| Common Name: | SYNPOWER FULL SYNTHETIC SAE 0W-40 MOTOR OIL |
| Manufacturer: | VALVOLINE |
| SDS Revision Date: | 5/22/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 453A95 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
V(TM)
VALVOLINE(TM)
SAFETY DATA SHEET
SYNPOWER(TM) FULL SYNTHETIC SAE 0W-40 MOTOR OIL
852518
REVISION DATE: 05/22/2017
PRINT DATE: 9/6/2017
SDS NUMBER: R0517098
VERSION: 1.4
29 CFR 1910.1200 (OSHA HAZCOM 2012)
| SECTION 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT IDENTIFIER:
TRADE NAME: SYNPOWER(TM) FULL SYNTHETIC SAE 0W-40 MOTOR OIL
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
VALVOLINE LLC
100 VALVOLINE WAY
LEXINGTON, KY 40509
UNITED STATES OF AMERICA (USA)
1-800-TEAMVAL
EMERGENCY TELEPHONE NUMBER: 1-800-VALVOLINE (1-800-825-8654)
REGULATORY INFORMATION NUMBER: 1-800-TEAMVAL
PRODUCT INFORMATION: 1-800-TEAMVAL
| SECTION 2. HAZARDS IDENTIFICATION | |
GHS CLASSIFICATION:
EYE IRRITATION: CATEGORY 2A
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS: EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD STATEMENTS: CAUSES SERIOUS EYE IRRITATION.
PRECAUTIONARY STATEMENTS:
IF MEDICAL ADVICE IS NEEDED, HAVE PRODUCT CONTAINER OR LABEL AT HAND.
KEEP OUT OF REACH OF CHILDREN.
READ LABEL BEFORE USE.
PREVENTION:
WASH SKIN THOROUGHLY AFTER HANDLING.
WEAR EYE PROTECTION/FACE PROTECTION.
RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
OTHER HAZARDS: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE / MIXTURE: MIXTURE
CHEMICAL NATURE: ORGANIC
HAZARDOUS COMPONENTS:
CHEMICAL NAME CAS-NO. CLASSIFICATION CONCENTRATION (%)
DECENE-1 HOMOPOLYMER 68037-01-4 ASP. TOX. 1; H304 53.90
HYDROGENATED
LUBRICATING OILS 72623-87-1 ASP. TOX. 1; H304 5.0599
(PETROLEUM), C20-50,
HYDROTREATED NEUTRAL
OIL-BASED
ZINC BIS[O- 93819-94-4 SKIN IRRIT. 2; H315 1.3299
(6-METHYLHELPTYL)] EYE DAM. 1; H318
BIS[O-SEC-BUTYL)]BIS
(DITHIOPHOSPATE)
| SECTION 4. FIRST AID MEASURES | |
GENERAL ADVICE:
MOVE OUT OF DANGEROUS AREA.
SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE.
DO NOT LEAVE THE VICTIM UNATTENDED.
IF INHALED:
IF BREATHED IN, MOVE PERSON INTO FRESH AIR.
IF UNCONSCIOUS, PLACE IN RECOVERY POSITION AND SEEK MEDICAL ADVICE.
IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
IN CASE OF SKIN CONTACT:
FIRST AID IS NOT NORMALLY REQUIRED. HOWEVER, IT IS RECOMMENDED THAT
EXPOSED AREAS BE CLEANED BY WASHING WITH SOAP AND WATER.
IN CASE OF EYE CONTACT:
FLUSH EYES WITH WATER AS A PRECAUTION.
REMOVE CONTACT LENSES.
PROTECT UNHARMED EYE.
IF EYE IRRITATION PERSISTS, CONSULT A SPECIALIST.
IF SWALLOWED:
OBTAIN MEDICAL ATTENTION.
DO NOT GIVE MILK OR ALCOHOLIC BEVERAGES.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
ACUTE ASPIRATION OF LARGE AMOUNTS OF OIL-LADEN MATERIAL MAY PRODUCE A
SERIOUS ASPIRATION PNEUMONIA. PATIENTS WHO ASPIRATE THESE OILS SHOULD BE
FOLLOWED FOR THE DEVELOPMENT OF LONG-TERM SEQUELAE. REPEATED ASPIRATION
OF SMALL QUANTITIES OF MINERAL OIL CAN PRODUCE CHRONIC INFLAMMATION OF
THE LUNGS (I.E. LIPOID PNEUMONIA) THAT MAY PROGRESS TO PULMONARY FIBROSIS.
SYMPTOMS ARE OFTEN SUBTLE AND RADIOLOGICAL CHANGES APPEAR WORSE THAN
CLINICAL ABNORMALITIES. OCCASIONALLY, PERSISTENT COUGH, IRRITATION OF THE
UPPER RESPIRATORY TRACT, SHORTNESS OF BREATH WITH EXERTION, FEVER, AND
BLOODY SPUTUM OCCUR. INHALATION EXPOSURE TO OIL MISTS BELOW CURRENT
WORKPLACE EXPOSURE LIMITS IS UNLIKELY TO CAUSE PULMONARY ABNORMALITIES.
SIGNS AND SYMPTOMS OF EXPOSURE TO THIS MATERIAL THROUGH BREATHING,
SWALLOWING, AND/OR PASSAGE OF THE MATERIAL THROUGH THE SKIN MAY INCLUDE:
STOMACH OR INTESTINAL UPSET (NAUSEA, VOMITING, DIARRHEA)
IRRITATION (NOSE, THROAT, AIRWAYS)
CAUSES SERIOUS EYE IRRITATION.
NOTES TO PHYSICIAN: NO HAZARDS WHICH REQUIRE SPECIAL FIRST AID MEASURES.
| SECTION 5. FIREFIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES
AND THE SURROUNDING ENVIRONMENT.
WATER SPRAY
FOAM
CARBON DIOXIDE (CO2)
DRY CHEMICAL
UNSUITABLE EXTINGUISHING MEDIA: HIGH VOLUME WATER JET
SPECIFIC HAZARDS DURING FIREFIGHTING:
DO NOT ALLOW RUN-OFF FROM FIRE FIGHTING TO ENTER DRAINS OR WATER COURSES.
HAZARDOUS COMBUSTION PRODUCTS:
CARBON DIOXIDE AND CARBON MONOXIDE
NITROGEN OXIDES (NOX)
ZINC OXIDE
SULPHUR OXIDES
HYDROGEN SULFIDE
MERCAPTANS
SPECIFIC EXTINGUISHING METHODS:
PRODUCT IS COMPATIBLE WITH STANDARD FIRE-FIGHTING AGENTS.
FURTHER INFORMATION: STANDARD PROCEDURE FOR CHEMICAL FIRES.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
IN THE EVENT OF FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONS NOT WEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA
OF SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED.
ENVIRONMENTAL PRECAUTIONS:
PREVENT PRODUCT FROM ENTERING DRAINS.
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
IF THE PRODUCT CONTAMINATES RIVERS AND LAKES OR DRAINS INFORM RESPECTIVE
AUTHORITIES.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND, SILICA GEL, ACID BINDER,
UNIVERSAL BINDER, SAWDUST).
KEEP IN SUITABLE, CLOSED CONTAINERS FOR DISPOSAL.
OTHER INFORMATION:
COMPLY WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL REGULATIONS.
| SECTION 7. HANDLING AND STORAGE | |
ADVICE ON SAFE HANDLING:
DO NOT BREATHE VAPOURS/DUST.
DO NOT SMOKE.
CONTAINER HAZARDOUS WHEN EMPTY.
SMOKING, EATING AND DRINKING SHOULD BE PROHIBITED IN THE APPLICATION AREA.
FOR PERSONAL PROTECTION SEE SECTION 8.
DISPOSE OF RINSE WATER IN ACCORDANCE WITH LOCAL AND NATIONAL REGULATIONS.
CONDITIONS FOR SAFE STORAGE:
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
COMPONENTS WITH WORKPLACE CONTROL PARAMETERS:
COMPONENTS CAS-NO. VALUE TYPE CONTROL BASIS
(FORM OF PARAMETERS /
EXPOSURE) PERMISSIBLE
CONCENTRATION
LUBRICATING OILS 72623-87-1 REL 5 MG/M3 NIOSH/GUIDE
(PETROLEUM), MIST.
C20-50,
HYDROTREATED STEL 10 MG/M3 NIOSH/GUIDE
NEUTRAL OIL-BASED MIST.
NIOSH/GUIDE
PEL 5 MG/M3 OSHA_TRANS
MIST.
OSHA_TRANS
TWA 5 MG/M3 ACGIH
MIST.
STEL 10 MG/M3 ACGIH
MIST.
ACGIH
TWA 0.2 MG/M3 ACGIHLIS_P
INHALABLE
FRACTION. ACGIHLIS_P
ACGIHLIS_P
ACGIHLIS_P
HAZARDOUS COMPONENTS WITHOUT WORKPLACE CONTROL PARAMETERS:
COMPONENTS CAS-NO.
ENGINEERING MEASURES:
PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION
TO MAINTAIN EXPOSURE BELOW EXPOSURE GUIDELINES (IF APPLICABLE) OR BELOW
LEVELS THAT CAUSE KNOWN, SUSPECTED OR APPARENT ADVERSE EFFECTS.
PERSONAL PROTECTIVE EQUIPMENT:
HAND PROTECTION:
REMARKS:
THE SUITABILITY FOR A SPECIFIC WORKPLACE SHOULD BE DISCUSSED WITH THE
PRODUCERS OF THE PROTECTIVE GLOVES.
EYE PROTECTION:
NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. WEAR SPLASH-PROOF SAFETY
GOGGLES IF MATERIAL COULD BE MISTED OR SPLASHED INTO EYES.
SKIN AND BODY PROTECTION:
WEAR RESISTANT GLOVES (CONSULT YOUR SAFETY EQUIPMENT SUPPLIER).
WEAR AS APPROPRIATE:
IMPERVIOUS CLOTHING
SAFETY SHOES
CHOOSE BODY PROTECTION ACCORDING TO THE AMOUNT AND CONCENTRATION OF THE
DANGEROUS SUBSTANCE AT THE WORK PLACE.
HYGIENE MEASURES: WASH HANDS BEFORE BREAKS AND AT THE END OF WORKDAY.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOUR: AMBER
ODOUR: OILY
ODOUR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
POUR POINT: <-44 DEG. F / -42 DEG. C
BOILING POINT/BOILING RANGE: >437.00 DEG. F / 225.00 DEG. C
FLASH POINT: 397 DEG. F / 203 DEG. C
METHOD: PENSKY MARTENS CLOSED CUP
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
UPPER EXPLOSION LIMIT: NO DATA AVAILABLE
LOWER EXPLOSION LIMIT: NO DATA AVAILABLE
VAPOUR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOUR DENSITY: NO DATA AVAILABLE
RELATIVE DENSITY: CA. 0.843 (15.6 DEG. C)
DENSITY: CA. 0.843 G/CM3 (15 DEG. C)
BULK DENSITY: NOT APPLICABLE
SOLUBILITY(IES):
WATER SOLUBILITY: INSOLUBLE
SOLUBILITY IN OTHER SOLVENTS: NO DATA AVAILABLE
THERMAL DECOMPOSITION: NO DATA AVAILABLE
VISCOSITY:
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
VISCOSITY, KINEMATIC:
CA. 13.5 MM2/S (100 DEG. C)
CA. 77 MM2/S (40 DEG. C)
OXIDIZING PROPERTIES: NO DATA AVAILABLE
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY: NO DECOMPOSITION IF STORED AND APPLIED AS DIRECTED.
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
PRODUCT WILL NOT UNDERGO HAZARDOUS POLYMERIZATION.
CONDITIONS TO AVOID: EXCESSIVE HEAT
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON DIOXIDE AND CARBON MONOXIDE
HYDROGEN SULFIDE
NITROGEN OXIDES (NOX)
SULPHUR OXIDES
ZINC OXIDE FUMES
MERCAPTANS
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION
SKIN CONTACT
EYE CONTACT
INGESTION
ACUTE TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
DECENE-1 HOMOPOLYMER HYDROGENATED:
ACUTE ORAL TOXICITY:
LD50 (RAT): >5,000 MG/KG
ACUTE INHALATION TOXICITY:
LC50 (RAT): >5.2 MG/L
EXPOSURE TIME: 4 H
TEST ATMOSPHERE: DUST/MIST
ASSESSMENT:
NO ADVERSE EFFECT HAS BEEN OBSERVED IN ACUTE INHALATION TOXICITY TESTS.
ACUTE DERMAL TOXICITY:
LD50 (RABBIT): >2,000 MG/KG
ASSESSMENT:
NO ADVERSE EFFECT HAS BEEN OBSERVED IN ACUTE DERMAL TOXICITY TESTS.
LUBRICATING OILS (PETROLEUM), C20-50, HYDROTREATED NEUTRAL OIL-BASED:
ACUTE ORAL TOXICITY:
LD50 (RAT): >5,000 MG/KG
ACUTE INHALATION TOXICITY:
LC50 (RAT): >5.58 MG/L
EXPOSURE TIME: 4 H
TEST ATMOSPHERE: DUST/MIST
ASSESSMENT: NOT CLASSIFIED AS ACUTELY TOXIC BY INHALATION UNDER GHS.
REMARKS: NO MORTALITY OBSERVED AT THIS DOSE.
ACUTE DERMAL TOXICITY:
LD50 (RABBIT): >5,000 MG/KG
REMARKS: NO MORTALITY OBSERVED AT THIS DOSE.
ZINC BIS[O-(6-METHYLHELPTYL)]BIS[O-SEC-BUTYL)]BIS(DITHIOPHOSPATE):
ACUTE ORAL TOXICITY:
LD50 (RAT): 2,600 MG/KG
ACUTE DERMAL TOXICITY:
LD50 (RABBIT): >3,160 MG/KG
METHOD: OECD TEST GUIDELINE 402
ASSESSMENT: NOT CLASSIFIED AS ACUTELY TOXIC BY DERMAL ABSORPTION UNDER GHS.
SKIN CORROSION/IRRITATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
DECENE-1 HOMOPOLYMER HYDROGENATED:
SPECIES: RABBIT
RESULT: NO SKIN IRRITATION
LUBRICATING OILS (PETROLEUM), C20-50, HYDROTREATED NEUTRAL OIL-BASED:
SPECIES: RABBIT
RESULT: NO SKIN IRRITATION
ZINC BIS[O-(6-METHYLHELPTYL)]BIS[O-SEC-BUTYL)]BIS(DITHIOPHOSPATE):
SPECIES: GUINEA PIG
METHOD: OECD TEST GUIDELINE 404
RESULT: IRRITATING TO SKIN.
REMARKS:
INFORMATION GIVEN IS BASED ON DATA OBTAINED FROM SIMILAR SUBSTANCES.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
PRODUCT:
RESULT: IRRITATING TO EYES.
REMARKS: EXPECTED BASED ON COMPONENTS.
REMARKS: UNLIKELY TO CAUSE EYE IRRITATION OR INJURY.
COMPONENTS:
DECENE-1 HOMOPOLYMER HYDROGENATED:
SPECIES: RABBIT
RESULT: SLIGHT, TRANSIENT IRRITATION
LUBRICATING OILS (PETROLEUM), C20-50, HYDROTREATED NEUTRAL OIL-BASED:
SPECIES: RABBIT
RESULT: NO EYE IRRITATION
ZINC BIS[O-(6-METHYLHELPTYL)]BIS[O-SEC-BUTYL)]BIS(DITHIOPHOSPATE):
SPECIES: RABBIT
RESULT: CORROSIVE
REMARKS:
INFORMATION GIVEN IS BASED ON DATA OBTAINED FROM SIMILAR SUBSTANCES.
RESPIRATORY OR SKIN SENSITISATION:
SKIN SENSITISATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
RESPIRATORY SENSITISATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
PRODUCT:
ASSESSMENT: DOES NOT CAUSE SKIN SENSITISATION.
COMPONENTS:
DECENE-1 HOMOPOLYMER HYDROGENATED:
TEST TYPE: MAXIMISATION TEST
SPECIES: GUINEA PIG
ASSESSMENT: DOES NOT CAUSE SKIN SENSITISATION.
METHOD: OECD TEST GUIDELINE 406
LUBRICATING OILS (PETROLEUM), C20-50, HYDROTREATED NEUTRAL OIL-BASED:
TEST TYPE: BUEHLER TEST
SPECIES: GUINEA PIG
ASSESSMENT: DOES NOT CAUSE SKIN SENSITISATION.
GERM CELL MUTAGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
DECENE-1 HOMOPOLYMER HYDROGENATED:
GENOTOXICITY IN VITRO:
TEST TYPE: AMES TEST
TEST SPECIES: SALMONELLA TYPHIMURIUM
METABOLIC ACTIVATION: WITH AND WITHOUT METABOLIC ACTIVATION
RESULT: NEGATIVE
ZINC BIS[O-(6-METHYLHELPTYL)]BIS[O-SEC-BUTYL)]BIS(DITHIOPHOSPATE):
GENOTOXICITY IN VITRO:
TEST TYPE: AMES TEST
TEST SPECIES: SALMONELLA TYPHIMURIUM
METABOLIC ACTIVATION: WITH AND WITHOUT METABOLIC ACTIVATION
METHOD: OECD TEST GUIDELINE 471
RESULT: NEGATIVE
REMARKS:
INFORMATION GIVEN IS BASED ON DATA OBTAINED FROM SIMILAR SUBSTANCES.
GENOTOXICITY IN VIVO:
TEST TYPE: MICRONUCLEUS TEST
TEST SPECIES: MOUSE
METHOD: OECD TEST GUIDELINE 474
RESULT: NEGATIVE
REMARKS:
INFORMATION GIVEN IS BASED ON DATA OBTAINED FROM SIMILAR SUBSTANCES.
CARCINOGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
REPRODUCTIVE TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
STOT - SINGLE EXPOSURE: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
STOT - REPEATED EXPOSURE: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
ASPIRATION TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
DECENE-1 HOMOPOLYMER HYDROGENATED:
THE SUBSTANCE OR MIXTURE IS KNOWN TO CAUSE HUMAN ASPIRATION TOXICITY
HAZARDS OR HAS TO BE REGARDED AS IF IT CAUSES A HUMAN ASPIRATION TOXICITY
HAZARD.
LUBRICATING OILS (PETROLEUM), C20-50, HYDROTREATED NEUTRAL OIL-BASED:
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
FURTHER INFORMATION:
PRODUCT:
REMARKS: NO DATA AVAILABLE
CARCINOGENICITY:
IARC:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS PROBABLE, POSSIBLE OR CONFIRMED HUMAN CARCINOGEN BY
IARC.
OSHA:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY OSHA.
NTP:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
| SECTION 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
PRODUCT:
ECOTOXICOLOGY ASSESSMENT:
ACUTE AQUATIC TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
CHRONIC AQUATIC TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
DECENE-1 HOMOPOLYMER HYDROGENATED:
TOXICITY TO FISH:
LL50 (ONCORHYNCHUS MYKISS (RAINBOW TROUT)): >1,000 MG/L
EXPOSURE TIME: 96 H
TEST TYPE: SEMI-STATIC TEST
TEST SUBSTANCE: WAF
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
EL50 (DAPHNIA MAGNA (WATER FLEA)): >1,000 MG/L
EXPOSURE TIME: 48 H
TEST TYPE: STATIC TEST
TEST SUBSTANCE: WAF
METHOD: OECD TEST GUIDELINE 202
TOXICITY TO ALGAE:
EL50 (SCENEDESMUS CAPRICORNUTUM (FRESH WATER ALGAE)): >1,000 MG/L
END POINT: GROWTH INHIBITION
EXPOSURE TIME: 72 H
TEST TYPE: STATIC TEST
TEST SUBSTANCE: WAF
METHOD: OECD TEST GUIDELINE 201
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES (CHRONIC TOXICITY):
NOELR (DAPHNIA MAGNA (WATER FLEA)): 125 MG/L
EXPOSURE TIME: 21 D
TEST TYPE: SEMI-STATIC TEST
TEST SUBSTANCE: WAF
METHOD: OECD TEST GUIDELINE 211
LUBRICATING OILS (PETROLEUM), C20-50, HYDROTREATED NEUTRAL OIL-BASED:
TOXICITY TO FISH:
LL50 (PIMEPHALES PROMELAS (FATHEAD MINNOW)): >100 MG/L
EXPOSURE TIME: 96 H
TEST TYPE: STATIC TEST
TEST SUBSTANCE: WAF
METHOD: OECD TEST GUIDELINE 203
REMARKS: NO TOXICITY AT THE LIMIT OF SOLUBILITY
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
EL50 (DAPHNIA MAGNA (WATER FLEA)): >10,000 MG/L
EXPOSURE TIME: 48 H
TEST TYPE: STATIC TEST
TEST SUBSTANCE: WAF
METHOD: OECD TEST GUIDELINE 202
TOXICITY TO ALGAE:
NOEL (PSEUDOKIRCHNERIELLA SUBCAPITATA (GREEN ALGAE)): >=100 MG/L
END POINT: GROWTH INHIBITION
EXPOSURE TIME: 72 H
TEST TYPE: STATIC TEST
TEST SUBSTANCE: WAF
METHOD: OECD TEST GUIDELINE 201
TOXICITY TO FISH (CHRONIC TOXICITY):
NOELR (ONCORHYNCHUS MYKISS (RAINBOW TROUT)): CALCULATED >=1,000 MG/L
EXPOSURE TIME: 14 D
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES (CHRONIC TOXICITY):
NOEL (DAPHNIA (WATER FLEA)): 10 MG/L
EXPOSURE TIME: 21 D
TEST SUBSTANCE: WAF
METHOD: OECD TEST GUIDELINE 211
ZINC BIS[O-(6-METHYLHELPTYL)]BIS[O-SEC-BUTYL)]BIS(DITHIOPHOSPATE):
TOXICITY TO FISH:
LL50 (ONCORHYNCHUS MYKISS (RAINBOW TROUT)): 4.5 MG/L
EXPOSURE TIME: 96 H
TEST TYPE: SEMI-STATIC TEST
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
EC50 (WATER FLEA (DAPHNIA MAGNA)): 5.4 MG/L
EXPOSURE TIME: 48 H
TEST TYPE: STATIC TEST
TOXICITY TO ALGAE:
EC50 (SELENASTRUM CAPRICORNUTUM (GREEN ALGAE)): 2.1 MG/L
END POINT: GROWTH INHIBITION
EXPOSURE TIME: 72 H
TEST TYPE: STATIC TEST
PERSISTENCE AND DEGRADABILITY:
COMPONENTS:
DECENE-1 HOMOPOLYMER HYDROGENATED:
BIODEGRADABILITY:
RESULT: INHERENTLY BIODEGRADABLE.
LUBRICATING OILS (PETROLEUM), C20-50, HYDROTREATED NEUTRAL OIL-BASED:
BIODEGRADABILITY:
RESULT: NOT READILY BIODEGRADABLE.
BIODEGRADATION: 2 - 4%
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 301B
ZINC BIS[O-(6-METHYLHELPTYL)]BIS[O-SEC-BUTYL)]BIS(DITHIOPHOSPATE):
BIODEGRADABILITY:
RESULT: NOT READILY BIODEGRADABLE.
BIODEGRADATION: 1.5%
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 301B
NO DATA AVAILABLE
BIOACCUMULATIVE POTENTIAL:
COMPONENTS:
DECENE-1 HOMOPOLYMER HYDROGENATED:
PARTITION COEFFICIENT N-OCTANOL/WATER:
LOG POW: >6.5
ZINC BIS[O-(6-METHYLHELPTYL)]BIS[O-SEC-BUTYL)]BIS(DITHIOPHOSPATE):
PARTITION COEFFICIENT N-OCTANOL/WATER:
LOG POW: 0.59 - 1.2 (23 DEG. C)
NO DATA AVAILABLE
MOBILITY IN SOIL:
COMPONENTS: NO DATA AVAILABLE
OTHER ADVERSE EFFECTS: NO DATA AVAILABLE
PRODUCT:
ADDITIONAL ECOLOGICAL INFORMATION: NO DATA AVAILABLE
COMPONENTS:
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
GENERAL ADVICE:
DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL
REGULATIONS.
DO NOT DISPOSE OF WASTE INTO SEWER.
DO NOT CONTAMINATE PONDS, WATERWAYS OR DITCHES WITH CHEMICAL OR USED
CONTAINER.
SEND TO A LICENSED WASTE MANAGEMENT COMPANY.
CONTAMINATED PACKAGING:
EMPTY REMAINING CONTENTS.
DISPOSE OF AS UNUSED PRODUCT.
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL.
DO NOT RE-USE EMPTY CONTAINERS.
| SECTION 14. TRANSPORT INFORMATION | |
INTERNATIONAL TRANSPORT REGULATIONS:
REGULATION:
ID NUMBER PROPER SHIPPING NAME *HAZARD SUBSIDIARY PACKING MARINE
CLASS HAZARDS GROUP POLLUTANT /
LTD. QTY.
U.S. DOT - ROAD: NOT DANGEROUS GOODS
CFR_RAIL_C: NOT DANGEROUS GOODS
U.S. DOT - INLAND WATERWAYS: NOT DANGEROUS GOODS
TDG_ROAD_C: NOT DANGEROUS GOODS
TDG_RAIL_C: NOT DANGEROUS GOODS
TDG_INWT_C: NOT DANGEROUS GOODS
INTERNATIONAL MARITIME DANGEROUS GOODS: NOT DANGEROUS GOODS
INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO: NOT DANGEROUS GOODS
INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER: NOT DANGEROUS GOODS
MX_DG: NOT DANGEROUS GOODS
*ORM = ORM-D
CBL = COMBUSTIBLE LIQUID
MARINE POLLUTANT: NO
DANGEROUS GOODS DESCRIPTIONS (IF INDICATED ABOVE) MAY NOT REFLECT
QUANTITY, END-USE OR REGION-SPECIFIC EXCEPTIONS THAT CAN BE APPLIED.
CONSULT SHIPPING DOCUMENTS FOR DESCRIPTIONS THAT ARE SPECIFIC TO THE
SHIPMENT.
| SECTION 15. REGULATORY INFORMATION | |
EPCRA - EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT:
CERCLA REPORTABLE QUANTITY:
THIS MATERIAL DOES NOT CONTAIN ANY COMPONENTS WITH A CERCLA RQ.
SARA 304 EXTREMELY HAZARDOUS SUBSTANCES REPORTABLE QUANTITY:
THIS MATERIAL DOES NOT CONTAIN ANY COMPONENTS WITH A SECTION 304 EHS RQ.
SARA 311/312 HAZARDS: ACUTE HEALTH HAZARD
SARA 313:
ZINC BIS[O-(6-METHYLHELPTYL)]BIS[O-SEC-BUTYL)] 93819-94-4 1.32%
BIS(DITHIOPHOSPATE)
CALIFORNIA PROP 65:
THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS KNOWN TO STATE OF CALIFORNIA
TO CAUSE CANCER, BIRTH DEFECTS, OR ANY OTHER REPRODUCTIVE HARM.
THE COMPONENTS OF THIS PRODUCT ARE REPORTED IN THE FOLLOWING INVENTORIES:
DSL: ALL COMPONENTS OF THIS PRODUCT ARE ON THE CANADIAN DSL
AICS: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
ENCS: NOT IN COMPLIANCE WITH THE INVENTORY
KECI: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
PICCS: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
IECSC: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
TSCA: ON TSCA INVENTORY
INVENTORIES:
AICS (AUSTRALIA), DSL (CANADA), IECSC (CHINA), REACH (EUROPEAN UNION),
ENCS (JAPAN), ISHL (JAPAN), KECI (KOREA), NZIOC (NEW ZEALAND), PICCS
(PHILIPPINES), TCSI (TAIWAN), TSCA (USA)
| SECTION 16. OTHER INFORMATION | |
FURTHER INFORMATION:
REVISION DATE: 05/22/2017
NFPA:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARD.
HMIS III:
HEALTH 2
FLAMMABILITY 1
PHYSICAL HAZARD 0
0 = NOT SIGNIFICANT
1 = SLIGHT
2 = MODERATE
3 = HIGH
4 = EXTREME
* = CHRONIC
NFPA FLAMMABLE AND COMBUSTIBLE LIQUIDS CLASSIFICATION:
COMBUSTIBLE LIQUID CLASS IIIB
FULL TEXT OF H-STATEMENTS:
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
H315: CAUSES SKIN IRRITATION.
H318: CAUSES SERIOUS EYE DAMAGE.
SOURCES OF KEY DATA USED TO COMPILE THE SAFETY DATA SHEET
VALVOLINE INTERNAL DATA INCLUDING OWN AND SPONSORED TEST REPORTS
THE UNECE ADMINISTERS REGIONAL AGREEMENTS IMPLEMENTING HARMONISED
CLASSIFICATION FOR LABELLING (GHS) AND TRANSPORT.
THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT IS NOT
WARRANTED TO BE WHETHER ORIGINATING WITH THE COMPANY OR NOT. RECIPIENTS
ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT,
APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCES. THIS SDS HAS BEEN
PREPARED BY VALVOLINE'S ENVIRONMENTAL HEALTH AND SAFETY DEPARTMENT
(1-800-VALVOLINE).
LIST OF ABBREVIATIONS AND ACRONYMS THAT COULD BE, BUT NOT NECESSARILY
ARE, USED IN THIS SAFETY DATA SHEET:
ACGIH: AMERICAN CONFERENCE OF INDUSTRIAL HYGIENISTS
BEI: BIOLOGICAL EXPOSURE INDEX
CAS:
CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY).
CMR: CARCINOGENIC, MUTAGENIC OR TOXIC FOR REPRODUCTION
FG: FOOD GRADE
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS.
H-STATEMENT: HAZARD STATEMENT
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION.
IATA-DGR:
DANGEROUS GOODS REGULATION BY THE "INTERNATIONAL AIR TRANSPORT ASSOCIATION"
(IATA).
ICAO: INTERNATIONAL CIVIL AVIATION ORGANIZATION
ICAO-TI (ICAO):
TECHNICAL INSTRUCTIONS BY THE "INTERNATIONAL CIVIL AVIATION ORGANIZATION"
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
ISO: INTERNATIONAL ORGANIZATION FOR STANDARDIZATION
LOGPOW: OCTANOL-WATER PARTITION COEFFICIENT
LCXX: LETHAL CONCENTRATION, FOR XX PERCENT OF TEST POPULATION
LDXX: LETHAL DOSE, FOR XX PERCENT OF TEST POPULATION.
ICXX: INHIBITORY CONCENTRATION FOR XX OF A SUBSTANCE
ECXX: EFFECTIVE CONCENTRATION OF XX
N.O.S.: NOT OTHERWISE SPECIFIED
OECD: ORGANIZATION FOR ECONOMIC CO-OPERATION AND DEVELOPMENT
OEL: OCCUPATIONAL EXPOSURE LIMIT
P-STATEMENT: PRECAUTIONARY STATEMENT
PBT: PERSISTENT, BIOACCUMULATIVE AND TOXIC
PPE: PERSONAL PROTECTIVE EQUIPMENT
STEL: SHORT-TERM EXPOSURE LIMIT
STOT: SPECIFIC TARGET ORGAN TOXICITY
TLV: THRESHOLD LIMIT VALUE
TWA: TIME-WEIGHTED AVERAGE
VPVB: VERY PERSISTENT AND VERY BIOACCUMULATIVE
WEL: WORKPLACE EXPOSURE LEVEL
CERCLA:
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT
DOT: DEPARTMENT OF TRANSPORTATION
FIFRA: FEDERAL INSECTICIDE, FUNGICIDE, AND RODENTICIDE ACT
HMIRC: HAZARDOUS MATERIALS INFORMATION REVIEW COMMISSION
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION
NIOSH: NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
PMRA: HEALTH CANADA PEST MANAGEMENT REGULATORY AGENCY
RTK: RIGHT TO KNOW
WHMIS: WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEME