| Common Name: | PHOSPHATE FREE TSP |
| Manufacturer: | SUNNYSIDE |
| SDS Revision Date: | 7/7/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 44ZU10, 44ZU12 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
PRODUCT NUMBER: 641
ISSUING DATE: 07/07/15
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT NAME: PHOSPHATE FREE TSP
OTHER MEANS OF IDENTIFICATION:
PRODUCT CODE(S): 641
SYNONYMS: TRISODIUM HYDROGENDICARBONATE
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE:
INDUSTRIAL CLEANER INGREDIENT, BATH SALT INGREDIENT, WATER SOFTENER, DIAPER
RINSE INGREDIENT, PH ADJUSTMENT, WATER TREATMENT, FOOD ADDITIVE, FOOD AND
DAIRY PLANT SANITIZERS
RESTRICTIONS ON USE: SEE SECTION 16 FOR MORE INFORMATION
MANUFACTURER ADDRESS:
SUNNYSIDE CORPORATION
225 CARPENTER AVENUE
WHEELING, IL 60090
800-323-8611
SSCONTACT@SUNNYSIDECORP.COM
EMERGENCY TELEPHONE NUMBER:
FOR LEAK, FIRE, SPILL OR ACCIDENT EMERGENCIES, CALL:
1 800 / 424 9300 (CHEMTREC - U.S.A.)
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
OSHA REGULATORY STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200)
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2
GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
EMERGENCY OVERVIEW:
WARNING
HAZARD STATEMENTS:
H319: CAUSES SERIOUS EYE IRRITATION
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS - PREVENTION:
P264: WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
P280: WEAR EYE PROTECTION/ FACE PROTECTION
PRECAUTIONARY STATEMENTS - RESPONSE:
P305 + P351 + P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
P337 + P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC):
NO HAZARDS NOT OTHERWISE CLASSIFIED WERE IDENTIFIED.
OTHER INFORMATION: MAY BE HARMFUL IF SWALLOWED.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
FORMULA: NaHCO3.Na2CO3
CHEMICAL NAME CAS-NO WEIGHT %
SODIUM SESQUICARBONATE 533-96-0 100
SYNONYMS ARE PROVIDED IN SECTION 1.
| 4. FIRST AID MEASURES | |
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
SKIN CONTACT:
WASH SKIN WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS
AND PERSISTS.
INHALATION:
REMOVE PERSON TO FRESH AIR. IF SIGNS/SYMPTOMS CONTINUE, GET MEDICAL
ATTENTION.
INGESTION:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL
ATTENTION IF SYMPTOMS OCCUR.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED: NONE KNOWN.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF
NECESSARY: TREAT SYMPTOMATICALLY.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL: NONE IN PARTICULAR
HAZARDOUS COMBUSTION PRODUCTS: FUMES OF SODIUM OXIDE.
EXPLOSION DATA:
SENSITIVITY TO MECHANICAL IMPACT: NOT SENSITIVE.
SENSITIVITY TO STATIC DISCHARGE: NOT SENSITIVE.
PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
SWEEP UP TO PREVENT SLIPPING HAZARD. FOR PERSONAL PROTECTION SEE SECTION 8.
OTHER:
FOR FURTHER CLEAN-UP INSTRUCTIONS, CALL EMERGENCY HOTLINE NUMBER LISTED IN
SECTION 1 "PRODUCT AND COMPANY IDENTIFICATION" ABOVE.
ENVIRONMENTAL PRECAUTIONS:
KEEP MATERIAL OUT OF LAKES, STREAMS, PONDS, AND SEWER DRAINS. SEE SECTION
12 FOR ADDITIONAL ECOLOGICAL INFORMATION.
METHODS FOR CONTAINMENT:
VACUUM OR SHOVEL WASTE INTO A DRUM AND LABEL CONTENTS FOR DISPOSAL. AVOID
DUST FORMATION.
METHODS FOR CLEANING UP:
PICK UP AND TRANSFER TO PROPERLY LABELED CONTAINERS. KEEP IN SUITABLE AND
CLOSED CONTAINERS FOR DISPOSAL. DISPOSE OF WASTE AS INDICATED IN SECTION
13.
| 7. HANDLING AND STORAGE | |
HANDLING:
KEEP AWAY FROM INCOMPATIBLE PRODUCTS (ACIDS). PROVIDE APPROPRIATE EXHAUST
VENTILATION AT PLACES WHERE DUST IS FORMED. REFERENCE TO OTHER SECTIONS.
STORAGE:
KEEP IN A DRY, COOL AND WELL-VENTILATED PLACE. KEEP AWAY FROM HEAT AND
STRONG ODOR. KEEP AWAY FROM INCOMPATIBLE PRODUCTS (ACIDS).
INCOMPATIBLE PRODUCTS:
EXCEPT UNDER CONTROLLED CONDITIONS: ACIDS
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
THIS PRODUCT, AS SUPPLIED, DOES NOT CONTAIN ANY HAZARDOUS MATERIALS WITH
OCCUPATIONAL EXPOSURE LIMITS ESTABLISHED BY THE REGION SPECIFIC REGULATORY
BODIES LOCAL NUISANCE DUST STANDARDS APPLY
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING MEASURES:
WHERE REASONABLY PRACTICABLE THIS SHOULD BE ACHIEVED BY THE USE OF LOCAL
EXHAUST VENTILATION AND GOOD GENERAL EXTRACTION.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: SAFETY GLASSES WITH SIDE-SHIELDS.
SKIN AND BODY PROTECTION:
WEAR SUITABLE PROTECTIVE CLOTHING. PROTECTIVE SHOES OR BOOTS.
HAND PROTECTION: PROTECTIVE GLOVES
RESPIRATORY PROTECTION:
IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
HYGIENE MEASURES:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
GENERAL INFORMATION:
IF THE PRODUCT IS USED IN MIXTURES, IT IS RECOMMENDED THAT YOU CONTACT THE
APPROPRIATE PROTECTIVE EQUIPMENT SUPPLIERS.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE: WHITE, ODORLESS, NEEDLE-SHAPED PARTICLES
PHYSICAL STATE: SOLID
COLOR: WHITE TO OFF WHITE
ODOR: ODORLESS
ODOR THRESHOLD: NOT APPLICABLE
PH: 9.9 (1% SOLUTION)
MELTING POINT/FREEZING POINT: DECOMPOSES ON HEATING
BOILING POINT/RANGE: NO INFORMATION AVAILABLE
FLASH POINT: NOT APPLICABLE
EVAPORATION RATE: NO INFORMATION AVAILABLE
FLAMMABILITY (SOLID, GAS): NO INFORMATION AVAILABLE
FLAMMABILITY LIMIT IN AIR:
UPPER FLAMMABILITY LIMIT: NO INFORMATION AVAILABLE
LOWER FLAMMABILITY LIMIT: NO INFORMATION AVAILABLE
VAPOR PRESSURE: NO INFORMATION AVAILABLE
VAPOR DENSITY: NO INFORMATION AVAILABLE
DENSITY: NO INFORMATION AVAILABLE
SPECIFIC GRAVITY: 2.12
WATER SOLUBILITY: 17.1% @ 25 DEG. C
SOLUBILITY IN OTHER SOLVENTS: NO INFORMATION AVAILABLE
PARTITION COEFFICIENT: NO INFORMATION AVAILABLE
AUTOIGNITION TEMPERATURE: NO INFORMATION AVAILABLE
DECOMPOSITION TEMPERATURE: DECOMPOSES ON HEATING
VISCOSITY, KINEMATIC: NO INFORMATION AVAILABLE
VISCOSITY, DYNAMIC: NO INFORMATION AVAILABLE
EXPLOSIVE PROPERTIES: NO INFORMATION AVAILABLE
OXIDIZING PROPERTIES: NON-OXIDIZING
MOLECULAR WEIGHT: NO INFORMATION AVAILABLE
BULK DENSITY: 0.74 G/CM3
KST: 0 BAR M/S
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NONE UNDER NORMAL USE CONDITIONS.
CHEMICAL STABILITY: STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
HAZARDOUS POLYMERIZATION: HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
CONDITIONS TO AVOID:
AVOID CONTACT WITH ACIDS, HEAT, HUMID AIR, STRONG ODOR.
INCOMPATIBLE MATERIALS:
EXCEPT UNDER CONTROLLED CONDITIONS: ACIDS.
HAZARDOUS DECOMPOSITION PRODUCTS: CARBON DIOXIDE (CO2), SODIUM OXIDES.
| 11. TOXICOLOGICAL INFORMATION | |
PRODUCT INFORMATION:
LD50 ORAL: >2000 MG/KG (RAT)
LD50 DERMAL: NO INFORMATION AVAILABLE
LC50 INHALATION: >5.03 MG/L 4 HR (RAT)
EYE CONTACT: IRRITATING TO EYES.
SKIN CONTACT: NON-IRRITATING (RABBIT)
SENSITIZATION: NON-SENSITIZING.
INFORMATION ON TOXICOLOGICAL EFFECTS:
SYMPTOMS: NO INFORMATION AVAILABLE.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
CHRONIC TOXICITY: NO KNOWN EFFECT.
MUTAGENICITY: NOT MUTAGENIC
CARCINOGENICITY:
NOT RECOGNIZED AS CARCINOGENIC BY RESEARCH AGENCIES (IARC, NTP, OSHA,
ACGIH).
REPRODUCTIVE TOXICITY: NO INFORMATION AVAILABLE.
STOT - SINGLE EXPOSURE: NO INFORMATION AVAILABLE.
STOT - REPEATED EXPOSURE: NO INFORMATION AVAILABLE.
ASPIRATION HAZARD: NO INFORMATION AVAILABLE.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
PERSISTENCE AND DEGRADABILITY:
BIODEGRADABILITY DOES NOT PERTAIN TO INORGANIC SUBSTANCES.
BIOACCUMULATION: DOES NOT BIOACCUMULATE.
MOBILITY: DISSOCIATES INTO IONS.
OTHER ADVERSE EFFECTS: NONE KNOWN.
| 13. DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL METHODS:
THIS MATERIAL, AS SUPPLIED, IS NOT A HAZARDOUS WASTE ACCORDING TO STATE AND
FEDERAL REGULATIONS (40 CFR 261). DISPOSE OF IN ACCORDANCE WITH LOCAL
REGULATIONS.
CONTAMINATED PACKAGING: DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS.
| 14. TRANSPORT INFORMATION | |
DOT: NOT REGULATED
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
SARA 313:
SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT OF 1986 (SARA). THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS WHICH ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF THE ACT AND TITLE 40 OF THE CODE
OF FEDERAL REGULATIONS, PART 372
SARA 311/312 HAZARD CATEGORIES:
ACUTE HEALTH HAZARD: YES
CHRONIC HEALTH HAZARD: NO
FIRE HAZARD: NO
REACTIVE HAZARD: NO
SUDDEN RELEASE OF PRESSURE HAZARD: NO
CLEAN WATER ACT:
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS POLLUTANTS
PURSUANT TO THE CLEAN WATER ACT (40 CFR 122.21 AND 40 CFR 122.42)
CERCLA:
THIS MATERIAL, AS SUPPLIED, DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS
HAZARDOUS SUBSTANCES UNDER THE COMPREHENSIVE ENVIRONMENTAL RESPONSE
COMPENSATION AND LIABILITY ACT (CERCLA) (40 CFR 302) OR THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) (40 CFR 355). THERE MAY BE
SPECIFIC REPORTING REQUIREMENTS AT THE LOCAL, REGIONAL, OR STATE LEVEL
PERTAINING TO RELEASES OF THIS MATERIAL
US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT DOES NOT CONTAIN ANY PROPOSITION 65 CHEMICALS.
U.S. STATE RIGHT-TO-KNOW REGULATIONS:
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES REGULATED BY STATE
RIGHT-TO-KNOW REGULATIONS
INTERNATIONAL INVENTORIES:
COMPONENT TSCA DSL EINECS/ ENCS
(UNITED STATES) (CANADA) ELINCS (JAPAN)
(EUROPE)
SODIUM SESQUICARBONATE X X X X
533-96-0 (100)
COMPONENT CHINA KECL PICCS AICS
(IECSC) (KOREA) (PHILIPPINES) (AUSTRALIA)
SODIUM SESQUICARBONATE X X X X
533-96-0 (100)
WHMIS HAZARD CLASS: D2B - TOXIC MATERIALS, EYE IRRITATION
D2B-TOXIC
| 16. OTHER INFORMATION | |
NFPA:
HEALTH HAZARDS 2
FLAMMABILITY 0
INSTABILITY 0
SPECIAL HAZARDS
HMIS:
HEALTH HAZARDS 2
FLAMMABILITY 0
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA/HMIS RATINGS LEGEND:
SEVERE = 4
SERIOUS = 3
MODERATE = 2
SLIGHT = 1
MINIMAL = 0
PRODUCT CERTIFICATIONS:
THIS PRODUCT MEETS THE CHEMICAL TESTING SPECIFICATIONS DEFINED IN THE FOOD
CHEMICALS CODEX (FCC), 8TH EDITION.
THIS PRODUCT IS CERTIFIED TO NSF/ANSI STANDARD 60 FOR USE IN DRINKING WATER
TREATMENT AT THE SPECIFIED MAXIMUM USE LIMIT. THE MUL (MAXIMUM USE LEVEL)
FOR SODIUM SESQUICARBONATE IS 100 MG/L UNDER NSF/ANSI STANDARD 60.
U
OU KOSHER CERTIFICATION
NSF(R*)
CERTIFIED TO NSF/ANSI 60
(R*)
AMERICAN WATER WORKS ASSOCIATION
DISCLAIMER:
SUNNYSIDE BELIEVES THAT THE INFORMATION AND RECOMMENDATIONS CONTAINED
HEREIN (INCLUDING DATA AND STATEMENTS) ARE ACCURATE AS OF THE DATE HEREOF.
NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF
MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE
CONCERNING THE INFORMATION PROVIDED HEREIN. THE INFORMATION PROVIDED HEREIN
RELATES ONLY TO THE SPECIFIED PRODUCT DESIGNATED AND MAY NOT BE APPLICABLE
WHERE SUCH PRODUCT IS USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN
ANY PROCESS. FURTHER, SINCE THE CONDITIONS AND METHODS OF USE ARE BEYOND
THE CONTROL OF SUNNYSIDE CORPORATION, SUNNYSIDE CORPORATION EXPRESSLY
DISCLAIMS ANY AND ALL LIABILITY AS TO ANY RESULTS OBTAINED OR ARISING FROM
ANY USE OF THE PRODUCTS OR RELIANCE ON SUCH INFORMATION.