| Common Name: | DPD INDICATOR SOLUTION, FOR RESIDUAL CHLORINE ANALYSIS |
| Manufacturer: | RICCA CHEMICAL |
| SDS Revision Date: | 10/6/2021 |
| SDS Format: | No Format Specified |
| Item Number(s): | 45D374 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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R
RICCA CHEMICAL COMPANY(R*)
SAFETY DATA SHEET
CLASSIFIED ACCORDING TO OSHA HAZARD COMMUNICATION STANDARD (HCS)
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
TRADE NAME OR DESIGNATION:
DPD INDICATOR SOLUTION, FOR RESIDUAL CHLORINE ANALYSIS
PRODUCT NUMBER: 2655
OTHER IDENTIFYING PRODUCT NUMBERS: 2655-1, 2655-100, 2655-16, 2655-32
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE: GENERAL LABORATORY REAGENT
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
COMPANY: RICCA CHEMICAL COMPANY
ADDRESS:
448 WEST FORK DRIVE
ARLINGTON, TX 76012
USA
TELEPHONE: 888-467-4222
1.4. EMERGENCY TELEPHONE NUMBER (24 HOURS):
CHEMTREC (USA): 800-424-9300
CHEMTREC (INTERNATIONAL): 1+ 703-527-3887
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FOR THE FULL TEXT OF THE HAZARD AND PRECAUTIONARY STATEMENTS LISTED BELOW,
SEE SECTION 16.
HAZARD CLASS CATEGORY HAZARD PRECAUTIONARY
STATEMENTS STATEMENTS
HAZARDOUS TO CATEGORY 3 H402 P273, P501
THE AQUATIC
ENVIRONMENT
(ACUTE)
2.2. GHS LABEL ELEMENTS:
PICTOGRAMS:
SIGNAL WORD:
HAZARD STATEMENTS:
HAZARD NUMBER HAZARD STATEMENT
H402 HARMFUL TO AQUATIC LIFE.
PRECAUTIONARY STATEMENTS:
PRECAUTIONARY NUMBER PRECAUTIONARY STATEMENT
P273 AVOID RELEASE TO THE ENVIRONMENT.
P501 DISPOSE OF CONTENTS IN ACCORDANCE WITH LOCAL,
STATE, FEDERAL AND INTERNATIONAL REGULATIONS.
2.4. HAZARDS NOT OTHERWISE CLASSIFIED OR COVERED BY GHS:
DATA NOT AVAILABLE.
| SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS | |
3.1. COMPONENTS OF SUBSTANCE OR MIXTURE:
CHEMICAL NAME FORMULA MOLECULAR CAS NUMBER WEIGHT%
WEIGHT
WATER H2O 18.01 G/MOL 7732-18-5 99.51
SULFURIC ACID H2SO4 98.07 G/MOL 7664-93-9 0.36
N,N-DIETHYL-1,4- C10H18N2O4S 262.32 G/MOL 6283-63-2 0.11
PHENYLENEDIAMINE
SULFATE
ETHYLENEDIAMINE- C10H14N2O8Na2 x 2H2O 372.24 G/MOL 6381-92-6 0.02
TETRAACETIC ACID
(EDTA), DISODIUM
SALT, DIHYDRATE
| SECTION 4: FIRST-AID MEASURES | |
4.1. GENERAL FIRST AID INFORMATION:
EYE CONTACT: MAY CAUSE SLIGHT IRRITATION.
INHALATION:
NOT EXPECTED TO REQUIRE FIRST AID. IF NECESSARY, REMOVE TO FRESH AIR.
SKIN CONTACT: MAY CAUSE SLIGHT IRRITATION.
INGESTION:
DILUTE WITH WATER OR MILK. DO NOT INDUCE VOMITING. CALL A PHYSICIAN IF
NECESSARY.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, ACUTE AND DELAYED:
THIS SOLUTION CONTAINS A VERY LOW CONCENTRATION OF A TOXIC SUBSTANCE AND
MAY BE HARMFUL IF INGESTED. IF INGESTED, DILUTE WITH WATER OR MILK AND
CALL A PHYSICIAN IF NECESSARY. WASH AREAS OF CONTACT WITH WATER. FOR EYES,
GET MEDICAL ATTENTION.
EYE CONTACT: MAY CAUSE SLIGHT IRRITATION.
SKIN CONTACT: MAY CAUSE SLIGHT IRRITATION.
4.3. MEDICAL ATTENTION OR SPECIAL TREATMENT NEEDED:
IRRIGATE IMMEDIATELY WITH LARGE QUANTITY OF WATER FOR AT LEAST 15 MINUTES.
CALL A PHYSICIAN IF IRRITATION DEVELOPS. REMOVE TO FRESH AIR. GIVE
ARTIFICIAL RESPIRATION IF NECESSARY. IF BREATHING IS DIFFICULT, GIVE
OXYGEN. WASH AREAS OF CONTACT WITH SOAP AND WATER FOR AT LEAST 15 MINUTES.
CALL A PHYSICIAN IF IRRITATION DEVELOPS. DILUTE WITH WATER OR MILK. DO NOT
INDUCE VOMITING. CALL A PHYSICIAN IF NECESSARY.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
USE ANY MEANS SUITABLE FOR EXTINGUISHING SURROUNDING FIRE.
5.2. SPECIFIC HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CONTACT WITH MOST METALS CAUSES FORMATION OF FLAMMABLE AND EXPLOSIVE
HYDROGEN GAS. HOWEVER, THE RISK IS REDUCED DUE TO THE WEAK CONCENTRATION
OF SULFURIC ACID PRESENT.
5.3. SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
USE PROTECTIVE CLOTHING AND BREATHING EQUIPMENT APPROPRIATE FOR THE
SURROUNDING FIRE.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
WEAR APPROPRIATE PPE FOR THE SIZE AND NATURE OF THE SPILL. AS A GENERAL
RULE, WEAR SAFETY GLASSES AND GLOVES.
6.2. CLEANUP AND CONTAINMENT METHODS AND MATERIALS:
COVER THE SPILL WITH SODIUM CARBONATE OR A SODA ASH-SLAKED LIME MIXTURE
(50:50). MIX AND ADD WATER TO FORM SLURRY. DECANT THE LIQUID TO THE DRAIN
WITH EXCESS WATER. TREAT THE SOLID RESIDUE AS NORMAL REFUSE. WASH SITE
WITH SODA ASH SOLUTION. ALWAYS DISPOSE OF IN ACCORDANCE WITH LOCAL
REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING AND STORAGE CONDITIONS:
AS WITH ALL CHEMICALS, WASH HANDS THOROUGHLY AFTER HANDLING. AVOID CONTACT
WITH EYES AND SKIN. PROTECT FROM FREEZING AND PHYSICAL DAMAGE.
| SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION | |
8.1 CONTROL PARAMETERS:
CHEMICAL NAME LIMIT TYPE COUNTRY EXPOSURE LIMIT INFORMATION SOURCE
SULFURIC ACID TWA USA 1 MG/M3 TWA U.S. - OSHA -
(7664-93-9) FINAL PELS -
TIME WEIGHTED
AVERAGES (TWAS)
SULFURIC ACID TLV-TWA USA 0.2 MG/M3 TWA ACGIH - THRESHOLD
(7664-93-9) (THORACIC LIMIT VALUES -
FRACTION) TIME WEIGHTED
AVERAGES (TLV-TWA)
8.2. EXPOSURE CONTROLS:
ENGINEERING CONTROLS:
NO SPECIFIC CONTROLS ARE NEEDED. NORMAL ROOM VENTILATION IS ADEQUATE.
RESPIRATORY PROTECTION: NORMAL ROOM VENTILATION IS ADEQUATE.
SKIN PROTECTION: CHEMICAL RESISTANT GLOVES.
EYE PROTECTION: SAFETY GLASSES OR GOGGLES.
8.3. PERSONAL PROTECTIVE EQUIPMENT:
NORMAL ROOM VENTILATION IS ADEQUATE. CHEMICAL RESISTANT GLOVES. SAFETY
GLASSES OR GOGGLES.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE: COLORLESS TO SLIGHTLY PINK LIQUID
PHYSICAL STATE: LIQUID
ODOR: DATA NOT AVAILABLE.
ODOR THRESHOLD: DATA NOT AVAILABLE.
PH: DATA NOT AVAILABLE.
MELTING/FREEZING POINT: 0.0 DEG. C
FLASH POINT: DATA NOT AVAILABLE.
INITIAL BOILING POINT/RANGE: 100 DEG. C - 100 DEG. C
EVAPORATION RATE: DATA NOT AVAILABLE.
FLAMMABILITY: DATA NOT AVAILABLE.
FLAMMABILITY/EXPLOSIVE LIMITS: DATA NOT AVAILABLE.
VAPOR PRESSURE: DATA NOT AVAILABLE.
VAPOR DENSITY: DATA NOT AVAILABLE.
RELATIVE DENSITY: 1.0
SOLUBILITY: MISCIBLE
PARTITION COEFFICIENT: DATA NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: DATA NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: DATA NOT AVAILABLE.
VISCOSITY: DATA NOT AVAILABLE.
EXPLOSIVE PROPERTIES: DATA NOT AVAILABLE.
OXIDIZING PROPERTIES: DATA NOT AVAILABLE.
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY AND CHEMICAL STABILITY:
STABLE UNDER NORMAL CONDITIONS OF USE AND STORAGE. REFRIGERATION WILL HELP
IN THE STABILITY OF THIS PRODUCT. REFRIGERATION MAY PRODUCE EDTA CRYSTALS
BUT THIS DOES NOT AFFECT PRODUCT QUALITY.
10.2. POSSIBILITY OF HAZARDOUS REACTIONS: DATA NOT AVAILABLE.
10.3. CONDITIONS TO AVOID AND INCOMPATIBLE MATERIALS:
ORGANICS, CHLORATES, CARBIDES, FULMINATES, PICRATES, ALKALINES, REDUCING
AGENTS, NITRATES, ACETIC ACID, OXIDIZING AGENTS, METALS.
10.4. HAZARDOUS DECOMPOSITION PRODUCTS: WILL NOT OCCUR.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY - ORAL EXPOSURE: NOT APPLICABLE.
ACUTE TOXICITY - DERMAL EXPOSURE: NOT APPLICABLE.
ACUTE TOXICITY - INHALATION EXPOSURE: NOT APPLICABLE.
ACUTE TOXICITY - OTHER INFORMATION:
LD50, ORAL, RAT:
2140 MG/KG (SULFURIC ACID), 2000 MG/KG (EDTA DISODIUM ANHYDROUS),
DETAILS OF TOXIC EFFECTS NOT REPORTED OTHER THAN LETHAL DOSE VALUE.
LC50, INHALATION, RAT (SULFURIC ACID): 510 MG/M3/2H, NO TOXIC EFFECT NOTED.
SKIN CORROSION AND IRRITATION: NOT APPLICABLE.
SERIOUS EYE DAMAGE AND IRRITATION: NOT APPLICABLE.
RESPIRATORY SENSITIZATION: NOT APPLICABLE.
SKIN SENSITIZATION: NOT APPLICABLE.
GERM CELL MUTAGENICITY: NOT APPLICABLE.
CARCINOGENICITY: NOT APPLICABLE.
REPRODUCTIVE TOXICITY: NOT APPLICABLE.
SPECIFIC TARGET ORGAN TOXICITY FROM SINGLE EXPOSURE: NOT APPLICABLE.
SPECIFIC TARGET ORGAN TOXICITY FROM REPEATED EXPOSURE: NOT APPLICABLE.
ASPIRATION HAZARD: NOT APPLICABLE.
ADDITIONAL TOXICOLOGY INFORMATION: DATA NOT AVAILABLE.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. ECOTOXICITY:
HARMFUL TO AQUATIC LIFE. AVOID RELEASE TO THE ENVIRONMENT. DISPOSE OF
CONTENTS IN ACCORDANCE WITH LOCAL, STATE, FEDERAL AND INTERNATIONAL
REGULATIONS.
12.2. PERSISTENCE AND DEGRADABILITY: DATA NOT AVAILABLE.
12.3. BIOACCUMULATIVE POTENTIAL: DATA NOT AVAILABLE.
12.4. MOBILITY IN SOIL: DATA NOT AVAILABLE.
12.5. OTHER ADVERSE ECOLOGICAL EFFECTS: DATA NOT AVAILABLE.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS: DATA NOT AVAILABLE.
| SECTION 14: TRANSPORTATION INFORMATION | |
14.1. TRANSPORTATION BY LAND-DEPARTMENT OF TRANSPORTATION (DOT, UNITED
STATES OF AMERICA): NOT REGULATED ACCORDING TO DOT REGULATIONS.
14.2. TRANSPORTATION BY AIR - INTERNATIONAL AIR TRANSPORT ASSOCIATION
(IATA): NOT REGULATED ACCORDING TO IATA DANGEROUS GOODS REGULATIONS.
14.3 TRANSPORTATION OF DANGEROUS GOODS (TDG, CANADA):
NOT REGULATED ACCORDING TO TDG REGULATIONS.
| SECTION 15: REGULATORY INFORMATION | |
15.1. OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA) HAZARDS:
NOT LISTED.
SULFURIC ACID (CAS # 7664-93-9): 1000 LB EPCRA RQ
SULFURIC ACID (CAS # 7664-93-9): 1000 LB TPQ
15.2. SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) 302 EXTREMELY
HAZARDOUS SUBSTANCES:
SULFURIC ACID (CAS # 7664-93-9):
1000 LB FINAL RQ
454 KG FINAL RQ
15.3. SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) 311/312 HAZARDOUS
CHEMICALS:
SULFURIC ACID (CAS # 7664-93-9):
1.0% DE MINIMIS CONCENTRATION (ACID AEROSOLS INCLUDING MISTS, VAPORS,
GAS, FOG, AND OTHER AIRBORNE FORMS OF ANY PARTICLE SIZE)
15.4. SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) 313 TOXIC RELEASE
INVENTORY (TRI):
SULFURIC ACID (CAS # 7664-93-9): EXTRAORDINARILY HAZARDOUS
15.5. MASSACHUSETTS RIGHT-TO-KNOW SUBSTANCE LIST:
SULFURIC ACID (CAS # 7664-93-9): ENVIRONMENTAL HAZARD
SULFURIC ACID (CAS # 7664-93-9): PRESENT
WATER (CAS # 7732-18-5): PRESENT
15.6. PENNSYLVANIA RIGHT-TO-KNOW HAZARDOUS SUBSTANCES:
SULFURIC ACID (CAS # 7664-93-9):
CARCINOGEN; CORROSIVE; REACTIVE - SECOND DEGREE
SULFURIC ACID (CAS # 7664-93-9): SN 1761
SULFURIC ACID (CAS # 7664-93-9): SN 1761 500 LB TPQ
15.7. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW COMPONENTS:
SULFURIC ACID (CAS # 7664-93-9): CARCINOGEN, 3/14/2003
15.8. CALIFORNIA PROPOSITION 65:
ETHYLENEDIAMINETETRAACETIC ACID (EDTA), DISODIUM SALT, DIHYDRATE
(CAS # 6381-92-6): PRESENT (DSL)
SULFURIC ACID (CAS # 7664-93-9): PRESENT (DSL)
WATER (CAS # 7732-18-5): PRESENT (DSL)
15.9. CANADA DOMESTIC SUBSTANCES LIST / NON-DOMESTIC SUBSTANCES LIST
(DSL/NDSL):
ETHYLENEDIAMINETETRAACETIC ACID (EDTA), DISODIUM SALT, DIHYDRATE
(CAS # 6381-92-6): PRESENT
SULFURIC ACID (CAS # 7664-93-9): PRESENT
WATER (CAS # 7732-18-5): PRESENT
15.10. UNITED STATES OF AMERICA TOXIC SUBSTANCES CONTROL ACT (TSCA) LIST:
ALL COMPONENTS OF THIS SOLUTION ARE LISTED AS ACTIVE ON THE TSCA INVENTORY
OR ARE MIXTURES (HYDRATES) OF ACTIVE ITEMS LISTED ON THE TSCA INVENTORY.
N,N-DIETHYL-1,4-PHENYLENEDIAMINE SULFATE (CAS # 6283-63-2): 228-500-6
ETHYLENEDIAMINETETRAACETIC ACID (EDTA), DISODIUM SALT, DIHYDRATE
(CAS # 6381-92-6): 230-944-0
SULFURIC ACID (CAS # 7664-93-9): 231-639-5
SULFURIC ACID (CAS # 7664-93-9): 237-464-0
WATER (CAS # 7732-18-5): 231-791-2
WATER (CAS # 7732-18-5): 232-148-9
15.11. EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES:
(EINECS), EUROPEAN:
LIST OF NOTIFIED CHEMICAL SUBSTANCES (ELINCS), AND NO LONGER POLYMERS
(NLP):
| SECTION 16: OTHER INFORMATION | |
16.1. FULL TEXT OF HAZARD STATEMENTS AND PRECAUTIONARY STATEMENTS:
HARMFUL TO AQUATIC LIFE.
AVOID RELEASE TO THE ENVIRONMENT.
DISPOSE OF CONTENTS IN ACCORDANCE WITH LOCAL, STATE, FEDERAL AND
INTERNATIONAL REGULATIONS.
16.2. MISCELLANEOUS HAZARD CLASSES:
CANADIAN CARCINOGENICITY HAZARD CLASS: NOT APPLICABLE.
PHYSICAL HAZARDS NOT OTHERWISE CLASSIFIED (PHNOC): NOT APPLICABLE.
HEALTH HAZARDS NOT OTHERWISE CLASSIFIED (HHNOC): NOT APPLICABLE.
BIOHAZARDOUS INFECTIOUS MATERIALS HAZARD CLASS: NOT APPLICABLE.
16.3. NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) RATING:
HEALTH 1
FLAMMABILITY 0
REACTIVITY 0
SPECIAL HAZARD
16.4. DOCUMENT REVISION:
LAST REVISION DATE: 2021-10-06
DISCLAIMER:
WHEN HANDLED PROPERLY BY QUALIFIED PERSONNEL, THE PRODUCT DESCRIBED HEREIN
DOES NOT PRESENT A SIGNIFICANT HEALTH OR SAFETY HAZARD. ALTERATION OF ITS
CHARACTERISTICS BY CONCENTRATION, EVAPORATION, ADDITION OF OTHER
SUBSTANCES, OR OTHER MEANS MAY PRESENT HAZARDS NOT SPECIFICALLY ADDRESSED
HEREIN AND WHICH MUST BE EVALUATED BY THE USER. THE INFORMATION FURNISHED
HEREIN IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST DATA CURRENTLY
AVAILABLE TO US. NO WARRANTY, EXPRESSED OR IMPLIED, IS MADE AND RICCA
CHEMICAL COMPANY ASSUMES NO LEGAL RESPONSIBILITY OR LIABILITY WHATSOEVER
RESULTING FROM ITS USE.