| Common Name: | D3 CITRUS DEGREASER |
| Manufacturer: | SPRAYWAY |
| SDS Revision Date: | 3/30/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 45A997 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SPRAYWAY(R*)
SAFETY DATA SHEET
| 1. IDENTIFICATION |  |
PRODUCT NUMBER: 1000008626
PRODUCT IDENTIFIER: D3 CITRUS DEGREASER
REVISION DATE: 03-30-2016
COMPANY INFORMATION:
SPRAYWAY, INC.
1005 S. WESTGATE DRIVE
ADDISON, IL 60101 UNITED STATES
COMPANY PHONE:
GENERAL ASSISTANCE: 1-630-628-3000
EMERGENCY TELEPHONE US: 1-866-836-8855
EMERGENCY TELEPHONE OUTSIDE US: 1-952-852-4646
VERSION #: 05
SUPERSEDES DATE: 02-15-2016
RECOMMENDED USE: DEGREASER
RECOMMENDED RESTRICTIONS: NONE KNOWN.
| 2. HAZARD(S) IDENTIFICATION | |
PHYSICAL HAZARDS:
FLAMMABLE AEROSOLS: CATEGORY 1
HEALTH HAZARDS:
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2
SENSITIZATION, SKIN: CATEGORY 1
ASPIRATION HAZARD: CATEGORY 1
OSHA DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS:
FLAME
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENT:
EXTREMELY FLAMMABLE AEROSOL. MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES SERIOUS EYE IRRITATION.
PRECAUTIONARY STATEMENT:
PREVENTION:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. DO NOT
SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE. PRESSURIZED CONTAINER: DO
NOT PIERCE OR BURN, EVEN AFTER USE. AVOID BREATHING GAS. WASH THOROUGHLY
AFTER HANDLING. CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE
WORKPLACE. AVOID RELEASE TO THE ENVIRONMENT. WEAR EYE PROTECTION/FACE
PROTECTION. WEAR PROTECTIVE GLOVES.
RESPONSE:
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER/DOCTOR. DO NOT INDUCE VOMITING.
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ADVICE/ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE.
COLLECT SPILLAGE.
STORAGE:
STORE LOCKED UP. PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES
EXCEEDING 50 DEG. C/122 DEG. F.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
ENVIRONMENTAL HAZARDS:
HAZARDOUS TO THE AQUATIC ENVIRONMENT, ACUTE HAZARD: CATEGORY 2
HAZARDOUS TO THE AQUATIC ENVIRONMENT, LONG-TERM HAZARD: CATEGORY 2
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): COMBUSTIBLE.
SUPPLEMENTAL INFORMATION: NONE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
CHEMICAL NAME COMMON NAME CAS NUMBER %
AND SYNONYMS
DIETHYLENE GLYCOL MONOBUTYL ETHER 112-34-5 20 - 40
DISTILLATES (PETROLEUM), 64742-47-8 20 - 40
HYDROTREATED LIGHT
ACETONE 67-64-1 10 - 20
DIMETHYL ADIPATE 627-93-0 10 - 20
CARBON DIOXIDE 124-38-9 2.5 - 10
D-LIMONENE 5989-27-5 2.5 - 10
ETHOXYLATED ALCOHOL 34398-01-1 2.5 - 10
DIMETHYL GLUTARATE 1119-40-0 1 - 2.5
OTHER COMPONENTS BELOW REPORTABLE 0.1 - 1
LEVELS
*DESIGNATES THAT A SPECIFIC CHEMICAL IDENTITY AND/OR PERCENTAGE OF
COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| 4. FIRST-AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. CALL A PHYSICIAN IF SYMPTOMS DEVELOP OR PERSIST.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND WASH SKIN WITH SOAP AND WATER.
IN CASE OF ECZEMA OR OTHER SKIN DISORDERS: SEEK MEDICAL ATTENTION AND TAKE
ALONG THESE INSTRUCTIONS.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. REMOVE
CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS AND PERSISTS.
INGESTION:
CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. RINSE MOUTH. DO NOT
INDUCE VOMITING. IF VOMITING OCCURS, KEEP HEAD LOW SO THAT STOMACH CONTENT
DOESN'T GET INTO THE LUNGS.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
ASPIRATION MAY CAUSE PULMONARY EDEMA AND PNEUMONITIS. SEVERE EYE
IRRITATION. SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND
BLURRED VISION. MAY CAUSE AN ALLERGIC SKIN REACTION. DERMATITIS. RASH.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY. KEEP VICTIM
UNDER OBSERVATION. SYMPTOMS MAY BE DELAYED.
GENERAL INFORMATION:
ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED, AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES. WASH CONTAMINATED CLOTHING BEFORE
REUSE.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
ALCOHOL RESISTANT FOAM. POWDER. DRY CHEMICALS. CARBON DIOXIDE (CO2).
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
CONTENTS UNDER PRESSURE. PRESSURIZED CONTAINER MAY EXPLODE WHEN EXPOSED TO
HEAT OR FLAME. DURING FIRE, GASES HAZARDOUS TO HEALTH MAY BE FORMED.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
FIREFIGHTERS MUST USE STANDARD PROTECTIVE EQUIPMENT INCLUDING FLAME
RETARDANT COAT, HELMET WITH FACE SHIELD, GLOVES, RUBBER BOOTS, AND IN
ENCLOSED SPACES, SCBA.
FIRE FIGHTING EQUIPMENT/INSTRUCTIONS:
MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO SO WITHOUT RISK. COOL
CONTAINERS EXPOSED TO HEAT WITH WATER SPRAY AND REMOVE CONTAINER, IF NO
RISK IS INVOLVED. CONTAINERS SHOULD BE COOLED WITH WATER TO PREVENT VAPOR
PRESSURE BUILD UP. FOR MASSIVE FIRE IN CARGO AREA, USE UNMANNED HOSE HOLDER
OR MONITOR NOZZLES, IF POSSIBLE. IF NOT, WITHDRAW AND LET FIRE BURN OUT.
SPECIFIC METHODS:
USE STANDARD FIREFIGHTING PROCEDURES AND CONSIDER THE HAZARDS OF OTHER
INVOLVED MATERIALS. MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO SO WITHOUT
RISK. IN THE EVENT OF FIRE AND/OR EXPLOSION DO NOT BREATHE FUMES.
GENERAL FIRE HAZARDS: EXTREMELY FLAMMABLE AEROSOL. COMBUSTIBLE.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND CLOTHING DURING
CLEAN-UP. AVOID BREATHING GAS. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED
MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING. VENTILATE CLOSED
SPACES BEFORE ENTERING THEM. LOCAL AUTHORITIES SHOULD BE ADVISED IF
SIGNIFICANT SPILLAGES CANNOT BE CONTAINED. FOR PERSONAL PROTECTION, SEE
SECTION 8 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
REFER TO ATTACHED SAFETY DATA SHEETS AND/OR INSTRUCTIONS FOR USE. STOP LEAK
IF YOU CAN DO SO WITHOUT RISK. MOVE THE CYLINDER TO A SAFE AND OPEN AREA IF
THE LEAK IS IRREPARABLE. USE WATER SPRAY TO REDUCE VAPORS OR DIVERT VAPOR
CLOUD DRIFT. ISOLATE AREA UNTIL GAS HAS DISPERSED. ELIMINATE ALL IGNITION
SOURCES (NO SMOKING, FLARES, SPARKS, OR FLAMES IN IMMEDIATE AREA). KEEP
COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM SPILLED MATERIAL. PREVENT
ENTRY INTO WATERWAYS, SEWER, BASEMENTS OR CONFINED AREAS. ABSORB IN
VERMICULITE, DRY SAND OR EARTH AND PLACE INTO CONTAINERS. FOLLOWING PRODUCT
RECOVERY, FLUSH AREA WITH WATER.
SMALL SPILLS:
WIPE UP WITH ABSORBENT MATERIAL (E.G. CLOTH, FLEECE). CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. FOR WASTE DISPOSAL, SEE
SECTION 13 OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. INFORM APPROPRIATE MANAGERIAL OR
SUPERVISORY PERSONNEL OF ALL ENVIRONMENTAL RELEASES. PREVENT FURTHER
LEAKAGE OR SPILLAGE IF SAFE TO DO SO. AVOID DISCHARGE INTO DRAINS, WATER
COURSES OR ONTO THE GROUND.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PRESSURIZED CONTAINER:
DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT USE IF SPRAY BUTTON IS
MISSING OR DEFECTIVE. DO NOT SPRAY ON A NAKED FLAME OR ANY OTHER
INCANDESCENT MATERIAL. DO NOT SMOKE WHILE USING OR UNTIL SPRAYED SURFACE IS
THOROUGHLY DRY. DO NOT CUT, WELD, SOLDER, DRILL, GRIND, OR EXPOSE
CONTAINERS TO HEAT, FLAME, SPARKS, OR OTHER SOURCES OF IGNITION. ALL
EQUIPMENT USED WHEN HANDLING THE PRODUCT MUST BE GROUNDED. DO NOT RE-USE
EMPTY CONTAINERS. AVOID BREATHING GAS. AVOID CONTACT WITH EYES, SKIN, AND
CLOTHING. AVOID PROLONGED OR REPEATED CONTACT WITH SKIN. AVOID PROLONGED
EXPOSURE. USE ONLY IN WELL-VENTILATED AREAS. WEAR APPROPRIATE PERSONAL
PROTECTIVE EQUIPMENT. WASH HANDS THOROUGHLY AFTER HANDLING. AVOID RELEASE
TO THE ENVIRONMENT. OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
LEVEL 3 AEROSOL.
STORE LOCKED UP. PRESSURIZED CONTAINER. PROTECT FROM SUNLIGHT AND DO NOT
EXPOSE TO TEMPERATURES EXCEEDING 50 DEG. C/122 DEG. F. DO NOT PUNCTURE,
INCINERATE OR CRUSH. DO NOT HANDLE OR STORE NEAR AN OPEN FLAME, HEAT OR
OTHER SOURCES OF IGNITION. THIS MATERIAL CAN ACCUMULATE STATIC CHARGE WHICH
MAY CAUSE SPARK AND BECOME AN IGNITION SOURCE. STORE AWAY FROM INCOMPATIBLE
MATERIALS (SEE SECTION 10 OF THE SDS).
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
ACETONE (CAS 67-64-1) PEL 2400 MG/M3
1000 PPM
CARBON DIOXIDE (CAS 124-38-9) PEL 9000 MG/M3
5000 PPM
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE FORM
ACETONE (CAS 67-64-1) STEL 500 PPM
TWA 250 PPM
CARBON DIOXIDE (CAS 124-38-9) STEL 30000 PPM
TWA 5000 PPM
DIETHYLENE GLYCOL MONOBUTYL TWA 10 PPM INHALABLE FRACTION
ETHER (CAS 112-34-5) AND VAPOR.
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
COMPONENTS TYPE VALUE
ACETONE (CAS 67-64-1) TWA 590 MG/M3
250 PPM
CARBON DIOXIDE (CAS 124-38-9) STEL 54000 MG/M3
30000 PPM
TWA 9000 MG/M3
5000 PPM
BIOLOGICAL LIMIT VALUES:
ACGIH BIOLOGICAL EXPOSURE INDICES:
COMPONENTS VALUE DETERMINANT SPECIMEN SAMPLING TIME
ACETONE (CAS 67-64-1) 25 MG/L ACETONE URINE *
* - FOR SAMPLING DETAILS, PLEASE SEE THE SOURCE DOCUMENT.
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE
USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE, USE
PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. IF
EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN
ACCEPTABLE LEVEL. PROVIDE EYEWASH STATION.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
FACE SHIELD IS RECOMMENDED. WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR
GOGGLES).
SKIN PROTECTION:
HAND PROTECTION:
WEAR APPROPRIATE CHEMICAL RESISTANT GLOVES. SUITABLE GLOVES CAN BE
RECOMMENDED BY THE GLOVE SUPPLIER.
OTHER:
WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING. USE OF AN IMPERVIOUS APRON IS
RECOMMENDED.
RESPIRATORY PROTECTION:
IF PERMISSIBLE LEVELS ARE EXCEEDED USE NIOSH MECHANICAL FILTER / ORGANIC
VAPOR CARTRIDGE OR AN AIR-SUPPLIED RESPIRATOR.
THERMAL HAZARDS:
WEAR APPROPRIATE THERMAL PROTECTIVE CLOTHING, WHEN NECESSARY.
GENERAL HYGIENE CONSIDERATIONS:
WHEN USING DO NOT SMOKE. ALWAYS OBSERVE GOOD PERSONAL HYGIENE MEASURES,
SUCH AS WASHING AFTER HANDLING THE MATERIAL AND BEFORE EATING, DRINKING,
AND/OR SMOKING. ROUTINELY WASH WORK CLOTHING AND PROTECTIVE EQUIPMENT TO
REMOVE CONTAMINANTS. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT
OF THE WORKPLACE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: GAS.
FORM: AEROSOL.
COLOR: NOT AVAILABLE.
ODOR: NOT AVAILABLE.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT/FREEZING POINT: NOT AVAILABLE.
INITIAL BOILING POINT AND BOILING RANGE:
347.49 DEG. F (175.27 DEG. C) ESTIMATED
FLASH POINT: -156.0 DEG. F (-104.4 DEG. C) PROPELLANT ESTIMATED
EVAPORATION RATE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): 1.4% ESTIMATED
FLAMMABILITY LIMIT - UPPER (%): 9.8% ESTIMATED
EXPLOSIVE LIMIT - LOWER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - UPPER (%): NOT AVAILABLE.
VAPOR PRESSURE: 60 - 70 PSIG @20C ESTIMATED
VAPOR DENSITY: NOT AVAILABLE.
RELATIVE DENSITY: NOT AVAILABLE.
SOLUBILITY(IES):
SOLUBILITY (WATER): NOT AVAILABLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: 430.79 DEG. F (221.55 DEG. C) ESTIMATED
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: NOT AVAILABLE.
OTHER INFORMATION:
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE.
OXIDIZING PROPERTIES: NOT OXIDIZING.
SPECIFIC GRAVITY: 0.897 ESTIMATED
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
THE PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS OF USE,
STORAGE AND TRANSPORT.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
CONDITIONS TO AVOID:
AVOID TEMPERATURES EXCEEDING THE FLASH POINT. CONTACT WITH INCOMPATIBLE
MATERIALS.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
NO HAZARDOUS DECOMPOSITION PRODUCTS ARE KNOWN.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION: PROLONGED INHALATION MAY BE HARMFUL.
SKIN CONTACT: MAY CAUSE AN ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION:
DROPLETS OF THE PRODUCT ASPIRATED INTO THE LUNGS THROUGH INGESTION OR
VOMITING MAY CAUSE A SERIOUS CHEMICAL PNEUMONIA.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
ASPIRATION MAY CAUSE PULMONARY EDEMA AND PNEUMONITIS. SEVERE EYE
IRRITATION. SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING,
AND BLURRED VISION. MAY CAUSE AN ALLERGIC SKIN REACTION. DERMATITIS.
RASH.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS. MAY CAUSE AN ALLERGIC SKIN
REACTION.
COMPONENTS SPECIES TEST RESULTS
ACETONE (CAS 67-64-1):
ACUTE:
DERMAL:
LD50 GUINEA PIG >7426 MG/KG, 24 HOURS
>9.4 ML/KG, 24 HOURS
RABBIT >7426 MG/KG, 24 HOURS
>9.4 ML/KG, 24 HOURS
INHALATION:
LC50 RAT 55700 PPM, 3 HOURS
132 MG/L, 3 HOURS
50.1 MG/L
ORAL:
LD50 RAT 5800 MG/KG
2.2 ML/KG
DIETHYLENE GLYCOL MONOBUTYL ETHER (CAS 112-34-5):
ACUTE:
DERMAL:
LD50 RABBIT 2764 MG/KG, 24 HOURS
RAT 2021 MG/KG
INHALATION:
LC50 RAT 74 MG/L/4H
ORAL:
LD100 RABBIT 4000 MG/KG
LD50 GUINEA PIG 2000 MG/KG
MOUSE 2410 MG/KG
RABBIT 2500 - 3000 MG/KG
RAT 7291 MG/KG
DIMETHYL ADIPATE (CAS 627-93-0):
ACUTE:
DERMAL:
LD50 RABBIT >1000 MG/KG, 24 HOURS
RAT >2000 MG/KG, 24 HOURS
INHALATION:
LC50 RAT >11 MG/L, 4 HOURS
ORAL:
LD50 RAT >2000 MG/KG
DIMETHYL GLUTARATE (CAS 1119-40-0):
ACUTE:
DERMAL:
LD50 RAT >2000 MG/KG, 24 HOURS
INHALATION:
LC50 RAT >11 MG/L, 4 HOURS
ORAL:
LD50 RAT >2000 MG/KG
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-47-8):
ACUTE:
DERMAL:
LD50 RABBIT >2000 MG/KG
>2000 MG/KG, 24 HOURS
INHALATION:
LC50 RAT >7.5 MG/L, 6 HOURS
>4.6 MG/L, 4 HOURS
ORAL:
LD50 RAT >5000 MG/KG
D-LIMONENE (CAS 5989-27-5):
ACUTE:
ORAL:
LD50 RAT >2000 MG/KG
* ESTIMATES FOR PRODUCT MAY BE BASED ON ADDITIONAL COMPONENT DATA NOT
SHOWN.
SKIN CORROSION/IRRITATION:
PROLONGED SKIN CONTACT MAY CAUSE TEMPORARY IRRITATION.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
RESPIRATORY OR SKIN SENSITIZATION:
RESPIRATORY SENSITIZATION: NOT A RESPIRATORY SENSITIZER.
SKIN SENSITIZATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
CARCINOGENICITY:
THIS PRODUCT IS NOT CONSIDERED TO BE A CARCINOGEN BY IARC, ACGIH, NTP, OR
OSHA.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY:
D-LIMONENE (CAS 5989-27-5):
3 NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
NOT REGULATED.
US. NATIONAL TOXICOLOGY PROGRAM (NTP) REPORT ON CARCINOGENS: NOT LISTED.
REPRODUCTIVE TOXICITY:
THIS PRODUCT IS NOT EXPECTED TO CAUSE REPRODUCTIVE OR DEVELOPMENTAL
EFFECTS.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NOT CLASSIFIED.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED.
ASPIRATION HAZARD: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
CHRONIC EFFECTS: PROLONGED INHALATION MAY BE HARMFUL.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
COMPONENTS SPECIES TEST RESULTS
ACETONE (CAS 67-64-1):
AQUATIC:
CRUSTACEA EC50 WATER FLEA (DAPHNIA MAGNA) 21.6 - 23.9 MG/L, 48
HOURS
FISH LC50 RAINBOW TROUT, DONALDSON TROUT 4740 - 6330 MG/L, 96
(ONCORHYNCHUS MYKISS) HOURS
DIETHYLENE GLYCOL MONOBUTYL ETHER (CAS 112-34-5):
AQUATIC:
CRUSTACEA EC50 DAPHNIA 2803 MG/L, 48 HOURS
FISH LC50 BLUEGILL (LEPOMIS MACROCHIRUS) 1300 MG/L, 96 HOURS
FISH 1304 MG/L, 96 HOURS
DIMETHYL GLUTARATE (CAS 1119-40-0):
AQUATIC:
CRUSTACEA EC50 DAPHNIA 142.8 MG/L, 48 HOURS
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-47-8):
AQUATIC:
FISH LC50 RAINBOW TROUT, DONALDSON TROUT 2.9 MG/L, 96 HOURS
(ONCORHYNCHUS MYKISS)
D-LIMONENE (CAS 5989-27-5):
AQUATIC:
CRUSTACEA EC50 WATER FLEA (DAPHNIA PULEX) 69.6 MG/L, 48 HOURS
FISH LC50 FATHEAD MINNOW (PIMEPHALES 0.619 - 0.796 MG/L,
PROMELAS) 96 HOURS
ETHOXYLATED ALCOHOL (CAS 34398-01-1):
AQUATIC:
CRUSTACEA EC50 WATER FLEA (DAPHNIA MAGNA) 1.6 - 2.5 MG/L, 48
HOURS
FISH LC50 FATHEAD MINNOW (PIMEPHALES 3.2 - 5 MG/L, 96 HOURS
PROMELAS)
* ESTIMATES FOR PRODUCT MAY BE BASED ON ADDITIONAL COMPONENT DATA NOT
SHOWN.
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF THIS PRODUCT.
BIOACCUMULATIVE POTENTIAL:
PARTITION COEFFICIENT N-OCTANOL / WATER (LOG KOW):
ACETONE: -0.24
DIETHYLENE GLYCOL MONOBUTYL ETHER: 0.56
DIMETHYL ADIPATE: 1.03
D-LIMONENE: 4.232
MOBILITY IN SOIL: NO DATA AVAILABLE.
OTHER ADVERSE EFFECTS:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION, PHOTOCHEMICAL
OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION, GLOBAL WARMING POTENTIAL)
ARE EXPECTED FROM THIS COMPONENT.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS:
COLLECT AND RECLAIM OR DISPOSE IN SEALED CONTAINERS AT LICENSED WASTE
DISPOSAL SITE. CONTENTS UNDER PRESSURE. DO NOT PUNCTURE, INCINERATE OR
CRUSH. DO NOT ALLOW THIS MATERIAL TO DRAIN INTO SEWERS/WATER SUPPLIES. DO
NOT CONTAMINATE PONDS, WATERWAYS OR DITCHES WITH CHEMICAL OR USED
CONTAINER. DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
LOCAL DISPOSAL REGULATIONS:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE:
THE WASTE CODE SHOULD BE ASSIGNED IN DISCUSSION BETWEEN THE USER, THE
PRODUCER AND THE WASTE DISPOSAL COMPANY.
WASTE FROM RESIDUES / UNUSED PRODUCTS:
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS. EMPTY CONTAINERS OR LINERS
MAY RETAIN SOME PRODUCT RESIDUES. THIS MATERIAL AND ITS CONTAINER MUST BE
DISPOSED OF IN A SAFE MANNER (SEE: DISPOSAL INSTRUCTIONS).
CONTAMINATED PACKAGING:
SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS
EVEN AFTER CONTAINER IS EMPTIED. EMPTY CONTAINERS SHOULD BE TAKEN TO AN
APPROVED WASTE HANDLING SITE FOR RECYCLING OR DISPOSAL. DO NOT RE-USE EMPTY
CONTAINERS.
| 14. TRANSPORT INFORMATION | |
DOT:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME:
AEROSOLS, FLAMMABLE, (EACH NOT EXCEEDING 1 L CAPACITY)
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.1
SUBSIDIARY RISK:
LABEL(S): 2.1
PACKING GROUP: NOT APPLICABLE.
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
SPECIAL PROVISIONS: N82
PACKAGING EXCEPTIONS: 306
PACKAGING NON BULK: NONE
PACKAGING BULK: NONE
THIS PRODUCT MEETS THE EXCEPTION REQUIREMENTS OF SECTION 173.306 AS A
LIMITED QUANTITY AND MAY BE SHIPPED AS A LIMITED QUANTITY. UNTIL
12/31/2020, THE "CONSUMER COMMODITY - ORM-D" MARKING MAY STILL BE USED IN
PLACE OF THE NEW LIMITED QUANTITY DIAMOND MARK FOR PACKAGES OF UN 1950
AEROSOLS. LIMITED QUANTITIES REQUIRE THE LIMITED QUANTITY DIAMOND MARK ON
CARTONS AFTER 12/31/20 AND MAY BE USED NOW IN PLACE OF THE "CONSUMER
COMMODITY ORM-D" MARKING AND BOTH MAY BE DISPLAYED CONCURRENTLY.
IATA:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.1
SUBSIDIARY RISK:
LABEL(S): 2.1
PACKING GROUP: NOT APPLICABLE.
ENVIRONMENTAL HAZARDS: YES
ERG CODE: 10L
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
OTHER INFORMATION:
PASSENGER AND CARGO AIRCRAFT: ALLOWED WITH RESTRICTIONS.
CARGO AIRCRAFT ONLY: ALLOWED WITH RESTRICTIONS.
PACKAGING EXCEPTIONS: LTD QTY
IMDG:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME: AEROSOLS
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.1
SUBSIDIARY RISK:
LABEL(S): 2.1
PACKING GROUP: NOT APPLICABLE.
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: YES
EMS: F-D, S-U
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
PACKAGING EXCEPTIONS: LTD QTY
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT APPLICABLE.
DOT: FLAMMABLE GAS, CLASS/DIVISION 2.1
IATA; IMDG: CLASS 2.1 - FLAMMABLE GASES
MARINE POLLUTANT: ENVIRONMENT
GENERAL INFORMATION: IMDG REGULATED MARINE POLLUTANT.
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4):
ACETONE (CAS 67-64-1): LISTED.
SARA 304 EMERGENCY RELEASE NOTIFICATION: NOT REGULATED.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
NOT REGULATED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
HAZARD CATEGORIES:
IMMEDIATE HAZARD: YES
DELAYED HAZARD: NO
FIRE HAZARD: YES
REACTIVITY HAZARD: NO
PRESSURE HAZARD: NO
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NOT LISTED.
SARA 311/312 HAZARDOUS CHEMICAL: NO
SARA 313 (TRI REPORTING): NOT REGULATED.
OTHER FEDERAL REGULATIONS:
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
NOT REGULATED.
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION (40 CFR
68.130): NOT REGULATED.
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
DRUG ENFORCEMENT ADMINISTRATION (DEA). LIST 2, ESSENTIAL CHEMICALS (21 CFR
1310.02(B) AND 1310.04(F)(2) AND CHEMICAL CODE NUMBER:
ACETONE (CAS 67-64-1): 6532
DRUG ENFORCEMENT ADMINISTRATION (DEA). LIST 1 & 2 EXEMPT CHEMICAL MIXTURES
(21 CFR 1310.12(C)):
ACETONE (CAS 67-64-1): 35%WV
DEA EXEMPT CHEMICAL MIXTURES CODE NUMBER:
ACETONE (CAS 67-64-1): 6532
US STATE REGULATIONS:
US. CALIFORNIA CONTROLLED SUBSTANCES. CA DEPARTMENT OF JUSTICE (CALIFORNIA
HEALTH AND SAFETY CODE SECTION 11100): NOT LISTED.
US. CALIFORNIA. CANDIDATE CHEMICALS LIST. SAFER CONSUMER PRODUCTS
REGULATIONS (CAL. CODE REGS, TIT. 22, 69502.3, SUBD. (A)):
ACETONE (CAS 67-64-1)
US. MASSACHUSETTS RTK - SUBSTANCE LIST:
ACETONE (CAS 67-64-1)
CARBON DIOXIDE (CAS 124-38-9)
US. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
ACETONE (CAS 67-64-1)
CARBON DIOXIDE (CAS 124-38-9)
US. PENNSYLVANIA WORKER AND COMMUNITY RIGHT-TO-KNOW LAW:
ACETONE (CAS 67-64-1)
CARBON DIOXIDE (CAS 124-38-9)
US. RHODE ISLAND RTK: ACETONE (CAS 67-64-1)
US. CALIFORNIA PROPOSITION 65:
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986
(PROPOSITION 65): THIS MATERIAL IS NOT KNOWN TO CONTAIN ANY CHEMICALS
CURRENTLY LISTED AS CARCINOGENS OR REPRODUCTIVE TOXINS.
INTERNATIONAL INVENTORIES:
COUNTRY(S) OR REGION INVENTORY NAME ON INVENTORY
(YES/NO)*
AUSTRALIA AUSTRALIAN INVENTORY OF CHEMICAL YES
SUBSTANCES (AICS)
CANADA DOMESTIC SUBSTANCES LIST (DSL) YES
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) NO
CHINA INVENTORY OF EXISTING CHEMICAL YES
SUBSTANCES IN CHINA (IECSC)
EUROPE EUROPEAN INVENTORY OF EXISTING YES
COMMERCIAL CHEMICAL SUBSTANCES
(EINECS)
EUROPE EUROPEAN LIST OF NOTIFIED CHEMICAL NO
SUBSTANCES (ELINCS)
JAPAN INVENTORY OF EXISTING AND NEW YES
CHEMICAL SUBSTANCES (ENCS)
KOREA EXISTING CHEMICALS LIST (ECL) YES
NEW ZEALAND NEW ZEALAND INVENTORY YES
PHILIPPINES PHILIPPINE INVENTORY OF CHEMICALS YES
AND CHEMICAL SUBSTANCES (PICCS)
UNITED STATES & TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
PUERTO RICO INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
A "NO" INDICATES THAT ONE OR MORE COMPONENTS OF THE PRODUCT ARE NOT LISTED
OR EXEMPT FROM LISTING ON THE INVENTORY ADMINISTERED BY THE GOVERNING
COUNTRY(S).
| 16. OTHER INFORMATION, INCLUDING DATE OF | |
PREPARATION OR LAST REVISION
ISSUE DATE: 05-31-2015
REVISION DATE: 03-30-2016
VERSION #: 05
DISCLAIMER:
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT. WE CANNOT ANTICIPATE ALL CONDITIONS
UNDER WHICH THIS INFORMATION AND ITS PRODUCT, OR THE PRODUCTS OF OTHER
MANUFACTURERS IN COMBINATION WITH ITS PRODUCT, MAY BE USED. IT IS THE
USER'S RESPONSIBILITY TO ENSURE SAFE CONDITIONS FOR HANDLING, STORAGE AND
DISPOSAL OF THE PRODUCT, AND TO ASSUME LIABILITY FOR LOSS, INJURY, DAMAGE
OR EXPENSE DUE TO IMPROPER USE. THE INFORMATION IN THE SHEET WAS WRITTEN
BASED ON THE BEST KNOWLEDGE AND EXPERIENCE CURRENTLY AVAILABLE.
REVISION INFORMATION:
PRODUCT AND COMPANY IDENTIFICATION: ALTERNATE TRADE NAMES
PRODUCT NAME: D3 CITRUS DEGREASER
PRODUCT #: 1000008626
SDS US