| Common Name: | GORILLA WELD RESIN, GORILLA WELD - HARDENER |
| Manufacturer: | GORILLA GLUE |
| SDS Revision Date: | 2/27/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 453U47 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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GORILLA
INCREDIBLY STRONG
100% TOUGH
SAFETY DATA SHEET
GORILLA WELD - RESIN
DATE REVISED: 02/27/2017
DATE ISSUED: 01/25/2017
VERSION: 1.1
FOR CHEMICAL EMERGENCY:
DURING BUSINESS HOURS: (800) 966-3458
OUTSIDE BUSINESS HOURS: (800) 420-7186
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS AND ACCORDING TO THE HAZARDOUS PRODUCTS REGULATION
(FEBRUARY 11, 2015).
| SECTION 1: IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT FORM: MIXTURE
PRODUCT NAME: GORILLA WELD RESIN
INTENDED USE OF THE PRODUCT: ADHESIVE
NAME, ADDRESS, AND TELEPHONE OF THE RESPONSIBLE PARTY:
COMPANY
THE GORILLA GLUE COMPANY
2101 E. KEMPER ROAD
CINCINNATI, OHIO 45241
513-271-3300
WWW.GORILLATOUGH.COM
EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER: 1-800-420-7186 (PROSAR)
| SECTION 2: HAZARDS IDENTIFICATION | |
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-US/CA CLASSIFICATION:
FLAM. LIQ. 2: H225
SKIN IRRIT. 2: H315
EYE DAM. 1: H318
SKIN SENS. 1: H317
STOT SE 3: H335
AQUATIC CHRONIC 3: H412
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
LABEL ELEMENTS:
GHS-US/CA LABELING:
HAZARD PICTOGRAMS (GHS-US/CA):
GHS02: FLAME
GHS05: CORROSION
GHS07: EXCLAMATION MARK
SIGNAL WORD (GHS-US/CA): DANGER
HAZARD STATEMENTS (GHS-US/CA):
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR.
H315: CAUSES SKIN IRRITATION.
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H318: CAUSES SERIOUS EYE DAMAGE.
H335: MAY CAUSE RESPIRATORY IRRITATION.
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENTS (GHS-US/CA):
P102: KEEP OUT OF REACH OF CHILDREN.
P210:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING.
P260: DO NOT BREATHE VAPORS, MIST, OR SPRAY.
P280: WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, AND EYE PROTECTION.
P302 + P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
OTHER HAZARDS:
NOTE:
GORILLA WELD CONTAINS METHACRYLIC ACID CAS NO. 79-41-4 WHICH, ACCORDING TO
ANNEX 1, TABLE 3.2.3 OF CLP CARRIES THE H314: CORROSIVE CLASSIFICATION.
PRODUCT LEVEL DERMAL CORROSIVITY TESTING FOR GORILLA WELD CONFIRMS THE
PRODUCT IS CLASSIFIED AS A SKIN IRRITANT RATHER THAN CORROSIVE. POSITIVE
RESULTS IN A VALID AND ACCEPTED SKIN CORROSION TEST (CORROSITEX TEST)
CLASSIFIES THE MIXTURE AS NON-CORROSIVE UTILIZING MULTIPLE REPLICATE
SAMPLES INDICATING HIGHLY REPRODUCIBLE RESULTS. AS A RESULT, THE HEALTH
HAZARD AND TRANSPORT CLASSIFICATION HAVE BEEN CHANGED TO REFLECT THE WELD
RESULTS: UN NON-CORROSIVE AND NOT A GHS CATEGORY 1.
UNKNOWN ACUTE TOXICITY (GHS-US/CA): NO DATA AVAILABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURE:
NAME PRODUCT IDENTIFIER % * GHS INGREDIENT
CLASSIFICATION
METHYL METHACRYLATE (CAS NO) 80-62-6 40-70 FLAM. LIQ. 2, H225
SKIN IRRIT. 2, H315
EYE IRRIT. 2B, H320
SKIN SENS. 1, H317
STOT SE 3, H335
AQUATIC ACUTE 3, H402
METHACRYLIC ACID (CAS NO) 79-41-4 5-15 FLAM. LIQ. 4, H227
ACUTE TOX. 4 (ORAL), H302
ACUTE TOX. 3 (DERMAL),
H311
ACUTE TOX. 3 (INHALATION:
VAPOR), H331
SKIN CORR. 1A, H314
EYE DAM. 1, H318
AQUATIC ACUTE 3, H402
2-PROPENOIC ACID, (CAS NO) 25053-09-2 5-10 SKIN IRRIT. 2, H315
2-METHYL-, METHYL EYE IRRIT. 2A, H319
ESTER, POLYMER WITH SKIN SENS. 1, H317
1,3-BUTADIENE AND
ETHENYLBENZENE
2-PROPENOIC ACID, (CAS NO) 32435-46-4 0.1-1 SKIN IRRIT. 2, H315
2-METHYL-, EYE IRRIT. 2A, H319
PHOSPHINICOBIS(OXY- STOT SE 3, H335
2,1-ETHANEDIYL) AQUATIC CHRONIC 3, H412
ESTER
CUMENE (CAS NO) 80-15-9 0.1-1 FLAM. LIQ. 4, H227
HYDROPEROXIDE ORG. PEROX. E, H242
ACUTE TOX. 4 (ORAL), H302
ACUTE TOX. 4 (DERMAL),
H312
ACUTE TOX. 3 (INHALATION:
DUST, MIST), H331
SKIN CORR. 1B, H314
EYE DAM. 1, H318
STOT RE 2, H373
AQUATIC ACUTE 2, H401
AQUATIC CHRONIC 2, H411
TALC (CAS NO) 14807-96-6 0.1-1 NOT CLASSIFIED
BENZENESULFONIC (CAS NO) 25167-32-2 0.1-1 ACUTE TOX. 4 (ORAL), H302
ACID, EYE DAM. 1, H318
OXYBIS[DODECYL-, AQUATIC ACUTE 2, H401
DISODIUM SALT AQUATIC CHRONIC 2, H411
2,6-DI-TERT-BUTYL- (CAS NO) 128-37-0 0.1-1 AQUATIC ACUTE 1, H400
P-CRESOL AQUATIC CHRONIC 1, H410
1,1,2- (CAS NO) 79-00-5 0.1-1 ACUTE TOX. 4 (ORAL), H302
TRICHLOROETHANE ACUTE TOX. 4 (DERMAL),
H312
ACUTE TOX. 4 (INHALATION:
DUST, MIST), H332
CARC. 2, H351
AQUATIC ACUTE 3, H402
CUMENE (CAS NO) 98-82-8 <0.1 FLAM. LIQ. 3, H226
STOT SE 3, H335
ASP. TOX. 1, H304
AQUATIC ACUTE 2, H401
AQUATIC CHRONIC 2, H411
ACETOPHENONE (CAS NO) 98-86-2 <0.1 FLAM. LIQ. 4, H227
ACUTE TOX. 4 (ORAL), H302
ACUTE TOX. 4 (DERMAL),
H312
EYE IRRIT. 2A, H319
FULL TEXT OF H-PHRASES: SEE SECTION 16
*PERCENTAGES ARE LISTED IN WEIGHT BY WEIGHT PERCENTAGE (W/W%) FOR LIQUID
AND SOLID INGREDIENTS. GAS INGREDIENTS ARE LISTED IN VOLUME BY VOLUME
PERCENTAGE (V/V%).
| SECTION 4: FIRST AID MEASURES | |
DESCRIPTION OF FIRST-AID MEASURES:
GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF YOU FEEL UNWELL,
SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
INHALATION:
WHEN SYMPTOMS OCCUR: GO INTO OPEN AIR AND VENTILATE SUSPECTED AREA. OBTAIN
MEDICAL ATTENTION IF BREATHING DIFFICULTY PERSISTS.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING. IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER
FOR AT LEAST 30 MINUTES. OBTAIN MEDICAL ATTENTION.
EYE CONTACT:
RINSE CAUTIOUSLY WITH WATER FOR AT LEAST 60 MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING. GET IMMEDIATE MEDICAL
ADVICE/ATTENTION.
INGESTION: RINSE MOUTH. DO NOT INDUCE VOMITING. OBTAIN MEDICAL ATTENTION.
MOST IMPORTANT SYMPTOMS AND EFFECTS BOTH ACUTE AND DELAYED:
GENERAL:
CAUSES SERIOUS EYE DAMAGE. CAUSES SEVERE SKIN IRRITATION AND EYE DAMAGE.
MAY CAUSE RESPIRATORY IRRITATION. SKIN SENSITIZATION.
INHALATION:
IRRITATION OF THE RESPIRATORY TRACT AND THE OTHER MUCOUS MEMBRANES. MAY BE
CORROSIVE TO THE RESPIRATORY TRACT. SYMPTOMS OF RESPIRATORY COMPLICATIONS
(LUNG EDEMA) MAY OCCUR SEVERAL HOURS AFTER EXPOSURE.
SKIN CONTACT:
CAUSES SEVERE IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES PERMANENT DAMAGE TO THE CORNEA, IRIS, OR CONJUNCTIVA.
INGESTION:
INGESTION MAY CAUSE ADVERSE EFFECTS. MAY CAUSE GASTROINTESTINAL IRRITATION.
CHRONIC SYMPTOMS: NONE ANTICIPATED
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
IF EXPOSED OR CONCERNED, GET MEDICAL ADVICE AND ATTENTION. IF MEDICAL
ADVICE IS NEEDED, HAVE PRODUCT CONTAINER OR LABEL AT HAND.
| SECTION 5: FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
DRY CHEMICAL POWDER, ALCOHOL-RESISTANT FOAM, CARBON DIOXIDE (CO2). WATER
MAY BE INEFFECTIVE BUT WATER SHOULD BE USED TO KEEP FIRE-EXPOSED CONTAINER
COOL.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE A HEAVY WATER STREAM. A HEAVY WATER STREAM MAY SPREAD BURNING
LIQUID.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
FIRE HAZARD: HIGHLY FLAMMABLE LIQUID AND VAPOR.
EXPLOSION HAZARD:
MAY FORM FLAMMABLE OR EXPLOSIVE VAPOR-AIR MIXTURE. WHEN MIXED WITH AIR AND
EXPOSED TO AN IGNITION SOURCE, FLAMMABLE VAPORS CAN BURN IN THE OPEN OR
EXPLODE IN CONFINED SPACES. BEING HEAVIER THAN AIR, VAPORS MAY TRAVEL LONG
DISTANCES TO AN IGNITION SOURCE AND FLASH BACK. RUNOFF TO SEWER MAY CAUSE
FIRE OR EXPLOSION HAZARD.
REACTIVITY:
REACTS VIOLENTLY WITH STRONG OXIDIZERS. INCREASED RISK OF FIRE OR
EXPLOSION. THE PRODUCT IS NORMALLY SUPPLIED IN A STABILIZED FORM. IF THE
PERMISSIBLE STORAGE PERIOD AND/OR STORAGE TEMPERATURE IS EXCEEDED, THE
PRODUCT MAY POLYMERIZE WITH HEAT EVOLUTION. POLYMERIZATION WITH HEAT
EVOLUTION MAY OCCUR IN THE PRESENCE OF RADICAL FORMING SUBSTANCES (E.G.
PEROXIDES), REDUCING SUBSTANCES, AND/OR HEAVY METAL IONS. PRODUCT REACTS
VIOLENTLY OR EXPLOSIVELY WITH ALKALI METALS, ALKALINE EARTH METALS, VARIOUS
METAL POWDERS, STRONG ALKALIS, AMMONIA, AND OTHER INCOMPATIBLE MATERIALS.
REACTS VIGOROUSLY WITH WATER PRODUCING HEAT. CONTACT WITH METALS AND WATER
LIBERATES HYDROGEN.
ADVICE FOR FIREFIGHTERS:
PRECAUTIONARY MEASURES FIRE:
EXERCISE CAUTION WHEN FIGHTING ANY CHEMICAL FIRE.
FIREFIGHTING INSTRUCTIONS:
REMOVE CONTAINERS FROM FIRE AREA IF THIS CAN BE DONE WITHOUT RISK. USE
WATER SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS. DO NOT GET WATER INSIDE
CONTAINERS. DO NOT APPLY WATER STREAM DIRECTLY AT SOURCE OF LEAK. IN CASE
OF MAJOR FIRE AND LARGE QUANTITIES: EVACUATE AREA. FIGHT FIRE REMOTELY DUE
TO THE RISK OF EXPLOSION. DO NOT BREATHE FUMES FROM FIRES OR VAPORS FROM
DECOMPOSITION.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
HAZARDOUS COMBUSTION PRODUCTS:
THERMAL DECOMPOSITION GENERATES:
CARBON OXIDES (CO, CO2). NITROGEN OXIDES. AMMONIA. PHENOL. PHENOLIC
COMPOUNDS. ACETONE. ACRYLATES. METHYL METHACRYLATE. CORROSIVE VAPORS.
PHOSGENE. CHLORINE. DIOXINS. HYDROGEN CHLORIDE.
OTHER INFORMATION:
DO NOT ALLOW RUN-OFF FROM FIRE FIGHTING TO ENTER DRAINS OR WATER COURSES.
EXPOSURE TO FIRE MAY CAUSE CONTAINERS TO RUPTURE/EXPLODE.
REFERENCE TO OTHER SECTIONS:
REFER TO SECTION 9 FOR FLAMMABILITY PROPERTIES.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. DO NOT BREATHE VAPOR, MIST OR
SPRAY. KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES, AND OTHER
IGNITION SOURCES. NO SMOKING. USE SPECIAL CARE TO AVOID STATIC ELECTRIC
CHARGES.
FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT: USE APPROPRIATE PERSONAL PROTECTION EQUIPMENT (PPE).
EMERGENCY PROCEDURES:
EVACUATE UNNECESSARY PERSONNEL. STOP LEAK IF SAFE TO DO SO.
FOR EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT: EQUIP CLEANUP CREW WITH PROPER PROTECTION.
EMERGENCY PROCEDURES:
VENTILATE AREA. ELIMINATE IGNITION SOURCES. UPON ARRIVAL AT THE SCENE, A
FIRST RESPONDER IS EXPECTED TO RECOGNIZE THE PRESENCE OF DANGEROUS GOODS,
PROTECT ONESELF AND THE PUBLIC, SECURE THE AREA, AND CALL FOR THE
ASSISTANCE OF TRAINED PERSONNEL AS SOON AS CONDITIONS PERMIT.
ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY TO SEWERS AND PUBLIC WATERS. AVOID RELEASE TO THE
ENVIRONMENT.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
FOR CONTAINMENT:
CONTAIN ANY SPILLS WITH DIKES OR ABSORBENTS TO PREVENT MIGRATION AND ENTRY
INTO SEWERS OR STREAMS. AS AN IMMEDIATE PRECAUTIONARY MEASURE, ISOLATE
SPILL OR LEAK AREA IN ALL DIRECTIONS.
METHODS FOR CLEANING UP:
CLEAN UP SPILLS IMMEDIATELY AND DISPOSE OF WASTE SAFELY. ELIMINATE ALL
IGNITION SOURCES. ABSORB AND/OR CONTAIN SPILL WITH INERT MATERIAL. DO NOT
TAKE UP IN COMBUSTIBLE MATERIAL SUCH AS: SAW DUST OR CELLULOSIC MATERIAL.
USE ONLY NON-SPARKING TOOLS. TRANSFER SPILLED MATERIAL TO A SUITABLE
CONTAINER FOR DISPOSAL. CONTACT COMPETENT AUTHORITIES AFTER A SPILL.
REFERENCE TO OTHER SECTIONS:
SEE SECTION 8 FOR EXPOSURE CONTROLS AND PERSONAL PROTECTION AND SECTION 13
FOR DISPOSAL CONSIDERATIONS.
| SECTION 7: HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
ADDITIONAL HAZARDS WHEN PROCESSED:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
HAZARDOUS POLYMERIZATION MAY OCCUR. VAPORS MAY BE UNINHIBITED AND
POLYMERIZE, CAUSING BLOCKAGE OF VENTS.
PRECAUTIONS FOR SAFE HANDLING:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. WASH HANDS AND OTHER EXPOSED AREAS
WITH MILD SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING AND WHEN
LEAVING WORK. TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE. USE
ONLY NON-SPARKING TOOLS. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. DO
NOT BREATHE MIST, SPRAY, AND VAPORS. USE APPROPRIATE PERSONAL PROTECTION
EQUIPMENT (PPE).
HYGIENE MEASURES:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PROCEDURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES:
COMPLY WITH APPLICABLE REGULATIONS. TAKE ACTION TO PREVENT STATIC
DISCHARGES. GROUND AND BOND CONTAINER AND RECEIVING EQUIPMENT. USE
EXPLOSION-PROOF ELECTRICAL, VENTILATING, AND LIGHTING EQUIPMENT.
STORAGE CONDITIONS:
STORE ONLY IF STABILIZED. STORE IN A DRY, COOL PLACE. STORE IN A
WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. CONTAINERS WHICH ARE
OPENED SHOULD BE PROPERLY RESEALED AND KEPT UPRIGHT TO PREVENT LEAKAGE.
PROTECT FROM SUNLIGHT. KEEP/STORE AWAY FROM DIRECT SUNLIGHT, EXTREMELY HIGH
OR LOW TEMPERATURES AND INCOMPATIBLE MATERIALS. KEEP IN FIREPROOF PLACE.
STORE IN ORIGINAL CONTAINER. STORE LOCKED UP.
INCOMPATIBLE MATERIALS:
STRONG ACIDS, STRONG BASES, STRONG OXIDIZERS. AMMONIA. ORGANIC PEROXIDES.
PEROXIDES. POLYMERIZATION CATALYSTS. AMINES. ULTRAVIOLET LIGHT. LIGHT.
FREE RADICAL INITIATORS. REDUCING AGENTS. HEAVY METAL IONS. MINERAL ACIDS.
IODIDES. SULFIDES. ISOCYANATES.
SPECIFIC END USE(S): ADHESIVE
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
FOR SUBSTANCES LISTED IN SECTION 3 THAT ARE NOT LISTED HERE, THERE ARE NO
ESTABLISHED EXPOSURE LIMITS FROM THE MANUFACTURER, SUPPLIER, IMPORTER, OR
THE APPROPRIATE ADVISORY AGENCY INCLUDING: ACGIH (TLV), AIHA (WEEL), NIOSH
(REL), OSHA (PEL), CANADIAN PROVINCIAL GOVERNMENTS, OR THE MEXICAN
GOVERNMENT.
METHYL METHACRYLATE (80-62-6):
MEXICO:
OEL TWA (MG/M3): 410 MG/M3
MEXICO:
OEL TWA (PPM): 100 PPM
MEXICO:
OEL STEL (MG/M3): 510 MG/M3
MEXICO:
OEL STEL (PPM): 125 PPM
USA ACGIH:
ACGIH TWA (PPM): 50 PPM
USA ACGIH:
ACGIH STEL (PPM): 100 PPM
USA ACGIH:
ACGIH CHEMICAL CATEGORY:
DERMAL SENSITIZER, NOT CLASSIFIABLE AS A HUMAN CARCINOGEN
USA OSHA:
OSHA PEL (TWA) (MG/M3): 410 MG/M3
USA OSHA:
OSHA PEL (TWA) (PPM): 100 PPM
USA NIOSH:
NIOSH REL (TWA) (MG/M3): 410 MG/M3
USA NIOSH:
NIOSH REL (TWA) (PPM): 100 PPM
USA IDLH:
US IDLH (PPM): 1000 PPM
ALBERTA:
OEL STEL (MG/M3): 410 MG/M3
ALBERTA:
OEL STEL (PPM): 100 PPM
ALBERTA:
OEL TWA (MG/M3): 205 MG/M3
ALBERTA:
OEL TWA (PPM): 50 PPM
BRITISH COLUMBIA:
OEL STEL (PPM): 100 PPM
BRITISH COLUMBIA:
OEL TWA (PPM): 50 PPM
MANITOBA:
OEL STEL (PPM): 100 PPM
MANITOBA:
OEL TWA (PPM): 50 PPM
NEW BRUNSWICK:
OEL TWA (MG/M3): 410 MG/M3
NEW BRUNSWICK:
OEL TWA (PPM): 100 PPM
NEWFOUNDLAND & LABRADOR:
OEL STEL (PPM): 100 PPM
NEWFOUNDLAND & LABRADOR:
OEL TWA (PPM): 50 PPM
NOVA SCOTIA:
OEL STEL (PPM): 100 PPM
NOVA SCOTIA:
OEL TWA (PPM): 50 PPM
NUNAVUT:
OEL STEL (PPM): 100 PPM
NUNAVUT:
OEL TWA (PPM): 50 PPM
NORTHWEST TERRITORIES:
OEL STEL (PPM): 100 PPM
NORTHWEST TERRITORIES:
OEL TWA (PPM): 50 PPM
ONTARIO:
OEL STEL (PPM): 100 PPM
ONTARIO:
OEL TWA (PPM): 50 PPM
PRINCE EDWARD ISLAND:
OEL STEL (PPM): 100 PPM
PRINCE EDWARD ISLAND:
OEL TWA (PPM): 50 PPM
QUEBEC:
VEMP (MG/M3): 205 MG/M3
QUEBEC:
VEMP (PPM): 50 PPM
SASKATCHEWAN:
OEL STEL (PPM): 100 PPM
SASKATCHEWAN:
OEL TWA (PPM): 50 PPM
YUKON:
OEL STEL (MG/M3): 510 MG/M3
YUKON:
OEL STEL (PPM): 125 PPM
YUKON:
OEL TWA (MG/M3): 410 MG/M3
YUKON:
OEL TWA (PPM): 100 PPM
METHACRYLIC ACID (79-41-4):
USA ACGIH:
ACGIH TWA (PPM): 20 PPM
USA NIOSH:
NIOSH REL (TWA) (MG/M3): 70 MG/M3
USA NIOSH:
NIOSH REL (TWA) (PPM): 20 PPM
ALBERTA:
OEL TWA (MG/M3): 70 MG/M3
ALBERTA:
OEL TWA (PPM): 20 PPM
BRITISH COLUMBIA:
OEL TWA (PPM): 20 PPM
MANITOBA:
OEL TWA (PPM): 20 PPM
NEW BRUNSWICK:
OEL TWA (MG/M3): 70 MG/M3
NEW BRUNSWICK:
OEL TWA (PPM): 20 PPM
NEWFOUNDLAND & LABRADOR:
OEL TWA (PPM): 20 PPM
NOVA SCOTIA:
OEL TWA (PPM): 20 PPM
NUNAVUT:
OEL STEL (PPM): 30 PPM
NUNAVUT:
OEL TWA (PPM): 20 PPM
NORTHWEST TERRITORIES:
OEL STEL (PPM): 30 PPM
NORTHWEST TERRITORIES:
OEL TWA (PPM): 20 PPM
ONTARIO:
OEL TWA (PPM): 20 PPM
PRINCE EDWARD ISLAND:
OEL TWA (PPM): 20 PPM
QUEBEC:
VEMP (MG/M3): 70 MG/M3
QUEBEC:
VEMP (PPM): 20 PPM
SASKATCHEWAN:
OEL STEL (PPM): 30 PPM
SASKATCHEWAN:
OEL TWA (PPM): 20 PPM
CUMENE HYDROPEROXIDE (80-15-9):
USA AIHA:
WEEL TWA (PPM): 1 PPM
USA AIHA:
AIHA CHEMICAL CATEGORY: SKIN NOTATION
TALC (14807-96-6):
MEXICO:
OEL TWA (MG/M3): 2 MG/M3 (RESPIRABLE FRACTION)
USA ACGIH:
ACGIH TWA (MG/M3):
2 MG/M3 (PARTICULATE MATTER CONTAINING NO ASBESTOS AND <1% CRYSTALLINE
SILICA, RESPIRABLE PARTICULATE MATTER)
USA ACGIH:
ACGIH CHEMICAL CATEGORY:
NOT CLASSIFIABLE AS A HUMAN CARCINOGEN CONTAINING NO ASBESTOS FIBERS
USA NIOSH:
NIOSH REL (TWA) (MG/M3):
2 MG/M3 (CONTAINING NO ASBESTOS AND <1% QUARTZ-RESPIRABLE DUST)
USA IDLH:
US IDLH (MG/M3): 1000 MG/M3 (CONTAINING NO ASBESTOS AND <1% QUARTZ)
ALBERTA:
OEL TWA (MG/M3): 2 MG/M3 (RESPIRABLE PARTICULATE)
BRITISH COLUMBIA:
OEL TWA (MG/M3):
2 MG/M3 (PARTICULATE MATTER CONTAINING NO ASBESTOS AND <1% CRYSTALLINE
SILICA-RESPIRABLE PARTICULATE)
MANITOBA:
OEL TWA (MG/M3):
2 MG/M3 (PARTICULATE MATTER CONTAINING NO ASBESTOS AND <1% CRYSTALLINE
SILICA-RESPIRABLE PARTICULATE MATTER)
NEW BRUNSWICK:
OEL TWA (MG/M3):
2 MG/M3 (PARTICULATE MATTER CONTAINING NO ASBESTOS AND <1% CRYSTALLINE
SILICA, RESPIRABLE FRACTION)
NEWFOUNDLAND & LABRADOR:
OEL TWA (MG/M3):
2 MG/M3 (PARTICULATE MATTER CONTAINING NO ASBESTOS AND <1% CRYSTALLINE
SILICA-RESPIRABLE PARTICULATE MATTER)
NOVA SCOTIA:
OEL TWA (MG/M3):
2 MG/M3 (PARTICULATE MATTER CONTAINING NO ASBESTOS AND <1% CRYSTALLINE
SILICA-RESPIRABLE PARTICULATE MATTER)
NUNAVUT:
OEL TWA (MG/M3): 2 MG/M3 (RESPIRABLE FRACTION)
NORTHWEST TERRITORIES:
OEL TWA (MG/M3): 2 MG/M3 (RESPIRABLE FRACTION)
ONTARIO:
OEL TWA (MG/M3):
2 MG/M3 (CONTAINING NO ASBESTOS AND <1% CRYSTALLINE SILICA-RESPIRABLE)
PRINCE EDWARD ISLAND:
OEL TWA (MG/M3):
2 MG/M3 (PARTICULATE MATTER CONTAINING NO ASBESTOS AND <1% CRYSTALLINE
SILICA-RESPIRABLE PARTICULATE MATTER)
QUEBEC:
VEMP (MG/M3): 3 MG/M3 (RESPIRABLE DUST)
SASKATCHEWAN:
OEL TWA (MG/M3): 2 MG/M3 (RESPIRABLE FRACTION)
YUKON:
OEL TWA (MG/M3): 20 MPPCF
2,6-DI-TERT-BUTYL-P-CRESOL (128-37-0):
MEXICO:
OEL TWA (MG/M3): 10 MG/M3
MEXICO:
OEL STEL (MG/M3): 20 MG/M3
USA ACGIH:
ACGIH TWA (MG/M3): 2 MG/M3 (INHALABLE FRACTION AND VAPOR)
USA ACGIH:
ACGIH CHEMICAL CATEGORY: NOT CLASSIFIABLE AS A HUMAN CARCINOGEN
USA NIOSH:
NIOSH REL (TWA) (MG/M3): 10 MG/M3
ALBERTA:
OEL TWA (MG/M3): 10 MG/M3
BRITISH COLUMBIA:
OEL TWA (MG/M3): 2 MG/M3 (AEROSOL, INHALABLE, AND VAPOR)
MANITOBA:
OEL TWA (MG/M3): 2 MG/M3 (INHALABLE FRACTION AND VAPOR)
NEW BRUNSWICK:
OEL TWA (MG/M3): 10 MG/M3
NEWFOUNDLAND & LABRADOR:
OEL TWA (MG/M3): 2 MG/M3 (INHALABLE FRACTION AND VAPOR)
NOVA SCOTIA:
OEL TWA (MG/M3): 2 MG/M3 (INHALABLE FRACTION AND VAPOR)
NUNAVUT:
OEL STEL (MG/M3): 4 MG/M3 (INHALABLE FRACTION AND VAPOR)
NUNAVUT:
OEL TWA (MG/M3): 2 MG/M3 (INHALABLE FRACTION AND VAPOR)
NORTHWEST TERRITORIES:
OEL STEL (MG/M3): 4 MG/M3 (INHALABLE FRACTION AND VAPOR)
NORTHWEST TERRITORIES:
OEL TWA (MG/M3): 2 MG/M3 (INHALABLE FRACTION AND VAPOR)
ONTARIO:
OEL TWA (MG/M3): 2 MG/M3 (INHALABLE FRACTION AND VAPOR)
PRINCE EDWARD ISLAND:
OEL TWA (MG/M3): 2 MG/M3 (INHALABLE FRACTION AND VAPOR)
QUEBEC:
VECD (MG/M3): 10 MG/M3
SASKATCHEWAN:
OEL STEL (MG/M3): 4 MG/M3 (INHALABLE FRACTION AND VAPOR)
SASKATCHEWAN:
OEL TWA (MG/M3): 2 MG/M3 (INHALABLE FRACTION AND VAPOR)
YUKON:
OEL STEL (MG/M3): 20 MG/M3
YUKON:
OEL TWA (MG/M3): 10 MG/M3
1,1,2-TRICHLOROETHANE (79-00-5):
MEXICO:
OEL TWA (MG/M3): 45 MG/M3
MEXICO:
OEL TWA (PPM): 10 PPM
MEXICO:
OEL STEL (MG/M3): 30 MG/M3
MEXICO:
OEL STEL (PPM): 20 PPM
USA ACGIH:
ACGIH TWA (PPM): 10 PPM
USA ACGIH:
ACGIH CHEMICAL CATEGORY:
SKIN - POTENTIAL SIGNIFICANT CONTRIBUTION TO OVERALL EXPOSURE BY THE
CUTANEOUS ROUTE, CONFIRMED ANIMAL CARCINOGEN WITH UNKNOWN RELEVANCE
TO HUMANS
USA OSHA:
OSHA PEL (TWA) (MG/M3): 45 MG/M3
USA OSHA:
OSHA PEL (TWA) (PPM): 10 PPM
USA OSHA:
LIMIT VALUE CATEGORY (OSHA): PREVENT OR REDUCE SKIN ABSORPTION
USA NIOSH:
NIOSH REL (TWA) (MG/M3): 45 MG/M3
USA NIOSH:
NIOSH REL (TWA) (PPM): 10 PPM
USA IDLH:
US IDLH (PPM): 100 PPM
ALBERTA:
OEL TWA (MG/M3): 55 MG/M3
ALBERTA:
OEL TWA (PPM): 10 PPM
BRITISH COLUMBIA:
OEL TWA (PPM): 10 PPM
MANITOBA:
OEL TWA (PPM): 10 PPM
NEW BRUNSWICK:
OEL TWA (MG/M3): 55 MG/M3
NEW BRUNSWICK:
OEL TWA (PPM): 10 PPM
NEWFOUNDLAND & LABRADOR:
OEL TWA (PPM): 10 PPM
NOVA SCOTIA:
OEL TWA (PPM): 10 PPM
NUNAVUT:
OEL STEL (PPM): 15 PPM
NUNAVUT:
OEL TWA (PPM): 10 PPM
NORTHWEST TERRITORIES:
OEL STEL (PPM): 15 PPM
NORTHWEST TERRITORIES:
OEL TWA (PPM): 10 PPM
ONTARIO:
OEL TWA (PPM): 10 PPM
PRINCE EDWARD ISLAND:
OEL TWA (PPM): 10 PPM
QUEBEC:
VEMP (MG/M3): 55 MG/M3
QUEBEC:
VEMP (PPM): 10 PPM
SASKATCHEWAN:
OEL STEL (PPM): 15 PPM
SASKATCHEWAN:
OEL TWA (PPM): 10 PPM
YUKON:
OEL STEL (MG/M3): 90 MG/M3
YUKON:
OEL STEL (PPM): 20 PPM
YUKON:
OEL TWA (MG/M3): 45 MG/M3
YUKON:
OEL TWA (PPM): 10 PPM
CUMENE (98-82-8):
MEXICO:
OEL TWA (MG/M3): 245 MG/M3
MEXICO:
OEL TWA (PPM): 50 PPM
MEXICO:
OEL STEL (MG/M3): 365 MG/M3
MEXICO:
OEL STEL (PPM): 75 PPM
USA ACGIH:
ACGIH TWA (PPM): 50 PPM
USA OSHA:
OSHA PEL (TWA) (MG/M3): 245 MG/M3
USA OSHA:
OSHA PEL (TWA) (PPM): 50 PPM
USA OSHA:
LIMIT VALUE CATEGORY (OSHA): PREVENT OR REDUCE SKIN ABSORPTION
USA NIOSH:
NIOSH REL (TWA) (MG/M3): 245 MG/M3
USA NIOSH:
NIOSH REL (TWA) (PPM): 50 PPM
USA IDLH:
US IDLH (PPM): 900 PPM (10% LEL)
ALBERTA:
OEL TWA (MG/M3): 246 MG/M3
ALBERTA:
OEL TWA (PPM): 50 PPM
BRITISH COLUMBIA:
OEL STEL (PPM): 75 PPM
BRITISH COLUMBIA:
OEL TWA (PPM): 25 PPM
MANITOBA:
OEL TWA (PPM): 50 PPM
NEW BRUNSWICK:
OEL TWA (MG/M3): 246 MG/M3
NEW BRUNSWICK:
OEL TWA (PPM): 50 PPM
NEWFOUNDLAND & LABRADOR:
OEL TWA (PPM): 50 PPM
NOVA SCOTIA:
OEL TWA (PPM): 50 PPM
NUNAVUT:
OEL STEL (PPM): 74 PPM
NUNAVUT:
OEL TWA (PPM): 50 PPM
NORTHWEST TERRITORIES:
OEL STEL (PPM): 74 PPM
NORTHWEST TERRITORIES:
OEL TWA (PPM): 50 PPM
ONTARIO:
OEL TWA (PPM): 50 PPM
PRINCE EDWARD ISLAND:
OEL TWA (PPM): 50 PPM
QUEBEC:
VEMP (MG/M3): 246 MG/M3
QUEBEC:
VEMP (PPM): 50 PPM
SASKATCHEWAN:
OEL STEL (PPM): 74 PPM
SASKATCHEWAN:
OEL TWA (PPM): 50 PPM
YUKON:
OEL STEL (MG/M3): 365 MG/M3
YUKON:
OEL STEL (PPM): 75 PPM
YUKON:
OEL TWA (MG/M3): 245 MG/M3
YUKON:
OEL TWA (PPM): 50 PPM
ACETOPHENONE (98-86-2):
USA ACGIH:
ACGIH TWA (PPM): 10 PPM
USA AIHA:
WEEL TWA (PPM): 10 PPM
ALBERTA:
OEL TWA (MG/M3): 49 MG/M3
ALBERTA:
OEL TWA (PPM): 10 PPM
BRITISH COLUMBIA:
OEL TWA (PPM): 10 PPM
MANITOBA:
OEL TWA (PPM): 10 PPM
NEW BRUNSWICK:
OEL TWA (MG/M3): 49 MG/M3
NEW BRUNSWICK:
OEL TWA (PPM): 10 PPM
NEWFOUNDLAND & LABRADOR:
OEL TWA (PPM): 10 PPM
NOVA SCOTIA:
OEL TWA (PPM): 10 PPM
NUNAVUT:
OEL STEL (PPM): 15 PPM
NUNAVUT:
OEL TWA (PPM): 10 PPM
NORTHWEST TERRITORIES:
OEL STEL (PPM): 15 PPM
NORTHWEST TERRITORIES:
OEL TWA (PPM): 10 PPM
ONTARIO:
OEL TWA (PPM): 10 PPM
PRINCE EDWARD ISLAND:
OEL TWA (PPM): 10 PPM
QUEBEC:
VEMP (MG/M3): 49 MG/M3
QUEBEC:
VEMP (PPM): 10 PPM
SASKATCHEWAN:
OEL STEL (PPM): 15 PPM
SASKATCHEWAN:
OEL TWA (PPM): 10 PPM
EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS AND SAFETY SHOWERS SHOULD BE AVAILABLE IN THE
IMMEDIATE VICINITY OF ANY POTENTIAL EXPOSURE. ENSURE ADEQUATE VENTILATION,
ESPECIALLY IN CONFINED AREAS. GAS DETECTORS SHOULD BE USED WHEN FLAMMABLE
GASES OR VAPORS MAY BE RELEASED. PROPER GROUNDING PROCEDURES TO AVOID
STATIC ELECTRICITY SHOULD BE FOLLOWED. USE EXPLOSION-PROOF EQUIPMENT.
VAPORS MAY BE UNINHIBITED AND POLYMERIZE, CAUSING BLOCKAGE OF VENTS.
ENSURE ALL NATIONAL/LOCAL REGULATIONS ARE OBSERVED.
PERSONAL PROTECTIVE EQUIPMENT:
GLOVES. PROTECTIVE CLOTHING. PROTECTIVE GOGGLES.
INSUFFICIENT VENTILATION: WEAR RESPIRATORY PROTECTION. FACE SHIELD.
MATERIALS FOR PROTECTIVE CLOTHING:
CHEMICALLY RESISTANT MATERIALS AND FABRICS. WEAR FIRE/FLAME
RESISTANT/RETARDANT CLOTHING.
HAND PROTECTION: WEAR PROTECTIVE GLOVES.
EYE PROTECTION: CHEMICAL SAFETY GOGGLES AND FACE SHIELD.
SKIN AND BODY PROTECTION: WEAR SUITABLE PROTECTIVE CLOTHING.
RESPIRATORY PROTECTION:
IF EXPOSURE LIMITS ARE EXCEEDED OR IRRITATION IS EXPERIENCED, APPROVED
RESPIRATORY PROTECTION SHOULD BE WORN. IN CASE OF INADEQUATE VENTILATION,
OXYGEN DEFICIENT ATMOSPHERE, OR WHERE EXPOSURE LEVELS ARE NOT KNOWN WEAR
APPROVED RESPIRATORY PROTECTION.
ENVIRONMENTAL EXPOSURE CONTROLS: AVOID RELEASE TO THE ENVIRONMENT.
OTHER INFORMATION: WHEN USING, DO NOT EAT, DRINK OR SMOKE
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: OFF-WHITE
ODOR: LIKE ACRYLIC
ODOR THRESHOLD: NOT AVAILABLE
PH: NOT AVAILABLE
EVAPORATION RATE: NOT AVAILABLE
MELTING POINT: NOT AVAILABLE
FREEZING POINT: NOT AVAILABLE
BOILING POINT: 100 DEG. C (212 DEG. F)
FLASH POINT: 8.9 DEG. C (48.02 DEG. F) CLOSED CUP
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE
DECOMPOSITION TEMPERATURE: NOT AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE
LOWER FLAMMABLE LIMIT: NOT AVAILABLE
UPPER FLAMMABLE LIMIT: NOT AVAILABLE
VAPOR PRESSURE: NOT AVAILABLE
RELATIVE VAPOR DENSITY AT 20 DEG. C: NOT AVAILABLE
RELATIVE DENSITY: NOT AVAILABLE
SPECIFIC GRAVITY: 0.979 G/CM3
SOLUBILITY: NOT AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE
VISCOSITY: NOT AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
REACTIVITY:
REACTS VIOLENTLY WITH STRONG OXIDIZERS. INCREASED RISK OF FIRE OR
EXPLOSION. THE PRODUCT IS NORMALLY SUPPLIED IN A STABILIZED FORM. IF THE
PERMISSIBLE STORAGE PERIOD AND/OR STORAGE TEMPERATURE IS EXCEEDED, THE
PRODUCT MAY POLYMERIZE WITH HEAT EVOLUTION. POLYMERIZATION WITH HEAT
EVOLUTION MAY OCCUR IN THE PRESENCE OF RADICAL FORMING SUBSTANCES (E.G.
PEROXIDES), REDUCING SUBSTANCES, AND/OR HEAVY METAL IONS. PRODUCT REACTS
VIOLENTLY OR EXPLOSIVELY WITH ALKALI METALS, ALKALINE EARTH METALS, VARIOUS
METAL POWDERS, STRONG ALKALIS, AMMONIA, AND OTHER INCOMPATIBLE MATERIALS.
REACTS VIGOROUSLY WITH WATER PRODUCING HEAT. CONTACT WITH METALS AND WATER
LIBERATES HYDROGEN.
CHEMICAL STABILITY:
EXTREMELY FLAMMABLE LIQUID AND VAPOR. MAY FORM FLAMMABLE OR EXPLOSIVE
VAPOR-AIR MIXTURE. STABILIZED PRODUCT.
POSSIBILITY OF HAZARDOUS REACTIONS:
THIS PRODUCT CONTAINS COMPONENTS THAT UNDERGO HAZARDOUS POLYMERIZATION,
HOWEVER, THEY ARE STABILIZED BY THE OTHER INGREDIENTS. HAZARDOUS
POLYMERIZATION CAN OCCUR IN CONTACT WITH CERTAIN INCOMPATIBLE MATERIALS.
HAZARDOUS POLYMERIZATION MAY OCCUR IF THE SUBSTANCE IS NOT STABILIZED.
HAZARDOUS POLYMERIZATION MAY OCCUR IF EXPOSED TO HIGH TEMPERATURE.
CONDITIONS TO AVOID:
DIRECT SUNLIGHT, EXTREMELY HIGH OR LOW TEMPERATURES, HEAT, HOT SURFACES,
SPARKS, OPEN FLAMES, INCOMPATIBLE MATERIALS, AND OTHER IGNITION SOURCES.
INCOMPATIBLE MATERIALS:
STRONG ACIDS, STRONG BASES, STRONG OXIDIZERS. AMMONIA. ORGANIC PEROXIDES.
PEROXIDES. POLYMERIZATION CATALYSTS. AMINES. ULTRAVIOLET LIGHT. LIGHT.
FREE RADICAL INITIATORS. REDUCING AGENTS. HEAVY METAL IONS. MINERAL ACIDS.
IODIDES. SULFIDES. ISOCYANATES.
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS - PRODUCT:
ACUTE TOXICITY (ORAL): NOT CLASSIFIED
ACUTE TOXICITY (DERMAL): NOT CLASSIFIED
ACUTE TOXICITY (INHALATION): NOT CLASSIFIED
LD50 AND LC50 DATA: NOT AVAILABLE
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
GORILLA WELD CONTAINS METHACRYLIC ACID CAS NO. 79-41-4 WHICH, ACCORDING TO
ANNEX 1, TABLE 3.2.3 OF CLP CARRIES THE H314: CORROSIVE CLASSIFICATION.
PRODUCT LEVEL DERMAL CORROSIVITY TESTING FOR GORILLA WELD CONFIRMS THE
PRODUCT IS CLASSIFIED AS A SKIN IRRITANT RATHER THAN CORROSIVE. POSITIVE
RESULTS IN A VALID AND ACCEPTED SKIN CORROSION TEST (CORROSITEX TEST)
CLASSIFIES THE MIXTURE AS NON-CORROSIVE UTILIZING MULTIPLE REPLICATE
SAMPLES INDICATING HIGHLY REPRODUCIBLE RESULTS. AS A RESULT, THE HEALTH
HAZARD AND TRANSPORT CLASSIFICATION HAVE BEEN CHANGED TO REFLECT THE WELD
RESULTS: UN NON-CORROSIVE AND NOT A GHS CATEGORY 1.
EYE DAMAGE/IRRITATION: CAUSES SERIOUS EYE DAMAGE.
RESPIRATORY OR SKIN SENSITIZATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT CLASSIFIED
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
MAY CAUSE RESPIRATORY IRRITATION.
ASPIRATION HAZARD: NOT CLASSIFIED
SYMPTOMS/INJURIES AFTER INHALATION:
IRRITATION OF THE RESPIRATORY TRACT AND THE OTHER MUCOUS MEMBRANES. MAY BE
CORROSIVE TO THE RESPIRATORY TRACT. SYMPTOMS OF RESPIRATORY COMPLICATIONS
(LUNG EDEMA) MAY OCCUR SEVERAL HOURS AFTER EXPOSURE.
SYMPTOMS/INJURIES AFTER SKIN CONTACT:
CAUSES SEVERE IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION.
SYMPTOMS/INJURIES AFTER EYE CONTACT:
CAUSES PERMANENT DAMAGE TO THE CORNEA, IRIS, OR CONJUNCTIVA.
SYMPTOMS/INJURIES AFTER INGESTION:
INGESTION MAY CAUSE ADVERSE EFFECTS. MAY CAUSE GASTROINTESTINAL IRRITATION.
CHRONIC SYMPTOMS: NONE ANTICIPATED.
INFORMATION ON TOXICOLOGICAL EFFECTS - INGREDIENT(S):
LD50 AND LC50 DATA:
METHYL METHACRYLATE (80-62-6):
LD50 ORAL RAT: 8420 - 10000 MG/KG
LD50 DERMAL RABBIT: 5000 - 7500 MG/KG
LC50 INHALATION RAT: 29 MG/L/4H
LC50 INHALATION RAT: 7093 PPM/4H
METHACRYLIC ACID (79-41-4):
LD50 ORAL RAT: 1060 MG/KG
LD50 DERMAL RABBIT: 500 - 1000 MG/KG
LC50 INHALATION RAT: 7.1 MG/L/4H
ATE US/CA (VAPORS): 7.10 MG/L/4H
CUMENE HYDROPEROXIDE (80-15-9):
LD50 ORAL RAT: 382 MG/KG
LD50 DERMAL RABBIT: 0.126 ML/KG
LC50 INHALATION RAT: 220 PPM/4H
LC50 INHALATION RAT: 1.4 MG/L/4H
ATE US/CA (DERMAL): 1,100.00 MG/KG BODY WEIGHT
ATE US/CA (DUST, MIST): 0.50 MG/L/4H
BENZENESULFONIC ACID, OXYBIS[DODECYL-, DISODIUM SALT (25167-32-2):
LD50 ORAL RAT: 1000 MG/KG
LD50 DERMAL RABBIT: >2000 MG/KG
2,6-DI-TERT-BUTYL-P-CRESOL (128-37-0):
LD50 ORAL RAT: >2930 MG/KG (SPECIES: SPRAGUE-DAWLEY)
LD50 DERMAL RAT: >2000 MG/KG
1,1,2-TRICHLOROETHANE (79-00-5):
LD50 ORAL RAT: 836 MG/KG
LD50 DERMAL RABBIT: 5371 MG/KG
LC50 INHALATION RAT: 2.78 MG/L (EXPOSURE TIME: 8 H)
ATE US/CA (DERMAL): 1,100.00 MG/KG BODY WEIGHT
CUMENE (98-82-8):
LD50 ORAL RAT: 2260 MG/KG
LD50 DERMAL RABBIT: 10000 MG/KG
LC50 INHALATION RAT: 9.83 MG/L/4H
LC50 INHALATION RAT: >3577 PPM (EXPOSURE TIME: 6 H)
ACETOPHENONE (98-86-2):
LD50 ORAL RAT: 900 MG/KG
LD50 DERMAL RABBIT: 1760 MG/KG
METHYL METHACRYLATE (80-62-6):
IARC GROUP 3:
TALC (14807-96-6):
IARC GROUP: 3
NATIONAL TOXICOLOGY PROGRAM (NTP) STATUS: EVIDENCE OF CARCINOGENICITY.
2,6-DI-TERT-BUTYL-P-CRESOL (128-37-0):
IARC GROUP: 3
1,1,2-TRICHLOROETHANE (79-00-5):
IARC GROUP: 3
CUMENE (98-82-8):
IARC GROUP: 2B
NATIONAL TOXICOLOGY PROGRAM (NTP) STATUS:
EVIDENCE OF CARCINOGENICITY, REASONABLY ANTICIPATED TO BE HUMAN CARCINOGEN.
OSHA HAZARD COMMUNICATION CARCINOGEN LIST:
IN OSHA HAZARD COMMUNICATION CARCINOGEN LIST.
| SECTION 12: ECOLOGICAL INFORMATION | |
TOXICITY:
ECOLOGY - GENERAL:
HARMFUL TO AQUATIC LIFE. HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
METHYL METHACRYLATE (80-62-6):
LC50 FISH 1:
243 - 275 MG/L (EXPOSURE TIME: 96 H - SPECIES: PIMEPHALES PROMELAS
[FLOW-THROUGH])
EC50 DAPHNIA 1: 69 MG/L (EXPOSURE TIME: 48 H - SPECIES: DAPHNIA MAGNA)
LC50 FISH 2:
125.5 - 190.7 MG/L (EXPOSURE TIME: 96 H - SPECIES: PIMEPHALES PROMELAS
[STATIC])
METHACRYLIC ACID (79-41-4):
LC50 FISH 1:
85 MG/L (EXPOSURE TIME: 96 H - SPECIES: ONCORHYNCHUS MYKISS[FLOW-THROUGH])
ERC50 (ALGAE): 14 MG/L
NOEC CHRONIC CRUSTACEA: 53 MG/L
CUMENE HYDROPEROXIDE (80-15-9):
LC50 FISH 1:
3.9 MG/L (EXPOSURE TIME: 96 H - SPECIES: ONCORHYNCHUS MYKISS [STATIC])
TALC (14807-96-6):
LC50 FISH 1:
>100 G/L (EXPOSURE TIME: 96 H - SPECIES: BRACHYDANIO RERIO [SEMI-STATIC])
BENZENESULFONIC ACID, OXYBIS[DODECYL-, DISODIUM SALT (25167-32-2):
LC50 FISH 1:
3.85 MG/L (EXPOSURE TIME: 96 H - SPECIES: PIMEPHALES PROMELAS
[FLOW-THROUGH])
EC50 DAPHNIA 1: 3.63 MG/L (EXPOSURE TIME: 48 H - SPECIES: DAPHNIA MAGNA)
LC50 FISH 2:
6.81 MG/L (EXPOSURE TIME: 96 H - SPECIES: LEPOMIS MACROCHIRUS [STATIC])
2,6-DI-TERT-BUTYL-P-CRESOL (128-37-0):
EC50 DAPHNIA 1: 0.48 MG/L (EXPOSURE TIME: 48 H - SPECIES: DAPHNIA MAGNA)
EC50 OTHER AQUATIC ORGANISMS 2:
0.43 MG/L (EXPOSURE TIME: 72 H - SPECIES: DESMODESMUS SUBSPICATUS)
1,1,2-TRICHLOROETHANE (79-00-5):
LC50 FISH 1:
81.6 MG/L (EXPOSURE TIME: 96 H - SPECIES: PIMEPHALES PROMELAS
[FLOW-THROUGH])
EC50 DAPHNIA 1: 18 MG/L (EXPOSURE TIME: 48 H - SPECIES: DAPHNIA MAGNA)
LC50 FISH 2:
35 - 47 MG/L (EXPOSURE TIME: 96 H - SPECIES: LEPOMIS MACROCHIRUS [STATIC])
EC50 DAPHNIA 2:
57 - 110 MG/L (EXPOSURE TIME: 48 H - SPECIES: DAPHNIA MAGNA [STATIC])
CUMENE (98-82-8):
LC50 FISH 1:
6.04 - 6.61 MG/L (EXPOSURE TIME: 96 H - SPECIES: PIMEPHALES PROMELAS
[FLOW-THROUGH])
LC50 FISH 2:
4.8 MG/L (EXPOSURE TIME: 96 H - SPECIES: ONCORHYNCHUS MYKISS
[FLOW-THROUGH])
EC50 DAPHNIA 2:
7.9 - 14.1 MG/L (EXPOSURE TIME: 48 H - SPECIES: DAPHNIA MAGNA [STATIC])
NOEC CHRONIC CRUSTACEA: 0.35 MG/L
NOEC CHRONIC ALGAE: 0.22 MG/L
ACETOPHENONE (98-86-2):
LC50 FISH 1:
162 MG/L (EXPOSURE TIME: 96 H - SPECIES: PIMEPHALES PROMELAS
[FLOW-THROUGH])
LC50 FISH 2:
155 MG/L (EXPOSURE TIME: 96 H - SPECIES: PIMEPHALES PROMELAS [STATIC])
PERSISTENCE AND DEGRADABILITY:
GORILLA WELD RESIN:
PERSISTENCE AND DEGRADABILITY:
MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE ENVIRONMENT.
BIOACCUMULATIVE POTENTIAL:
GORILLA WELD RESIN:
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
METHYL METHACRYLATE (80-62-6):
LOG POW: 0.7
METHACRYLIC ACID (79-41-4):
LOG POW: 0.93
CUMENE HYDROPEROXIDE (80-15-9):
BCF FISH 1: 35.5
TALC (14807-96-6):
BCF FISH 1: (NO KNOWN BIOACCUMULATION)
2,6-DI-TERT-BUTYL-P-CRESOL (128-37-0):
BCF FISH 1: 230 - 2500
LOG POW: 4.17
1,1,2-TRICHLOROETHANE (79-00-5):
BCF FISH 1: 0.7 - 6.7
LOG POW: 1.89
CUMENE (98-82-8):
BCF FISH 1: 35.5
LOG POW: 3.7
ACETOPHENONE (98-86-2):
LOG POW: 1.7
MOBILITY IN SOIL: NOT AVAILABLE
OTHER ADVERSE EFFECTS:
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL, NATIONAL,
TERRITORIAL, PROVINCIAL, AND INTERNATIONAL REGULATIONS
ADDITIONAL INFORMATION:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE. DO
NOT PRESSURIZE, CUT, OR WELD CONTAINERS.
ECOLOGY - WASTE MATERIALS:
AVOID RELEASE TO THE ENVIRONMENT. THIS MATERIAL IS HAZARDOUS TO THE AQUATIC
ENVIRONMENT. KEEP OUT OF SEWERS AND WATERWAYS.
| SECTION 14: TRANSPORT INFORMATION | |
THE SHIPPING DESCRIPTION(S) STATED HEREIN WERE PREPARED IN ACCORDANCE WITH
CERTAIN ASSUMPTIONS AT THE TIME THE SDS WAS AUTHORED, AND CAN VARY BASED ON
A NUMBER OF VARIABLES THAT MAY OR MAY NOT HAVE BEEN KNOWN AT THE TIME THE
SDS WAS ISSUED.
IN ACCORDANCE WITH DOT:
PROPER SHIPPING NAME: FLAMMABLE LIQUID, N.O.S. (METHYL METHACRYLATE)
HAZARD CLASS: 3
IDENTIFICATION NUMBER: UN1993
LABEL CODES: 3
PACKING GROUP: II
ERG NUMBER: 128
FLAMMABLE LIQUID, CLASS/DIVISION 3.1, 3.2, 3.3
IN ACCORDANCE WITH IMDG:
PROPER SHIPPING NAME: FLAMMABLE LIQUID, N.O.S. (METHYL METHACRYLATE)
HAZARD CLASS: 3
IDENTIFICATION NUMBER: UN1993
LABEL CODES: 3
PACKING GROUP: II
EMS-NO. (FIRE): F-E
EMS-NO. (SPILLAGE): S-E
CLASS 3 - FLAMMABLE LIQUIDS
IN ACCORDANCE WITH IATA:
PROPER SHIPPING NAME: FLAMMABLE LIQUID, N.O.S. (METHYL METHACRYLATE)
IDENTIFICATION NUMBER: 3
HAZARD CLASS: UN1993
LABEL CODES: 3
PACKING GROUP: II
ERG CODE (IATA): 3L
CLASS 3, FLAMMABLE LIQUIDS
IN ACCORDANCE WITH TDG:
PROPER SHIPPING NAME: FLAMMABLE LIQUID, N.O.S. (METHYL METHACRYLATE)
HAZARD CLASS: 3
IDENTIFICATION NUMBER: UN1993
LABEL CODES: 3
PACKING GROUP: II
CLASS 3, FLAMMABLE LIQUIDS
| SECTION 15: REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
GORILLA WELD RESIN:
SARA SECTION 311/312 HAZARD CLASSES:
FIRE HAZARD
IMMEDIATE (ACUTE) HEALTH HAZARD
REACTIVE HAZARD
METHYL METHACRYLATE (80-62-6):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
SUBJECT TO REPORTING REQUIREMENTS OF UNITED STATES SARA SECTION 313
EPA TSCA REGULATORY FLAG:
T - T - INDICATES A SUBSTANCE THAT IS THE SUBJECT OF A SECTION 4 TEST RULE
UNDER TSCA
CERCLA RQ: 1000 LB
SARA SECTION 313 - EMISSION REPORTING: 1.0%
METHACRYLIC ACID (79-41-4):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
2-PROPENOIC ACID, 2-METHYL-, METHYL ESTER, POLYMER WITH 1,3-BUTADIENE AND
ETHENYLBENZENE (25053-09-2):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
EPA TSCA REGULATORY FLAG:
XU - XU - INDICATES A SUBSTANCE EXEMPT FROM REPORTING UNDER THE INVENTORY
UPDATE REPORTING RULE, I.E, PARTIAL UPDATING OF THE TSCA INVENTORY DATA
BASE PRODUCTION AND SITE REPORTS (40 CFR 710(C))
2-PROPENOIC ACID, 2-METHYL-, PHOSPHINICOBIS(OXY-2,1-ETHANEDIYL) ESTER
(32435-46-4):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
CUMENE HYDROPEROXIDE (80-15-9):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
SUBJECT TO REPORTING REQUIREMENTS OF UNITED STATES SARA SECTION 313
CERCLA RQ: 10 LB
SARA SECTION 313 - EMISSION REPORTING: 1.0%
TALC (14807-96-6):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
BENZENESULFONIC ACID, OXYBIS[DODECYL-, DISODIUM SALT (25167-32-2):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
2,6-DI-TERT-BUTYL-P-CRESOL (128-37-0):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
1,1,2-TRICHLOROETHANE (79-00-5):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
SUBJECT TO REPORTING REQUIREMENTS OF UNITED STATES SARA SECTION 313
CERCLA RQ: 100 LB
SARA SECTION 313 - EMISSION REPORTING: 1.0%
CUMENE (98-82-8):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
SUBJECT TO REPORTING REQUIREMENTS OF UNITED STATES SARA SECTION 313
CERCLA RQ: 5000 LB
SARA SECTION 313 - EMISSION REPORTING: 1.0%
ACETOPHENONE (98-86-2):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
SUBJECT TO REPORTING REQUIREMENTS OF UNITED STATES SARA SECTION 313
EPA TSCA REGULATORY FLAG:
T - T - INDICATES A SUBSTANCE THAT IS THE SUBJECT OF A SECTION 4 TEST RULE
UNDER TSCA
CERCLA RQ: 5000 LB
SARA SECTION 313 - EMISSION REPORTING: 1.0%
US STATE REGULATIONS:
1,1,2-TRICHLOROETHANE (79-00-5):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST:
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
CUMENE (98-82-8):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST:
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
METHYL METHACRYLATE (80-62-6):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - ENVIRONMENTAL HAZARD LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
METHACRYLIC ACID (79-41-4):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
CUMENE HYDROPEROXIDE (80-15-9):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - ENVIRONMENTAL HAZARD LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
TALC (14807-96-6):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
2,6-DI-TERT-BUTYL-P-CRESOL (128-37-0):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
1,1,2-TRICHLOROETHANE (79-00-5):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - ENVIRONMENTAL HAZARD LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
CUMENE (98-82-8):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - ENVIRONMENTAL HAZARD LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
ACETOPHENONE (98-86-2):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - ENVIRONMENTAL HAZARD LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
CANADIAN REGULATIONS:
METHYL METHACRYLATE (80-62-6):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
METHACRYLIC ACID (79-41-4):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
2-PROPENOIC ACID, 2-METHYL-, METHYL ESTER, POLYMER WITH 1,3-BUTADIENE AND
ETHENYLBENZENE (25053-09-2):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
2-PROPENOIC ACID, 2-METHYL-, PHOSPHINICOBIS(OXY-2,1-ETHANEDIYL) ESTER
(32435-46-4): LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
CUMENE HYDROPEROXIDE (80-15-9):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
TALC (14807-96-6):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
BENZENESULFONIC ACID, OXYBIS[DODECYL-, DISODIUM SALT (25167-32-2):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
2,6-DI-TERT-BUTYL-P-CRESOL (128-37-0):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
1,1,2-TRICHLOROETHANE (79-00-5):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
CUMENE (98-82-8): LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
ACETOPHENONE (98-86-2):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
| SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION | |
OR LAST REVISION
REVISION DATE: 01/20/2017
OTHER INFORMATION:
THIS DOCUMENT HAS BEEN PREPARED IN ACCORDANCE WITH THE SDS REQUIREMENTS OF
THE OSHA HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200 AND CANADA'S
HAZARDOUS PRODUCTS REGULATIONS (HPR).
GHS FULL TEXT PHRASES:
ACUTE TOX. 3 (DERMAL): ACUTE TOXICITY (DERMAL) CATEGORY 3
ACUTE TOX. 3 (INHALATION: DUST, MIST):
ACUTE TOXICITY (INHALATION: DUST, MIST) CATEGORY 3
ACUTE TOX. 3 (INHALATION: VAPOR):
ACUTE TOXICITY (INHALATION: VAPOR) CATEGORY 3
ACUTE TOX. 4 (DERMAL): ACUTE TOXICITY (DERMAL) CATEGORY 4
ACUTE TOX. 4 (INHALATION: DUST, MIST):
ACUTE TOXICITY (INHALATION: DUST, MIST) CATEGORY 4
ACUTE TOX. 4 (ORAL): ACUTE TOXICITY (ORAL) CATEGORY 4
AQUATIC ACUTE 1:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD CATEGORY 1
AQUATIC ACUTE 2:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD CATEGORY 2
AQUATIC ACUTE 3:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD CATEGORY 3
AQUATIC CHRONIC 1:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - CHRONIC HAZARD CATEGORY 1
AQUATIC CHRONIC 2:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - CHRONIC HAZARD CATEGORY 2
AQUATIC CHRONIC 3:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - CHRONIC HAZARD CATEGORY 3
ASP. TOX. 1: ASPIRATION HAZARD CATEGORY 1
CARC. 2: CARCINOGENICITY CATEGORY 2
COMB. DUST: COMBUSTIBLE DUST
EYE DAM. 1: SERIOUS EYE DAMAGE/EYE IRRITATION CATEGORY 1
EYE IRRIT. 2A: SERIOUS EYE DAMAGE/EYE IRRITATION CATEGORY 2A
EYE IRRIT. 2B: SERIOUS EYE DAMAGE/EYE IRRITATION CATEGORY 2B
FLAM. LIQ. 2: FLAMMABLE LIQUIDS CATEGORY 2
FLAM. LIQ. 3: FLAMMABLE LIQUIDS CATEGORY 3
FLAM. LIQ. 4: FLAMMABLE LIQUIDS CATEGORY 4
ORG. PEROX. E: ORGANIC PEROXIDE CATEGORY E
SKIN CORR. 1A: SKIN CORROSION/IRRITATION CATEGORY 1A
SKIN CORR. 1B: SKIN CORROSION/IRRITATION CATEGORY 1B
SKIN IRRIT. 2: SKIN CORROSION/IRRITATION CATEGORY 2
SKIN SENS. 1: SKIN SENSITIZATION CATEGORY 1
STOT RE 2: SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) CATEGORY 2
STOT SE 3: SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CATEGORY 3
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR
H226: FLAMMABLE LIQUID AND VAPOR
H227: COMBUSTIBLE LIQUID
H242: HEATING MAY CAUSE A FIRE
H302: HARMFUL IF SWALLOWED
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS
H311: TOXIC IN CONTACT WITH SKIN
H312: HARMFUL IN CONTACT WITH SKIN
H315: CAUSES SKIN IRRITATION
H317: MAY CAUSE AN ALLERGIC SKIN REACTION
H318: CAUSES SERIOUS EYE DAMAGE
H319: CAUSES SERIOUS EYE IRRITATION
H320: CAUSES EYE IRRITATION
H331: TOXIC IF INHALED
H332: HARMFUL IF INHALED
H335: MAY CAUSE RESPIRATORY IRRITATION
H350: MAY CAUSE CANCER
H351: SUSPECTED OF CAUSING CANCER
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE
H400: VERY TOXIC TO AQUATIC LIFE
H401: TOXIC TO AQUATIC LIFE
H402: HARMFUL TO AQUATIC LIFE
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
H411: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS
THE INFORMATION PRESENTED IN THIS SAFETY DATA SHEET WAS PREPARED BY
QUALIFIED PERSONNEL AND TO THE BEST OF OUR KNOWLEDGE IS TRUE AND ACCURATE.
THE INFORMATION AND RECOMMENDATIONS ARE FURNISHED FOR THIS PRODUCT WITH THE
UNDERSTANDING THAT THE PURCHASER WILL INDEPENDENTLY DETERMINE THE
SUITABILITY OF THE PRODUCT FOR THIS PURPOSE. THIS DATA DOES NOT CONSTITUTE
A WARRANTY, EXPRESSED OR IMPLIED, STATUTORY OR OTHERWISE, NOR IS IT
REPRESENTATION FOR WHICH THE GORILLA GLUE COMPANY ASSUMES LEGAL
RESPONSIBILITY. THE DATA IS SUBMITTED FOR THE USER'S INFORMATION AND
CONSIDERATION ONLY. ANY USE OF THIS PRODUCT MUST BE DETERMINED BY THE USER
TO BE IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE, PROVINCIAL AND LOCAL
LAWS AND REGULATIONS.
GORILLA GLUE NA GHS SDS 2015
GORILLA
INCREDIBLY STRONG
100% TOUGH
SAFETY DATA SHEET
GORILLA WELD - HARDENER
DATE REVISED: 01/24/2017
DATE ISSUED: 01/24/2017
VERSION 1.0
FOR CHEMICAL EMERGENCY:
DURING BUSINESS HOURS: (800) 966-3458
OUTSIDE BUSINESS HOURS: (800) 420-7186
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS AND ACCORDING TO THE HAZARDOUS PRODUCTS REGULATION
(FEBRUARY 11, 2015).
| SECTION 1: IDENTIFICATION | |
PRODUCT IDENTIFIER:
PRODUCT FORM: MIXTURE
PRODUCT NAME: GORILLA WELD - HARDENER
INTENDED USE OF THE PRODUCT: ADHESIVE
NAME, ADDRESS, AND TELEPHONE OF THE RESPONSIBLE PARTY:
COMPANY:
THE GORILLA GLUE COMPANY
2101 E. KEMPER ROAD
CINCINNATI, OHIO 45241
513-271-3300
WWW.GORILLATOUGH.COM
EMERGENCY TELEPHONE NUMBER
EMERGENCY NUMBER: 1-800-420-7186 (PROSAR)
| SECTION 2: HAZARDS IDENTIFICATION | |
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-US/CA CLASSIFICATION:
FLAM. LIQ. 2: H225
SKIN IRRIT. 2: H315
EYE IRRIT. 2A: H319
SKIN SENS. 1: H317
STOT SE 3: H335
AQUATIC ACUTE 3: H402
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
LABEL ELEMENTS:
GHS-US/CA LABELING:
HAZARD PICTOGRAMS (GHS-US/CA):
GHS02: FLAME
GHS07: EXCLAMATION MARK
SIGNAL WORD (GHS-US/CA): DANGER
HAZARD STATEMENTS (GHS-US/CA):
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR.
H315: CAUSES SKIN IRRITATION.
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H319: CAUSES SERIOUS EYE IRRITATION.
H335: MAY CAUSE RESPIRATORY IRRITATION.
H402: HARMFUL TO AQUATIC LIFE.
PRECAUTIONARY STATEMENTS (GHS-US/CA):
P102: KEEP OUT OF REACH OF CHILDREN.
P210:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING.
P261: AVOID BREATHING VAPORS, MIST, OR SPRAY.
P280: WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, AND EYE PROTECTION.
P303+P361+P353:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P370+P378:
IN CASE OF FIRE: USE APPROPRIATE MEDIA (SEE SECTION 5) TO EXTINGUISH.
OTHER HAZARDS: NONE KNOWN
UNKNOWN ACUTE TOXICITY (GHS-US/CA): NO DATA AVAILABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURE:
NAME PRODUCT IDENTIFIER % * GHS INGREDIENT
CLASSIFICATION
METHYL METHACRYLATE (CAS NO) 80-62-6 60-100 FLAM. LIQ. 2, H225
SKIN IRRIT. 2, H315
EYE IRRIT. 2B, H320
SKIN SENS. 1, H317
STOT SE 3, H335
AQUATIC ACUTE 3, H402
2-PROPENOIC ACID, (CAS NO) 25053-09-2 5-10 SKIN IRRIT. 2, H315
2-METHYL-, METHYL EYE IRRIT. 2A, H319
ESTER, POLYMER WITH SKIN SENS. 1, H317
1,3-BUTADIENE AND
ETHENYLBENZENE
PYRIDINE, 3,5- (CAS NO) 34562-31-7 1-5 ACUTE TOX. 4 (ORAL),
DIETHYL-1,2- H302
DIHYDRO-1-PHENYL- ACUTE TOX. 4 (DERMAL),
2-PROPYL- H312
SKIN IRRIT. 2, H315
EYE IRRIT. 2A, H319
STOT SE 3, H335
SILICA, AMORPHOUS, (CAS NO) 112945-52-5 0.1-1 NOT CLASSIFIED
FUMED,
CRYSTALLINE-FREE
2,6-DI-TERT-BUTYL- (CAS NO) 128-37-0 0.1-1 AQUATIC ACUTE 1, H400
P-CRESOL AQUATIC CHRONIC 1, H410
BENZENESULFONIC (CAS NO) 25167-32-2 0.1-1 ACUTE TOX. 4 (ORAL),
ACID, H302
OXYBIS[DODECYL-, EYE DAM. 1, H318
DISODIUM SALT AQUATIC ACUTE 2, H401
AQUATIC CHRONIC 2, H411
TALC (CAS NO) 14807-96-6 <0.1 NOT CLASSIFIED
N-BUTYL ACRYLATE (CAS NO) 141-32-2 <0.1 FLAM. LIQ. 3, H226
ACUTE TOX. 4
(INHALATION: VAPOR),
H332
SKIN IRRIT. 2, H315
EYE IRRIT. 2A, H319
SKIN SENS. 1, H317
STOT SE 3, H335
AQUATIC ACUTE 2, H401
AQUATIC CHRONIC 3, H412
COPPER(II) 8-HY- (CAS NO) 10380-28-6 <0.1 ACUTE TOX. 4 (ORAL),
DROXYQUINOLINATE H302
ACUTE TOX. 3
(INHALATION: DUST,
MIST), H331
SKIN IRRIT. 2, H315
EYE IRRIT. 2A, H319
AQUATIC ACUTE 1, H400
4-VINYLCYCLOHEXENE (CAS NO) 100-40-3 <0.1 FLAM. LIQ. 2, H225
SKIN IRRIT. 2, H315
CARC. 2, H351
REPR. 2, H361
ASP. TOX. 1, H304
AQUATIC ACUTE 2, H401
AQUATIC CHRONIC 3, H412
ETHANOLAMINE (CAS NO) 141-43-5 <0.1 FLAM. LIQ. 4, H227
ACUTE TOX. 4 (ORAL),
H302
ACUTE TOX. 4 (DERMAL),
H312
ACUTE TOX. 4
(INHALATION: VAPOR),
H332
SKIN CORR. 1B, H314
EYE DAM. 1, H318
STOT SE 3, H335
AQUATIC ACUTE 2, H401
AQUATIC CHRONIC 3, H412
DIETHANOLAMINE (CAS NO) 111-42-2 <0.1 ACUTE TOX. 4 (ORAL),
H302
SKIN IRRIT. 2, H315
EYE DAM. 1, H318
STOT RE 2, H373
AQUATIC ACUTE 2, H401
AQUATIC CHRONIC 3, H412
FULL TEXT OF H-PHRASES: SEE SECTION 16
*PERCENTAGES ARE LISTED IN WEIGHT BY WEIGHT PERCENTAGE (W/W%) FOR LIQUID
AND SOLID INGREDIENTS. GAS INGREDIENTS ARE LISTED IN VOLUME BY VOLUME
PERCENTAGE (V/V%).
| SECTION 4: FIRST AID MEASURES | |
DESCRIPTION OF FIRST-AID MEASURES:
GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF YOU FEEL UNWELL,
SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
INHALATION:
WHEN SYMPTOMS OCCUR:
GO INTO OPEN AIR AND VENTILATE SUSPECTED AREA. OBTAIN MEDICAL ATTENTION IF
BREATHING DIFFICULTY PERSISTS.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING. DRENCH AFFECTED AREA WITH WATER FOR AT LEAST
15 MINUTES. OBTAIN MEDICAL ATTENTION IF IRRITATION DEVELOPS OR PERSISTS.
EYE CONTACT:
RINSE CAUTIOUSLY WITH WATER FOR AT LEAST 15 MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING. OBTAIN MEDICAL ATTENTION.
INGESTION: RINSE MOUTH. DO NOT INDUCE VOMITING. OBTAIN MEDICAL ATTENTION.
MOST IMPORTANT SYMPTOMS AND EFFECTS BOTH ACUTE AND DELAYED:
GENERAL:
CAUSES SERIOUS EYE IRRITATION. CAUSES SKIN IRRITATION. MAY CAUSE
RESPIRATORY IRRITATION. SKIN SENSITIZATION.
INHALATION:
IRRITATION OF THE RESPIRATORY TRACT AND THE OTHER MUCOUS MEMBRANES.
SKIN CONTACT:
REDNESS, PAIN, SWELLING, ITCHING, BURNING, DRYNESS, AND DERMATITIS. MAY
CAUSE AN ALLERGIC SKIN REACTION.
EYE CONTACT:
CONTACT CAUSES SEVERE IRRITATION WITH REDNESS AND SWELLING OF THE
CONJUNCTIVA.
INGESTION: INGESTION MAY CAUSE ADVERSE EFFECTS.
CHRONIC SYMPTOMS: NONE KNOWN.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
IF EXPOSED OR CONCERNED, GET MEDICAL ADVICE AND ATTENTION. IF MEDICAL
ADVICE IS NEEDED, HAVE PRODUCT CONTAINER OR LABEL AT HAND.
| SECTION 5: FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
DRY CHEMICAL POWDER, ALCOHOL-RESISTANT FOAM, CARBON DIOXIDE (CO2). WATER
MAY BE INEFFECTIVE BUT WATER SHOULD BE USED TO KEEP FIRE-EXPOSED CONTAINER
COOL.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE A HEAVY WATER STREAM. A HEAVY WATER STREAM MAY SPREAD BURNING
LIQUID.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
FIRE HAZARD: HIGHLY FLAMMABLE LIQUID AND VAPOR.
EXPLOSION HAZARD:
MAY FORM FLAMMABLE OR EXPLOSIVE VAPOR-AIR MIXTURE. WHEN MIXED WITH AIR AND
EXPOSED TO AN IGNITION SOURCE, FLAMMABLE VAPORS CAN BURN IN THE OPEN OR
EXPLODE IN CONFINED SPACES. BEING HEAVIER THAN AIR, VAPORS MAY TRAVEL LONG
DISTANCES TO AN IGNITION SOURCE AND FLASH BACK. RUNOFF TO SEWER MAY CAUSE
FIRE OR EXPLOSION HAZARD.
REACTIVITY:
REACTS VIOLENTLY WITH STRONG OXIDIZERS. INCREASED RISK OF FIRE OR
EXPLOSION. THE PRODUCT IS NORMALLY SUPPLIED IN A STABILIZED FORM. IF THE
PERMISSIBLE STORAGE PERIOD AND/OR STORAGE TEMPERATURE IS EXCEEDED, THE
PRODUCT MAY POLYMERIZE WITH HEAT EVOLUTION. POLYMERIZATION WITH HEAT
EVOLUTION MAY OCCUR IN THE PRESENCE OF RADICAL FORMING SUBSTANCES (E.G.
PEROXIDES), REDUCING SUBSTANCES, AND/OR HEAVY METAL IONS. PRODUCT REACTS
VIOLENTLY OR EXPLOSIVELY WITH ALKALI METALS, ALKALINE EARTH METALS, VARIOUS
METAL POWDERS, STRONG ALKALIS, AMMONIA, AND OTHER INCOMPATIBLE MATERIALS.
ADVICE FOR FIREFIGHTERS:
PRECAUTIONARY MEASURES FIRE:
EXERCISE CAUTION WHEN FIGHTING ANY CHEMICAL FIRE.
FIREFIGHTING INSTRUCTIONS:
REMOVE CONTAINERS FROM FIRE AREA IF THIS CAN BE DONE WITHOUT RISK. USE
WATER SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS. DO NOT GET WATER INSIDE
CONTAINERS. IN CASE OF MAJOR FIRE AND LARGE QUANTITIES: EVACUATE AREA.
FIGHT FIRE REMOTELY DUE TO THE RISK OF EXPLOSION.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
HAZARDOUS COMBUSTION PRODUCTS:
THERMAL DECOMPOSITION GENERATES: CARBON OXIDES (CO, CO2). NITROGEN OXIDES.
ACRYLATES. METHYL METHACRYLATE. AMINES.
OTHER INFORMATION:
CONTAINS METHYL METHACRYLATE, WHEN HEATED THIS PRODUCT MAY UNDERGO
HAZARDOUS POLYMERIZATION, INCREASING FIRE INTENSITY. DO NOT ALLOW RUN-OFF
FROM FIREFIGHTING TO ENTER DRAINS OR WATER COURSES.
REFERENCE TO OTHER SECTIONS:
REFER TO SECTION 9 FOR FLAMMABILITY PROPERTIES.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
AVOID BREATHING (VAPOR, MIST, SPRAY). DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES, AND OTHER
IGNITION SOURCES. NO SMOKING. USE SPECIAL CARE TO AVOID STATIC ELECTRIC
CHARGES.
FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT: USE APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (PPE).
EMERGENCY PROCEDURES:
EVACUATE UNNECESSARY PERSONNEL. STOP LEAK IF SAFE TO DO SO.
FOR EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT: EQUIP CLEANUP CREW WITH PROPER PROTECTION.
EMERGENCY PROCEDURES:
VENTILATE AREA. ELIMINATE IGNITION SOURCES. EVACUATE UNNECESSARY PERSONNEL.
UPON ARRIVAL AT THE SCENE, A FIRST RESPONDER IS EXPECTED TO RECOGNIZE THE
PRESENCE OF DANGEROUS GOODS, PROTECT ONESELF AND THE PUBLIC, SECURE THE
AREA, AND CALL FOR THE ASSISTANCE OF TRAINED PERSONNEL AS SOON AS
CONDITIONS PERMIT.
ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY TO SEWERS AND PUBLIC WATERS. AVOID RELEASE TO THE
ENVIRONMENT.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
FOR CONTAINMENT:
CONTAIN ANY SPILLS WITH DIKES OR ABSORBENTS TO PREVENT MIGRATION AND ENTRY
INTO SEWERS OR STREAMS. AS AN IMMEDIATE PRECAUTIONARY MEASURE, ISOLATE
SPILL OR LEAK AREA IN ALL DIRECTIONS.
METHODS FOR CLEANING UP:
CLEAN UP SPILLS IMMEDIATELY AND DISPOSE OF WASTE SAFELY. ELIMINATE ALL
IGNITION SOURCES. ABSORB AND/OR CONTAIN SPILL WITH INERT MATERIAL. DO NOT
TAKE UP IN COMBUSTIBLE MATERIAL SUCH AS: SAW DUST OR CELLULOSIC MATERIAL.
TRANSFER SPILLED MATERIAL TO A SUITABLE CONTAINER FOR DISPOSAL. USE ONLY
NON-SPARKING TOOLS. TAKE UP LARGE SPILLS WITH PUMP OR VACUUM. USE WATER
SPRAY TO DISPERSE VAPORS. CONTACT COMPETENT AUTHORITIES AFTER A SPILL.
REFERENCE TO OTHER SECTIONS:
SEE SECTION 8 FOR EXPOSURE CONTROLS AND PERSONAL PROTECTION AND SECTION 13
FOR DISPOSAL CONSIDERATIONS.
| SECTION 7: HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
ADDITIONAL HAZARDS WHEN PROCESSED:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
THIS PRODUCT IS STABILIZED WITH INHIBITORS. IF USED, STORED, AND
TRANSPORTED ACCORDING TO DIRECTIONS, HAZARDOUS POLYMERIZATION WILL NOT
OCCUR. CONTAINS METHACRYLATE COMPOUNDS THAT IF UNINHIBITED, OR IF THE
INHIBITOR IS LOST CAN UNDERGO HAZARDOUS POLYMERIZATION UNDER CERTAIN
CONDITIONS INCLUDING ELEVATED TEMPERATURES, WHEN EXPOSED TO STRONG
OXIDIZERS OR OTHER CONTAMINANTS, INCOMPATIBLE MATERIALS (SEE SECTION 10),
OR UV LIGHT. VAPORS MAY BE UNINHIBITED AND POLYMERIZE, CAUSING BLOCKAGE OF
VENTS.
PRECAUTIONS FOR SAFE HANDLING:
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK. AVOID BREATHING VAPORS, MIST,
AND SPRAY. AVOID CONTACT WITH SKIN, EYES AND CLOTHING. TAKE PRECAUTIONARY
MEASURES AGAINST STATIC DISCHARGE. USE ONLY NON-SPARKING TOOLS.
HYGIENE MEASURES:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PROCEDURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES:
COMPLY WITH APPLICABLE REGULATIONS. TAKE ACTION TO PREVENT STATIC
DISCHARGES. GROUND AND BOND CONTAINER AND RECEIVING EQUIPMENT. USE
EXPLOSION-PROOF ELECTRICAL, VENTILATING, AND LIGHTING EQUIPMENT.
STORAGE CONDITIONS:
STORE IN A DRY, COOL AND WELL-VENTILATED PLACE. CONTAINERS WHICH ARE OPENED
SHOULD BE PROPERLY RESEALED AND KEPT UPRIGHT TO PREVENT LEAKAGE. KEEP/STORE
AWAY FROM DIRECT SUNLIGHT, EXTREMELY HIGH OR LOW TEMPERATURES AND
INCOMPATIBLE MATERIALS. STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER
TIGHTLY CLOSED. KEEP IN FIREPROOF PLACE. STORE IN ORIGINAL CONTAINER.
INCOMPATIBLE MATERIALS:
STRONG ACIDS, STRONG BASES, STRONG OXIDIZERS. FREE RADICAL INITIATORS.
PEROXIDES. REDUCING AGENTS. HEAVY METAL IONS. ALKALI METALS. ALKALINE
EARTH METALS. VARIOUS METAL POWDERS. STRONG ALKALIS. AMMONIA.
SPECIFIC END USE(S): ADHESIVE
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
FOR SUBSTANCES LISTED IN SECTION 3 THAT ARE NOT LISTED HERE, THERE ARE NO
ESTABLISHED EXPOSURE LIMITS FROM THE MANUFACTURER, SUPPLIER, IMPORTER, OR
THE APPROPRIATE ADVISORY AGENCY INCLUDING:
ACGIH (TLV), AIHA (WEEL), NIOSH (REL), OSHA (PEL), CANADIAN PROVINCIAL
GOVERNMENTS, OR THE MEXICAN GOVERNMENT.
2,6-DI-TERT-BUTYL-P-CRESOL (128-37-0):
MEXICO:
OEL TWA (MG/M3): 10 MG/M3
MEXICO:
OEL STEL (MG/M3): 20 MG/M3
USA ACGIH:
ACGIH TWA (MG/M3): 2 MG/M3 (INHALABLE FRACTION AND VAPOR)
USA ACGIH:
ACGIH CHEMICAL CATEGORY: NOT CLASSIFIABLE AS A HUMAN CARCINOGEN
USA NIOSH:
NIOSH REL (TWA) (MG/M3): 10 MG/M3
ALBERTA:
OEL TWA (MG/M3): 10 MG/M3
BRITISH COLUMBIA:
OEL TWA (MG/M3): 2 MG/M3 (AEROSOL, INHALABLE, AND VAPOUR)
MANITOBA:
OEL TWA (MG/M3): 2 MG/M3 (INHALABLE FRACTION AND VAPOR)
NEW BRUNSWICK:
OEL TWA (MG/M3): 10 MG/M3
NEWFOUNDLAND & LABRADOR:
OEL TWA (MG/M3): 2 MG/M3 (INHALABLE FRACTION AND VAPOR)
NOVA SCOTIA:
OEL TWA (MG/M3): 2 MG/M3 (INHALABLE FRACTION AND VAPOR)
NUNAVUT:
OEL STEL (MG/M3): 4 MG/M3 (INHALABLE FRACTION AND VAPOUR)
NUNAVUT:
OEL TWA (MG/M3): 2 MG/M3 (INHALABLE FRACTION AND VAPOUR)
NORTHWEST TERRITORIES:
OEL STEL (MG/M3): 4 MG/M3 (INHALABLE FRACTION AND VAPOUR)
NORTHWEST TERRITORIES:
OEL TWA (MG/M3): 2 MG/M3 (INHALABLE FRACTION AND VAPOUR)
ONTARIO:
OEL TWA (MG/M3): 2 MG/M3 (INHALABLE FRACTION AND VAPOR)
PRINCE EDWARD ISLAND:
OEL TWA (MG/M3): 2 MG/M3 (INHALABLE FRACTION AND VAPOR)
QUEBEC:
VECD (MG/M3): 10 MG/M3
SASKATCHEWAN:
OEL STEL (MG/M3): 4 MG/M3 (INHALABLE FRACTION AND VAPOUR)
SASKATCHEWAN:
OEL TWA (MG/M3): 2 MG/M3 (INHALABLE FRACTION AND VAPOUR)
YUKON:
OEL STEL (MG/M3): 20 MG/M3
YUKON:
OEL TWA (MG/M3): 10 MG/M3
ETHANOLAMINE (141-43-5):
MEXICO:
OEL TWA (MG/M3): 8 MG/M3
MEXICO:
OEL TWA (PPM): 3 PPM
MEXICO:
OEL STEL (MG/M3): 15 MG/M3
MEXICO:
OEL STEL (PPM): 6 PPM
USA ACGIH:
ACGIH TWA (PPM): 3 PPM
USA ACGIH:
ACGIH STEL (PPM): 6 PPM
USA OSHA:
OSHA PEL (TWA) (MG/M3): 6 MG/M3
USA OSHA:
OSHA PEL (TWA) (PPM): 3 PPM
USA NIOSH:
NIOSH REL (TWA) (MG/M3): 8 MG/M3
USA NIOSH:
NIOSH REL (TWA) (PPM): 3 PPM
USA NIOSH:
NIOSH REL (STEL) (MG/M3): 15 MG/M3
USA NIOSH:
NIOSH REL (STEL) (PPM): 6 PPM
USA IDLH:
US IDLH (PPM): 30 PPM
ALBERTA:
OEL STEL (MG/M3): 15 MG/M3
ALBERTA:
OEL STEL (PPM): 6 PPM
ALBERTA:
OEL TWA (MG/M3): 7.5 MG/M3
ALBERTA:
OEL TWA (PPM): 3 PPM
BRITISH COLUMBIA:
OEL STEL (PPM): 6 PPM
BRITISH COLUMBIA:
OEL TWA (PPM): 3 PPM
MANITOBA:
OEL STEL (PPM): 6 PPM
MANITOBA:
OEL TWA (PPM): 3 PPM
NEW BRUNSWICK:
OEL STEL (MG/M3): 15 MG/M3
NEW BRUNSWICK:
OEL STEL (PPM): 6 PPM
NEW BRUNSWICK:
OEL TWA (MG/M3): 7.5 MG/M3
NEW BRUNSWICK:
OEL TWA (PPM): 3 PPM
NEWFOUNDLAND & LABRADOR:
OEL STEL (PPM): 6 PPM
NEWFOUNDLAND & LABRADOR:
OEL TWA (PPM): 3 PPM
NOVA SCOTIA:
OEL STEL (PPM): 6 PPM
NOVA SCOTIA:
OEL TWA (PPM): 3 PPM
NUNAVUT:
OEL STEL (PPM): 6 PPM
NUNAVUT:
OEL TWA (PPM): 3 PPM
NORTHWEST TERRITORIES:
OEL STEL (PPM): 6 PPM
NORTHWEST TERRITORIES:
OEL TWA (PPM): 3 PPM
ONTARIO:
OEL STEL (PPM): 6 PPM
ONTARIO:
OEL TWA (PPM): 3 PPM
PRINCE EDWARD ISLAND:
OEL STEL (PPM): 6 PPM
PRINCE EDWARD ISLAND:
OEL TWA (PPM): 3 PPM
QUEBEC:
VECD (MG/M3): 15 MG/M3
QUEBEC:
VECD (PPM): 6 PPM
QUEBEC:
VEMP (MG/M3): 7.5 MG/M3
QUEBEC:
VEMP (PPM): 3 PPM
SASKATCHEWAN:
OEL STEL (PPM): 6 PPM
SASKATCHEWAN:
OEL TWA (PPM): 3 PPM
YUKON:
OEL STEL (MG/M3): 12 MG/M3
YUKON:
OEL STEL (PPM): 6 PPM
YUKON:
OEL TWA (MG/M3): 6 MG/M3
YUKON:
OEL TWA (PPM): 3 PPM
DIETHANOLAMINE (111-42-2):
USA ACGIH:
ACGIH TWA (MG/M3): 1 MG/M3 (INHALABLE FRACTION AND VAPOR)
USA ACGIH:
ACGIH CHEMICAL CATEGORY:
SKIN - POTENTIAL SIGNIFICANT CONTRIBUTION TO OVERALL EXPOSURE BY THE
CUTANEOUS ROUTE, CONFIRMED ANIMAL CARCINOGEN WITH UNKNOWN RELEVANCE
TO HUMANS
USA NIOSH:
NIOSH REL (TWA) (MG/M3): 15 MG/M3
USA NIOSH:
NIOSH REL (TWA) (PPM): 3 PPM
ALBERTA:
OEL TWA (MG/M3): 2 MG/M3
BRITISH COLUMBIA:
OEL TWA (MG/M3): 2 MG/M3
MANITOBA:
OEL TWA (MG/M3): 1 MG/M3 (INHALABLE FRACTION AND VAPOR)
NEW BRUNSWICK:
OEL TWA (MG/M3): 2 MG/M3
NEW BRUNSWICK:
OEL TWA (PPM): 0.46 PPM
NEWFOUNDLAND & LABRADOR:
OEL TWA (MG/M3): 1 MG/M3 (INHALABLE FRACTION AND VAPOR)
NOVA SCOTIA:
OEL TWA (MG/M3): 1 MG/M3 (INHALABLE FRACTION AND VAPOR)
NUNAVUT:
OEL STEL (MG/M3): 4 MG/M3
NUNAVUT:
OEL TWA (MG/M3): 2 MG/M3
NORTHWEST TERRITORIES:
OEL STEL (MG/M3): 4 MG/M3
NORTHWEST TERRITORIES:
OEL TWA (MG/M3): 2 MG/M3
ONTARIO:
OEL TWA (MG/M3): 1 MG/M3 (INHALABLE FRACTION AND VAPOR)
PRINCE EDWARD ISLAND:
OEL TWA (MG/M3): 1 MG/M3 (INHALABLE FRACTION AND VAPOR)
QUEBEC:
VEMP (MG/M3): 13 MG/M3
QUEBEC:
VEMP (PPM): 3 PPM
SASKATCHEWAN:
OEL STEL (MG/M3): 4 MG/M3
SASKATCHEWAN:
OEL TWA (MG/M3): 2 MG/M3
TALC (14807-96-6):
MEXICO:
OEL TWA (MG/M3): 2 MG/M3 (RESPIRABLE FRACTION)
USA ACGIH:
ACGIH TWA (MG/M3):
2 MG/M3 (PARTICULATE MATTER CONTAINING NO ASBESTOS AND <1% CRYSTALLINE
SILICA, RESPIRABLE PARTICULATE MATTER)
USA ACGIH:
ACGIH CHEMICAL CATEGORY:
NOT CLASSIFIABLE AS A HUMAN CARCINOGEN CONTAINING NO ASBESTOS FIBERS
USA NIOSH:
NIOSH REL (TWA) (MG/M3):
2 MG/M3 (CONTAINING NO ASBESTOS AND <1% QUARTZ-RESPIRABLE DUST)
USA IDLH:
US IDLH (MG/M3): 1000 MG/M3 (CONTAINING NO ASBESTOS AND <1% QUARTZ)
ALBERTA:
OEL TWA (MG/M3): 2 MG/M3 (RESPIRABLE PARTICULATE)
BRITISH COLUMBIA:
OEL TWA (MG/M3):
2 MG/M3 (PARTICULATE MATTER CONTAINING NO ASBESTOS AND <1% CRYSTALLINE
SILICA-RESPIRABLE PARTICULATE)
MANITOBA:
OEL TWA (MG/M3):
2 MG/M3 (PARTICULATE MATTER CONTAINING NO ASBESTOS AND <1% CRYSTALLINE
SILICA-RESPIRABLE PARTICULATE MATTER)
NEW BRUNSWICK:
OEL TWA (MG/M3):
2 MG/M3 (PARTICULATE MATTER CONTAINING NO ASBESTOS AND <1% CRYSTALLINE
SILICA, RESPIRABLE FRACTION)
NEWFOUNDLAND & LABRADOR:
OEL TWA (MG/M3):
2 MG/M3 (PARTICULATE MATTER CONTAINING NO ASBESTOS AND <1% CRYSTALLINE
SILICA-RESPIRABLE PARTICULATE MATTER)
NOVA SCOTIA:
OEL TWA (MG/M3):
2 MG/M3 (PARTICULATE MATTER CONTAINING NO ASBESTOS AND <1% CRYSTALLINE
SILICA-RESPIRABLE PARTICULATE MATTER)
NUNAVUT:
OEL TWA (MG/M3): 2 MG/M3 (RESPIRABLE FRACTION)
NORTHWEST TERRITORIES:
OEL TWA (MG/M3): 2 MG/M3 (RESPIRABLE FRACTION)
ONTARIO:
OEL TWA (MG/M3):
2 MG/M3 (CONTAINING NO ASBESTOS AND <1% CRYSTALLINE SILICA-RESPIRABLE)
PRINCE EDWARD ISLAND:
OEL TWA (MG/M3):
2 MG/M3 (PARTICULATE MATTER CONTAINING NO ASBESTOS AND <1% CRYSTALLINE
SILICA-RESPIRABLE PARTICULATE MATTER)
QUEBEC:
VEMP (MG/M3): 3 MG/M3 (RESPIRABLE DUST)
SASKATCHEWAN:
OEL TWA (MG/M3): 2 MG/M3 (RESPIRABLE FRACTION)
YUKON:
OEL TWA (MG/M3): 20 MPPCF
4-VINYLCYCLOHEXENE (100-40-3):
USA ACGIH:
ACGIH TWA (PPM): 0.1 PPM
USA ACGIH:
ACGIH CHEMICAL CATEGORY:
CONFIRMED ANIMAL CARCINOGEN WITH UNKNOWN RELEVANCE TO HUMANS
USA AIHA:
WEEL TWA (PPM): 1 PPM
ALBERTA:
OEL TWA (MG/M3): 0.4 MG/M3
ALBERTA:
OEL TWA (PPM): 0.1 PPM
BRITISH COLUMBIA:
OEL TWA (PPM): 0.1 PPM
MANITOBA:
OEL TWA (PPM): 0.1 PPM
NEW BRUNSWICK:
OEL TWA (MG/M3): 0.44 MG/M3
NEW BRUNSWICK:
OEL TWA (PPM): 0.1 PPM
NEWFOUNDLAND & LABRADOR:
OEL TWA (PPM): 0.1 PPM
NOVA SCOTIA:
OEL TWA (PPM): 0.1 PPM
NUNAVUT:
OEL STEL (PPM): 0.3 PPM
NUNAVUT:
OEL TWA (PPM): 0.1 PPM
NORTHWEST TERRITORIES:
OEL STEL (PPM): 0.3 PPM
NORTHWEST TERRITORIES:
OEL TWA (PPM): 0.1 PPM
ONTARIO:
OEL TWA (PPM): 0.1 PPM
PRINCE EDWARD ISLAND:
OEL TWA (PPM): 0.1 PPM
SASKATCHEWAN:
OEL STEL (PPM): 0.3 PPM
SASKATCHEWAN:
OEL TWA (PPM): 0.1 PPM
N-BUTYL ACRYLATE (141-32-2):
MEXICO:
OEL TWA (MG/M3): 55 MG/M3
MEXICO:
OEL TWA (PPM): 10 PPM
USA ACGIH:
ACGIH TWA (PPM): 2 PPM
USA ACGIH:
ACGIH CHEMICAL CATEGORY:
DERMAL SENSITIZER, NOT CLASSIFIABLE AS A HUMAN CARCINOGEN
USA NIOSH:
NIOSH REL (TWA) (MG/M3): 55 MG/M3
USA NIOSH:
NIOSH REL (TWA) (PPM): 10 PPM
ALBERTA:
OEL TWA (MG/M3): 10 MG/M3
ALBERTA:
OEL TWA (PPM): 2 PPM
BRITISH COLUMBIA:
OEL TWA (PPM): 2 PPM
MANITOBA:
OEL TWA (PPM): 2 PPM
NEW BRUNSWICK:
OEL TWA (MG/M3): 52 MG/M3
NEW BRUNSWICK:
OEL TWA (PPM): 10 PPM
NEWFOUNDLAND & LABRADOR:
OEL TWA (PPM): 2 PPM
NOVA SCOTIA:
OEL TWA (PPM): 2 PPM
NUNAVUT:
OEL STEL (PPM): 4 PPM
NUNAVUT:
OEL TWA (PPM): 2 PPM
NORTHWEST TERRITORIES:
OEL STEL (PPM): 4 PPM
NORTHWEST TERRITORIES:
OEL TWA (PPM): 2 PPM
ONTARIO:
OEL TWA (PPM): 2 PPM
PRINCE EDWARD ISLAND:
OEL TWA (PPM): 2 PPM
QUEBEC:
VEMP (MG/M3): 10 MG/M3
QUEBEC:
VEMP (PPM): 2 PPM
SASKATCHEWAN:
OEL STEL (PPM): 4 PPM
SASKATCHEWAN:
OEL TWA (PPM): 2 PPM
YUKON:
OEL STEL (MG/M3): 82 MG/M3
YUKON:
OEL STEL (PPM): 15 PPM
YUKON:
OEL TWA (MG/M3): 55 MG/M3
YUKON:
OEL TWA (PPM): 10 PPM
METHYL METHACRYLATE (80-62-6):
MEXICO:
OEL TWA (MG/M3): 410 MG/M3
MEXICO:
OEL TWA (PPM): 100 PPM
MEXICO:
OEL STEL (MG/M3): 510 MG/M3
MEXICO:
OEL STEL (PPM): 125 PPM
USA ACGIH:
ACGIH TWA (PPM): 50 PPM
USA ACGIH:
ACGIH STEL (PPM): 100 PPM
USA ACGIH:
ACGIH CHEMICAL CATEGORY:
DERMAL SENSITIZER, NOT CLASSIFIABLE AS A HUMAN CARCINOGEN
USA OSHA:
OSHA PEL (TWA) (MG/M3): 410 MG/M3
USA OSHA:
OSHA PEL (TWA) (PPM): 100 PPM
USA NIOSH:
NIOSH REL (TWA) (MG/M3): 410 MG/M3
USA NIOSH:
NIOSH REL (TWA) (PPM): 100 PPM
USA IDLH:
US IDLH (PPM): 1000 PPM
ALBERTA:
OEL STEL (MG/M3): 410 MG/M3
ALBERTA:
OEL STEL (PPM): 100 PPM
ALBERTA:
OEL TWA (MG/M3): 205 MG/M3
ALBERTA:
OEL TWA (PPM): 50 PPM
BRITISH COLUMBIA:
OEL STEL (PPM): 100 PPM
BRITISH COLUMBIA:
OEL TWA (PPM): 50 PPM
MANITOBA:
OEL STEL (PPM): 100 PPM
MANITOBA:
OEL TWA (PPM): 50 PPM
NEW BRUNSWICK:
OEL TWA (MG/M3): 410 MG/M3
NEW BRUNSWICK:
OEL TWA (PPM): 100 PPM
NEWFOUNDLAND & LABRADOR:
OEL STEL (PPM): 100 PPM
NEWFOUNDLAND & LABRADOR:
OEL TWA (PPM): 50 PPM
NOVA SCOTIA:
OEL STEL (PPM): 100 PPM
NOVA SCOTIA:
OEL TWA (PPM): 50 PPM
NUNAVUT:
OEL STEL (PPM): 100 PPM
NUNAVUT:
OEL TWA (PPM): 50 PPM
NORTHWEST TERRITORIES:
OEL STEL (PPM): 100 PPM
NORTHWEST TERRITORIES:
OEL TWA (PPM): 50 PPM
ONTARIO:
OEL STEL (PPM): 100 PPM
ONTARIO:
OEL TWA (PPM): 50 PPM
PRINCE EDWARD ISLAND:
OEL STEL (PPM): 100 PPM
PRINCE EDWARD ISLAND:
OEL TWA (PPM): 50 PPM
QUEBEC:
VEMP (MG/M3): 205 MG/M3
QUEBEC:
VEMP (PPM): 50 PPM
SASKATCHEWAN:
OEL STEL (PPM): 100 PPM
SASKATCHEWAN:
OEL TWA (PPM): 50 PPM
YUKON:
OEL STEL (MG/M3): 510 MG/M3
YUKON:
OEL STEL (PPM): 125 PPM
YUKON:
OEL TWA (MG/M3): 410 MG/M3
YUKON:
OEL TWA (PPM): 100 PPM
EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS AND SAFETY SHOWERS SHOULD BE AVAILABLE IN THE
IMMEDIATE VICINITY OF ANY POTENTIAL EXPOSURE. GAS DETECTORS SHOULD BE USED
WHEN FLAMMABLE GASES OR VAPORS MAY BE RELEASED. ENSURE ADEQUATE
VENTILATION, ESPECIALLY IN CONFINED AREAS. VAPORS MAY BE UNINHIBITED AND
POLYMERIZE, CAUSING BLOCKAGE OF VENTS. PROPER GROUNDING PROCEDURES TO AVOID
STATIC ELECTRICITY SHOULD BE FOLLOWED. USE EXPLOSION-PROOF EQUIPMENT.
ENSURE ALL NATIONAL/LOCAL REGULATIONS ARE OBSERVED.
PERSONAL PROTECTIVE EQUIPMENT:
GLOVES. PROTECTIVE CLOTHING. PROTECTIVE GOGGLES.
INSUFFICIENT VENTILATION: WEAR RESPIRATORY PROTECTION.
MATERIALS FOR PROTECTIVE CLOTHING:
CHEMICALLY RESISTANT MATERIALS AND FABRICS. WEAR FIRE/FLAME
RESISTANT/RETARDANT CLOTHING.
HAND PROTECTION: WEAR PROTECTIVE GLOVES.
EYE PROTECTION: CHEMICAL SAFETY GOGGLES.
SKIN AND BODY PROTECTION: WEAR SUITABLE PROTECTIVE CLOTHING.
RESPIRATORY PROTECTION:
IF EXPOSURE LIMITS ARE EXCEEDED OR IRRITATION IS EXPERIENCED, APPROVED
RESPIRATORY PROTECTION SHOULD BE WORN. IN CASE OF INADEQUATE VENTILATION,
OXYGEN DEFICIENT ATMOSPHERE, OR WHERE EXPOSURE LEVELS ARE NOT KNOWN WEAR
APPROVED RESPIRATORY PROTECTION.
ENVIRONMENTAL EXPOSURE CONTROLS: AVOID RELEASE TO THE ENVIRONMENT.
OTHER INFORMATION: WHEN USING, DO NOT EAT, DRINK OR SMOKE
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: BLACK LIQUID
ODOR: LIKE ACRYLIC
ODOR THRESHOLD: NOT AVAILABLE
PH: NOT AVAILABLE
EVAPORATION RATE: NOT AVAILABLE
MELTING POINT: NOT AVAILABLE
FREEZING POINT: NOT AVAILABLE
BOILING POINT: 100 DEG. C (212 DEG. F)
FLASH POINT: 8.9 DEG. C (48.02 DEG. F) CLOSED CUP
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE
DECOMPOSITION TEMPERATURE: NOT AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE
LOWER FLAMMABLE LIMIT: NOT AVAILABLE
UPPER FLAMMABLE LIMIT: NOT AVAILABLE
VAPOR PRESSURE: NOT AVAILABLE
RELATIVE VAPOR DENSITY AT 20 DEG. C: NOT AVAILABLE
RELATIVE DENSITY: NOT AVAILABLE
SPECIFIC GRAVITY: 0.979 G/CM3
SOLUBILITY: NOT AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE
VISCOSITY: NOT AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
REACTIVITY:
REACTS VIOLENTLY WITH STRONG OXIDIZERS. INCREASED RISK OF FIRE OR
EXPLOSION. THE PRODUCT IS NORMALLY SUPPLIED IN A STABILIZED FORM. IF THE
PERMISSIBLE STORAGE PERIOD AND/OR STORAGE TEMPERATURE IS EXCEEDED, THE
PRODUCT MAY POLYMERIZE WITH HEAT EVOLUTION. POLYMERIZATION WITH HEAT
EVOLUTION MAY OCCUR IN THE PRESENCE OF RADICAL FORMING SUBSTANCES (E.G.
PEROXIDES), REDUCING SUBSTANCES, AND/OR HEAVY METAL IONS. PRODUCT REACTS
VIOLENTLY OR EXPLOSIVELY WITH ALKALI METALS, ALKALINE EARTH METALS, VARIOUS
METAL POWDERS, STRONG ALKALIS, AMMONIA, AND OTHER INCOMPATIBLE MATERIALS.
REACTS VIGOROUSLY WITH WATER PRODUCING HEAT. CONTACT WITH METALS AND WATER
LIBERATES HYDROGEN.
CHEMICAL STABILITY:
AS SUPPLIED, THIS PRODUCT IS STABILIZED WITH INHIBITORS. EXTREMELY
FLAMMABLE LIQUID AND VAPOR. MAY FORM FLAMMABLE OR EXPLOSIVE VAPOR-AIR
MIXTURE.
POSSIBILITY OF HAZARDOUS REACTIONS:
THIS PRODUCT HAS BEEN STABILIZED BY INHIBITORS. HAZARDOUS REACTIONS WILL
NOT OCCUR UNDER NORMAL CONDITIONS. CONTAINS METHACRYLATE COMPOUNDS THAT
UNINHIBITED CAN UNDERGO HAZARDOUS POLYMERIZATION AT ELEVATED TEMPERATURES,
OR WHEN EXPOSED TO STRONG OXIDIZERS OR UV LIGHT. TAKE APPROPRIATE
PRECAUTIONS TO AVOID THESE CONDITIONS.
CONDITIONS TO AVOID:
DIRECT SUNLIGHT, EXTREMELY HIGH OR LOW TEMPERATURES, HEAT, HOT SURFACES,
SPARKS, OPEN FLAMES, INCOMPATIBLE MATERIALS, AND OTHER IGNITION SOURCES.
INCOMPATIBLE MATERIALS:
STRONG ACIDS, STRONG BASES, STRONG OXIDIZERS. FREE RADICAL INITIATORS.
PEROXIDES. REDUCING AGENTS. HEAVY METAL IONS. EPOXIDES. ULTRAVIOLET LIGHT.
DIRECT SUNLIGHT. ALKALI METALS. ALKALINE EARTH METALS. VARIOUS METAL
POWDERS. STRONG ALKALIS. AMMONIA.
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS - PRODUCT:
ACUTE TOXICITY (ORAL): NOT CLASSIFIED
ACUTE TOXICITY (DERMAL): NOT CLASSIFIED
ACUTE TOXICITY (INHALATION): NOT CLASSIFIED
LD50 AND LC50 DATA: NOT AVAILABLE
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
EYE DAMAGE/IRRITATION: CAUSES SERIOUS EYE IRRITATION.
RESPIRATORY OR SKIN SENSITIZATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT CLASSIFIED
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
MAY CAUSE RESPIRATORY IRRITATION.
ASPIRATION HAZARD: NOT CLASSIFIED
SYMPTOMS/INJURIES AFTER INHALATION:
IRRITATION OF THE RESPIRATORY TRACT AND THE OTHER MUCOUS MEMBRANES.
SYMPTOMS/INJURIES AFTER SKIN CONTACT:
REDNESS, PAIN, SWELLING, ITCHING, BURNING, DRYNESS, AND DERMATITIS. MAY
CAUSE AN ALLERGIC SKIN REACTION.
SYMPTOMS/INJURIES AFTER EYE CONTACT:
CONTACT CAUSES SEVERE IRRITATION WITH REDNESS AND SWELLING OF THE
CONJUNCTIVA.
SYMPTOMS/INJURIES AFTER INGESTION: INGESTION MAY CAUSE ADVERSE EFFECTS.
CHRONIC SYMPTOMS: NONE KNOWN.
INFORMATION ON TOXICOLOGICAL EFFECTS - INGREDIENT(S):
LD50 AND LC50 DATA:
2,6-DI-TERT-BUTYL-P-CRESOL (128-37-0):
LD50 ORAL RAT: >2930 MG/KG (SPECIES: SPRAGUE-DAWLEY)
LD50 DERMAL RAT: >2000 MG/KG
ETHANOLAMINE (141-43-5):
LD50 ORAL RAT: 1720 MG/KG
LD50 DERMAL RABBIT: 1025 MG/KG
ATE US/CA (VAPORS): 11.00 MG/L/4H
DIETHANOLAMINE (111-42-2):
LD50 ORAL RAT: 1820 MG/KG
SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE (112945-52-5):
LD50 ORAL RAT: 3160 MG/KG
PYRIDINE, 3,5-DIETHYL-1,2-DIHYDRO-1-PHENYL-2-PROPYL- (34562-31-7):
ATE US/CA (ORAL): 500.00 MG/KG BODY WEIGHT
ATE US/CA (DERMAL): 1,100.00 MG/KG BODY WEIGHT
4-VINYLCYCLOHEXENE (100-40-3):
LD50 ORAL RAT: 2600 MG/KG
LD50 DERMAL RABBIT: 17000 MG/KG
LC50 INHALATION RAT: 17.7 - 35.4 MG/L/4H
N-BUTYL ACRYLATE (141-32-2):
LD50 ORAL RAT: 9050 MG/KG
LD50 DERMAL RABBIT: 3024 MG/KG
LC50 INHALATION RAT: 10.3 MG/L/4H
METHYL METHACRYLATE (80-62-6):
LD50 ORAL RAT: 8420 - 10000 MG/KG
LD50 DERMAL RABBIT: 5000 - 7500 MG/KG
LC50 INHALATION RAT: 29 MG/L/4H
LC50 INHALATION RAT: 7093 PPM/4H
BENZENESULFONIC ACID, OXYBIS[DODECYL-, DISODIUM SALT (25167-32-2):
LD50 ORAL RAT: 1000 MG/KG
LD50 DERMAL RABBIT: >2000 MG/KG
COPPER(II) 8-HYDROXYQUINOLINATE (10380-28-6):
LD50 ORAL RAT: 500 MG/KG
LD50 DERMAL RABBIT: >2000 MG/KG
LC50 INHALATION RAT: >0.94 MG/L/4H
ATE US/CA (DUST, MIST): 0.50 MG/L/4H
2,6-DI-TERT-BUTYL-P-CRESOL (128-37-0):
IARC GROUP: 3
DIETHANOLAMINE (111-42-2):
IARC GROUP: 2B
OSHA HAZARD COMMUNICATION CARCINOGEN LIST:
IN OSHA HAZARD COMMUNICATION CARCINOGEN LIST.
TALC (14807-96-6):
IARC GROUP: 3
NATIONAL TOXICOLOGY PROGRAM (NTP) STATUS: EVIDENCE OF CARCINOGENICITY.
SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE (112945-52-5):
IARC GROUP: 3
4-VINYLCYCLOHEXENE (100-40-3):
IARC GROUP: 2B
OSHA HAZARD COMMUNICATION CARCINOGEN LIST:
IN OSHA HAZARD COMMUNICATION CARCINOGEN LIST.
N-BUTYL ACRYLATE (141-32-2):
IARC GROUP: 3
METHYL METHACRYLATE (80-62-6):
IARC GROUP: 3
COPPER(II) 8-HYDROXYQUINOLINATE (10380-28-6):
IARC GROUP: 3
| SECTION 12: ECOLOGICAL INFORMATION | |
TOXICITY:
ECOLOGY - GENERAL: HARMFUL TO AQUATIC LIFE.
2,6-DI-TERT-BUTYL-P-CRESOL (128-37-0):
EC50 DAPHNIA 1: 0.48 MG/L (EXPOSURE TIME: 48 H - SPECIES: DAPHNIA MAGNA)
EC50 OTHER AQUATIC ORGANISMS 2:
0.43 MG/L (EXPOSURE TIME: 72 H - SPECIES: DESMODESMUS SUBSPICATUS)
ETHANOLAMINE (141-43-5):
LC50 FISH 1:
227 MG/L (EXPOSURE TIME: 96 H - SPECIES: PIMEPHALES PROMELAS
[FLOW-THROUGH])
EC50 DAPHNIA 1: 65 MG/L (EXPOSURE TIME: 48 H - SPECIES: DAPHNIA MAGNA)
LC50 FISH 2:
3684 MG/L (EXPOSURE TIME: 96 H - SPECIES: BRACHYDANIO RERIO [STATIC])
ERC50 (ALGAE): 2.5 MG/L
DIETHANOLAMINE (111-42-2):
LC50 FISH 1:
4460 (4460 - 4980) MG/L (EXPOSURE TIME: 96 H - SPECIES: PIMEPHALES PROMELAS
[FLOW-THROUGH])
EC50 DAPHNIA 1: 55 MG/L (EXPOSURE TIME: 48 H - SPECIES: DAPHNIA MAGNA)
LC50 FISH 2:
1200 (1200 - 1580) MG/L (EXPOSURE TIME: 96 H - SPECIES: PIMEPHALES PROMELAS
[STATIC])
EC50 OTHER AQUATIC ORGANISMS 2:
2.1 (2.1 - 2.3) MG/L (EXPOSURE TIME: 96 H - SPECIES: PSEUDOKIRCHNERIELLA
SUBCAPITATA)
ERC50 (ALGAE):
2.2 MG/L (EXPOSURE TIME: 96 H - SPECIES: PSEUDOKIRCHNERIELLA SUBCAPITATA
[STATIC])
NOEC CHRONIC CRUSTACEA: 0.78 MG/L
TALC (14807-96-6):
LC50 FISH 1:
>100 G/L (EXPOSURE TIME: 96 H - SPECIES: BRACHYDANIO RERIO [SEMI-STATIC])
4-VINYLCYCLOHEXENE (100-40-3):
EC50 DAPHNIA 1: 1.87 MG/L
N-BUTYL ACRYLATE (141-32-2):
LC50 FISH 1:
5.2 MG/L (EXPOSURE TIME: 96 H - SPECIES: ONCORHYNCHUS MYKISS
[FLOW-THROUGH])
EC50 DAPHNIA 1: 8.2 MG/L (EXPOSURE TIME: 48 H - SPECIES: DAPHNIA MAGNA)
METHYL METHACRYLATE (80-62-6):
LC50 FISH 1:
243 - 275 MG/L (EXPOSURE TIME: 96 H - SPECIES: PIMEPHALES PROMELAS
[FLOW-THROUGH])
EC50 DAPHNIA 1: 69 MG/L (EXPOSURE TIME: 48 H - SPECIES: DAPHNIA MAGNA)
LC50 FISH 2:
125.5 - 190.7 MG/L (EXPOSURE TIME: 96 H - SPECIES: PIMEPHALES PROMELAS
[STATIC])
BENZENESULFONIC ACID, OXYBIS[DODECYL-, DISODIUM SALT (25167-32-2):
LC50 FISH 1:
3.85 MG/L (EXPOSURE TIME: 96 H - SPECIES: PIMEPHALES PROMELAS
[FLOW-THROUGH])
EC50 DAPHNIA 1: 3.63 MG/L (EXPOSURE TIME: 48 H - SPECIES: DAPHNIA MAGNA)
LC50 FISH 2:
6.81 MG/L (EXPOSURE TIME: 96 H - SPECIES: LEPOMIS MACROCHIRUS [STATIC])
COPPER(II) 8-HYDROXYQUINOLINATE (10380-28-6):
ERC50 (ALGAE): 0.0762 MG/L
PERSISTENCE AND DEGRADABILITY:
GORILLA WELD - HARDENER:
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
BIOACCUMULATIVE POTENTIAL:
GORILLA WELD - HARDENER:
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
2,6-DI-TERT-BUTYL-P-CRESOL (128-37-0):
BCF FISH 1: 230 - 2500
LOG POW: 4.17
ETHANOLAMINE (141-43-5):
LOG POW: -1.91 (AT 25 DEG. C)
DIETHANOLAMINE (111-42-2):
BCF FISH 1: (NO SIGNIFICANT BIOCONCENTRATION)
LOG POW: -2.18 (AT 25 DEG. C)
TALC (14807-96-6):
BCF FISH 1: (NO KNOWN BIOACCUMULATION)
N-BUTYL ACRYLATE (141-32-2):
LOG POW: 2.38 (AT 25 DEG. C)
METHYL METHACRYLATE (80-62-6):
LOG POW: 0.7
MOBILITY IN SOIL: NOT AVAILABLE
OTHER ADVERSE EFFECTS:
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL, NATIONAL,
TERRITORIAL, PROVINCIAL, AND INTERNATIONAL REGULATIONS
ADDITIONAL INFORMATION:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE. DO
NOT PRESSURIZE, CUT, OR WELD CONTAINERS.
ECOLOGY - WASTE MATERIALS:
AVOID RELEASE TO THE ENVIRONMENT. THIS MATERIAL IS HAZARDOUS TO THE AQUATIC
ENVIRONMENT. KEEP OUT OF SEWERS AND WATERWAYS.
| SECTION 14: TRANSPORT INFORMATION | |
THE SHIPPING DESCRIPTION(S) STATED HEREIN WERE PREPARED IN ACCORDANCE WITH
CERTAIN ASSUMPTIONS AT THE TIME THE SDS WAS AUTHORED, AND CAN VARY BASED ON
A NUMBER OF VARIABLES THAT MAY OR MAY NOT HAVE BEEN KNOWN AT THE TIME THE
SDS WAS ISSUED.
IN ACCORDANCE WITH DOT:
PROPER SHIPPING NAME: FLAMMABLE LIQUID, N.O.S. (METHYL METHACRYLATE)
HAZARD CLASS: 3
IDENTIFICATION NUMBER: UN1993
LABEL CODES: 3
PACKING GROUP: II
ERG NUMBER: 128
FLAMMABLE LIQUID, CLASS/DIVISION 3.1, 3.2, 3.3
IN ACCORDANCE WITH IMDG:
PROPER SHIPPING NAME: FLAMMABLE LIQUID, N.O.S. (METHYL METHACRYLATE)
HAZARD CLASS: 3
IDENTIFICATION NUMBER: UN1993
LABEL CODES: 3
PACKING GROUP: II
EMS-NO. (FIRE): F-E
EMS-NO. (SPILLAGE): S-E
CLASS 3 - FLAMMABLE LIQUIDS
IN ACCORDANCE WITH IATA:
PROPER SHIPPING NAME: FLAMMABLE LIQUID, N.O.S. (METHYL METHACRYLATE)
IDENTIFICATION NUMBER: 3
HAZARD CLASS: UN1993
LABEL CODES: 3
PACKING GROUP: II
ERG CODE (IATA): 3L
CLASS 3, FLAMMABLE LIQUIDS
IN ACCORDANCE WITH TDG:
PROPER SHIPPING NAME: FLAMMABLE LIQUID, N.O.S. (METHYL METHACRYLATE)
HAZARD CLASS: 3
IDENTIFICATION NUMBER: UN1993
LABEL CODES: 3
PACKING GROUP: II
CLASS 3, FLAMMABLE LIQUIDS
| SECTION 15: REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
GORILLA WELD - HARDENER:
SARA SECTION 311/312 HAZARD CLASSES
FIRE HAZARD
IMMEDIATE (ACUTE) HEALTH HAZARD
REACTIVE HAZARD
2,6-DI-TERT-BUTYL-P-CRESOL (128-37-0):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
ETHANOLAMINE (141-43-5):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
DIETHANOLAMINE (111-42-2):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
SUBJECT TO REPORTING REQUIREMENTS OF UNITED STATES SARA SECTION 313
CERCLA RQ: 100 LB
SARA SECTION 313 - EMISSION REPORTING: 1.0%
TALC (14807-96-6):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
PYRIDINE, 3,5-DIETHYL-1,2-DIHYDRO-1-PHENYL-2-PROPYL- (34562-31-7):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
4-VINYLCYCLOHEXENE (100-40-3):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
N-BUTYL ACRYLATE (141-32-2):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
SUBJECT TO REPORTING REQUIREMENTS OF UNITED STATES SARA SECTION 313
SARA SECTION 313 - EMISSION REPORTING: 1.0%
METHYL METHACRYLATE (80-62-6):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
SUBJECT TO REPORTING REQUIREMENTS OF UNITED STATES SARA SECTION 313
CERCLA RQ: 1000 LB
SARA SECTION 313 - EMISSION REPORTING: 1.0%
2-PROPENOIC ACID, 2-METHYL-, METHYL ESTER, POLYMER WITH 1,3-BUTADIENE AND
ETHENYLBENZENE (25053-09-2):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
EPA TSCA REGULATORY FLAG:
XU - XU - INDICATES A SUBSTANCE EXEMPT FROM REPORTING UNDER THE INVENTORY
UPDATE REPORTING RULE, I.E, PARTIAL UPDATING OF THE TSCA INVENTORY DATA
BASE PRODUCTION AND SITE REPORTS (40 CFR 710(C))
BENZENESULFONIC ACID, OXYBIS[DODECYL-, DISODIUM SALT (25167-32-2):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
COPPER(II) 8-HYDROXYQUINOLINATE (10380-28-6):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
US STATE REGULATIONS:
DIETHANOLAMINE (111-42-2):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST:
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
4-VINYLCYCLOHEXENE (100-40-3):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST:
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE:
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
(FEMALE) REPRODUCTIVE HARM.
2,6-DI-TERT-BUTYL-P-CRESOL (128-37-0):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
ETHANOLAMINE (141-43-5):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
DIETHANOLAMINE (111-42-2):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - ENVIRONMENTAL HAZARD LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
TALC (14807-96-6):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
4-VINYLCYCLOHEXENE (100-40-3):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
N-BUTYL ACRYLATE (141-32-2):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - ENVIRONMENTAL HAZARD LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
METHYL METHACRYLATE (80-62-6):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - ENVIRONMENTAL HAZARD LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
CANADIAN REGULATIONS:
2,6-DI-TERT-BUTYL-P-CRESOL (128-37-0):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
ETHANOLAMINE (141-43-5):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
DIETHANOLAMINE (111-42-2):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
TALC (14807-96-6): LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
PYRIDINE, 3,5-DIETHYL-1,2-DIHYDRO-1-PHENYL-2-PROPYL- (34562-31-7):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
4-VINYLCYCLOHEXENE (100-40-3):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
N-BUTYL ACRYLATE (141-32-2):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
METHYL METHACRYLATE (80-62-6):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
2-PROPENOIC ACID, 2-METHYL-, METHYL ESTER, POLYMER WITH 1,3-BUTADIENE AND
ETHENYLBENZENE (25053-09-2):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
BENZENESULFONIC ACID, OXYBIS[DODECYL-, DISODIUM SALT (25167-32-2):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
COPPER(II) 8-HYDROXYQUINOLINATE (10380-28-6):
LISTED ON THE CANADIAN NDSL (NON-DOMESTIC SUBSTANCES LIST)
| SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION | |
OR LAST REVISION
REVISION DATE: 01/20/2017
OTHER INFORMATION:
THIS DOCUMENT HAS BEEN PREPARED IN ACCORDANCE WITH THE SDS REQUIREMENTS
OF THE OSHA HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200 AND CANADA'S
HAZARDOUS PRODUCTS REGULATIONS (HPR).
GHS FULL TEXT PHRASES:
ACUTE TOX. 3 (INHALATION: DUST, MIST):
ACUTE TOXICITY (INHALATION: DUST, MIST) CATEGORY 3
ACUTE TOX. 4 (DERMAL): ACUTE TOXICITY (DERMAL) CATEGORY 4
ACUTE TOX. 4 (INHALATION: VAPOR):
ACUTE TOXICITY (INHALATION: VAPOR) CATEGORY 4
ACUTE TOX. 4 (ORAL): ACUTE TOXICITY (ORAL) CATEGORY 4
AQUATIC ACUTE 1:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD CATEGORY 1
AQUATIC ACUTE 2:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD CATEGORY 2
AQUATIC ACUTE 3:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD CATEGORY 3
AQUATIC CHRONIC 1:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - CHRONIC HAZARD CATEGORY 1
AQUATIC CHRONIC 2:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - CHRONIC HAZARD CATEGORY 2
AQUATIC CHRONIC 3:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - CHRONIC HAZARD CATEGORY 3
ASP. TOX. 1: ASPIRATION HAZARD CATEGORY 1
CARC. 2: CARCINOGENICITY CATEGORY 2
COMB. DUST: COMBUSTIBLE DUST
EYE DAM. 1: SERIOUS EYE DAMAGE/EYE IRRITATION CATEGORY 1
EYE IRRIT. 2A: SERIOUS EYE DAMAGE/EYE IRRITATION CATEGORY 2A
EYE IRRIT. 2B: SERIOUS EYE DAMAGE/EYE IRRITATION CATEGORY 2B
FLAM. LIQ. 2: FLAMMABLE LIQUIDS CATEGORY 2
FLAM. LIQ. 3: FLAMMABLE LIQUIDS CATEGORY 3
FLAM. LIQ. 4: FLAMMABLE LIQUIDS CATEGORY 4
REPR. 2: REPRODUCTIVE TOXICITY CATEGORY 2
SKIN CORR. 1B: SKIN CORROSION/IRRITATION CATEGORY 1B
SKIN IRRIT. 2: SKIN CORROSION/IRRITATION CATEGORY 2
SKIN SENS. 1: SKIN SENSITIZATION CATEGORY 1
STOT RE 2: SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) CATEGORY 2
STOT SE 3: SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CATEGORY 3
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR
H226: FLAMMABLE LIQUID AND VAPOR
H227: COMBUSTIBLE LIQUID
H302: HARMFUL IF SWALLOWED
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS
H312: HARMFUL IN CONTACT WITH SKIN
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
H315: CAUSES SKIN IRRITATION
H317: MAY CAUSE AN ALLERGIC SKIN REACTION
H318: CAUSES SERIOUS EYE DAMAGE
H319: CAUSES SERIOUS EYE IRRITATION
H320: CAUSES EYE IRRITATION
H331: TOXIC IF INHALED
H332: HARMFUL IF INHALED
H335: MAY CAUSE RESPIRATORY IRRITATION
H351: SUSPECTED OF CAUSING CANCER
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE
H400: VERY TOXIC TO AQUATIC LIFE
H401: TOXIC TO AQUATIC LIFE
H402: HARMFUL TO AQUATIC LIFE
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
H411: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS
THE INFORMATION PRESENTED IN THIS SAFETY DATA SHEET WAS PREPARED BY
QUALIFIED PERSONNEL AND TO THE BEST OF OUR KNOWLEDGE IS TRUE AND ACCURATE.
THE INFORMATION AND RECOMMENDATIONS ARE FURNISHED FOR THIS PRODUCT WITH THE
UNDERSTANDING THAT THE PURCHASER WILL INDEPENDENTLY DETERMINE THE
SUITABILITY OF THE PRODUCT FOR THIS PURPOSE. THIS DATA DOES NOT CONSTITUTE
A WARRANTY, EXPRESSED OR IMPLIED, STATUTORY OR OTHERWISE, NOR IS IT
REPRESENTATION FOR WHICH THE GORILLA GLUE COMPANY ASSUMES LEGAL
RESPONSIBILITY. THE DATA IS SUBMITTED FOR THE USER'S INFORMATION AND
CONSIDERATION ONLY. ANY USE OF THIS PRODUCT MUST BE DETERMINED BY THE USER
TO BE IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE, PROVINCIAL AND LOCAL
LAWS AND REGULATIONS.
GORILLA GLUE NA GHS SDS 2015