| Common Name: | INTERIOR DETAILER |
| Manufacturer: | SPRAYWAY |
| SDS Revision Date: | 8/28/2019 |
| SDS Format: | GHS-US |
| Item Number(s): | 350DD2, 45C013 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SPRAYWAY(R*)
VERSION: 1.0
REVISION DATE: 08/28/2019
SAFETY DATA SHEET
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER: INTERIOR DETAILER
OTHER MEANS OF IDENTIFICATION:
SDS NUMBER: RE1000011758
RECOMMENDED RESTRICTIONS:
PRODUCT USE: COATING
RESTRICTIONS ON USE: NOT KNOWN.
MANUFACTURER/IMPORTER/DISTRIBUTOR INFORMATION:
MANUFACTURER:
COMPANY NAME: SPRAYWAY, INC.
ADDRESS:
1000 INTEGRAM DR.
PACIFIC, MO 63069
TELEPHONE: 1-630-628-3000
FAX:
EMERGENCY TELEPHONE NUMBER: 1-866-836-8855
| 2. HAZARD(S) IDENTIFICATION | |
HAZARD CLASSIFICATION:
PHYSICAL HAZARDS:
FLAMMABLE AEROSOL: CATEGORY 1
HEALTH HAZARDS:
SKIN CORROSION/IRRITATION: CATEGORY 2
TOXIC TO REPRODUCTION: CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: CATEGORY 3(1).
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: CATEGORY 2
ASPIRATION HAZARD: CATEGORY 1
TARGET ORGANS: 1. NARCOTIC EFFECT.
ENVIRONMENTAL HAZARDS:
ACUTE HAZARDS TO THE AQUATIC ENVIRONMENT: CATEGORY 2
CHRONIC HAZARDS TO THE AQUATIC ENVIRONMENT: CATEGORY 3
LABEL ELEMENTS:
HAZARD SYMBOL:
FLAME
EXCLAMATION MARK
HEALTH HAZARD
SIGNAL WORD: DANGER
HAZARD STATEMENT:
EXTREMELY FLAMMABLE AEROSOL.
CAUSES SKIN IRRITATION.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
MAY CAUSE DROWSINESS OR DIZZINESS.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
TOXIC TO AQUATIC LIFE.
HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENTS:
PREVENTION:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING. DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION
SOURCE. DO NOT PIERCE OR BURN, EVEN AFTER USE. WASH THOROUGHLY AFTER
HANDLING. WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE
PROTECTION. OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL
ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. USE PERSONAL
PROTECTIVE EQUIPMENT AS REQUIRED. USE ONLY OUTDOORS OR IN A WELL-VENTILATED
AREA. DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY. AVOID RELEASE TO THE
ENVIRONMENT.
RESPONSE:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF ON SKIN: WASH WITH PLENTY OF WATER/...
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER/DOCTOR/... DO NOT INDUCE VOMITING. CALL
A POISON CENTER/DOCTOR IF YOU FEEL UNWELL. SPECIFIC TREATMENT (SEE ON THIS
LABEL). TAKE OFF CONTAMINATED CLOTHING.
STORAGE:
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C/122 DEG. F. STORE LOCKED UP. STORE IN A WELL-VENTILATED PLACE.
KEEP CONTAINER TIGHTLY CLOSED.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROPRIATE TREATMENT AND DISPOSAL
FACILITY IN ACCORDANCE WITH APPLICABLE LAWS AND REGULATIONS, AND PRODUCT
CHARACTERISTICS AT TIME OF DISPOSAL.
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): NONE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
CHEMICAL IDENTITY CAS NUMBER CONTENT IN PERCENT (%)*
PROPANE 74-98-6 20 - <50%
BUTANE 106-97-8 20 - <50%
HEXANE 110-54-3 10 - <25%
NAPHTHA (PETROLEUM), HYDROTREATED 64742-49-0 10 - <25%
LIGHT
SILOXANES AND SILICONES, DI-ME 63148-62-9 5 - <10%
2-PROPANONE 67-64-1 5 - <10%
CYCLOHEXANE 110-82-7 0.1 - <1%
HEPTANE 142-82-5 0.1 - <1%
1,2-BENZENEDICARBOXYLIC ACID, 84-66-2 0.1 - <1%
1,2-DIETHYL ESTER
SOLVENT NAPHTHA (PETROLEUM), 64742-89-8 0.1 - <1%
LIGHT ALIPH.
* ALL CONCENTRATIONS ARE PERCENT BY WEIGHT UNLESS INGREDIENT IS A GAS.
GAS CONCENTRATIONS ARE IN PERCENT BY VOLUME.
| 4. FIRST-AID MEASURES | |
INGESTION:
RINSE MOUTH. CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. NEVER
GIVE LIQUID TO AN UNCONSCIOUS PERSON. IF VOMITING OCCURS, KEEP HEAD LOW SO
THAT STOMACH CONTENT DOESN'T GET INTO THE LUNGS.
INHALATION: MOVE TO FRESH AIR.
SKIN CONTACT:
IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE
REMOVING CONTAMINATED CLOTHING AND SHOES. WASH CONTAMINATED CLOTHING
BEFORE REUSE. GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. IF EASY
TO DO, REMOVE CONTACT LENSES. GET MEDICAL ATTENTION.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
SYMPTOMS: NO DATA AVAILABLE.
HAZARDS: NO DATA AVAILABLE.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
TREATMENT: NO DATA AVAILABLE.
| 5. FIRE-FIGHTING MEASURES | |
GENERAL FIRE HAZARDS:
USE WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL. FIGHT FIRE FROM A
PROTECTED LOCATION. MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO SO
WITHOUT RISK.
SUITABLE (AND UNSUITABLE) EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE FIRE-EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING MATERIALS.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
VAPORS MAY TRAVEL CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH
BACK.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
SPECIAL FIRE FIGHTING PROCEDURES: NO DATA AVAILABLE.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIREFIGHTERS MUST USE STANDARD PROTECTIVE EQUIPMENT INCLUDING FLAME
RETARDANT COAT, HELMET WITH FACE SHIELD, GLOVES, RUBBER BOOTS, AND IN
ENCLOSED SPACES, SCBA.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
VENTILATE CLOSED SPACES BEFORE ENTERING THEM. ELIMINATE ALL IGNITION
SOURCES (NO SMOKING, FLARES, SPARKS OR FLAMES IN IMMEDIATE AREA). KEEP
UPWIND. SEE SECTION 8 OF THE SDS FOR PERSONAL PROTECTIVE EQUIPMENT. DO
NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS WEARING APPROPRIATE
PROTECTIVE CLOTHING. KEEP UNAUTHORIZED PERSONNEL AWAY.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN A
CONTAINER FOR CHEMICAL WASTE. DIKE FAR AHEAD OF LARGER SPILL FOR LATER
RECOVERY AND DISPOSAL.
NOTIFICATION PROCEDURES:
DIKE FOR LATER DISPOSAL. PREVENT ENTRY INTO WATERWAYS, SEWER, BASEMENTS
OR CONFINED AREAS. STOP THE FLOW OF MATERIAL, IF THIS IS WITHOUT RISK.
ELIMINATE ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS OR FLAMES IN
IMMEDIATE AREA). STOP LEAK IF YOU CAN DO SO WITHOUT RISK.
ENVIRONMENTAL PRECAUTIONS:
DO NOT CONTAMINATE WATER SOURCES OR SEWER. PREVENT FURTHER LEAKAGE OR
SPILLAGE IF SAFE TO DO SO. AVOID RELEASE TO THE ENVIRONMENT.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
WASH HANDS THOROUGHLY AFTER HANDLING. KEEP AWAY FROM HEAT, HOT SURFACES,
SPARKS, OPEN FLAMES AND OTHER IGNITION SOURCES. NO SMOKING. DO NOT SPRAY
ON AN OPEN FLAME OR OTHER IGNITION SOURCE. DO NOT PIERCE OR BURN, EVEN
AFTER USE. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND
UNDERSTOOD. OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. USE PERSONAL PROTECTIVE
EQUIPMENT AS REQUIRED. AVOID CONTACT WITH SKIN.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE LOCKED UP.
PRESSURIZED CONTAINER:
PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C. DO NOT PIERCE OR BURN, EVEN AFTER USE. AEROSOL LEVEL 3
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
CHEMICAL IDENTITY TYPE EXPOSURE LIMIT SOURCE
VALUES
PROPANE REL 1,000 PPM US. NIOSH:
1,800 MG/M3 POCKET GUIDE TO
CHEMICAL HAZARDS (2005)
PEL 1,000 PPM US. OSHA TABLE Z-1
1,800 MG/M3 LIMITS FOR AIR
CONTAMINANTS
(29 CFR 1910.1000)
(02 2006)
TWA 1,000 PPM US. OSHA TABLE Z-1-A
1,800 MG/M3 (29 CFR 1910.1000)
(1989)
BUTANE REL 800 PPM US. NIOSH:
1,900 MG/M3 POCKET GUIDE TO
CHEMICAL HAZARDS (2005)
STEL 1,000 PPM US. ACGIH THRESHOLD
LIMIT VALUES (03 2018)
TWA 800 PPM US. OSHA TABLE Z-1-A
1,900 MG/M3 (29 CFR 1910.1000)
(1989)
HEXANE TWA 50 PPM US. OSHA TABLE Z-1-A
180 MG/M3 (29 CFR 1910.1000)
(1989)
PEL 500 PPM US. OSHA TABLE Z-1
1,800 MG/M3 LIMITS FOR AIR
CONTAMINANTS
(29 CFR 1910.1000)
(02 2006)
REL 50 PPM US. NIOSH:
180 MG/M3 POCKET GUIDE TO
CHEMICAL HAZARDS (2005)
TWA 50 PPM US. ACGIH THRESHOLD
LIMIT VALUES (2008)
NAPHTHA PEL 100 PPM US. OSHA TABLE Z-1
(PETROLEUM), 400 MG/M3 LIMITS FOR AIR
HYDROTREATED LIGHT CONTAMINANTS
(29 CFR 1910.1000)
(03 2016)
REL 100 PPM US. NIOSH:
400 MG/M3 POCKET GUIDE TO
CHEMICAL HAZARDS (2010)
TWA 100 PPM US. OSHA TABLE Z-1-A
400 MG/M3 (29 CFR 1910.1000)
(1989)
2-PROPANONE STEL 1,000 PPM US. OSHA TABLE Z-1-A
2,400 MG/M3 (29 CFR 1910.1000)
(1989)
PEL 1,000 PPM US. OSHA TABLE Z-1
2,400 MG/M3 LIMITS FOR AIR
CONTAMINANTS
(29 CFR 1910.1000)
(02 2006)
TWA 250 PPM US. ACGIH THRESHOLD
LIMIT VALUES (03 2015)
TWA 750 PPM US. OSHA TABLE Z-1-A
1,800 MG/M3 (29 CFR 1910.1000)
(1989)
STEL 500 PPM US. ACGIH THRESHOLD
LIMIT VALUES (03 2015)
REL 250 PPM US. NIOSH:
590 MG/M3 POCKET GUIDE TO
CHEMICAL HAZARDS (2005)
CYCLOHEXANE TWA 100 PPM US. ACGIH THRESHOLD
LIMIT VALUES (2008)
TWA 300 PPM US. OSHA TABLE Z-1-A
1,050 MG/M3 (29 CFR 1910.1000)
(1989)
REL 300 PPM US. NIOSH:
1,050 MG/M3 POCKET GUIDE TO
CHEMICAL HAZARDS (2005)
PEL 300 PPM US. OSHA TABLE Z-1
1,050 MG/M3 LIMITS FOR AIR
CONTAMINANTS
(29 CFR 1910.1000)
(02 2006)
HEPTANE TWA 400 PPM US. OSHA TABLE Z-1-A
1,600 MG/M3 (29 CFR 1910.1000)
(1989)
REL 85 PPM US. NIOSH:
350 MG/M3 POCKET GUIDE TO
CHEMICAL HAZARDS (2005)
PEL 500 PPM US. OSHA TABLE Z-1
2,000 MG/M3 LIMITS FOR AIR
CONTAMINANTS
(29 CFR 1910.1000)
(02 2006)
STEL 500 PPM US. OSHA TABLE Z-1-A
2,000 MG/M3 (29 CFR 1910.1000)
(1989)
TWA 400 PPM US. ACGIH THRESHOLD
LIMIT VALUES (02 2012)
STEL 500 PPM US. ACGIH THRESHOLD
LIMIT VALUES (02 2012)
CEIL_TIME 440 PPM US. NIOSH:
1,800 MG/M3 POCKET GUIDE TO
CHEMICAL HAZARDS (2005)
1,2-BENZENE- REL 5 MG/M3 US. NIOSH:
DICARBOXYLIC ACID, POCKET GUIDE TO
1,2-DIETHYL ESTER CHEMICAL HAZARDS (2005)
TWA 5 MG/M3 US. ACGIH THRESHOLD
LIMIT VALUES (2008)
TWA 5 MG/M3 US. OSHA TABLE Z-1-A
(29 CFR 1910.1000)
(1989)
SOLVENT NAPHTHA REL 100 PPM US. NIOSH:
(PETROLEUM), 400 MG/M3 POCKET GUIDE TO
LIGHT ALIPH. CHEMICAL HAZARDS (2010)
TWA 100 PPM US. OSHA TABLE Z-1-A
400 MG/M3 (29 CFR 1910.1000)
(1989)
PEL 100 PPM US. OSHA TABLE Z-1
400 MG/M3 LIMITS FOR AIR
CONTAMINANTS
(29 CFR 1910.1000)
(03 2016)
BENZENE, DIMETHYL- STEL 150 PPM US. OSHA TABLE Z-1-A
655 MG/M3 (29 CFR 1910.1000)
(1989)
TWA 100 PPM US. OSHA TABLE Z-1-A
435 MG/M3 (29 CFR 1910.1000)
(1989)
TWA 100 PPM US. ACGIH THRESHOLD
LIMIT VALUES (2008)
REL 100 PPM US. NIOSH:
435 MG/M3 POCKET GUIDE TO
CHEMICAL HAZARDS (2016)
PEL 100 PPM US. OSHA TABLE Z-1
435 MG/M3 LIMITS FOR AIR
CONTAMINANTS
(29 CFR 1910.1000)
(02 2006)
STEL 150 PPM US. ACGIH THRESHOLD
LIMIT VALUES (2008)
STEL 150 PPM US. NIOSH:
655 MG/M3 POCKET GUIDE TO
CHEMICAL HAZARDS (2016)
ACETIC ACID, REL 100 PPM US. NIOSH:
PENTYL ESTER 525 MG/M3 POCKET GUIDE TO
CHEMICAL HAZARDS (2005)
TWA 50 PPM US. ACGIH THRESHOLD
LIMIT VALUES (2008)
STEL 100 PPM US. ACGIH THRESHOLD
LIMIT VALUES (2008)
PEL 100 PPM US. OSHA TABLE Z-1
525 MG/M3 LIMITS FOR AIR
CONTAMINANTS
(29 CFR 1910.1000)
(02 2006)
TWA 100 PPM US. OSHA TABLE Z-1-A
525 MG/M3 (29 CFR 1910.1000)
(1989)
BENZENE, METHYL- STEL 150 PPM US. OSHA TABLE Z-1-A
560 MG/M3 (29 CFR 1910.1000)
(1989)
REL 100 PPM US. NIOSH:
375 MG/M3 POCKET GUIDE TO
CHEMICAL HAZARDS (2005)
TWA 100 PPM US. OSHA TABLE Z-1-A
375 MG/M3 (29 CFR 1910.1000)
(1989)
CEILING 300 PPM US. OSHA TABLE Z-2
(29 CFR 1910.1000)
(02 2006)
TWA 20 PPM US. ACGIH THRESHOLD
LIMIT VALUES (2008)
TWA 200 PPM US. OSHA TABLE Z-2
(29 CFR 1910.1000)
(02 2006)
MAX. 500 PPM US. OSHA TABLE Z-2
CONC (29 CFR 1910.1000)
(02 2006)
STEL 150 PPM US. NIOSH:
560 MG/M3 POCKET GUIDE TO
CHEMICAL HAZARDS (2005)
BENZENE, ETHYL- STEL 125 PPM US. NIOSH:
545 MG/M3 POCKET GUIDE TO
CHEMICAL HAZARDS (2005)
REL 100 PPM US. NIOSH:
435 MG/M3 POCKET GUIDE TO
CHEMICAL HAZARDS (2005)
PEL 100 PPM US. OSHA TABLE Z-1
435 MG/M3 LIMITS FOR AIR
CONTAMINANTS
(29 CFR 1910.1000)
(02 2006)
STEL 125 PPM US. OSHA TABLE Z-1-A
545 MG/M3 (29 CFR 1910.1000)
(1989)
TWA 100 PPM US. OSHA TABLE Z-1-A
435 MG/M3 (29 CFR 1910.1000)
(1989)
TWA 20 PPM US. ACGIH THRESHOLD
LIMIT VALUES (12 2010)
ACETIC ACID TWA 400 PPM US. ACGIH THRESHOLD
ETHYL ESTER LIMIT VALUES (2008)
REL 400 PPM US. NIOSH:
1,400 MG/M3 POCKET GUIDE TO
CHEMICAL HAZARDS (2005)
PEL 400 PPM US. OSHA TABLE Z-1
1,400 MG/M3 LIMITS FOR AIR
CONTAMINANTS
(29 CFR 1910.1000)
(02 2006)
TWA 400 PPM US. OSHA TABLE Z-1-A
1,400 MG/M3 (29 CFR 1910.1000)
(1989)
BENZENE REL 0.1 PPM US. NIOSH:
POCKET GUIDE TO
CHEMICAL HAZARDS (2005)
TWA 1 PPM US. OSHA TABLE Z-1-A
(29 CFR 1910.1000)
(1989)
CEILING 25 PPM US. OSHA TABLE Z-2
(29 CFR 1910.1000)
(02 2006)
STEL 1 PPM US. NIOSH:
POCKET GUIDE TO
CHEMICAL HAZARDS (2005)
TWA 0.5 PPM US. ACGIH THRESHOLD
LIMIT VALUES (2008)
STEL 5 PPM US. OSHA TABLE Z-1-A
(29 CFR 1910.1000)
(1989)
TWA 1 PPM US. OSHA SPECIFICALLY
REGULATED SUBSTANCES
(29 CFR 1910.1001-1053)
(02 2006)
STEL 2.5 PPM US. ACGIH THRESHOLD
LIMIT VALUES (2008)
STEL 5 PPM US. OSHA SPECIFICALLY
REGULATED SUBSTANCES
(29 CFR 1910.1001-1053)
(02 2006)
OSHA_ACT 0.5 PPM US. OSHA SPECIFICALLY
REGULATED SUBSTANCES
(29 CFR 1910.1001-1053)
(02 2006)
TWA 10 PPM US. OSHA TABLE Z-2
(29 CFR 1910.1000)
(02 2006)
MAX. 50 PPM US. OSHA TABLE Z-2
CONC (29 CFR 1910.1000)
(02 2006)
NAPHTHALENE PEL 10 PPM US. OSHA TABLE Z-1
50 MG/M3 LIMITS FOR AIR
CONTAMINANTS
(29 CFR 1910.1000)
(02 2006)
TWA 10 PPM US. OSHA TABLE Z-1-A
50 MG/M3 (29 CFR 1910.1000)
(1989)
TWA 10 PPM US. ACGIH THRESHOLD
LIMIT VALUES (2008)
STEL 15 PPM US. NIOSH:
75 MG/M3 POCKET GUIDE TO
CHEMICAL HAZARDS (2005)
REL 10 PPM US. NIOSH:
50 MG/M3 POCKET GUIDE TO
CHEMICAL HAZARDS (2005)
STEL 15 PPM US. OSHA TABLE Z-1-A
75 MG/M3 (29 CFR 1910.1000)
(1989)
BIOLOGICAL LIMIT VALUES:
CHEMICAL IDENTITY EXPOSURE LIMIT VALUES SOURCE
HEXANE (2,5-HEXANEDION, 0.5 MG/L (URINE) ACGIH BEL (03 2018)
WITHOUT HYDROLYSIS: SAMPLING
TIME: END' OF SHIFT.)
2-PROPANONE (ACETONE: 25 MG/L (URINE) ACGIH BEL (03 2015)
SAMPLING TIME: END OF SHIFT.)
BENZENE, DIMETHYL- 1.5 G/G ACGIH BEL (03 2013)
(METHYLHIPPURIC ACIDS: (CREATININE IN URINE)
SAMPLING TIME: END OF SHIFT.)
BENZENE, METHYL- (TOLUENE: 0.03 MG/L (URINE) ACGIH BEL (03 2013)
SAMPLING TIME: END OF SHIFT.)
BENZENE, METHYL- (O-CRESOL, 0.3 MG/G ACGIH BEL (03 2013)
WITH HYDROLYSIS: (CREATININE IN URINE)
SAMPLING TIME: END OF SHIFT.)
BENZENE, METHYL- (TOLUENE: 0.02 MG/L (BLOOD) ACGIH BEL (03 2013)
SAMPLING TIME: PRIOR TO
LAST SHIFT OF WORK WEEK.)
BENZENE, ETHYL- (SUM OF 0.15 G/G ACGIH BEL (02 2014)
MANDELIC ACID AND (CREATININE IN URINE)
PHENYLGLYOXYLIC ACID:
SAMPLING TIME: END OF SHIFT.)
BENZENE (T,T-MUCONIC ACID: 500 (MICRO)G/G ACGIH BEL (03 2013)
SAMPLING TIME: END OF SHIFT.) (CREATININE IN URINE)
BENZENE (S-PHENYLMERCAPTURIC 25 (MICRO)G/G ACGIH BEL (03 2013)
ACID: SAMPLING TIME: (CREATININE IN URINE)
END OF SHIFT.)
APPROPRIATE ENGINEERING CONTROLS: NO DATA AVAILABLE.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
GENERAL INFORMATION:
PROVIDE EASY ACCESS TO WATER SUPPLY AND EYE WASH FACILITIES. GOOD GENERAL
VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE USED. VENTILATION
RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE, USE PROCESS
ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING CONTROLS TO
MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. IF EXPOSURE
LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN ACCEPTABLE
LEVEL. IF EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE
LEVELS TO AN ACCEPTABLE LEVEL.
EYE/FACE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
SKIN PROTECTION:
HAND PROTECTION: NO DATA AVAILABLE.
OTHER:
WEAR SUITABLE PROTECTIVE CLOTHING. WEAR CHEMICAL-RESISTANT GLOVES,
FOOTWEAR, AND PROTECTIVE CLOTHING APPROPRIATE FOR THE RISK OF EXPOSURE.
CONTACT HEALTH AND SAFETY PROFESSIONAL OR MANUFACTURER FOR SPECIFIC
INFORMATION.
RESPIRATORY PROTECTION:
IN CASE OF INADEQUATE VENTILATION USE SUITABLE RESPIRATOR. SEEK ADVICE
FROM LOCAL SUPERVISOR.
HYGIENE MEASURES:
OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES. WHEN USING DO NOT SMOKE. DO
NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. WASH CONTAMINATED CLOTHING BEFORE
REUSE. AVOID CONTACT WITH SKIN. WASH HANDS BEFORE BREAKS AND IMMEDIATELY
AFTER HANDLING THE PRODUCT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID
FORM: SPRAY AEROSOL
COLOR: NO DATA AVAILABLE.
ODOR: NO DATA AVAILABLE.
ODOR THRESHOLD: NO DATA AVAILABLE.
PH: NO DATA AVAILABLE.
MELTING POINT/FREEZING POINT: NO DATA AVAILABLE.
INITIAL BOILING POINT AND BOILING RANGE: ESTIMATED 56.05 DEG. C
FLASH POINT: -104.4 DEG. C
EVAPORATION RATE: NO DATA AVAILABLE.
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE.
UPPER/LOWER LIMIT ON FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - UPPER (%): 11.2%(V)
FLAMMABILITY LIMIT - LOWER (%): 2.3%(V)
EXPLOSIVE LIMIT - UPPER (%): NO DATA AVAILABLE.
EXPLOSIVE LIMIT - LOWER (%): NO DATA AVAILABLE.
VAPOR PRESSURE: NO DATA AVAILABLE.
VAPOR DENSITY: NO DATA AVAILABLE.
DENSITY: NO DATA AVAILABLE.
RELATIVE DENSITY: NO DATA AVAILABLE.
SOLUBILITY(IES):
SOLUBILITY IN WATER: NO DATA AVAILABLE.
SOLUBILITY (OTHER): NO DATA AVAILABLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NO DATA AVAILABLE.
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE.
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE.
VISCOSITY: NO DATA AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NO DATA AVAILABLE.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: NO DATA AVAILABLE.
CONDITIONS TO AVOID: AVOID HEAT OR CONTAMINATION.
INCOMPATIBLE MATERIALS: NO DATA AVAILABLE.
HAZARDOUS DECOMPOSITION PRODUCTS: NO DATA AVAILABLE.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION: NO DATA AVAILABLE.
SKIN CONTACT: NO DATA AVAILABLE.
EYE CONTACT: NO DATA AVAILABLE.
INGESTION: NO DATA AVAILABLE.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
INHALATION: NO DATA AVAILABLE.
SKIN CONTACT: NO DATA AVAILABLE.
EYE CONTACT: NO DATA AVAILABLE.
INGESTION: NO DATA AVAILABLE.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY (LIST ALL POSSIBLE ROUTES OF EXPOSURE):
ORAL:
PRODUCT: NOT CLASSIFIED FOR ACUTE TOXICITY BASED ON AVAILABLE DATA.
SPECIFIED SUBSTANCE(S):
HEXANE:
LD50: >2,000 MG/KG
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT:
LD50 (RAT): >5,000 MG/KG
2-PROPANONE:
LD50 (RAT): 5,800 MG/KG
CYCLOHEXANE:
LD50 (RAT): >5,000 MG/KG
HEPTANE:
LD50 (RAT): >5,000 MG/KG
1,2-BENZENEDICARBOXYLIC ACID, 1,2-DIETHYL ESTER:
LD50 (MOUSE): 2,500 MG/KG
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH.:
LD50 (RAT): >5,000 MG/KG
DERMAL:
PRODUCT: NOT CLASSIFIED FOR ACUTE TOXICITY BASED ON AVAILABLE DATA.
SPECIFIED SUBSTANCE(S):
HEXANE:
LD50 (RABBIT): >2,000 MG/KG
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT:
LD50 (RABBIT): >3,750 MG/KG
2-PROPANONE:
LD50 (RABBIT): >7,426 MG/KG
CYCLOHEXANE:
LD50 (RABBIT): >2,000 MG/KG
HEPTANE:
LD50 (RABBIT): >2,000 MG/KG
1,2-BENZENEDICARBOXYLIC ACID, 1,2-DIETHYL ESTER:
LD50: >2,000 MG/KG
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH.:
LD50 (RABBIT): >2,000 MG/KG
INHALATION:
PRODUCT: NOT CLASSIFIED FOR ACUTE TOXICITY BASED ON AVAILABLE DATA.
SPECIFIED SUBSTANCE(S):
PROPANE:
LC50 (MOUSE): 1,237 MG/L
BUTANE:
LC50 (MOUSE): 1,237 MG/L
HEXANE:
LC50 (RAT): >31.86 MG/L
LC50: >5 MG/L
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT:
LOAEL (HUMAN): 2,400 MG/M3
LC50 (RAT): >7,630 MG/M3
LC50: >5 MG/L
2-PROPANONE:
LC50 (RAT): 50.1 MG/L
LC50: >5 MG/L
CYCLOHEXANE:
LC50 (RAT): >32,880 MG/M3
HEPTANE:
LC50 (RAT): >29.29 MG/L
1,2-BENZENEDICARBOXYLIC 1,2-DIETHYL ESTER:
LC50: >20 MG/L ACID,
LC50: >5 MG/L
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH.:
LOAEL (HUMAN): 4,320 MG/M3
LC50: 5.6 MG/L
LC50: >20 MG/L
REPEATED DOSE TOXICITY:
PRODUCT: NO DATA AVAILABLE.
SPECIFIED SUBSTANCE(S):
PROPANE:
NOAEL (RAT(FEMALE, MALE), INHALATION, >=28 D):
4,000 PPM(M) INHALATION EXPERIMENTAL RESULT, KEY STUDY
LOAEL (RAT(FEMALE, MALE), INHALATION, >=28 D):
12,000 PPM(M) INHALATION EXPERIMENTAL RESULT, KEY STUDY
BUTANE:
NOAEL (RAT(FEMALE, MALE), INHALATION, >=28 D):
4,000 PPM(M) INHALATION EXPERIMENTAL RESULT, KEY STUDY
LOAEL (RAT(FEMALE, MALE), INHALATION, >=28 D):
12,000 PPM(M) INHALATION EXPERIMENTAL RESULT, KEY STUDY
HEXANE:
NOAEL (MOUSE(MALE), INHALATION, 13 WEEKS):
500 PPM(M) INHALATION EXPERIMENTAL RESULT, KEY STUDY
LOAEL (MOUSE(MALE), INHALATION, 13 WEEKS):
1,000 PPM(M) INHALATION EXPERIMENTAL RESULT, KEY STUDY
LOAEL (RAT(MALE), INHALATION, 16 WEEKS):
3,000 PPM(M) INHALATION EXPERIMENTAL RESULT, KEY STUDY
LOAEL (MOUSE(FEMALE), INHALATION, 13 WEEKS):
500 PPM(M) INHALATION EXPERIMENTAL RESULT, KEY STUDY
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT:
LOAEL (RAT(FEMALE, MALE), ORAL, 13 WEEKS):
1,250 MG/KG ORAL READ-ACROSS BASED ON GROUPING OF SUBSTANCES
(CATEGORY APPROACH), KEY STUDY
NOAEL (RAT(FEMALE, MALE), DERMAL, 28 D):
>375 MG/KG DERMAL EXPERIMENTAL RESULT, SUPPORTING STUDY
NOAEL (RAT(FEMALE, MALE), INHALATION):
10,000 MG/M3 INHALATION EXPERIMENTAL RESULT, KEY STUDY
2-PROPANONE:
NOAEL (RAT(MALE), ORAL, 13 WEEKS):
10,000 PPM(M) ORAL EXPERIMENTAL RESULT, KEY STUDY
CYCLOHEXANE:
NOAEL (RAT(FEMALE, MALE), INHALATION, 13 - 18 WEEKS):
7,000 PPM(M) INHALATION EXPERIMENTAL RESULT, KEY STUDY
NOAEL (MOUSE(FEMALE, MALE), INHALATION, 13 - 18 WEEKS):
500 PPM(M) INHALATION EXPERIMENTAL RESULT, KEY STUDY
HEPTANE:
NOAEL (RAT(MALE), INHALATION):
12,470 MG/M3 INHALATION EXPERIMENTAL RESULT, KEY STUDY
1,2-BENZENEDICARBOXYLIC ACID, 1,2-DIETHYL ESTER:
NOAEL (RAT(FEMALE, MALE), ORAL, 6 - 16 WEEKS):
150 MG/KG ORAL EXPERIMENTAL RESULT, KEY STUDY
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH.:
NOAEL (MOUSE, RAT(FEMALE, MALE), INHALATION, 107 - 113 WEEKS):
1,402 MG/M3 INHALATION EXPERIMENTAL RESULT, KEY STUDY
NOAEL (RAT(FEMALE, MALE), DERMAL, 5 - 28 D):
3,750 MG/KG DERMAL EXPERIMENTAL RESULT, KEY STUDY
NOAEL (RAT(FEMALE, MALE), DERMAL, 28 D):
>375 MG/KG DERMAL EXPERIMENTAL RESULT, SUPPORTING STUDY
SKIN CORROSION/IRRITATION:
PRODUCT: NO DATA AVAILABLE.
SPECIFIED SUBSTANCE(S):
2-PROPANONE:
IN VIVO (RABBIT): NOT IRRITANT EXPERIMENTAL RESULT, SUPPORTING STUDY
CYCLOHEXANE:
REVIEW (VARIOUS): IRRITATING.
IN VIVO (RABBIT):
NOT IRRITANT EXPERIMENTAL RESULT, WEIGHT OF EVIDENCE STUDY
HEPTANE:
IN VIVO (RABBIT):
IRRITATING READ-ACROSS BASED ON GROUPING OF SUBSTANCES (CATEGORY APPROACH),
KEY STUDY
1,2-BENZENEDICARBOXYLIC ACID, 1,2-DIETHYL ESTER:
IN VIVO (RABBIT): NOT IRRITANT EXPERIMENTAL RESULT, KEY STUDY
SERIOUS EYE DAMAGE/EYE IRRITATION:
PRODUCT: NO DATA AVAILABLE.
SPECIFIED SUBSTANCE(S):
HEXANE:
RABBIT, 1 - 72 HRS: NOT IRRITATING
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT:
RABBIT, 24 - 72 HRS: NOT IRRITATING
2-PROPANONE: IRRITATING.
RABBIT, 24 HRS: MINIMUM GRADE OF SEVERE EYE IRRITANT
HEPTANE:
RABBIT, 24 - 72 HRS: NOT IRRITATING
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH.:
RABBIT: NOT IRRITATING
RESPIRATORY OR SKIN SENSITIZATION:
PRODUCT: NO DATA AVAILABLE.
SPECIFIED SUBSTANCE(S):
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT:
SKIN SENSITIZATION:
IN VIVO (GUINEA PIG): NON SENSITISING
2-PROPANONE:
SKIN SENSITIZATION:
IN VIVO (GUINEA PIG): NON SENSITISING
CYCLOHEXANE:
SKIN SENSITIZATION:
IN VIVO (GUINEA PIG): NON SENSITISING
HEPTANE:
SKIN SENSITIZATION:
IN VIVO (GUINEA PIG): NON SENSITISING
1,2-BENZENEDICARBOXYLIC ACID, 1,2-DIETHYL ESTER:
SKIN SENSITIZATION:
IN VIVO (GUINEA PIG): NON SENSITISING
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH.:
SKIN SENSITIZATION:
IN VIVO (GUINEA PIG): NON SENSITISING
CARCINOGENICITY:
PRODUCT: NO DATA AVAILABLE.
IARC MONOGRAPHS ON THE EVALUATION OF CARCINOGENIC RISKS TO HUMANS:
NO CARCINOGENIC COMPONENTS IDENTIFIED
US. NATIONAL TOXICOLOGY PROGRAM (NTP) REPORT ON CARCINOGENS:
NO CARCINOGENIC COMPONENTS IDENTIFIED
US. OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
NO CARCINOGENIC COMPONENTS IDENTIFIED
GERM CELL MUTAGENICITY:
IN VITRO:
PRODUCT: NO DATA AVAILABLE.
IN VIVO:
PRODUCT: NO DATA AVAILABLE.
REPRODUCTIVE TOXICITY:
PRODUCT: NO DATA AVAILABLE.
SPECIFIED SUBSTANCE(S):
HEXANE: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
PRODUCT: NO DATA AVAILABLE.
SPECIFIED SUBSTANCE(S):
HEXANE:
INHALATION - VAPOR: NARCOTIC EFFECT. - CATEGORY 3 WITH NARCOTIC EFFECTS.
2-PROPANONE:
INHALATION - VAPOR: NARCOTIC EFFECT. - CATEGORY 3 WITH NARCOTIC EFFECTS.
CYCLOHEXANE:
INHALATION - VAPOR: NARCOTIC EFFECT. - CATEGORY 3 WITH NARCOTIC EFFECTS.
HEPTANE: NARCOTIC EFFECT. - CATEGORY 3 WITH NARCOTIC EFFECTS.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
PRODUCT: NO DATA AVAILABLE.
SPECIFIED SUBSTANCE(S):
HEXANE:
INHALATION - VAPOR: NERVOUS SYSTEM - CATEGORY 2
TARGET ORGANS:
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NARCOTIC EFFECT.
ASPIRATION HAZARD:
PRODUCT: NO DATA AVAILABLE.
SPECIFIED SUBSTANCE(S):
HEXANE: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT:
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
CYCLOHEXANE: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
HEPTANE: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH.:
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
OTHER EFFECTS: NO DATA AVAILABLE.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
ACUTE HAZARDS TO THE AQUATIC ENVIRONMENT:
FISH:
PRODUCT: NO DATA AVAILABLE.
SPECIFIED SUBSTANCE(S):
PROPANE:
LC50 (VARIOUS, 96 H): 147.54 MG/L QSAR QSAR, KEY STUDY
BUTANE:
LC50 (VARIOUS, 96 H): 147.54 MG/L QSAR QSAR, KEY STUDY
HEXANE:
LC50 (FATHEAD MINNOW (PIMEPHALES PROMELAS), 96 H):
2.101 - 2.981 MG/L MORTALITY
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT:
LC50 (96 H): 8.41 MG/L EXPERIMENTAL RESULT, KEY STUDY
SILOXANES AND SILICONES, DI-ME:
LC50 (REDEAR SUNFISH (LEPOMIS MICROLOPHUS), 96 H):
26.27 - 56.73 MG/L MORTALITY
2-PROPANONE:
LC50 (ONCORHYNCHUS MYKISS, 96 H): 5,540 MG/L EXPERIMENTAL RESULT, KEY STUDY
CYCLOHEXANE:
LC50 (PIMEPHALES PROMELAS, 96 H): 4.53 MG/L EXPERIMENTAL RESULT, KEY STUDY
HEPTANE:
LC50 (MOZAMBIQUE TILAPIA (TILAPIA MOSSAMBICA), 96 H): 375 MG/L MORTALITY
1,2-BENZENEDICARBOXYLIC ACID, 1,2-DIETHYL ESTER:
NOAEL (ONCORHYNCHUS MYKISS, 96 H): 1.9 MG/L EXPERIMENTAL RESULT, KEY STUDY
LC50 (ONCORHYNCHUS MYKISS, 96 H): 12 MG/L EXPERIMENTAL RESULT, KEY STUDY
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH.:
LL50 (PIMEPHALES PROMELAS, 96 H): 8.2 MG/L EXPERIMENTAL RESULT, KEY STUDY
AQUATIC INVERTEBRATES:
PRODUCT: NO DATA AVAILABLE.
SPECIFIED SUBSTANCE(S):
BUTANE:
LC50 (DAPHNIA SP., 48 H): 69.43 MG/L QSAR QSAR, KEY STUDY
HEXANE:
EC50 (DAPHNIA MAGNA, 48 H): 21.85 MG/L QSAR QSAR, KEY STUDY
LC50 (WATER FLEA (DAPHNIA MAGNA), 24 H): >50 MG/L MORTALITY
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT:
EC50 (DAPHNIA MAGNA, 48 H): 4.5 MG/L EXPERIMENTAL RESULT, KEY STUDY
SILOXANES AND SILICONES, DI-ME:
LC50 (WATER FLEA (DAPHNIA MAGNA), 48 H): 44.5 MG/L MORTALITY
2-PROPANONE:
LC50 (DAPHNIA PULEX, 48 H): 8,800 MG/L EXPERIMENTAL RESULT, KEY STUDY
CYCLOHEXANE:
EC50 (DAPHNIA MAGNA, 48 H): 0.9 MG/L EXPERIMENTAL RESULT, KEY STUDY
HEPTANE:
EC50 (DAPHNIA MAGNA, 48 H): 1.5 MG/L EXPERIMENTAL RESULT, KEY STUDY
1,2-BENZENEDICARBOXYLIC ACID, 1,2-DIETHYL ESTER:
NOAEL (DAPHNIA MAGNA, 48 H): 43 MG/L EXPERIMENTAL RESULT, KEY STUDY
LC50 (DAPHNIA MAGNA, 48 H): 90 MG/L EXPERIMENTAL RESULT, KEY STUDY
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH.:
EC50 (DAPHNIA MAGNA, 48 H): 4.5 MG/L EXPERIMENTAL RESULT, KEY STUDY
NOAEL (DAPHNIA MAGNA, 48 H): 0.5 MG/L EXPERIMENTAL RESULT, KEY STUDY
CHRONIC HAZARDS TO THE AQUATIC ENVIRONMENT:
FISH:
PRODUCT: NO DATA AVAILABLE.
SPECIFIED SUBSTANCE(S):
HEXANE:
NOAEL (ONCORHYNCHUS MYKISS): 2.8 MG/L QSAR QSAR, KEY STUDY
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT:
EC50 (DAPHNIA MAGNA): 10 MG/L OTHER, KEY STUDY
NOAEL (DAPHNIA MAGNA): 2.6 MG/L OTHER, KEY STUDY
HEPTANE:
NOAEL (ONCORHYNCHUS MYKISS): 1.284 MG/L QSAR QSAR, KEY STUDY
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH.:
NOAEL (DAPHNIA MAGNA): 2.6 MG/L OTHER, KEY STUDY
AQUATIC INVERTEBRATES:
PRODUCT: NO DATA AVAILABLE.
SPECIFIED SUBSTANCE(S):
HEXANE:
NOAEL (DAPHNIA MAGNA): 4.888 MG/L QSAR QSAR, KEY STUDY
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT:
EC50 (DAPHNIA MAGNA): 10 MG/L EXPERIMENTAL RESULT, KEY STUDY
NOAEL (DAPHNIA MAGNA): 2.6 MG/L EXPERIMENTAL RESULT, KEY STUDY
2-PROPANONE:
LOAEL (DAPHNIA MAGNA): 2,212 MG/L EXPERIMENTAL RESULT, KEY STUDY
NOAEL (DAPHNIA MAGNA): 2,212 MG/L EXPERIMENTAL RESULT, KEY STUDY
HEPTANE:
NOAEL (DAPHNIA MAGNA):
0.17 MG/L READ-ACROSS BASED ON GROUPING OF SUBSTANCES (CATEGORY APPROACH),
KEY STUDY
EC50 (DAPHNIA MAGNA):
0.23 MG/L READ-ACROSS BASED ON GROUPING OF SUBSTANCES (CATEGORY APPROACH),
KEY STUDY
1,2-BENZENEDICARBOXYLIC ACID, 1,2-DIETHYL ESTER:
NOAEL (DAPHNIA MAGNA): 25 MG/L EXPERIMENTAL RESULT, KEY STUDY
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH.:
EC50 (DAPHNIA MAGNA): >40 MG/L EXPERIMENTAL RESULT, KEY STUDY
TOXICITY TO AQUATIC PLANTS:
PRODUCT: NO DATA AVAILABLE.
PERSISTENCE AND DEGRADABILITY:
BIODEGRADATION:
PRODUCT: NO DATA AVAILABLE.
SPECIFIED SUBSTANCE(S):
PROPANE:
100% (385.5 H) DETECTED IN WATER. EXPERIMENTAL RESULT, KEY STUDY
50% (3.19 D) DETECTED IN WATER. QSAR, WEIGHT OF EVIDENCE STUDY
BUTANE:
100% (385.5 H) DETECTED IN WATER. EXPERIMENTAL RESULT, KEY STUDY
50% (3.19 D) DETECTED IN WATER. QSAR, WEIGHT OF EVIDENCE STUDY
HEXANE:
81% DETECTED IN WATER. READ-ACROSS BASED ON GROUPING OF SUBSTANCES
(CATEGORY APPROACH), KEY STUDY
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT:
90.35% (28 D) DETECTED IN WATER. EXPERIMENTAL RESULT, SUPPORTING STUDY
2-PROPANONE: 90.9% (28 D) DETECTED IN WATER. EXPERIMENTAL RESULT, KEY STUDY
CYCLOHEXANE: 77% (28 D) DETECTED IN WATER. EXPERIMENTAL RESULT, KEY STUDY
HEPTANE: 70% DETECTED IN WATER. EXPERIMENTAL RESULT, KEY STUDY
1,2-BENZENEDICARBOXYLIC ACID, 1,2-DIETHYL ESTER:
94.6% (28 D) DETECTED IN WATER. EXPERIMENTAL RESULT, KEY STUDY
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH.:
89% (28 D) DETECTED IN WATER. EXPERIMENTAL RESULT, SUPPORTING STUDY
94% (25 D) DETECTED IN WATER. EXPERIMENTAL RESULT, SUPPORTING STUDY
74.76% DETECTED IN WATER. EXPERIMENTAL RESULT, SUPPORTING STUDY
90.35% (28 D) DETECTED IN WATER. EXPERIMENTAL RESULT, SUPPORTING STUDY
14.89% DETECTED IN WATER. EXPERIMENTAL RESULT, SUPPORTING STUDY
BOD/COD RATIO:
PRODUCT: NO DATA AVAILABLE.
BIOACCUMULATIVE POTENTIAL:
BIOCONCENTRATION FACTOR (BCF):
PRODUCT: NO DATA AVAILABLE.
SPECIFIED SUBSTANCE(S):
HEXANE:
PIMEPHALES PROMELAS, BIOCONCENTRATION FACTOR (BCF):
501.19 AQUATIC SEDIMENT QSAR, KEY STUDY
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT:
BIOCONCENTRATION FACTOR (BCF):
10 - 2,500 AQUATIC SEDIMENT ESTIMATED BY CALCULATION, KEY STUDY
2-PROPANONE:
HADDOCK, ADULT, BIOCONCENTRATION FACTOR (BCF):
0.69 AQUATIC SEDIMENT EXPERIMENTAL RESULT, NOT SPECIFIED
CYCLOHEXANE:
CYPRINUS CARPIO, BIOCONCENTRATION FACTOR (BCF):
37 - 129 AQUATIC SEDIMENT EXPERIMENTAL RESULT, SUPPORTING STUDY
HEPTANE:
BIOCONCENTRATION FACTOR (BCF):
552 AQUATIC SEDIMENT ESTIMATED BY CALCULATION, KEY STUDY
1,2-BENZENEDICARBOXYLIC ACID, 1,2-DIETHYL ESTER:
BLUEGILL (LEPOMIS MACROCHIRUS), BIOCONCENTRATION FACTOR (BCF):
117 (FLOW THROUGH)
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH.:
BIOCONCENTRATION FACTOR (BCF):
10 - 2,500 AQUATIC SEDIMENT ESTIMATED BY CALCULATION, KEY STUDY
PARTITION COEFFICIENT N-OCTANOL / WATER (LOG KOW):
PRODUCT: NO DATA AVAILABLE.
SPECIFIED SUBSTANCE(S):
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT:
LOG KOW: >2.4 - <5.7 23 DEG. C YES EXPERIMENTAL RESULT, KEY STUDY
LOG KOW: 2.2 - 5.2 23 DEG. C YES EXPERIMENTAL RESULT, KEY STUDY
LOG KOW: 2.2 - 6.1 23 DEG. C YES EXPERIMENTAL RESULT, KEY STUDY
MOBILITY IN SOIL: NO DATA AVAILABLE.
KNOWN OR PREDICTED DISTRIBUTION TO ENVIRONMENTAL COMPARTMENTS:
PROPANE: NO DATA AVAILABLE.
BUTANE: NO DATA AVAILABLE.
HEXANE: NO DATA AVAILABLE.
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT: NO DATA AVAILABLE.
SILOXANES AND SILICONES, DI-ME: NO DATA AVAILABLE.
2-PROPANONE: NO DATA AVAILABLE.
CYCLOHEXANE: NO DATA AVAILABLE.
HEPTANE: NO DATA AVAILABLE.
1,2-BENZENEDICARBOXYLIC ACID, 1,2-DIETHYL ESTER: NO DATA AVAILABLE.
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH.: NO DATA AVAILABLE.
OTHER ADVERSE EFFECTS:
TOXIC TO AQUATIC ORGANISMS. HARMFUL TO AQUATIC LIFE WITH LONG LASTING
EFFECTS.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS:
DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE, OR
LOCAL LAWS.
CONTAMINATED PACKAGING: NO DATA AVAILABLE.
| 14. TRANSPORT INFORMATION | |
DOT:
UN NUMBER: UN 1950
UN PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.1
LABEL(S):
PACKING GROUP: II
MARINE POLLUTANT: NO
ENVIRONMENTAL HAZARDS: NO
MARINE POLLUTANT: NO
SPECIAL PRECAUTIONS FOR USER: NOT REGULATED.
IMDG:
UN NUMBER: UN 1950
UN PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE
TRANSPORT HAZARD CLASS(ES):
CLASS: 2
LABEL(S):
EMS NO.: F-D, S-U
PACKING GROUP:
ENVIRONMENTAL HAZARDS: YES
MARINE POLLUTANT: NO
SPECIAL PRECAUTIONS FOR USER: NOT REGULATED.
IATA:
UN NUMBER: UN 1950
PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.1
LABEL(S):
PACKING GROUP:
ENVIRONMENTAL HAZARDS: YES
MARINE POLLUTANT: NO
SPECIAL PRECAUTIONS FOR USER: NOT REGULATED.
CARGO AIRCRAFT ONLY: ALLOWED.
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
RESTRICTIONS ON USE: NOT KNOWN.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
US. OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
CHEMICAL IDENTITY OSHA HAZARD(S)
BENZENE RESPIRATORY TRACT IRRITATION
CENTRAL NERVOUS SYSTEM
BLOOD
SKIN
FLAMMABILITY
CANCER
ASPIRATION
EYE
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4):
CHEMICAL IDENTITY REPORTABLE QUANTITY
PROPANE LBS. 100
BUTANE LBS. 100
HEXANE LBS. 5000
CYCLOPENTANE, METHYL- LBS. 100
2-PROPANONE LBS. 5000
CYCLOHEXANE LBS. 1000
HEPTANE LBS. 100
1,2-BENZENEDICARBOXYLIC ACID, LBS. 1000
1,2-DIETHYL ESTER
BENZENE, DIMETHYL- LBS. 100
ACETIC ACID, PENTYL ESTER LBS. 5000
BENZENE, METHYL- LBS. 1000
BUTANOIC ACID, ETHYL ESTER LBS. 100
BENZENE, ETHYL- LBS. 1000
ACETIC ACID ETHYL ESTER LBS. 5000
BENZENE LBS. 10
NAPHTHALENE LBS. 100
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
HAZARD CATEGORIES:
FIRE HAZARD
IMMEDIATE (ACUTE) HEALTH HAZARDS
DELAYED (CHRONIC) HEALTH HAZARD
FLAMMABLE AEROSOL
SKIN CORROSION/IRRITATION
TOXIC TO REPRODUCTION
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE
ASPIRATION HAZARD
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE:
CHEMICAL IDENTITY REPORTABLE QUANTITY THRESHOLD PLANNING QUANTITY
HEXANE
2-PROPANONE
TERPENES AND
TERPENOIDS, LEMON-OIL
SARA 304 EMERGENCY RELEASE NOTIFICATION:
CHEMICAL IDENTITY REPORTABLE QUANTITY
PROPANE LBS. 100
BUTANE LBS. 100
HEXANE LBS. 5000
CYCLOPENTANE, METHYL- LBS. 100
2-PROPANONE LBS. 5000
CYCLOHEXANE LBS. 1000
HEPTANE LBS. 100
1,2-BENZENEDICARBOXYLIC ACID, LBS. 1000
1,2-DIETHYL ESTER
BENZENE, DIMETHYL- LBS. 100
ACETIC ACID, PENTYL ESTER LBS. 5000
BENZENE, METHYL- LBS. 1000
BUTANOIC ACID, ETHYL ESTER LBS. 100
BENZENE, ETHYL- LBS. 1000
ACETIC ACID ETHYL ESTER LBS. 5000
BENZENE LBS. 10
NAPHTHALENE LBS. 100
TERPENES AND TERPENOIDS, LEMON-OIL
SARA 311/312 HAZARDOUS CHEMICAL:
CHEMICAL IDENTITY THRESHOLD PLANNING QUANTITY
PROPANE 10000 LBS
BUTANE 10000 LBS
HEXANE 10000 LBS
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT 10000 LBS
SILOXANES AND SILICONES, DI-ME 10000 LBS
2-PROPANONE 10000 LBS
CYCLOHEXANE 10000 LBS
HEPTANE 10000 LBS
1,2-BENZENEDICARBOXYLIC ACID, 10000 LBS
1,2-DIETHYL ESTER
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH. 10000 LBS
BENZENE, DIMETHYL- 10000 LBS
ACETIC ACID, PENTYL ESTER 10000 LBS
BENZENE, METHYL- 10000 LBS
BENZENE, ETHYL- 10000 LBS
ACETIC ACID ETHYL ESTER 10000 LBS
BENZENE 10000 LBS
NAPHTHALENE 10000 LBS
SARA 313 (TRI REPORTING):
CHEMICAL IDENTITY REPORTING THRESHOLD REPORTING THRESHOLD FOR
FOR OTHER USERS MANUFACTURING AND PROCESSING
HEXANE LBS LBS.
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION
(40 CFR 68.130):
CLEAN WATER ACT SECTION 311 HAZARDOUS SUBSTANCES (40 CFR 117.3):
US STATE REGULATIONS:
US. CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER AND/OR TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
HEXANE: MALE REPRODUCTIVE TOXIN. 12 2017
BENZENE, METHYL-: DEVELOPMENTAL TOXIN. 03 2008
BENZENE, ETHYL-: CARCINOGENIC. 05 2011
BENZENE: DEVELOPMENTAL TOXIN. 03 2008
BENZENE: CARCINOGENIC. 05 2011
BENZENE: MALE REPRODUCTIVE TOXIN. 03 2008
NAPHTHALENE: CARCINOGENIC. 05 2011
US. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
CHEMICAL IDENTITY:
PROPANE
BUTANE
HEXANE
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT
CYCLOPENTANE, METHYL-
2-PROPANONE
US. MASSACHUSETTS RTK - SUBSTANCE LIST:
CHEMICAL IDENTITY: BENZENE
US. PENNSYLVANIA RTK - HAZARDOUS SUBSTANCES:
CHEMICAL IDENTITY:
PROPANE
BUTANE
HEXANE
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT
CYCLOPENTANE, METHYL-
2-PROPANONE
US. RHODE ISLAND RTK:
NO INGREDIENT REGULATED BY RI RIGHT-TO-KNOW LAW PRESENT.
INTERNATIONAL REGULATIONS:
MONTREAL PROTOCOL:
HEXANE
2-PROPANONE
STOCKHOLM CONVENTION:
HEXANE
2-PROPANONE
ROTTERDAM CONVENTION:
HEXANE
2-PROPANONE
KYOTO PROTOCOL:
INVENTORY STATUS:
AUSTRALIA AICS: NOT IN COMPLIANCE WITH THE INVENTORY.
EINECS, ELINCS OR NLP: NOT IN COMPLIANCE WITH THE INVENTORY.
JAPAN (ENCS) LIST: NOT IN COMPLIANCE WITH THE INVENTORY.
CHINA INV. EXISTING CHEMICAL SUBSTANCES:
NOT IN COMPLIANCE WITH THE INVENTORY.
KOREA EXISTING CHEMICALS INV. (KECI): NOT IN COMPLIANCE WITH THE INVENTORY.
CANADA NDSL INVENTORY: NOT IN COMPLIANCE WITH THE INVENTORY.
PHILIPPINES PICCS: NOT IN COMPLIANCE WITH THE INVENTORY.
NEW ZEALAND INVENTORY OF CHEMICALS: NOT IN COMPLIANCE WITH THE INVENTORY.
JAPAN ISHL LISTING: NOT IN COMPLIANCE WITH THE INVENTORY.
JAPAN PHARMACOPOEIA LISTING: NOT IN COMPLIANCE WITH THE INVENTORY.
MEXICO INSQ: NOT IN COMPLIANCE WITH THE INVENTORY.
ONTARIO INVENTORY: NOT IN COMPLIANCE WITH THE INVENTORY.
TAIWAN CHEMICAL SUBSTANCE INVENTORY: NOT IN COMPLIANCE WITH THE INVENTORY.
CANADA DSL INVENTORY LIST: ON OR IN COMPLIANCE WITH THE INVENTORY
US TSCA INVENTORY: ON OR IN COMPLIANCE WITH THE INVENTORY
| 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION | |
OR LAST REVISION
ISSUE DATE: 08/28/2019
REVISION INFORMATION: NO DATA AVAILABLE.
VERSION #: 1.0
FURTHER INFORMATION: NO DATA AVAILABLE.
DISCLAIMER:
THIS INFORMATION IS PROVIDED WITHOUT WARRANTY. THE INFORMATION IS BELIEVED
TO BE CORRECT. THIS INFORMATION SHOULD BE USED TO MAKE AN INDEPENDENT
DETERMINATION OF THE METHODS TO SAFEGUARD WORKERS AND THE ENVIRONMENT.
SDS_US - RE1000011758