| Common Name: | HYDROFLUORIC ACID, 2% (V/V) |
| Manufacturer: | RICCA CHEMICAL |
| SDS Revision Date: | 10/6/2021 |
| SDS Format: | No Format Specified |
| Item Number(s): | 45E548 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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R
RICCA CHEMICAL COMPANY(R*)
SAFETY DATA SHEET
CLASSIFIED ACCORDING TO OSHA HAZARD COMMUNICATION STANDARD (HCS)
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER
TRADE NAME OR DESIGNATION: HYDROFLUORIC ACID, 2% (V/V)
PRODUCT NUMBER: 3819.2
OTHER IDENTIFYING PRODUCT NUMBERS: 3819.2-1, 3819.2-100, 3819.2-32
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE: GENERAL LABORATORY REAGENT
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
COMPANY: RICCA CHEMICAL COMPANY
ADDRESS:
448 WEST FORK DRIVE
ARLINGTON, TX 76012
USA
TELEPHONE: 888-467-4222
1.4. EMERGENCY TELEPHONE NUMBER (24 HOURS):
CHEMTREC (USA): 800-424-9300
CHEMTREC (INTERNATIONAL): 1+703-527-3887
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FOR THE FULL TEXT OF THE HAZARD AND PRECAUTIONARY STATEMENTS LISTED BELOW,
SEE SECTION 16.
HAZARD CLASS CATEGORY HAZARD PRECAUTIONARY
STATEMENTS STATEMENTS
ACUTE TOXICITY - CATEGORY 2 H300 P264, P270, P301+P310,
ORAL P321, P330, P405, P501
ACUTE TOXICITY - CATEGORY 3 H311 P280, P302+P352, P312,
DERMAL P321, P361, P405, P501
ACUTE TOXICITY - CATEGORY 3 H331 P261, P271, P304+P340,
INHALATION P311, P321, P403+P233,
P405, P501
SKIN CORROSION / CATEGORY 1A H314 P260, P264, P280,
IRRITATION P301+P330+P331,
P303+P361+P353, P363,
P304+P340, P310, P321,
P305+P351+P338, P405,
P501
EYE DAMAGE / CATEGORY 2A H319 P264, P280, P305+P351+P338,
IRRITATION P337+P313
RESPIRATORY CATEGORY 1 H334 P261, P285, P304+P341,
SENSITIZER P342+P311, P501
SKIN SENSITIZER CATEGORY 1 H317 P261, P272, P280, P302+P352,
P332+P313, P321, P363, P501
GERM CELL CATEGORY 2 H341 P201, P202, P280, P308+P313,
MUTAGENICITY P405, P501
SPECIFIC TARGET CATEGORY 1 H370 P260, P264, P270, P307+P311,
ORGANS/SYSTEMIC P321, P405, P501
TOXICITY FOLLOWING
SINGLE EXPOSURE
SPECIFIC TARGET CATEGORY 1 H372 P260, P264, P270, P314, P501
ORGANS/SYSTEMIC
TOXICITY FOLLOWING
REPEATED EXPOSURE
CORROSIVE TO CATEGORY 1 H290 P234, P390, P406
METALS
2.2. GHS LABEL ELEMENTS:
PICTOGRAMS:
HEALTH HAZARD
SKULLS AND CROSSBONES
CORROSION
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
HAZARD NUMBER HAZARD STATEMENT
H290 MAY BE CORROSIVE TO METALS.
H300 FATAL IF SWALLOWED.
H311 TOXIC IN CONTACT WITH SKIN.
H314 CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
H317 MAY CAUSE AN ALLERGIC SKIN REACTION.
H319 CAUSES SERIOUS EYE IRRITATION.
H331 TOXIC IF INHALED.
H334 MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING
DIFFICULTIES IF INHALED.
H341 SUSPECTED OF CAUSING GENETIC DEFECTS.
H370 CAUSES DAMAGE TO ORGANS.
H372 CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR
REPEATED EXPOSURE.
PRECAUTIONARY STATEMENTS:
PRECAUTIONARY NUMBER PRECAUTIONARY STATEMENT
P201 OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202 DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE
BEEN READ AND UNDERSTOOD.
P234 KEEP ONLY IN ORIGINAL CONTAINER.
P260 DO NOT BREATHE FUMES, MIST, VAPORS, OR SPRAY.
P261 AVOID BREATHING FUMES, MIST, VAPORS, OR SPRAY.
P264 WASH ARMS, HANDS AND FACE THOROUGHLY AFTER
HANDLING.
P270 DO NOT EAT, DRINK OR SMOKE WHEN USING THIS
PRODUCT.
P271 USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P272 CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED
OUT OF THE WORKPLACE.
P280 WEAR PROTECTIVE GLOVES AND EYE PROTECTION.
P285 IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY
PROTECTION.
P301+P310 IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN.
P301+P330+P331 IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
P302+P352 IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P303+P361+P353 IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
RINSE SKIN WITH WATER.
P304+P340 IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE
FOR BREATHING.
P304+P341 IF INHALED:
IF BREATHING IS DIFFICULT, REMOVE PERSON TO FRESH
AIR AND KEEP COMFORTABLE FOR BREATHING.
P305+P351+P338 IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES.
REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO.
CONTINUE RINSING.
P307+P311 IF EXPOSED: CALL A POISON CENTER OR PHYSICIAN.
P308+P313 IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
P310 IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN.
P311 CALL A POISON CENTER OR PHYSICIAN.
P312 CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL
UNWELL.
P314 GET MEDICAL ATTENTION IF YOU FEEL UNWELL.
P321 SPECIFIC TREATMENT (TREAT WITH CALCIUM GLUCONATE
GEL).
P330 RINSE MOUTH.
P332+P313 IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION.
P337+P313 IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
P342+P311 IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR PHYSICIAN.
P361 TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING
AND WASH IT BEFORE REUSE.
P363 WASH CONTAMINATED CLOTHING BEFORE REUSE.
P390 ABSORB SPILLAGE TO PREVENT MATERIAL DAMAGE.
P403+P233 STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER
TIGHTLY CLOSED.
P405 STORE LOCKED UP.
P406 STORE IN CORROSIVE RESISTANT CONTAINER WITH A
RESISTANT INNER LINER.
P501 DISPOSE OF CONTENTS IN ACCORDANCE WITH LOCAL,
STATE, FEDERAL AND INTERNATIONAL REGULATIONS.
2.4. HAZARDS NOT OTHERWISE CLASSIFIED OR COVERED BY GHS:
DATA NOT AVAILABLE.
| SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS | |
3.1. COMPONENTS OF SUBSTANCE OR MIXTURE:
CHEMICAL NAME FORMULA MOLECULAR WEIGHT CAS NUMBER WEIGHT%
WATER H2O 18.01 G/MOL 7732-18-5 98.90
HYDROFLUORIC ACID HF 20.00 G/MOL 7664-39-3 1.10
| SECTION 4: FIRST-AID MEASURES | |
4.1. GENERAL FIRST AID INFORMATION:
EYE CONTACT:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
CORROSIVE!
CAUSES IRRITATION AND BURNS. CAN CAUSE BURNS THAT MAY LEAD TO PERMANENT
IMPAIRMENT OF VISION, INCLUDING BLINDNESS.
INHALATION:
IF INHALED:
IF BREATHING IS DIFFICULT, REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE
FOR BREATHING.
SKIN CONTACT:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER.
SKIN CONTACT MAY CAUSE BURNS WHICH MAY NOT BE IMMEDIATELY APPARENT OR
PAINFUL. THE BURNS CAN BE BONE DEEP.
INGESTION:
IF SWALLOWED:
RINSE MOUTH. DO NOT INDUCE VOMITING. DO NOT INDUCE VOMITING. GIVE LARGE
QUANTITY OF WATER. CALL A PHYSICIAN IMMEDIATELY.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, ACUTE AND DELAYED:
FATAL IF SWALLOWED. TOXIC IN CONTACT WITH SKIN. CAUSES SEVERE SKIN BURNS
AND EYE DAMAGE. MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES SERIOUS EYE
IRRITATION. TOXIC IF INHALED. MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR
BREATHING DIFFICULTIES IF INHALED. SUSPECTED OF CAUSING GENETIC DEFECTS.
CAUSES DAMAGE TO ORGANS. CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR
REPEATED EXPOSURE. CAUSES SEVERE BURNS WHICH MAY NOT BE IMMEDIATELY
NOTICEABLE. MAY BE FATAL IF SWALLOWED. DO NOT GET IN EYES, ON SKIN, OR
ON CLOTHING. AVOID BREATHING VAPOR. USE WITH ADEQUATE VENTILATION. IF
SWALLOWED, DO NOT INDUCE VOMITING. GIVE LARGE QUANTITY OF WATER AND CALL
A PHYSICIAN. WASH AREAS OF CONTACT WITH PLENTY OF WATER FOR 15 MINUTES.
FOR EYES, GET MEDICAL ATTENTION. FIRST AID PROCEDURES SHOULD BE PRE-PLANNED
FOR HYDROFLUORIC ACID EMERGENCIES BEFORE BEGINNING PROCESS.
EYE CONTACT:
CORROSIVE!
CAUSES IRRITATION AND BURNS. CAN CAUSE BURNS THAT MAY LEAD TO PERMANENT
IMPAIRMENT OF VISION, INCLUDING BLINDNESS.
SKIN CONTACT:
SKIN CONTACT MAY CAUSE BURNS WHICH MAY NOT BE IMMEDIATELY APPARENT OR
PAINFUL. THE BURNS CAN BE BONE DEEP.
CHRONIC EFFECTS / CARCINOGENICITY:
CHRONIC EXPOSURES MAY CAUSE MOTTLING OF TEETH AND BONE DAMAGE AND
FLUOROSIS. SYMPTOMS OF FLUOROSIS INCLUDE BRITTLE BONES, WEIGHT LOSS,
ANEMIA, CALCIFIED LIGAMENTS, GENERAL ILL HEALTH AND JOINT STIFFNESS.
4.3. MEDICAL ATTENTION OR SPECIAL TREATMENT NEEDED:
IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. SPECIFIC TREATMENT (TREAT
WITH CALCIUM GLUCONATE GEL). DO NOT ALLOW VICTIM TO KEEP EYES SHUT.
CHECK FOR AND REMOVE ANY CONTACT LENSES. FLUSH IMMEDIATELY WITH WATER FOR
AT LEAST 15 MINUTES. CALL A PHYSICIAN. REMOVE TO FRESH AIR. GIVE ARTIFICIAL
RESPIRATION IF NECESSARY. IF BREATHING IS DIFFICULT, GIVE OXYGEN. WASH
AREAS OF CONTACT IMMEDIATELY WITH WATER FOR AT LEAST 15 MINUTES. SOAK THE
AFFECTED AREA WITH 70% DENATURED ETHYL ALCOHOL SOLUTION OR EPSOM SALTS FOR
1 TO 4 HOURS. CALL A PHYSICIAN IMMEDIATELY. DO NOT INDUCE VOMITING. GIVE
LARGE QUANTITY OF WATER. CALL A PHYSICIAN IMMEDIATELY.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
USE DRY CHEMICAL, ALCOHOL FOAM, OR CARBON DIOXIDE FOR EXTINGUISHING THE
SURROUNDING FIRE. USE WATER AS FOG IN FLOODING QUANTITIES.
5.2. SPECIFIC HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NOT CONSIDERED TO BE A FIRE OR EXPLOSION HAZARD. MAY REACT WITH METALS TO
RELEASE FLAMMABLE HYDROGEN GAS.
5.3. SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
USE PROTECTIVE CLOTHING AND BREATHING EQUIPMENT APPROPRIATE FOR THE
SURROUNDING FIRE.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
WEAR PROTECTIVE GLOVES AND EYE PROTECTION. IN CASE OF INADEQUATE
VENTILATION WEAR RESPIRATORY PROTECTION.
6.2. CLEANUP AND CONTAINMENT METHODS AND MATERIALS:
COVER THE SPILL WITH SODIUM BICARBONATE OR A MIXTURE OF SODA ASH AND SLAKED
LIME (50-50). MIX AND SPRAY WATER CAUTIOUSLY. SCOOP UP AND ADD SLOWLY TO A
LARGE CONTAINER OF WATER. WHEN REACTION IS COMPLETE, NEUTRALIZE AND WASH
DOWN THE DRAIN WITH LARGE EXCESS OF WATER. ALWAYS DISPOSE OF IN ACCORDANCE
WITH LOCAL, STATE AND FEDERAL REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING AND STORAGE CONDITIONS:
STORE IN CORROSIVE RESISTANT CONTAINER WITH A RESISTANT INNER LINER. AS
WITH ALL CHEMICALS, WASH HANDS THOROUGHLY AFTER HANDLING. AVOID CONTACT
WITH EYES AND SKIN. PROTECT FROM FREEZING AND PHYSICAL DAMAGE. DO NOT MIX
WITH BASES. CONTACT WITH WATER WILL GENERATE HEAT.
| SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION | |
8.1 CONTROL PARAMETERS:
CHEMICAL NAME LIMIT TYPE COUNTRY EXPOSURE LIMIT INFORMATION SOURCE
HYDROFLUORIC TWA USA 3 PPM TWA U.S. - OSHA -
ACID (AS F) FINAL PELS - TIME
(7664-39-3) WEIGHTED AVERAGES
(TWAS)
HYDROFLUORIC TLV-CEILING USA 2 PPM CEILING ACGIH - THRESHOLD
ACID (AS F) LIMIT VALUES -
(7664-39-3) CEILINGS (TLV-C)
HYDROFLUORIC TLV-TWA USA 0.5 PPM TWA ACGIH - THRESHOLD
ACID (AS F) LIMIT VALUES -
(7664-39-3) TIME WEIGHTED
AVERAGES (TLV-TWA)
HYDROFLUORIC TWA USA 2.5 MG/M3 TWA U.S. - OSHA -
ACID (AS F); 2.5 FINAL PELS - TIME
(7664-39-3) MG/M3 TWA WEIGHTED AVERAGES
(DUST) (TWAS)
HYDROFLUORIC TLV-TWA USA 2.5 MG/M3 TWA ACGIH - THRESHOLD
ACID (AS F) LIMIT VALUES -
(7664-39-3) TIME WEIGHTED
AVERAGES (TLV-TWA)
8.2. EXPOSURE CONTROLS:
ENGINEERING CONTROLS:
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. A SYSTEM OF LOCAL AND/OR
GENERAL EXHAUST IS RECOMMENDED TO KEEP EMPLOYEE EXPOSURES BELOW THE
AIRBORNE EXPOSURE LIMIT.
RESPIRATORY PROTECTION:
IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE CONCENTRATIONS BELOW
RECOMMENDED EXPOSURE LIMITS, AN APPROVED RESPIRATOR MUST BE WORN.
SKIN PROTECTION:
WEAR PROTECTIVE GLOVES AND EYE PROTECTION. CHEMICAL RESISTANT GLOVES,
NEOPRENE OR PVC.
EYE PROTECTION:
WEAR PROTECTIVE GLOVES AND EYE PROTECTION. SAFETY GLASSES OR GOGGLES.
8.3. PERSONAL PROTECTIVE EQUIPMENT:
WEAR PROTECTIVE GLOVES AND EYE PROTECTION. IN CASE OF INADEQUATE
VENTILATION WEAR RESPIRATORY PROTECTION. IF ENGINEERING CONTROLS DO NOT
MAINTAIN AIRBORNE CONCENTRATIONS BELOW RECOMMENDED EXPOSURE LIMITS, AN
APPROVED RESPIRATOR MUST BE WORN. CHEMICAL RESISTANT GLOVES, NEOPRENE OR
PVC. SAFETY GLASSES OR GOGGLES.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE: COLORLESS LIQUID
PHYSICAL STATE: LIQUID
ODOR: DATA NOT AVAILABLE.
ODOR THRESHOLD: DATA NOT AVAILABLE.
PH: <2
MELTING/FREEZING POINT: 0.0 DEG. C
INITIAL BOILING POINT/RANGE: 100 DEG. C - 100 DEG. C
FLASH POINT: DATA NOT AVAILABLE.
EVAPORATION RATE: DATA NOT AVAILABLE.
FLAMMABILITY: DATA NOT AVAILABLE.
FLAMMABILITY/EXPLOSIVE LIMITS: DATA NOT AVAILABLE.
VAPOR PRESSURE: DATA NOT AVAILABLE.
VAPOR DENSITY: DATA NOT AVAILABLE.
RELATIVE DENSITY: 1.00
SOLUBILITY: MISCIBLE
PARTITION COEFFICIENT: DATA NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: DATA NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: DATA NOT AVAILABLE.
VISCOSITY: DATA NOT AVAILABLE.
EXPLOSIVE PROPERTIES: DATA NOT AVAILABLE.
OXIDIZING PROPERTIES: DATA NOT AVAILABLE.
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY AND CHEMICAL STABILITY:
STABLE UNDER NORMAL CONDITIONS OF USE AND STORAGE.
10.2. POSSIBILITY OF HAZARDOUS REACTIONS:
DATA NOT AVAILABLE.
10.3. CONDITIONS TO AVOID AND INCOMPATIBLE MATERIALS:
KEEP ONLY IN ORIGINAL CONTAINER. AVOID CONTACT WITH METALS, CONCRETE, GLASS
AND CERAMICS. CONTACT WITH METALS MAY FORM FLAMMABLE HYDROGEN GAS.
10.4. HAZARDOUS DECOMPOSITION PRODUCTS: WILL NOT OCCUR.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY - ORAL EXPOSURE:
FATAL IF SWALLOWED. WASH ARMS, HANDS AND FACE THOROUGHLY AFTER HANDLING.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. SPECIFIC TREATMENT (TREAT
WITH CALCIUM GLUCONATE GEL). RINSE MOUTH. STORE LOCKED UP. DISPOSE OF
CONTENTS IN ACCORDANCE WITH LOCAL, STATE, FEDERAL AND INTERNATIONAL
REGULATIONS.
ACUTE TOXICITY - DERMAL EXPOSURE:
TOXIC IN CONTACT WITH SKIN. WEAR PROTECTIVE GLOVES AND EYE PROTECTION.
IF ON SKIN:
WASH WITH PLENTY OF SOAP AND WATER. CALL A POISON CENTER OR PHYSICIAN IF
YOU FEEL UNWELL. SPECIFIC TREATMENT (TREAT WITH CALCIUM GLUCONATE GEL).
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
STORE LOCKED UP. DISPOSE OF CONTENTS IN ACCORDANCE WITH LOCAL, STATE,
FEDERAL AND INTERNATIONAL REGULATIONS.
ACUTE TOXICITY - INHALATION EXPOSURE:
TOXIC IF INHALED. AVOID BREATHING FUMES, MIST, VAPORS, OR SPRAY. USE ONLY
OUTDOORS OR IN A WELL-VENTILATED AREA.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER OR PHYSICIAN. SPECIFIC TREATMENT (TREAT WITH CALCIUM
GLUCONATE GEL). STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY
CLOSED. STORE LOCKED UP. DISPOSE OF CONTENTS IN ACCORDANCE WITH LOCAL,
STATE, FEDERAL AND INTERNATIONAL REGULATIONS.
ACUTE TOXICITY - OTHER INFORMATION:
LC50, INHALATION, RAT: 1276 PPM/1 H.
SKIN CORROSION AND IRRITATION:
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE. DO NOT BREATHE FUMES, MIST,
VAPORS, OR SPRAY. WASH ARMS, HANDS AND FACE THOROUGHLY AFTER HANDLING.
WEAR PROTECTIVE GLOVES AND EYE PROTECTION. IF SWALLOWED: RINSE MOUTH.
DO NOT INDUCE VOMITING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. IMMEDIATELY
CALL A POISON CENTER OR PHYSICIAN. SPECIFIC TREATMENT (TREAT WITH CALCIUM
GLUCONATE GEL). IF IN EYES: RINSE CAUTIOUSLY WITH WATER FOR SEVERAL
MINUTES. REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE
RINSING. STORE LOCKED UP. DISPOSE OF CONTENTS IN ACCORDANCE WITH LOCAL,
STATE, FEDERAL AND INTERNATIONAL REGULATIONS.
SERIOUS EYE DAMAGE AND IRRITATION:
CAUSES SERIOUS EYE IRRITATION. WASH ARMS, HANDS AND FACE THOROUGHLY AFTER
HANDLING. WEAR PROTECTIVE GLOVES AND EYE PROTECTION.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
RESPIRATORY SENSITIZATION:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
AVOID BREATHING FUMES, MIST, VAPORS, OR SPRAY. IN CASE OF INADEQUATE
VENTILATION WEAR RESPIRATORY PROTECTION.
IF INHALED:
IF BREATHING IS DIFFICULT, REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE
FOR BREATHING.
IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR PHYSICIAN. DISPOSE OF CONTENTS IN ACCORDANCE WITH
LOCAL, STATE, FEDERAL AND INTERNATIONAL REGULATIONS.
SKIN SENSITIZATION:
MAY CAUSE AN ALLERGIC SKIN REACTION. AVOID BREATHING FUMES, MIST, VAPORS,
OR SPRAY. CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE
WORKPLACE. WEAR PROTECTIVE GLOVES AND EYE PROTECTION.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OCCURS:
GET MEDICAL ATTENTION. SPECIFIC TREATMENT (TREAT WITH CALCIUM GLUCONATE
GEL). WASH CONTAMINATED CLOTHING BEFORE REUSE. DISPOSE OF CONTENTS IN
ACCORDANCE WITH LOCAL, STATE, FEDERAL AND INTERNATIONAL REGULATIONS.
GERM CELL MUTAGENICITY:
SUSPECTED OF CAUSING GENETIC DEFECTS. OBTAIN SPECIAL INSTRUCTIONS BEFORE
USE. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND
UNDERSTOOD. WEAR PROTECTIVE GLOVES AND EYE PROTECTION.
IF EXPOSED OR CONCERNED:
GET MEDICAL ATTENTION. STORE LOCKED UP. DISPOSE OF CONTENTS IN ACCORDANCE
WITH LOCAL, STATE, FEDERAL AND INTERNATIONAL REGULATIONS.
CARCINOGENICITY: NOT APPLICABLE.
REPRODUCTIVE TOXICITY: NOT APPLICABLE.
SPECIFIC TARGET ORGAN TOXICITY FROM SINGLE EXPOSURE:
CAUSES DAMAGE TO ORGANS. DO NOT BREATHE FUMES, MIST, VAPORS, OR SPRAY.
WASH ARMS, HANDS AND FACE THOROUGHLY AFTER HANDLING. DO NOT EAT, DRINK OR
SMOKE WHEN USING THIS PRODUCT. IF EXPOSED: CALL A POISON CENTER OR
PHYSICIAN. SPECIFIC TREATMENT (TREAT WITH CALCIUM GLUCONATE GEL). STORE
LOCKED UP. DISPOSE OF CONTENTS IN ACCORDANCE WITH LOCAL, STATE, FEDERAL
AND INTERNATIONAL REGULATIONS.
SPECIFIC TARGET ORGAN TOXICITY FROM REPEATED EXPOSURE:
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. DO NOT
BREATHE FUMES, MIST, VAPORS, OR SPRAY. WASH ARMS, HANDS AND FACE THOROUGHLY
AFTER HANDLING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
GET MEDICAL ATTENTION IF YOU FEEL UNWELL. DISPOSE OF CONTENTS IN ACCORDANCE
WITH LOCAL, STATE, FEDERAL AND INTERNATIONAL REGULATIONS.
ASPIRATION HAZARD: NOT APPLICABLE.
ADDITIONAL TOXICOLOGY INFORMATION: DATA NOT AVAILABLE.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. ECOTOXICITY: NOT APPLICABLE.
12.2. PERSISTENCE AND DEGRADABILITY: DATA NOT AVAILABLE.
12.3. BIOACCUMULATIVE POTENTIAL: DATA NOT AVAILABLE.
12.4. MOBILITY IN SOIL: DATA NOT AVAILABLE.
12.5. OTHER ADVERSE ECOLOGICAL EFFECTS: DATA NOT AVAILABLE.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS: DATA NOT AVAILABLE.
| SECTION 14: TRANSPORTATION INFORMATION | |
14.1. TRANSPORTATION BY LAND-DEPARTMENT OF TRANSPORTATION (DOT, UNITED
STATES OF AMERICA):
SIZES: 1 L, 4 L, 100 ML
UN NUMBER: UN1790
PROPER SHIPPING NAME: HYDROFLUORIC ACID SOLUTION
HAZARD CLASS: 8 (6.1)
PACKING GROUP: II
HAZARD LABEL(S):
CORROSIVE, CLASS/DIVISION 8
CLASS 6.1, TOXIC
14.2. TRANSPORTATION BY AIR - INTERNATIONAL AIR TRANSPORT ASSOCIATION
(IATA):
SIZES: 1 L, 4 L, 100 ML
UN NUMBER: UN1790
PROPER SHIPPING NAME: HYDROFLUORIC ACID SOLUTION
HAZARD CLASS: 8 (6.1)
PACKING GROUP: II
HAZARD LABEL(S):
CORROSIVE, CLASS/DIVISION 8
CLASS 6.1, TOXIC
14.3 TRANSPORTATION OF DANGEROUS GOODS (TDG, CANADA):
SIZES: 1 L, 4 L, 100 ML
UN NUMBER: UN1790
PROPER SHIPPING NAME: HYDROFLUORIC ACID SOLUTION
HAZARD CLASS: 8 (6.1)
PACKING GROUP: II
HAZARD LABEL(S):
CLASS 8, CORROSIVES
CLASS 6.1, TOXIC
| SECTION 15: REGULATORY INFORMATION | |
15.1. OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA) HAZARDS:
NOT LISTED.
15.2. SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) 302 EXTREMELY
HAZARDOUS SUBSTANCES:
HYDROFLUORIC ACID (CAS # 7664-39-3): 100 LB EPCRA RQ
HYDROFLUORIC ACID (CAS # 7664-39-3): 100 LB TPQ
15.3. SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) 311/312 HAZARDOUS
CHEMICALS:
HYDROFLUORIC ACID (CAS # 7664-39-3):
100 LB FINAL RQ
45.4 KG FINAL RQ
15.4. SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) 313 TOXIC RELEASE
INVENTORY (TRI):
HYDROFLUORIC ACID (CAS # 7664-39-3): 1.0% DE MINIMIS CONCENTRATION
15.5. MASSACHUSETTS RIGHT-TO-KNOW SUBSTANCE LIST:
HYDROFLUORIC ACID (CAS # 7664-39-3): EXTRAORDINARILY HAZARDOUS
15.6. PENNSYLVANIA RIGHT-TO-KNOW HAZARDOUS SUBSTANCES:
HYDROFLUORIC ACID (CAS # 7664-39-3): ENVIRONMENTAL HAZARD
HYDROFLUORIC ACID (CAS # 7664-39-3): PRESENT
WATER (CAS # 7732-18-5): PRESENT
15.7. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW COMPONENTS:
HYDROFLUORIC ACID (CAS # 7664-39-3): CORROSIVE
HYDROFLUORIC ACID (CAS # 7664-39-3): SN 0936
HYDROFLUORIC ACID (CAS # 7664-39-3): SN 3759
HYDROFLUORIC ACID (CAS # 7664-39-3):
SN 3759 100 LB TPQ; SN 1014 500 LB TPQ (HYDROGEN FLUORIDE GAS ONLY)
15.8. CALIFORNIA PROPOSITION 65: NOT LISTED.
15.9. CANADA DOMESTIC SUBSTANCES LIST / NON-DOMESTIC SUBSTANCES LIST
(DSL/NDSL):
HYDROFLUORIC ACID (CAS # 7664-39-3): PRESENT (DSL)
WATER (CAS # 7732-18-5): PRESENT (DSL)
15.10. UNITED STATES OF AMERICA TOXIC SUBSTANCES CONTROL ACT (TSCA) LIST:
ALL COMPONENTS OF THIS SOLUTION ARE LISTED AS ACTIVE ON THE TSCA INVENTORY
OR ARE MIXTURES (HYDRATES) OF ACTIVE ITEMS LISTED ON THE TSCA INVENTORY.
HYDROFLUORIC ACID (CAS # 7664-39-3): PRESENT [T]
WATER (CAS # 7732-18-5): PRESENT
15.11. EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES
(EINECS), EUROPEAN:
LIST OF NOTIFIED CHEMICAL SUBSTANCES (ELINCS), AND NO LONGER POLYMERS
(NLP):
HYDROFLUORIC ACID (CAS # 7664-39-3): 231-634-8
WATER (CAS # 7732-18-5): 231-791-2
WATER (CAS # 7732-18-5): 232-148-9
| SECTION 16: OTHER INFORMATION | |
16.1. FULL TEXT OF HAZARD STATEMENTS AND PRECAUTIONARY STATEMENTS:
MAY BE CORROSIVE TO METALS. FATAL IF SWALLOWED. TOXIC IN CONTACT WITH SKIN.
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE. MAY CAUSE AN ALLERGIC SKIN
REACTION. CAUSES SERIOUS EYE IRRITATION. TOXIC IF INHALED. MAY CAUSE
ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED. SUSPECTED
OF CAUSING GENETIC DEFECTS. CAUSES DAMAGE TO ORGANS. CAUSES DAMAGE TO
ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. KEEP ONLY IN ORIGINAL CONTAINER.
DO NOT BREATHE FUMES, MIST, VAPORS, OR SPRAY. WASH ARMS, HANDS AND FACE
THOROUGHLY AFTER HANDLING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS
PRODUCT. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. CONTAMINATED
WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR PROTECTIVE
GLOVES AND EYE PROTECTION. IN CASE OF INADEQUATE VENTILATION WEAR
RESPIRATORY PROTECTION.
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EXPOSED:
CALL A POISON CENTER OR PHYSICIAN. GET MEDICAL ATTENTION IF YOU FEEL
UNWELL. SPECIFIC TREATMENT (TREAT WITH CALCIUM GLUCONATE GEL).
IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR PHYSICIAN. WASH CONTAMINATED CLOTHING BEFORE REUSE.
ABSORB SPILLAGE TO PREVENT MATERIAL DAMAGE. STORE IN A WELL-VENTILATED
PLACE. KEEP CONTAINER TIGHTLY CLOSED.
STORE LOCKED UP. STORE IN CORROSIVE RESISTANT CONTAINER WITH A RESISTANT
INNER LINER.
DISPOSE OF CONTENTS IN ACCORDANCE WITH LOCAL, STATE, FEDERAL AND
INTERNATIONAL REGULATIONS.
16.2. MISCELLANEOUS HAZARD CLASSES:
CANADIAN CARCINOGENICITY HAZARD CLASS: NOT APPLICABLE.
PHYSICAL HAZARDS NOT OTHERWISE CLASSIFIED (PHNOC): NOT APPLICABLE.
HEALTH HAZARDS NOT OTHERWISE CLASSIFIED (HHNOC): NOT APPLICABLE.
BIOHAZARDOUS INFECTIOUS MATERIALS HAZARD CLASS: NOT APPLICABLE.
16.3. NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) RATING:
HEALTH 3
FLAMMABILITY 0
REACTIVITY 0
SPECIAL HAZARD
16.4. DOCUMENT REVISION:
LAST REVISION DATE: 2021-10-06
DISCLAIMER:
WHEN HANDLED PROPERLY BY QUALIFIED PERSONNEL, THE PRODUCT DESCRIBED HEREIN
DOES NOT PRESENT A SIGNIFICANT HEALTH OR SAFETY HAZARD. ALTERATION OF ITS
CHARACTERISTICS BY CONCENTRATION, EVAPORATION, ADDITION OF OTHER
SUBSTANCES, OR OTHER MEANS MAY PRESENT HAZARDS NOT SPECIFICALLY ADDRESSED
HEREIN AND WHICH MUST BE EVALUATED BY THE USER. THE INFORMATION FURNISHED
HEREIN IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST DATA CURRENTLY
AVAILABLE TO US. NO WARRANTY, EXPRESSED OR IMPLIED, IS MADE AND RICCA
CHEMICAL COMPANY ASSUMES NO LEGAL RESPONSIBILITY OR LIABILITY WHATSOEVER
RESULTING FROM ITS USE.