING POINT AND BOILING RANGE: NOT APPLICABLE
FLASH POINT: NOT APPLICABLE
EXPLOSIVE PROPERTIES:
IN USE, MAY FORM FLAMMABLE/EXPLOSIVE VAPOUR-AIR MIXTURE.
LOWER EXPLOSION LIMITS: 3,2 VOL. %
UPPER EXPLOSION LIMITS: 26,2 VOL. %
IGNITION TEMPERATURE: >230 DEG. C
VAPOUR PRESSURE: 5500 - 6000 HPA
DENSITY: NOT DETERMINED
WATER SOLUBILITY: PRACTICALLY INSOLUBLE
PARTITION COEFFICIENT: NOT DETERMINED
VISCOSITY / DYNAMIC: NOT APPLICABLE
VISCOSITY / KINEMATIC: NOT APPLICABLE
VAPOUR DENSITY: NOT DETERMINED
EVAPORATION RATE: NOT DETERMINED
9.2. OTHER INFORMATION: NONE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
10.2. CHEMICAL STABILITY:
THE PRODUCT IS STABLE UNDER STORAGE AT NORMAL AMBIENT TEMPERATURES.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
EXOTHERMIC REACTIONS WITH: OXIDIZING AGENTS, STRONG.
IN USE, MAY FORM FLAMMABLE/EXPLOSIVE VAPOUR-AIR MIXTURE.
10.4. CONDITIONS TO AVOID:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
DO NOT EXPOSE TO TEMPERATURES ABOVE 50 DEG. C. HEATING CAUSES RISE IN
PRESSURE WITH RISK OF BURSTING.
10.5. INCOMPATIBLE MATERIALS:
EXOTHERMIC REACTIONS WITH: OXIDIZING AGENTS, STRONG.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON MONOXIDE. CARBON DIOXIDE. NITROGEN OXIDES (NOX). HYDROGEN CHLORIDE
(HCL). HYDROCYANIC ACID (HYDROCYANIC ACID). FLUORHYDRIC ACID.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
TOXICOCINETICS, METABOLISM AND DISTRIBUTION:
THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
ACUTE TOXICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
ACUTE TOXICITY:
CAS NO CHEMICAL NAME
EXPOSURE ROUTES METHOD DOSE SPECIES SOURCE
9016-87-9 DIPHENYLMETHANEDIISOCYANATE, ISOMERS AND HOMOLOGUES
ORAL LD50 >10000 MG/KG RAT
DERMAL LD50 >10000 MG/KG RABBIT
INHALATIVE VAPOUR ATE 11 MG/L
INHALATIVE AEROSOL ATE 1,5 MG/L
811-97-2 1,1,1,2-TETRAFLUOROETHANE
INHALATIVE (4 H) LC50 500000 MG/L RAT
VAPOUR
13674-84-5 TRIS(2-CHLOROISOPROPYL)PHOSPHATE
ORAL LD50 630 - 2000 RAT
MG/KG
DERMAL LD50 >5000 MG/KG RABBIT
INHALATIVE (4 H) LC50 >7 MG/L RAT
VAPOUR
115-10-6 DIMETHYL ETHER
INHALATIVE (4 H) GAS LC50 309 PPM RAT
9016-45-9 NONYLPHENOLPOLYGLYKOLETHER
ORAL LD50 500 - 2000 RAT
MG/KG
107-21-1 ETHANEDIOL, ETHYLENE GLYCOL
ORAL ATE 500 MG/KG
DERMAL LD50 10600 MG/KG RABBIT GESTIS
IRRITATION AND CORROSIVITY:
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE DAMAGE.
SENSITISING EFFECTS:
MAY CAUSE AN ALLERGIC SKIN REACTION. (DIPHENYLMETHANEDIISOCYANATE, ISOMERS
AND HOMOLOGUES)
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
(DIPHENYLMETHANEDIISOCYANATE, ISOMERS AND HOMOLOGUES)
DO NOT APPLY TO THE CURED FOAM.
STOT-SINGLE EXPOSURE:
MAY CAUSE RESPIRATORY IRRITATION. (DIPHENYLMETHANEDIISOCYANATE, ISOMERS AND
HOMOLOGUES)
SEVERE EFFECTS AFTER REPEATED OR PROLONGED EXPOSURE:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
(DIPHENYLMETHANEDIISOCYANATE, ISOMERS AND HOMOLOGUES)
CARCINOGENIC/MUTAGENIC/TOXIC EFFECTS FOR REPRODUCTION:
SUSPECTED OF CAUSING CANCER. (DIPHENYLMETHANEDIISOCYANATE, ISOMERS AND
HOMOLOGUES)
ASPIRATION HAZARD:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
CAS NO CHEMICAL NAME
AQUATIC METHOD DOSE [H] SPECIES SOURCE
TOXICITY [D]
9016-87-9 DIPHENYLMETHANEDIISOCYANATE, ISOMERS AND HOMOLOGUES
ACUTE FISH LC50 >1000 96 H BRACHYDANIO
TOXICITY MG/L RERIO
(ZEBRA-FISH)
13674-84-5 TRIS (2-CHLOROISOPROPYL)PHOSPHATE
ACUTE FISH LC50 56,2 96 H
TOXICITY MG/L
ACUTE ALGAE ERC50 82 72 H
TOXICITY MG/L
ACUTE EC50 131 48 H DAPHNIA MAGNA
CRUSTACEA MG/L
TOXICITY
115-10-6 DIMETHYL ETHER
ACUTE FISH LC50 >4,1 96 H POECILIA
TOXICITY MG/L RETICULATA
(GUPPY)
ACUTE ALGAE ERC50 154,9 96 H
TOXICITY MG/L
ACUTE EC50 >4,4 48 H DAPHNIA MAGNA
CRUSTACEA MG/L (BIG WATER
TOXICITY FLEA)
9016-45-9 NONYLPHENOLPOLYGLYKOLETHER
ACUTE FISH LC50 10 - 100 96 H BRACHYDANIO
TOXICITY MG/L RERIO
(ZEBRA-FISH)
ACUTE ALGAE ERC50 >1000 BACTERIAL
TOXICITY MG/L TOXICITY:
12.2. PERSISTENCE AND DEGRADABILITY:
THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
CAS NO CHEMICAL NAME
METHOD VALUE D SOURCE
EVALUATION
9016-87-9 DIPHENYLMETHANEDIISOCYANATE, ISOMERS AND HOMOLOGUES
OECD 302C <10% 28
POORLY BIODEGRADABLE.
12.3. BIOACCUMULATIVE POTENTIAL:
THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
PARTITION COEFFICIENT N-OCTANOL/WATER:
CAS NO CHEMICAL NAME LOG POW
13674-84-5 TRIS (2-CHLOROISOPROPYL) PHOSPHATE -2,68
115-10-6 DIMETHYL ETHER 0,1
9016-45-9 NONYLPHENOLPOLYGLYKOLETHER 3,16
107-21-1 ETHANEDIOL, ETHYLENE GLYCOL -1,36
12.4. MOBILITY IN SOIL:
THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
12.5. RESULTS OF PBT AND VPVB ASSESSMENT:
THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
12.6. OTHER ADVERSE EFFECTS
OZONE DEPLETION POTENTIAL (ODP): 0 (R134A)
GLOBAL WARMING POTENTIAL (GWP): 1300 (R134A)
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
ADVICE ON DISPOSAL: DISPOSE OF WASTE ACCORDING TO APPLICABLE LEGISLATION.
WASTE DISPOSAL NUMBER OF WASTE FROM RESIDUES/UNUSED PRODUCTS:
160504:
WASTES NOT OTHERWISE SPECIFIED IN THE LIST; GASES IN PRESSURE CONTAINERS
AND DISCARDED CHEMICALS; GASES IN PRESSURE CONTAINERS (INCLUDING HALONS)
CONTAINING DANGEROUS SUBSTANCES CLASSIFIED AS HAZARDOUS WASTE.
WASTE DISPOSAL NUMBER OF USED PRODUCT:
170203:
CONSTRUCTION AND DEMOLITION WASTES (INCLUDING EXCAVATED SOIL FROM
CONTAMINATED SITES); WOOD, GLASS AND PLASTIC; PLASTIC
WASTE DISPOSAL NUMBER OF CONTAMINATED PACKAGING:
080409:
WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS
(PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING
INKS; WASTES FROM MFSU OF ADHESIVES AND SEALANTS (INCLUDING WATERPROOFING
PRODUCTS); WASTE ADHESIVES AND SEALANTS CONTAINING ORGANIC SOLVENTS OR
OTHER DANGEROUS SUBSTANCES CLASSIFIED AS HAZARDOUS WASTE.
CONTAMINATED PACKAGING:
IN GERMANY:
TAKING BACK WITHOUT ADDITIONAL COSTS BY PU-DOSEN-RECYCLING GMBH & CO.
BETRIEBSKG (PDR), AM ALTEN SAGEWERK 3, D-95349 THURNAU.
ORDER AND PICKUP: PHONE 0800-7836736 OR FAX 0800-7836737.
| SECTION 14: TRANSPORT INFORMATION | |
LAND TRANSPORT (ADR/RID):
14.1. UN NUMBER: UN 1950
14.2. UN PROPER SHIPPING NAME: AEROSOLS
14.3. TRANSPORT HAZARD CLASS(ES): 2
14.4. PACKING GROUP:
HAZARD LABEL: 2.1
CLASS 2.1, FLAMMABLE GASES
CLASSIFICATION CODE: 5F
LIMITED QUANTITY: 1 L
TRANSPORT CATEGORY: 2
TUNNEL RESTRICTION CODE: D
OTHER APPLICABLE INFORMATION (LAND TRANSPORT):
TRANSPORT AS "LIMITED QUANTITY" ACCORDING TO CHAPTER 3.4 ADR/RID.
INLAND WATERWAYS TRANSPORT (ADN):
14.1. UN NUMBER: UN 1950
14.2. UN PROPER SHIPPING NAME: AEROSOLS
14.3. TRANSPORT HAZARD CLASS(ES): 2
14.4. PACKING GROUP:
HAZARD LABEL: 2.1
CLASS 2.1, FLAMMABLE GASES
CLASSIFICATION CODE: 5F
LIMITED QUANTITY: 1 L
MARINE TRANSPORT (IMDG):
14.1. UN NUMBER: UN 1950
14.2. UN PROPER SHIPPING NAME: AEROSOLS
14.3. TRANSPORT HAZARD CLASS(ES): 2.1
14.4. PACKING GROUP:
HAZARD LABEL: 2.1
CLASS 2.1 - FLAMMABLE GASES
MARINE POLLUTANT:
LIMITED QUANTITY: 1000 ML
EMS: F-D, S-U
AIR TRANSPORT (ICAO):
14.1. UN NUMBER: UN 1950
14.2. UN PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE
14.3. TRANSPORT HAZARD CLASS(ES): 2.1
14.4. PACKING GROUP:
HAZARD LABEL: 2.1
CLASS 2.1, FLAMMABLE GASES
LIMITED QUANTITY PASSENGER: 30 KG G
14.5. ENVIRONMENTAL HAZARDS:
ENVIRONMENTALLY HAZARDOUS: NO
14.6. SPECIAL PRECAUTIONS FOR USER: SEE CHAPTER 6 - 8
14.7. TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC
CODE: NOT RELEVANT
| SECTION 15: REGULATORY INFORMATION | |
15.1. SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR
THE SUBSTANCE OR MIXTURE:
EU REGULATORY INFORMATION:
1999/13/EC (VOC): (PLEASE REFER TO THE MANUFACTURER)
NATIONAL REGULATORY INFORMATION:
EMPLOYMENT RESTRICTIONS:
OBSERVE EMPLOYMENT RESTRICTIONS FOR YOUNG PEOPLE. OBSERVE EMPLOYMENT
RESTRICTIONS FOR CHILD BEARING MOTHERS AND NURSING.
SKIN RESORPTION/SENSITIZATION: CAUSES ALLERGIC HYPERSENSITIVITY REACTIONS.
15.2. CHEMICAL SAFETY ASSESSMENT:
CHEMICAL SAFETY ASSESSMENTS FOR SUBSTANCES IN THIS MIXTURE WERE NOT CARRIED
OUT.
| SECTION 16: OTHER INFORMATION | |
CHANGES:
SECTION: 2, 11, 12, 13
RELEVANT R-PHRASES (NUMBER AND FULL TEXT):
12: EXTREMELY FLAMMABLE.
20: HARMFUL BY INHALATION.
22: HARMFUL IF SWALLOWED.
36/37/38: IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
40: LIMITED EVIDENCE OF A CARCINOGENIC EFFECT.
41: RISK OF SERIOUS DAMAGE TO EYES.
42/43: MAY CAUSE SENSITISATION BY INHALATION AND SKIN CONTACT.
48/20:
HARMFUL:
DANGER OF SERIOUS DAMAGE TO HEALTH BY PROLONGED EXPOSURE THROUGH
INHALATION.
51: TOXIC TO AQUATIC ORGANISMS.
53: MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE AQUATIC ENVIRONMENT.
RELEVANT H- AND EUH-PHRASES (NUMBER AND FULL TEXT):
H220: EXTREMELY FLAMMABLE GAS.
H222: EXTREMELY FLAMMABLE AEROSOL.
H229:
PRESSURISED CONTAINER: MAY BURST IF HEATED.
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
H302: HARMFUL IF SWALLOWED.
H315: CAUSES SKIN IRRITATION.
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H318: CAUSES SERIOUS EYE DAMAGE.
H319: CAUSES SERIOUS EYE IRRITATION.
H332: HARMFUL IF INHALED.
H334:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
H335: MAY CAUSE RESPIRATORY IRRITATION.
H351: SUSPECTED OF CAUSING CANCER.
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
H411: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
EUH204: CONTAINS ISOCYANATES. MAY PRODUCE AN ALLERGIC REACTION.
FURTHER INFORMATION:
DATA SOURCES: DATA ARISE FROM REFERENCE WORKS AND LITERATURE.
THE ABOVE INFORMATION DESCRIBES EXCLUSIVELY THE SAFETY REQUIREMENTS OF
THE PRODUCT AND IS BASED ON OUR PRESENT-DAY KNOWLEDGE. THE INFORMATION IS
INTENDED TO GIVE YOU ADVICE ABOUT THE SAFE HANDLING OF THE PRODUCT NAMED
IN THIS SAFETY DATA SHEET, FOR STORAGE, PROCESSING, TRANSPORT AND DISPOSAL.
THE INFORMATION CANNOT BE TRANSFERRED TO OTHER PRODUCTS. IN THE CASE OF
MIXING THE PRODUCT WITH OTHER PRODUCTS OR IN THE CASE OF PROCESSING, THE
INFORMATION ON THIS SAFETY DATA SHEET IS NOT NECESSARILY VALID FOR THE NEW
MADE-UP MATERIAL.
(THE DATA FOR THE HAZARDOUS INGREDIENTS WERE TAKEN RESPECTIVELY FROM THE
LAST VERSION OF THE SUB-CONTRACTOR'S SAFETY DATA SHEET.)
REVISION NO: 7.01
GB - EN
REVISION DATE: 26.08.2014