| Common Name: | ETK ACID TEST KIT |
| Manufacturer: | PARKER HANNIFIN |
| SDS Revision Date: | 4/20/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 459W18 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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PARKER
PARKER HANNIFIN CORPORATION
SPORLAN DIVISION
206 LANGE DRIVE
WASHINGTON, MO 63090
U.S.A.
ETK ACID TEST KIT ETK
SDS REVISION DATE (MM/DD/YYYY): 04/20/2015
SAFETY DATA SHEET
| SECTION 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER USED ON THE LABEL: ETK ACID TEST KIT
PRODUCT CODE(S): ETK (P/N 475360)
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
OIL REFRIGERATION TEST KIT
CHEMICAL FAMILY: MIXTURE.
NAME, ADDRESS, AND TELEPHONE NUMBER OF THE SUPPLIER:
PARKER HANNIFIN CORPORATION - SPORLAN DIVISION
206 LANGE DRIVE
WASHINGTON, MO, 63090
U.S.A.
NAME, ADDRESS, AND TELEPHONE NUMBER OF THE MANUFACTURER: REFER TO SUPPLIER
SUPPLIER'S TELEPHONE #: (636-239-1111
24 HR. EMERGENCY TEL #:
CHEMTREC: 1-800-424-9300 (WITHIN CONTINENTAL U.S.)
CHEMTREC: 703-527-3887 (OUTSIDE U.S.).
| SECTION 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION OF THE CHEMICAL:
WHMIS INFORMATION:
THIS PRODUCT IS A WHMIS CONTROLLED PRODUCT. IT MEETS ONE OR MORE OF THE
CRITERIA FOR A CONTROLLED PRODUCT PROVIDED IN PART IV OF THE CANADIAN
CONTROLLED PRODUCTS REGULATIONS (CPR).
WHMIS CLASSIFICATION:
CLASS B2 (FLAMMABLE LIQUIDS)
CLASS D2A (MATERIALS CAUSING OTHER TOXIC EFFECTS, VERY TOXIC MATERIAL)
CLASS D2B (MATERIALS CAUSING OTHER TOXIC EFFECTS, TOXIC MATERIAL)
OSHA:
THIS MATERIAL IS CLASSIFIED AS HAZARDOUS UNDER OSHA REGULATIONS
(29 CFR 1910.1200).
HAZARDOUS CLASSIFICATION:
FLAMMABLE LIQUID: CATEGORY 2
EYE DAMAGE/IRRITATION: CATEGORY 2A
SKIN IRRITATION: CATEGORY 2
REPRODUCTIVE TOXICITY: CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE: CATEGORY 3 (CNS)
SPECIFIC TARGET ORGAN TOXICITY, REPEATED EXPOSURE: CATEGORY 2
ASPIRATION TOXICITY: CATEGORY 1
LABEL ELEMENTS:
THE FOLLOWING LABEL INFORMATION IS APPLICABLE ONLY TO THE UNITED STATES
ACCORDING TO OSHA REGULATIONS (29 CFR 1910.1200) (HAZCOM 2012):
SIGNAL WORD:
DANGER!
HAZARD STATEMENT(S):
HIGHLY FLAMMABLE LIQUID AND VAPOR.
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE IRRITATION.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
PRECAUTIONARY STATEMENT(S):
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAME. - NO SMOKING. KEEP CONTAINER
TIGHTLY CLOSED. GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING/EQUIPMENT.
USE ONLY NON-SPARKING TOOLS.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
WASH THOROUGHLY AFTER HANDLING.
AVOID BREATHING MIST, VAPORS OR SPRAY.
USE ONLY IN WELL-VENTILATED AREAS.
WEAR PROTECTIVE GLOVES/CLOTHING AND EYE/FACE PROTECTION.
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION/ADVICE.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OCCURS, GET MEDICAL ADVICE/ATTENTION.
TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE RE-USE.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO.
CONTINUE RINSING.
IF EYE IRRITATION PERSISTS, GET MEDICAL ADVICE/ATTENTION.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
DO NOT INDUCE VOMITING.
IN CASE OF FIRE, USE WATER FOG, DRY CHEMICAL, CO2 OR 'ALCOHOL' FOAM.
STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
KEEP CONTAINER TIGHTLY CLOSED.
STORE LOCKED UP.
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
FLAME
HEALTH HAZARD
EXCLAMATION MARK
THE FOLLOWING LABEL INFORMATION IS APPLICABLE ONLY TO CANADA ACCORDING TO
THE CANADIAN CONTROLLED PRODUCTS REGULATIONS (CPR/WHMIS):
DANGER!
HIGHLY FLAMMABLE LIQUID AND VAPOUR HARMFUL IF INHALED. MAY CAUSE
RESPIRATORY IRRITATION. MAY CAUSE HEADACHE, NAUSEA, DIZZINESS AND OTHER
SYMPTOMS OF CENTRAL NERVOUS SYSTEM DEPRESSION. MAY BE FATAL IF SWALLOWED
AND ENTERS AIRWAYS. ASPIRATION INTO THE LUNGS MAY CAUSE CHEMICAL
PNEUMONITIS. CAUSES SKIN AND EYE IRRITATION. CONTAINS MATERIAL WHICH MAY
CAUSE REPRODUCTIVE HARM.
WEAR PROTECTIVE GLOVES/CLOTHING AND EYE/FACE PROTECTION. USE IN A
WELL-VENTILATED AREA. KEEP AWAY FROM FLAMES AND HOT SURFACES. - NO SMOKING.
BOND AND GROUND TRANSFER CONTAINERS AND EQUIPMENT TO AVOID STATIC
ACCUMULATION. WASH THOROUGHLY AFTER HANDLING.
IF INHALED:
REMOVE TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
IF ON SKIN:
WASH WITH PLENTY OF SOAP AND WATER. CALL A PHYSICIAN IF IRRITATION DEVELOPS
OR PERSISTS.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING. CALL A PHYSICIAN IF IRRITATION
DEVELOPS OR PERSISTS. IF SWALLOWED, CALL A POISON CONTROL CENTRE OR DOCTOR
IMMEDIATELY.
B - FLAMMABLE AND COMBUSTIBLE MATERIAL
D2 - MATERIALS CAUSING OTHER TOXIC EFFECTS
OTHER HAZARDS:
OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION:
INGESTION CAN CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, AND DIARRHEA.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS # CONCENTRATION
TOLUENE 108-88-3 30.0 - 60.0
ETHYL ALCOHOL 64-17-5 30.0 - 60.0
| SECTION 4. FIRST-AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
INGESTION:
SEEK IMMEDIATE MEDICAL ATTENTION/ADVICE. DO NOT INDUCE VOMITING. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
INHALATION:
IMMEDIATELY REMOVE PERSON TO FRESH AIR. IF BREATHING HAS STOPPED, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN BY QUALIFIED
MEDICAL PERSONNEL ONLY. SEEK IMMEDIATE MEDICAL ATTENTION/ADVICE.
SKIN CONTACT:
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. WASH OFF IMMEDIATELY
WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. IF IRRITATION PERSISTS, SEEK
PROMPT MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH RUNNING WATER FOR AT LEAST 20 MINUTES. SEEK
IMMEDIATE MEDICAL ATTENTION/ADVICE.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
MAY CAUSE IRRITATION TO THE NOSE, THROAT AND UPPER RESPIRATORY TRACT.
SYMPTOMS MAY INCLUDE PAIN, HEADACHE, NAUSEA, VOMITING, DIZZINESS,
DROWSINESS AND OTHER CENTRAL NERVOUS SYSTEM EFFECTS. MAY CAUSE SKIN
IRRITATION. SYMPTOMS MAY INCLUDE REDNESS, ITCHING AND SWELLING. MAY CAUSE
SEVERE EYE IRRITATION. SYMPTOMS WILL INCLUDE PAIN, REDNESS AND TEARING.
INGESTION MAY CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING AND
DIARRHEA. MAY CAUSE DAMAGE TO THE CENTRAL NERVOUS SYSTEM THROUGH PROLONGED
OR REPEATED EXPOSURE IF INHALED. SUSPECTED OF DAMAGING THE UNBORN CHILD.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
TREAT SYMPTOMATICALLY. ASPIRATION HAZARD THIS PRODUCT IS A CNS DEPRESSANT.
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
DRY CHEMICAL, FOAM, CARBON DIOXIDE AND WATER FOG. DO NOT USE WATER JET,
AS THIS MAY SPREAD BURNING MATERIAL.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE A SOLID WATER STREAM AS IT MAY SCATTER AND SPREAD FIRE.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE / CONDITIONS OF
FLAMMABILITY:
HIGHLY FLAMMABLE LIQUID AND VAPOR.VAPOUR MAY CAUSE FLASH FIRE!
VAPOURS ARE HEAVIER THAN AIR AND MAY SPREAD ALONG FLOORS. VAPOURS MAY
IGNITE EXPLOSIVELY.
FLAMMABILITY CLASSIFICATION (OSHA 29 CFR 1910.106):
FLAMMABLE LIQUID - CATEGORY 2
EXPLOSION DATA:
SENSITIVITY TO MECHANICAL IMPACT / STATIC DISCHARGE:
MAY BE SENSITIVE TO STATIC DISCHARGE. NOT EXPECTED TO BE SENSITIVE TO
MECHANICAL IMPACT.
HAZARDOUS COMBUSTION PRODUCTS:
CARBON OXIDES; ALDEHYDES; HYDROCARBONS; IRRITATING FUMES AND SMOKE.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIREFIGHTERS MUST USE STANDARD PROTECTIVE EQUIPMENT INCLUDING FLAME
RETARDANT COAT, HELMET WITH FACE SHIELD, GLOVES, RUBBER BOOTS, AND IN
ENCLOSED SPACES, SCBA.
SPECIAL FIRE-FIGHTING PROCEDURES:
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
BREATHING APPARATUS WITH FULL FACE PIECE OPERATED IN POSITIVE PRESSURE
MODE. MOVE CONTAINERS FROM FIRE AREA IF SAFE TO DO SO. WATER SPRAY MAY BE
USEFUL IN COOLING EQUIPMENT EXPOSED TO HEAT AND FLAME.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
ALL PERSONS DEALING WITH THE CLEAN-UP SHOULD WEAR THE APPROPRIATE
CHEMICALLY PROTECTIVE EQUIPMENT. KEEP ALL OTHER PERSONNEL UPWIND AND AWAY
FROM THE SPILL/RELEASE. RESTRICT ACCESS TO AREA UNTIL COMPLETION OF
CLEAN-UP. REFER TO PROTECTIVE MEASURES LISTED IN SECTIONS 7 AND 8.
ENVIRONMENTAL PRECAUTIONS:
ENSURE SPILLED PRODUCT DOES NOT ENTER DRAINS, SEWERS, WATERWAYS, OR
CONFINED SPACES. FOR LARGE SPILLS, DIKE THE AREA TO PREVENT SPREADING.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
REMOVE ALL SOURCES OF IGNITION. VENTILATE AREA OF RELEASE. DIKE FOR WATER
CONTROL. STOP SPILL OR LEAK AT SOURCE IF SAFELY POSSIBLE. CONTAIN AND
ABSORB SPILLED LIQUID WITH NON-COMBUSTIBLE, INERT ABSORBENT MATERIAL
(E.G. SAND), THEN PLACE ABSORBENT MATERIAL INTO A CONTAINER FOR LATER
DISPOSAL (SEE SECTION 13). CONTACT THE PROPER LOCAL AUTHORITIES.
SPECIAL SPILL RESPONSE PROCEDURES:
IF A SPILL/RELEASE IN EXCESS OF THE EPA REPORTABLE QUANTITY IS MADE INTO
THE ENVIRONMENT, IMMEDIATELY NOTIFY THE NATIONAL RESPONSE CENTER IN THE
UNITED STATES (PHONE: 1-800-424-8802).
US CERCLA REPORTABLE QUANTITY (RQ): TOLUENE (1000 LBS / 454 KG)
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. USE IN A WELL-VENTILATED AREA.
WEAR PROTECTIVE GLOVES/CLOTHING AND EYE/FACE PROTECTION. AVOID BREATHING
VAPOUR OR MIST. AVOID CONTACT WITH SKIN, EYES AND CLOTHING. KEEP AWAY FROM
HEAT, SPARKS, AND OPEN FLAMES.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT. USE ONLY NON-SPARKING TOOLS.
KEEP AWAY FROM ACIDS AND INCOMPATIBLES. TAKE PRECAUTIONARY MEASURES AGAINST
STATIC DISCHARGES. ALWAYS REPLACE CAP AFTER USE. KEEP CONTAINER TIGHTLY
CLOSED. WASH THOROUGHLY AFTER HANDLING.
CONDITIONS FOR SAFE STORAGE:
STORE LOCKED UP. STORE IN A COOL, DRY, WELL-VENTILATED AREA. KEEP CONTAINER
TIGHTLY CLOSED. STORE AWAY FROM INCOMPATIBLES AND OUT OF DIRECT SUNLIGHT.
STORAGE AREA SHOULD BE CLEARLY IDENTIFIED, CLEAR OF OBSTRUCTION AND
ACCESSIBLE ONLY TO TRAINED AND AUTHORIZED PERSONNEL. INSPECT PERIODICALLY
FOR DAMAGE OR LEAKS. NO SMOKING IN THE AREA.
INCOMPATIBLE MATERIALS:
CARBON OXIDES; ALDEHYDES; HYDROCARBONS; IRRITATING FUMES AND SMOKE.
| SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EXPOSURE LIMITS:
CHEMICAL NAME ACGIH TLV OSHA PEL
TWA STEL PEL STEL
TOLUENE 20 PPM N/AV 200 PPM 300 PPM (CEILING)
ETHYL ALCOHOL N/AV 1000 PPM 1000 PPM N/AV
1900 MG/M3
EXPOSURE CONTROLS:
VENTILATION AND ENGINEERING MEASURES:
USE GENERAL OR LOCAL EXHAUST VENTILATION TO MAINTAIN AIR CONCENTRATIONS
BELOW RECOMMENDED EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
IF THE TLV IS EXCEEDED, A NIOSH/MSHA-APPROVED RESPIRATOR IS ADVISED. ADVICE
SHOULD BE SOUGHT FROM RESPIRATORY PROTECTION SPECIALISTS. RESPIRATORS
SHOULD BE SELECTED BASED ON THE FORM AND CONCENTRATION OF CONTAMINANTS IN
AIR, AND IN ACCORDANCE WITH OSHA (29 CFR 1910.134) OR CSA Z94.4-02.
SKIN PROTECTION:
IMPERVIOUS GLOVES MUST BE WORN WHEN USING THIS PRODUCT. ADVICE SHOULD BE
SOUGHT FROM GLOVE SUPPLIERS.
EYE / FACE PROTECTION:
CHEMICAL SPLASH GOGGLES ARE RECOMMENDED. A FULL FACE SHIELD MAY ALSO BE
NECESSARY.
OTHER PROTECTIVE EQUIPMENT:
WEAR RESISTANT CLOTHING AND BOOTS. AN EYEWASH STATION AND SAFETY SHOWER
SHOULD BE MADE AVAILABLE IN THE IMMEDIATE WORKING AREA.
GENERAL HYGIENE CONSIDERATIONS:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
AVOID BREATHING VAPOUR OR MIST. AVOID CONTACT WITH SKIN, EYES AND CLOTHING.
WASH CONTAMINATED CLOTHING BEFORE REUSE. WASH HANDS THOROUGHLY AFTER USING
THIS PRODUCT, AND BEFORE EATING, DRINKING OR SMOKING.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: CLEAR, RED LIQUID.
ODOUR: SOLVENT ODOUR.
ODOUR THRESHOLD: N/AV
PH: N/AV
MELTING/FREEZING POINT: -30 DEG. C (-22 DEG. F)
INITIAL BOILING POINT AND BOILING RANGE: 78 DEG. C (172 DEG. F)
FLASH POINT: 4.4 DEG. C (40 DEG. F)
FLASHPOINT (METHOD): SETA CLOSED CUP
EVAPORATION RATE (BUAE = 1): >1
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE.
LOWER FLAMMABLE LIMIT (% BY VOL.): N/AV
UPPER FLAMMABLE LIMIT (% BY VOL.): N/AV
OXIDIZING PROPERTIES: NONE KNOWN.
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE
VAPOUR PRESSURE: 19 MMHg
VAPOUR DENSITY: 1.6
RELATIVE DENSITY / SPECIFIC GRAVITY: 0.86
SOLUBILITY IN WATER: PARTIALLY SOLUBLE.
OTHER SOLUBILITY(IES): NOT AVAILABLE.
PARTITION COEFFICIENT N-OCTANOL/WATER OR COEFFICIENT OF WATER/OIL
DISTRIBUTION: N/AV
AUTO-IGNITION TEMPERATURE: N/AV
DECOMPOSITION TEMPERATURE: N/AV
VISCOSITY: <2 CPS
VOLATILES (% BY WEIGHT): >99%
VOLATILE ORGANIC COMPOUNDS (VOC'S): 860 G/L
ABSOLUTE PRESSURE OF CONTAINER: N/AP
FLAME PROJECTION LENGTH: N/AP
OTHER PHYSICAL/CHEMICAL COMMENTS: NONE.
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
THE PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS OF USE,
STORAGE AND TRANSPORT.
CHEMICAL STABILITY:
STABLE UNDER THE RECOMMENDED STORAGE AND HANDLING CONDITIONS PRESCRIBED.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE. HAZARDOUS
POLYMERIZATION DOES NOT OCCUR.
CONDITIONS TO AVOID:
AVOID HEAT AND OPEN FLAME. KEEP AWAY FROM DIRECT SUNLIGHT. ENSURE ADEQUATE
VENTILATION, ESPECIALLY IN CONFINED AREAS.
INCOMPATIBLE MATERIALS:
CARBON OXIDES; ALDEHYDES; HYDROCARBONS; IRRITATING FUMES AND SMOKE.
HAZARDOUS DECOMPOSITION PRODUCTS:
NONE KNOWN, REFER TO HAZARDOUS COMBUSTION PRODUCTS IN SECTION 5.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
ROUTES OF ENTRY INHALATION: YES
ROUTES OF ENTRY SKIN & EYE: YES
ROUTES OF ENTRY INGESTION: YES
ROUTES OF EXPOSURE SKIN ABSORPTION: NO
POTENTIAL HEALTH EFFECTS:
SIGNS AND SYMPTOMS OF SHORT-TERM (ACUTE) EXPOSURE:
SIGN AND SYMPTOMS INHALATION:
MAY CAUSE IRRITATION TO THE NOSE, THROAT AND UPPER RESPIRATORY TRACT.
SYMPTOMS MAY INCLUDE PAIN, HEADACHE, NAUSEA, VOMITING, DIZZINESS,
DROWSINESS AND OTHER CENTRAL NERVOUS SYSTEM EFFECTS.
SIGN AND SYMPTOMS INGESTION:
MAY CAUSE GASTROINTESTINAL IRRITATION. MAY CAUSE NAUSEA, VOMITING,
HEADACHE AND OTHER CENTRAL NERVOUS SYSTEM EFFECTS. ASPIRATION INTO THE
LUNGS DURING SWALLOWING OR SUBSEQUENT VOMITING MAY CAUSE CHEMICAL
PNEUMONITIS, WHICH CAN BE FATAL.
SIGN AND SYMPTOMS SKIN:
THIS MATERIAL IS CLASSIFIED AS HAZARDOUS UNDER OSHA REGULATIONS
(29 CFR 1910.1200) (HAZCOM 2012).
CLASSIFICATION: SKIN IRRITATION - CATEGORY 2 CAUSES SKIN IRRITATION.
SIGN AND SYMPTOMS EYES:
THIS MATERIAL IS CLASSIFIED AS HAZARDOUS UNDER OSHA REGULATIONS
(29 CFR 1910.1200) (HAZCOM 2012).
CLASSIFICATION:
EYE DAMAGE/IRRITATION - CATEGORY 2A CAUSES SERIOUS EYE IRRITATION.
POTENTIAL CHRONIC HEALTH EFFECTS:
PROLONGED OR REPEATED CONTACT MAY CAUSE DRYING, CRACKING AND DEFATTING OF
THE SKIN.
MUTAGENICITY: NOT EXPECTED TO BE MUTAGENIC IN HUMANS.
CARCINOGENICITY:
NO COMPONENTS ARE LISTED AS CARCINOGENS BY ACGIH, IARC, OSHA OR NTP. NOTE
THAT THIS PRODUCT CONTAINS ETHANOL, A CONFIRMED ANIMAL CARCINOGEN (A3) BY
THE ACGIH AND HUMAN CARCINOGEN (GROUP 1) BY THE IARC; HOWEVER, THIS IS
ONLY APPLICABLE WHEN THE CHEMICAL IS PRESENT IN ALCOHOLIC BEVERAGES.
REPRODUCTIVE EFFECTS & TERATOGENICITY:
THIS MATERIAL IS CLASSIFIED AS HAZARDOUS UNDER OSHA REGULATIONS
(29 CFR 1910.1200) (HAZCOM 2012).
CLASSIFICATION:
REPRODUCTIVE TOXICITY - CATEGORY 2 SUSPECTED OF DAMAGING FERTILITY OR THE
UNBORN CHILD IF INHALED.
SENITIZATION TO MATERIAL:
NOT EXPECTED TO BE A SKIN OR RESPIRATORY SENSITIZER.
SPECIFIC TARGET ORGAN EFFECTS:
THIS MATERIAL IS CLASSIFIED AS HAZARDOUS UNDER OSHA REGULATIONS
(29 CFR 1910.1200) (HAZCOM 2012).
CLASSIFICATION:
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE - CATEGORY 3 (CNS)
SPECIFIC TARGET ORGAN TOXICITY, REPEATED EXPOSURE - CATEGORY 2
MAY CAUSE DROWSINESS OR DIZZINESS.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
IRRITANCY:
SEVERE EYE IRRITANT. MAY CAUSE RESPIRATORY IRRITATION. SKIN IRRITATION
MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE:
PRE-EXISTING SKIN, EYE, RESPIRATORY AND CENTRAL NERVOUS SYSTEM DISORDERS.
SYNERGISTIC MATERIALS: NONE KNOWN OR REPORTED BY THE MANUFACTURER.
TOXICOLOGICAL DATA:
SEE BELOW FOR INDIVIDUAL INGREDIENT ACUTE TOXICITY DATA.
CHEMICAL NAME LC50(4HR) LD50
INH, RAT (ORAL, RAT) (RABBIT, DERMAL)
TOLUENE 7585 PPM 5580 MG/KG 12 125 MG/KG
(28.1 MG/L)
ETHYL ALCOHOL >32 380 PPM 7060 MG/KG >15 800 MG/KG
OTHER IMPORTANT TOXICOLOGICAL HAZARDS: NONE KNOWN.
| SECTION 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS. DO NOT ALLOW MATERIAL
TO CONTAMINATE GROUND WATER SYSTEM. SEE THE FOLLOWING TABLES FOR INDIVIDUAL
INGREDIENT ECOTOXICITY DATA.
ECOTOXICITY DATA:
INGREDIENTS CAS NO TOXICITY TO FISH
LC50 / 96H NOEC / 21 DAY M FACTOR
INGREDIENTS CAS NO TOXICITY TO DAPHNIA
EC50 / 48H NOEC / 21 DAY M FACTOR
INGREDIENTS CAS NO TOXICITY TO ALGAE
EC50 / 96H OR 72H NOEC / 96H OR 72H M FACTOR
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE PRODUCT ITSELF. THIS PRODUCT CONTAINS:
TOLUENE; ETHANOL.
TOLUENE IS CONSIDERED TO BE READILY BIODEGRADABLE.
ETHANOL IS CONSIDERED TO BE READILY BIODEGRADABLE.
BIOACCUMULATION POTENTIAL:
NO DATA IS AVAILABLE ON THE PRODUCT ITSELF. THIS PRODUCT CONTAINS: TOLUENE.
THE LOG KOW VALUE FOR TOLUENE IS 2.65, AND ITS BIOCONCENTRATION FACTOR
(BCF) IS 90 (OECD).
MOBILITY IN SOIL: NO DATA IS AVAILABLE ON THE PRODUCT ITSELF.
OTHER ADVERSE ENVIRONMENTAL EFFECTS:
NO DATA IS AVAILABLE ON THE PRODUCT ITSELF.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
HANDLING FOR DISPOSAL:
HANDLE WASTE ACCORDING TO RECOMMENDATIONS IN SECTION 7. EMPTY CONTAINERS
RETAIN RESIDUE (LIQUID AND/OR VAPOUR) AND CAN BE DANGEROUS.
METHODS OF DISPOSAL:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, PROVINCIAL AND
LOCAL REGULATIONS.
RCRA:
IF THIS PRODUCT, AS SUPPLIED, BECOMES A WASTE IN THE UNITED STATES, IT MAY
MEET THE CRITERIA OF A HAZARDOUS WASTE AS DEFINED UNDER RCRA, TITLE 40 CFR
261. IT IS THE RESPONSIBILITY OF THE WASTE GENERATOR TO DETERMINE THE
PROPER WASTE IDENTIFICATION AND DISPOSAL METHOD. FOR DISPOSAL OF UNUSED OR
WASTE MATERIAL, CHECK WITH LOCAL, STATE AND FEDERAL ENVIRONMENTAL AGENCIES.
| SECTION 14. TRANSPORTATION INFORMATION | |
REGULATORY UN UN PROPER SHIPPING TRANSPORT PACKING LABEL
INFORMATION NUMBER NAME HAZARD GROUP
CLASS(ES)
49 CFR/DOT UN1993 FLAMMABLE LIQUIDS, 3 II FLAMMABLE
N.O.S. (TOLUENE; LIQUID,
ETHANOL) CLASS/
DIVISION
3.1, 3.2,
3.3
49 CFR/DOT MAY BE SHIPPED AS A LIMITED QUANTITY ACCORDING TO PACKAGING
ADDITIONAL SECTION 173.150. REFER TO 49 CFR SECTION 173.150.
INFORMATION
TDG UN1993 FLAMMABLE LIQUID, 3 II CLASS 3,
N.O.S. (TOLUENE; FLAMMABLE
ETHANOL) LIQUIDS
TDG WITHIN CANADA, THE LIMITED QUANTITY EXEMPTION MAY APPLY
ADDITIONAL FOR CONTAINERS WHICH HOLD SPECIFIC QUANTITIES OF THE
INFORMATION PRODUCT. UNDER THE TDGR, REFER TO SECTION 1.17 FOR LIMITED
QUANTITY EXEMPTION INFORMATION, IF SHIPPING UNDER THIS
EXEMPTION.
ICAO/IATA UN1993 FLAMMABLE LIQUID, 3 II CLASS 3,
N.O.S. (TOLUENE; FLAMMABLE
ETHANOL) LIQUIDS
ICAO/IATA PRODUCT MAY BE RECLASSIFIED FOR AIR TRANSPORTATION IF
ADDITIONAL PACKAGED IN ACCORDANCE WITH IATA REGULATIONS
INFORMATION (I.E. ID 8000, CONSUMER COMMODITY, CLASS 9).
SPECIAL PRECAUTIONS FOR USER:
ENVIRONMENTAL HAZARDS: SEE ECOLOGICAL INFORMATION, SECTION 12.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
| SECTION 15. REGULATORY INFORMATION | |
US FEDERAL INFORMATION:
COMPONENTS LISTED BELOW ARE PRESENT ON THE FOLLOWING U.S. FEDERAL CHEMICAL
LISTS:
INGREDIENTS CAS # TSCA INVENTORY CERCLA REPORTABLE
QUANTITY(RQ)
(40 CFR 117.302):
TOLUENE 108-88-3 YES 1000 LB/454 KG
ETHYL ALCOHOL 64-17-5 YES N/AP
INGREDIENTS SARA TITLE III: SARA TITLE III:
SEC. 302, EXTREMELY SEC. 313, 40 CFR 372,
HAZARDOUS SUBSTANCE, SPECIFIC TOXIC CHEMICAL
40 CFR 355: TOXIC CHEMICAL DE MINIMUS
CONCENTRATION
TOLUENE NONE. YES 1%
ETHYL ALCOHOL NONE. NO NS
US STATE RIGHT TO KNOW LAWS:
THE FOLLOWING CHEMICALS ARE SPECIFICALLY LISTED BY INDIVIDUAL STATES:
INGREDIENTS CAS # CALIFORNIA PROPOSITION 65
LISTED TYPE OF TOXICITY
TOLUENE 108-88-3 NO DEVELOPMENTAL
ETHYL ALCOHOL 64-17-5 YES DEVELOPMENTAL TOXICI
INGREDIENTS STATE "RIGHT TO KNOW" LISTS
CA MA MN NJ PA RI
TOLUENE YES YES YES YES YES YES
ETHYL ALCOHOL YES YES YES YES YES YES
CANADIAN INFORMATION:
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) INFORMATION:
ALL INGREDIENTS LISTED APPEAR ON THE DOMESTIC SUBSTANCES LIST (DSL).
WHMIS INFORMATION:
REFER TO SECTION 2 FOR A WHMIS CLASSIFICATION FOR THIS PRODUCT.
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
CPR AND THE MSDS CONTAINS ALL OF THE INFORMATION REQUIRED BY THE CPR.
INTERNATIONAL INFORMATION:
COMPONENTS LISTED BELOW ARE PRESENT ON THE FOLLOWING INTERNATIONAL
INVENTORY LIST:
INGREDIENTS CAS # EUROPEAN AUSTRALIA PHILIPPINES
EINECS AICS PICCS
TOLUENE 108-88-3 203-625-9 PRESENT PRESENT
ETHYL ALCOHOL 64-17-5 200-578-6 PRESENT PRESENT
INGREDIENTS JAPAN ENCS KOREA CHINA NEWZEALAND
KECI/KECL IECSC IOC
TOLUENE (3)-2 KE-33936 PRESENT HSR001227
ETHYL ALCOHOL (2)-202 KE-13217 PRESENT HSR001144
| SECTION 16. OTHER INFORMATION | |
LEGEND:
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
CA: CALIFORNIA
CAS: CHEMICAL ABSTRACT SERVICES
CERCLA:
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT OF
1980
CFR: CODE OF FEDERAL REGULATIONS
CNS: CENTRAL NERVOUS SYSTEM
DOT: DEPARTMENT OF TRANSPORTATION
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
HSDB: HAZARDOUS SUBSTANCES DATA BANK
IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
INH: INHALATION
LC: LETHAL CONCENTRATION
LD: LETHAL DOSE
MA: MASSACHUSETTS
MN: MINNESOTA
MSHA: MINE SAFETY AND HEALTH ADMINISTRATION
N/AP: NOT APPLICABLE
N/AV: NOT AVAILABLE
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION
NJ: NEW JERSEY
NIOSH: NATIONAL INSTITUTE OF OCCUPATIONAL SAFETY AND HEALTH
NTP: NATIONAL TOXICOLOGY PROGRAM
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
PA: PENNSYLVANIA
PEL: PERMISSIBLE EXPOSURE LIMIT
RCRA: RESOURCE CONSERVATION AND RECOVERY ACT
RI: RHODE ISLAND
RTECS: REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES
SARA: SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT
STEL: SHORT TERM EXPOSURE LIMIT
TDG: CANADIAN TRANSPORTATION OF DANGEROUS GOODS ACT & REGULATIONS
TLV: THRESHOLD LIMIT VALUES
TWA: TIME WEIGHTED AVERAGE
WHMIS: WORKPLACE HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
REFERENCES:
CANADIAN CENTRE FOR OCCUPATIONAL HEALTH AND SAFETY, CCINFOWEB DATABASES,
2015 (CHEMPENDIUM, RTECS, HSDB, INCHEM).
EUROPEAN CHEMICALS AGENCY, CLASSIFICATION LEGISLATION, 2015
OECD-THE GLOBAL PORTAL TO INFORMATION ON CHEMICAL SUBSTANCES - ECHEMPORTAL,
2015
MATERIAL SAFETY DATA SHEET FROM MANUFACTURER
PREPARATION DATE (MM/DD/YYYY): 08/23/2012
REVIEWED DATE SDS (DD/MM/YYYY): 20/04/2015
REVISION NO.: 2
REVISION INFORMATION: ALL (FORMAT CHANGE)
OTHER SPECIAL CONSIDERATIONS FOR HANDLING:
HMIS RATING:
* - CHRONIC HAZARD
0 - MINIMAL
1 - SLIGHT
2 - MODERATE
3 - SERIOUS
4 - SEVERE
HEALTH 2*
FLAMMABILITY 3
REACTIVITY 0
NFPA RATING:
0 - MINIMAL
1 - SLIGHT
2 - MODERATE
3 - SERIOUS
4 - SEVERE
HEALTH 2
FLAMMABILITY 3
INSTABILITY 0
SPECIAL HAZARDS NONE.
PREPARED FOR:
PARKER HANNIFIN CORPORATION - SPORLAN DIVISION
206 LANGE DRIVE
WASHINGTON, MO, 63090
U.S.A.
TELEPHONE: (636) 239-1111
WWW.PARKER.COM
DIRECT ALL ENQUIRIES TO: PARKER HANNIFIN CORPORATION - SPORLAN DIVISION.
PREPARED BY: ICC THE COMPLIANCE CENTER INC.
TELEPHONE:
(888) 442-9628 (U.S.)
(888) 977-4834 (CANADA)
HTTP://WWW.THECOMPLIANCECENTER.COM
PARKER
ICC COMPLIANCE CENTER
DISCLAIMER:
THIS MATERIAL SAFETY DATA SHEET WAS PREPARED BY ICC THE COMPLIANCE CENTER
INC. USING INFORMATION PROVIDED BY / OBTAINED FROM PARKER HANNIFIN CORP
AND CCOHS' WEB INFORMATION SERVICE. THE INFORMATION IN THE MATERIAL SAFETY
DATA SHEET IS OFFERED FOR YOUR CONSIDERATION AND GUIDANCE WHEN EXPOSED TO
THIS PRODUCT. ICC THE COMPLIANCE CENTER INC AND PARKER HANNIFIN CORP
EXPRESSLY DISCLAIM ALL EXPRESSED OR IMPLIED WARRANTIES AND ASSUME NO
RESPONSIBILITIES FOR THE ACCURACY OR COMPLETENESS OF THE DATA CONTAINED
HEREIN. THE DATA IN THIS MSDS DOES NOT APPLY TO USE WITH ANY OTHER PRODUCT
OR IN ANY OTHER PROCESS.
THIS MATERIAL SAFETY DATA SHEET MAY NOT BE CHANGED, OR ALTERED IN ANY WAY
WITHOUT THE EXPRESSED KNOWLEDGE AND PERMISSION OF ICC THE COMPLIANCE CENTER
INC. AND PARKER HANNIFIN CORP.