| Common Name: | 11 OZ SW INSTANT SHINE LT 12PK |
| Manufacturer: | SPRAYWAY |
| SDS Revision Date: | 4/13/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 45C012 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SPRAYWAY(R*)
SAFETY DATA SHEET
| 1. IDENTIFICATION |  |
PRODUCT NUMBER: 1000007779
PRODUCT IDENTIFIER: 11 OZ SW INSTANT SHINE LT 12PK
COMPANY INFORMATION:
SPRAYWAY, INC.
1000 INTEGRAM DR
PACIFIC, MO 63069
UNITED STATES
COMPANY PHONE: 1-630-628-3000
EMERGENCY TELEPHONE US: 1-866-836-8855
EMERGENCY TELEPHONE OUTSIDE US: 1-952-852-4646
VERSION #: 01
RECOMMENDED USE: NOT AVAILABLE.
RECOMMENDED RESTRICTIONS: NONE KNOWN.
| 2. HAZARD(S) IDENTIFICATION | |
PHYSICAL HAZARDS:
FLAMMABLE AEROSOLS: CATEGORY 1
HEALTH HAZARDS:
SKIN CORROSION/IRRITATION: CATEGORY 2
REPRODUCTIVE TOXICITY: CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY, REPEATED EXPOSURE: CATEGORY 2
ASPIRATION HAZARD: CATEGORY 1
OSHA DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS:
FLAME
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENT:
EXTREMELY FLAMMABLE AEROSOL. MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
CAUSES SKIN IRRITATION. SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN
CHILD. MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
PRECAUTIONARY STATEMENT:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. KEEP AWAY FROM HEAT/SPARKS/OPEN
FLAMES/HOT SURFACES. - NO SMOKING. DO NOT SPRAY ON AN OPEN FLAME OR OTHER
IGNITION SOURCE. PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER
USE. DO NOT BREATHE GAS. WASH THOROUGHLY AFTER HANDLING. WEAR PROTECTIVE
GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
RESPONSE:
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER/DOCTOR. DO NOT INDUCE VOMITING.
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
IF SKIN IRRITATION OCCURS:
GET MEDICAL ADVICE/ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH
BEFORE REUSE.
STORAGE:
STORE LOCKED UP. PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES
EXCEEDING 50 DEG. C/122 DEG. F.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
ENVIRONMENTAL HAZARDS:
HAZARDOUS TO THE AQUATIC ENVIRONMENT, ACUTE HAZARD: CATEGORY 3
HAZARDOUS TO THE AQUATIC ENVIRONMENT, LONG-TERM HAZARD: CATEGORY 3
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN.
SUPPLEMENTAL INFORMATION: NONE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
CHEMICAL NAME COMMON NAME CAS NUMBER %
AND SYNONYMS
BUTANE 106-97-8 20 - 40
NAPHTHA, (PETROLEUM), HYDROTREATED 64742-49-0 20 - 40
LIGHT
N-HEXANE 110-54-3 10 - 20
PROPANE 74-98-6 2.5 - 10
CYCLOHEXANE 110-82-7 0.1 - 1
OTHER COMPONENTS BELOW REPORTABLE 10 - 20
LEVELS
*DESIGNATES THAT A SPECIFIC CHEMICAL IDENTITY AND/OR PERCENTAGE OF
COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| 4. FIRST-AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. CALL A PHYSICIAN IF SYMPTOMS DEVELOP OR PERSIST.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING. WASH WITH PLENTY OF SOAP AND WATER. IF SKIN
IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION. WASH CONTAMINATED CLOTHING
BEFORE REUSE.
EYE CONTACT:
RINSE WITH WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS AND
PERSISTS.
INGESTION:
CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. RINSE MOUTH. DO NOT
INDUCE VOMITING. IF VOMITING OCCURS, KEEP HEAD LOW SO THAT STOMACH CONTENT
DOESN'T GET INTO THE LUNGS.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
ASPIRATION MAY CAUSE PULMONARY EDEMA AND PNEUMONITIS. DIZZINESS. SKIN
IRRITATION. MAY CAUSE REDNESS AND PAIN. PROLONGED EXPOSURE MAY CAUSE
CHRONIC EFFECTS.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY. KEEP VICTIM
UNDER OBSERVATION. SYMPTOMS MAY BE DELAYED.
GENERAL INFORMATION:
IF EXPOSED OR CONCERNED:
GET MEDICAL ADVICE/ATTENTION. IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE (SHOW
THE LABEL WHERE POSSIBLE). ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE
MATERIAL(S) INVOLVED, AND TAKE PRECAUTIONS TO PROTECT THEMSELVES. SHOW THIS
SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA: FOAM. POWDER. CARBON DIOXIDE (CO2).
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
CONTENTS UNDER PRESSURE. PRESSURIZED CONTAINER MAY EXPLODE WHEN EXPOSED TO
HEAT OR FLAME. DURING FIRE, GASES HAZARDOUS TO HEALTH MAY BE FORMED.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
FIREFIGHTERS MUST USE STANDARD PROTECTIVE EQUIPMENT INCLUDING FLAME
RETARDANT COAT, HELMET WITH FACE SHIELD, GLOVES, RUBBER BOOTS, AND IN
ENCLOSED SPACES, SCBA.
FIRE FIGHTING EQUIPMENT/INSTRUCTIONS:
MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO SO WITHOUT RISK. CONTAINERS
SHOULD BE COOLED WITH WATER TO PREVENT VAPOR PRESSURE BUILD UP. FOR MASSIVE
FIRE IN CARGO AREA, USE UNMANNED HOSE HOLDER OR MONITOR NOZZLES, IF
POSSIBLE. IF NOT, WITHDRAW AND LET FIRE BURN OUT.
SPECIFIC METHODS:
USE STANDARD FIREFIGHTING PROCEDURES AND CONSIDER THE HAZARDS OF OTHER
INVOLVED MATERIALS. MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO SO WITHOUT
RISK. USE WATER SPRAY TO COOL UNOPENED CONTAINERS. IN THE EVENT OF FIRE
AND/OR EXPLOSION DO NOT BREATHE FUMES.
GENERAL FIRE HAZARDS: EXTREMELY FLAMMABLE AEROSOL.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND CLOTHING DURING
CLEAN-UP. DO NOT BREATHE GAS. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED
MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING. VENTILATE CLOSED
SPACES BEFORE ENTERING THEM. LOCAL AUTHORITIES SHOULD BE ADVISED IF
SIGNIFICANT SPILLAGES CANNOT BE CONTAINED. FOR PERSONAL PROTECTION, SEE
SECTION 8 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
REFER TO ATTACHED SAFETY DATA SHEETS AND/OR INSTRUCTIONS FOR USE. STOP LEAK
IF YOU CAN DO SO WITHOUT RISK. MOVE THE CYLINDER TO A SAFE AND OPEN AREA IF
THE LEAK IS IRREPARABLE. ISOLATE AREA UNTIL GAS HAS DISPERSED. ELIMINATE
ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS, OR FLAMES IN IMMEDIATE
AREA). KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM SPILLED
MATERIAL. PREVENT PRODUCT FROM ENTERING DRAINS. COVER WITH PLASTIC SHEET TO
PREVENT SPREADING. ABSORB IN VERMICULITE, DRY SAND OR EARTH AND PLACE INTO
CONTAINERS. FOLLOWING PRODUCT RECOVERY, FLUSH AREA WITH WATER.
SMALL SPILLS:
WIPE UP WITH ABSORBENT MATERIAL (E.G. CLOTH, FLEECE). CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. FOR WASTE DISPOSAL, SEE
SECTION 13 OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. INFORM APPROPRIATE MANAGERIAL OR
SUPERVISORY PERSONNEL OF ALL ENVIRONMENTAL RELEASES. PREVENT FURTHER
LEAKAGE OR SPILLAGE IF SAFE TO DO SO. AVOID DISCHARGE INTO DRAINS, WATER
COURSES OR ONTO THE GROUND.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
PRESSURIZED CONTAINER:
DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT USE IF SPRAY BUTTON IS
MISSING OR DEFECTIVE. DO NOT SPRAY ON A NAKED FLAME OR ANY OTHER
INCANDESCENT MATERIAL. DO NOT SMOKE WHILE USING OR UNTIL SPRAYED SURFACE
IS THOROUGHLY DRY. DO NOT CUT, WELD, SOLDER, DRILL, GRIND, OR EXPOSE
CONTAINERS TO HEAT, FLAME, SPARKS, OR OTHER SOURCES OF IGNITION. ALL
EQUIPMENT USED WHEN HANDLING THE PRODUCT MUST BE GROUNDED. DO NOT RE-USE
EMPTY CONTAINERS. DO NOT BREATHE GAS. AVOID CONTACT WITH EYES, SKIN, AND
CLOTHING. PREGNANT OR BREASTFEEDING WOMEN MUST NOT HANDLE THIS PRODUCT.
SHOULD BE HANDLED IN CLOSED SYSTEMS, IF POSSIBLE. USE ONLY IN
WELL-VENTILATED AREAS. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. WASH
HANDS THOROUGHLY AFTER HANDLING. AVOID RELEASE TO THE ENVIRONMENT. OBSERVE
GOOD INDUSTRIAL HYGIENE PRACTICES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
LEVEL 3 AEROSOL.
STORE LOCKED UP. PRESSURIZED CONTAINER. PROTECT FROM SUNLIGHT AND DO NOT
EXPOSE TO TEMPERATURES EXCEEDING 50 DEG. C/122 DEG. F. DO NOT PUNCTURE,
INCINERATE OR CRUSH. DO NOT HANDLE OR STORE NEAR AN OPEN FLAME, HEAT OR
OTHER SOURCES OF IGNITION. THIS MATERIAL CAN ACCUMULATE STATIC CHARGE WHICH
MAY CAUSE SPARK AND BECOME AN IGNITION SOURCE. STORE AWAY FROM INCOMPATIBLE
MATERIALS (SEE SECTION 10 OF THE SDS).
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
CYCLOHEXANE (CAS 110-82-7) PEL 1050 MG/M3
300 PPM
N-HEXANE (CAS 110-54-3) PEL 1800 MG/M3
500 PPM
PROPANE (CAS 74-98-6) PEL 1800 MG/M3
1000 PPM
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE
BUTANE (CAS 106-97-8) STEL 1000 PPM
CYCLOHEXANE (CAS 110-82-7) TWA 100 PPM
N-HEXANE (CAS 110-54-3) TWA 50 PPM
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
COMPONENTS TYPE VALUE
BUTANE (CAS 106-97-8) TWA 1900 MG/M3
800 PPM
CYCLOHEXANE (CAS 110-82-7) TWA 1050 MG/M3
300 PPM
N-HEXANE (CAS 110-54-3) TWA 180 MG/M3
50 PPM
PROPANE (CAS 74-98-6) TWA 1800 MG/M3
1000 PPM
BIOLOGICAL LIMIT VALUES:
ACGIH BIOLOGICAL EXPOSURE INDICES:
COMPONENTS VALUE DETERMINANT SPECIMEN SAMPLING TIME
N-HEXANE 0.4 MG/L 2,5-HEXANEDION, URINE *
(CAS 110-54-3) WITHOUT HYDROLYSIS
* - FOR SAMPLING DETAILS, PLEASE SEE THE SOURCE DOCUMENT.
EXPOSURE GUIDELINES:
US - CALIFORNIA OELS: SKIN DESIGNATION
N-HEXANE (CAS 110-54-3) CAN BE ABSORBED THROUGH THE SKIN.
US ACGIH THRESHOLD LIMIT VALUES: SKIN DESIGNATION
N-HEXANE (CAS 110-54-3) CAN BE ABSORBED THROUGH THE SKIN.
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE
USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE, USE
PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. IF
EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN
ACCEPTABLE LEVEL. EYE WASH FACILITIES AND EMERGENCY SHOWER MUST BE
AVAILABLE WHEN HANDLING THIS PRODUCT.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
SKIN PROTECTION:
HAND PROTECTION:
WEAR APPROPRIATE CHEMICAL RESISTANT GLOVES. SUITABLE GLOVES CAN BE
RECOMMENDED BY THE GLOVE SUPPLIER.
OTHER:
WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING. USE OF AN IMPERVIOUS APRON IS
RECOMMENDED.
RESPIRATORY PROTECTION:
IF PERMISSIBLE LEVELS ARE EXCEEDED USE NIOSH MECHANICAL FILTER / ORGANIC
VAPOR CARTRIDGE OR AN AIR-SUPPLIED RESPIRATOR.
THERMAL HAZARDS:
WEAR APPROPRIATE THERMAL PROTECTIVE CLOTHING, WHEN NECESSARY.
GENERAL HYGIENE CONSIDERATIONS:
OBSERVE ANY MEDICAL SURVEILLANCE REQUIREMENTS. WHEN USING DO NOT SMOKE.
ALWAYS OBSERVE GOOD PERSONAL HYGIENE MEASURES, SUCH AS WASHING AFTER
HANDLING THE MATERIAL AND BEFORE EATING, DRINKING, AND/OR SMOKING.
ROUTINELY WASH WORK CLOTHING AND PROTECTIVE EQUIPMENT TO REMOVE
CONTAMINANTS.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: GAS.
FORM: AEROSOL.
COLOR: NOT AVAILABLE.
ODOR: NOT AVAILABLE.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT/FREEZING POINT: NOT AVAILABLE.
INITIAL BOILING POINT AND BOILING RANGE: NOT AVAILABLE.
FLASH POINT: -156.0 DEG. F (-104.4 DEG. C) PROPELLANT ESTIMATED
EVAPORATION RATE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): NOT AVAILABLE.
FLAMMABILITY LIMIT - UPPER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - LOWER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - UPPER (%): NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
VAPOR DENSITY: NOT AVAILABLE.
RELATIVE DENSITY: NOT AVAILABLE.
SOLUBILITY(IES):
SOLUBILITY (WATER): NOT AVAILABLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: 496.4 DEG. F (258 DEG. C) ESTIMATED
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: NOT AVAILABLE.
OTHER INFORMATION:
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE.
OXIDIZING PROPERTIES: NOT OXIDIZING.
SPECIFIC GRAVITY: 0.69 ESTIMATED
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
THE PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS OF USE,
STORAGE AND TRANSPORT.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
CONDITIONS TO AVOID:
AVOID TEMPERATURES EXCEEDING THE FLASH POINT. CONTACT WITH INCOMPATIBLE
MATERIALS.
INCOMPATIBLE MATERIALS:
STRONG OXIDIZING AGENTS. NITRATES. FLUORINE. CHLORINE.
HAZARDOUS DECOMPOSITION PRODUCTS:
NO HAZARDOUS DECOMPOSITION PRODUCTS ARE KNOWN.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE BY
INHALATION.
SKIN CONTACT: CAUSES SKIN IRRITATION.
EYE CONTACT: DIRECT CONTACT WITH EYES MAY CAUSE TEMPORARY IRRITATION.
INGESTION:
DROPLETS OF THE PRODUCT ASPIRATED INTO THE LUNGS THROUGH INGESTION OR
VOMITING MAY CAUSE A SERIOUS CHEMICAL PNEUMONIA.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
ASPIRATION MAY CAUSE PULMONARY EDEMA AND PNEUMONITIS. DIZZINESS. SKIN
IRRITATION. MAY CAUSE REDNESS AND PAIN.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
COMPONENTS SPECIES TEST RESULTS
BUTANE (CAS 106-97-8):
ACUTE:
INHALATION:
LC50 MOUSE 1237 MG/L, 120 MINUTES
52%, 120 MINUTES
RAT 1355 MG/L
CYCLOHEXANE (CAS 110-82-7):
ACUTE:
DERMAL:
LD50 RABBIT >2000 MG/KG
INHALATION:
LC50 RAT >32880 MG/M3, 4 HOURS
>5540 PPM, 4 HOURS
ORAL:
LD50 RABBIT >5000 MG/KG
RAT >5000 MG/KG
NAPHTHA, (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-49-0):
ACUTE:
DERMAL:
LD50 GUINEA PIG; >9.4 ML/KG, 24 HOURS
RABBIT
RABBIT >1900 MG/KG, 24 HOURS
INHALATION:
LC50 RAT >5000 MG/M3, 4 HOURS
>4980 MG/M3
>4980 MG/M3, 4 HOURS
>4.96 MG/L, 4 HOURS
13700 PPM, 4 HOURS
ORAL:
LD50 RAT 4820 MG/KG
N-HEXANE (CAS 110-54-3):
ACUTE:
DERMAL:
LD50 RABBIT >2000 MG/KG, 4 HOURS
>5 ML/KG, 4 HOURS
INHALATION:
LC50 RAT >5000 PPM, 24 HOURS
>31.86 MG/L
73860 PPM, 4 HOURS
ORAL:
LD50 RAT 24 ML/KG
24 G/KG
WISTAR RAT 49 G/KG
PROPANE (CAS 74-98-6):
ACUTE:
INHALATION:
LC50 MOUSE 1237 MG/L, 120 MINUTES
52%, 120 MINUTES
RAT 1355 MG/L
658 MG/L/4H
* ESTIMATES FOR PRODUCT MAY BE BASED ON ADDITIONAL COMPONENT DATA NOT
SHOWN.
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
SERIOUS EYE DAMAGE/EYE IRRITATION:
DIRECT CONTACT WITH EYES MAY CAUSE TEMPORARY IRRITATION.
RESPIRATORY OR SKIN SENSITIZATION:
RESPIRATORY SENSITIZATION: NOT A RESPIRATORY SENSITIZER.
SKIN SENSITIZATION:
THIS PRODUCT IS NOT EXPECTED TO CAUSE SKIN SENSITIZATION.
GERM CELL MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
CARCINOGENICITY: RISK OF CANCER CANNOT BE EXCLUDED WITH PROLONGED EXPOSURE.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY: NOT LISTED.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
NOT REGULATED.
US. NATIONAL TOXICOLOGY PROGRAM (NTP) REPORT ON CARCINOGENS: NOT LISTED.
REPRODUCTIVE TOXICITY: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NOT CLASSIFIED.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
RESPIRATORY SYSTEM. SKIN. CENTRAL NERVOUS SYSTEM. EYES. PERIPHERAL NERVOUS
SYSTEM. MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
ASPIRATION HAZARD: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
CHRONIC EFFECTS:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
PROLONGED EXPOSURE MAY CAUSE CHRONIC EFFECTS.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
COMPONENTS SPECIES TEST RESULTS
CYCLOHEXANE (CAS 110-82-7):
AQUATIC:
FISH LC50 FATHEAD MINNOW (PIMEPHALES PROMELAS) 23.03 - 42.07
MG/L, 96 HOURS
N-HEXANE (CAS 110-54-3):
AQUATIC:
FISH LC50 FATHEAD MINNOW (PIMEPHALES PROMELAS) 2.101 - 2.981
MG/L, 96 HOURS
* ESTIMATES FOR PRODUCT MAY BE BASED ON ADDITIONAL COMPONENT DATA NOT
SHOWN.
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF THIS PRODUCT.
BIOACCUMULATIVE POTENTIAL:
PARTITION COEFFICIENT N-OCTANOL / WATER (LOG KOW):
BUTANE: 2.89
CYCLOHEXANE: 3.44
N-HEXANE: 3.9
PROPANE: 2.36
MOBILITY IN SOIL: NO DATA AVAILABLE.
OTHER ADVERSE EFFECTS:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION, PHOTOCHEMICAL
OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION, GLOBAL WARMING POTENTIAL)
ARE EXPECTED FROM THIS COMPONENT.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS:
COLLECT AND RECLAIM OR DISPOSE IN SEALED CONTAINERS AT LICENSED WASTE
DISPOSAL SITE. CONTENTS UNDER PRESSURE. DO NOT PUNCTURE, INCINERATE OR
CRUSH. DO NOT ALLOW THIS MATERIAL TO DRAIN INTO SEWERS/WATER SUPPLIES. DO
NOT CONTAMINATE PONDS, WATERWAYS OR DITCHES WITH CHEMICAL OR USED
CONTAINER. DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
LOCAL DISPOSAL REGULATIONS:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE:
THE WASTE CODE SHOULD BE ASSIGNED IN DISCUSSION BETWEEN THE USER, THE
PRODUCER AND THE WASTE DISPOSAL COMPANY.
WASTE FROM RESIDUES / UNUSED PRODUCTS:
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS. EMPTY CONTAINERS OR LINERS
MAY RETAIN SOME PRODUCT RESIDUES. THIS MATERIAL AND ITS CONTAINER MUST BE
DISPOSED OF IN A SAFE MANNER (SEE: DISPOSAL INSTRUCTIONS).
CONTAMINATED PACKAGING:
SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS
EVEN AFTER CONTAINER IS EMPTIED. EMPTY CONTAINERS SHOULD BE TAKEN TO AN
APPROVED WASTE HANDLING SITE FOR RECYCLING OR DISPOSAL. DO NOT RE-USE EMPTY
CONTAINERS.
| 14. TRANSPORT INFORMATION | |
DOT:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME:
AEROSOLS, FLAMMABLE, (EACH NOT EXCEEDING 1 L CAPACITY)
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.1
SUBSIDIARY RISK:
LABEL(S): 2.1
PACKING GROUP: NOT APPLICABLE.
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
SPECIAL PROVISIONS: N82
PACKAGING EXCEPTIONS: 306
PACKAGING NON BULK: NONE
PACKAGING BULK: NONE
THIS PRODUCT MEETS THE EXCEPTION REQUIREMENTS OF SECTION 173.306 AS A
LIMITED QUANTITY AND MAY BE SHIPPED AS A LIMITED QUANTITY. UNTIL
12/31/2020, THE "CONSUMER COMMODITY - ORM-D" MARKING MAY STILL BE USED IN
PLACE OF THE NEW LIMITED QUANTITY DIAMOND MARK FOR PACKAGES OF UN 1950
AEROSOLS. LIMITED QUANTITIES REQUIRE THE LIMITED QUANTITY DIAMOND MARK ON
CARTONS AFTER 12/31/20 AND MAY BE USED NOW IN PLACE OF THE "CONSUMER
COMMODITY ORM-D" MARKING.
IATA:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.1
SUBSIDIARY RISK:
LABEL(S): 2.1
PACKING GROUP: NOT APPLICABLE.
ENVIRONMENTAL HAZARDS: NO.
ERG CODE: 10L
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
PASSENGER AND CARGO AIRCRAFT: ALLOWED WITH RESTRICTIONS.
CARGO AIRCRAFT ONLY: ALLOWED WITH RESTRICTIONS.
OTHER INFORMATION:
PACKAGING EXCEPTIONS: LTD QTY
IMDG:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME: AEROSOLS
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.1
SUBSIDIARY RISK:
LABEL(S): 2.1
PACKING GROUP: NOT APPLICABLE.
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO.
EMS: F-D, S-U
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
PACKAGING EXCEPTIONS: LTD QTY
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT APPLICABLE.
DOT: FLAMMABLE GAS, CLASS/DIVISION 2.1
IATA; IMDG: CLASS 2.1 - FLAMMABLE GASES
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4):
CYCLOHEXANE (CAS 110-82-7): LISTED.
N-HEXANE (CAS 110-54-3): LISTED.
SARA 304 EMERGENCY RELEASE NOTIFICATION: NOT REGULATED.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
NOT REGULATED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
HAZARD CATEGORIES:
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
FIRE HAZARD: YES
REACTIVITY HAZARD: NO
PRESSURE HAZARD: NO
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NOT LISTED.
SARA 311/312 HAZARDOUS CHEMICAL: NO
SARA 313 (TRI REPORTING):
CHEMICAL NAME CAS NUMBER % BY WT.
N-HEXANE 110-54-3 10 - 20
CYCLOHEXANE 110-82-7 0.1 - 1
OTHER FEDERAL REGULATIONS:
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
N-HEXANE (CAS 110-54-3)
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION
(40 CFR 68.130):
BUTANE (CAS 106-97-8)
PROPANE (CAS 74-98-6)
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
US STATE REGULATIONS:
US. CALIFORNIA CONTROLLED SUBSTANCES. CA DEPARTMENT OF JUSTICE
(CALIFORNIA HEALTH AND SAFETY CODE SECTION 11100):
NOT LISTED.
US. CALIFORNIA. CANDIDATE CHEMICALS LIST. SAFER CONSUMER PRODUCTS
REGULATIONS (CAL. CODE REGS, TIT. 22, 69502.3, SUBD. (A)):
BUTANE (CAS 106-97-8)
NAPHTHA, (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-49-0)
N-HEXANE (CAS 110-54-3)
US. MASSACHUSETTS RTK - SUBSTANCE LIST:
BUTANE (CAS 106-97-8)
CYCLOHEXANE (CAS 110-82-7)
N-HEXANE (CAS 110-54-3)
PROPANE (CAS 74-98-6)
US. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
BUTANE (CAS 106-97-8)
CYCLOHEXANE (CAS 110-82-7)
N-HEXANE (CAS 110-54-3)
PROPANE (CAS 74-98-6)
US. PENNSYLVANIA WORKER AND COMMUNITY RIGHT-TO-KNOW LAW:
BUTANE (CAS 106-97-8)
CYCLOHEXANE (CAS 110-82-7)
N-HEXANE (CAS 110-54-3)
PROPANE (CAS 74-98-6)
US. RHODE ISLAND RTK:
BUTANE (CAS 106-97-8)
CYCLOHEXANE (CAS 110-82-7)
N-HEXANE (CAS 110-54-3)
PROPANE (CAS 74-98-6)
US. CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
US - CALIFORNIA PROPOSITION 65 - CRT: LISTED DATE/CARCINOGENIC SUBSTANCE
BENZENE (CAS 71-43-2):
LISTED: FEBRUARY 27, 1987
ETHYL BENZENE (CAS 100-41-4):
LISTED: JUNE 11, 2004
US - CALIFORNIA PROPOSITION 65 - CRT: LISTED DATE/DEVELOPMENTAL TOXIN
BENZENE (CAS 71-43-2):
LISTED: DECEMBER 26, 1997
TOLUENE (CAS 108-88-3):
LISTED: JANUARY 1, 1991
US - CALIFORNIA PROPOSITION 65 - CRT: LISTED DATE/MALE REPRODUCTIVE TOXIN
BENZENE (CAS 71-43-2):
LISTED: DECEMBER 26, 1997
INTERNATIONAL INVENTORIES:
COUNTRY(S) OR REGION INVENTORY NAME ON INVENTORY
(YES/NO)*
AUSTRALIA AUSTRALIAN INVENTORY OF CHEMICAL NO
SUBSTANCES (AICS)
CANADA DOMESTIC SUBSTANCES LIST (DSL) YES
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) NO
CHINA INVENTORY OF EXISTING CHEMICAL NO
SUBSTANCES IN CHINA (IECSC)
EUROPE EUROPEAN INVENTORY OF EXISTING NO
COMMERCIAL CHEMICAL SUBSTANCES
(EINECS)
EUROPE EUROPEAN LIST OF NOTIFIED CHEMICAL NO
SUBSTANCES (ELINCS)
JAPAN INVENTORY OF EXISTING AND NEW NO
CHEMICAL SUBSTANCES (ENCS)
KOREA EXISTING CHEMICALS LIST (ECL) NO
NEW ZEALAND NEW ZEALAND INVENTORY NO
PHILIPPINES PHILIPPINE INVENTORY OF CHEMICALS NO
AND CHEMICAL SUBSTANCES (PICCS)
UNITED STATES & TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
PUERTO RICO INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
A "NO" INDICATES THAT ONE OR MORE COMPONENTS OF THE PRODUCT ARE NOT LISTED
OR EXEMPT FROM LISTING ON THE INVENTORY ADMINISTERED BY THE GOVERNING
COUNTRY(S).
| 16. OTHER INFORMATION, INCLUDING DATE OF | |
PREPARATION OR LAST REVISION
ISSUE DATE: 04-13-2017
VERSION #: 01
DISCLAIMER:
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT.
REVISION INFORMATION:
PRODUCT AND COMPANY IDENTIFICATION: ALTERNATE TRADE NAMES
PRODUCT NAME: 11 OZ SW INSTANT SHINE LT 12PK
PRODUCT #: 1000007779
SDS US