| Common Name: | COPPER SULFATE SOLUTION, FOR ALUMINUM CAN COATING TEST |
| Manufacturer: | RICCA CHEMICAL |
| SDS Revision Date: | 10/6/2021 |
| SDS Format: | No Format Specified |
| Item Number(s): | 45E435 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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R
RICCA CHEMICAL COMPANY(R*)
SAFETY DATA SHEET
CLASSIFIED ACCORDING TO OSHA HAZARD COMMUNICATION STANDARD (HCS)
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
TRADE NAME OR DESIGNATION:
COPPER SULFATE SOLUTION, FOR ALUMINUM CAN COATING TEST
PRODUCT NUMBER: 2326
OTHER IDENTIFYING PRODUCT NUMBERS: 2326-1, 2326-32
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE: GENERAL LABORATORY REAGENT
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
COMPANY: RICCA CHEMICAL COMPANY
ADDRESS:
448 WEST FORK DRIVE
ARLINGTON, TX 76012
USA
TELEPHONE: 888-467-4222
1.4. EMERGENCY TELEPHONE NUMBER (24 HOURS):
CHEMTREC (USA): 800-424-9300
CHEMTREC (INTERNATIONAL): 1+703-527-3887
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FOR THE FULL TEXT OF THE HAZARD AND PRECAUTIONARY STATEMENTS LISTED BELOW,
SEE SECTION 16.
HAZARD CLASS CATEGORY HAZARD STATEMENTS PRECAUTIONARY STATEMENTS
ACUTE TOXICITY - CATEGORY 4 H302 P264, P270, P301+P312,
ORAL P330, P501
ACUTE TOXICITY - CATEGORY 4 H312 P280, P302+P352, P312,
DERMAL P321, P362, P501
ACUTE TOXICITY - CATEGORY 4 H332 P261, P271, P304+P340,
INHALATION P312
SKIN CORROSION / CATEGORY 1A H314 P260, P264, P280,
IRRITATION P301+P330+P331,
P303+P361+P353, P363,
P304+P340, P310, P321,
P305+P351+P338, P405,
P501
EYE DAMAGE / CATEGORY 1 H318 P280, P305+P351+P338,
IRRITATION P310
RESPIRATORY CATEGORY 1 H334 P261, P285, P304+P341,
SENSITIZER P342+P311, P501
SKIN SENSITIZER CATEGORY 1 H317 P261, P272, P280,
P302+P352, P332+P313,
P321, P363, P501
GERM CELL CATEGORY 2 H341 P201, P202, P280,
MUTAGENICITY P308+P313, P405, P501
REPRODUCTIVE CATEGORY 2 H361 P201, P202, P280,
TOXICITY P308+P313, P405, P501
SPECIFIC TARGET CATEGORY 1 H370 P260, P264, P270,
ORGANS/SYSTEMIC P307+P311, P321, P405,
TOXICITY P501
FOLLOWING SINGLE
EXPOSURE
SPECIFIC TARGET CATEGORY 1 H372 P260, P264, P270, P314,
ORGANS/SYSTEMIC P501
TOXICITY
FOLLOWING
REPEATED
EXPOSURE
CORROSIVE TO CATEGORY 1 H290 P234, P390, P406
METALS
HAZARDOUS TO THE CATEGORY 1 H400 P273, P391, P501
AQUATIC
ENVIRONMENT
(ACUTE)
HAZARDOUS TO THE CATEGORY 2 H411 P273, P391, P501
AQUATIC
ENVIRONMENT
(CHRONIC)
2.2. GHS LABEL ELEMENTS:
PICTOGRAMS:
HEALTH HAZARD
EXCLAMATION MARK
CORROSION
ENVIRONMENT
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
HAZARD NUMBER HAZARD STATEMENT
H290 MAY BE CORROSIVE TO METALS.
H302 HARMFUL IF SWALLOWED.
H312 HARMFUL IN CONTACT WITH SKIN.
H314 CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
H317 MAY CAUSE AN ALLERGIC SKIN REACTION.
H318 CAUSES SERIOUS EYE DAMAGE.
H332 HARMFUL IF INHALED.
H334 MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING
DIFFICULTIES IF INHALED.
H341 SUSPECTED OF CAUSING GENETIC DEFECTS.
H361 SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
H370 CAUSES DAMAGE TO ORGANS.
H372 CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED
EXPOSURE.
H400 VERY TOXIC TO AQUATIC LIFE.
H411 TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENTS:
PRECAUTIONARY NUMBER PRECAUTIONARY STATEMENT
P201 OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202 DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE
BEEN READ AND UNDERSTOOD.
P234 KEEP ONLY IN ORIGINAL CONTAINER.
P260 DO NOT BREATHE FUMES, MIST, VAPORS, OR SPRAY.
P261 AVOID BREATHING FUMES, MIST, VAPORS, OR SPRAY.
P264 WASH ARMS, HANDS AND FACE THOROUGHLY AFTER
HANDLING.
P270 DO NOT EAT, DRINK OR SMOKE WHEN USING THIS
PRODUCT.
P271 USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P272 CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED
OUT OF THE WORKPLACE.
P273 AVOID RELEASE TO THE ENVIRONMENT.
P280 WEAR PROTECTIVE GLOVES AND EYE PROTECTION.
P285 IN CASE OF INADEQUATE VENTILATION WEAR
RESPIRATORY PROTECTION.
P301+P312 IF SWALLOWED:
CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL
UNWELL.
P301+P330+P331 IF SWALLOWED:
RINSE MOUTH. DO NOT INDUCE VOMITING.
P302+P352 IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P303+P361+P353 IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
RINSE SKIN WITH WATER.
P304+P340 IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE
FOR BREATHING.
P304+P341 IF INHALED:
IF BREATHING IS DIFFICULT, REMOVE PERSON TO
FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
P305+P351+P338 IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES.
REMOVE CONTACT LENSES, IF PRESENT AND EASY TO
DO. CONTINUE RINSING.
P307+P311 IF EXPOSED: CALL A POISON CENTER OR PHYSICIAN.
P308+P313 IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
P310 IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN.
P312 CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL
UNWELL.
P314 GET MEDICAL ATTENTION IF YOU FEEL UNWELL.
P321 SPECIFIC TREATMENT (WASH AREAS OF CONTACT WITH
WATER).
P330 RINSE MOUTH.
P332+P313 IF SKIN IRRITATION OCCURS:
GET MEDICAL ATTENTION.
P342+P311 IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR PHYSICIAN.
P362 TAKE OFF CONTAMINATED CLOTHING AND WASH IT
BEFORE REUSE.
P363 WASH CONTAMINATED CLOTHING BEFORE REUSE.
P390 ABSORB SPILLAGE TO PREVENT MATERIAL DAMAGE.
P391 COLLECT SPILLAGE.
P405 STORE LOCKED UP.
P406 STORE IN CORROSIVE RESISTANT CONTAINER WITH A
RESISTANT INNER LINER.
P501 DISPOSE OF CONTENTS IN ACCORDANCE WITH LOCAL,
STATE, FEDERAL AND INTERNATIONAL REGULATIONS.
2.4. HAZARDS NOT OTHERWISE CLASSIFIED OR COVERED BY GHS:
DATA NOT AVAILABLE.
| SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS | |
3.1. COMPONENTS OF SUBSTANCE OR MIXTURE:
CHEMICAL NAME FORMULA MOLECULAR WEIGHT CAS NUMBER WEIGHT%
WATER H2O 18.01 G/MOL 7732-18-5 74.99
COPPER SULFATE CuSO4x5H2O 249.68 G/MOL 7758-99-8 21.00
PENTAHYDRATE
HYDROCHLORIC ACID HCl 36.46 G/MOL 7647-01-0 4.01
| SECTION 4: FIRST-AID MEASURES | |
4.1. GENERAL FIRST AID INFORMATION:
EYE CONTACT:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING. MAY CAUSE IRRITATION, REDNESS,
PAIN, AND TEARING.
INHALATION:
IF INHALED:
IF BREATHING IS DIFFICULT, REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE
FOR BREATHING.
SKIN CONTACT:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER. MAY
CAUSE IRRITATION, REDNESS, AND PAIN.
INGESTION:
IF SWALLOWED:
RINSE MOUTH. DO NOT INDUCE VOMITING. DILUTE WITH WATER OR MILK. DO NOT
INDUCE VOMITING. CALL A PHYSICIAN IF NECESSARY.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, ACUTE AND DELAYED:
HARMFUL IF SWALLOWED. HARMFUL IN CONTACT WITH SKIN. CAUSES SEVERE SKIN
BURNS AND EYE DAMAGE. MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES SERIOUS
EYE DAMAGE. HARMFUL IF INHALED. MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR
BREATHING DIFFICULTIES IF INHALED. SUSPECTED OF CAUSING GENETIC DEFECTS.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD. CAUSES DAMAGE TO
ORGANS. CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
MILDLY CORROSIVE, NON-FLAMMABLE. WASH AREAS OF CONTACT WITH WATER FOR AT
LEAST 15 MINUTES. AVOID INGESTION OR CONTACT WITH SKIN, EYES, OR CLOTHING.
IF INGESTED, DILUTE WITH LARGE QUANTITY OF WATER AND CALL A PHYSICIAN. DO
NOT INDUCE VOMITING.
EYE CONTACT: MAY CAUSE IRRITATION, REDNESS, PAIN, AND TEARING.
SKIN CONTACT: MAY CAUSE IRRITATION, REDNESS, AND PAIN.
CHRONIC EFFECTS / CARCINOGENICITY:
PROLONGED OR REPEATED EXPOSURE MAY CAUSE DERMATITIS.
4.3. MEDICAL ATTENTION OR SPECIAL TREATMENT NEEDED:
IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. SPECIFIC TREATMENT (WASH
AREAS OF CONTACT WITH WATER). IRRIGATE IMMEDIATELY WITH LARGE QUANTITY OF
WATER FOR AT LEAST 15 MINUTES. CALL A PHYSICIAN IF IRRITATION DEVELOPS.
REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF NECESSARY. IF BREATHING
IS DIFFICULT, GIVE OXYGEN. WASH AREAS OF CONTACT WITH SOAP AND WATER FOR AT
LEAST 15 MINUTES. CALL A PHYSICIAN IF IRRITATION DEVELOPS. DILUTE WITH
WATER OR MILK. DO NOT INDUCE VOMITING. CALL A PHYSICIAN IF NECESSARY.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
USE ANY MEANS SUITABLE FOR EXTINGUISHING SURROUNDING FIRE (WATER OR WATER
SPRAY). NEUTRALIZE WITH SODA ASH OR SLAKED LIME.
5.2. SPECIFIC HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NOT CONSIDERED TO BE A FIRE OR EXPLOSION HAZARD. MAY REACT WITH METALS TO
RELEASE FLAMMABLE HYDROGEN GAS.
5.3. SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
USE PROTECTIVE CLOTHING AND BREATHING EQUIPMENT APPROPRIATE FOR THE
SURROUNDING FIRE.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
WEAR PROTECTIVE GLOVES AND EYE PROTECTION. IN CASE OF INADEQUATE
VENTILATION WEAR RESPIRATORY PROTECTION.
6.2. CLEANUP AND CONTAINMENT METHODS AND MATERIALS:
ABSORB WITH SUITABLE INERT MATERIAL (VERMICULITE, DRY SAND, ETC) AND PLACE
IN A CHEMICAL WASTE CONTAINER FOR PROPER DISPOSAL. DO NOT FLUSH TO SEWER.
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING AND STORAGE CONDITIONS:
STORE IN CORROSIVE RESISTANT CONTAINER WITH A RESISTANT INNER LINER. AS
WITH ALL CHEMICALS, WASH HANDS THOROUGHLY AFTER HANDLING. AVOID CONTACT
WITH EYES AND SKIN. PROTECT FROM FREEZING AND PHYSICAL DAMAGE.
| SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION | |
8.1 CONTROL PARAMETERS:
CHEMICAL NAME LIMIT TYPE COUNTRY EXPOSURE LIMIT INFORMATION SOURCE
HYDROCHLORIC ACID TLV-CEILING USA 2 PPM CEILING ACGIH - THRESHOLD
(7647-01-0) LIMIT VALUES -
CEILINGS (TLV-C)
HYDROCHLORIC ACID PEL-CEILING USA 5 PPM CEILING U.S. - OSHA -
(7647-01-0) FINAL PELS -
7 MG/M3 CEILING LIMITS
CEILING
COPPER SULFATE TLV-TWA USA 1 MG/M3 TWA ACGIH - THRESHOLD
PENTAHYDRATE (DUST AND LIMIT VALUES -
(7758-99-8) MIST, AS Cu) TIME WEIGHTED
AVERAGES (TLV-TWA)
8.2. EXPOSURE CONTROLS:
ENGINEERING CONTROLS:
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. NO SPECIFIC CONTROLS ARE
NEEDED. NORMAL ROOM VENTILATION IS ADEQUATE.
RESPIRATORY PROTECTION:
IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION. NORMAL ROOM
VENTILATION IS ADEQUATE.
SKIN PROTECTION:
WEAR PROTECTIVE GLOVES AND EYE PROTECTION. CHEMICAL RESISTANT GLOVES.
EYE PROTECTION:
WEAR PROTECTIVE GLOVES AND EYE PROTECTION. SAFETY GLASSES OR GOGGLES.
8.3. PERSONAL PROTECTIVE EQUIPMENT:
WEAR PROTECTIVE GLOVES AND EYE PROTECTION. IN CASE OF INADEQUATE
VENTILATION WEAR RESPIRATORY PROTECTION. NORMAL ROOM VENTILATION IS
ADEQUATE. CHEMICAL RESISTANT GLOVES. SAFETY GLASSES OR GOGGLES.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE: BLUE LIQUID
PHYSICAL STATE: LIQUID
ODOR: DATA NOT AVAILABLE.
ODOR THRESHOLD: DATA NOT AVAILABLE.
PH: 1.98 - 2.16
MELTING/FREEZING POINT: DATA NOT AVAILABLE.
INITIAL BOILING POINT/RANGE:
APPROXIMATELY 100 DEG. C - APPROXIMATELY 100 DEG. C
FLASH POINT: DATA NOT AVAILABLE.
EVAPORATION RATE: DATA NOT AVAILABLE.
FLAMMABILITY: DATA NOT AVAILABLE.
FLAMMABILITY/EXPLOSIVE LIMITS: DATA NOT AVAILABLE.
VAPOR PRESSURE: DATA NOT AVAILABLE.
VAPOR DENSITY: DATA NOT AVAILABLE.
RELATIVE DENSITY: 1.1
SOLUBILITY: MISCIBLE
PARTITION COEFFICIENT: DATA NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: DATA NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: DATA NOT AVAILABLE.
VISCOSITY: DATA NOT AVAILABLE.
EXPLOSIVE PROPERTIES: DATA NOT AVAILABLE.
OXIDIZING PROPERTIES: DATA NOT AVAILABLE.
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY AND CHEMICAL STABILITY:
STABLE UNDER NORMAL CONDITIONS OF USE AND STORAGE.
10.2. POSSIBILITY OF HAZARDOUS REACTIONS: DATA NOT AVAILABLE.
10.3. CONDITIONS TO AVOID AND INCOMPATIBLE MATERIALS:
KEEP ONLY IN ORIGINAL CONTAINER. MOST METALS, ALKALIS, ACTIVE METALS,
CYANIDES, SULFIDES, SULFITES, METAL OXIDES, FORMALDEHYDE, HYDROXYLAMINE.
10.4. HAZARDOUS DECOMPOSITION PRODUCTS: WILL NOT OCCUR.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY - ORAL EXPOSURE:
HARMFUL IF SWALLOWED. WASH ARMS, HANDS AND FACE THOROUGHLY AFTER HANDLING.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
IF SWALLOWED:
CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL. RINSE MOUTH. DISPOSE
OF CONTENTS IN ACCORDANCE WITH LOCAL, STATE, FEDERAL AND INTERNATIONAL
REGULATIONS.
ACUTE TOXICITY - DERMAL EXPOSURE:
HARMFUL IN CONTACT WITH SKIN. WEAR PROTECTIVE GLOVES AND EYE PROTECTION.
IF ON SKIN:
WASH WITH PLENTY OF SOAP AND WATER. CALL A POISON CENTER OR PHYSICIAN IF
YOU FEEL UNWELL. SPECIFIC TREATMENT (WASH AREAS OF CONTACT WITH WATER).
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE. DISPOSE OF
CONTENTS IN ACCORDANCE WITH LOCAL, STATE, FEDERAL AND INTERNATIONAL
REGULATIONS.
ACUTE TOXICITY - INHALATION EXPOSURE:
HARMFUL IF INHALED. AVOID BREATHING FUMES, MIST, VAPORS, OR SPRAY. USE ONLY
OUTDOORS OR IN A WELL-VENTILATED AREA.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
ACUTE TOXICITY - OTHER INFORMATION:
LD50, ORAL, RABBIT: (HYDROCHLORIC ACID) 900 MG/KG
LD50, ORAL, RAT:
(COPPER SULFATE) 300 MG/KG, DETAILS OF TOXIC EFFECTS NOT REPORTED OTHER
THAN LETHAL DOSE VALUE.
LCLO, INHALATION, HUMAN:
(HYDROCHLORIC ACID) 3000 PPM/5 MINUTES: NO TOXIC EFFECTS NOTED.
SKIN CORROSION AND IRRITATION:
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE. DO NOT BREATHE FUMES, MIST,
VAPORS, OR SPRAY. WASH ARMS, HANDS AND FACE THOROUGHLY AFTER HANDLING. WEAR
PROTECTIVE GLOVES AND EYE PROTECTION.
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER. WASH
CONTAMINATED CLOTHING BEFORE REUSE.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. IMMEDIATELY
CALL A POISON CENTER OR PHYSICIAN. SPECIFIC TREATMENT (WASH AREAS OF
CONTACT WITH WATER).
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING. STORE LOCKED UP. DISPOSE OF
CONTENTS IN ACCORDANCE WITH LOCAL, STATE, FEDERAL AND INTERNATIONAL
REGULATIONS.
SERIOUS EYE DAMAGE AND IRRITATION:
CAUSES SERIOUS EYE DAMAGE. WEAR PROTECTIVE GLOVES AND EYE PROTECTION.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON CENTER
OR PHYSICIAN.
RESPIRATORY SENSITIZATION:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
AVOID BREATHING FUMES, MIST, VAPORS, OR SPRAY. IN CASE OF INADEQUATE
VENTILATION WEAR RESPIRATORY PROTECTION.
IF INHALED:
IF BREATHING IS DIFFICULT, REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE
FOR BREATHING. IF EXPERIENCING RESPIRATORY SYMPTOMS: CALL A POISON CENTER
OR PHYSICIAN. DISPOSE OF CONTENTS IN ACCORDANCE WITH LOCAL, STATE, FEDERAL
AND INTERNATIONAL REGULATIONS.
SKIN SENSITIZATION:
MAY CAUSE AN ALLERGIC SKIN REACTION. AVOID BREATHING FUMES, MIST, VAPORS,
OR SPRAY. CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE
WORKPLACE. WEAR PROTECTIVE GLOVES AND EYE PROTECTION.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OCCURS:
GET MEDICAL ATTENTION. SPECIFIC TREATMENT (WASH AREAS OF CONTACT WITH
WATER). WASH CONTAMINATED CLOTHING BEFORE REUSE. DISPOSE OF CONTENTS IN
ACCORDANCE WITH LOCAL, STATE, FEDERAL AND INTERNATIONAL REGULATIONS.
GERM CELL MUTAGENICITY:
SUSPECTED OF CAUSING GENETIC DEFECTS. OBTAIN SPECIAL INSTRUCTIONS BEFORE
USE. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND
UNDERSTOOD. WEAR PROTECTIVE GLOVES AND EYE PROTECTION.
IF EXPOSED OR CONCERNED:
GET MEDICAL ATTENTION. STORE LOCKED UP. DISPOSE OF CONTENTS IN ACCORDANCE
WITH LOCAL, STATE, FEDERAL AND INTERNATIONAL REGULATIONS.
CARCINOGENICITY: NOT APPLICABLE.
REPRODUCTIVE TOXICITY:
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD. OBTAIN SPECIAL
INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE
BEEN READ AND UNDERSTOOD. WEAR PROTECTIVE GLOVES AND EYE PROTECTION.
IF EXPOSED OR CONCERNED:
GET MEDICAL ATTENTION. STORE LOCKED UP. DISPOSE OF CONTENTS IN ACCORDANCE
WITH LOCAL, STATE, FEDERAL AND INTERNATIONAL REGULATIONS.
SPECIFIC TARGET ORGAN TOXICITY FROM SINGLE EXPOSURE:
CAUSES DAMAGE TO ORGANS. DO NOT BREATHE FUMES, MIST, VAPORS, OR SPRAY. WASH
ARMS, HANDS AND FACE THOROUGHLY AFTER HANDLING. DO NOT EAT, DRINK OR SMOKE
WHEN USING THIS PRODUCT.
IF EXPOSED:
CALL A POISON CENTER OR PHYSICIAN. SPECIFIC TREATMENT (WASH AREAS OF
CONTACT WITH WATER). STORE LOCKED UP. DISPOSE OF CONTENTS IN ACCORDANCE
WITH LOCAL, STATE, FEDERAL AND INTERNATIONAL REGULATIONS.
SPECIFIC TARGET ORGAN TOXICITY FROM REPEATED EXPOSURE:
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. DO NOT
BREATHE FUMES, MIST, VAPORS, OR SPRAY. WASH ARMS, HANDS AND FACE THOROUGHLY
AFTER HANDLING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. GET
MEDICAL ATTENTION IF YOU FEEL UNWELL. DISPOSE OF CONTENTS IN ACCORDANCE
WITH LOCAL, STATE, FEDERAL AND INTERNATIONAL REGULATIONS.
ASPIRATION HAZARD: NOT APPLICABLE.
ADDITIONAL TOXICOLOGY INFORMATION: DATA NOT AVAILABLE.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. ECOTOXICITY:
VERY TOXIC TO AQUATIC LIFE. AVOID RELEASE TO THE ENVIRONMENT. COLLECT
SPILLAGE. DISPOSE OF CONTENTS IN ACCORDANCE WITH LOCAL, STATE, FEDERAL AND
INTERNATIONAL REGULATIONS. TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
AVOID RELEASE TO THE ENVIRONMENT. COLLECT SPILLAGE. DISPOSE OF CONTENTS IN
ACCORDANCE WITH LOCAL, STATE, FEDERAL AND INTERNATIONAL REGULATIONS.
12.2. PERSISTENCE AND DEGRADABILITY: DATA NOT AVAILABLE.
12.3. BIOACCUMULATIVE POTENTIAL: DATA NOT AVAILABLE.
12.4. MOBILITY IN SOIL: DATA NOT AVAILABLE.
12.5. OTHER ADVERSE ECOLOGICAL EFFECTS: DATA NOT AVAILABLE.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS: DATA NOT AVAILABLE.
| SECTION 14: TRANSPORTATION INFORMATION | |
14.1. TRANSPORTATION BY LAND-DEPARTMENT OF TRANSPORTATION (DOT, UNITED
STATES OF AMERICA):
SIZES: 1 L, 4 L
UN NUMBER: UN3264
PROPER SHIPPING NAME:
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (HYDROCHLORIC ACID)
HAZARD CLASS: 8
PACKING GROUP: III
HAZARD LABEL(S): CORROSIVE, CLASS/DIVISION 8
14.2. TRANSPORTATION BY AIR - INTERNATIONAL AIR TRANSPORT ASSOCIATION
(IATA):
SIZES: 1 L, 4 L
UN NUMBER: UN3264
PROPER SHIPPING NAME:
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (HYDROCHLORIC ACID)
HAZARD CLASS: 8
PACKING GROUP: III
HAZARD LABEL(S): CORROSIVE, CLASS/DIVISION 8
14.3 TRANSPORTATION OF DANGEROUS GOODS (TDG, CANADA):
SIZES: 1 L, 4 L
UN NUMBER: UN3264
PROPER SHIPPING NAME:
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (HYDROCHLORIC ACID)
HAZARD CLASS: 8
PACKING GROUP: III
HAZARD LABEL(S): CLASS 8, CORROSIVES
| SECTION 15: REGULATORY INFORMATION | |
15.1. OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA) HAZARDS:
NOT LISTED.
15.2. SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) 302 EXTREMELY
HAZARDOUS SUBSTANCES:
HYDROCHLORIC ACID (CAS # 7647-01-0): 500 LB TPQ (GAS ONLY)
HYDROCHLORIC ACID (CAS # 7647-01-0): 5000 LB EPCRA RQ (GAS ONLY)
15.3. SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) 311/312 HAZARDOUS
CHEMICALS:
HYDROCHLORIC ACID (CAS # 7647-01-0):
5000 LB FINAL RQ
2270 KG FINAL RQ
COPPER SULFATE PENTAHYDRATE (CAS # 7758-99-8):
10 LB FINAL RQ
4.54 KG FINAL RQ
15.4. SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) 313 TOXIC RELEASE
INVENTORY (TRI):
HYDROCHLORIC ACID (CAS # 7647-01-0):
1.0 % DE MINIMIS CONCENTRATION (ACID AEROSOLS INCLUDING MISTS, VAPORS, GAS,
FOG, AND OTHER AIRBORNE FORMS OF ANY PARTICLE SIZE)
COPPER SULFATE PENTAHYDRATE (CAS # 7758-99-8):
1.0 % DE MINIMIS CONCENTRATION (THIS CATEGORY DOES NOT INCLUDE CAS NUMBERS
147-14-8, 1328-53-6, OR 14302-13-7, OR COPPER PHTHALOCYANINE COMPOUNDS THAT
ARE SUBSTITUTED WITH ONLY HYDROGEN AND/OR CHLORINE AND/OR BROMINE., LISTED
UNDER CHEMICAL CATEGORY N100)
15.5. MASSACHUSETTS RIGHT-TO-KNOW SUBSTANCE LIST:
HYDROCHLORIC ACID (CAS # 7647-01-0): EXTRAORDINARILY HAZARDOUS
COPPER SULFATE PENTAHYDRATE (CAS # 7758-99-8): PRESENT
15.6. PENNSYLVANIA RIGHT-TO-KNOW HAZARDOUS SUBSTANCES:
HYDROCHLORIC ACID (CAS # 7647-01-0): ENVIRONMENTAL HAZARD
HYDROCHLORIC ACID (CAS # 7647-01-0): PRESENT
WATER (CAS # 7732-18-5): PRESENT
COPPER SULFATE PENTAHYDRATE (CAS # 7758-99-8): ENVIRONMENTAL HAZARD
COPPER SULFATE PENTAHYDRATE (CAS # 7758-99-8): PRESENT
15.7. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW COMPONENTS:
HYDROCHLORIC ACID (CAS # 7647-01-0): CORROSIVE
HYDROCHLORIC ACID (CAS # 7647-01-0): SN 1012
HYDROCHLORIC ACID (CAS # 7647-01-0):
SN 1012 500 LB TPQ (>=37% CONCENTRATION); SN 2909 500 LB TPQ (HYDROGEN
CHLORIDE GAS ONLY)
COPPER SULFATE PENTAHYDRATE (CAS # 7758-99-8): SN 0549
COPPER SULFATE PENTAHYDRATE (CAS # 7758-99-8): SN 2215
COPPER SULFATE PENTAHYDRATE (CAS # 7758-99-8):
SN 2215 500 LB TPQ (EXCEPT C.I. PIGMENT BLUE 15, C.I. PIGMENT GREEN 7, AND
C.I. PIGMENT GREEN 36, CATEGORY CODE N100)
15.8. CALIFORNIA PROPOSITION 65: NOT LISTED.
15.9. CANADA DOMESTIC SUBSTANCES LIST / NON-DOMESTIC SUBSTANCES LIST
(DSL/NDSL):
HYDROCHLORIC ACID (CAS # 7647-01-0): PRESENT (DSL)
WATER (CAS # 7732-18-5): PRESENT (DSL)
COPPER SULFATE PENTAHYDRATE (CAS # 7758-99-8): PRESENT (DSL)
15.10. UNITED STATES OF AMERICA TOXIC SUBSTANCES CONTROL ACT (TSCA) LIST:
ALL COMPONENTS OF THIS SOLUTION ARE LISTED AS ACTIVE ON THE TSCA INVENTORY
OR ARE MIXTURES (HYDRATES) OF ACTIVE ITEMS LISTED ON THE TSCA INVENTORY.
HYDROCHLORIC ACID (CAS # 7647-01-0): PRESENT [T]
WATER (CAS # 7732-18-5): PRESENT
COPPER SULFATE PENTAHYDRATE (CAS # 7758-99-8): PRESENT
15.11. EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES
(EINECS), EUROPEAN:
LIST OF NOTIFIED CHEMICAL SUBSTANCES (ELINCS), AND NO LONGER POLYMERS
(NLP):
HYDROCHLORIC ACID (CAS # 7647-01-0): 231-595-7
HYDROCHLORIC ACID (CAS # 7647-01-0): 231-715-8
WATER (CAS # 7732-18-5): 231-791-2
WATER (CAS # 7732-18-5): 232-148-9
COPPER SULFATE PENTAHYDRATE (CAS # 7758-99-8): 231-847-6
| SECTION 16: OTHER INFORMATION | |
16.1. FULL TEXT OF HAZARD STATEMENTS AND PRECAUTIONARY STATEMENTS:
MAY BE CORROSIVE TO METALS. HARMFUL IF SWALLOWED. HARMFUL IN CONTACT WITH
SKIN. CAUSES SEVERE SKIN BURNS AND EYE DAMAGE. MAY CAUSE AN ALLERGIC SKIN
REACTION. CAUSES SERIOUS EYE DAMAGE. HARMFUL IF INHALED. MAY CAUSE ALLERGY
OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED. SUSPECTED OF
CAUSING GENETIC DEFECTS. SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN
CHILD. CAUSES DAMAGE TO ORGANS. CAUSES DAMAGE TO ORGANS THROUGH PROLONGED
OR REPEATED EXPOSURE. VERY TOXIC TO AQUATIC LIFE.
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. KEEP ONLY IN ORIGINAL
CONTAINER. DO NOT BREATHE FUMES, MIST, VAPORS, OR SPRAY. WASH ARMS, HANDS
AND FACE THOROUGHLY AFTER HANDLING. DO NOT EAT, DRINK OR SMOKE WHEN USING
THIS PRODUCT. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. CONTAMINATED
WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE. AVOID RELEASE TO
THE ENVIRONMENT. WEAR PROTECTIVE GLOVES AND EYE PROTECTION. IN CASE OF
INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
IF SWALLOWED: CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EXPOSED:
CALL A POISON CENTER OR PHYSICIAN. GET MEDICAL ATTENTION IF YOU FEEL
UNWELL. SPECIFIC TREATMENT (WASH AREAS OF CONTACT WITH WATER).
IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION.
IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR PHYSICIAN. TAKE OFF CONTAMINATED CLOTHING AND WASH
IT BEFORE REUSE. ABSORB SPILLAGE TO PREVENT MATERIAL DAMAGE. COLLECT
SPILLAGE.
STORE LOCKED UP. STORE IN CORROSIVE RESISTANT CONTAINER WITH A RESISTANT
INNER LINER.
DISPOSE OF CONTENTS IN ACCORDANCE WITH LOCAL, STATE, FEDERAL AND
INTERNATIONAL REGULATIONS.
16.2. MISCELLANEOUS HAZARD CLASSES:
CANADIAN CARCINOGENICITY HAZARD CLASS: NOT APPLICABLE.
PHYSICAL HAZARDS NOT OTHERWISE CLASSIFIED (PHNOC): NOT APPLICABLE.
HEALTH HAZARDS NOT OTHERWISE CLASSIFIED (HHNOC): NOT APPLICABLE.
BIOHAZARDOUS INFECTIOUS MATERIALS HAZARD CLASS: NOT APPLICABLE.
16.3. NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) RATING:
HEALTH 2
FLAMMABILITY 0
REACTIVITY 0
SPECIAL HAZARD
16.4. DOCUMENT REVISION:
LAST REVISION DATE: 2021-10-06
DISCLAIMER:
WHEN HANDLED PROPERLY BY QUALIFIED PERSONNEL, THE PRODUCT DESCRIBED HEREIN
DOES NOT PRESENT A SIGNIFICANT HEALTH OR SAFETY HAZARD. ALTERATION OF ITS
CHARACTERISTICS BY CONCENTRATION, EVAPORATION, ADDITION OF OTHER
SUBSTANCES, OR OTHER MEANS MAY PRESENT HAZARDS NOT SPECIFICALLY ADDRESSED
HEREIN AND WHICH MUST BE EVALUATED BY THE USER. THE INFORMATION FURNISHED
HEREIN IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST DATA CURRENTLY
AVAILABLE TO US. NO WARRANTY, EXPRESSED OR IMPLIED, IS MADE AND RICCA
CHEMICAL COMPANY ASSUMES NO LEGAL RESPONSIBILITY OR LIABILITY WHATSOEVER
RESULTING FROM ITS USE.