| Common Name: | METHYLENE BLUE, 1% (W/V) IN DENATURED ALCOHOL |
| Manufacturer: | RICCA CHEMICAL |
| SDS Revision Date: | 10/6/2021 |
| SDS Format: | No Format Specified |
| Item Number(s): | 45C919 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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R
RICCA CHEMICAL COMPANY
SAFETY DATA SHEET
CLASSIFIED ACCORDING TO OSHA HAZARD COMMUNICATION STANDARD (HCS)
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
TRADE NAME OR DESIGNATION: METHYLENE BLUE, 1% (W/V) IN DENATURED ALCOHOL
PRODUCT NUMBER: 4864
OTHER IDENTIFYING PRODUCT NUMBERS: 4864-16, 4864-32, 4864-4
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE: GENERAL LABORATORY REAGENT
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET
COMPANY: RICCA CHEMICAL COMPANY
ADDRESS:
448 WEST FORK DRIVE
ARLINGTON, TX 76012
USA
TELEPHONE: 888-467-4222
1.4. EMERGENCY TELEPHONE NUMBER (24 HOURS):
CHEMTREC (USA): 800-424-9300
CHEMTREC (INTERNATIONAL): 1+703-527-3887
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FOR THE FULL TEXT OF THE HAZARD AND PRECAUTIONARY STATEMENTS LISTED BELOW,
SEE SECTION 16.
HAZARD CLASS CATEGORY HAZARD PRECAUTIONARY
STATEMENTS STATEMENTS
EYE DAMAGE / IRRITATION CATEGORY 2A H319 P264, P280,
P305+P351+P338,
P337+P313
GERM CELL MUTAGENICITY CATEGORY 1 H340 P201, P202, P280,
P308+P313, P405,
P501
REPRODUCTIVE TOXICITY CATEGORY 1 H360 P201, P202, P280,
P308+P313, P405,
P501
SPECIFIC TARGET CATEGORY 1 H370 P260, P264, P270,
ORGANS/SYSTEMIC TOXICITY P307+P311, P321,
FOLLOWING SINGLE EXPOSURE P405, P501
SPECIFIC TARGET CATEGORY 1 H372 P260, P264, P270,
ORGANS/SYSTEMIC TOXICITY P314, P501
FOLLOWING REPEATED EXPOSURE
FLAMMABLE LIQUIDS CATEGORY 2 H225 P210, P233, P240,
P241, P242, P243,
P280,
P303+P361+P353,
P370+P378,
P403+P235, P501
2.2. GHS LABEL ELEMENTS:
PICTOGRAMS:
HEALTH HAZARD
EXCLAMATION MARK
FLAME
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
HAZARD NUMBER HAZARD STATEMENT
H225 HIGHLY FLAMMABLE LIQUID AND VAPOR.
H319 CAUSES SERIOUS EYE IRRITATION.
H340 MAY CAUSE GENETIC DEFECTS.
H360 MAY DAMAGE FERTILITY OR THE UNBORN CHILD.
H370 CAUSES DAMAGE TO ORGANS.
H372 CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED
EXPOSURE.
PRECAUTIONARY STATEMENTS:
PRECAUTIONARY NUMBER PRECAUTIONARY STATEMENT
P201 OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202 DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE
BEEN READ AND UNDERSTOOD.
P210 KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAME. NO
SMOKING.
P233 KEEP CONTAINER TIGHTLY CLOSED.
P240 GROUND CONTAINER AND RECEIVING EQUIPMENT.
P241 USE EXPLOSION-PROOF EQUIPMENT.
P242 USE ONLY NON-SPARKING TOOLS.
P243 TAKE PRECAUTIONARY MEASURES AGAINST STATIC
DISCHARGE.
P260 DO NOT BREATHE FUMES, MIST, VAPORS, OR SPRAY.
P264 WASH ARMS, HANDS AND FACE THOROUGHLY AFTER
HANDLING.
P270 DO NOT EAT, DRINK OR SMOKE WHEN USING THIS
PRODUCT.
P280 WEAR PROTECTIVE GLOVES AND EYE PROTECTION.
P303+P361+P353 IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
RINSE SKIN WITH WATER.
P305+P351+P338 IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES.
REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO.
CONTINUE RINSING.
P307+P311 IF EXPOSED: CALL A POISON CENTER OR PHYSICIAN.
P308+P313 IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
P314 GET MEDICAL ATTENTION IF YOU FEEL UNWELL.
P321 SPECIFIC TREATMENT (WASH AREAS OF CONTACT WITH
WATER).
P337+P313 IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
P370+P378 IN CASE OF FIRE:
USE DRY CHEMICAL, FOAM OR CARBON DIOXIDE TO
EXTINGUISH.
P403+P235 STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
P405 STORE LOCKED UP.
P501 DISPOSE OF CONTENTS IN ACCORDANCE WITH LOCAL,
STATE, FEDERAL AND INTERNATIONAL REGULATIONS.
2.4. HAZARDS NOT OTHERWISE CLASSIFIED OR COVERED BY GHS:
DATA NOT AVAILABLE.
| SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS | |
3.1. COMPONENTS OF SUBSTANCE OR MIXTURE
CHEMICAL NAME FORMULA MOLECULAR WEIGHT CAS NUMBER WEIGHT%
ETHYL ALCOHOL CH3CH2OH 46.06 G/MOL 64-17-5 94.05
METHYL ALCOHOL CH3OH 32.04 G/MOL 67-56-1 4.70
METHYLENE BLUE C16H18ClN3S x 3H2O 373.90 G/MOL 7220-79-3 1.25
TRIHYDRATE
| SECTION 4: FIRST-AID MEASURES | |
4.1. GENERAL FIRST AID INFORMATION:
EYE CONTACT:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING. MAY CAUSE IRRITATION WITH BURNING
AND STINGING WITH POSSIBLE DAMAGE TO THE CORNEA AND CONJUNCTIVA.
INHALATION:
NOT EXPECTED TO REQUIRE FIRST AID. IF NECESSARY, REMOVE TO FRESH AIR.
SKIN CONTACT:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER.
RESULTS IN DRYING AND CRACKING WHICH CAN LEAD TO SECONDARY INFECTIONS AND
DERMATITIS.
INGESTION:
DILUTE IMMEDIATELY WITH WATER OR MILK. INDUCE VOMITING. CALL A PHYSICIAN.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, ACUTE AND DELAYED:
CAUSES SERIOUS EYE IRRITATION. MAY CAUSE GENETIC DEFECTS. MAY DAMAGE
FERTILITY OR THE UNBORN CHILD. CAUSES DAMAGE TO ORGANS. CAUSES DAMAGE TO
ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. FLAMMABLE LIQUID. PRIMARILY
TOXIC BY INGESTION. IF INGESTED, GIVE LARGE QUANTITY OF WATER AND INDUCE
VOMITING. CALL A PHYSICIAN. CONTACT MAY CAUSE DRYNESS AND CRACKING OF THE
SKIN. MAY CAUSE IRRITATION TO THE EYES. WASH AREAS OF CONTACT WITH PLENTY
OF WATER. MAY CAUSE IRRITATION OF THE RESPIRATORY SYSTEM.
EYE CONTACT:
MAY CAUSE IRRITATION WITH BURNING AND STINGING WITH POSSIBLE DAMAGE TO THE
CORNEA AND CONJUNCTIVA.
SKIN CONTACT:
RESULTS IN DRYING AND CRACKING WHICH CAN LEAD TO SECONDARY INFECTIONS AND
DERMATITIS.
4.3. MEDICAL ATTENTION OR SPECIAL TREATMENT NEEDED:
SPECIFIC TREATMENT (WASH AREAS OF CONTACT WITH WATER). IRRIGATE IMMEDIATELY
WITH LARGE QUANTITY OF WATER FOR AT LEAST 15 MINUTES. CALL A PHYSICIAN IF
IRRITATION DEVELOPS. REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF
NECESSARY. IF BREATHING IS DIFFICULT, GIVE OXYGEN. WASH AREAS OF CONTACT
WITH SOAP AND WATER FOR AT LEAST 15 MINUTES. CALL A PHYSICIAN IF IRRITATION
DEVELOPS. DILUTE IMMEDIATELY WITH WATER OR MILK. INDUCE VOMITING. CALL A
PHYSICIAN.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE DRY CHEMICAL, FOAM OR CARBON DIOXIDE TO EXTINGUISH. USE DRY CHEMICAL,
ALCOHOL FOAM, OR CARBON DIOXIDE FOR EXTINGUISHING THE SURROUNDING FIRE.
USE WATER AS FOG IN FLOODING QUANTITIES. WATER CAN BE USED TO DILUTE
SPILLS TO NON-FLAMMABLE MIXTURES.
5.2. SPECIFIC HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
HIGHLY FLAMMABLE LIQUID AND VAPOR. VAPORS CAN FLOW ALONG SURFACES TO
DISTANT IGNITION SOURCE AND FLASHBACK. USE WATER SPRAY TO BLANKET FIRE,
COOL FIRE EXPOSED CONTAINERS, AND TO FLUSH NON-IGNITED SPILLS OR VAPORS
AWAY FROM FIRE. EXPLOSION HAZARD WHEN EXPOSED TO HEAT, FLAME OR OXIDIZERS.
5.3. SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
WEAR FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING
APPARATUS WITH FULL FACEPIECE OPERATED IN THE PRESSURE DEMAND OR OTHER
POSITIVE PRESSURE MODE.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GROUND CONTAINER AND RECEIVING EQUIPMENT. USE EXPLOSION-PROOF EQUIPMENT.
USE ONLY NON-SPARKING TOOLS. TAKE PRECAUTIONARY MEASURES AGAINST STATIC
DISCHARGE. WEAR PROTECTIVE GLOVES AND EYE PROTECTION.
6.2. CLEANUP AND CONTAINMENT METHODS AND MATERIALS:
REMOVE ALL SOURCES OF IGNITION. CONTAIN SPILL. DO NOT FLUSH TO SEWER.
ABSORB WITH SUITABLE INERT MATERIAL (VERMICULITE, DRY SAND, ETC) AND PLACE
IN A CHEMICAL WASTE CONTAINER FOR PROPER DISPOSAL IN AN APPROVED WASTE
DISPOSAL FACILITY. VENTILATE AREA OF SPILL. HAVE EXTINGUISHING AGENT
AVAILABLE IN CASE OF FIRE. USE NON-SPARKING TOOLS AND EQUIPMENT. DISPOSE
OF IN ACCORDANCE WITH LOCAL REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING AND STORAGE CONDITIONS:
STORE LOCKED UP. AS WITH ALL CHEMICALS, WASH HANDS THOROUGHLY AFTER
HANDLING. AVOID CONTACT WITH EYES AND SKIN. PROTECT FROM FREEZING AND
PHYSICAL DAMAGE. STORE IN SECURE, FLAMMABLE STORAGE AREA AWAY FROM ALL
SOURCES OF IGNITION. EMPTY CONTAINERS MAY BE HAZARDOUS SINCE THEY RETAIN
PRODUCT RESIDUES.
| SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION | |
8.1 CONTROL PARAMETERS:
CHEMICAL NAME LIMIT COUNTRY EXPOSURE INFORMATION SOURCE
TYPE LIMIT
ETHYL ALCOHOL TWA USA 1000 PPM TWA U.S. - OSHA - FINAL
(64-17-5) 1900 MG/M3 TWA PELS - TIME
WEIGHTED AVERAGES
(TWAS)
ETHYL ALCOHOL TLV-STEL USA 1000 PPM STEL ACGIH - THRESHOLD
(64-17-5) LIMIT VALUES -
SHORT TERM
EXPOSURE LIMITS
(TLV-STEL)
METHYL ALCOHOL TWA USA 200 PPM TWA U.S. - OSHA - FINAL
(67-56-1) 260 MG/M3 TWA PELS - TIME
WEIGHTED AVERAGES
(TWAS)
METHYL ALCOHOL TLV-STEL USA 250 PPM STEL ACGIH - THRESHOLD
(67-56-1) LIMIT VALUES -
SHORT TERM EXPOSURE
LIMITS (TLV-STEL)
METHYL ALCOHOL TLV-TWA USA 200 PPM TWA ACGIH - THRESHOLD
(67-56-1) LIMIT VALUES - TIME
WEIGHTED AVERAGES
(TLV-TWA)
8.2. EXPOSURE CONTROLS:
ENGINEERING CONTROLS:
A SYSTEM OF LOCAL AND/OR GENERAL EXHAUST IS RECOMMENDED TO KEEP EMPLOYEE
EXPOSURES BELOW THE AIRBORNE EXPOSURE LIMIT.
RESPIRATORY PROTECTION:
NORMAL ROOM VENTILATION IS ADEQUATE. IF THE EXPOSURE LIMIT IS EXCEEDED, A
FULL FACEPIECE RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE MAY BE WORN.
SKIN PROTECTION:
WEAR PROTECTIVE GLOVES AND EYE PROTECTION. CHEMICAL RESISTANT GLOVES.
EYE PROTECTION:
WEAR PROTECTIVE GLOVES AND EYE PROTECTION. SAFETY GLASSES OR GOGGLES.
8.3. PERSONAL PROTECTIVE EQUIPMENT:
WEAR PROTECTIVE GLOVES AND EYE PROTECTION. NORMAL ROOM VENTILATION IS
ADEQUATE. IF THE EXPOSURE LIMIT IS EXCEEDED, A FULL FACEPIECE RESPIRATOR
WITH ORGANIC VAPOR CARTRIDGE MAY BE WORN. CHEMICAL RESISTANT GLOVES.
SAFETY GLASSES OR GOGGLES.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE: BLUE LIQUID
PHYSICAL STATE: LIQUID
ODOR: DATA NOT AVAILABLE.
ODOR THRESHOLD: DATA NOT AVAILABLE.
PH: DATA NOT AVAILABLE.
MELTING/FREEZING POINT: DATA NOT AVAILABLE.
INITIAL BOILING POINT/RANGE:
APPROXIMATELY 77 DEG. C - APPROXIMATELY 77 DEG. C
FLASH POINT: APPROXIMATELY 15.5 DEG. C
EVAPORATION RATE: DATA NOT AVAILABLE.
FLAMMABILITY: DATA NOT AVAILABLE.
FLAMMABILITY/EXPLOSIVE LIMITS: DATA NOT AVAILABLE.
VAPOR PRESSURE: DATA NOT AVAILABLE.
VAPOR DENSITY: DATA NOT AVAILABLE.
RELATIVE DENSITY: 0.8
SOLUBILITY: DATA NOT AVAILABLE.
PARTITION COEFFICIENT: DATA NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: DATA NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: DATA NOT AVAILABLE.
VISCOSITY: DATA NOT AVAILABLE.
EXPLOSIVE PROPERTIES: DATA NOT AVAILABLE.
OXIDIZING PROPERTIES: DATA NOT AVAILABLE.
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY AND CHEMICAL STABILITY:
STABLE UNDER NORMAL CONDITIONS OF USE AND STORAGE.
10.2. POSSIBILITY OF HAZARDOUS REACTIONS: DATA NOT AVAILABLE.
10.3. CONDITIONS TO AVOID AND INCOMPATIBLE MATERIALS:
KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAME. NO SMOKING. KEEP CONTAINER
TIGHTLY CLOSED. OXIDIZERS, PLATINUM, SODIUM, POTASSIUM DIOXIDE, BROMINE
PENTAFLUORIDE, ACETYL BROMIDE, ACETYL CHLORIDE, HEAT, SPARKS, OPEN FLAME.
10.4. HAZARDOUS DECOMPOSITION PRODUCTS: WILL NOT OCCUR.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY - ORAL EXPOSURE: NOT APPLICABLE.
ACUTE TOXICITY - DERMAL EXPOSURE: NOT APPLICABLE.
ACUTE TOXICITY - INHALATION EXPOSURE: NOT APPLICABLE.
ACUTE TOXICITY - OTHER INFORMATION:
LD50, ORAL, RAT:
(METHANOL) 5628 MG/KG, (METHYLENE BLUE) 1180 MG/KG, DETAILS OF TOXIC
EFFECTS NOT REPORTED OTHER THAN LETHAL DOSE VALUE, (ETHANOL) 7060 MG/KG,
RESPIRATION CHANGES NOTED.
SKIN CORROSION AND IRRITATION: NOT APPLICABLE.
SERIOUS EYE DAMAGE AND IRRITATION:
CAUSES SERIOUS EYE IRRITATION. WASH ARMS, HANDS AND FACE THOROUGHLY AFTER
HANDLING. WEAR PROTECTIVE GLOVES AND EYE PROTECTION.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
RESPIRATORY SENSITIZATION: NOT APPLICABLE.
SKIN SENSITIZATION: NOT APPLICABLE.
GERM CELL MUTAGENICITY:
MAY CAUSE GENETIC DEFECTS. OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT
HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. WEAR
PROTECTIVE GLOVES AND EYE PROTECTION.
IF EXPOSED OR CONCERNED:
GET MEDICAL ATTENTION. STORE LOCKED UP. DISPOSE OF CONTENTS IN ACCORDANCE
WITH LOCAL, STATE, FEDERAL AND INTERNATIONAL REGULATIONS.
CARCINOGENICITY: NOT APPLICABLE.
REPRODUCTIVE TOXICITY:
MAY DAMAGE FERTILITY OR THE UNBORN CHILD. OBTAIN SPECIAL INSTRUCTIONS
BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ
AND UNDERSTOOD. WEAR PROTECTIVE GLOVES AND EYE PROTECTION.
IF EXPOSED OR CONCERNED:
GET MEDICAL ATTENTION. STORE LOCKED UP. DISPOSE OF CONTENTS IN ACCORDANCE
WITH LOCAL, STATE, FEDERAL AND INTERNATIONAL REGULATIONS.
SPECIFIC TARGET ORGAN TOXICITY FROM SINGLE EXPOSURE:
CAUSES DAMAGE TO ORGANS. DO NOT BREATHE FUMES, MIST, VAPORS, OR SPRAY.
WASH ARMS, HANDS AND FACE THOROUGHLY AFTER HANDLING. DO NOT EAT, DRINK OR
SMOKE WHEN USING THIS PRODUCT.
IF EXPOSED:
CALL A POISON CENTER OR PHYSICIAN. SPECIFIC TREATMENT (WASH AREAS OF
CONTACT WITH WATER). STORE LOCKED UP. DISPOSE OF CONTENTS IN ACCORDANCE
WITH LOCAL, STATE, FEDERAL AND INTERNATIONAL REGULATIONS.
SPECIFIC TARGET ORGAN TOXICITY FROM REPEATED EXPOSURE:
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. DO NOT
BREATHE FUMES, MIST, VAPORS, OR SPRAY. WASH ARMS, HANDS AND FACE
THOROUGHLY AFTER HANDLING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS
PRODUCT. GET MEDICAL ATTENTION IF YOU FEEL UNWELL. DISPOSE OF CONTENTS IN
ACCORDANCE WITH LOCAL, STATE, FEDERAL AND INTERNATIONAL REGULATIONS.
ASPIRATION HAZARD: NOT APPLICABLE.
ADDITIONAL TOXICOLOGY INFORMATION: DATA NOT AVAILABLE.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. ECOTOXICITY: NOT APPLICABLE.
12.2. PERSISTENCE AND DEGRADABILITY: DATA NOT AVAILABLE.
12.3. BIOACCUMULATIVE POTENTIAL: DATA NOT AVAILABLE.
12.4. MOBILITY IN SOIL: DATA NOT AVAILABLE.
12.5. OTHER ADVERSE ECOLOGICAL EFFECTS: DATA NOT AVAILABLE.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS: DATA NOT AVAILABLE.
| SECTION 14: TRANSPORTATION INFORMATION | |
14.1. TRANSPORTATION BY LAND-DEPARTMENT OF TRANSPORTATION (DOT, UNITED
STATES OF AMERICA):
SIZES: 1 L, 120 ML, 500 ML
UN NUMBER: UN1987
PROPER SHIPPING NAME: ALCOHOLS, N.O.S. (ETHANOL, METHANOL)
HAZARD CLASS: 3
PACKING GROUP: II
HAZARD LABEL(S): FLAMMABLE LIQUID, CLASS/DIVISION 3.1, 3.2, 3.3
14.2. TRANSPORTATION BY AIR - INTERNATIONAL AIR TRANSPORT ASSOCIATION
(IATA):
SIZES: 1 L, 120 ML, 500 ML
UN NUMBER: UN1987
PROPER SHIPPING NAME: ALCOHOLS, N.O.S. (ETHANOL, METHANOL)
HAZARD CLASS: 3
PACKING GROUP: II
HAZARD LABEL(S): FLAMMABLE LIQUID, CLASS/DIVISION 3.1, 3.2, 3.3
14.3 TRANSPORTATION OF DANGEROUS GOODS (TDG, CANADA):
SIZES: 1 L, 120 ML, 500 ML
UN NUMBER: UN1987
PROPER SHIPPING NAME: ALCOHOLS, N.O.S. (ETHANOL, METHANOL)
HAZARD CLASS: 3
PACKING GROUP: II
HAZARD LABEL(S): CLASS 3, FLAMMABLE LIQUIDS
| SECTION 15: REGULATORY INFORMATION | |
15.1. OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA) HAZARDS:
NOT LISTED.
15.2. SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) 302 EXTREMELY
HAZARDOUS SUBSTANCES: NOT LISTED.
15.3. SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) 311/312
HAZARDOUS CHEMICALS:
METHYL ALCOHOL (CAS # 67-56-1):
5000 LB FINAL RQ
2270 KG FINAL RQ
15.4. SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) 313 TOXIC RELEASE
INVENTORY (TRI):
METHYL ALCOHOL (CAS # 67-56-1): 1.0% DE MINIMIS CONCENTRATION
15.5. MASSACHUSETTS RIGHT-TO-KNOW SUBSTANCE LIST:
ETHYL ALCOHOL (CAS # 64-17-5): TERATOGEN
METHYL ALCOHOL (CAS # 67-56-1): PRESENT
15.6. PENNSYLVANIA RIGHT-TO-KNOW HAZARDOUS SUBSTANCES:
ETHYL ALCOHOL (CAS # 64-17-5): PRESENT
METHYL ALCOHOL (CAS # 67-56-1): ENVIRONMENTAL HAZARD
METHYL ALCOHOL (CAS # 67-56-1): PRESENT
15.7. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW COMPONENTS:
ETHYL ALCOHOL (CAS # 64-17-5):
CARCINOGEN; FLAMMABLE - THIRD DEGREE; MUTAGEN; TERATOGEN
ETHYL ALCOHOL (CAS # 64-17-5): SN 0844
METHYL ALCOHOL (CAS # 67-56-1): FLAMMABLE - THIRD DEGREE; TERATOGEN
METHYL ALCOHOL (CAS # 67-56-1): SN 1222
METHYL ALCOHOL (CAS # 67-56-1): SN 1222 500 LB TPQ
15.8. CALIFORNIA PROPOSITION 65:
ETHYL ALCOHOL (CAS # 64-17-5):
CARCINOGEN, 4/29/2011 (IN ALCOHOLIC BEVERAGES)
ETHYL ALCOHOL (CAS # 64-17-5):
CARCINOGEN, 7/1/1988 (WHEN ASSOCIATED WITH ALCOHOL ABUSE)
ETHYL ALCOHOL (CAS # 64-17-5):
DEVELOPMENTAL TOXICITY, 10/1/1987 (IN ALCOHOLIC BEVERAGES)
METHYL ALCOHOL (CAS # 67-56-1): DEVELOPMENTAL TOXICITY, 3/16/2012
15.9. CANADA DOMESTIC SUBSTANCES LIST / NON-DOMESTIC SUBSTANCES LIST
(DSL/NDSL):
ETHYL ALCOHOL (CAS # 64-17-5): PRESENT (DSL)
ETHYL ALCOHOL (CAS # 64-17-5): PRESENT (NDSL)
METHYL ALCOHOL (CAS # 67-56-1): PRESENT (DSL)
METHYL ALCOHOL (CAS # 67-56-1): PRESENT (NDSL)
METHYLENE BLUE TRIHYDRATE (CAS # 7220-79-3): PRESENT (DSL)
15.10. UNITED STATES OF AMERICA TOXIC SUBSTANCES CONTROL ACT (TSCA) LIST:
ALL COMPONENTS OF THIS SOLUTION ARE LISTED AS ACTIVE ON THE TSCA INVENTORY
OR ARE MIXTURES (HYDRATES) OF ACTIVE ITEMS LISTED ON THE TSCA INVENTORY.
ETHYL ALCOHOL (CAS # 64-17-5): PRESENT
METHYL ALCOHOL (CAS # 67-56-1): PRESENT
METHYLENE BLUE TRIHYDRATE (CAS # 7220-79-3): PRESENT
15.11. EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES
(EINECS), EUROPEAN:
LIST OF NOTIFIED CHEMICAL SUBSTANCES (ELINCS), AND NO LONGER POLYMERS
(NLP):
ETHYL ALCOHOL (CAS # 64-17-5): 200-578-6
ETHYL ALCOHOL (CAS # 64-17-5): 270-649-4
METHYL ALCOHOL (CAS # 67-56-1): 200-659-6
METHYL ALCOHOL (CAS # 67-56-1): 212-378-6
METHYL ALCOHOL (CAS # 67-56-1): 217-435-9
METHYL ALCOHOL (CAS # 67-56-1): 270-649-4
METHYLENE BLUE TRIHYDRATE (CAS # 7220-79-3): 200-515-2
| SECTION 16: OTHER INFORMATION | |
16.1. FULL TEXT OF HAZARD STATEMENTS AND PRECAUTIONARY STATEMENTS:
HIGHLY FLAMMABLE LIQUID AND VAPOR. CAUSES SERIOUS EYE IRRITATION. MAY
CAUSE GENETIC DEFECTS. MAY DAMAGE FERTILITY OR THE UNBORN CHILD. CAUSES
DAMAGE TO ORGANS. CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED
EXPOSURE.
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. KEEP AWAY FROM HEAT, SPARKS
AND OPEN FLAME. NO SMOKING. KEEP CONTAINER TIGHTLY CLOSED. GROUND
CONTAINER AND RECEIVING EQUIPMENT. USE EXPLOSION-PROOF EQUIPMENT. USE ONLY
NON-SPARKING TOOLS. TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
DO NOT BREATHE FUMES, MIST, VAPORS, OR SPRAY. WASH ARMS, HANDS AND FACE
THOROUGHLY AFTER HANDLING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS
PRODUCT. WEAR PROTECTIVE GLOVES AND EYE PROTECTION.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EXPOSED:
CALL A POISON CENTER OR PHYSICIAN. GET MEDICAL ATTENTION IF YOU FEEL
UNWELL. SPECIFIC TREATMENT (WASH AREAS OF CONTACT WITH WATER).
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
IN CASE OF FIRE: USE DRY CHEMICAL, FOAM OR CARBON DIOXIDE TO EXTINGUISH.
STORE IN A WELL-VENTILATED PLACE. KEEP COOL. STORE LOCKED UP.
DISPOSE OF CONTENTS IN ACCORDANCE WITH LOCAL, STATE, FEDERAL AND
INTERNATIONAL REGULATIONS.
16.2. MISCELLANEOUS HAZARD CLASSES:
CANADIAN CARCINOGENICITY HAZARD CLASS: NOT APPLICABLE.
PHYSICAL HAZARDS NOT OTHERWISE CLASSIFIED (PHNOC): NOT APPLICABLE.
HEALTH HAZARDS NOT OTHERWISE CLASSIFIED (HHNOC): NOT APPLICABLE.
BIOHAZARDOUS INFECTIOUS MATERIALS HAZARD CLASS: NOT APPLICABLE.
16.3. NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) RATING:
HEALTH 1
FLAMMABILITY 3
REACTIVITY 0
SPECIAL HAZARD
16.4. DOCUMENT REVISION:
LAST REVISION DATE: 2021-10-06
DISCLAIMER:
WHEN HANDLED PROPERLY BY QUALIFIED PERSONNEL, THE PRODUCT DESCRIBED HEREIN
DOES NOT PRESENT A SIGNIFICANT HEALTH OR SAFETY HAZARD. ALTERATION OF ITS
CHARACTERISTICS BY CONCENTRATION, EVAPORATION, ADDITION OF OTHER
SUBSTANCES, OR OTHER MEANS MAY PRESENT HAZARDS NOT SPECIFICALLY ADDRESSED
HEREIN AND WHICH MUST BE EVALUATED BY THE USER. THE INFORMATION FURNISHED
HEREIN IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST DATA CURRENTLY
AVAILABLE TO US. NO WARRANTY, EXPRESSED OR IMPLIED, IS MADE AND RICCA
CHEMICAL COMPANY ASSUMES NO LEGAL RESPONSIBILITY OR LIABILITY WHATSOEVER
RESULTING FROM ITS USE.